阅读说明：本技术 一种混凝土表面增强剂及其制备和使用方法 (Concrete surface reinforcing agent and preparation and use methods thereof ) 是由 李超 何开伟 王佩勋 王林 舒春雪 于 2020-06-08 设计创作，主要内容包括：本发明涉及混凝土工程技术领域,具体涉及一种混凝土表面增强剂及其制备和使用方法。该表面增强剂含有以下重量百分比的组分,5～30%的有机硅树脂、3%～20%的滑石粉、2%～10%的硫酸盐、余量为水；其中所述有机硅树脂为有机硅树脂乳液。增强剂透过表面孔隙渗入混凝土表层内部,硫酸盐与氢氧化钙反应后,有机硅树脂和沉淀物质混合充分,形成交叉网状结构；同时混凝土表面的有机树脂乳液形成坚硬的薄膜,薄膜与孔隙中的网状结构相连,使得表面增强剂与混凝土形成紧密连接。从而提高混凝土表面的强度,同时阻挡空气中的酸性气体、酸性可溶性盐等物质的渗入。(The invention relates to the technical field of concrete engineering, in particular to a concrete surface reinforcing agent and preparation and use methods thereof. The surface reinforcing agent comprises the following components, by weight, 5-30% of organic silicon resin, 3-20% of talcum powder, 2-10% of sulfate and the balance of water; wherein the organic silicon resin is organic silicon resin emulsion. The reinforcing agent permeates into the interior of the concrete surface layer through surface pores, and after the sulfate reacts with the calcium hydroxide, the organic silicon resin and the precipitate are fully mixed to form a cross net structure; meanwhile, the organic resin emulsion on the surface of the concrete forms a hard film, and the film is connected with the net structure in the pores, so that the surface reinforcing agent is tightly connected with the concrete. Thereby improving the strength of the concrete surface and simultaneously blocking the infiltration of substances such as acid gas, acid soluble salt and the like in the air.)

1. The concrete surface reinforcing agent is characterized by comprising the following components, by weight, 5-30% of organic silicon resin, 3-20% of talcum powder, 2-15% of sulfate and the balance of water; wherein the organic silicon resin is organic silicon resin emulsion.

2. The concrete surface enhancer as claimed in claim 1, wherein the silicone resin is one or more of an organosilane, a silicate and a siloxane.

3. The concrete surface enhancer according to claim 1, wherein the weight ratio of the silicone resin in the concrete surface enhancer is 8 to 20%.

4. The concrete surface enhancer as claimed in claim 1, wherein the sulfate is present in the concrete surface enhancer in an amount of 6 to 10% by weight.

5. The concrete surface reinforcing agent according to claim 1, further comprising 0.5 to 2.5% of an additive component, wherein the additive component is one or more of polyoxypropylene polyoxyethylene glycerol ether, silicone emulsion, polyoxypropylene glycerol ether, polyoxyethylene polyoxypropylene pentaerythritol ether, polyoxyethylene polyoxypropylene amine ether, a higher alcohol fatty acid ester compound or polydimethylsiloxane.

6. The concrete surface reinforcing agent of claim 1, further comprising 2-15% of a filler component, wherein the filler component is one or both of lignocellulose and latex powder.

7. The method for producing a concrete surface reinforcing agent according to any one of claims 1 to 6, comprising the steps of:

s1, weighing the components according to the proportion, and mixing uniformly;

s2, standing the uniformly mixed mixture for 22-26 hours in an environment with the temperature of 20 +/-2 ℃ and the relative humidity of 60 +/-5%; obtaining the surface reinforcing agent.

8. The method for using the concrete surface reinforcing agent according to any one of claims 1 to 6, wherein the concrete surface reinforcing agent is applied to the concrete surface by brushing, spraying or roll coating; and curing for 7-14 days.

9. Use according to claim 8, wherein the number of applications by brushing, spraying or rolling is 3 to 5.

10. The use method of claim 8, wherein the surface reinforcing agent is coated, sprayed or rolled on the surface of the concrete by 0.2-0.4 kg per square meter.

Technical Field

The invention relates to the technical field of concrete engineering, in particular to a concrete surface reinforcing agent and preparation and use methods thereof.

Background

Insufficient strength of the concrete surface is one of the concrete problems that are common today. When the concrete is not cured in the natural environment, the surface is lack of water due to water evaporation, the concrete is not fully hydrated, and the surface concrete is loose and porous; the concrete structure is exposed to the natural environment all the year round, and water, soluble salt, acid gas containing sulfur dioxide and the like in the air enter the concrete through the pores, so that the irreversible quality problems of the concrete, such as the reduction of the surface strength, the easy corrosion, the great reduction of the durability and the like, are caused.

At present, inorganic salt type and organic emulsion type are commonly used as methods for reinforcing the surface of concrete. The inorganic salt type is formed by reacting inorganic salt with cement hydration products on the surface of concrete, and has the effects of infiltration and sealing. However, the surface reinforcing agent of inorganic salts has poor permeability and insufficient clogging of harmful pores of concrete, resulting in poor durability. Although the organic emulsion type can greatly improve the surface strength of the concrete, the organic emulsion type has poor permeability and cannot penetrate into the concrete to be integrated with the concrete, so that the durability of the concrete is poor.

Disclosure of Invention

The invention aims to: aiming at the problem of low durability of the concrete surface reinforcing agent in the prior art, the concrete surface reinforcing agent is provided, and the sulfate and the talcum powder are added, so that the permeability of the organic silicon resin emulsion is enhanced, the porosity of a concrete surface layer is effectively reduced, the pore structure of the concrete surface layer is improved, micro cracks are repaired, and the surface strength and durability of concrete can be obviously improved.

In order to achieve the purpose, the invention adopts the technical scheme that:

a concrete surface reinforcing agent comprises the following components, by weight, 5-30% of organic silicon resin, 3-20% of talcum powder, 2-10% of sulfate and the balance of water; wherein the organic silicon resin is organic silicon resin emulsion.

The silicone resin of 5-30% refers to that the silicone resin exists in the form of silicone resin emulsion, the silicone resin emulsion contains the silicone resin, and the silicone resin accounts for 5-30% of the whole surface reinforcing agent by weight. The water in the component (a) comprises the water in the silicone resin emulsion.

The organic silicon resin emulsion in the components has the advantages of high temperature resistance, electric insulation, radiation resistance, flame retardance, water resistance, corrosion resistance and the like; the sulfate can react with the cement hydration product calcium hydroxide to generate a precipitate, so that harmful pores of the concrete are blocked, and the compactness of the concrete is improved. The talcum powder can improve the fluidity of the organic silicon resin emulsion; the sulfate and the organic silicon resin emulsion are easy to permeate into harmful pores of concrete, so that the blocking effect of the sulfate is favorably exerted, and formed precipitated substances are fully bonded with the concrete and the organic silicon resin to realize the full combination of organic and inorganic materials.

After the concrete surface reinforcing agent is coated on the surface of concrete or building mortar, the reinforcing agent permeates into the interior of the concrete surface layer through surface pores, and after sulfate reacts with calcium hydroxide, organic silicon resin and a precipitate are fully mixed to form a cross-network structure; meanwhile, the organic resin emulsion on the surface of the concrete forms a hard film, and the film is connected with the net structure in the pores, so that the surface reinforcing agent is tightly connected with the concrete. After the surface reinforcing agent is used for treatment, the surface elastic strength of concrete is enhanced, meanwhile, substances such as acid gas, acid soluble salt and the like in the air are difficult to permeate into the concrete, the permeability of chloride ions is reduced, the compactness of the surface of the concrete is improved, and the durability of the concrete is enhanced.

As a preferable scheme of the invention, the organic silicon resin is one or more of organosilane, silicate and siloxane.

In a preferred embodiment of the present invention, the weight ratio of the silicone resin in the concrete surface enhancer is 8% to 20%.

The silicone resin can improve the rebound strength and durability of concrete as the weight ratio of the silicone resin increases, but when the ratio exceeds 20%, the rebound strength and durability both show a tendency of decreasing because the viscosity of the resin emulsion increases, bubbles increase during use, resulting in insufficient infiltration performance, and the rebound strength and durability are reduced. More preferably, the weight ratio of the silicone resin is 15% to 20%.

In a preferred embodiment of the present invention, the sulfate is one or both of sodium sulfate and potassium sulfate.

In a preferred embodiment of the present invention, the sulfate is present in an amount of 6 to 10% by weight of the concrete surface enhancer.

With the increase of the proportion of the sodium sulfate, the precipitate formed by the sulfate and the calcium hydroxide is interwoven with the organic silicon resin to form a net structure, so that the connection degree of the film and the net structure in pores is improved, and the surface elastic strength of the concrete is improved; on the other hand, the precipitation ratio is increased, so that the compactness of the net structure is reduced, the organic silicon resin part is in a fracture state, external acid gas or acid soluble salt is easy to permeate into the concrete, and the durability of the concrete is reduced. When the weight ratio of the sulfate is 6-10%, the rebound strength and the durability of the concrete are both in a better state, and the effect is better.

As a preferable scheme of the invention, the concrete surface reinforcing agent also comprises 0.5-2.5% of additive components, wherein the additive components are one or more of polyoxypropylene polyoxyethylene glycerol ether, emulsified silicone oil, polyoxypropylene glycerol ether, polyoxyethylene polyoxypropylene pentaerythritol ether, polyoxyethylene polyoxypropylene amine ether, high alcohol fatty acid ester compound or polydimethylsiloxane.

The additive component is a film forming agent or a defoaming agent, the film forming agent promotes the plastic flow of latex particles to improve the coalescence of the latex particles, and the film forming speed of the coating can be increased; the foam in the high molecular polymer emulsion belongs to an unstable system, the introduction of the defoaming agent reduces the local surface tension of the foam, improves the dispersibility of the added materials and the stability of the emulsion, and promotes the stability of the surface reinforcing agent and the film forming speed.

As a preferable scheme of the invention, the concrete surface reinforcing agent also comprises 2-15% of filling components, and the filling components are one or two of lignocellulose and latex powder.

The filling components such as latex powder or wood fiber bundles and the like can improve the viscosity of the emulsion, increase the stability of the surface reinforcing agent, and contribute to reducing the loss of the surface reinforcing agent so as to improve the viscosity of the emulsion and ensure the exertion of the reinforcing effect of the surface reinforcing agent.

The preparation method of the concrete surface reinforcing agent comprises the following steps:

s1, weighing the components according to the proportion, and mixing uniformly;

s2, standing the uniformly mixed mixture for 22-26 hours in an environment with the temperature of 20 +/-2 ℃ and the relative humidity of 60 +/-5%; obtaining the surface reinforcing agent.

The using method of the concrete surface reinforcing agent is characterized in that the concrete surface reinforcing agent is coated on the surface of concrete in a brushing, spraying or roller coating mode; and curing for 7-14 days.

As a preferable scheme of the invention, the painting times of brushing, spraying or roller coating are 3-5 times.

As a preferable scheme of the invention, the surface reinforcing agent is coated, sprayed or rolled on the surface of the concrete per square meter by 0.2-0.4 kg.

In summary, due to the adoption of the technical scheme, the invention has the beneficial effects that:

1. the concrete surface reinforcing agent is combined with sulfate through the organic silicon resin emulsion, the reinforcing agent permeates into the interior of a concrete surface layer through surface pores, and after the sulfate reacts with calcium hydroxide, the organic silicon resin and a precipitate are fully mixed to form a cross net structure; meanwhile, the organic resin emulsion on the surface of the concrete forms a hard film, and the film is connected with the net structure in the pores, so that the surface reinforcing agent is tightly connected with the concrete. Thereby improving the strength of the concrete surface, simultaneously blocking the infiltration of substances such as acid gas, acidic soluble salt and the like in the air, improving the compactness of the concrete and enhancing the durability of the concrete.

2. The concrete surface reinforcing agent can improve the fluidity of the reinforcing agent through the talcum powder; under the action of the talcum powder, the sulfate and the organic silicon resin emulsion are easy to permeate into harmful pores of concrete, so that the sulfate blocking effect is favorably exerted, and formed precipitate is fully bonded with the concrete and the organic silicon resin.

3. The concrete surface reinforcing agent of the invention improves the effect of the concrete surface reinforcing agent by selecting proper additive components.

4. According to the preparation method of the concrete surface reinforcing agent, the mixed components are maintained for 24 hours, so that the components of the reinforcing agent are pre-reacted, the combination of the components is tighter, and the improvement of the performance of the surface reinforcing agent is facilitated.

Drawings

FIG. 1 is a schematic view showing the state of a concrete surface enhancer of the present invention.

FIG. 2 is a schematic view showing the effect of the concrete surface enhancer of the present invention.

Detailed Description

In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention will be described in further detail below with reference to the accompanying drawings and examples. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.

After the surface reinforcing agent is coated on the surface of concrete, the performance of the concrete is tested. And testing the initial resilience strength, the reinforced resilience strength after 3 days and the reinforced resilience strength after 56 days by adopting a GHT450 type resiliometer.

Resistance to chloride ion penetration: according to the requirement of a concrete chloride ion penetration resistance test, after curing for 28 days in a standard curing room with the temperature of 20 +/-2 ℃ and the relative humidity of more than 95%, a concrete test block with the size of 100mm multiplied by 50mm is prepared, then a high polymer surface reinforcing agent is coated, after curing for 7, 14 and 28 days, vacuum water saturation is carried out on the concrete test block, the high polymer surface reinforcing agent is coated on the surface of the concrete, the concrete test block is subjected to vacuum water saturation, after water saturation, the test block is taken out and installed in a test groove, the sealing performance of the test block is checked, a sodium chloride solution with the concentration of 3% and a sodium hydroxide solution with the concentration of 0.3mol/L are injected into the test groove, the current value is recorded every 30 minutes, and the test is finished after 6.

And (3) carbonization test: in the standard of test methods for long-term performance and durability of ordinary concrete (GB/T50082-2009), concrete test blocks coated with a high-molecular polymer surface reinforcing agent are placed into a carbonization box, the distance between the test blocks is 50mm, the concentration is kept at 20 +/-3%, the relative humidity is controlled at 70%, and the temperature is controlled at 20 +/-2 ℃. And taking out the test blocks according to different ages, splitting the test blocks, dripping 1% phenolphthalein alcohol solution, and measuring the carbonization depth of each measurement area by using a vernier caliper after 30 s.

And (3) freezing resistance test: and (3) soaking the concrete test block coated with the high molecular polymer surface reinforcing agent for 28 days in water, and taking out the test block after 4 days to measure the initial mass and the initial value of the transverse fundamental frequency of the test block. And (3) putting the test block into a freeze-thaw box for freeze-thaw cycle test, and measuring the quality and the transverse fundamental frequency of the test block after each 50 times of freeze-thaw cycles. And measuring the mass loss rate and the relative dynamic elastic modulus according to a formula.

Sulfate corrosion resistance: and respectively soaking the concrete test blocks coated with the high molecular polymer surface reinforcing agent for 28 days in plastic containers filled with 5% sodium sulfate solution and clear water for 28, 60, 90 and 150 days. The pH value and the temperature of the sodium sulfate solution are periodically checked, so that the pH value is kept between 6 and 8, and the temperature is kept at 25 +/-2 ℃. And (3) periodically detecting the compressive strength of the concrete soaked in different solutions, and calculating the corrosion resistance coefficient according to a formula.

Wherein K represents corrosion resistance (%);

R₁-compressive strength (MPa) of concrete soaked in clear water;

R₂compressive strength (MPa) of concrete soaked in solution.

The raw materials used in this application are as follows

Silicone resin emulsion:

6683 silicone resin emulsion from Dow Corning, whose chemical components are mainly organosilane and silicate; SH9608 silicone resin emulsion from New Sihai corporation, whose chemical composition is mainly siloxane.

The sulfate is industrial grade sodium sulfate or potassium sulfate.

The latex powder adopts SAE latex powder. Namely styrene-butyl acrylate copolymer latex powder, which is called styrene-acrylic copolymer latex powder for short. The main chemical component is acrylate copolymer, pH value is 8, white powder, no coarse grain and impurity, bulk density is 0.5kg/L, solid content is 99 +/-1%, and average particle size is 20 μm.

Lignocellulose with fiber length of 0.5-3mm, 800 deg.C resistance, flame retardance, and bulk density of about 20g/cm³。

The talcum powder comprises the main chemical components of silicon dioxide and magnesium oxide, wherein the silicon dioxide content is 61.2 percent, the magnesium oxide content is 31.8 percent, and the water content is 7 percent; the physical properties were white powder with an average particle size of 45 μm.