Coating agent composition comprising PVC and plasticizing component

文档序号:1618144 发布日期:2020-01-10 浏览:32次 中文

阅读说明:本技术 包含pvc和增塑组分的涂覆剂组合物 (Coating agent composition comprising PVC and plasticizing component ) 是由 A·格里姆 M·普费弗尔 H·莫根施特恩 于 2018-02-28 设计创作,主要内容包括:本发明涉及一种涂覆剂组合物,其包含a)聚氯乙烯,b)一种或多种通式(I)化合物,其中R<Sup>1a</Sup>和R<Sup>1b</Sup>独立地为C<Sub>7</Sub>-C<Sub>12</Sub>烷基,c)一种或多种具有增塑性能的化合物,其选自具有C<Sub>1</Sub>-C<Sub>6</Sub>基团的己二酸酯、具有C<Sub>1</Sub>-C<Sub>6</Sub>基团的戊二酸酯、具有C<Sub>2</Sub>-C<Sub>6</Sub>基团的癸二酸酯、二苯甲酸酯、具有C<Sub>5</Sub>-C<Sub>10</Sub>烷基或苄基的单苯甲酸酯、通式(II)的化合物、通式(III)的化合物、十五烷基磺酸的苯基酯、十五烷基磺酸的甲苯基酯、具有C<Sub>1</Sub>-C<Sub>6</Sub>基团的对苯二甲酸酯、具有C<Sub>1</Sub>-C<Sub>6</Sub>基团的乙酰丙酸酯、戊酸异山梨醇酯,具有C<Sub>1</Sub>-C<Sub>6</Sub>基团的偏苯三酸酯和2,2,4-三甲基-1,3-戊二醇二异丁酸酯,和d)一种或多种通式(IV)的化合物。<Image he="623" wi="700" file="DDA0002185377450000011.GIF" imgContent="drawing" imgFormat="GIF" orientation="portrait" inline="no"></Image>(The invention relates to a coating agent composition containing a) polyvinyl chloride, b) one or more compounds of general formula (I), wherein R 1a And R 1b Independently is C 7 ‑C 12 Alkyl, C) one or more compounds having plasticizing properties selected from compounds having C 1 ‑C 6 Adipate of the group, having C 1 ‑C 6 Glutarate of the radical, having C 2 ‑C 6 Sebacates, dibenzoates, having C of the group 5 ‑C 10 Alkyl or benzyl monobenzoate, compounds of the general formula (II), compounds of the general formula (III), phenyl ester of pentadecyl sulfonic acid, tolyl ester of pentadecyl sulfonic acid, C-containing compounds 1 ‑C 6 Terephthalic esters of radicals, having C 1 ‑C 6 Levulinic acid esters, isosorbide valerate of the group having C 1 ‑C 6 Trimellitate and 2,2, 4-trimethyl-1, 3-pentanediol diisobutyrate of the radicals, and d) one or more compounds of the general formula (IV).)

1. A coating composition comprising:

a) the polyvinyl chloride (PVC) is prepared by mixing polyvinyl chloride,

b) one or more compounds of the general formula (I):

Figure FDA0002298566470000011

wherein:

R1aand R1bIndependently of one another are C7-C12An alkyl group, a carboxyl group,

c) one or more compounds having plasticizing properties selected from the group consisting of C1-C6Adipate of radicals, containing C1-C6Glutarate of a radical, containing C2-C6Sebacate, dibenzoate, C-containing of the group5-C10Mono-benzoates of alkyl or benzyl groups,

a compound of the general formula (II):

Figure FDA0002298566470000012

wherein R is2a、R2bAnd R2cIndependent of each other and of R2dGround is C2-C6Alkyl radical, R2dIndependently of R2a、R2bAnd R2cGround is C1-C5An alkyl group, a carboxyl group,

a compound of the general formula (III):

Figure FDA0002298566470000013

wherein R is3a、R3bAnd R3cIndependently of one another are C2-C6An alkyl group, a carboxyl group,

phenyl ester of pentadecylsulfonic acid, tolyl ester of pentadecylsulfonic acid, containing C1-C6Terephthalic acid ester of radicals comprising C1-C6Levulinic acid esters of radicals, isosorbide valerate, comprising C1-C6Trimellitate and 2,2, 4-trimethyl-1, 3-pentanediol diisobutyrate of the groups,

d) one or more compounds of formula (IV):

Figure FDA0002298566470000021

2. the coating composition according to claim 1, wherein the proportion of the one or more compounds of the formula (I) is from 5 to 150 phr.

3. The coating composition according to claim 1 or 2, wherein the proportion of the one or more compounds having plasticizing properties is from 5 to 150 phr.

4. A coating composition according to any one of claims 1 to 3, wherein the proportion of the one or more compounds of the general formula (IV) is from 0.1 to 10 phr.

5. A coating composition according to any one of claims 1 to 4, wherein the compound of formula (I) is di (2-ethylhexyl) terephthalate.

6. The coating composition according to any one of claims 1 to 5, wherein the one or more compounds having plasticizing properties are one or more compounds of the general formula (II).

Figure FDA0002298566470000022

Wherein R is2a、R2bAnd R2cIndependent of each other and of R2dGround is C2-C6Alkyl radical, R2dIndependently of R2a、R2bAnd R2cGround is C1-C5An alkyl group.

7. The coating composition according to any one of claims 1 to 5, wherein the one or more compounds having plasticizing properties are one or more dibenzoate esters selected from the group consisting of diethylene glycol dibenzoate, triethylene glycol dibenzoate, polyethylene glycol dibenzoate and dipropylene glycol dibenzoate.

8. The coating composition according to any one of claims 1 to 7, wherein the coating composition comprises one or more isocyanurates different from general formula (IV).

9. The coating composition according to any one of claims 1 to 8, wherein the coating composition comprises one or more polymers other than polyvinyl chloride.

10. A method of preparing a coating composition according to any one of claims 1 to 9, comprising the steps of:

a. suspending polyvinyl chloride in one or more compounds of formula (I),

b. adding one or more compounds of the general formula (IV) to the suspension obtained in step a.,

wherein the one or more compounds having plasticizing properties according to claim 1c) may be added in step a, or after step a and before step b, or in step b, or after step b, or at any desired time.

11. A method of coating a textile fibre or fabric, wherein one or more sides of the textile fibre or fabric are contacted with a coating composition according to any one of claims 1 to 9.

12. The method of claim 11, wherein the fabric is a synthetic fabric.

13. An article comprising a fabric, wherein the fabric is at least partially coated on one or more sides with a coating composition according to any one of claims 1-9.

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