阅读说明：本技术 一种超顺排碳纳米管环氧树脂复合材料及其制备方法和应用 (Super-ordered carbon nanotube epoxy resin composite material and preparation method and application thereof ) 是由 王胜强 高锋 张晖 于 2020-07-14 设计创作，主要内容包括：本发明涉及一种超顺排碳纳米管环氧树脂复合材料及其制备方法和应用,所述超顺排碳纳米管环氧树脂复合材料包括母料和固化剂；所述母料包括环氧树脂和分散于所述环氧树脂中的超顺排碳纳米管。本发明首次将长径比更高、缺陷更少的超顺排碳纳米管添加入环氧树脂中形成复合材料,仅需非常少的添加量就可获得高导电率极低阈值的导电材料。进一步地,本发明以非共价官能化的表面处理技术对超顺排碳纳米管进行改性,提高其在环氧树脂中的分散以及与环氧树脂的结合能力,且不会在碳管表面引入缺陷,从而提高碳管的本征电导率。同时,通过不同机械分散方法的组合,进一步地提高超顺排碳纳米管在环氧树脂中的分散能力。(The invention relates to a super-ordered carbon nanotube epoxy resin composite material and a preparation method and application thereof, wherein the super-ordered carbon nanotube epoxy resin composite material comprises a master batch and a curing agent; the masterbatch comprises epoxy resin and carbon nanotubes dispersed in the epoxy resin. The invention adds the super-ordered carbon nano-tubes with higher length-diameter ratio and less defects into the epoxy resin for the first time to form the composite material, and the conductive material with high conductivity and extremely low threshold can be obtained only by very little addition amount. Furthermore, the invention modifies the carbon nanotube with noncovalent functionalization surface treatment technology, improves the dispersion of the carbon nanotube in epoxy resin and the binding capacity of the carbon nanotube with the epoxy resin, and does not introduce defects on the surface of the carbon tube, thereby improving the intrinsic conductivity of the carbon tube. Meanwhile, the dispersing ability of the super-ordered carbon nano-tubes in the epoxy resin is further improved through the combination of different mechanical dispersing methods.)

1. The carbon nanotube epoxy resin composite material is characterized by comprising a master batch and a curing agent; the masterbatch comprises epoxy resin and carbon nanotubes dispersed in the epoxy resin.

2. The carbon nanotube epoxy composite material of claim 1, wherein the epoxy comprises bisphenol a epoxy;

preferably, the curing agent comprises an anhydride curing agent and/or an amine curing agent;

preferably, the diameter of the super-ordered carbon nanotube is 6-15nm, and the length is 290-310 μm.

3. The carbon nanotube epoxy composite material of claim 1 or 2, wherein the carbon nanotubes are present in the masterbatch in an amount of 0.0002 to 1.0 wt% by weight;

preferably, the mass ratio of the master batch to the curing agent is 10 (8-11).

4. The carbon nanotube epoxy composite of any of claims 1-3, wherein the carbon nanotubes are surface modified;

preferably, the carbon nanotubes are surface-modified by a surfactant in a non-covalent manner;

preferably, the surfactant comprises a nonionic surfactant;

preferably, the non-ionic surfactant comprises triton.

5. The carbon nanotube epoxy composite material of claim 4, wherein the surface modified carbon nanotubes are prepared by a method comprising:

and mixing the carbon nano tubes with the surface modifier solution, stirring, and ultrasonically dispersing to obtain the surface modified carbon nano tubes with super rows.

6. The carbon nanotube epoxy composite material of claim 5, wherein the concentration of said carbon nanotubes in said surface modifier solution is (1-2) g/L;

preferably, the stirring temperature is 20-30 ℃, and the stirring time is 18-30 h;

preferably, the ultrasonic dispersion comprises carrying out water bath type ultrasonic dispersion for 10-14h and then carrying out probe type ultrasonic dispersion for 5-15 min.

7. The method of preparing a carbon nanotube epoxy composite material of any of claims 1-6, wherein the method comprises the steps of:

(1) mixing and dispersing the carbon nanotubes and the epoxy resin to obtain a master batch;

(2) mixing the master batch obtained in the step (1) with a curing agent and removing bubbles to obtain a mixture;

(3) and (3) pouring the mixture obtained in the step (2) into a mould for curing to obtain the carbon nanotube epoxy resin composite material with the super-ordered structure.

8. The method for preparing the carbon nanotube epoxy resin composite material as claimed in claim 7, wherein the mixing and dispersing manner of the step (1) comprises:

(S1) mixing and dispersing the carbon nanotubes and the epoxy resin in a high-speed mixer to obtain a blend;

(S2) the blend is further mixed and dispersed by a three-roll mill to obtain a master batch.

9. The method for preparing a carbon nanotube epoxy resin composite material as claimed in claim 8, wherein the temperature of the mixing and dispersing in (S1) is 70 to 90 ℃;

preferably, the stirring speed for mixing and dispersing in (S1) is 3000-5000rpm, and the stirring time is 1-3 h;

preferably, the epoxy resin is preheated at 70-90 ℃ for 20-40min before the mixing and dispersing in (S1);

preferably, the mixing and de-bubbling of step (2) is performed in a planetary de-bubbling blender.

10. Use of the carbon nanotube epoxy composite material of any one of claims 1-6 in the preparation of an electrically conductive material.

Technical Field

The invention belongs to the technical field of nano materials, relates to an epoxy resin composite material, a preparation method and an application thereof, in particular to a super-ordered carbon nanotube epoxy resin composite material, a preparation method and an application thereof, and particularly relates to a high-conductivity and extremely-low-threshold super-ordered carbon nanotube epoxy resin composite material, a preparation method and an application thereof.

Background

The epoxy material has excellent comprehensive performance and is widely applied to various fields. However, epoxy resin is an insulating material with a volume resistivity of up to 10¹⁶Omega cm, it can not be used in some fields requiring the material to have conductivity, such as electromagnetic shielding material, antistatic material, lightning protection material, etc. If the epoxy resin can be endowed with certain conductive performance, the application field of the epoxy resin must be greatly widened. In recent years, with the development of nanotechnology, researchers have developed various conductive nanoparticles, such as metal nanoparticles, metal nanowires, Carbon Nanotubes (CNTs), Graphene (Graphene), and the like, to improve the conductive properties of epoxy materials.

The conductive epoxy composite material is a composite conductive polymer, and the conductive mechanism of the conductive epoxy composite material is that a three-dimensional conductive network is formed by conductive filler in a resin matrix, and a large number of experimental research results show that when the content of the conductive filler in a composite system is increased to a certain critical content, the conductivity of the system is sharply increased, a narrow mutation area appears on a curve of the conductivity and the content of the conductive filler, in the area, any slight change of the content of the conductive filler can cause the obvious change of the resistivity, the phenomenon is generally called as the phenomenon of percolation, and after the mutation area, the conductivity of the system is smoothly restored along with the change of the content of the conductive filler. One factor that is closely related to how fast this region occurs is the geometric size of the filler, and the larger the aspect ratio, the easier the filler builds up a conductive network in the resin matrix, which occurs sooner. Among all the conductive fillers, carbon nanotubes have the obvious advantage of large length-diameter ratio compared with other conductive fillers (metal particles, carbon fibers, graphite flakes, graphite and the like) of 0 dimension, 1 dimension, 2 dimension, 3 dimension and the like, so that the carbon nanotubes are easy to contact with each other in a resin matrix, and are more favorable for forming a three-dimensional conductive network.

The carbon nano tube has excellent conductivity and large length-diameter ratio, and is an ideal choice for improving the conductivity of the epoxy resin, but the current application still has some problems: (1) the carbon nano tube has large specific surface area and high surface energy, and the carbon tube is very easy to agglomerate due to van der Waals force and fibrous structure and is difficult to completely disperse in resin; (2) in order to achieve better conductivity, the addition amount of a common short carbon tube (which is dozens of microns long) is higher, and the addition amount causes many problems of sharp increase of viscosity, incomplete curing, increase of defects of a composite material and the like for the resin.

Disclosure of Invention

Aiming at the defects of the prior art, the invention aims to provide an epoxy resin composite material, a preparation method and application thereof, in particular to a super-ordered carbon nanotube epoxy resin composite material, a preparation method and application thereof, and particularly provides a super-ordered carbon nanotube epoxy resin composite material with high conductivity and extremely low threshold value, a preparation method and application thereof.

In order to achieve the purpose, the invention adopts the following technical scheme:

in a first aspect, the invention provides a carbon nanotube epoxy resin composite material with super-ordered arrangement, which comprises a master batch and a curing agent; the masterbatch comprises epoxy resin and carbon nanotubes dispersed in the epoxy resin.

The super-aligned carbon nanotubes of the present invention can be prepared by CVD growth method, which is described in Fan S S, Chapline M G, Franklin N R, et al, Self-oriented regular arrays of carbon nanotubes and carbon field emission properties, science,1999,283(5401), 512. sub.514, Zhang X B, Jiang K L, Feng C, et al, Spingand processing properties from 4-inch water crystal sub-excellent-aligned carbon nanotube arrays, 705. Mat, 2006,18(12) 1505, Liu K, Sun Y H, chemistry L, et al, patent layer of carbon nanotubes of the present invention, 2008. sub.2. sub.8:

(a) depositing a catalyst on the silicon substrate to form a film;

(b) placing the silicon substrate in an argon atmosphere to reach the growth temperature of 660-680 ℃ and maintaining for 15 min;

(c) adding H into argon₂And C₂H₂Growth of carbon tubes was started.

Compared with common carbon nanotubes, the super-ordered carbon nanotubes are thinner, longer, straight and less in defects, and the length-diameter ratio is as high as 5 multiplied by 10⁴And the carbon nanotubes are far higher than the common carbon nanotubes and are easier to contact with each other, so that the construction of a conductive network in epoxy resin is facilitated. According to the invention, the super-ordered carbon nanotubes are added into the epoxy resin for the first time, and the conductive material with high conductivity (the conductivity reaches 3S/m when the addition amount is 0.3 wt%) and extremely low threshold (0.0011 wt%) can be obtained only by very small addition amount, so that the problems of viscosity surge, incomplete curing and the like of the resin can not be caused.

Preferably, the epoxy resin comprises a bisphenol a type epoxy resin.

The reason why the epoxy resin is preferably a bisphenol a type epoxy resin is that the properties of the bisphenol a type epoxy resin have the following characteristics due to its molecular structure: (1) can form a plurality of cured products with excellent performance with a plurality of curing agents, catalysts and additives, and can almost meet various use requirements; (2) the manufacturability of the resin is good. During curing, basically no micromolecular volatile matters are generated, the low-pressure forming can be realized, and the low-pressure forming can be dissolved in various solvents; (3) the condensate has high strength and bonding strength; (4) the condensate has higher corrosion resistance and electrical property; (5) the cured product has certain toughness and heat resistance.

Preferably, the curing agent includes an acid anhydride-based curing agent and/or an amine-based curing agent.

Preferably, the diameter of the super-ordered carbon nanotube is 6-15nm, and the length is 290-310 μm.

The diameters of the super-ordered carbon nanotubes can be 6nm, 8nm, 10nm, 12nm or 15nm, and other specific values in the numerical range can be selected, and are not described in detail herein.

The length of the super-ordered carbon nanotube can be 290 μm, 295 μm, 300 μm, 305 μm or 310 μm, and other specific values within the above numerical range can be selected, and are not described in detail herein.

The super-ordered carbon nano tube has very low defect content and Raman peak I_D/I_GIs 0.65-0.75.

Preferably, the mass percentage of the super-aligned carbon nanotubes in the masterbatch is 0.0002 to 1.0 wt%, such as 0.0002 wt%, 0.0006 wt%, 0.001 wt%, 0.002 wt%, 0.005 wt%, 0.01 wt%, 0.02 wt%, 0.05 wt%, 0.1 wt%, 0.2 wt%, 0.6 wt%, or 1.0 wt%, and other specific values within the above numerical range can be selected, and are not repeated herein.

The mass percentage of the super-ordered carbon nano tube in the master batch is specially selected to be in a numerical range of 0.0002-1.0 wt%, if the content of the filler exceeds the range, the viscosity of a system is increased sharply, blending steps cannot be carried out, and if the content of the filler is too low, a conductive network cannot be constructed, so that the super-ordered carbon nano tube does not contribute to the conductivity of resin, and is meaningless.

Preferably, the mass ratio of the master batch to the curing agent is 10 (8-11), for example, 10:8, 10:9, 10:10 or 10:11, and other specific values within the above numerical range can be selected, and are not described in detail herein.

The mass ratio of the master batch to the curing agent is specifically selected to be 10 (8-11), if the relative mass of the curing agent is too high, the master batch and the curing agent are excessively crosslinked, the material is excessively brittle, and if the relative mass of the curing agent is too low, the resin is incompletely cured, the glass transition temperature is reduced, and the mechanical property of the material is influenced.

Preferably, the carbon nanotubes with super-ordered rows are surface-modified carbon nanotubes with super-ordered rows.

Preferably, the carbon nanotubes are surface-modified by a surfactant.

The characteristic that the carbon nano material is difficult to disperse due to the large specific surface area of the carbon nano material is also an important condition for influencing the conductivity of the composite material because whether the carbon nano tube has excellent dispersibility in the high polymer composite material or not is further discussed in the invention, and how to better promote the dispersibility of the super-ordered carbon nano tube in the epoxy resin is also further discussed. In the prior art, covalent functionalization treatment methods such as acidification treatment and surface functional group connection are often adopted for the carbon tube to improve the dispersion of the carbon tube in resin and the binding capacity of the carbon tube with the resin, but although the methods can better improve the dispersion of the carbon tube, due to covalent reaction, defects can be introduced on the surface of the carbon tube, so that the structure of the carbon tube is damaged, and a conduction path of electrons is blocked, so that the intrinsic conductivity of the carbon tube is reduced, and the improvement of the conductivity of the composite material is finally not facilitated. The invention modifies the carbon nano-tube with noncovalent functionalization surface treatment technology, further improves the dispersion of the carbon nano-tube in epoxy resin and the binding capacity of the carbon nano-tube with the epoxy resin, does not introduce defects on the surface of the carbon nano-tube, causes the damage of the structure of the carbon nano-tube, and blocks the conduction path of electrons, thereby improving the intrinsic conductivity of the carbon nano-tube.

Preferably, the surfactant comprises a nonionic surfactant.

Preferably, the non-ionic surfactant comprises triton.

The reason why the non-ionic surfactant is preferably triton is that triton is common in non-ionic surfactants and has a better dispersing effect on multi-walled carbon tubes than anionic and cationic surfactants.

In the invention, the surface-modified super-ordered carbon nanotube is prepared by the following method:

and mixing the carbon nano tubes with the surface modifier solution, stirring, and ultrasonically dispersing to obtain the surface modified carbon nano tubes with super rows.

Preferably, the concentration of the super-ordered carbon nanotubes in the surface modifier solution is (1-2) g/L, for example, 1g/L, 1.2g/L, 1.5g/L, 1.8g/L, 2g/L, or the like, and other specific values within the above numerical range can be selected, and are not repeated herein.

Preferably, the stirring temperature is 20-30 ℃, for example, 20 ℃, 25 ℃,28 ℃ or 30 ℃, and the time is 18-30h, for example, 18h, 20h, 25h or 30h, and other specific values within the above numerical range can be selected, and are not described in detail herein.

Preferably, the ultrasonic dispersion includes performing water bath type ultrasonic dispersion for 10 to 14 hours, for example, 10 hours, 11 hours, 12 hours, 13 hours or 14 hours, and then performing probe type ultrasonic dispersion for 5 to 15 minutes, for example, 5 minutes, 8 minutes, 10 minutes, 12 minutes or 15 minutes, and other specific point values within the above numerical value range can be selected, and are not described in detail herein.

In a second aspect, the present invention provides a method for preparing the above-mentioned super-ordered carbon nanotube epoxy resin composite material, comprising the following steps:

(1) mixing and dispersing the carbon nanotubes and the epoxy resin to obtain a master batch;

(2) mixing the master batch obtained in the step (1) with a curing agent and removing bubbles to obtain a mixture;

(3) and (3) pouring the mixture obtained in the step (2) into a mould for curing to obtain the carbon nanotube epoxy resin composite material with the super-ordered structure.

Preferably, the mixing and dispersing manner in the step (1) comprises:

(S1) mixing and dispersing the carbon nanotubes and the epoxy resin in a high-speed mixer to obtain a blend;

(S2) the blend is further mixed and dispersed by a three-roll mill to obtain a master batch.

The mixing and dispersing mode in the step (1) is a combined dispersing mode, and the effect is better than that of single mixing and dispersing through a high-speed stirrer or three-roll grinder, the dispersing degree of the super-ordered carbon nano tubes in the epoxy resin can be remarkably improved, and the electric conductivity can be further improved.

Preferably, the temperature of the mixing and dispersing in (S1) is 70-90 ℃, for example, 70 ℃, 75 ℃, 80 ℃, 85 ℃ or 90 ℃, and other specific values in the above numerical range can be selected, and are not repeated herein.

Preferably, the stirring speed during the mixing and dispersing in (S1) is 3000-5000rpm, such as 3000rpm, 3500rpm, 4000rpm or 5000rpm, and the stirring time is 1-3h, such as 1h, 1.5h, 2h, 2.5h or 3h, and other specific values within the above range can be selected, and are not repeated herein.

Preferably, the epoxy resin is preheated at 70 to 90 ℃ (e.g., 70 ℃, 75 ℃, 80 ℃, 85 ℃ or 90 ℃ or the like) for 20 to 40min (e.g., 20min, 30min or 40min or the like) before the mixing and dispersing as described in (S1).

Preferably, the mixing and dispersing in (S2) is performed in a pitch pattern with roll pitches set to 120:40, 105:35, 90:30, 60:20, 45:15, 30:10, 15:5, and each pitch process is repeated twice. The drive roll speed was set at 90rpm, increased to 100rpm with decreasing roll spacing, and finally to 110 rpm. In the three-roller grinding process, the resin at the outlet and the feed inlet are often mixed, so that the unevenness of the resin is avoided.

Preferably, the mixing and de-bubbling of step (2) is performed in a planetary de-bubbling blender.

Preferably, the mixing speed of the planetary defoaming machine is set as follows: 800rpm/2min, 1000rpm/2min, 2000rpm/5min, in that order.

Preferably, the curing conditions in step (3) are set as follows: 90 ℃/30min, 120 ℃/60min, 140 ℃/30min, 160 ℃/120 min. And after the solidification process is finished, taking out the sample after the sample is naturally cooled to room temperature.

In a third aspect, the invention provides an application of the above-mentioned super-ordered carbon nanotube epoxy resin composite material in preparing a conductive material.

Compared with the prior art, the invention has the following beneficial effects:

the invention adds the super-ordered carbon nano-tubes with higher length-diameter ratio and less defects into the epoxy resin for the first time to form the composite material, and the conductive material with high conductivity (the conductivity reaches 3S/m when the addition amount is 0.3 wt%) and extremely low threshold (0.0011 wt%) can be obtained only by very little addition amount, so that the problems of viscosity surge, incomplete curing and the like of the epoxy resin can not be caused. Furthermore, the invention modifies the carbon nanotube with noncovalent functionalization surface treatment technology, improves the dispersion of the carbon nanotube in epoxy resin and the binding capacity of the carbon nanotube with the epoxy resin, does not introduce defects on the surface of the carbon tube, causes the damage of the structure of the carbon tube, and blocks the conduction path of electrons, thereby improving the intrinsic conductivity of the carbon tube. Meanwhile, the dispersing ability of the super-ordered carbon nano-tubes in the epoxy resin is further improved through the combination of different mechanical dispersing methods.

Drawings

FIG. 1 is an SEM photograph (50 μm) of a super-aligned carbon nanotube prepared in preparation example 1;

FIG. 2 is an SEM photograph (10 μm) of a super aligned carbon nanotube prepared in preparation example 1;

FIG. 3 is a TEM image (100nm) of the super aligned carbon nanotube prepared in preparation example 1;

FIG. 4 is a TEM image (10nm) of the super aligned carbon nanotube prepared in preparation example 1;

FIG. 5 is a Raman spectrum of the carbon nanotubes prepared in preparation examples 1 and 2;

FIG. 6 is a schematic view of a process for preparing a super aligned carbon nanotube epoxy composite material according to preparation example 3;

FIG. 7 is a diagram of a test apparatus for measuring the conductivity of a sample in example 1;

FIG. 8 is a schematic diagram of the conductivity test of the test sample in example 1;

FIG. 9 is a graph of conductivity as a function of added mass of super-ordered carbon nanotubes for samples of preparative examples 3 and 4;

FIG. 10 is a graph of conductivity as a function of volume of addition of the super-ordered carbon nanotubes for the samples of preparative examples 3 and 4;

FIG. 11 is lg (σ) vs. lg (f-f) for samples of preparation examples 3 and 4 in calculating the percolation threshold_c) A variation graph of (2);

FIG. 12 is lg (σ) vs. lg (f-f) for samples of preparation examples 3 and 4 in calculating the percolation threshold_c) A variation graph of (2);

FIG. 13 is an observation under an optical microscope of samples of preparation examples 3 and 4 (a-d are samples of preparation example 3, and e-h are samples of preparation example 4);

FIG. 14 is an observation under an optical microscope of a sample of uncured production example 4.

Detailed Description

The technical solution of the present invention is further explained by the following embodiments. It should be understood by those skilled in the art that the examples are only for the understanding of the present invention and should not be construed as the specific limitations of the present invention.

Preparation example 1

The preparation example adopts a CVD growth method to prepare the super-ordered carbon nano tube (marked as SACNTs), and the specific preparation method comprises the following steps:

(1) the silicon substrate was etched in a teflon cell using a platinum cathode under back illumination with a halogen lamp for 5 min. The etching solution contains one part of hydrogen fluoride (50% aqueous solution) and one part of ethanol, and the anodic oxidation current density is maintained at 10mA/cm². The obtained porous silicon has a thin nano porous layer (with the aperture of 3nm) on the top of a macroporous layer (with sub-micron pores);

(2) depositing an iron powder catalyst into a film on a silicon substrate;

(3) placing the silicon substrate in argon (Ar, 1000sccm) atmosphere, and keeping the temperature for 15min after the temperature reaches 680 ℃;

(4) adding hydrogen (H) to argon₂) With acetylene (C)₂H₂) The carbon tube growth is started, the temperature is raised to 700 ℃, and the time is kept for 60 min.

Preparation example 2

The preparation example prepares a surface-modified super-ordered carbon nanotube (marked as f-SACNTs), and the method comprises the following steps:

(1) preparing Triton X-100 (Triton) acetone solution, adding Triton X-100 into acetone solution, magnetically stirring at 25 deg.C for 1 hr to obtain 2 × 10 solution^-3mol/L Triton X-100 acetone solution.

(2) Placing 0.5g of the super-ordered carbon nanotube prepared in preparation example 1 in 300mL of acetone solution containing Triton X-100, and magnetically stirring for 24h at 25 ℃; then carrying out ultrasonic dispersion for 12h in a water bath mode, and primarily scattering the carbon tubes; and then, carrying out probe type ultrasonic dispersion for 10min to ensure that the Triton X-100 is fully adsorbed to the surface of the carbon tube, thereby obtaining the surface non-covalent chemical modified carbon nanotube.

SEM characterization was performed on the super-aligned carbon nanotubes prepared in preparation example 1, as shown in fig. 1 and 2, it can be seen that: the carbon tubes are arranged in parallel and orderly, and the degree of order is very high. TEM characterization of single super-aligned carbon nanotubes is performed, as shown in fig. 3 and 4, and it can be seen from the figure that: the diameter of the super-parallel carbon discharge tube is very small, about 10 nm.

The super-aligned carbon nanotubes prepared in preparation examples 1 and 2 were subjected to raman spectroscopic characterization, and as shown in fig. 5, it was found that: the surface of the carbon nanotube is very clean and has few defects.

Preparation example 3

The preparation example prepares a super-ordered carbon nanotube/epoxy resin composite material (marked as SACNTs/EP), and the preparation method comprises the following steps:

(1) the carbon tube powder prepared in preparation example 1 was blended with epoxy resin (type E51, preheated for 30min at 80 ℃) by a high speed mixer (AE03, DISPERMAT VAM-GETZMANN, Germany), the blending temperature was 80 ℃, the stirring speed was 4000rpm, and the stirring time was 2 h.

(2) The mixture obtained from the treatment of (1) was further mixed and dispersed by a three-roll mill (EXAKT 80E, EXAKT Technologies, Germany). The spacing mode is adopted during dispersion, the roller spacing is set to be 120:40, 105:35, 90:30, 60:20, 45:15, 30:10 and 15:5, and each spacing process is repeated twice; the drive roll speed was set at 90rpm, increased to 100rpm with decreasing roll spacing, and finally to 110rpm, resulting in a dispersed SACNTs/EP masterbatch. By adding the super-ordered carbon nano-tubes with different masses, master batches with the carbon tube contents of 0.0002 wt%, 0.0006 wt%, 0.001 wt%, 0.002 wt%, 0.005 wt%, 0.01 wt%, 0.02 wt%, 0.05 wt%, 0.1 wt%, 0.2 wt%, 0.6 wt% and 1.0 wt% are obtained.

(3) Uniformly mixing the master batch obtained in the step (2) and a curing agent (anhydride curing agent HE600) in a planetary defoaming stirrer (ARV-310, THINKY Shashin-Kagaku, Japan) according to a mass ratio of 100:91.9, and defoaming, wherein the mixing speed of the planetary defoaming machine is set as follows: 800rpm/2min, 1000rpm/2min, 2000rpm/5min, in that order.

(4) And (4) preheating the mixture obtained in the step (3) in a 60 ℃ oven, uniformly spraying a release agent on the surface of a curing mold and a mold cavity, installing and fixing, and preheating for 30min at 90 ℃. And finally pouring the preheated mixture into a mold for curing, wherein the curing conditions are as follows: sequentially carrying out 90 ℃/30min, 120 ℃/60min, 140 ℃/30min and 160 ℃/120min, and naturally cooling and taking out the sample after the curing process is finished to obtain the carbon nanotube/epoxy resin composite material (recorded as SACNTs/EP).

A schematic of the above preparation process is shown in FIG. 6.

Preparation example 4

The preparation example prepares a surface modified super-ordered carbon nanotube/epoxy resin composite material (marked as f-SACNTs/EP), and the preparation method comprises the following steps:

(1) the suspension obtained in preparation example 2 was poured into an epoxy resin (type E51, preheated at 80 ℃ for 30min), mixed uniformly by a high-speed mixer (AE03, DISPERMAT VAM-GETZMANN, Germany) (blending temperature 80 ℃, stirring speed 4000rpm, stirring time 2h), placed in an air-blast drying oven (temperature set at 80 ℃) to remove the acetone solvent, and then placed in a vacuum drying oven, vacuumized, and the solvent was sufficiently removed.

(2) - (4) in accordance with preparation example 3. And obtaining the surface modified super-ordered carbon nanotube/epoxy resin composite material (f-SACNTs/EP).

Preparation example 5

The preparation example prepares a super-ordered carbon nanotube/epoxy resin composite material (recorded as SACNTs/EP-2), and the preparation method comprises the following steps:

(1) the carbon tube powder prepared in preparation example 1 was blended with epoxy resin (type E51, preheated for 30min at 80 ℃) by a high speed mixer (AE03, DISPERMAT VAM-GETZMANN, Germany), the blending temperature was 80 ℃, the stirring speed was 4000rpm, and the stirring time was 2 h. By adding the super-ordered carbon nano-tubes with different masses, master batches with the carbon tube contents of 0.0002 wt%, 0.0006 wt%, 0.001 wt%, 0.002 wt%, 0.005 wt%, 0.01 wt%, 0.02 wt%, 0.05 wt%, 0.1 wt%, 0.2 wt%, 0.6 wt% and 1.0 wt% are obtained.

(2) Uniformly mixing the master batch obtained in the step (1) and a curing agent (HE600) in a planetary defoaming mixer (ARV-310, THINKY Shashin-Kagaku, Japan) according to a mass ratio of 100:91.9, and defoaming, wherein the mixing speed of the planetary defoaming machine is set as follows: 800rpm/2min, 1000rpm/2min, 2000rpm/5min, in that order.

(3) And (3) preheating the mixture obtained in the step (2) in a 60 ℃ oven, uniformly spraying a release agent on the surface of a curing mold and a mold cavity, installing and fixing, and preheating for 30min at 90 ℃. And finally pouring the preheated mixture into a mold for curing, wherein the curing conditions are as follows: sequentially carrying out 90 ℃/30min, 120 ℃/60min, 140 ℃/30min and 160 ℃/120min, and naturally cooling and taking out the sample after the curing process is finished to obtain the carbon nanotube/epoxy resin composite material (recorded as SACNTs/EP-2).

Preparation example 6

The preparation example prepares a super-ordered carbon nanotube/epoxy resin composite material (recorded as SACNTs/EP-3), and the preparation method comprises the following steps:

(1) the carbon nanotube powder prepared in preparation example 1 was further mixed and dispersed with an epoxy resin (type E51, preheated at 80 ℃ for 30min) using a three-roll mill (EXAKT 80E, EXAKT Technologies, Germany). The spacing mode is adopted during dispersion, the roller spacing is set to be 120:40, 105:35, 90:30, 60:20, 45:15, 30:10 and 15:5, and each spacing process is repeated twice; the drive roll speed was set at 90rpm, increased to 100rpm with decreasing roll spacing, and finally to 110rpm, resulting in a dispersed SACNTs/EP masterbatch. By adding the super-ordered carbon nano-tubes with different masses, master batches with the carbon tube contents of 0.0002 wt%, 0.0006 wt%, 0.001 wt%, 0.002 wt%, 0.005 wt%, 0.01 wt%, 0.02 wt%, 0.05 wt%, 0.1 wt%, 0.2 wt%, 0.6 wt% and 1.0 wt% are obtained.

(2) Uniformly mixing the master batch obtained in the step (1) and a curing agent (HE600) in a planetary defoaming mixer (ARV-310, THINKY Shashin-Kagaku, Japan) according to a mass ratio of 100:91.9, and defoaming, wherein the mixing speed of the planetary defoaming machine is set as follows: 800rpm/2min, 1000rpm/2min, 2000rpm/5min, in that order.

(3) And (3) preheating the mixture obtained in the step (2) in a 60 ℃ oven, uniformly spraying a release agent on the surface of a curing mold and a mold cavity, installing and fixing, and preheating for 30min at 90 ℃. And finally pouring the preheated mixture into a mold for curing, wherein the curing conditions are as follows: sequentially carrying out 90 ℃/30min, 120 ℃/60min, 140 ℃/30min and 160 ℃/120min, and naturally cooling and taking out the sample after the curing process is finished to obtain the carbon nanotube/epoxy resin composite material (recorded as SACNTs/EP-3).