阅读说明：本技术 包含氨基多羧酸盐的成型洗涤剂产品 (Shaped detergent products comprising aminopolycarboxylates ) 是由 H·J·M·阿拉博塞 R·J·默尔 于 2019-02-12 设计创作，主要内容包括：一种成型洗涤剂产品,其包含10至100重量％的第一固相和0至90重量％的一个或多个其它相,所述第一固相包含：a)非晶手性氨基多羧酸盐；b)不同于组分a)的非晶有机酸；c)至多30重量％的水；d)至多50重量％的不同于组分a)或组分b)的非晶水溶性组分；e)至多20重量％的均匀分散的晶体材料；其中所述组分a)、b)和c)的组合以所述固相的总重量的至少35重量％的浓度存在于所述第一固相中；和其中组分a)、b)和c)以25至88重量份的游离酸当量的组分a)：10至60重量份的游离酸当量的组分b)：2至30重量份的组分c)的比率存在于所述固相中；和其中所述成型洗涤剂产品包含至少0.5重量％的表面活性剂。(A shaped detergent product comprising from 10 to 100 wt% of a first solid phase comprising: a) amorphous chiral aminopolycarboxylates; b) an amorphous organic acid different from component a); c) up to 30 wt% water; d) up to 50% by weight of an amorphous water-soluble component different from component a) or component b); e) up to 20% by weight of a homogeneously dispersed crystalline material; wherein the combination of components a), b) and c) is present in the first solid phase in a concentration of at least 35 wt% of the total weight of the solid phase; and wherein components a), b) and c) are present in an amount of from 25 to 88 parts by weight of free acid equivalent of component a): 10 to 60 parts by weight of a free acid equivalent of component b): a ratio of from 2 to 30 parts by weight of component c) is present in the solid phase; and wherein the shaped detergent product comprises at least 0.5 wt% surfactant.)

1. A shaped detergent product comprising from 10 to 100 wt% of a first solid phase comprising:

a) amorphous chiral aminopolycarboxylates;

b) an amorphous organic acid different from component a);

c) up to 30 wt% water;

d) up to 50% by weight of an amorphous water-soluble component different from component a) or component b);

e) up to 20% by weight of a homogeneously dispersed crystalline material;

wherein the combination of components a), b) and c) is present in the first solid phase in a concentration of at least 35 wt% of the total weight of the solid phase; and

wherein components a), b) and c) component a) are present in a free acid equivalent amount of 25 to 88 parts by weight: 10 to 60 parts by weight of a free acid equivalent of component b): a ratio of from 2 to 30 parts by weight of component c) is present in the solid phase; and

wherein the shaped detergent product comprises at least 0.5 wt% surfactant.

2. Shaped detergent product according to claim 1, wherein the product contains from 10 to 90 wt% of the first solid phase and from 10 to 90 wt% of one or more further solid phases.

3. A shaped detergent product according to claim 1 or 2 wherein the first solid phase is an amorphous solid phase.

4. The shaped detergent product according to any of the preceding claims wherein the first solid phase comprises at least 12 wt% of free acid equivalent of an aminopolycarboxylate selected from the group consisting of: glutamic acid N, N-diacetic acid (GLDA), methylglycinediacetic acid (MGDA), ethylenediamine disuccinic acid (EDDS), iminodisuccinic acid (IDS), iminodimalic acid (IDM), and combinations thereof.

5. The shaped detergent product of any one of the preceding claims, wherein the first solid phase contains at least 0.2 wt% of free acid equivalents of an acid other than aminopolycarboxylate.

6. The shaped detergent product of claim 5, wherein the first solid phase comprises at least 10 wt% of free acid equivalent of an acid selected from the group consisting of: acetic acid, citric acid, aspartic acid, lactic acid, adipic acid, succinic acid, glutaric acid, malic acid, tartaric acid, maleic acid, fumaric acid, sugar acids, sulfuric acid, hydrochloric acid, and combinations thereof.

7. The shaped detergent product of any one of the preceding claims wherein the first solid phase comprises from 5 to 25 wt% water.

8. The shaped detergent product according to any one of the preceding claims wherein the first solid phase comprises from 12 to 45 wt% of the water soluble component.

9. The shaped detergent product of claim 8 wherein the first solid phase contains at least 12 wt% of a water soluble component selected from the group consisting of polycarboxylate polymers, sulfonated polymers, and combinations thereof.

10. The shaped detergent product of any one of the preceding claims, wherein the combination of components a), b), c) and e) is present in the first solid phase in a combined concentration of at least 80 wt% of the total weight of the solid phase.

11. The shaped detergent product according to any of the preceding claims, wherein at least part of the shaped detergent product is visually distinct from the remainder of the detergent product portion.

12. The shaped detergent product of any one of the preceding claims, wherein the detergent product is a unit dose detergent product.

13. A process for preparing a shaped detergent product according to any preceding claim, the process comprising:

I. providing an aqueous solution comprising an aminopolycarboxylate salt, an acid and a water-soluble component; and

removing water from the aqueous solution.

14. The method of claim 13, wherein the method comprises:

removing water from the aqueous solution by evaporation at a temperature of at least 50 ℃ to produce a liquid dry mixture having a water content of no more than 30% by weight; and

reducing the temperature of the dried mixture to less than 25 ℃ to obtain the shaped detergent product.

15. A process according to claim 13 or 14, wherein water is removed from the aqueous solution by evaporation at a temperature of at least 95 ℃.

Technical Field

The present invention relates to shaped detergent products. In particular, the present invention relates to shaped detergent products comprising a first solid phase comprising an amorphous chiral amino polycarboxylate (aminopolycarboxylate), an amorphous organic acid which is not an amino polycarboxylate, and water.

Background

Detergent products typically contain a variety of different active ingredients including builders, surfactants, enzymes and bleaching agents. Surfactants are used to remove stains and soils and to disperse the released components into the cleaning liquid. Enzymes help remove stubborn stains from proteins, starches, and lipids by hydrolyzing these components. Bleaching agents are used to remove stains by oxidizing the components that make up these stains. In order to reduce the adverse effect of especially calcium and magnesium ions on stain/soil removal, so-called "builders" (complexing agents) are often used in detergent products.

Shaped detergent products are known in the art. Detergent tablets are an example of a shaped detergent product. Tablets generally comprise a mixture of components which are solid at room temperature and components which are liquid at room temperature. The solid component is typically present in particulate form to facilitate processing and speed of dissolution/dispersion. The tablets are generally prepared by mixing the tablet components followed by compression molding.

Shaped detergent products in the form of multi-phase tablets are also known in the art. These multi-phase tablets comprise one or more component formulations that are typically present in a layered arrangement/body with insert formation. The component preparations contained in the multi-phase tablets are usually composed of opaque compressed materials.

Phosphorus-based builders have been used for many years in a wide range of detergent products. Some phosphorus-based builders, such as trisodium phosphate and Sodium Tripolyphosphate (STPP), have set benchmarks in the dishwasher detergent industry for their superior performance. Thus, phosphorus containing builder components are generally considered to be "high performance" builders. The use of phosphorus-based builders in detergent products leads to environmental problems such as eutrophication. To reduce such problems, many jurisdictions have issued or are issuing laws and regulations to limit the maximum amount of phosphorus in detergent products. Thus, there is a need for more environmentally friendly alternative builders that have equivalent (on-par) efficacy and that are also economical. Examples of such alternative builders are aminopolycarboxylates such as glutamic acid N, N-diacetic acid (GLDA), methylglycinediacetic acid (MGDA) and ethylenediaminetetraacetic acid (ethylenediaminetetraacetic acid). A disadvantage of many of these aminopolycarboxylates is that they tend to be water-absorbent.

WO 2014/086662 discloses a solid GLDA (i.e. aminopolycarboxylate) material comprising a combination of GLDA, sulfuric acid and sodium sulfate crystals. Also described is a process for producing a solid GLDA composition comprising the following successive steps:

combining GLDA sodium salt and sulfuric acid in a high water activity phase; and

allowing water to evaporate from the phase to produce a precipitate.

It would be desirable to have available shaped detergent products comprising solid aminopolycarboxylates that provide one or more important product benefits, such as attractive appearance, improved stability and improved dissolution/dispersion properties.

It is an object of the present invention to provide shaped detergent products containing aminopolycarboxylates which provide such benefits.

Disclosure of Invention

In a first aspect of the invention, one or more of the above objects are achieved by a shaped detergent product comprising from 10 to 100 wt% of a first solid phase comprising:

a) amorphous chiral aminopolycarboxylates;

b) an amorphous organic acid different from component a);

c) up to 30 wt% water;

d) up to 50% by weight of an amorphous water-soluble component different from component a) or component b);

e) up to 20% by weight of a homogeneously dispersed crystalline material;

wherein the combination of components a), b) and c) is present in the first solid phase in a concentration of at least 35 wt% of the total weight of the solid phase; and

wherein components a), b) and c) component a) are present in a free acid equivalent amount of 25 to 88 parts by weight: 10 to 60 parts by weight of a free acid equivalent of component b): a ratio of from 2 to 30 parts by weight of component c) is present in the solid phase; and

wherein the shaped detergent product comprises at least 0.5 wt% surfactant.

It has been unexpectedly found that shaped detergent products can be prepared which contain an attractive translucent or even transparent solid phase comprising an aminopolycarboxylate, an organic acid and water in the weight ratios described above. Very attractive shaped detergent products can be produced by incorporating such a translucent/transparent and even glossy solid phase as a visible element.

The aforementioned solid phase may also suitably be applied as an external, optionally transparent, coating of the shaped detergent product.

It was found that a translucent/transparent solid phase according to the invention can be prepared if it contains not more than 50 wt.% of other amorphous water-soluble components and not more than 20 wt.% of homogeneously dispersed crystalline material. It has been unexpectedly found that a translucent/transparent solid phase according to the present invention can be prepared from an aqueous solution containing an aminopolycarboxylate, an acid and at least 35 wt% water by reducing the water content of the solution to 30 wt% or less to produce a liquid dried (desired) mixture while maintaining the liquid mixture at a temperature of at least 50 degrees celsius followed by cooling the dried mixture to a temperature of less than 25 degrees celsius to obtain a first solid phase.

Although the inventors do not wish to be bound by theory, it is believed that the dried liquid formed by reducing the water content of the solution to 30% by weight or less is a substantially amorphous material in its viscous (or rubbery) state. By cooling the drying liquid, the viscosity increases to a level where the material becomes solid. This method offers the advantage that it allows the production of a first solid phase in the form of a (shaped) block. Further, the method may be used to coat a solid substrate with the first solid phase by drying the mixture with a hot liquid and allowing the hot mixture to cool.

Detailed Description

Definition of

Weight percentages (wt%) are based on the total weight of the shaped detergent product or first solid phase as indicated, unless otherwise indicated. It is understood that the total weight of the ingredients is not more than 100% by weight. Whenever an amount or concentration of a component is quantified herein, unless otherwise indicated, the quantified amount or concentration refers to the component by itself, even though such component may conventionally be added in solution or in a blend with one or more other ingredients. It will be further understood that the verb "to comprise" and its conjugations are used in its non-limiting sense to mean that items following the word are included, but items not specifically mentioned are not excluded. Finally, reference to an element by the indefinite article "a" does not exclude the possibility that more than one of the element is present, unless the context clearly requires that there be one of the element and only one of the element. Thus, the indefinite article "a" or "an" generally means "at least one". All measurements were made under standard conditions, unless otherwise indicated. Whenever a parameter such as concentration or ratio is considered to be less than a certain upper limit, it is understood that in the absence of a specified lower limit, the lower limit of the parameter is 0.

The term "different" or "distinct" as used herein in relation to the first solid phase means that the phases are visually distinct/distinguishable by the untrained human eye.

The term "solid" according to the present invention is according to its conventional usage. For example, while a glass (wineglass) is considered a solid in its conventional usage, it is an extremely viscous liquid in a strict physical sense.

Unless otherwise indicated, the term "aminopolycarboxylate" includes partial acids and full acids thereof. Salts of aminopolycarboxylates other than the whole acids are more preferred, and alkali metal salts thereof are particularly preferred. Unless otherwise indicated, the term "acid" includes partial or complete alkali metal salts thereof.

The concentration expressed as% by weight of "free acid equivalents" refers to the concentration of the aminopolycarboxylate or acid expressed as% by weight, assuming that the aminopolycarboxylate or acid is present only in fully protonated form. The following table shows how the free acid equivalent concentration can be calculated for some (anhydrous) aminopolycarboxylates and (anhydrous) acid salts.

The term "transparency" as used herein refers to the ability of light within the visible spectrum to at least partially pass through the first solid phase. For quantification, it is preferred that it is based on a path length evaluation of 0.5cm through the first solid phase, measuring the amount of light passing through. A shaped detergent product is considered translucent if its first solid phase has a maximum light transmission of at least 5% in the wavelength range of 400 to 700nm under the aforementioned measurement conditions. A first solid phase is considered transparent if it has a maximum light transmission of at least 20% in the aforementioned wavelength range. Here, the light transmittance is defined as the ratio between the intensity of light measured after light passes through the first solid phase sample and the intensity of light measured when the sample is removed.

Gloss is the fraction of light reflected in the specular (mirror-like) direction. The angle of incident light at which gloss is measured is 20 degrees to obtain a measurement result of "high gloss finish", it is 60 degrees to obtain a measurement result of "medium gloss finish", and it is 85 degrees to obtain a measurement result of "matt finish". Good gloss attributes provide better visual appeal and suggest glass cleaning performance of the solid composition. These gloss values were measured using Rhopoint IQ (Goniophorometers; super Rhopoint Instruments) according to the Supplier's instructions. To measure the gloss of the solid composition, this was done on a (separate, continuous) solid composition sample having a thickness of 0.5cm, a flat, smooth surface (e.g. shaped like a disc or a flat plate), and white paper was used as background (100% recycled paper, bright white; supplier: Office depth).

Advantageously, in order to provide even better visual appeal, the first solid phase has the following gloss properties:

a specular reflectance of at least 5%, 10%, 15%, 20%, 25%, 30%, 35%, 40%, 45%, 50%, 55%, and even more preferably at least 60% at 20 degrees of incident light. Preferably, at most 95%, 90%, 85%, 80% and more preferably at most 75% of reflectance at 20 degrees. The most advantageous 20 degrees reflectance is from 40 to 85%, more preferably from 50 to 80%, and even more preferably from 55 to 75%.

A specular reflectance of at least 5%, 10%, 15%, 20%, 25%, 30%, 35%, 40%, 45%, 50%, 55%, 60%, 65%, 70%, 75%, 80%, 85% at 60 degrees of incident light. Preferably, a reflectance at 60 degrees of at most 99.5%, 99.0%, 98.5% and more preferably 98.0%. The most advantageous 60 degrees is a reflectance of 50 to 99.5%, more preferably 70 to 99.0%, and even more preferably 80 to 98.5%.

A specular reflectance of at least 5%, 10%, 15%, 20%, 25%, 30%, 35%, 40%, 45%, 50%, 55%, and even more preferably at least 60% at 85 degrees of incident light. Preferably, a reflectance at 85 degrees of at most 95%, 90%, 85%, 80% and more preferably at most 75%. The most advantageous 85 degree reflectance is from 40 to 85%, more preferably from 50 to 80%, and even more preferably from 55 to 75%.

Of course, it is even more advantageous that the first solid phase has a preferred reflectivity at 20, 60 and 85 degrees in combination (i.e. has a good high gloss finish and a good medium gloss finish and a good matte finish).

The first solid phase may contain a large amount of uniformly dispersed crystalline material. Even in the presence of such uniformly dispersed crystalline materials, the first solid phase can be translucent and provide the desired "milky glass" like appearance. Preferably, the homogeneously dispersed crystalline material, if present, is present in an amount such that the first solid phase has a maximum light transmittance of at least 2%, more preferably at least 5%, in the wavelength range of 400 to 700 nm.

In a preferred embodiment, the amount of homogeneously dispersed crystalline material different from component a) or component b) in the first solid phase is preferably from 0.1 to 15 wt. -%, more preferably from 0.2 to 10 wt. -%, even more preferably from 0.5 to 5 wt. -%, and still even more preferably from 0.7 to 3 wt. -%, based on the weight of the first solid phase. The crystalline material may be any suitable crystalline material, but is preferably a detergent active crystalline material. In another preferred embodiment, the first solid phase is free of crystalline material, i.e. according to this embodiment the first solid phase is substantially amorphous.

The first solid phase of the shaped detergent of the invention comprises a combination of component a), component b) and component c) in a concentration of at least 35 wt% of the total weight of the solid phase. Preferably, the combination of a) to c) constitutes at least 40 wt.%, more preferably at least 50 wt.%, even more preferably at least 55 wt.% of the first solid phase.

Preferably, components a), b) and c) are present in 35 to 80 parts by weight of free acid equivalent of component a): 15 to 50 parts by weight of a free acid equivalent of component b): a ratio of from 5 to 25 parts by weight of component c) is present in the first solid phase. More preferably, components a), b) and c) are present in 30 to 70 parts by weight of free acid equivalent of component a): 20 to 50 parts by weight of a free acid equivalent of component b): a ratio of from 6 to 20 parts by weight of component c) is present in the first solid phase.

According to another preferred embodiment, the combination of components a), b), c) and e) is present in the first solid phase in a combined concentration of at least 80 wt. -%, more preferably of at least 90 wt. -%, based on the total weight of the solid phase.

Amorphous chiral aminopolycarboxylates

Aminopolycarboxylates are well known in the detergent industry and are sometimes referred to as aminocarboxylate chelants. They are generally considered to be strong builders.

Chirality is the geometric property of a molecule caused by the molecule having at least one chiral center. Chiral molecules are not superimposable with their mirror image. The chiral aminopolycarboxylate as used in the present invention may include all molecular mirror images thereof.

Chiral and preferred aminopolycarboxylates are glutamic acid N, N-diacetic acid (GLDA), methylglycine diacetic acid (MGDA), ethylenediamine disuccinic acid (EDDS), iminodisuccinic acid (IDS), iminodimalic acid (IDM) or mixtures thereof, more preferably GLDA, MGDA, EDDS or mixtures thereof, and even more preferably GLDA and MGDA or mixtures thereof. Preferably, the aminopolycarboxylate as used in the first solid phase is substantially GLDA and/or MGDA. In the case of GLDA, it is preferably present predominantly (i.e. more than 80 mole%) in one of its chiral forms.

Examples of achiral aminopolycarboxylates are ethylenediaminetetraacetic acid (EDTA), nitrilotriacetic acid (NTA), iminodiacetic acid (IDA), diethylenetriaminepentaacetic acid (DTPA), hydroxyethyliminodiacetic acid (HEIDA), aspartic acid diethoxysuccinic Acid (AES), aspartic acid-N, N-diacetic acid (ASDA), hydroxyethylethylenediaminetetraacetic acid (HEDTA), hydroxyethylethylenediaminetriacetic acid (HEEDTA), iminodifumaric acid (IDF), iminoditartaric acid (IDT), iminodimaleic acid (IDMAL), ethylenediamine difumaric acid (EDDF), ethylenediamine dimalic acid (EDDM), ethylenediamine ditartaric acid (EDDT), ethylenediamine dimaleic acid and (EDDMAL), dipicolinic acid. The achiral aminopolycarboxylate is preferably present in an amount of up to 10 wt%, more preferably up to 5 wt%, and even more preferably is substantially absent from the first solid phase of the shaped detergent product of the present invention.

The first solid phase of the invention preferably comprises from 12 to 70% by weight of free acid equivalent of the aminopolycarboxylate. More preferably, the aminopolycarboxylate content is 20 to 68 wt% free acid equivalents, and even more preferably 35 to 60 wt% free acid equivalents. Preferably, the first solid phase contains at least 12 wt.%, more preferably at least 20 wt.%, even more preferably at least 25 wt.% of free acid equivalents of an aminopolycarboxylate selected from the group consisting of: glutamic acid N, N-diacetic acid (GLDA), methylglycinediacetic acid (MGDA), ethylenediamine disuccinic acid (EDDS), iminodisuccinic acid (IDS), iminodimalic acid (IDM), and combinations thereof. It is highly preferred that the first solid phase contains at least 12 wt.%, more preferably at least 20 wt.%, even more preferably at least 25 wt.% of free acid equivalent of an aminopolycarboxylate selected from GLDA, MGDA, EDDS and combinations thereof.

Amorphous organic acids

The first solid phase of the shaped detergent product of the invention comprises a non-crystalline organic acid different from component a), i.e. the organic acid is not an aminopolycarboxylate.

As explained herein before, it has been unexpectedly found that a transparent first solid phase comprising an aminopolycarboxylate, an organic acid and water can be prepared.

The presence of crystals in the first solid phase can be determined by WAXS, suitably using the methods outlined in the examples. Without wishing to be bound by theory, it is believed that the molecular interaction of the aminopolycarboxylate with the acid (although not covalently bound thereto) prevents crystallization of either of these components. Thus, another benefit of the composition according to the invention is that the composition may be free of further added crystal formation inhibitors.

The organic acid used in the first solid phase according to the invention may be any organic acid. Particularly good results are achieved with organic acids which are polybasic acids (i.e. acids having more than one carboxylic acid group), more particularly with organic acids which are di-or tricarboxylic acids.

It is further preferred that the organic acid used in the present invention has an average molecular weight of at most 500 daltons, based on free acid equivalent weight. In any case, preferably, the organic acid is not a polymer-based acid. Even more preferably the organic acid has from 3 to 25 carbon atoms, preferably from 4 to 15 carbon atoms.

Generally, any organic acid may be used, but in view of consumer acceptance, the organic acids are preferably those which are also found naturally, for example in plants. Thus, organic acids of note are acetic acid, citric acid, aspartic acid, lactic acid, adipic acid, succinic acid, glutaric acid, malic acid, tartaric acid, maleic acid, fumaric acid, sugar acids, salts thereof, or mixtures thereof. Of particular interest are citric acid, aspartic acid, acetic acid, lactic acid, succinic acid, glutaric acid, adipic acid, gluconic acid, salts thereof or mixtures thereof. Citric acid, lactic acid, acetic acid and aspartic acid are even more preferred. Citric acid and/or salts thereof are particularly beneficial because, in addition to being a builder, they are also highly biodegradable. Thus, a more preferred amorphous organic acid of the present invention comprises (or consists essentially of) citric acid, a citrate salt, or a mixture thereof. Generally, the acids of the organic acids are preferred over their alkali metal salt equivalents.

Preferably, the first solid phase comprises 0.2 to 55% by weight of free acid equivalents of the acid. More preferably the total amount of acid is from 2 to 52% by weight free acid equivalents, more preferably from 5 to 50% by weight free acid equivalents, and most preferably from 15 to 40% by weight free acid equivalents.

Better results are achieved with a certain weight ratio of aminopolycarboxylate and the acid in the first solid phase. Thus, it is preferred that the weight ratio of aminopolycarboxylate to acid is from 1:2 to 1:0.15, more preferably from 1:1.5 to 1:0.4, more preferably from 1:1.4 to 1:0.5, based on the weight of free acid equivalents.

Preferably, the first solid phase comprises at least 2 wt.%, more preferably at least 5 wt.%, even more preferably at least 15 wt.%, most preferably at least 20 wt.% of free acid equivalents of an acid selected from the group consisting of: acetic acid, citric acid, aspartic acid, lactic acid, adipic acid, succinic acid, glutaric acid, malic acid, tartaric acid, maleic acid, fumaric acid, sugar acids, sulfuric acid, hydrochloric acid, and combinations thereof.

It is particularly preferred that the first solid phase contains at least 2 wt.%, more preferably at least 5 wt.%, even more preferably at least 15 wt.%, most preferably at least 20 wt.% of dicarboxylic and/or tricarboxylic acids having a free acid equivalent weight of less than 500 dalton, more preferably less than 400 dalton and most preferably less than 300 dalton.

Most preferably, the first solid phase contains at least 2 wt.%, more preferably at least 5 wt.%, even more preferably at least 15 wt.%, most preferably at least 20 wt.% of citric acid in free acid equivalents.

It is particularly preferred that the combination of the aminopolycarboxylate and the organic acid comprises GLDA and citric acid; or MGDA and citric acid.

It was found that the first solid phase of the invention can be made substantially more plastic (less solid) by heating said first solid phase to a temperature of at least 50 degrees celsius. The thermoplastic properties may suitably be used for the preparation of shaped detergent products, for example by introducing a plasticized first solid phase into a mould and solidifying the plasticized phase within the mould by cooling. Also, the plasticized phase may be spread as a layer on a solid substrate, followed by cooling to solidify. Moreover, its thermoplastic properties make it more suitable for extrusion.

Water (W)

The first solid phase according to the invention comprises from 2 to 30% by weight of water. It has surprisingly been found that the use of such a water content provides a good balance of hardness and plasticity to the solid composition. Depending on the water content, the first solid phase may be a hard solid (water content of 2 to 20 wt.%), or a soft solid (water content above 20 to 30 wt.%). The general plastic and thermoplastic properties offer significant practical advantages, since the solid composition can be processed with a low probability of failure or crack formation (machine). Also, not inconsequential, it may provide an improved sensory experience when operated by a user. Better results were obtained with 5 to 25 wt% water and still better results with 6 to 20 wt% water. The latter range provides further optimal results between suitable hardness, reduced brittleness and plasticity. Water-activity a of the first solid phase according to the invention_wAnd may be 0.7 or less. Water activity a of at most 0.6 is preferred_wFurther preferred is a water activity a of at most 0.5_w. Water Activity a_wA preferred lower limit of (d) may be 0.15.

pH profile

The first solid phase of the invention preferably has the following pH profile: the pH of the first solid phase solution prepared by dissolving the first solid phase in water at a 1:1 weight ratio was at most 10.0 as measured at 25 degrees celsius. Such a pH profile improves the stability of the first solid phase. Particularly good results are obtained for a pH profile of at most 9.0, more preferably at most 8.0. Many detergent products are generally alkaline. Thus, for practical reasons and to increase the formulation freedom, it is preferred that the pH of the solution prepared by dissolving 1 wt% of the first solid phase in water is at least 5.0, more preferably at least 6.0, most preferably at least 6.5.

Amorphous water soluble componentThe first solid phase of the shaped detergent product may comprise up to 50 wt.% of an amorphous water-soluble component different from component a) or component b). When considered in pure form, the amorphous water-soluble component may be a liquid or a solid, but is preferably a solid. If in the form of a liquid (e.g., a liquid surfactant), it is preferably present in an amount of up to 20 wt.%, more preferably up to 10 wt.%, and even more preferably up to 5 wt.%.

Preferably, the first solid phase comprises from 5 to 45 wt%, more preferably from 10 to 40 wt%, even more preferably from 15 to 35 wt%, most preferably from 25 to 30 wt% of the amorphous water soluble component.

In a preferred embodiment, the first solid phase contains at least 10% by weight of a water soluble component selected from the group consisting of polycarboxylate polymers (polycarboxylated polymers), sulfonated polymers, and combinations thereof. In the case where the water soluble component is an acid or salt, the weight percent refers to the free acid equivalent weight percent.

Here, the term polycarboxylate polymer is also used to cover the acid form and is different from the organic acid present in the first solid phase. The addition of polycarboxylate polymer shows surprisingly further improvement of the plasticity of the first solid phase and an increase of the glass transition temperature (T) of the first solid phase_g). Improved plasticity is beneficial as it makes the first solid phase easier to (mechanically) process and makes it easier to prepare a detergent product comprising the first solid phase. A higher glass transition temperature is beneficial as it contributes to the stability of the first solid phase during storage and handling, especially in view of temperature stress. Also hasThat is, the glass transition temperature (which is not too high) contributes to a fast dissolution of the first solid phase in warm water, as it contributes to liquefaction of the first solid phase during use by increasing the surface area.

Preferably, the glass transition temperature (T) of the first solid phase_g) Less than 80 degrees celsius, more preferably 10 to 60 degrees celsius, even more preferably 15 to 50 degrees celsius, and most preferably 20 to 40 degrees celsius.

According to a particularly preferred embodiment, the first solid phase of the shaped detergent product contains at least 5 wt%, more preferably at least 10 wt%, even more preferably at least 15 wt%, and most preferably at least 25 wt% of polycarboxylate polymer, e.g. based on free acid equivalents.

Suitable polycarboxylate polymers have an average molar mass Mw of from 500 to 500000. They may be modified unmodified, but are preferably unmodified. Moreover, they may be copolymers or homopolymers, although homopolymers are considered more beneficial.

Surprisingly, it was observed that the hygroscopicity is reduced if the first solid phase of the shaped detergent product comprises a polycarboxylate polymer. This reduction is more pronounced if the polycarboxylate polymer used has a lower molecular weight. Having reduced hygroscopicity is of course beneficial as it helps to improve the stability of the shaped detergent product and generally increases shelf life. In further improving the glass transition temperature (T)_g) Polycarboxylate polymers having an average molar mass (Mw) of 900 to 100000, more preferably 1100 to 10000, give better results in terms of plasticity and hygroscopicity.

In a preferred embodiment, the first solid phase comprises at least 5 wt%, more preferably at least 10 wt%, even more preferably at least 15 wt% and most preferably at least 25 wt% of free acid equivalent polycarboxylate polymer selected from the group consisting of polyacrylates, copolymers of polyacrylates, polymaleates, copolymers of polymaleates, polymethacrylates, copolymers of polymethacrylates, polymethyl-methacrylate, copolymers of polymethyl-methacrylate, polyaspartate, copolymers of polyaspartate, polylactate, copolymers of polylactate, polyitaconates, copolymers of polyitaconates and combinations thereof.

A highly preferred polycarboxylate polymer is polyacrylate. Suitable polyacrylates are commercially available, such as those from BASF under the following trade names: sokalan PA 13PN, Solakan PA 15, Sokalan PA 20PN, Sokalan PA 20, Sokalan PA 25PN, Sokalan PA 30, Sokalan 30CL, Sokalan PA 40, Sokalan PA 50, Sokalan PA 70PN, Sokalan PA 80S and Sokalan PA 110S. PN represents partially neutralized and S represents the free acid form. Preferred are partially or fully neutralized polyacrylates. These commercially available polyacrylates differ in other aspects of their average molar mass (higher numbers indicate higher average molar masses Mw).

Thus, highly preferred for use in the first solid phase of the present invention are polyacrylates having the following combination of properties:

present in an amount of from 10 to 40% by weight, based on free acid equivalents; and

it is partially or fully neutralized; and

it has an average molar mass (Mw) of 500 to 500000; and

it is a homopolymer.

From the above, it follows that even more preferred are polyacrylates having the following combination of properties:

used in an amount of 10 to 40% by weight, based on free acid equivalents; and

it is partially or fully neutralized; and

it has an average molar mass (Mw) of from 900 to 100000; and

_·it is a homopolymer.

The sulfonated polymers preferably used according to the present invention may be copolymers or homopolymers. Preferably, the sulfonated polymer is a copolymer. Suitable sulfonated polymers have a mass average molecular weight of 3,000 to 50,000, more preferably 4,500 to 35,000. Surprisingly, it was observed that the hygroscopicity decreases if the first solid phase comprises a sulfonated polymer. Having reduced hygroscopicity is of course beneficial as it helps to improve the stability of the shaped detergent product and generally increases shelf life.

In a preferred embodiment, the first solid phase comprises at least 0.3 wt%, more preferably at least 0.6 wt%, even more preferably at least 2 wt% and most preferably at least 3 wt% of a sulfonated polymer having free acid equivalents of polymerized units comprising one or more unsaturated sulfonate monomers selected from the group consisting of 2-acrylamidomethyl-1-propanesulfonic acid, 2-methacrylamido-2-methyl-1-propanesulfonic acid, 3-methacrylamido-2-hydroxypropanesulfonic acid, allylsulfonic acid, methallylsulfonic acid, allyloxybenzenesulfonic acid. Methallyloxybenzenesulfonic acid, 2-hydroxy-3- (2-propenyloxy) propanesulfonic acid, 2-methyl-2-propene-1-sulfonic acid, styrenesulfonic acid, vinylsulfonic acid, 3-sulfopropyl acrylate, 3-sulfopropyl methacrylate, sulfomethacrylamide, sulfomethyl methacrylamide.

More preferably, the first solid phase comprises at least 0.3 wt%, more preferably at least 0.6 wt%, even more preferably at least 2 wt% and most preferably at least 3 wt% of a sulfonated polymer comprising polymerized units of one or more unsaturated sulfonate monomers selected from the group consisting of 2-acrylamidomethyl-1-propanesulfonic acid, 2-methacrylamido-2-methyl-1-propanesulfonic acid, 3-methacrylamido-2-hydroxypropanesulfonic acid, in free acid equivalents. More preferably, the first solid phase comprises at least 0.3 wt%, more preferably at least 0.6 wt%, even more preferably at least 2 wt% and most preferably at least 3 wt% of the sulfonated polymer comprising polymerized units of 2-acrylamidomethyl-1-propanesulfonic acid as free acid equivalents.

According to another preferred embodiment, the first solid phase comprises at least 0.3 wt%, more preferably at least 0.6 wt%, even more preferably at least 2 wt% and most preferably at least 3 wt% of a sulfonated polymer having free acid equivalent weight comprising polymerized units of one or more unsaturated sulfonate monomers represented by the formula:

CH₂＝CR¹-CR²R³-O-C₄H₃R⁴-SO₃X

wherein

R¹、R²、R³、R⁴Independently represent C₁-C₆Alkyl or hydrogen;

x represents hydrogen or an alkali metal.

According to a particularly preferred embodiment, the sulfonated polymer is a polymer comprising monoethylenically unsaturated C₃-C₆Copolymers of polymerized units of monocarboxylic acids. More preferably, the sulfonated copolymer comprises the following monomers in polymerized form:

from 50 to 90% by weight of one or more monoethylenically unsaturated C₃-C₆A monocarboxylic acid;

10-50% by weight of an unsaturated sulphonate monomer as defined hereinbefore.

According to another preferred embodiment, the monoethylenically unsaturated C in the sulfonated copolymer₃-C₆The monocarboxylic acid is selected from the group consisting of acrylic acid, meth (acrylic) acid, and combinations thereof.

Thus, highly preferred for use in the first solid phase of the present invention are sulfonated copolymers having the following combination of properties:

used in an amount of 2 to 15% by weight, based on free acid equivalents; and

it is partially or fully neutralized; and

it has an average molar mass (Mw) of 3000 to 50000;

it comprises in polymerized form the following monomers: 50-90% by weight of one or more monoethylenically unsaturated C₃-C₆A monocarboxylic acid; and 10-50 wt% of an unsaturated sulfonate monomer selected from the group consisting of 2-acrylamidomethyl-1-propanesulfonic acid, 2-methacrylamido-2-methyl-1-propanesulfonic acid, 3-methacrylamido-2-hydroxypropanesulfonic acid.

From the above, it can be seen that even more preferred are sulfonated copolymers having the following combination of properties:

used in amounts of 3 to 12% by weight, based on free acid equivalents; and

it is partially or fully neutralized; and

it has an average molar mass (Mw) of 4500 to 35000;

which comprises the following monomers in polymerized form: 50-90% by weight of acrylic acid and/or methyl (acrylic acid); and 10-50% by weight of 2-acrylamidomethyl-1-propanesulfonic acid.

Shaped detergent product

The first solid phase of the shaped detergent product is preferably visually distinct from the remainder of the detergent product. The detergent product is advantageously a unit dose detergent product.

Preferably, the first solid phase present in the shaped detergent product is present at from 0.1 to 20cm³More preferably 0.2 to 15cm³And even more preferably 0.4 to 10cm³Most preferably 0.5 to 5cm³Is present in at least one coherent volume (coherent volume). The preferred volume allows the first solid phase of the invention to be more easily visible to the naked eye, which is better attended to by virtue of its visual appeal. The first solid phase may be present in any suitable form such as a layer (skin/coating), a strip, a cube, etc.

The first solid phase preferably has a maximum light transmission of at least 5%, more preferably at least 10%, even more preferably at least 20%, still more preferably at least 25% and most preferably at least 30% in the wavelength range of 400 to 700 nm. Preferably, the first solid phase has an average light transmission of at least 5%, more preferably at least 10%, even more preferably at least 20%, and most preferably at least 25% in the wavelength range of 400 to 700 nm.

In a preferred embodiment, the shaped detergent product comprises from 10 to 90 wt% of the first solid phase and from 10 to 90 wt% of one or more further solid phases. An example of a shaped detergent product containing a first solid phase in combination with one or more other solid phases is a tablet coated with the first solid phase. Another example is a multilayer tablet comprising one or more layers of a first solid phase and one or more layers of a second solid phase.

Preferably, the second solid phase is visually distinct from the first solid phase.

According to a particularly preferred embodiment, the first solid phase is translucent or transparent and the second solid phase is opaque.

Preferably, the shaped detergent product of the invention is a dishwashing detergent product, a laundry detergent product or a toilet seat bar detergent product. Most preferably, the shaped detergent product is a dish washing machine detergent product.

In the case of a dishwashing detergent product, a particularly preferred amount of the first solid phase is from 5 to 60 wt%, more preferably from 10 to 50 wt%, and even more preferably from 15 to 40 wt%.

In the case of laundry detergent products, particularly preferred amounts of the first solid phase of the invention are from 10 to 60 wt%, more preferably from 20 to 50 wt%, and even more preferably from 25 to 35 wt%.

In the case of toilet seat detergent products, particularly preferred amounts of the first solid phase of the invention are from 10 to 85 wt%, more preferably from 20 to 80 wt%, and even more preferably from 40 to 70 wt%.

The distinctiveness of the first solid phase of the shaped detergent product may be further enhanced by suitable distinguishable colourings. This may be done by making it more or less intense in color (e.g., colorless). It is of course preferred that the transparency is maintained to a perceptible degree when coloring is applied. Generally, colorants such as dyes and/or pigments are effective at low amounts, and thus this generally does not pose a problem. In any case, the first solid phase of the invention is specifically intended for use in detergent products and to increase its visual appeal.

The first solid phase may be present in the detergent product of the invention in any one or more suitable shapes, such as one or more layers, wires (e.g. rods, rods), spherical or cubic shapes or combinations thereof. Preferred shapes are as follows: cubes, cylinders, spheres, bars, X-bars, pyramids, prisms, cones, domes and (circular) tubes. Among these, the more preferred shapes are strips, X-strips, cylinders, cubes, (round) tubes and spheres.

Preferably, the shaped detergent product has a unit weight of from 5 to 50 grams, more preferably a unit dose of from 10 to 30 grams, even more preferably a unit dose of from 12 to 25 grams.

Preferably, the shaped detergent product is a tablet.

Regardless of the geometric arrangement of the first solid phase within the overall detergent product, it is preferred that at least part of the solid composition forms part of the surface of the detergent product. More preferably, at least 10%, 20%, 30%, 40%, more preferably at least 50% of the surface area of the detergent product is formed by the solid composition. Preferably, at most 95%, 90% and more preferably at most 85% of the surface area of the detergent product is formed by the solid composition.

In detergent products, the first solid phase of the invention may act as a matrix and contain part or all of further ingredients in the detergent product. In this sense, the solid composition of the invention may be used to form (part of) the skin layer. Advantageously, the solid composition is used as a translucent matrix containing one or more visually distinct objects. The object is preferably spherical or cubic in shape. The object is preferably coloured.

Generally, the skilled person has the ability to use the first solid phase of the invention to exploit its advantages when preparing more attractive detergent products. In particular, the first solid phase may be used to provide a (partially) translucent detergent product and/or to provide a (partially) glossy detergent product. As mentioned above, the manner in which the first solid phase is used in a detergent product in which the solid remains visible and can be perceived due to its translucent and/or glossy nature is highly preferred.

Additional ingredients

Depending on the aminopolycarboxylate and the acid used, the first solid phase of the present invention may be colored and, for example, have a pale yellow hue. The transparency of such a first solid phase may be further improved by the addition of a relatively coloring agent, preferably a dye, to the color wheel. For example, on a color wheel, yellow is opposite to blue, and purple is opposite to green. This will make the first solid phase substantially more colorless, which may be preferred. It is noted that typical dyes need to be added in relatively small amounts to be effective. Therefore, it is recommended that their level is not higher than 0.5% by weight, preferably at most 0.2% by weight.

The detergent product according to the invention comprises a first solid phase according to the invention. The detergent product also preferably comprises, in other parts, at least one further detergent active ingredient and preferably one or more of the following: enzymes, enzyme stabilizers, bleaches, bleach activators, bleach catalysts, bleach scavengers, drying aids, silicates, metal conditioners, colorants, perfumes, lime soap dispersants, anti-foam agents, anti-discoloration agents, anti-corrosion agents, surfactants, and additional builders.

Additional builders

Additional builder materials may be selected from 1) calcium sequestrant materials, 2) deposition materials, 3) calcium ion-exchange materials, and 4) mixtures thereof. Examples of calcium sequestrant builder materials include alkali metal polyphosphates such as sodium tripolyphosphate, and organic sequestrants such as ethylenediamine tetraacetic acid. Examples of precipitating builder materials include sodium orthophosphate and sodium carbonate. Preferably, the detergent product comprises sodium carbonate in the range of 5 to 50 wt%, more preferably in the range of 10 to 35 wt%. Examples of calcium ion exchange builder materials include various types of water-insoluble crystalline or amorphous aluminosilicates, of which zeolites are the most well known representatives, such as zeolite ｃA, zeolite B (also known as zeolite P), zeolite C, zeolite X, zeolite Y and the P-type zeolites described in EP- ｃA-0,384,070.

The detergent product may also contain 0-65% of a builder or complexing agent such as ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, alkyl or alkenyl succinic acid, nitrilotriacetic acid or other builders as described hereinafter. Many builders are simultaneously bleach stabilizers by virtue of their ability to complex metal ions. Zeolites and carbonates (including bicarbonates and sesquicarbonates)) are preferred additional builders.

The builder may be a crystalline aluminosilicate, preferably an alkali metal aluminosilicate, more preferably a sodium aluminosilicate. This is typically present at a level of less than 15 wt%. Aluminosilicates are materials having the general formula: 0.8-1.5M₂O·Al₂O₃·0.8-6SiO₂Wherein M is a monovalent cation, preferably sodium. These materials contain some bound water and need to have a calcium ion exchange capacity of at least 50mg CaO/g. Preferred sodium aluminosilicates contain 1.5-3.5 SiO in the above formula₂And (4) units. They can be easily prepared by reaction between sodium silicate and sodium aluminate, as fully described in the literature. The ratio of surfactant to aluminosilicate (when present) is preferably greater than 5:2, more preferably greater than 3: 1.

Alternatively, or in addition to aluminosilicate builders, phosphate builders may be used. In the present invention, the term "phosphate" includes diphosphate, triphosphate and phosphonate species. Other forms of builders include silicates, such as soluble silicates, metasilicates, layered silicates (e.g., SKS-6 from Hoechst). Preferably, however, the detergent product is a non-phosphate built detergent product, i.e. contains less than 1 wt% phosphate, and preferably is substantially free of phosphate.

In view of the environmental concerns associated with the use of high levels of phosphorus-based builders in detergent compositions, it is preferred that the detergent products according to the invention comprise up to 5 wt%, more preferably up to 1 wt% of phosphorus-based builder, and in particular are substantially free of phosphorus-based builder. Examples of phosphorus-based builders are 1-hydroxyethane-1, 1-diphosphonic acid (HEDP), diethylenetriaminepentakis (methylenephosphonic acid) (DTPMP), Ethylenediaminetetramethylenephosphonate (EDTMP), tripolyphosphate, pyrophosphate.

Alkali metal carbonates are of interest for their dual function as builders and buffers, and are preferably present in detergent products. Preferred amounts of alkali metal carbonate in the detergent product, if present, are from 2 to 75 wt%, more preferably from 3 to 50 wt%, and even more preferably from 5 to 20 wt%. Alkali metal carbonates at this level provide good Ca for most types of water hardness levels²⁺And Mg²⁺Ion scavenging, and other builder functions, such as providing good buffering capacity. Preferred alkali metal carbonates are sodium carbonate and/or potassium carbonate, with sodium carbonate being particularly preferred. Alkali metals present in the detergent products of the inventionThe acid salt may be present as such or as part of a more complex composition (e.g., sodium carbonate in sodium percarbonate).

Surface active agent

The shaped detergent product of the invention comprises 0.5 wt% surfactant, preferably 1 to 70 wt% surfactant, more preferably 2 to 50 wt% surfactant. The surfactant may be nonionic or anionic.

In the case of dishwashing machine detergent products, particularly preferred amounts of surfactants are from 0.5 to 25% by weight, preferably from 2 to 15% by weight. In the case of toilet seat detergent products, particularly preferred amounts of surfactant are from 0.5 to 55% by weight, preferably from 10 to 40% by weight. In the case of laundry detergent products, particularly preferred amounts of surfactant are from 2 to 70 wt%, preferably from 10 to 35 wt%.

The nonionic and anionic surfactants of the surfactant system may be selected from "Surface active Agents", Vol.1, Schwartz & Perry, Interscience 1949; volume 2, Schwartz, Perry & Berch, Interscience 1958; surfactants as described in the current version of "McCutcheon's emulsifiers and Detergents", published by Manufacturing conditioners Company, or "Tenside-Taschenbuch", H.Stache, 2 nd edition, Carl Hauser Verlag, 1981. Preferably, the surfactant used is saturated.

Nonionic surfactant

Suitable nonionic surfactants which may be used include in particular the reaction products of compounds having a hydrophobic group and active hydrogen atoms, such as aliphatic alcohols, acids, amides or alkylphenols, with alkylene oxides, in particular ethylene oxide alone or together with propylene oxide.

Preferably, low-foaming nonionic surfactants from the group of alkoxylated alcohols are used in particular. Alkoxylated (advantageously ethoxylated), in particular primary alcohols, having preferably 8 to 18C atoms and an average of 1 to 12mol of Ethylene Oxide (EO) per mole of alcohol, where the alcohol residue may be linear or methyl-branched, preferably in the 2-position, or may be presentThe mixture contains straight chain and methyl branched residues, as are typically present in oxoalcohol residues, preferably used as nonionic surfactants. In particular, however, alcohol ethoxylates having a linear residue prepared from alcohols of natural origin having from 12 to 18C atoms (for example from coconut, palm, tallow fat or oleyl alcohol) and having an average of from 2 to 8mol EO per mol of alcohol are preferred. Preferred ethoxylated alcohols include, for example, C with 3EO to 4EO_12-14Alcohols, C with 7EO_9-12Alcohols, C with 3EO, 5EO, 7EO or 8EO_13-15Alcohols, C with 3EO, 5EO or 7EO_12-18Alcohols and mixtures of these, e.g. C with 3EO_12-14Alcohols and C with 5EO_12-19A mixture of alcohols. Preferred tallow fatty alcohols with more than 12EO have 60 to 100EO, more preferably 70 to 90 EO. A particularly preferred tallow fatty alcohol with more than 12EO is a tallow fatty alcohol with 80 EO.

Likewise particular preference is given to using nonionic surfactants from the group of alkoxylated alcohols, particular preference being given to the group of mixed alkoxylated alcohols, in particular from the group of EO-AO-EO nonionic surfactants. The surfactants preferably used originate from the group comprising alkoxylated nonionic surfactants, in particular ethoxylated primary alcohols, and also mixtures of these surfactants with surfactants of complex structure, such as polyoxypropylene/polyoxyethylene/polyoxypropylene (PO/EO/PO) surfactants. Such (PO/EO/PO) nonionic surfactants also differ by good foam control.

The most preferred nonionic surfactants are according to the formula:

wherein n is 0 to 5 and m is 10 to 50, more preferably wherein n is 0 to 3 and m is 15 to 40, and even more preferably wherein n is 0 and m is 18 to 25. Surfactants according to this formula are particularly useful for reducing spotting of dishes treated in a dish washing machine. Preferably, the detergent product of the invention comprises at least 50 wt% of the nonionic surfactant according to this formula. Such nonionic surfactants are commercially available, for example under the trade names Dehypon WET (supplier: BASF) and Genapol EC50 (supplier: Clariant).

The shaped detergent products of the invention preferably comprise from 0.5 to 15 wt% of nonionic surfactant. A more preferred total amount of nonionic surfactant is an amount of from 2.0 to 8 wt%, and even more preferred is from 2.5 to 5.0 wt%. The nonionic surfactant used in the detergent products of the invention may be a single nonionic surfactant or a mixture of two or more nonionic surfactants.

The nonionic surfactant is preferably present in an amount of from 25 to 90 wt%, based on the total weight of the surfactant system. The anionic surfactant may be present, for example, in an amount in the range of 5 to 40 wt% of the surfactant system.

Anionic surfactants

Suitable anionic surfactants which may be used are preferably water-soluble alkali metal salts of organic sulfuric and sulfonic acids having an alkyl group containing from about 8 to about 22 carbon atoms, the term alkyl being used to include the alkyl portion of higher acyl groups. Examples of suitable synthetic anionic surfactants are sodium and potassium alkyl sulfates, especially those obtained by sulfating higher C8 to C18 alcohols (e.g., produced from tallow or coconut oil), sodium and potassium alkyl C9 to C20 benzene sulfonates, especially sodium linear secondary alkyl C10 to C15 benzene sulfonates; and sodium alkyl glyceryl ether sulfates, particularly those derived from higher alcohols of tallow or coconut oil and synthetic alcohols derived from petroleum. Preferred anionic surfactants are sodium C11 to C15 alkyl benzene sulfonates and sodium C12 to C18 alkyl sulfonates. Surfactants such as those described in EP-A-328177 (Unilever) which exhibit resistance to salting out, alkylpolyglycoside surfactants described in EP-A-070074, and alkylmonoglycosides are also suitable.

Bleaching system

It is preferred that the shaped detergent product according to the invention comprises at least 5 wt%, more preferably at least 8 wt%, and even more preferably at least 10 wt% of bleach, based on the total weight of the product. The bleaching agent preferably comprises a chlorine or bromine releasing agent or a peroxy compound. Preferably, the bleaching agent is selected from the group consisting of peroxides (including peroxide salts, such as sodium percarbonate), organic peracids, salts of organic peracids and combinations thereof. More preferably, the bleaching agent is a peroxide. Most preferably, the bleaching agent is percarbonate.

The shaped detergent products of the present invention may contain one or more bleach activators, such as peroxyacid bleach precursors. Peroxyacid bleach precursors are well known in the art. By way of non-limiting example, mention may be made of N, N, N ', N' -Tetraacetylethylenediamine (TAED), Sodium Nonanoyloxybenzenesulfonate (SNOBS), sodium benzoyloxybenzenesulfonate (SBOBS) and cationic peroxyacid precursors (SPCC), as described in U.S. Pat. No. 4,751,015.

Preferably, the shaped detergent product comprises a bleach catalyst. Particularly preferred are bleach catalysts as manganese complexes, such as Mn-Me TACN, as described in EP-A-0458397, and/or sulphoimides of US-A-5,041,232 and US-A-5,047,163 (sulphoimines). It is advantageous that the bleach catalyst is physically separated from the bleach in the detergent product (to avoid premature bleach activation). Cobalt or iron catalysts may also be used.

Enzyme

The shaped detergent product of the invention preferably further comprises one or more enzymes selected from the group consisting of: proteases, alpha-amylases, cellulases, lipases, peroxidases/oxidases, pectate lyases and mannanases. Particularly preferred are proteases, amylases, or combinations thereof. If present, the level of each enzyme is from 0.0001 to 1.0 wt%, more preferably from 0.001 to 0.8 wt%.

Silicates of acid or alkali

Silicates are known detergent ingredients and are typically included to provide dishwashing care benefits and to reduce dishwashing corrosion. Particularly preferred silicates are sodium disilicate, sodium metasilicate and crystalline layered silicates or mixtures thereof. If present, the total amount of silicate is preferably from 1 to 15 wt%, more preferably from 2 to 10 wt%, and even more preferably from 2.5 to 5.0 wt%, based on the weight of the shaped detergent product.

Perfume

Preferably, the shaped detergent product of the invention comprises one or more colorants, perfumes or mixtures thereof in an amount of from 0.0001 to 8 wt%, more preferably from 0.001 to 4 wt% and even more preferably from 0.001 to 1.5 wt%.

The perfume is preferably present in the range of 0.1 to 1 wt%. Many suitable examples of perfumes are provided in the CTFA published by CFTAPublifications (Cosmetic, Toiletry and Fragrance Association)1992International layers Guide and the OPD 1993chemical layers Directory 80th annular Edition published by Schnell Publishing Co. In the perfume mixture, preferably 15 to 25% by weight is top notes. Top notes are defined by Poucher (Journal of the Society of Cosmetic Chemists 6(2):80[1955 ]). Preferred headnotes are selected from the group consisting of citrus oils, linalool, linalyl acetate, lavender, dihydromyrcenol, rose oxide and cis-3-hexanol.

Shading dye

In particular, for laundry detergent compositions according to the present invention, it is preferred that they comprise a hueing dye. For example, shading dyes are added to laundry detergent formulations to enhance the whiteness of fabrics. The shading dye is preferably a blue or violet dye which is substantive to the fabric. Mixtures of hueing dyes may be used and, in practice, are preferred for treating mixed fibre fabrics. Preferred amounts of hueing dye are from 0.00001 to 1.0 wt%, preferably from 0.0001 to 0.1 wt%, in particular, amounts of from 0.001 to 0.01 wt% are preferred. Hueing dyes are discussed in WO2005/003274, WO2006/032327, WO2006/032397, WO2006/045275, WO2006/027086, WOO2008/017570, WO 2008/141880, WO2009/132870, WO2009/141173, WO 2010/099997, WO2010/102861, WO2010/148624, WO2008/087497 and WO 2011/011799.

Shaped detergent product forms

Due to the presence of the first solid phase, the shaped detergent product comprises at least a solid part. The remainder of the detergent product may also be non-solid, such as in liquid form, but preferably comprises at least one further solid portion.

The detergent product is preferably provided as a water-soluble or water-dispersible unit dose. Particularly preferred unit doses are in the form of sachets containing at least one additional non-forming stable ingredient, such as a liquid and/or a powder; or in the form of tablets. For ease of use, the unit dose is sized and shaped to fit into a detergent cup of a conventional household dish washing machine, washing machine or toilet seat holder, as is known in the art.

An advantageous unit dose bag preferably has more than one compartment.

Advantageous unit dose tablets are those having more than one visually distinct tablet region. Such areas may be formed, for example, by two different (colored) layers or tablets having a body and different inserts, such as to form nested eggs (nested eggs). Regardless of orientation, one benefit of using a multi-compartment pouch/multi-region tablet is that it can be used to reduce/prevent unwanted chemical reactions between two or more ingredients during storage by physical isolation.

Preferably, the unit dose detergent product is packaged for improved hygiene and consumer safety. The wrapper is advantageously based on a water-soluble film, which is preferably a polyvinyl alcohol (PVA) based film. Such a wrapping prevents the detergent product from coming into direct contact with the skin of the consumer when a unit dose is placed in, for example, a detergent cup/holder of a dishwashing machine. Of course, a further benefit is that the consumer does not need to remove the water-soluble wrap prior to use.

The detergent products according to the invention can be prepared using methods and equipment known in the art of detergent preparation. Detergent products according to the invention may be prepared by combining the first solid phase of the invention with the remainder of the detergent ingredients. In view of the preparation of tablets, a particularly preferred combination is to press the first solid phase of the invention onto (or into) the rest of the tablet ingredients and/or by adding the first solid phase in heated (liquid) form.

Preferred detergent product formulationsHeightPreferred general purpose detergent product formulations are as follows:

composition (I)	Amount (wt%)
		First solid phase according to the invention	10 to 80
Surface active agent	0.5 to 70
		Phosphate salts	At most 1.0
Preferably, a combined amount of fragrance and colorant	0.0001 to 8.0

In the case of a dishwashing machine detergent product, the product is preferably a unit dose tablet having the following composition:

composition (I)	Amount (wt%)
		First solid phase according to the invention	15 to 40
Additional builders, preferably basesMetal carbonates	5 to 20
		Nonionic surfactant	0.5 to 15
Enzyme	0.001 to 0.8
		Silicates of acid or alkali	1 to 10
Bleaching agent + bleach activator + bleach catalyst	2 to 20
		Phosphate salts	At most 1.0
Preferably, a combined amount of fragrance and colorant	0.001 to 1.5

In the case of toilet seat detergent products, the product is preferably a solid block composition, e.g. free of liquid parts and/or powder/granular parts, and even more preferably has the following composition:

in the case of laundry detergent products, they advantageously have the following composition:

composition (I)	Amount (wt%)
		First solid phase according to the invention	5 to 35
Surface active agent	10 to 35
		Enzyme	0.001 to 0.8
Phosphate salts	At most 1.0
		Preferably, a combined amount of fragrance and colorant	0.001 to 4

Process for preparing a first solid phase of a shaped detergent product

Another aspect of the invention relates to a method of preparing a first solid phase, the method comprising the steps of:

I. providing an aqueous solution comprising an aminopolycarboxylate salt, an acid and a water-soluble component; and

removing water from the aqueous solution.

In a preferred embodiment of the process of the invention, the preparation process comprises the following steps:

removing water from the aqueous solution by evaporation at a temperature of at least 50 ℃ to produce a liquid dry mixture having a water content of no more than 30% by weight; and

reducing the temperature of the dried mixture to less than 25 ℃ to obtain a shaped detergent product.

The method of preparing the first solid phase according to the invention has the advantage of being simple and economical and obviates the need for adding additional crystal formation inhibitors.

Step i. of the process according to the invention is the provision of an aqueous solution comprising:

a) amorphous chiral aminopolycarboxylates; and

b) an amorphous organic acid different from a).

The combination of ingredients in step i. The amount of water used to provide the aqueous solution is advantageously sufficient to completely dissolve components a) and b) at boiling temperatures to simplify processing. Both the aminopolycarboxylate and the organic acid may be added as separate pre-prepared aqueous solutions, which is preferred for further simplification of processing. As indicated, preferred step i. addition of a) as (part of) the alkali metal salt and b) as the acid. When the aminopolycarboxylate salt is combined with an acid, additional water may need to be added and/or heat applied to completely dissolve the ingredients, as a precipitate may form.

Heat may be applied to (more quickly) dissolve components a) and b). Applying heat in step i. is preferred because it not only reduces the time to dissolve (if necessary) components a) and b), as it can also reduce the amount of water required to provide the solution, thereby saving costs. Also, having less water in the solution provided in step I may save time for completing step ii. Preferably in step i.an aqueous solution having a temperature of at least 50, more preferably at least 70, even more preferably at least 95 degrees celsius, most preferably at least 100 degrees celsius is provided.

The aqueous solution in step i. should be homogeneous at least with respect to the chiral aminopolycarboxylate, the acid and the water. More preferably, the aqueous solution is completely homogeneous. Thus, it is particularly preferred that the aqueous solution of step i. The aqueous solution provided in step i.

Adding a large amount of water in step i. means that more water needs to be removed in step II, requiring additional time and/or energy. Thus, preferably, the aqueous solution provided in step I comprises 40 to 95 wt% water, preferably 45 to 85 wt% water.

The first solid phase is characterized by a pH profile, as measured at 25 degrees celsius, of at most 10.0 based on the first solid phase in a 1:1 first solid phase to water weight ratio solution in water. This can be easily achieved by suitably adjusting the pH of the aqueous solution accordingly (preferably in step I.) according to conventional methods. For example, the balanced use of the acid or (partially) neutralized salt forms of components a) and b) can be applied.

In step ii. of the process, water is removed from the aqueous solution provided in step i. by evaporation at a temperature of at least 50 degrees celsius to provide a water content of 2 to 30% by weight. Preferably, the water is removed from the aqueous solution by evaporation at a temperature of at least 70 degrees celsius, more preferably at least 95 degrees celsius and most preferably at least 100 degrees celsius.

A preferred way of removing water in step ii. is by applying sufficient heat to boil the aqueous solution provided in step i. This allows for a fast removal of water, which is advantageous for obtaining the benefits of the first solid phase according to the invention. Thus, the removal of water may be performed by any suitable method, but preferably such that the removal of water is equivalent to (on-par), or faster than, boiling under otherwise standard environmental conditions.

Preferably step ii. Spray drying is believed to promote crystal formation, thereby reducing the transparency of the resulting solid phase.

In step iii, the temperature of the dried mixture is reduced to below 25 ℃ to obtain a solid phase. Preferably, the temperature is reduced to 20 to 25 degrees celsius. Step iii can be performed using passive cooling or active cooling. Active cooling may be performed using any conventional means, such as by refrigeration.

In a particularly preferred step iii, the cooling of the dry mixture is effected by heat exchange with the remainder of the detergent product portion. In this sense it is particularly preferred that the "first solid phase" is applied to the remainder of the detergent product in liquid/viscous form having an elevated temperature and allowed to solidify (further) in situ. A further surprising benefit conferred by the first solid phase of the invention is: it can be reheated to increase its plasticity for machining.

Preferably, the first solid phase according to the invention is obtainable by a method according to the invention.

Unless otherwise indicated, preferred aspects in the context of one aspect of the invention (e.g. the first solid phase) also apply (mutatis mutandis) to preferred aspects in the context of one other aspect of the invention.

The invention will now be illustrated by the following non-limiting examples.