阅读说明：本技术 具有含硫取代基的杀有害生物活性杂环衍生物 (Pesticidally active heterocyclic derivatives with sulphur containing substituents ) 是由 M·米尔巴赫 A·埃德蒙兹 S·伦德勒 V·斯科瓦尔 G·拉瓦尔 I·森 于 2018-04-26 设计创作，主要内容包括：具有式I的化合物<Image he="387" wi="620" file="DDA0002284183410000011.GIF" imgContent="drawing" imgFormat="GIF" orientation="portrait" inline="no"></Image>其中取代基是如在权利要求1中所定义的,以及那些化合物的农用化学上可接受的盐、立体异构体、对映异构体、互变异构体和N-氧化物可以用作杀昆虫剂并且可按照本身已知的方式制备。(A compound having the formula I Wherein the substituents are as defined in claim 1, and the agrochemically acceptable salts, stereoisomers, enantiomers, tautomers and N-oxides of those compounds can be used as insecticides and can be prepared in a manner known per se.)

1. A compound having the formula I

Wherein

A is CH or N;

x is S, SO or SO 2;

r1 is C1-C4 alkyl, C1-C4 haloalkyl or C3-C6 cycloalkyl-C1-C4 alkyl;

r7 and R8 are independently of each other C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C1-C6 cyanoalkyl, C1-C4 alkoxy C1-C4 alkyl, pyridyl or phenyl, wherein said pyridyl or phenyl may be mono-or polysubstituted by a substituent selected from the group consisting of: halogen, cyano, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 haloalkoxy, C1-C4 alkoxy, C1-C4 haloalkylsulfanyl, C1-C4 haloalkylsulfinyl, C1-C4 haloalkylsulfonyl and-C (O) C1-C4 haloalkyl; or

R7 and R8, together with the sulfur atom to which they are attached, form a four to six membered saturated ring system, which may be mono or polysubstituted with substituents selected from the group consisting of: halogen, cyano, C1-C4 alkyl, C1-C4 alkoxy, and C1-C4 haloalkyl; and the ring system may comprise one heteroatom selected from the group consisting of: nitrogen, sulfur and oxygen;

n is 0 or 1;

q is a group selected from the group consisting of: formulae Q1 to Q4

Wherein the arrow indicates the point of attachment to the ring incorporating group a;

and wherein

X1 is O, S or NR3 wherein R3 is C1-C4 alkyl;

r2 is halogen, C1-C6 haloalkyl, C1-C4 haloalkylsulfanyl, C1-C4 haloalkylsulfinyl, C1-C4 haloalkylsulfonyl or C1-C6 haloalkoxy;

g1 is N or CH;

g2 and G3 are independently from each other N or CH; and

agrochemically acceptable salts, stereoisomers, enantiomers, tautomers and N-oxides of the compounds having formula I.

2. The compound of formula I according to claim 1, represented by the compound of formula I-1

Wherein Q, a, n, R7 and R8 are as defined under formula I in claim 1;

xa1 is S, SO or SO 2; and is

Ra1 is methyl, ethyl, n-propyl, isopropyl or cyclopropylmethyl.

3. The compound of formula I according to claim 1, represented by the compound of formula I-2

Wherein X1, R2, G1, a, n, R7 and R8 are as defined in claim 1 under formula I;

xa2 is S, SO or SO 2; and is

Ra2 is methyl, ethyl, n-propyl, isopropyl or cyclopropylmethyl.

4. The compound of formula I according to claim 1, represented by the compound of formula I-3

Wherein

A is N;

r2 is C1-C6 haloalkyl;

g1 is N or CH;

n is 0 or 1;

r7 and R8 are independently of each other C1-C6 alkyl; or

R7 and R8 form, together with the sulfur atom to which they are attached, a six-membered saturated ring system, which may contain one oxygen atom.

5. The compound of formula I according to claim 1, represented by the compound of formula I-4

Wherein R2, G3, a, n, R7 and R8 are as defined under formula I in claim 1;

xa3 is S, SO or SO 2; and is

Ra3 is methyl, ethyl, n-propyl, isopropyl or cyclopropylmethyl.

6. The compound of formula I according to claim 1, represented by compounds of formula I-5

Wherein

A is CH or N;

r2 is C1-C6 haloalkyl;

g3 is N or CH;

n is 0 or 1; and is

R7 and R8 are independently of each other C1-C6 alkyl; or

R7 and R8 form, together with the sulfur atom to which they are attached, a six membered saturated ring system, which may contain one oxygen atom.

7. The compound of formula I according to claim 1, represented by the compound of formula I-5, the compound of formula I-5 represented by the compound of formula I-6

Wherein X1, R2, G1, a, n, R7 and R8 are as defined in claim 1 under formula I;

xa4 is S, SO or SO 2; and is

Ra4 is methyl, ethyl, n-propyl, isopropyl or cyclopropylmethyl.

8. The compound of formula I according to claim 1, represented by compounds of formula I-7

Wherein

A is N;

r2 is C1-C6 haloalkyl;

g1 is N or CH;

n is 0 or 1; and is

R7 and R8 are independently of each other C1-C6 alkyl; or

R7 and R8 form, together with the sulfur atom to which they are attached, a six membered saturated ring system, which may contain one oxygen atom.

9. The compound of formula I according to claim 1, represented by a compound of formula I-8:

wherein

A is CH or N;

n is 0 or 1;

r7 and R8 are independently of each other C1-C6 alkyl; or

R7 and R8, together with the sulfur atom to which they are attached, form a six membered saturated ring system, which may contain one oxygen atom; and is

Q is a group selected from the group consisting of: the formulae Q1a, Q1b and Q2a

Wherein the arrow indicates the point of attachment to the ring incorporating group a;

and wherein

R2 is C1-C6 haloalkyl.

10. A pesticidal composition comprising: at least one compound of the formula I according to claim 1 or, where appropriate, a tautomer thereof, in each case in free form or in agrochemically usable salt form, as active ingredient; and at least one auxiliary agent.

11. A method for controlling pests, said method comprising applying a composition according to claim 10 to the pests or their environment, except for methods for treating the human or animal body by surgery or therapy and diagnostic methods carried out on the human or animal body.

12. A method for protecting plant propagation material from attack by pests, which comprises treating the propagation material or the locus where the propagation material is planted with a composition according to claim 10.

Example 1 provides a compound having formula I as defined above or an agrochemically acceptable salt, stereoisomer, enantiomer, tautomer or N-oxide thereof.