阅读说明：本技术 发酵生物质烃酿造重烃生产轻质柴油的方法 (Method for producing light diesel oil by fermenting biomass hydrocarbon to brew heavy hydrocarbon ) 是由 刘宏伟 姜国文 王丽华 姜钧奇 周诗博 李晓峰 于 2019-11-12 设计创作，主要内容包括：本发明属草禾烃与重烃混合酿造工艺领域,尤其涉及一种发酵生物质烃酿造重烃生产轻质柴油的方法,包括如下步骤：(1)将生物质加工粉碎研磨成120～188目；(2)加入生物肽重烃解离酶及石墨肽；(3)向步骤(2)中加入化合游离转因子助剂四氢呋喃锶叮及六氢喹啉钠；(4)将以上备好的原料,加入135～178目,重量百分含量为1～7%的辅助物料生物质；在温度26～75℃进行发酵,时间35～65h,得到草禾烃；(5)将草禾烃与重烃类物质混合,加热至罐中热量达到1.8万大卡,出口温度达到89～298℃时,生产出轻质燃料烃C<Sub>8</Sub>-C<Sub>24</Sub>。本发明低能耗,低成本,低危险,环保效能显著。(The invention belongs to the field of a mixed brewing process of grass hydrocarbon and heavy hydrocarbon, and particularly relates to a method for producing light diesel oil by fermenting biomass hydrocarbon to brew heavy hydrocarbon, which comprises the following steps: (1) processing, crushing and grinding biomass into 120-188 meshes; (2) adding biological peptide heavy hydrocarbon resolvase and graphite peptide; (3) adding a compound free transfer factor auxiliary agent of strontium tetrahydrofuran and sodium hexahydroquinoline into the step (2); (4) adding the prepared raw materials into an auxiliary material biomass of 135-178 meshes and 1-7 wt%; fermenting at the temperature of 26-75 ℃ for 35-65 h to obtain the grass hydrocarbon; (5) mixing the grass-grain hydrocarbon and the heavy hydrocarbon substances, heating until the heat in the tank reaches 1.8 ten thousand calories, and when the outlet temperature reaches 89-298 ℃, producing the light fuel hydrocarbon C 8 ‑C 24 . The invention has the advantages of low energy consumption, low cost, low danger and obvious environmental protection efficiency.)

1. The method for producing the light diesel by fermenting the biomass hydrocarbon to brew the heavy hydrocarbon is characterized by comprising the following steps of:

(1) processing, crushing and grinding biomass into 120-188 meshes;

(2) adding a biological peptide heavy hydrocarbon resolvase and graphite peptide into the product obtained in the step (1); the weight ratio of the biomass to the biologic peptide heavy hydrocarbon resolvase is 75-97: 7-18; the graphite peptide comprises the following components in percentage by weight: 1-5%;

(3) adding a compound free transfer factor auxiliary agent of strontium tetrahydrofuran and sodium hexahydroquinoline into the step (2); the weight ratio of the free transfer factor assistant tetrahydrofuran strontium bite and sodium hexahydroquinoline to the biomass is 0.02-0.06: 97-110; the weight ratio of the tetrahydrofuran strontium bite to the hexahydroquinoline sodium is 1-5: 3;

(4) adding the prepared raw materials into an auxiliary material biomass of 135-178 meshes and 1-7 wt%; fermenting at the temperature of 26-75 ℃ for 35-65 h to obtain the grass hydrocarbon;

(5) mixing the grass-grain hydrocarbon and the heavy hydrocarbon substances, heating until the heat in the tank reaches 1.8 ten thousand calories, and when the outlet temperature reaches 89-298 ℃, producing the light fuel hydrocarbon C₈-C₂₄(ii) a Weight ratio of grass hydrocarbon to heavy hydrocarbon: 18-94: 17-86.

2. The method for producing light diesel oil by fermenting biomass hydrocarbon to brew heavy hydrocarbon according to claim 1, characterized in that: the graphite peptide is similar to petroleum peptide PCR-petroleum enzyme.

3. The method for producing light diesel oil by fermenting biomass hydrocarbon to brew heavy hydrocarbon according to claim 2, characterized in that: the biomass is crop straws, plant branches and leaves or hay; the heavy hydrocarbon substances are heavy residual oil deposit, coal tar, waste asphalt, heavy oil, clean oil of chemical plants, waste rubber, old tires, waste engineering plastics or coal.

Technical Field

The invention belongs to the field of a mixed brewing process of grass hydrocarbon and heavy hydrocarbon, and particularly relates to a method for producing light diesel oil by fermenting biomass hydrocarbon to brew heavy hydrocarbon.

Background

China faces multiple dilemmas in energy development. First, energy consumption is growing rapidly and energy supply is growing correspondingly, but energy supply increases continue to rely primarily on coal and imported petroleum. Secondly, although China sets out policies and targets for energy conservation and emission reduction, the effects of energy conservation and emission reduction are challenged by the acceleration of GDP. Thirdly, the energy structure adjustment progresses slowly, and the high coal ratio is still a real problem. Due to the factors, the price of energy in China is continuously increased, the pressure of energy environment is continuously increased, and the energy safety faces multiple challenges.

The "congenital deficiency" of energy structure in our country is also the natural endowment we often say. Since this century, the total energy consumption of our country has rapidly increased, mainly depending on coal, petroleum and natural gas. At present, China becomes one of the largest energy consuming countries in the world, but the energy production capacity in China does not rise as fast as the consumption capacity in China, wherein the petroleum consumption growth speed is obviously higher than the domestic yield increase. Second only to the united states, china is the second largest petroleum consumer world country. Production of natural gas and non-fossil energy (hydroelectric, nuclear and wind) has increased rapidly in recent years, but the total is still limited. The energy and related infrastructure investments are enormous. At present, the oil refining process is a production process with high energy consumption, high cost and high danger. Part of oil field and industrial waste remains a considerable part of deposited heavy hydrocarbon resources. How to utilize the renewable materials is significant for solving the problems of energy shortage and environmental pollution. The foreign developed biofuel oil uses soybean and rapeseed as raw materials, needs to be planted in large quantities, occupies land, and has limited resource amount, thus resulting in high cost, high oil price and great popularization difficulty.

Disclosure of Invention

The invention aims to overcome the defects of the prior art and provides the preparation method of the fermented biomass hydrocarbonized diesel oil, which has low energy consumption, low cost, low danger and remarkable environmental protection efficiency.

To solve the above-described problems, the present invention is thus achieved.

The method for producing the light diesel by fermenting the biomass hydrocarbon to brew the heavy hydrocarbon is characterized by comprising the following steps of:

(1) processing, crushing and grinding biomass into 120-188 meshes;

(2) adding a biological peptide heavy hydrocarbon resolvase and graphite peptide into the product obtained in the step (1); the weight ratio of the biomass to the biologic peptide heavy hydrocarbon resolvase is 75-97: 7-18; the graphite peptide comprises the following components in percentage by weight: 1-5%;

(3) adding a compound free transfer factor auxiliary agent of strontium tetrahydrofuran and sodium hexahydroquinoline into the step (2); the weight ratio of the free transfer factor assistant tetrahydrofuran strontium bite and sodium hexahydroquinoline to the biomass is 0.02-0.06: 97-110; the weight ratio of the tetrahydrofuran strontium bite to the hexahydroquinoline sodium is 1-5: 3; tetrahydrofuran strontium bite is used as metal activator, and potassium calcium element is suitable. In Japan, where tetrahydrofuran strontium is produced, the marine organism "pancreas of electric eel" is contained as a bioenergy factor, also called as the n-side of RNA, and has strong activation to the enzyme, which is in direct proportion to the activity of the enzyme.

(4) Adding the prepared raw materials into an auxiliary material biomass of 135-178 meshes and 1-7 wt%; fermenting at the temperature of 26-75 ℃ for 35-65 h to obtain the grass hydrocarbon;

(5) mixing the grass-grain hydrocarbon and the heavy hydrocarbon substances, heating until the heat in the tank reaches 1.8 ten thousand calories, and when the outlet temperature reaches 89-298 ℃, producing the light fuel hydrocarbon C₈-C₂₄(ii) a Weight ratio of grass hydrocarbon to heavy hydrocarbon: 18-94: 17-86.

As a preferred scheme, the graphite peptide is similar to petroleum peptide PCR-petroleum enzyme. See CN 00110698-petroleum peptide PCR-petroleum enzyme, coenzyme and its special activator.

Furthermore, the biomass is crop straws, plant branches and leaves or hay; the heavy hydrocarbon substances are heavy residual oil deposit, coal tar, waste asphalt, heavy oil, clean oil of chemical plants, waste rubber, old tires, waste engineering plastics or coal.

The organic supplementary material biological peptide heavy hydrocarbon resolvase is one kind of petroleum peptide (enzyme) extracted from extreme microbe industrial bacteria extracted from petroleum and constituted by active 'DNA' amino acid factor. The matter has one end of lipophilic molecular structure, under the condition of sublimation heat, the other end of hydrophilic group must be ensured to dissolve biological petroleum enzyme and obtain positive input, and make it be transferred into heavy hydrocarbon heterocyclic structure, and continuously act on C-C bond position in hydrocarbon chain according to original sublimation process temperature to make it be cracked, and self still is fixed in the complex petroleum enzyme marshalling on the peptide chain, and its quality standard is stability of synthesis in production. The heavy hydrocarbon dissociation enzyme of biological peptide used in the invention is prepared by mixing the armillaria lanuginosa petroleum enzyme produced by Liaoning Shangjingtangtaiwang petroleum auxiliary factory with the super-heavy crude oil and the heavy oil in any proportion at normal temperature and normal pressure, and after heating to 140 ℃, the chain breaking recombination of the macromolecular structures of the super-heavy crude oil and the heavy oil is carried out to form a small molecular structure, thus being capable of achieving the refining standard of oil products. The kinetic energy generated by the activity of the enzyme is higher than the potential energy of a macromolecular carbon skeleton of alkane, so that the carbon skeleton is cracked and the carbon-hydrogen bonds are broken, and the high-efficiency and rapid viscosity reduction and condensation reduction effects of super-heavy oil, high-pour-point oil and heavy (slag) oil products are achieved.

The invention uses biological peptide heavy hydrocarbon dissociation enzyme complex tetrahydrofuran strontium-bite and sodium hexahydroquinoline as compound free transfer factor assistant, which is affinity carboxyl in grass-leaved hydrocarbon essence, contains a large amount of organic calcium, organic silicon and active calcium in straws, determines the activity of hydrocarbon enzyme in grass-leaved hydrocarbon brewing according to the ratio of multiplier of a counting plate, adds graphite peptide, the enzymatic reaction acts on the C-C energy unbalance in the heavy hydrocarbon component in direct proportion, grass-leaved hydrocarbon basic groups and free radical ions are operated to receive absorption to maintain the residual ends of the dissociated small-molecule light-component hydrocarbon molecules, the surface tension of the molecules is balanced, in the process of exchanging the two-way cross flow state factors, a great number of cellulose, hemicellulose, xylan and inositol sugar obtain peptide-based free negative ion peptide hydrogen elements before sublimation, overheating and carbonization, and modification is carried out to participate in liquid phase recombination of modification and mixing. The graphite peptide and the petroleum peptide belong to the same kind of mineral deposit protein structure and are also called carbon-series DNA.

The invention utilizes the waste residue after the reaction of the grass hydrocarbon and the oils containing colloid and high asphaltene, such as heavy oil, heavy oil and the like, as the raw material of the graphite electrode, the waste residue after the reaction with the heavy residual oil and the waste asphalt is activated carbon and carbon powder, and the waste residue after the reaction with coal, coal tar and high molecular engineering plastics is the raw material of acetylene, thereby being beneficial to the recycling of waste resources, solving the problem of energy shortage and purifying the environment. The oil yield of the ton raw material reaches 50-60%; the cost is lower than 2000 yuan/ton. The normal pressure and the temperature of the low-energy consumption production operation are 240 ℃. Initial boiling point: 135 ℃ lower than the distillation range of the non-gramineous hydrocarbon by 138 ℃, and the measured amount of heavy super heavy oil: 100ml, 306 ℃ and 60.45 percent of yield.

Detailed Description