Room temperature curable organopolysiloxane composition and electrical/electronic device
阅读说明：本技术 可室温固化的有机聚硅氧烷组合物和电装置/电子装置 (Room temperature curable organopolysiloxane composition and electrical/electronic device ) 是由 J·J·亨宁 J·B·霍斯特曼 V·O·简诗玛 S·斯威尔 于 2019-03-21 设计创作，主要内容包括：本发明公开了一种可室温固化的有机聚硅氧烷组合物,其包含：(A)在两个分子末端具有含烷氧基甲硅烷基的基团的有机聚硅氧烷；(B)有机聚硅氧烷树脂；(C)烷氧基硅烷；以及(D)缩合反应催化剂。可室温固化的有机聚硅氧烷组合物表现出良好至优异的储存稳定性。此外,可室温固化的有机聚硅氧烷组合物可形成表现出良好至优异的机械性能的固化产物。(Disclosed is a room-temperature curable organopolysiloxane composition comprising: (A) an organopolysiloxane having alkoxysilyl-containing groups at both molecular terminals; (B) an organopolysiloxane resin; (C) an alkoxysilane; and (D) a condensation reaction catalyst. The room-temperature-curable organopolysiloxane composition exhibits good to excellent storage stability. In addition, the room-temperature-curable organopolysiloxane composition can form a cured product that exhibits good to excellent mechanical properties.)
1. A room temperature curable organopolysiloxane composition comprising:
(A) about 100 parts by mass of an organopolysiloxane represented by the following general formula:
X-(SiR1 2O)m-SiR1 2-X；
wherein each R1Are identical or different monovalent hydrocarbon groups free of aliphatic unsaturation, each X is an alkoxysilyl-containing group selected from the group represented by the following general formula:
-R3-SiR1 a(OR2)(3-a)，
a group represented by the following general formula:
-R3-(SiR1 2O)n-SiR1 2-R3-SiR1 a(OR2)(3-a)，
and a group represented by the following general formula:
-R3-(SiR1 2O)n-SiR1 b-[OSiR1 2-R3-SiR1 a(OR2)(3-a)](3-b)，
wherein each R1As mentioned above, R2Is an alkyl radical, each R3Are the same or different alkylene groups, "a" is 0, 1 or 2, "b" is 0 or 1, "n" is an integer from 1 to 20, and "m" is an integer from 50 to 1000;
(B) from about 50 to about 200 parts by mass of an organopolysiloxane resin having an OZ content in the range of from about 30 to about 54 mol%, wherein each Z is H or an alkyl group such that OZ represents a silanol group and/or a silicon atom-bonded alkoxy group and is represented by the following average unit formula:
(R4 3SiO1/2)c(R4 2SiO2/2)d(R4SiO3/2)e；
wherein each R4Are identical or different monovalent hydrocarbon groups, and "c", "d" and "e" are numbers satisfying the following conditions: c is not less than 0<0.1, 0.3 < d < 0.6, 0.4 < e < 0.7, and c + d + e equal to 1;
(C) from about 0.5 parts by mass to about 20 parts by mass of an alkoxysilane represented by the general formula:
R5 xSi(OR6)(4-x)；
wherein R is5Is a monovalent hydrocarbon radical, R6Is an alkyl group, and "x" is an integer from 0 to 2; and
(D) about 0.1 to about 20 parts by mass of a condensation reaction catalyst.
2. The room-temperature curable organopolysiloxane composition according to claim 1, wherein the alkoxysilyl group-containing group in component (a) is a group represented by the following formula:
-C2H4-Si(CH3)2O-Si(CH3)2-C2H4-Si(OCH3)3。
3. the room-temperature-curable organopolysiloxane composition according to claim 1 or claim 2, wherein component (B) comprises an organopolysiloxane resin represented by the following average unit formula:
[(CH3)2SiO2/2]d(CH3SiO3/2)e；
wherein "c", "d", and "e" are numbers satisfying the following conditions: d is 0.3-0.6, e is 0.4-0.7, and d + e is 1.
4. The room-temperature-curable organopolysiloxane composition according to any one of claims 1 to 3, wherein component (C) comprises dimethyldimethoxysilane and/or methyltrimethoxysilane.
5. The room temperature-curable organopolysiloxane composition according to any one of claims 1 to 4, wherein each Z is H or a methyl group, such that OZ represents a silanol group and/or a silicon atom-bonded methoxy group, or optionally a silanol group and a silicon atom-bonded methoxy group.
6. A conformal coating agent comprising the room-temperature-curable organopolysiloxane composition according to any one of claims 1 to 5.
7. An electric/electronic device obtained by using the room-temperature-curable organopolysiloxane composition according to any one of claims 1 to 5.
Technical Field
The present invention relates to a room-temperature-curable organopolysiloxane composition that can be cured at room temperature by contact with moisture in the air, and an electrical/electronic device obtained by using the composition.
Background
Room temperature-curable organopolysiloxane compositions that cure by exposure to moisture in the air at room temperature to form cured products are used as sealants, adhesives, or coatings for electrical/electronic devices because they do not require heating to cure. Patent document 1 proposes a room-temperature curable organopolysiloxane composition comprising: an organopolysiloxane having at least two alkoxysilyl group-containing groups in one molecule on a silicon atom in a molecular chain, an organopolysiloxane having neither a hydroxyl group nor an alkoxy group on a silicon atom in a molecular chain, an alkoxysilane or a partial hydrolysis and condensation product thereof, and a condensation reaction catalyst. Patent document 2 proposes a room-temperature curable organopolysiloxane composition comprising: an organopolysiloxane having at least two alkoxysilyl-containing groups in one molecule on silicon atoms in the molecular chain, a diorganodialkoxysilane or a partial hydrolytic condensate thereof, and a condensation reaction catalyst. Patent document 3 proposes a room-temperature curable organopolysiloxane composition comprising: an organopolysiloxane composed of two terminal alkoxysilyl-terminated polyorganosiloxanes and a partial hydrolytic condensate, an alkoxysilane compound or a partial hydrolytic condensate thereof, and an organotitanium compound.
However, although the room-temperature-curable organopolysiloxane compositions described in patent documents 1 to 3 form cured products having good adhesion to substrates, they have a problem that the cured products have poor mechanical properties, such as stress at break and elongation.
Disclosure of Invention
Technical problem
It is an object of the present invention to provide a room-temperature-curable organopolysiloxane composition that exhibits good to excellent storage stability and cures by exposure to moisture in the air at room temperature to form a cured product that exhibits good to excellent mechanical properties. Another object of the present invention is to provide an electric/electronic device exhibiting good to excellent reliability.
Solution to the problem
In various embodiments, the room temperature curable organopolysiloxane compositions of the present disclosure comprise:
(A) about 100 parts by mass of an organopolysiloxane represented by the following general formula:
X-(SiR1 2O)m-SiR1 2-X；
wherein each R1Are identical or different monovalent hydrocarbon groups free of aliphatic unsaturation, each X is an alkoxysilyl-containing group selected from the group represented by the following general formula:
-R3-SiR1 a(OR2)(3-a)；
a group represented by the following general formula:
-R3-(SiR1 2O)n-SiR1 2-R3-SiR1 a(OR2)(3-a)；
and a group represented by the following general formula:
-R3-(SiR1 2O)n-SiR1 b-[OSiR1 2-R3-SiR1 a(OR2)(3-a)](3-b)；
wherein each R1As mentioned above, R2Is an alkyl radical, each R3Are the same or different alkylene groups, "a" is 0, 1 or 2, "b" is 0 or 1, "n" is an integer from 1 to 20, and "m" is an integer from 50 to 1000;
(B) from about 50 to about 200 parts by mass of an organopolysiloxane resin having an OZ content in the range of from about 30 to about 54 mol%, wherein each Z is H or an alkyl group such that OZ represents a silanol group and/or a silicon atom-bonded alkoxy group (e.g., a silicon atom-bonded methoxy group), and is represented by the following average unit formula:
(R4 3SiO1/2)c(R4 2SiO2/2)d(R4SiO3/2)e；
wherein each R4Are identical or different monovalent hydrocarbon groups, and "c", "d" and "e" are numbers satisfying the following conditions: c is not less than 0<0.1, 0.3 < d < 0.6, 0.4 < e < 0.7, and c + d + e equal to 1;
(C) from about 0.5 parts by mass to about 20 parts by mass of an alkoxysilane represented by the general formula:
R5 xSi(OR6)(4-x)；
wherein R is5Is a monovalent hydrocarbon radical, R6Is an alkyl group, and "x" is an integer from 0 to 2; and
(D) about 0.1 to about 20 parts by mass of a condensation reaction catalyst.
In various embodiments, the alkoxysilyl-containing group in component (a) is a group represented by the formula:
-C2H4-Si(CH3)2O-Si(CH3)2-C2H4-Si(OCH3)3。
in various embodiments, component (B) comprises an organopolysiloxane resin represented by the following average unit formula:
[(CH3)2SiO2/2]d(CH3SiO3/2)e；
wherein "c", "d", and "e" are numbers satisfying the following conditions: d is 0.3-0.6, e is 0.4-0.7, and d + e is 1.
In various embodiments, component (C) comprises dimethyldimethoxysilane and/or methyltrimethoxysilane.
The room temperature curable organopolysiloxane compositions of the present disclosure can be used in various applications. In certain embodiments, the room temperature curable organopolysiloxane composition is used as a conformal coating agent, for example, as a conformal coating agent for electrical/electronic devices. Thus, in various embodiments, the electrical/electronic devices of the present disclosure may be obtained by using a room temperature curable organopolysiloxane composition.
Effects of the invention
The room temperature curable organopolysiloxane composition according to the present disclosure generally exhibits good to excellent storage stability. In addition, the room-temperature-curable organopolysiloxane composition can form a cured product that exhibits good to excellent mechanical properties (such as stress at break and/or elongation) by allowing the room-temperature-curable organopolysiloxane composition to cure by exposure to moisture in the air at room temperature.
In addition, the electric/electronic devices according to the present disclosure generally have good to excellent reliability due to high hardness and/or good to excellent thermal shock stability properties of the cured product of the room temperature-curable organopolysiloxane composition.
Detailed Description
The terms "comprising" or "containing" are used herein in their broadest sense to mean and encompass the concepts of "comprising," consisting essentially of …, "and" consisting of …. The use of "e.g.," such as, "for example," "such as," and "including" to list example examples is not meant to be limited to only the listed examples. Thus, "for example" or "such as" means "for example, but not limited to" or "such as, but not limited to" and encompasses other similar or equivalent examples. As used herein, the term "about" is used to reasonably encompass or describe minor variations in numerical values measured by instrumental analysis or as a result of sample processing. Such minor variations may be in the order of values of 0-25, ± 0-10, ± 0-5 or ± 0-2.5%. In addition, the term "about" when used in relation to a range of values applies to both values. In addition, the term "about" applies to numerical values even when not explicitly stated.
Generally, as used herein, a hyphen "-" or dash "-" in a range of values is "to" or "to"; ">" is "higher than" or "greater than"; "≧" is "at least" or "greater than or equal to"; "<" is "lower than" or "less than"; and ≦ is "at most" or "less than or equal to". Each of the foregoing patent applications, patents, and/or patent application publications is expressly incorporated by reference in their entirety into this text, each in one or more non-limiting embodiments.
It is to be understood that the appended claims are not limited to the specific and specific compounds, compositions, or methods described in the detailed description, which may vary between specific embodiments falling within the scope of the appended claims. With respect to any markush group relied upon herein to describe a particular feature or aspect of various embodiments, it should be understood that different, special and/or unexpected results may be obtained from each member of the respective markush group independently of all other markush members. Each member of the markush group may be relied upon individually and/or in combination and provide adequate support for specific embodiments within the scope of the appended claims.
It is also to be understood that any ranges and subranges relied upon in describing various embodiments of the invention, individually and collectively, fall within the scope of the appended claims, and are to be understood as describing and envisaging all ranges including whole and/or fractional values therein, even if such values are not expressly written herein. Those skilled in the art will readily recognize that the enumerated ranges and subranges sufficiently describe and enable various embodiments of the present invention, and such ranges and subranges may be further delineated into relevant halves, thirds, quarters, fifths, and so on. As but one example, a range of "from 0.1 to 0.9" may be further delineated into a lower third (i.e., from 0.1 to 0.3), a middle third (i.e., from 0.4 to 0.6), and an upper third (i.e., from 0.7 to 0.9), which are individually and collectively within the scope of the appended claims, and which may be relied upon individually and/or collectively and provide sufficient support for specific embodiments within the scope of the appended claims. Further, with respect to language such as "at least," "greater than," "less than," "no more than," and the like, defining or modifying a range, it is to be understood that such language includes subranges and/or an upper or lower limit. As another example, a range of "at least 10" inherently includes at least a sub-range of 10 to 35, at least a sub-range of 10 to 25, a sub-range of 25 to 35, and the like, and each sub-range may be relied upon individually and/or collectively and provide adequate support for specific embodiments within the scope of the appended claims. Finally, independent numerical values within the disclosed ranges may be relied upon and provide sufficient support for specific embodiments within the scope of the appended claims. For example, a range of "from 1 to 9" includes individual integers such as 3, and individual numbers including decimal points (or fractions) such as 4.1, which may be relied upon and provide adequate support for specific embodiments within the scope of the appended claims.
<Room temperature curable organopolysiloxane composition>
In various embodiments, the room temperature curable organopolysiloxane composition (hereinafter, "composition") according to the present disclosure comprises the above-described components (a) to (D). In further embodiments, the composition consists essentially of, or optionally consists of, components (a) through (D) above. In some embodiments, the composition further comprises one or more optional additives. Without being bound or limited by any particular theory, it is believed that the composition exhibits good to excellent storage stability. Further, by allowing the composition to cure by contacting it with moisture in the air at room temperature, the composition can form a cured product exhibiting good to excellent mechanical properties such as stress at break and/or elongation.
In various embodiments, component (a) comprises or is an organopolysiloxane represented by the general formula:
X-(SiR1 2O)m-SiR1 2-X。
in the formula, each R1Are identical or different monovalent hydrocarbon groups which contain no aliphatic unsaturation. Examples of such groups include, but are not limited to: alkyl groups such as methyl groups, ethyl groups, propyl groups, butyl groups, pentyl groups, hexyl groups, heptyl groups, octyl groups, nonyl groups, decyl groups, and octadecyl groups; cycloalkyl groups such as cyclopentyl and cyclohexyl; aryl groups such as phenyl, tolyl, xylyl, and naphthyl; aralkyl groups such as benzyl, phenethyl and phenylpropyl; and halogenated alkyl groups such as 3-chloropropyl and 3,3, 3-trifluoropropyl. In certain embodiments, each R is1Individually a methyl group, a cycloalkyl group or an aryl group. In other embodiments, each R is1Is a methyl group or a phenyl group.
In this formula, "m" refers to the degree of polymerization ("DP"). In various embodiments, "m" is an integer from 50 to 1000, optionally an integer from 50 to 500, or optionally an integer from 50 to 300. It is considered that when "m" is greater than or equal to the lower limit of the above range, the elastic properties of the cured product are improved, and when "m" is less than or equal to the upper limit of the above range, the miscibility, handling properties and processability of the resulting composition are improved.
In this formula, each X is an alkoxysilyl-containing group. In various embodiments, X is selected from:
a group represented by the following general formula:
-R3-SiR1 a(OR2)(3-a)，
a group represented by the following general formula:
-R3-(SiR1 2O)n-SiR1 2-R3-SiR1 a(OR2)(3-a)，
and a group represented by the following general formula:
-R3-(SiR1 2O)n-SiR1 b-[OSiR1 2-R3-SiR1 a(OR2)(3-a)](3-b)。
in the formula, each R1As described above. In the formula, R2Is an alkyl group. Examples of such groups include, but are not limited to: a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, a heptyl group, an octyl group, a nonyl group, a decyl group, and an octadecyl group. In certain embodiments, R2Is a methyl group or an ethyl group.
In the formula, each R3Are identical or different alkylene groups. Examples of such groups include, but are not limited to, a methylmethylene group, an ethylene group, a methylethylene group, a propylene group, a butylene group, a pentylene group, a hexylene group, a heptylene group, and an octylene group. In certain embodiments, each R is3Is a methyl methylene group, an ethylene group, a methyl ethylene group or a propylene group.
In this formula, "a" is 0, 1 or 2, or optionally 0 or 1. In this formula, "b" is 0 or 1, or optionally 0. In this formula, "n" is an integer from 1 to 20, optionally an integer from 1 to 10, or optionally an integer from 1 to 5.
Examples of suitable alkoxysilyl-containing groups include groups represented by the following formula:
-C2H4-Si(OCH3)3
-C2H4-SiCH3(OCH3)2
-C3H6-Si(OCH3)3
-C2H4-Si(OC2H5)3
-C2H4-Si(CH3)2O-Si(CH3)2-C2H4-Si(OCH3)3
-C3H6-Si(CH3)2O-Si(CH3)2-C2H4-Si(OCH3)3
-C2H4-Si(CH3)2O-Si(CH3)2-C2H4-SiCH3(OCH3)2
-C2H4-Si(CH3)2O-Si(CH3)2-C3H6-Si(OCH3)3
-C3H6-Si(CH3)2O-Si(CH3)2-C3H6-Si(OCH3)3
-C2H4-Si(CH3)2O-Si(CH3)2-C6H12-Si(OCH3)3
-C2H4-[Si(CH3)2O]2-Si(CH3)2-C2H4-Si(OCH3)3
-C2H4-Si(CH3)2O-Si(CH3)2-C2H4-Si(OC2H5)3
-C2H4-Si(CH3)2OSiC3H7[OSi(CH3)2-C2H4-Si(OCH3)3]2
-C2H4-Si(CH3)2OSiCH3[OSi(CH3)2-C2H4-Si(OCH3)3]2
-C2H4-Si(CH3)2OSiC3H7[OSi(CH3)2-C2H4-SiCH3(OCH3)2]2
the viscosity of component (A) at 23 ℃. + -. 2 ℃ is not limited. In various embodiments, component (A) has a viscosity in the range of from about 100 to about 10,000 mPa-s, or optionally in the range of from about 100 to about 1,000 mPa-s, at 23 ℃. + -. 2 ℃. It is considered that when the viscosity of component (a) is greater than or equal to the minimum value of the range given above, the elastic properties of the cured product are improved, and when it is less than or equal to the maximum value of the range given above, the miscibility, handling properties, and processability of the resulting composition are improved.
In various embodiments, component (B) comprises or is an organopolysiloxane resin represented by the average unit formula:
(R4 3SiO1/2)c(R4 2SiO2/2)d(R4SiO3/2)e。
in the formula, each R4Are identical or different monovalent hydrocarbon radicals. Examples of such groups include, but are not limited to: alkyl groups such as methyl groups, ethyl groups, propyl groups, butyl groups, pentyl groups, hexyl groups, heptyl groups, octyl groups, nonyl groups, decyl groups, and octadecyl groups; cycloalkyl groups such as cyclopentyl and cyclohexyl; aryl groups such as phenyl, tolyl, xylyl, and naphthyl; aralkyl groups such as benzyl, phenethyl and phenylpropyl; and halogenated alkyl groups such as 3-chloropropyl and 3,3, 3-trifluoropropyl. In certain embodiments, each R is4Is an alkyl group, a cycloalkyl group or an aryl group. In other embodiments, each R is4Is a methyl group or a phenyl group.
In the formula, "c", "d", and "e" are numbers satisfying the following conditions: c is more than or equal to 0 and less than or equal to 0.1, d is more than or equal to 0.3 and less than or equal to 0.6, e is more than or equal to 0.4 and less than or equal to 0.7, and c + d + e is equal to 1; or optionally c ═ 0, d ≦ 0.3 ≦ 0.6, 0.4 ≦ e ≦ 0.7, and c + d + e ≦ 1. It is considered that when "d" is greater than or equal to the lower limit of the above range, the composition forms a cured product exhibiting good flexibility, and when "b" is less than or equal to the upper limit of the above range, the composition forms a cured product exhibiting good mechanical strength.
In certain embodiments, component (B) comprises an organopolysiloxane resin represented by the average unit formula:
[(CH3)2SiO2/2]d(CH3SiO3/2)e。
in this formula, "d" and "e" are numbers as described above.
In various embodiments, component (B) has an OZ content in the range of from about 30 mol% to about 54 mol%, optionally in the range of from about 30 mol% to about 53 mol%, optionally in the range of from about 30 mol% to about 52 mol%, optionally in the range of from about 30 mol% to about 51 mol%, optionally in the range of from about 35 mol% to about 54 mol%, optionally in the range of from about 35 mol% to about 53 mol%, optionally in the range of from about 35 mol% to about 52 mol%, or optionally in the range of from about 35 mol% to about 51 mol%. It is considered that when the content of OZ is within one or more of the ranges given above, the compatibility of component (B) in component (a) is improved. Wherein each Z is H or an alkyl group such that OZ represents a silanol group and/or a silicon atom-bonded alkoxy group. In certain embodiments, each Z is H or a methyl group such that OZ represents a silanol group and/or a silicon atom-bonded methoxy group. In various embodiments, the OZ content comprises a silanol group, a silicon atom-bonded alkoxy group, or a combination of a silanol group and a silicon atom-bonded alkoxy group.
An example of a test method for determining the OZ content is as follows. In the test method for obtaining OZ mol%, by29Si and13c NMR was analyzed in deuterated benzene. Total OZ content of29Si NMR analysis determined and reported in mole fraction based on Si units. In certain embodiments, from13C NMR analysis (1, 4-dioxane as internal standard) determined the amount of the methoxy OZ content. The difference between the total OZ content and the amount of methoxy groups is the amount of silanol groups present.
Component (B) generally has a molecular weight distribution and is a mixture of a plurality of organopolysiloxane resins. Further, the component (B) can be obtained by blending separately prepared organopolysiloxane resins. In these cases, it is not necessary that each organopolysiloxane resin corresponds to the average unit formula specified above, and mixtures thereof may satisfy the above average unit formula.
In various embodiments, component (B) is present in a range of about 50 parts by mass to about 200 parts by mass, optionally in a range of about 80 parts by mass to about 200 parts by mass, or optionally in a range of about 100 parts by mass to about 200 parts by mass, relative to 100 parts by mass of component (a). It is considered that when the content of the component (B) is greater than or equal to the lower limit of the above range, the heat shock stability of the resulting cured product is improved, and when the content is less than or equal to the upper limit of the above range, the hardness is improved, with good heat shock stability.
In various embodiments, component (C) comprises or is an alkoxysilane represented by the general formula:
R5 xSi(OR6)(4-x)。
in the formula, R5Is a monovalent hydrocarbon group. Examples of such groups include, but are not limited to: alkyl groups such as methyl groups, ethyl groups, propyl groups, butyl groups, pentyl groups, hexyl groups, heptyl groups, octyl groups, nonyl groups, decyl groups, and octadecyl groups; cycloalkyl groups such as cyclopentyl and cyclohexyl; alkenyl groups such as vinyl groups, allyl groups, butenyl groups, pentenyl groups, hexenyl groups, heptenyl groups, octenyl groups, nonenyl groups, decenyl groups, and octadecenyl groups; aryl radicals, e.g. phenyl, tolyl, xylylAnd naphthyl; aralkyl groups such as benzyl, phenethyl and phenylpropyl; and halogenated alkyl groups such as 3-chloropropyl and 3,3, 3-trifluoropropyl. In certain embodiments, R5Is an alkyl group or an alkenyl group. In other embodiments, R5Is a methyl group or a vinyl group.
In the formula, R6Is an alkyl group. Examples of such groups include those described above for R5The alkyl group. In certain embodiments, R6Is a methyl group or an ethyl group.
In this formula, "x" is an integer of 0 to 2, preferably 1 or 2.
Examples of component (C) include, but are not limited to, dimethyldimethoxysilane, methyltrimethoxysilane, methylphenyldimethoxysilane, and dimethyldiethoxysilane. Component (C) may be one of these alkoxysilanes or a combination of two or more thereof used as a mixture. In certain embodiments, component (C) comprises or is dimethyldimethoxysilane and/or methyltrimethoxysilane.
In various embodiments, component (C) is present in a range of about 0.5 parts by mass to about 20 parts by mass, optionally in a range of about 1 part by mass to about 15 parts by mass, or optionally in a range of about 0.5 parts by mass to about 10 parts by mass, relative to 100 parts by mass of component (a). It is considered that when the content of the component (C) is greater than or equal to the lower limit of the above range, the resultant composition is rapidly cured by moisture in air, and when the content is less than or equal to the upper limit of the above range, the curability of the resultant composition is sufficient, and the shelf life of the resultant composition under moisture blocking is improved.
Component (D) is a condensation reaction catalyst. Examples of component (D) include, but are not limited to: tin compounds such as tin dimethyldineodecanoate, stannous octoate, and the like; and titanium compounds such as tetrakis (isopropoxy) titanium, tetrakis (n-butoxy) titanium, tetrakis (t-butoxy) titanium, bis (isopropoxy) bis (ethylacetoacetate) titanium, bis (isopropoxy) bis (methylacetoacetate) titanium, and bis (isopropoxy) bis (acetylacetonate) titanium, and the like.
In various embodiments, component (D) is present in a range of about 0.1 parts by mass to about 20 parts by mass, optionally in a range of about 0.1 parts by mass to about 15 parts by mass, or optionally in a range of about 1 part by mass to about 15 parts by mass, relative to 100 parts by mass of component (a). It is considered that when the content of the component (D) is greater than or equal to the lower limit of the above range, the resulting composition is sufficiently cured by moisture in the air, and when the content is less than or equal to the upper limit of the above range, the surface curing rate of the resulting composition is improved.
As described above, the composition according to the present disclosure may further include components other than the components (a) to (D). For example, the composition may further comprise at least one of a chelating agent, an adhesion promoter, and the like.
In various embodiments, the composition further comprises a chelating agent for component (D). Examples of chelating agents include alpha-substituted acetoacetates, such as methyl acetoacetate, ethyl acetoacetate, and the like.
The content of the chelating agent is not limited, provided that it is an amount that can impart sufficient stability to component (D). In various embodiments, the chelating agent is present in a range of about 0.01 parts by mass to about 20 parts by mass, or optionally in a range of about 0.01 parts by mass to about 15 parts by mass, relative to 100 parts by mass of component (a).
In various embodiments, the composition further comprises an adhesion promoter. Examples of adhesion promoters include, but are not limited to, epoxy group-containing alkoxysilanes such as 3-glycidoxypropyltrimethoxysilane, 3-glycidoxypropyltriethoxysilane, 3-glycidoxypropylmethoxysilane, 2- (3, 4-epoxycyclohexyl) ethyltrimethoxysilane, and 4-oxysilylbutyltrimethoxysilane; acrylic group-containing alkoxysilanes such as 3-methacryloxypropyltrimethoxysilane, 3-methacryloxypropyltriethoxysilane, and 3-acryloxypropyltrimethoxysilane; amino group-containing alkoxysilanes such as 3-aminopropyltrimethoxysilane, 3-aminopropyltriethoxysilane, N- (2-aminoethyl) -3-aminopropyltrimethoxysilane and N-phenyl-3-aminopropyltrimethoxysilane; and a reaction mixture of the above epoxy group-containing alkoxysilane and the above amino group-containing alkoxysilane. In certain embodiments, the adhesion promoter comprises, or is, selected from, a reaction mixture of the aforementioned epoxy-containing alkoxysilane with the aforementioned amino-containing alkoxysilane.
The content of the adhesion promoter is not limited, provided that it is an amount that can impart sufficient adhesion to the organic resin with which the composition is contacted during curing. In various embodiments, the adhesion promoter is present in a range of about 0.01 parts by mass to about 10 parts by mass, or optionally in a range of about 0.01 parts by mass to about 5 parts by mass, relative to 100 parts by mass of component (a).
<Electric/electronic device>
In various embodiments, electrical/electronic devices according to the present disclosure are obtained by using the room temperature curable organopolysiloxane compositions described above. The electric/electronic device is not particularly limited, but is exemplified by an electric/electronic device including a circuit, an electrode, and the like. It is considered that such electric/electronic devices have good to excellent reliability due to good to excellent adhesion to a contacted substrate during curing of the cured product, and/or good to excellent thermal shock stability.