阅读说明：本技术 用于防除冰的复合编织电加热膜和电加热结构 (Composite braided electric heating film for preventing and removing ice and electric heating structure ) 是由 崔溢 韦家虎 王程成 马学刚 于 2019-10-25 设计创作，主要内容包括：本发明公开一种用于防除冰的复合编织电加热膜和电加热结构。其中,防除冰用复合编织电加热膜可由碳基导电纤维及金属导电纤维层内混合编织而成,以碳基导电纤维为经向纤维束、金属导电纤维为纬向纤维束或者以金属导电纤维为经向纤维束、碳基导电纤维为纬向纤维束,按照斜纹布编织或缎纹布编织的方法制得,纤维弯曲小、纤维强度损失最小,得到的电加热膜,柔性好、可铺覆在形状复杂的制件表面,不仅导电、导热性能优异,而且机械性能和电热转换效率也得到提高,更关键的是复合编织电加热膜比金属网重量轻。采用复合编织电加热膜与绝缘隔热膜可包覆、粘贴或缠绕在被加热物表面,尤其可以用于飞行器中复合材料制件的防除冰。(The invention discloses a composite braided electric heating film for preventing and removing ice and an electric heating structure. The composite woven electric heating film for preventing and removing ice is prepared by mixing and weaving carbon-based conductive fibers and metal conductive fiber layers, taking the carbon-based conductive fibers as warp-wise fiber bundles, taking the metal conductive fibers as weft-wise fiber bundles or taking the metal conductive fibers as warp-wise fiber bundles and taking the carbon-based conductive fibers as weft-wise fiber bundles according to a twill weaving or satin weaving method, has small fiber bending and minimum fiber strength loss, has good flexibility, can be laid on the surface of a part with a complex shape, has excellent electric conduction and heat conduction performance, improves the mechanical performance and the electric heating conversion efficiency, and is more critical that the composite woven electric heating film is lighter than a metal mesh. The composite braided electric heating film and the insulating and heat-insulating film can be coated, adhered or wound on the surface of a heated object, and can be particularly used for preventing and removing ice of composite material workpieces in an aircraft.)

1. A composite braided electrical heating film (10) for preventing ice detachment, comprising: carbon-based conductive fiber (1) and metal conductive fiber (2), wherein:

the carbon-based conductive fiber (1) and the metal conductive fiber (2) are woven into a sheet structure in a mixed weaving mode;

the volume proportion of the carbon-based conductive fiber (1) in the sheet structure is more than or equal to 25% and less than or equal to 75%;

the volume proportion of the metal conductive fiber (2) in the fiber mixture is more than or equal to 25% and less than or equal to 75%;

the diameter of the metal conductive fiber (2) is more than or equal to 0.5 μm and less than or equal to 100 μm.

2. The composite braided electric heating film for deicing according to claim 1, wherein:

the carbon-based conductive fiber (1) is a warp fiber bundle or a weft fiber bundle of a sheet structure;

the metal conductive fiber (2) is a weft fiber bundle or a warp fiber bundle of a sheet structure;

the warp fiber bundles and the weft fiber bundles are prepared into the sheet structure by adopting a twill cloth weaving method or a satin cloth weaving method.

3. The composite braided electric heating film for deicing according to claim 1, wherein:

the carbon-based conductive fiber (1) includes one or more of the following fibers:

pitch-based carbon fibers, polyacrylonitrile carbon fibers, carbon nanofibers, graphene fibers, carbon nanotube fibers, graphite fibers;

the metal conductive fibers (2) comprise one or more of the following fibers:

copper fiber, aluminum fiber, nickel fiber, stainless steel fiber, iron fiber, silver fiber, and gold fiber.

4. The composite braided electric heating film for deicing as set forth in any one of claims 1 to 3, wherein:

the carbon-based conductive fiber (1) is an asphalt-based carbon fiber with the model number of 6K;

the metal conductive fiber (2) is a copper fiber with the diameter of 20 mu m;

the volume ratio of the pitch-based carbon fiber to the copper fiber is 50 percent;

alternatively, the first and second electrodes may be,

the carbon-based conductive fiber (1) is an asphalt-based carbon fiber with the model number of 3K;

the metal conductive fiber (2) is a copper fiber with the diameter of 5 mu m;

the pitch-based carbon fiber accounts for 25% of the volume ratio, and the stainless steel fiber accounts for 75% of the volume ratio.

Alternatively, the first and second electrodes may be,

the carbon-based conductive fiber (1) is an asphalt-based carbon fiber with the model number of 12K;

the metal conductive fiber (2) is a copper fiber with the diameter of 100 mu m;

the pitch-based carbon fiber accounts for 70% of the volume ratio, and the stainless steel fiber accounts for 30% of the volume ratio.

5. An electric heating structure for deicing comprising:

the composite braided electric heating film (10), the insulating and heat insulating film (20), the insulating and heat conducting film (30), and the electrode (40) according to any one of claims 1 to 4, wherein:

the composite braided electric heating film (10) is arranged between the insulating heat-insulating film (20) and the insulating heat-conducting film (30) and is bonded into a whole through hot-pressing curing;

electrodes (40) are arranged on two sides of the composite braided electric heating film (10);

the 2 electrodes (40) are connected with external wires and a power supply.

6. The electric heating structure for deicing according to claim 5, wherein:

the insulating and heat insulating film (20) is made of heat-resistant resin material,

the thickness of the insulating and heat-insulating film (20) is 0.01mm or more and 0.50mm or less.

7. The electric heating structure for deicing according to claim 5, wherein:

the insulating heat-conducting film (20) is made of heat-resistant resin filled with high-heat-conductivity ceramic particles;

the thickness of the insulating heat-conducting film (20) is more than or equal to 0.01mm and less than or equal to 0.50 mm.

8. The electric heating structure for deicing according to claim 7, wherein:

the volume content of the high-heat-conductivity ceramic particles is more than or equal to 1 vol% and less than or equal to 60 vol%;

the grain diameter of the high heat conduction ceramic grain is more than or equal to 0.1 μm and less than or equal to 100 μm.

The high thermal conductivity ceramic particles include one or more of the following particles:

AlN, Al2O3, SiC, SiO2, Si3N4, BN, diamond powder.

9. The electric heating structure for deicing according to claim 7, wherein:

the insulating and heat insulating film (20) comprises one or more of the following materials:

heat-resistant rubber, polyimide, aramid fiber, polyester, polyethylene, polypropylene.

10. The electric heating structure for deicing as set forth in claims 5 to 9, wherein:

the thickness of the electrode (40) is 0.005mm or more and 0.2mm or less.

Technical Field

The invention relates to the technical field of aviation deicing, in particular to a composite braided electric heating film for deicing, an electric heating structure containing the composite braided electric heating film and application of the electric heating structure in deicing.

Background

When an airplane flies under icing meteorological conditions, supercooled water drops (water drops with the temperature lower than 0 ℃ and existing in a liquid state) in a cloud layer impact the surface, and an icing phenomenon can occur. Among them, icing phenomena are severe on the surfaces of transparent parts such as wings, horizontal stabilizers, vertical stabilizer leading edges, engine inlet lips, air inlet parts (guide vanes, supports, etc.), propeller blades, cowlings, windshields, and covers, and the surfaces of atmospheric data detection devices such as pitot tubes, attack angles, and temperature sensors. The ice accumulation on the surface of the airplane can cause a large number of aerodynamic problems, which are represented by the reduction of lift-drag ratio, the increase of flight oil consumption, the interference of static pressure system instrument indication and the serious influence on the stability and maneuverability of the airplane, and is an important risk factor threatening the service safety of aviation equipment.

The applicant finds out through research that:

at present, the airplane deicing and anti-icing technology is mainly divided into a passive deicing and anti-icing technology and an active deicing and anti-icing technology. The passive anti-icing technology includes a coating anti-icing technology in which a hydrophobic coating and a heat absorbing coating are coated on the surface, and a solution anti-icing technology using an anti-icing fluid. However, with the prolonging of the service time, the performance of the coating is obviously degraded, the duration of the deicing effect is not long, the coating needs to be re-coated regularly, and the micro-rough structure of the hydrophobic coating is easily damaged by external force to lose the super-hydrophobic property.

Compared with the passive deicing prevention technology, the active deicing prevention technology has high deicing efficiency, but has certain disadvantages. For example: the mixed hot gas ice preventing and removing system guides hot gas generated in the engine to the inner side of the surface of the wing through a series of pipelines, but the design is complicated, the non-effective load of the airplane is increased, and the effective thrust of the engine is reduced; the traditional air bag deicing and preventing system expands and contracts an air bag through the inflation and deflation of the air bag to generate mechanical force and mechanical vibration for deicing, but the method has high requirements on the corrosivity and the service life of materials, and has large influence on the aerodynamics of an airplane during the inflation and the inflation; the electric pulse deicing preventing system generates mechanical force with high amplitude and extremely short duration on the skin of the airplane to break and shed ice, although the deicing efficiency is high, the system enables the weight of the structure of an airplane body to be seriously increased, the deicing effect depends on the deformation size of the skin and the frequency of the pulse force, and the deicing effect on the front edge is not ideal.

The electric heating deicing technology is the mainstream deicing technology of the airplane at present, and the metal net is laid at the position needing deicing, and when the temperature is lower than a limit, the metal net is electrified to generate heat, so that the deicing is realized. The method has extremely high technical maturity, the anti-icing and deicing systems of the domestic aircrafts in active service abroad basically adopt an electric heating mode, but the problems of obvious weight gain (for example, the S-76 helicopter only increases the deicing system by 68-113kg), low electric-heat conversion efficiency and the like generally exist.

Disclosure of Invention

In view of the above, in order to solve at least one technical problem in the prior art, the present invention provides a composite braided electric heating film for deicing. The composite woven electric heating film is formed by weaving carbon-based conductive fibers and metal conductive fiber layers in a mixed mode, the carbon-based conductive fibers are used as warp-wise fiber bundles, the metal conductive fibers are used as weft-wise fiber bundles, or the metal conductive fibers are used as warp-wise fiber bundles, the carbon-based conductive fibers are used as weft-wise fiber bundles, the warp-wise and weft-wise composite woven electric heating film is prepared according to a twill weaving or satin weaving method, the proportion of the carbon-based conductive fibers is not lower than 25%, and the proportion of the metal conductive fibers is not lower than 25%. Wherein, the carbon-based conductive fiber can be pitch-based carbon fiber, polyacrylonitrile carbon fiber, carbon nanofiber, graphene fiber, carbon nanotube fiber and graphite fiber; the metal conductive fiber can be copper fiber, aluminum fiber, nickel fiber, stainless steel fiber, iron fiber, silver fiber, and gold fiber, and the diameter of the metal fiber is 0.5-100 μm. The volume proportion of the carbon-based conductive fiber is not less than 25%, and the volume proportion of the metal conductive fiber is not less than 25%.

The invention also provides an electric heating structure for preventing and removing ice, which consists of an insulating heat-insulating film, a composite braided electric heating film, an insulating heat-conducting film, an electrode and a lead. The composite braided electric heating film is arranged between the insulating heat insulation film and the insulating heat conduction film, is bonded into a whole through hot-pressing curing, and is connected with a power supply through an electrode and a lead to realize electric heating. Wherein the insulating and heat insulating film is prepared from one or more of heat-resistant resin materials such as heat-resistant rubber, polyimide, aramid fiber, polyester, polyethylene, polypropylene and the like, and the thickness of the insulating and heat insulating film is 0.01-0.50 mm; the insulating and heat-insulating film has the function of reducing the heat damage of the composite material substrate caused by electric heating.

The insulating heat-conducting film is made of heat-resistant resin (one or more of polyimide, aramid fiber, polyester, polyethylene and polypropylene) filled with high-heat-conductivity ceramic particles (one or more of AlN, Al2O3, SiC, SiO2, Si3N4, BN and diamond powder), the thickness of the insulating heat-conducting film is 0.01-0.50mm, the content of the high-heat-conductivity ceramic particles is 1-60 vol%, the particle size of the high-heat-conductivity ceramic particles is 0.1-100 mu m, and the heat conductivity coefficient of the insulating heat-conducting layer can be improved by adding the high-heat-conductivity ceramic particles; the insulating heat conduction membrane can conduct the heat of the composite woven electric heating membrane to the ice layer more quickly and efficiently, and deicing efficiency and anti-icing effect are improved.

Preparing electrodes on two sides of the composite woven electric heating film, wherein the thickness of the electrodes is 0.005-0.2mm, and the electrodes can be prepared by bonding, spraying, electro-deposition, 3D printing and other modes of metals or alloys such as silver, copper, gold, aluminum, nickel and the like; the electrodes may be connected to a power source via wires.

The electric heating structure for preventing and removing ice can be coated, adhered or wound on the surface of a heated object, and particularly can be used for preventing and removing ice of a composite material workpiece; the composite material part may be a helicopter blade, a leading edge of a wing, a leading edge of a vertical tail.

The invention has the following beneficial effects:

the composite woven electric heating film is formed by combining light and heat-conducting carbon-based fibers with conductive and flexible metal fibers, has complementary advantages, is formed by weaving the carbon-based conductive fibers and the metal conductive fiber layers in a mixed mode through a twill or satin weaving method, is small in fiber bending and minimum in fiber strength loss, is good in flexibility, can be laid on the surface of a part with a complex shape, is excellent in electric conduction and heat conduction performance, and is improved in mechanical performance and electric heating conversion efficiency, and more importantly, the composite woven electric heating film is lighter than a metal net. The composite braided electric heating film is arranged between the insulating heat-insulating film and the insulating heat-conducting film, the three films are bonded into a whole after hot-pressing curing, the electric heating is realized by connecting the electrodes and the leads with a power supply, and the composite braided electric heating film can be coated, adhered or wound on the surface of an object to be heated, and particularly can be used for preventing and removing ice of a composite material workpiece.

Drawings

In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings needed to be used in the embodiments of the present invention will be briefly described below, and it is obvious that the drawings described below are only some embodiments of the present invention, and it is obvious for those skilled in the art to obtain other drawings based on these drawings without creative efforts.

FIG. 1 is a schematic view of a composite woven electric heating membrane prepared by a twill weaving method according to an embodiment of the present invention;

fig. 2 is a schematic view of a composite woven electric heating film manufactured by a satin weaving method according to an embodiment of the present invention;

fig. 3 is a schematic view of an electric heating structure for deicing according to an embodiment of the present invention.

Detailed Description

In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention. It is to be understood that the embodiments described are only a few embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

Features and illustrative embodiments of various aspects of the invention are described in detail below. In the following detailed description, numerous specific details are set forth in order to provide a thorough understanding of the present invention. It will be apparent, however, to one skilled in the art that the present invention may be practiced without some of these specific details. The following description of the embodiments is merely intended to provide a better understanding of the present invention by illustrating examples of the present invention. The present invention is in no way limited to any specific arrangement and method set forth below, but rather covers any improvements, substitutions and modifications in structure, method, and apparatus without departing from the spirit of the invention. In the drawings and the following description, well-known structures and techniques are not shown to avoid unnecessarily obscuring the present invention.

It should be noted that, in the case of conflict, the embodiments and features of the embodiments of the present invention may be combined with each other, and the respective embodiments may be mutually referred to and cited. The present invention will be described in detail below with reference to the embodiments with reference to the attached drawings.

Carbon-based materials are light in weight and excellent in thermal conductivity, and theoretically, carbon-based materials all have high thermal conductivity values, for example, the thermal conductivity of graphene is 5000W/(mK), the thermal conductivity of natural graphite is 2000W/(mK), the thermal conductivity of carbon nanotubes is 3500W/(mK), and the thermal conductivity of carbon fibers is 1000W/(mK). However, carbon-based fibers are poor in flexibility and easy to break, and are generally used as a reinforcing material in combination with a resin. The light and heat-conducting carbon-based fiber and the conductive and flexible metal fiber are combined, the advantages are complementary, the electric heating film with good electric conductivity, heat-conducting property, mechanical property and electric-heat conversion efficiency is prepared, and the electric heating film has a good application prospect in the field of deicing of airplanes.

Fig. 1 is a schematic view of a composite woven electric heating film manufactured by a twill weaving method according to an embodiment of the present invention.

Referring to fig. 1, a composite braided electrical heating film 10 for preventing ice may include: carbon-based conductive fibers 1 and metal conductive fibers 2. Wherein: the carbon-based conductive fiber 1 and the metal conductive fiber 2 are woven into a sheet structure in a mixed weaving mode; the volume proportion of the carbon-based conductive fiber 1 in the sheet structure is more than or equal to 25% and less than or equal to 75%; the volume proportion of the metal conductive fiber 2 in the fiber mixture is more than or equal to 25% and less than or equal to 75%; the diameter of the metal conductive fiber 2 is not less than 0.5 μm and not more than 100 μm.

In some embodiments, the carbon-based conductive fiber 1 is a warp fiber bundle or a weft fiber bundle of a sheet structure; the metal conductive fiber 2 is a weft fiber bundle or a warp fiber bundle of a sheet structure; the warp fiber bundles and the weft fiber bundles are prepared into the sheet structure by adopting a twill cloth weaving method or a satin cloth weaving method.

In some embodiments, the carbon-based conductive fiber 1 includes one or more of the following fibers: pitch-based carbon fibers, polyacrylonitrile carbon fibers, carbon nanofibers, graphene fibers, carbon nanotube fibers, graphite fibers;

in some embodiments, the metal conductive fibers 2 include one or more of the following fibers: copper fiber, aluminum fiber, nickel fiber, stainless steel fiber, iron fiber, silver fiber, and gold fiber.

In some embodiments, carbon-based conductive fiber 1 is a 6K pitch-based carbon fiber; the metal conductive fibers 2 are copper fibers having a diameter of 20 μm; the volume ratio of the pitch-based carbon fiber to the copper fiber is 50 percent;

in some embodiments, carbon-based conductive fiber 1 is a pitch-based carbon fiber with a type number of 3K; the metal conductive fibers 2 are copper fibers having a diameter of 5 μm; the pitch-based carbon fiber accounts for 25% of the volume ratio, and the stainless steel fiber accounts for 75% of the volume ratio.

In some embodiments, carbon-based conductive fiber 1 is a pitch-based carbon fiber with a model number of 12K; the metal conductive fibers 2 are copper fibers having a diameter of 100 μm; the pitch-based carbon fiber accounts for 70% of the volume ratio, and the stainless steel fiber accounts for 30% of the volume ratio.

In some embodiments, a composite braided electric heating film for deicing selects 6K pitch-based carbon fibers as carbon-based conductive fibers, and copper fibers with the diameter of 20 μm as metal conductive fibers; the pitch-based carbon fibers are used as warp-wise fiber bundles, the copper fibers are used as weft-wise fiber bundles, and the pitch-based carbon fibers and the copper fibers are prepared according to the weaving method of the twill shown in the attached drawing 1 in the warp direction and the weft direction; wherein the volume of the pitch-based carbon fiber and the volume of the copper fiber respectively account for 50 percent.

Fig. 2 is a schematic view of a composite woven electric heating film manufactured by a satin weaving method according to an embodiment of the present invention.

Referring to fig. 2, a composite braided electric heating film for deicing selects 3K graphite fiber as carbon-based conductive fiber and stainless steel fiber with a diameter of 5 μm as metal conductive fiber; the pitch-based carbon fibers are used as warp-wise fiber bundles, the stainless steel fibers are used as weft-wise fiber bundles, and the warp-wise fiber bundles and the weft-wise fiber bundles are prepared according to a satin weaving method shown in the attached drawing 2; wherein, the asphalt-based carbon fiber accounts for 25 percent, and the stainless steel fiber accounts for 75 percent.

In some embodiments, the composite braided electric heating film for deicing selects 12K polyacrylonitrile-based carbon fiber as carbon-based conductive fiber, and aluminum fiber with the diameter of 100 μm as metal conductive fiber; the aluminum fiber is used as a warp fiber bundle, the polyacrylonitrile-based carbon fiber is used as a weft fiber bundle, and the warp and weft fibers are prepared according to a weaving method of twill cloth; wherein, the aluminum fiber accounts for 30 percent, and the pitch-based carbon fiber accounts for 70 percent.

In some embodiments, an electric heating structure for deicing containing a composite braided electric heating film is composed of an insulating heat-insulating film, a composite braided electric heating film, an insulating heat-conducting film, electrodes and wires; the electrodes are made of copper foil with the thickness of 0.02mm, the electrodes are adhered to two ends of the composite woven electric heating film through conductive adhesive, and wires are reserved; aramid cloth with the thickness of 0.5mm is selected as an insulating and heat-insulating film; the insulating heat-conducting film is prepared by filling AlN powder with the grain diameter D50 of 20 mu m serving as high heat-conducting ceramic particles into polyimide resin, wherein the content of the AlN powder is 20 vol%, and the thickness of the prepared insulating heat-conducting film is 0.1 mm; and placing the composite braided electric heating film between the insulating heat-insulating film and the insulating heat-conducting film, and bonding the three films into a whole after hot-pressing curing to obtain the electric heating structure for preventing and removing ice.

In some embodiments, an electric heating structure for deicing containing a composite braided electric heating film is composed of an insulating heat-insulating film, a composite braided electric heating film, an insulating heat-conducting film, electrodes and wires; the electrode is made by spraying conductive films with the thickness of 0.03mm on the two ends of the composite braided electric heating film, and a lead is reserved; selecting a polyimide film with the thickness of 0.1mm as an insulating and heat-insulating film; the insulating heat-conducting film is prepared by filling SiC powder with the grain diameter D50 of 30 mu m serving as high heat-conducting ceramic particles into polyimide resin, wherein the content of the SiC powder is 50 vol%, and the thickness of the prepared insulating heat-conducting film is 0.3 mm; and placing the composite braided electric heating film between the insulating heat-insulating film and the insulating heat-conducting film, and bonding the three films into a whole after hot-pressing curing to obtain the electric heating structure for preventing and removing ice.

In some embodiments, an electric heating structure for deicing containing a composite braided electric heating film is composed of an insulating heat-insulating film, a composite braided electric heating film, an insulating heat-conducting film, electrodes and wires; the electrodes are nickel electrodes with the thickness of 0.1mm prepared at two ends of the composite braided electric heating film by a 3D printing method, and wires are reserved; selecting a polypropylene film with the thickness of 0.2mm as an insulating and heat-insulating film; the insulating heat-conducting film is prepared by mixing BN powder with the particle size D50 of 10 mu m serving as high heat-conducting ceramic particles with polyester, wherein the content of the BN powder is 30 vol%, and the thickness of the prepared insulating heat-conducting film is 0.2 mm; and placing the composite braided electric heating film between the insulating heat-insulating film and the insulating heat-conducting film, and bonding the three films into a whole after hot-pressing curing to obtain the electric heating structure for preventing and removing ice.

In some embodiments, the electric heating structure is applied to ice prevention, one side of an insulating and heat-insulating film of the electric heating structure is pasted on the surface of a helicopter propeller blade, the surface of a leading edge of an airplane wing or the surface of a leading edge of a vertical tail wing of the airplane by an adhesive film, and the ice layer attached to the surface of the electric heating structure can be melted by heating after the electric heating structure is electrified.

Fig. 3 is a schematic view of an electric heating structure for deicing according to an embodiment of the present invention.

Referring to fig. 3, an electric heating structure for deicing may include: the composite braided electric heating film 10, the insulating and heat insulating film 20, the insulating and heat conducting film 30 and the electrode 40. Wherein: the composite braided electric heating film 10 is arranged between the insulating heat-insulating film 20 and the insulating heat-conducting film 30 and is bonded into a whole through hot-pressing curing; electrodes 40 are arranged on two sides of the composite braided electric heating film 10; the 2 electrodes 40 are used for connection to external wires and power.

In some embodiments, the insulating and heat insulating film 20 is a heat-resistant resin material, and the insulating and heat insulating film 20 has a thickness of 0.01mm or more and 0.50mm or less.

In some embodiments, the insulating heat-conductive film 20 is made of a heat-resistant resin filled with high-heat-conductive ceramic particles; the thickness of the insulating heat-conducting film 20 is not less than 0.01mm and not more than 0.50 mm.

In some embodiments, the volume content of the high thermal conductive ceramic particles is 1 vol% or more and 60 vol% or less; the grain diameter of the high heat conduction ceramic grain is more than or equal to 0.1 μm and less than or equal to 100 μm.

In some embodiments, the high thermal conductivity ceramic particles include one or more of the following: AlN, Al2O3, SiC, SiO2, Si3N4, BN, diamond powder.

In some embodiments, the insulating and thermally insulating film 20 includes one or more of the following materials: heat-resistant rubber, polyimide, aramid fiber, polyester, polyethylene, polypropylene.

In some embodiments, the thickness of the electrode 40 is 0.005mm or more and 0.2mm or less.

In some embodiments, a composite braided electric heating film for deicing can be formed by mixing and braiding carbon-based conductive fibers and metal conductive fiber layers, wherein the volume proportion of the carbon-based conductive fibers is not less than 25%, the volume proportion of the metal conductive fibers is not less than 25%, and the diameter of the metal fibers is 0.5-100 μm. Numerical ranges herein include the endpoints.

In some embodiments, the composite woven electric heating film for deicing can be prepared by taking carbon-based conductive fibers as warp fiber bundles and metal conductive fibers as weft fiber bundles by adopting a twill weaving method or a satin weaving method.

In some embodiments, the composite woven electric heating film for deicing can be prepared by using a twill weaving method or a satin weaving method with the warp fiber bundles of the metal conductive fibers and the weft fiber bundles of the carbon-based conductive fibers.

In some embodiments, the composite braided ice control electric heating film may be a carbon-based conductive fiber that is at least one of pitch-based carbon fiber, polyacrylonitrile carbon fiber, carbon nanofiber, graphene fiber, carbon nanotube fiber, and graphite fiber; the metal conductive fiber may be at least one of copper fiber, aluminum fiber, nickel fiber, stainless steel fiber, iron fiber, silver fiber, and gold fiber.

In some embodiments, the composite braided electric heating film for deicing can select 6K asphalt-based carbon fibers as carbon-based conductive fibers, and copper fibers with the diameter of 20 μm as metal conductive fibers; the pitch-based carbon fibers and the copper fibers each account for 50%.

In some embodiments, the composite braided electric heating film for deicing can select 3K graphite fiber as carbon-based conductive fiber, and stainless steel fiber with the diameter of 5 μm as metal conductive fiber; the asphalt-based carbon fiber accounts for 25 percent, and the stainless steel fiber accounts for 75 percent.

In some embodiments, the composite braided electric heating film for deicing can select 12K polyacrylonitrile-based carbon fibers as carbon-based conductive fibers and aluminum fibers with the diameter of 100 microns as metal conductive fibers; 30% of aluminum fiber and 70% of asphalt-based carbon fiber.

In some embodiments, the electric heating structure for deicing of the composite woven electric heating film may be composed of an insulating heat-insulating film, a composite woven electric heating film, an insulating heat-conducting film, electrodes, and wires, the composite woven electric heating film is disposed between the insulating heat-insulating film and the insulating heat-conducting film, and is bonded into a whole by hot-pressing and curing, and both sides of the composite woven electric heating film are connected to a power supply through the electrodes and the wires.

In some embodiments, the electric heating structure for deicing may be an insulating and heat insulating film made of one or more heat-resistant resin materials such as heat-resistant rubber, polyimide, aramid, polyester, polyethylene, polypropylene, etc., and has a thickness of 0.01-0.50 mm.

In some embodiments, the electric heating structure for deicing may be such that the insulating heat conductive film is made of a heat-resistant resin filled with high thermal conductive ceramic particles, and has a thickness of 0.01 to 0.50mm, a content of the high thermal conductive ceramic particles is 1 to 60 vol%, and a particle size of the high thermal conductive ceramic particles is 0.1 to 100 μm.

In some embodiments, the electric heating structure for deicing may be one or more of high thermal conductive ceramic particles of AlN, Al2O3, SiC, SiO2, Si3N4, BN, diamond dust.

In some embodiments, the electric heating structure for deicing may be one or more of polyimide, aramid, polyester, polyethylene and polypropylene as the heat-resistant resin.

In some embodiments, the thickness of the electrode in the electric heating structure for deicing is 0.005-0.2mm, and the electrode can be prepared by bonding, spraying, electrodeposition, 3D printing and the like of metals or alloys such as silver, copper, gold, aluminum, nickel and the like.

In some embodiments, the electric heating structure may be widely applied in aviation ice and ice prevention, and the electric heating structure may be coated, adhered or wound on the surface of the heated object, which may be a composite material object.

In some embodiments, the electrically heated structure may be a composite article that may be a helicopter blade, an aircraft wing leading edge, an aircraft vertical tail leading edge.

It should be noted that the above technical features may be combined and applied in different degrees, and for simplicity, implementation manners of various combinations are not described again, and a person skilled in the art may flexibly adjust the sequence of the above operation steps according to actual needs, or flexibly combine the above steps, and the like.

The above embodiments are only for illustrating the technical solutions of the present invention, but the scope of protection is not limited thereto, and any person skilled in the art can easily think of various equivalent modifications or substitutions within the technical scope of the present invention, and these modifications or substitutions should be covered within the scope of protection of the present invention.