阅读说明：本技术 一种炼焦工艺及装置 (Coking process and device ) 是由 张继龙 王美君 张露雅 杨艳芳 王海苹 于 2020-05-14 设计创作，主要内容包括：本发明公开一种炼焦工艺及装置,废油脂通过脱杂与煤炭在预处理装置中混合,然后经过真空过滤分离出预处理煤和液体；预处理煤经粉碎筛分后进入预热解装置,液体经油水分离分离出油脂和水；分离后油脂进入预热解装置和预处理煤混合反应,分离水经压滤得到压滤水和矿物质；反应后的油脂和煤混合物先通过真空过滤将过滤油脂收集,再将过滤后的煤在炼焦炉中炼焦后得到焦炭；收集的过滤油脂经压滤得到煤泥和压滤油脂,煤泥和过滤后的煤一同装入炼焦炉中炼焦,压滤油脂先通过蒸馏分离出低沸物,再通过精馏分离出中沸物,高沸物的精馏油脂返回到预处理装置循环使用。本发明开发了烟煤炼焦加工新途径,扩展了炼焦用煤的煤种,改善了炼焦煤资源的紧缺状况。(The invention discloses a coking process and a device, waste oil and fat are mixed with coal in a pretreatment device through impurity removal, and then pretreated coal and liquid are separated through vacuum filtration; crushing and screening the pretreated coal, then feeding the crushed coal into a pre-pyrolysis device, and separating oil and water from liquid through oil-water separation; the separated grease enters a pre-pyrolysis device to be mixed and reacted with the pretreated coal, and the separated water is subjected to filter pressing to obtain filter pressing water and mineral substances; filtering the mixture of the reacted grease and coal by vacuum filtration to collect filtered grease, and coking the filtered coal in a coke oven to obtain coke; and carrying out filter pressing on the collected filtering grease to obtain coal slime and filter pressing grease, loading the coal slime and the filtered coal into a coke oven for coking, distilling the filter pressing grease to separate low-boiling-point substances, rectifying the filter pressing grease to separate medium-boiling-point substances, and returning the rectified grease of the high-boiling-point substances to the pretreatment device for recycling. The invention develops a new way for coking and processing bituminous coal, expands the coal types of coking coal and improves the shortage of coking coal resources.)

1. A coking process, which is characterized in that: mixing the waste oil and fat with crushed and screened coal in a pretreatment device through impurity removal, and separating pretreated coal and liquid through vacuum filtration after treatment; crushing and screening the pretreated coal, then feeding the crushed coal into a pre-pyrolysis device, and separating oil and fat and separated water from liquid through oil-water separation; the separated oil enters a pre-pyrolysis device to be mixed and reacted with the pretreated coal, and the separated water is subjected to filter pressing to obtain filter pressing water and mineral substances; collecting filtered grease through vacuum filtration of the mixture of the grease and the coal after reaction, and then charging the filtered coal into a coke oven for coking to obtain coke; and carrying out filter pressing on the collected filtering grease to obtain coal slime and filter pressing grease, loading the coal slime and the filtered coal into a coke oven for coking, distilling the filter pressing grease to separate low-boiling-point substances, rectifying the filter pressing grease to separate medium-boiling-point substances, and returning the rectified grease of the high-boiling-point substances to the pretreatment device for recycling.

2. The coking process according to claim 1, characterized in that: the process flow specifically comprises the steps that waste oil enters an oil storage tank after passing through a impurity removal and purification tower, and then is added into a preprocessor according to the oil-coal mass ratio of 5-10: 1; the coal is crushed by a crusher and then passes through a grading sieve, oversize materials return to the crusher to be crushed continuously, undersize materials are added from the top of a preprocessor by a lifter, are mixed with waste oil under the stirring of a stirrer, react for 0.5 to 10 hours at the temperature of between 0 and 250 ℃ in vacuum or inert atmosphere, then enter the lower part of the preprocessor through a discharge valve, and the preprocessed coal and liquid are separated by vacuum suction filtration; after the pumping filtration is finished, pushing the pretreated coal out of a discharge port along a filter screen by a coal pushing rod of a coal pusher, and feeding the pretreated coal into a crusher; standing and layering the liquid at the bottom of the preprocessor, and pumping the upper layer of grease into a grease intermediate tank from the side part and then into a pre-pyrolysis device; the separated water at the lower layer enters a filter press from the bottom for filter pressing, the mineral substances filtered by the filter press fall into a mineral storage tank, and the filter pressing water enters a filter pressing water tank; the pretreated coal in the crusher is crushed and then passes through a grading sieve, undersize materials are added from a coal charging port at the top of a preheating decomposition device by a lifter, are mixed and stirred with the grease from a grease intermediate tank under inert atmosphere, and react for 0.1-6h at the temperature of 251-; a discharge port of the pre-pyrolysis device is butted with an inlet at the top of the grease tank, a filter sieve is arranged at the top of the grease tank, and the grease and coal mixture after the reaction is separated by suction filtration; after the pumping filtration is finished, the preheating and decomposing device is moved to the top of the coke oven and is butted with a coal charging hole, and the coal is charged into the coke oven for coking; the pumped and filtered grease enters a filter press from the bottom of the grease tank for filter pressing, the filter-pressed coal mud falls into a coal mud storage tank and then is sent into a coal charging port at the top of the pre-pyrolysis device to be added into a coke oven together for coking; the filter-pressed grease enters a fractionating tower for distillation, low-boiling-point substance gas separated from the top enters a gas holder, liquid at the bottom enters a rectifying tower for rectification, medium-boiling-point substances distilled from the top of the tower enter a collecting tank, and high-boiling-point substance grease at the bottom of the tower enters a grease storage tank for recycling; the grease storage tank is connected with the top of the pre-pyrolysis device and is used for supplementing grease in the reaction.

3. The coking process according to claim 2, characterized in that: the waste oil is one or more of swill-cooked dirty oil, hogwash oil, frying oil, overdue edible oil and leftover oil in slaughter houses, and also comprises oil prepared from biological microalgae, non-grain oil crops and the like; the impurity removal and purification refers to degumming, impurity removal and deodorization treatment.

4. The coking process according to claim 2, characterized in that: the coal comprises one of lignite, bituminous coal and anthracite, and the bituminous coal comprises one of long flame coal, gas coal, fat coal, coking coal, lean coal and lean coal.

5. The coking process according to claim 2, characterized in that: the range of the pre-treatment temperature is set to be 0-250 ℃, the pre-pyrolysis temperature is 251-600 ℃, and the coking temperature is 1000-1200 ℃;

the distillation temperature of the fractionating tower is set within the range of 100-250 ℃, and the temperature of the rectifying tower is set within the range of 250-400 ℃.

6. The coking process according to claim 2, characterized in that: the atmosphere is vacuum or inert atmosphere, the vacuum degree is-0.1 MPa-0 MPa, the inert gas is one of nitrogen, helium, argon and neon, and the pressure of the inert atmosphere is 0 MPa-1 MPa.

7. A coking plant for use in accordance with any one of claims 1 to 6, characterized in that: the device comprises a impurity-removing purification tower, a grease storage tank and a preprocessor which are connected in sequence, wherein a crusher is connected with a classifying screen and a lifter in sequence, the lifter is connected with the preprocessor, the upper part of the preprocessor is a stirring kettle, a stirrer is arranged in the stirring kettle, the bottom of the stirring kettle is provided with a discharge valve, the bottom of the discharge valve is connected with a conical kettle, the upper part of the conical kettle is provided with a first filter screen, the first filter screen is arranged in an inclined manner, one side of the first filter screen is provided with a solid discharge port, the other side of the first filter screen is provided with a coal pushing rod connected with a first coal pusher; the preprocessor is heated by introducing steam or heat-conducting oil into a heating sleeve; the discharge port is connected with a crusher, the bottom of the preprocessor is connected with a filter press, the side part of the preprocessor is connected with a grease intermediate tank, the top part and the side part below the filter screen are connected with control valves, the control valves are connected with a converter, the converter is respectively connected with an inert gas bottle and a vacuum pump, the lower part of the filter press is provided with a mineral storage tank, and the side bottom of the filter press is connected with a filter; the pulverizer is connected with the classifying screen and then connected with the elevator, the elevator is connected with a coal charging port at the top of the pre-pyrolysis device, the pre-pyrolysis device is provided with a stirring and discharging port, the top of the pre-pyrolysis device is connected with a control valve, the control valve is connected with a converter, the converter is respectively connected with an inert gas bottle and a vacuum pump, and the grease intermediate tank and the grease storage tank are respectively connected with the top of the pre-pyrolysis device; the preheating and decomposing device can move, and the discharge hole of the preheating and decomposing device can be respectively butted with the inlet at the top of the grease tank and the coal charging hole of the coke oven; the lower part of the grease tank is connected with a filter press, the lower part of the filter press is provided with a coal slime storage tank and then is connected with a coal charging port at the top of the pre-pyrolysis device, the bottom of the side of the filter press is connected with a fractionating tower, the top of the fractionating tower is connected with a gas holder, the bottom of the fractionating tower is connected with a rectifying tower, the top of the rectifying tower is connected with a collection tank, and the bottom of;

the preheating and decomposing device comprises a feeding hole, an oil inlet, a stirring paddle, a heating sleeve and an air vent; the stirring paddle is horizontally arranged, and the heating sleeve is communicated with steam or hot oil.

8. The coking apparatus according to claim 7, wherein: the crusher is one of a ball mill, a rod mill, a hammer crusher and a drum crusher;

the stirrer is used for horizontal stirring or vertical stirring or stirring at an angle of 30-60 ℃;

the pretreatment device is one of a cubic type, a cylindrical type, a conical type and a kettle type; the preheating and decomposing device is of a kettle type structure.

9. The coking apparatus according to claim 7, wherein: the aperture range of the sieve plate of the first classifying sieve is 1 mm-3 mm, and the aperture range of the sieve plate of the second classifying sieve is 0.075 mm-0.5 mm.

10. The coking apparatus according to claim 7, wherein: the filter screen forms an included angle of 15-45 degrees with the horizontal line;

the aperture range of the sieve plate of the first filter sieve is 0.075 mm-1 mm, and the aperture range of the sieve plate of the second filter sieve is 0.045 mm-0.075 mm;

the included angle formed by the coal pushing rod and the sieve plate of the coal pusher is 45-85 degrees.

Technical Field

The invention relates to a coking process and a device, belonging to the field of waste oil utilization and coal processing.

Background

The returning of the illegal cooking oil to the dining table can seriously harm the health of people, and the sources of the illegal cooking oil are wide, such as frying oil, illegal cooking oil, hogwash oil, overdue oil and the like. The 'illegal cooking oil' generally refers to the grease produced and processed by non-food raw materials such as kitchen waste, meat processing waste, livestock and poultry products with unqualified inspection and quarantine, and the like. Because animal and vegetable oil can generate carcinogens such as aflatoxin, benzopyrene and the like with high toxicity after being oxidized at high temperature, the animal and vegetable oil causes great harm to the health of people. Therefore, research and development of waste oil utilization ways can benefit and guarantee healthy life of people, and the method has important social value and significance.

Coal occupies a major part in energy consumption structures in China and even the world, but if the process and the technology are imperfect, environmental pollution such as air pollution (PM 2.5), water body pollution (wastewater discharge) and the like can be caused in the utilization process of the coal. Coal is divided into three major categories of lignite, bituminous coal and anthracite according to the difference of metamorphic degrees, and the bituminous coal is subdivided into 12 subclasses. The metamorphic degree directly determines the utilization way and mode of coal, for example, anthracite with high metamorphic degree is used for preparing chemical fertilizers such as synthetic ammonia, urea and the like, bituminous coal with high metamorphic degree can be used for coking, and lignite with low metamorphic degree can be used for preparing chemicals through gasification or liquefaction, and lignite is mainly used for heating and power generation. The value or market price of coal is positively correlated with the degree of deterioration, i.e. the higher the degree of deterioration, the higher the value, so the promotion of coal upgrading processing and graded utilization become the main tasks and action targets of the national energy strategy (action plan for clean and efficient utilization of coal (2015) 2020), national energy coal [2015] 141). The novel coal utilization mode of graded and quality-divided utilization is adopted, specifically, light components such as volatile matters and impurities such as oxygen, sulfur, nitrogen, phosphorus and the like are removed from clean coal, the calorific value is improved to be cleaner, and the clean coal can replace anthracite, lean coal and be widely used in the fields of power generation, blast furnace injection, civil use, chemical industry and the like; the coal gas can be used as a raw material for hydrogen production, natural gas and chemical production, and can also be directly combusted for power generation after desulfurization and denitrification; the coal tar can be used for extracting dozens of or even hundreds of fine chemical products such as benzene, phenol, pyridine and the like, and can also be used for preparing clean liquid fuels such as diesel oil, naphtha and the like by hydrogenation. The method has important significance for realizing transformation and upgrading in the coal industry and solving the crisis of excess capacity (brief description of coal grading and quality-based utilization condition in China, search for fox network 2016-05-20). Coal pyrolysis is a leading technology for coal grading and quality-based utilization at present. According to the requirement of pyrolysis on the granularity of coal, the method can be divided into a lump coal pyrolysis technology and a pulverized coal pyrolysis technology. The pyrolysis of lump coal in China adopts a vertical furnace, the technology is mature, the pyrolysis has certain scale application in Yu Lin, inner Mongolia Uhai and other places in Shaanxi, the production capacity is nearly 5000 ten thousand tons/year, but the technology is relatively backward, the production capacity of a single set of device is lower than 10 ten thousand tons/year, the pollutant control means is not in place, and the influence on the environment is large. Meanwhile, with the popularization of large-scale mechanized coal mining in China, the specific gravity of lump coal produced by coal mines is smaller and smaller (less than 20%). Chinese invention patent CN105038827A discloses a low-rank crushed coal quality-based grading cascade utilization system and method, which couple pyrolysis gasification and combustion processes in the crushed coal thermal conversion process, and realize that high-temperature semicoke and heat carrier in a gasification reactor can be used as a pyrolysis heat source of the pyrolysis reactor and also can be used as fuel of the combustion reactor.

The coking is a high-temperature dry distillation form of coal, and mainly uses gas coal, fat coal, coking coal and lean coal for coking after coal blending to obtain coke, and due to the shortage of coking coal resources, other coal types are adopted for matching to achieve the purpose of coking. However, many low-grade coals cannot be used as coal blending for coking, and cannot be used with high value. If a new process and a new device can be used for processing coal, the coal types are expanded to achieve the coking purpose. The method is an innovative idea of coal quality improvement processing and has important significance for clean and efficient utilization of coal.

Disclosure of Invention

The invention aims to provide a coking process and a device, in particular to a process and a device for further coking coal to prepare coke after dewatering, demineralizing, desulfurizing, denitrifying and recovering organic matters of coal by using waste oil such as frying oil, illegal cooking oil, hogwash oil, overdue oil and the like as media.

The invention adopts waste oil as heat conduction and solvent medium to dehydrate, remove minerals, desulfurize and denitrify coal, dissolve and absorb soluble organic molecules, and then coke to prepare coke, namely, the coal is treated step by boiling the waste oil to obtain the coke, and low boiling point organic matter, medium boiling point organic matter, water and mineral substances are by-produced.

The invention provides a coking process, waste oil is mixed with coal after crushing and screening in a pretreatment device through impurity removal, the mixture reacts for 0.5 to 10 hours at the temperature of between 0 and 250 ℃, and after the treatment is finished, the pretreated coal and liquid are separated through vacuum filtration; crushing and screening the pretreated coal, then feeding the crushed coal into a pre-pyrolysis device, and separating oil and fat and separated water from liquid through oil-water separation; the separated oil enters a pre-pyrolysis device to be mixed with pretreated coal and react for 0.1-6h at the temperature of 251-; collecting filtered grease through vacuum filtration of the mixture of the grease and the coal after reaction, and then charging the filtered coal into a coke oven for coking to obtain coke; and carrying out filter pressing on the collected filtering grease to obtain coal slime and filter pressing grease, loading the coal slime and the filtered coal into a coke oven for coking, distilling the filter pressing grease to separate low-boiling-point substances, rectifying the filter pressing grease to separate medium-boiling-point substances, and returning the rectified grease of the high-boiling-point substances to the pretreatment device for recycling.

The process flow specifically comprises the steps that waste oil enters an oil storage tank after passing through a impurity removal and purification tower, and then is added into a preprocessor according to the oil-coal mass ratio of 5-10: 1; the coal is crushed by a crusher and then passes through a grading sieve, oversize materials return to the crusher to be crushed continuously, undersize materials are added from the top of a preprocessor by a lifter, are mixed with waste oil and fat under the stirring of a stirrer, are stirred for a certain time at a certain temperature in vacuum or inert atmosphere, then enter the lower part of the preprocessor through a discharge valve, and are subjected to vacuum filtration to separate preprocessed coal from liquid; after the pumping filtration is finished, pushing the pretreated coal out of a discharge port along a filter screen by a coal pushing rod of a coal pusher, and feeding the pretreated coal into a crusher; standing and layering the liquid at the bottom of the preprocessor, and pumping the upper layer of grease into a grease intermediate tank from the side part and then into a pre-pyrolysis device; the separated water at the lower layer enters a filter press from the bottom for filter pressing, the mineral substances filtered by the filter press fall into a mineral storage tank, and the filter pressing water enters a filter pressing water tank; the pretreated coal in the pulverizer is pulverized and then passes through a grading sieve, undersize materials are added from a coal charging port at the top of a preheating decomposition device by a lifter, are mixed and stirred with the grease from a grease intermediate tank under inert atmosphere, and react at a certain temperature for a certain time; a discharge port of the pre-pyrolysis device is butted with an inlet at the top of the grease tank, a filter sieve is arranged at the top of the grease tank, and the grease and coal mixture after the reaction is separated by suction filtration; after the pumping filtration is finished, the preheating and decomposing device is moved to the top of the coke oven and is butted with a coal charging hole, and the coal is charged into the coke oven for coking; the pumped and filtered grease enters a filter press from the bottom of the grease tank for filter pressing, the filter-pressed coal mud falls into a coal mud storage tank and then is sent into a coal charging port at the top of the pre-pyrolysis device to be added into a coke oven together for coking; the filter-pressed grease enters a fractionating tower for distillation, low-boiling-point substance gas separated from the top enters a gas holder, liquid at the bottom enters a rectifying tower for rectification, medium-boiling-point substances distilled from the top of the tower enter a collecting tank, and high-boiling-point substance grease at the bottom of the tower enters a grease storage tank for recycling; the grease storage tank is connected with the top of the pre-pyrolysis device and is used for supplementing grease in the reaction.

In the process, the waste oil is one or more of waste oil, hogwash oil, frying oil, overdue edible oil and leftover oil in slaughter houses, and also comprises oil prepared from biological microalgae, non-grain oil crops and the like.

In the above process, the impurity removal and purification refers to degumming, impurity removal and deodorization treatment.

In the process, the coal comprises one of lignite, bituminous coal and anthracite, and the bituminous coal comprises one of long flame coal, gas coal, fat coal, coking coal, lean coal and lean coal.

In the process, the pre-treatment temperature range is set to be 0-250 ℃, the pre-pyrolysis temperature is set to be 251-600 ℃, and the coking temperature is set to be 1000-1200 ℃.

In the process, the atmosphere is vacuum or inert atmosphere, the vacuum degree is-0.1 MPa-0 MPa, the inert gas is one of nitrogen, helium, argon and neon, and the pressure of the inert atmosphere is 0 MPa-1 MPa.

In the process, the distillation temperature of the fractionating tower is set to be within a range of 100-250 ℃, and the temperature of the rectifying tower is set to be within a range of 250-400 ℃.

The invention provides a coking device, which comprises a impurity-removing purification tower, a grease storage tank and a preprocessor which are connected in sequence, wherein a crusher is connected with a classifying screen and a lifter in sequence, the lifter is connected with the preprocessor, a stirrer, a discharge valve, a discharge port, a filter screen and a coal pusher are arranged in the preprocessor, the upper part of the preprocessor is a stirring kettle, the stirrer is arranged in the stirring kettle, the bottom of the stirring kettle is provided with the discharge valve, the bottom of the discharge valve is connected with a conical kettle, the upper part of the conical kettle is provided with a first filter screen, the first filter screen is arranged in an inclined manner, one side of the first filter screen is provided with a solid discharge port, the other side of the first filter screen is provided with a coal pushing rod; the preprocessor is heated by introducing steam or heat-conducting oil into a heating sleeve; the discharge port is connected with a crusher, the bottom of the preprocessor is connected with a filter press, the side part of the preprocessor is connected with a grease intermediate tank, the top part and the side part below the filter screen are connected with control valves, the control valves are connected with a converter, the converter is respectively connected with an inert gas bottle and a vacuum pump, the lower part of the filter press is provided with a mineral storage tank, and the side bottom of the filter press is connected with a filter; the pulverizer is connected with the classifying screen and then connected with the elevator, the elevator is connected with a coal charging port at the top of the pre-pyrolysis device, the pre-pyrolysis device is provided with a stirring and discharging port, the top of the pre-pyrolysis device is connected with a control valve, the control valve is connected with a converter, the converter is respectively connected with an inert gas bottle and a vacuum pump, and the grease intermediate tank and the grease storage tank are respectively connected with the top of the pre-pyrolysis device; the preheating and decomposing device can move, and the discharge hole of the preheating and decomposing device can be respectively butted with the inlet at the top of the grease tank and the coal charging hole of the coke oven; the lower part of the grease tank is connected with a filter press, the lower part of the filter press is provided with a coal slime storage tank which is then connected with a top coal charging port of the pre-pyrolysis device, the bottom of the side of the filter press is connected with a fractionating tower, the top of the fractionating tower is connected with a gas holder, the bottom of the fractionating tower is connected with a rectifying tower, the top of the rectifying tower is connected with a collection tank, and the bottom of the rectifying.

The pretreatment device is one of a cubic type, a cylindrical type, a conical type and a kettle type;

the preheating and decomposing device comprises a feeding hole, an oil inlet, a stirring paddle, a heating sleeve and an air vent; the stirring paddle is horizontally arranged, and the heating sleeve is communicated with steam or hot oil; the preheating and decomposing device is of a kettle type structure.

The converter in the invention is used for converting inert gas and vacuum, when the inert gas is needed, the converter is communicated with the inert gas bottle, and the control valve is opened, the inert gas is introduced, and similarly, when the vacuum is needed, the converter is communicated with the vacuum pump, and the vacuum state of the container is realized by opening the control valve.

In the above apparatus, the crusher means one of a ball mill, a rod mill, a hammer crusher, a drum crusher, and the like.

In the device, the aperture range of the sieve plate of the first classifying sieve is 1 mm-3 mm, and the aperture range of the sieve plate of the second classifying sieve is 0.075 mm-0.5 mm.

In the device, the stirrer is used for horizontal stirring, vertical stirring or stirring at an angle (30-60 ℃).

In the above apparatus, the filter screen is at an angle of 0 ° to 60 °, preferably 15 ° to 45 °, to the horizontal.

In the device, the aperture range of the sieve plate of the first filter sieve is 0.075 mm-1 mm, and the aperture range of the sieve plate of the second filter sieve is 0.045 mm-0.075 mm.

In the device, the angle between the coal pushing rod of the coal pusher and the sieve plate ranges from 45 degrees to 85 degrees.

The invention has the beneficial effects that:

(1) the waste oil is used as a processing medium in the bituminous coal coking process, so that the waste oil is changed into valuable and recycled, and a new way for utilizing the waste oil is developed;

(2) a way for coking and processing bituminous coal is developed, the coal types of coking coal are expanded, and the shortage condition of coking coal resources is improved;

(3) low-molecular volatile matters and soluble organic matters generated in the coal pyrolysis coking process are absorbed and re-extracted through grease, so that the method is more environment-friendly and more efficient, and the coking time is greatly shortened in the coking process.

(4) The process and the device have wide application range, are beneficial to environmental protection and are beneficial to graded utilization of coal according to quality.

Drawings

FIG. 1 is a schematic diagram of a novel coking process.

FIG. 2 is a schematic diagram of a new coking process and apparatus.

In the figure, 1-a impurity removal purification tower; 2-a grease storage tank; 3-a preprocessor; 4-a crusher; 5-a first classifying screen; 6-a first hoisting machine; 7, a stirrer; 8-a first coal pusher; 9-a first filter sieve; 10-grease intermediate tank; 11-a first filter press; 12-mineral storage tank; 13-filter pressing water tank; 14-a discharge hole; 15 — a first control valve; 16-a discharge valve; 17 — a second control valve; 18-a converter; 19-inert gas bottle; 20-a vacuum pump; 21-a pulverizer; 22-a second sizing screen; 23-a second hoist; 24-a third control valve; 25-a fourth control valve; 26-a coal charging port; 27-preheating and decomposing device; 28-a second filter sieve; 29-grease tank; 30-a second filter press; 31-a fractionation column; 32-gas holder; 33-coal slurry storage tank; 34-a coke oven; 35-a rectifying tower; 36-collection tank. A is waste oil and fat, and B is raw coal.

Detailed Description

The present invention is further illustrated by, but is not limited to, the following examples.