阅读说明：本技术 基于工业固废的铁铝酸盐轻质保温墙体材料及制备方法 (Iron aluminate light heat-insulating wall material based on industrial solid wastes and preparation method thereof ) 是由 李召峰 高益凡 王衍升 张健 齐延海 于 2019-10-29 设计创作，主要内容包括：本公开提供了基于工业固废的铁铝酸盐轻质保温墙体材料及制备方法,墙体材料原料由固体原料和水组成,固体原料由基于工业固废的铁铝酸盐水泥、再生材料、发泡剂、骨料、引气剂、增强材料组成,基于工业固废的铁铝酸盐水泥的原料由赤泥、钢渣、矿渣、脱硫石膏、硅灰、铝灰组成。制备方法为：将赤泥、钢渣、矿渣、脱硫石膏、硅灰、铝灰依次经过原料粉磨、均化、烧成、熟料粉磨获得基于工业固废的铁铝酸盐水泥,将基于工业固废的铁铝酸盐水泥与再生材料、水、发泡剂、骨料、引气剂、增强材料搅拌,发泡形成。本公开能够将工业固废制备轻质保温墙体材料,大大提高了固废的利用率,又具有高流态轻质特性,同时,具有较高的强度及更好的保温效果等性能。(The invention provides an iron aluminate lightweight thermal insulation wall material based on industrial solid waste and a preparation method thereof. The preparation method comprises the following steps: the method is characterized by sequentially grinding, homogenizing, firing and grinding raw materials of red mud, steel slag, desulfurized gypsum, silica fume and aluminum ash to obtain the industrial solid waste-based ferro-aluminate cement, and stirring and foaming the industrial solid waste-based ferro-aluminate cement, a regeneration material, water, a foaming agent, an aggregate, an air entraining agent and a reinforcing material. The method can prepare the light heat-insulating wall material from industrial solid wastes, greatly improves the utilization rate of the solid wastes, has the characteristic of high flow state light weight, and simultaneously has the performances of higher strength, better heat-insulating effect and the like.)

1. The light heat-insulating ferric aluminate wall material based on industrial solid waste is characterized in that raw materials of the wall material consist of solid raw materials and water, the solid raw materials consist of ferric aluminate cement based on industrial solid waste, a regeneration material, a foaming agent, aggregate, an air entraining agent and a reinforcing material, and the raw materials of the ferric aluminate cement based on industrial solid waste consist of red mud, steel slag, desulfurized gypsum, silica fume and aluminum ash.

2. The light-weight thermal insulation ferric aluminate wall material based on industrial solid wastes as claimed in claim 1, which is characterized in that the raw materials of the ferric aluminate cement based on the industrial solid wastes comprise, by weight, 13-20 parts of red mud, 15-20 parts of steel slag, 30-35 parts of slag, 10-15 parts of desulfurized gypsum, 5-10 parts of silica fume and 6-12 parts of aluminum ash.

3. The light-weight thermal insulation ferric aluminate wall material based on industrial solid wastes as claimed in claim 1, which is characterized in that the preparation method of the ferric aluminate cement based on industrial solid wastes comprises the following steps: mixing red mud, steel slag, desulfurized gypsum, silica fume and aluminum ash serving as raw materials, and performing wet grinding, homogenization treatment and dehydration to obtain slurry; then calcining at high temperature to obtain the catalyst;

preferably, the calcination temperature is 1250-1300 ℃.

4. The light-weight heat-insulating ferric aluminate wall material based on industrial solid wastes as claimed in claim 1, wherein the water cement ratio of the components is 0.5-0.6.

5. The light-weight thermal insulation ferric aluminate wall material based on industrial solid wastes as claimed in claim 1, wherein the aggregate is any one or a mixture of steel slag, tailings, manganese slag, construction wastes, nickel slag, ferrochromium slag and silicomanganese slag;

or the foaming agent is any one or mixture of a plurality of rubber foaming agents, glass foaming agents, cement foaming agents, concrete foaming agents, plastic foaming agents and polyurethane foaming agents;

or the air entraining agent is any one or mixture of more of rosin resins, alkyl benzene sulfonates and fatty alcohol sulfonates;

or the reinforcing material is any one or a mixture of glass fiber, carbon fiber and aromatic polyamide fiber.

6. The light-weight thermal insulation ferric aluminate wall material based on industrial solid wastes as claimed in claim 1, wherein the raw material of the ferric aluminate cement based on industrial solid wastes is ground by a ball mill, and the specific surface area is 330-400 m²And/kg, the mass density of the solid material is 70-83%.

7. The iron aluminate lightweight thermal insulation wall material based on industrial solid wastes according to claim 1, wherein the solid raw materials comprise, by mass, 30-50% of iron aluminate cement, 30-50% of a recycled material, 1-3% of a foaming agent, 5-10% of an aggregate, 0.5-3% of an air entraining agent, and 1-5% of a reinforcing material.

8. A preparation method of an iron aluminate lightweight thermal insulation wall material based on industrial solid wastes is characterized in that red mud, steel slag, desulfurized gypsum, silica fume and aluminum ash are sequentially subjected to raw material grinding, homogenization, firing and clinker grinding to obtain iron aluminate cement based on industrial solid wastes, and the iron aluminate cement based on industrial solid wastes is stirred with a regeneration material, water, a foaming agent, an aggregate, an air entraining agent and a reinforcing material and is formed by foaming.

9. The method for preparing the light-weight thermal insulation ferric aluminate wall material based on the industrial solid wastes as claimed in claim 8, wherein the ferric aluminate cement based on the industrial solid wastes, the recycled material and the aggregate are mixed and stirred to obtain a dry mixture, and then water, the air entraining agent, the foaming agent and the reinforcing material are added, and the dry mixture is uniformly mixed, pressed, molded, demolded and maintained.

10. The preparation method of the light-weight thermal insulation ferric aluminate wall material based on the industrial solid wastes as claimed in claim 9, is characterized in that an air entraining agent, a foaming agent, a reinforcing material and water are mixed to obtain a solution, the dry mixture is added into the solution to be mixed to obtain a slurry, the slurry is heated to 45-60 ℃ at a heating rate of 6-8 ℃/min, stirred at a constant temperature for 9-11 min, then cooled to 40 +/-2 ℃ at a cooling rate of 8-10 ℃/min, and then foaming, forming, curing and drying are carried out;

preferably, the mixing temperature of the air entraining agent, the foaming agent and the reinforcing material with water is 30-40 ℃;

preferably, the curing temperature is 50-60 ℃, and the humidity is 75-85%.

Technical Field

The disclosure belongs to the field of building materials, and relates to an iron aluminate light heat-insulating wall material based on industrial solid wastes and a preparation method thereof.

Background

The information in this background section is only for enhancement of understanding of the general background of the disclosure and is not necessarily to be construed as an admission or any form of suggestion that this information forms the prior art that is already known to a person of ordinary skill in the art.

With the rapid economic development of China, a large amount of industrial solid wastes are generated due to the consumption of a large amount of energy, and the industrial solid wastes mainly comprise red mud, steel slag, desulfurized gypsum, smelting slag, tailing sand, coal gangue and the like. At present, the industrial solid waste discharge amount in China exceeds 30 hundred million tons per year, and the effective disposal rate is only about 60 percent. With the continuous acceleration of the industrialization process in China, the industrial solid wastes occupy a large amount of land and have the danger of polluting the environment at any time. Meanwhile, with the increase of the population of China, a large amount of construction waste generated by the transformation of old urban areas and the construction of new urban areas and the surrounding phenomenon of waste become more and more serious, and severe examination is brought to the clearing and transportation of the construction waste, the occupation of landfill land, the pollution to urban environment and the urban management. Therefore, the industrial solid wastes and the construction wastes are utilized to the maximum extent, and the realization of multi-channel and large-quantity resource utilization is urgent.

Along with the continuous development of modernization, the problem of 'difficult employment' in the building industry is very prominent, especially the manual wall building, the labor intensity is high, and the shortage of technical workers is more a hindrance to the smooth construction. People have higher and higher requirements on the aspects of quality, safety, energy conservation, environmental protection and the like of building engineering, buildings gradually develop towards the direction of greening, environmental protection, energy conservation and comfort, and new materials and technologies are needed, wherein light weight is an important part, and the light weight can reduce the labor capacity and is convenient to install. However, through the research of the inventor, the existing lightweight wall material has the performance defects of high cost, high economic defect, low strength, poor heat insulation effect and the like.

Disclosure of Invention

In order to solve the defects of the prior art, the purpose of the disclosure is to provide an iron aluminate light thermal insulation wall material based on industrial solid wastes and a preparation method thereof, the industrial solid wastes can be prepared into the light thermal insulation wall material, the utilization rate of the solid wastes is greatly improved, secondary pollution is reduced, and the cost is reduced; but also has the characteristic of high flow state and light weight, and the construction process is effectively optimized. Meanwhile, the light heat-insulating wall material disclosed by the invention has the performances of higher strength, better heat-insulating effect and the like.

In order to achieve the purpose, the technical scheme of the disclosure is as follows:

on the one hand, the light heat-insulating ferric aluminate wall material based on industrial solid wastes comprises raw materials of solid raw materials and water, wherein the solid raw materials comprise ferric aluminate cement based on industrial solid wastes, a regeneration material, a foaming agent, an aggregate, an air entraining agent and a reinforcing material, and the raw materials of the ferric aluminate cement based on industrial solid wastes comprise red mud, steel slag, desulfurized gypsum, silica fume and aluminum ash.

On the other hand, the preparation method of the light-weight thermal insulation ferric aluminate wall material based on the industrial solid wastes comprises the steps of sequentially grinding the red mud, the steel slag, the desulfurized gypsum, the silica fume and the aluminum ash through raw materials, homogenizing, firing and grinding clinker to obtain the ferrous aluminate cement based on the industrial solid wastes, stirring the ferrous aluminate cement based on the industrial solid wastes with a regeneration material, water, a foaming agent, an aggregate, an air entraining agent and a reinforcing material, and foaming to obtain the light-weight thermal insulation ferric aluminate wall material based on the industrial solid wastes.

The light heat-insulating wall material prepared by the method has the characteristic of high flow state and light weight, and can effectively optimize the construction process.

The beneficial effect of this disclosure does:

(1) the product obtained by the method belongs to a preparation method for preparing the iron aluminate high-flow-state light heat-insulating wall material by using industrial solid wastes, the raw materials of the technology have wide application range, and various solid wastes can be used in a large proportion, so that the method is an ideal way for realizing the resource utilization of the solid wastes.

(2) The method has the advantages that the solid waste is utilized as a main raw material in a large amount, finished cement products are not needed, the single consumption of the cement is reduced, the utilization rate of the solid waste is greatly improved, secondary pollution is reduced, and the cost is reduced. The main raw materials used in the method are red mud, steel slag, desulfurized gypsum, silica fume, aluminum ash, construction waste and the like which are huge waste resources, so the raw materials are low in cost.

(3) The light heat-insulating wall material has the advantages of high flow state, strong fluidity, high strength and excellent heat-insulating property.

(4) The operation method disclosed by the invention is simple, low in cost, universal and easy for large-scale production.

Detailed Description

It should be noted that the following detailed description is exemplary and is intended to provide further explanation of the disclosure. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this disclosure belongs.

It is noted that the terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of example embodiments according to the present disclosure. As used herein, the singular forms "a", "an" and "the" are intended to include the plural forms as well, and it should be understood that when the terms "comprises" and/or "comprising" are used in this specification, they specify the presence of stated features, steps, operations, devices, components, and/or combinations thereof, unless the context clearly indicates otherwise.

In view of the performance defects of high cost and the like of the existing light wall material, low strength, poor heat insulation effect and the like, the disclosure provides an iron aluminate light heat insulation wall material based on industrial solid wastes and a preparation method thereof.

The typical embodiment of the disclosure provides an iron aluminate lightweight thermal insulation wall material based on industrial solid waste, the wall material raw materials consist of solid raw materials and water, the solid raw materials consist of iron aluminate cement based on industrial solid waste, a regeneration material, a foaming agent, aggregate, an air entraining agent and a reinforcing material, and the raw materials of the iron aluminate cement based on industrial solid waste consist of red mud, steel slag, desulfurized gypsum, silica fume and aluminum ash.

In one or more embodiments of the embodiment, the raw materials of the industrial solid waste-based ferrous aluminate cement comprise, by weight, 13-20 parts of red mud, 15-20 parts of steel slag, 30-35 parts of slag, 10-15 parts of desulfurized gypsum, 5-10 parts of silica fume and 6-12 parts of aluminum ash. Can effectively improve the solidification strength of the iron aluminate cement.

In one or more embodiments of this embodiment, the method for preparing an industrial solid waste-based ferrous aluminate cement comprises: mixing red mud, steel slag, desulfurized gypsum, silica fume and aluminum ash serving as raw materials, and performing wet grinding, homogenization treatment and dehydration to obtain slurry; and then calcining at high temperature to obtain the catalyst. The high-temperature calcination in the disclosure means calcination at a temperature of not less than 1000 ℃.

The method utilizes the industrial solid wastes such as red mud, steel slag, desulfurized gypsum, silica fume, aluminum ash and the like to replace high-quality mineral resources to prepare the ferrous aluminate cement and further prepare the light thermal insulation material, realizes the recycling comprehensive utilization of a large amount of industrial solid wastes, greatly reduces the preparation cost of the light thermal insulation material, can realize the energy utilization of construction wastes, and reduces the use of sandstone aggregate, thereby not only treating the construction wastes, but also reducing the cost for producing the ultrahigh water filling material.

The research of the present disclosure finds that: different calcination temperatures can affect the performance of the ferro-aluminate cement, so that in order to recycle various waste raw materials and obtain better curing performance, the calcination temperature of the industrial solid waste raw materials is optimized, and therefore in the series of embodiments, the calcination temperature is 1250-1300 ℃. If the calcining temperature is too low, the performance of the calcined product is unstable; if the calcination temperature is too high, the bulk density of the calcined product is reduced, and the curing strength at the later stage is reduced. The calcination time is 100-130 min.

The water-cement ratio influences the rheological property of concrete, the cement paste coagulation structure and the compactness of the hardened concrete, so that under the condition of given composition materials, the water-cement ratio is a main parameter for determining the strength, durability and other series of physical and mechanical properties of the concrete, and therefore in the series of embodiments, the water-cement ratio of the components is 0.5-0.6, and the better rheological property and coagulation cement paste structure are obtained.

The steel slag, the tailings, the manganese slag and the like are common waste materials, and in order to improve the utilization rate of waste materials and simultaneously meet the requirements of the framework and the filling effect of the aggregate, in one or more embodiments of the embodiment, the aggregate is any one or mixture of the steel slag, the tailings, the manganese slag, the construction waste, the nickel slag, the ferrochromium slag and the silicomanganese slag, and the prepared light heat-insulating wall material has the advantages of high fluidity, strong fluidity, low water content, high strength and the like. The workability of the lightweight thermal insulation wall material mixture, the strength and the crack resistance are improved through the mutual matching of various different aggregates.

In one or more embodiments of the embodiment, raw materials based on industrial solid waste ferrous aluminate cement (the industrial solid waste raw materials are any one or a mixture of several of red mud, steel slag, desulfurized gypsum, silica fume and aluminum ash) are ground by a ball mill, and the specific surface area of dry materials is 330-400 m²And/kg, the mass density of the solid material is 70-83%.

In one or more embodiments of this embodiment, the weight of the water is 50 to 60% of the solid feedstock.

In one or more embodiments of the embodiment, the solid raw material comprises, by mass, 30-50% of the iron aluminate cement, 30-50% of the recycled material, 1-3% of the foaming agent, 5-10% of the aggregate, 0.5-3% of the air-entraining agent, and 1-5% of the reinforcing material.

In one or more embodiments of this embodiment, the foaming agent is any one or a mixture of several of a rubber foaming agent, a glass foaming agent, a cement foaming agent, a concrete foaming agent, a plastic foaming agent, and a polyurethane foaming agent.

In one or more embodiments of the present invention, the air-entraining agent is any one or a mixture of several of rosin resins, alkyl benzene sulfonates, and fatty alcohol sulfonates.

In one or more embodiments of this embodiment, the reinforcing material is any one or a mixture of glass fibers, carbon fibers, and aramid fibers.

The recycled material disclosed by the disclosure is prepared by grinding and grading sieving building powder (such as concrete blocks, broken bricks and tiles, broken stones, waste gypsum and the like) in building garbage, and activating at 700 ℃, and has certain activity.

The red mud, steel slag, desulfurized gypsum, silica fume and aluminum ash are sequentially subjected to raw material grinding, homogenization, firing and clinker grinding to obtain the iron aluminate cement based on the industrial solid waste, and the iron aluminate cement based on the industrial solid waste is stirred with a regeneration material, water, a foaming agent, aggregate, an air entraining agent and a reinforcing material and is formed by foaming.

The light heat-insulating wall material prepared by the method has the characteristic of high flow state and light weight, and can effectively optimize the construction process.

In one or more embodiments of the embodiment, the industrial solid waste-based ferrous aluminate cement, the recycled material and the aggregate are mixed and stirred to obtain a dry mixture, and then water, the air entraining agent, the foaming agent and the reinforcing material are added, and the mixture is uniformly mixed, pressed, molded, demoulded and maintained.

In the series of embodiments, an air entraining agent, a foaming agent, a reinforcing material and water are mixed to obtain a solution, a dry mixture is added into the solution to be mixed to obtain a slurry, the temperature of the slurry is raised to 45-60 ℃ at a temperature raising speed of 6-8 ℃/min, the slurry is stirred at a constant temperature for 9-11 min, then the temperature is lowered to 40 +/-2 ℃ at a temperature lowering speed of 8-10 ℃/min, and then foaming, forming, maintaining and drying are carried out.

In the series of embodiments, the temperature for mixing the air entraining agent, the foaming agent, the reinforcing material and the water is 30-40 ℃.

In the series of embodiments, the curing temperature is 50-60 ℃, and the humidity is 75-85%.

The preparation method, the raw material proportion and the selection of the industrial solid waste-based ferrous aluminate cement in the embodiment are consistent with those of the industrial solid waste-based ferrous aluminate lightweight thermal insulation wall material.

In order to make the technical solutions of the present disclosure more clearly understood by those skilled in the art, the technical solutions of the present disclosure will be described in detail below with reference to specific embodiments.