阅读说明：本技术 一种铁水包内衬用捣打料及其制备方法 (Ramming material for ladle lining and preparation method thereof ) 是由 李胜春 宋永宏 刘坤仑 牛强 邸俊明 华永才 于 2019-10-11 设计创作，主要内容包括：本发明涉及一种铁水包内衬用捣打料及其制备方法,其原料组成质量百分比为：所述的硅石为52～57％,高铝矾土为20～23％,粘土为5～10％,石墨为5～15％,粉煤灰为0.1～5％,碳化硅粉为0.2～5％,铬渣粉为0.1～3％,硅酸钠为0.1～1％,聚磷酸铝为0.1～1％。本发明的优点：使用过程中结构强度较高,不会在使用过程中发生松动、剥落等损坏而导致漏包事故,保障了铁水包吊运过程中周边的人身和设备安全,同时不会发生铁水粘包现象,避免渣中包裹铁水,提高铁水的回收率,在安全性和经济性方面都有极大的提升。(The invention relates to a ramming material for a ladle lining and a preparation method thereof, wherein the ramming material comprises the following raw materials in percentage by mass: 52-57% of silica, 20-23% of high-alumina, 5-10% of clay, 5-15% of graphite, 0.1-5% of fly ash, 0.2-5% of silicon carbide powder, 0.1-3% of chromium slag powder, 0.1-1% of sodium silicate and 0.1-1% of aluminum polyphosphate. The invention has the advantages that: structural strength is higher in the use, can not take place not hard up in the use, peel off etc. and damage and lead to leaking the package accident, has ensured the peripheral personal and the equipment safety of ladle handling in-process, can not take place the molten iron simultaneously and glue a packet phenomenon, avoids wrapping up in the sediment molten iron, improves the rate of recovery of molten iron, all has very big promotion in the aspect of security and economic nature.)

1. The ramming material for the inner lining of the foundry ladle is characterized by comprising the following raw materials in percentage by mass: 72-80% of aggregate, 10.1-30% of powder, 0.3-8% of anti-erosion agent and 0.2-2% of binding agent; the aggregate comprises silica and high-alumina, the powder comprises clay, graphite and fly ash, the erosion-resistant agent comprises silicon carbide powder and chromium slag powder, and the binding agent comprises sodium silicate and aluminum polyphosphate.

2. The ramming mass for ladle inner lining of claim 1, wherein the amount of silica is 52-57%, the amount of bauxite is 20-23%, the amount of clay is 5-10%, the amount of graphite is 5-15%, the amount of fly ash is 0.1-5%, the amount of silicon carbide powder is 0.2-5%, the amount of chromium slag powder is 0.1-3%, the amount of sodium silicate is 0.1-1%, and the amount of aluminum polyphosphate is 0.1-1% based on the total amount of the ramming mass.

3. The ramming mass for a ladle liner according to claim 1, wherein the total amount of the ramming mass is 55% of silica, 20% of high-alumina, 8% of clay, 9.5% of graphite, 2.5% of fly ash, 1.5% of silicon carbide powder, 2.3% of chromium slag powder, 0.4% of sodium silicate and 0.8% of aluminum polyphosphate.

4. The ramming mass for ladle liners according to claim 1, wherein the silica has a particle size distribution, based on the total amount of silica, of: 16% of 6-7 mm, 17% of 5-6 mm, 17% of 4-5 mm, 24% of 3-4 mm and 26% of 2-3 mm;

based on the total amount of the bauxite, the particle size distribution of the bauxite is as follows: 12% of 4-5 mm, 16% of 3-4 mm, 17.5% of 2-3 mm, 22.5% of 1-2 mm and 32% of 0.38-1 mm;

the particle sizes of the clay, the graphite, the fly ash, the silicon carbide powder and the chromium slag are respectively larger than or equal to 200 meshes; the sodium silicate and the aluminum polyphosphate are solid powder.

5. The ramming mass for ladle liners according to claim 1, wherein the silica has a decrepitation rate of 80% or more and SiO is contained in the ramming mass₂The content is not less than 98%; the high-alumina bauxite contains Al₂O₃Content ≧ 80%, Fe₂O₃Content ≦ 2%, TiO₂The content is less than or equal to 4 percent, the content of CaO and MgO is less than or equal to 0.6 percent, and K₂O+Na₂O content is less than or equal to 0.6 percent, and volume density is not less than 2.75g/cm³(ii) a SiO in the clay₂Content ≧ 44%, Al₂O₃Content ≧ 37%, Fe₂O₃Content ≦ 2%, TiO₂The content is less than or equal to 2 percent, the content of CaO and MgO is less than or equal to 0.8 percent, and K₂O+Na₂The O content is less than or equal to 0.8 percent; SiO in the fly ash₂Content ≧ 50%, Al₂O₃Content ≧ 31%, Fe₂O₃The content is less than or equal to 6 percent, the content of CaO and MgO is less than or equal to 4.5 percent, and the weight loss is less than or equal to 5 percent; the Cr in the chromium slag powder₂O₃Content ≧ 12%, SiO₂+Al₂O₃The content is not less than 38 percent, the content of CaO and MgO is not less than 40 percent, and Fe₂O₃The content is less than or equal to 0.3 percent.

6. The preparation method of the ramming mass for the ladle lining, as claimed in claim 1, comprises the following specific steps:

(1) weighing sodium silicate and aluminum polyphosphate according to the weight percentage, adding 3 times of water according to the weight ratio of 1:3, heating to 50 ℃, and stirring until the sodium silicate and the aluminum polyphosphate are completely dissolved in the water to form an additive solution;

(2) weighing clay, graphite, fly ash, silicon carbide powder and chromium slag powder according to the weight percentage, premixing, adding silica and high-alumina, mixing to form a batch mixture, and atomizing and adding an additive solution in the mixing process;

(3) according to the batch: weighing tap water according to the weight ratio of 9:1, adding the tap water into the batch while stirring for 6 minutes to form a wet-based ramming mass;

(4) and (3) smearing the wet base ramming mass in a die gap on the inner wall of the ladle for ramming operation.

Technical Field

The invention belongs to the technical field of ferrosilicon production, and particularly relates to a ramming mass for a ladle lining and a preparation method thereof.

Background

In the production of ferrosilicon, a ladle for containing molten iron belongs to main equipment, the quality of the ladle, particularly the quality of internal refractory materials directly influences the safety (particularly the occurrence of a ladle penetrating accident), the molten iron recovery rate and the ladle repair workload in the use process of the ladle. The ladle structure is used in production of tradition ferrosilicon comprises box hat and inside lining refractory material, and inside lining refractory material clay brick commonly used builds by laying bricks or stones, has more shortcoming in the use: for example, the safety factor is low, the ladle penetrating accident or even the ladle leaking accident occurs occasionally, the ladle loss is at least more than ten thousand yuan per time of ladle leaking, great hidden dangers are brought to the personal and equipment safety around the ladle hoisting process, meanwhile, the molten iron is seriously stuck, a large amount of molten iron is treated along with slag, and great waste is brought.

Disclosure of Invention

The invention aims to overcome the defects of the prior art and provides a ramming material for a ladle lining and a preparation method thereof. The ramming mass prepared by the method disclosed by the invention is high in structural strength, and meanwhile, the phenomenon of molten iron sticking is avoided, the molten iron is prevented from being wrapped in slag, the recovery rate of the molten iron is improved, and the safety and the economical efficiency are greatly improved.

The purpose of the invention is realized by the following technical scheme:

the ramming material for the inner lining of the foundry ladle comprises the following raw materials in percentage by mass: 72-80% of aggregate, 10.1-30% of powder, 0.3-8% of anti-erosion agent and 0.2-2% of binding agent;

the aggregate comprises silica and high-alumina, the powder comprises clay, graphite and fly ash, the erosion-resistant agent comprises silicon carbide powder and chromium slag powder, and the binding agent comprises sodium silicate and aluminum polyphosphate.

Preferably, based on the total amount of the ramming mass, the ramming mass comprises 52-57% of silica, 20-23% of high-alumina, 5-10% of clay, 5-15% of graphite, 0.1-5% of fly ash, 0.2-5% of silicon carbide powder, 0.1-3% of chromium slag powder, 0.1-1% of sodium silicate and 0.1-1% of aluminum polyphosphate;

preferably, based on the total amount of the ramming mass, the content of the silica is 55%, the content of the high-alumina is 20%, the content of the clay is 8%, the content of the graphite is 9.5%, the content of the fly ash is 2.5%, the content of the silicon carbide powder is 1.5%, the content of the chromium slag powder is 2.3%, the content of the sodium silicate is 0.4%, and the content of the aluminum polyphosphate is 0.8%.

Preferably, the silica particle size distribution is, based on the total amount of silica: 16% of 6-7 mm, 17% of 5-6 mm, 17% of 4-5 mm, 24% of 3-4 mm and 26% of 2-3 mm;

preferably, the bauxite grain size distribution is as follows based on the total amount of the bauxite: 12% of 4-5 mm, 16% of 3-4 mm, 17.5% of 2-3 mm, 22.5% of 1-2 mm and 32% of 0.38-1 mm; the particle sizes of the clay, the graphite, the fly ash, the silicon carbide powder and the chromium slag are respectively larger than or equal to 200 meshes; the sodium silicate and the aluminum polyphosphate are solid powder.

The silica cracking rate is not less than 80 percent, and SiO is₂The content is not less than 98%; the high-alumina bauxite contains Al₂O₃Content ≧ 80%, Fe₂O₃Content ≦ 2%, TiO₂The content is less than or equal to 4 percent, the content of CaO and MgO is less than or equal to 0.6 percent, and K₂O+Na₂O content is less than or equal to 0.6 percent, and volume density is not less than 2.75g/cm³(ii) a SiO in the clay₂Content ≧ 44%, Al₂O₃Content ≧ 37%, Fe₂O₃Content ≦ 2%, TiO₂The content is less than or equal to 2 percent, the content of CaO and MgO is less than or equal to 0.8 percent, and K₂O+Na₂The O content is less than or equal to 0.8 percent; SiO in the fly ash₂Content ≧ 50%, Al₂O₃Content ≧ 31%, Fe₂O₃The content is less than or equal to 6 percent, the content of CaO and MgO is less than or equal to 4.5 percent, and the weight loss is less than or equal to 5 percent; the Cr in the chromium slag powder₂O₃Content ≧ 12%, SiO₂+Al₂O₃The content is not less than 38 percent, the content of CaO and MgO is not less than 40 percent, and Fe₂O₃The content is less than or equal to 0.3 percent.

The invention also aims to provide a preparation method of the ramming mass for the ladle lining, which comprises the following steps:

(1) weighing sodium silicate and aluminum polyphosphate according to the weight percentage, adding 3 times of water according to the weight ratio of 1:3, heating to 50 ℃, and stirring until the sodium silicate and the aluminum polyphosphate are completely dissolved in the water to form an additive solution;

(2) weighing clay, graphite, fly ash, silicon carbide powder and chromium slag powder according to the weight percentage, premixing, adding silica and high-alumina, mixing to form a batch mixture, and atomizing and adding an additive solution in the mixing process;

(3) according to the batch: weighing tap water according to the weight ratio of 9:1, adding the tap water into the batch while stirring for 6 minutes to form a wet-based ramming mass;

(4) and (3) smearing the wet base ramming mass in a die gap on the inner wall of the ladle for ramming operation.

The silica and the high-alumina of the invention are used as aggregates and play a role of a framework in the ramming mass, and particularly under the high-temperature condition, the high-temperature-resistant high-strength concrete ramming mass has good physical and mechanical properties and higher refractoriness, can bear the erosion and washing of high-temperature molten iron and scum, and simultaneously reduces the cost of the refractory ramming mass by introducing a large amount of low-cost aggregates. When the total weight percentage of the silica and the high-alumina is less than 72 percent, the flushing point of molten iron flowing into the ladle from the submerged arc furnace is easy to be flushed and eroded, and the ramming material layer at the position is thinned to reduce the service life of the ladle, so that the powder raw materials are easy to fall off in the high-temperature molten iron flushing process due to excessive powder raw materials, and the quality of a ferrosilicon product is reduced; when the total weight percentage of the silica and the high-alumina is more than 80 percent, a large number of micro cracks are easy to generate in the process of baking the ramming mass, and molten iron is easy to accelerate erosion to the interior of the ramming mass along the gaps in the using process, so that the service life of the foundry ladle is reduced; when the total weight percentage of the silica and the high-alumina is 72-80%, the optimum range of the service performance is reached, cracks are not easy to appear in the baking process, the surface quality in the ramming material ladle is improved, and therefore a compact refractory layer is formed, meanwhile, the aggregate is sufficient, the molten iron scouring resistance performance is excellent, and the number of times of using the ladle is large.

The clay, graphite and fly ash are used as powder, play a role in filling gaps of aggregates, improving processing operation performance, avoiding slag adhesion and iron water adhesion, enhancing material performance and the like, have good bonding performance, are filled in gaps caused by the aggregates, achieve optimal stacking density and facilitate obtaining optimal use performance, and in addition, the powder can expel water in air holes so as to reduce the water adding amount of the ramming material; the introduction of the industrial solid waste fly ash enables the ramming layer to have high heat insulation efficiency, high refractoriness and small heat conductivity, and can reduce the thickness of the ramming layer, shorten the firing time, reduce the fuel consumption, improve the heat efficiency and reduce the cost. When the total weight percentage of the clay, the graphite and the fly ash is less than 10%, the powder is too little in the ramming mass proportion, and the powder cannot effectively fill gaps among aggregates, so that a large number of tiny gaps exist in the aggregates, the binding property among the aggregates is reduced, the strength of the ramming mass after baking is seriously insufficient, the ramming mass is easy to fall off, great potential safety hazard exists in the using process, and meanwhile, a large number of gaps exist in a ramming layer, the using frequency of the foundry ladle is reduced, and a ladle penetrating accident is easy to occur; when the total weight percentage of the clay, the graphite and the fly ash is more than 30%, the powder in the ramming mass is excessive, so that the strength after baking is reduced, a large number of micro cracks are easily generated in the baking process, molten iron is easy to accelerate erosion to the interior of the ramming mass along gaps in the using process, and the cost of raw materials is increased; when the total weight percentage of the clay, the graphite and the fly ash is 10.1-30%, the range of the optimal range of the use performance is reached, the powder fills pores among large, medium and small particles to improve the volume density of a ramming mass blank and reduce the porosity, and simultaneously, the water addition amount of the ramming mass can be reduced due to the extrusion of water in the pores, so that the strength of a ramming layer after baking and the use frequency of a foundry ladle are improved.

The silicon carbide powder and the chromium slag powder are used as erosion-resistant agents, so that the erosion and scouring resistance of the ramming mass to molten iron and slag is greatly improved, the slag adhesion and the molten iron adhesion of the ramming layer are reduced, the refractoriness and the thermal shock resistance of the ramming layer in the use process are improved, the industrial hazardous waste chromium slag powder which is difficult to treat is changed into valuable, and the maximum economical efficiency is exerted. When the total weight percentage of the silicon carbide powder and the chromium slag powder is less than 0.3 percent, the excellent effect is not obvious, and the using effect is not obvious; when the total weight percentage of the silicon carbide powder and the chromium slag powder is more than 8%, the powder raw materials in the ramming material are excessive, the baked strength is reduced, a large number of microcracks are easily generated in the baking process, molten iron is easy to accelerate erosion to the interior of the ramming material along gaps in the using process, and the cost of the raw materials is increased; when the total weight percentage of the silicon carbide powder and the chromium slag powder is 0.3-8%, the optimal range of the service performance is reached, the cost performance is high, and the addition amount of the industrial hazardous waste chromium slag powder is large.

The sodium silicate and the aluminum polyphosphate are used as binding agents, so that the high-temperature resistance, the vibration resistance, the stripping resistance, the high-temperature airflow resistance and the molten iron scouring resistance of the ramming mass are improved, the solidification binding capacity of the ramming mass is high, the materials are convenient and quick to prepare, and the refractory plasticity and the erosion resistance of the ramming mass are improved. When the total weight percentage of the sodium silicate and the aluminum polyphosphate is less than 0.2%, the excellent effect is not obvious, and the using effect is difficult to reach the expected level; when the total weight percentage of the sodium silicate and the aluminum polyphosphate is more than 2 percent, a large amount of low-melting-point substances are easily separated out from the ladle in the using process, so that the slag adhesion phenomenon is serious, and especially, the raw material cost is greatly increased; when the total weight percentage of the sodium silicate and the aluminum polyphosphate is 0.2-2%, the optimal range of the service performance is reached, and the cost performance is higher.

In the aggregate composition, the proportion of silica is 52-57%, the proportion of high-alumina is 20-23%, the combination of the silica and the high-alumina contributes to improving the refractoriness of the ramming mass and the molten iron scouring and erosion resistance, and the ramming layer is not easy to crack in the ladle baking process; the ramming mass prepared under the proportion combination has obvious effect in the using process of the foundry ladle and has the advantage of higher cost performance.

In the powder composition, the clay accounts for 5-10%, the graphite accounts for 5-15%, and the fly ash accounts for 0.1-5%, the proportion combination of the clay, the graphite and the fly ash meets the combination effect of the ramming materials after sintering, the strength, the refractoriness and the molten iron erosion and corrosion resistance of the ramming materials after baking are improved, the generation of internal cracks of the ramming layers is reduced, the processing operation performance of the ramming materials is improved, the slag and molten iron adhesion and reinforcing performance are avoided, gaps caused by aggregates are filled, and the optimal stacking density is achieved; the ramming mass prepared under the proportion combination has obvious effect in the using process of the foundry ladle and has the advantage of higher cost performance.

In the composition of the erosion-resistant agent, the silicon carbide powder is 0.2-5%, the chromium slag powder is 0.1-3%, and the proportion combination of the silicon carbide powder and the chromium slag powder greatly improves the erosion and scouring resistance of the ramming mass to molten iron and slag, reduces the slag adhesion and molten iron adhesion of a ramming layer, and improves the refractoriness and thermal shock resistance of the ramming layer in the using process; the ramming mass prepared under the proportion combination has obvious effect in the process of using a ladle, and has the advantages of high performance-price ratio and capability of changing industrial hazardous waste chromium slag powder which is difficult to dispose into valuable.

In the composition of the binding agent, the sodium silicate is 0.1-1%, the aluminum polyphosphate is 0.1-1%, and the proportion combination of the sodium silicate and the aluminum polyphosphate greatly improves the curing and bonding capacity of the ramming mass, so that the high temperature resistance, vibration resistance, stripping resistance, high temperature airflow resistance and molten iron scouring resistance of the ramming mass are obviously improved, and the fire resistance plasticity of the ramming mass is improved in the processing process; the ramming mass prepared under the proportion combination has obvious effect in the using process of the foundry ladle and has the advantage of higher cost performance.

In the aggregate composition of the invention, the silica particle size distribution is: 16% of 6-7 mm, 17% of 5-6 mm, 17% of 4-5 mm, 24% of 3-4 mm and 26% of 2-3 mm; the high-alumina bauxite has the following particle size distribution: 12% of 4-5 mm, 16% of 3-4 mm, 17.5% of 2-3 mm, 22.5% of 1-2 mm and 32% of 0.38-1 mm; the particle size distribution and the proportion combination of the two are favorable for the interpenetration, occlusion and nailing of particles, can improve the bonding strength, and are favorable for improving the rheological property of the pug, improving the thixotropy, thereby being favorable for improving the volume density and leading the ramming mass to achieve the closest packing; the ramming mass prepared under the proportion combination has obvious effect in the using process of the foundry ladle and has the advantage of higher cost performance.

Firstly, weighing clay, graphite, fly ash, silicon carbide powder and chromium slag powder for premixing, and aiming at promoting the uniform mixing of powder raw materials, especially the powder raw materials with less content; and silica and high-alumina are added for mixing, so that the aggregate and the powder raw material are uniformly mixed, the filling of the aggregate gap is facilitated, the optimal bulk density is achieved, the optimal use performance is convenient to obtain, and in addition, the powder can extrude water in the air holes, so that the water adding amount of the ramming material is reduced.

In the mixing process of the batch, the atomized additive solution is added, so that the sodium silicate binding agent, the aluminum polyphosphate binding agent and other powder raw materials are fully mixed, the powder raw materials with the surface attached with the binding agent are uniformly wrapped on the surface of the aggregate, the bonding strength between the materials can be improved, the rheological property of the mud is improved, the thixotropy is improved, the volume density is improved, and the ramming mass is most closely stacked.

Compared with the prior art, the invention has the following positive effects:

(1) the ramming material is used as the inner lining of the ladle, so that the ladle has higher thermal shock stability, erosion resistance and penetration resistance, and a ramming layer is less in iron-sticking slag and free of cracks and stripping in use;

(2) the ladle leakage accident caused by damage such as loosening and stripping in the using process can be avoided, and the safety of peripheral personnel and equipment in the hoisting process of the ladle is guaranteed;

(3) the phenomenon that molten iron is stuck to the ladle can not occur, the molten iron is prevented from being wrapped in the slag, the recovery rate of the molten iron is improved, and the safety and the economical efficiency are greatly improved.

(4) The inner refractory material of the ladle is divided into two layers, the outer layer belongs to a permanent layer and is not contacted with molten iron, and the inner layer is directly contacted with the molten iron and is periodically replaced, thereby belonging to a ramming material for lining.

(5) The ramming material for the lining has high structural strength in the using process, can not generate loosening, stripping and other damages in the using process to cause a ladle leakage accident, ensures the personal safety and equipment safety of the periphery in the hoisting process of a ladle, can not generate the phenomenon of molten iron sticking, avoids the molten iron from being wrapped in slag, improves the recovery rate of the molten iron, and greatly improves the safety and the economical efficiency.

Drawings

FIG. 1: the ladle structure of the invention is a top view;

the specific meanings of the symbols in the drawings are as follows: 1 is ramming mass, 2 is permanent layer, 3 is shell, 4 is tap hole, 5 is ladle chamber.

The invention will now be further illustrated with reference to the accompanying drawings and examples:

Detailed Description

The compositions of the raw materials in examples 1 to 4 of the present invention are shown in Table 1;

the preparation method of the ramming mass for the ladle lining in the embodiments 1-4 of the invention comprises the following steps:

(1) weighing sodium silicate and aluminum polyphosphate according to the weight percentage, adding 3 times of water according to the weight ratio of 1:3, heating to 50 ℃, and stirring until the sodium silicate and the aluminum polyphosphate are completely dissolved in the water to form an additive solution;

(2) weighing clay, graphite, fly ash, silicon carbide powder and chromium slag powder according to the weight percentage, premixing, adding silica and high-alumina, mixing to form a batch mixture, and atomizing and adding an additive solution in the mixing process;

(3) according to the batch: weighing tap water according to the weight ratio of 9:1, adding the tap water into the batch while stirring for 6 minutes to form a wet-based ramming mass;

(4) and (3) smearing the wet base ramming mass in a die gap on the inner wall of the ladle for ramming operation.

And according to GB/T4513.6-2017 amorphous refractory part 6: the performance parameters in the examples 1-4 of the invention are tested according to the standard of the determination of physical properties and the test method for the normal temperature rupture strength and the compressive strength of the GB 8932.3-1988 compact castable refractory, which are shown in Table 1;

TABLE 1 raw Material composition and Performance parameters

Therefore, the ramming mass for the ladle lining has better performance parameters.

The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, several modifications and decorations can be made without departing from the concept of the present invention, and these modifications and decorations should also be regarded as being within the protection scope of the present invention.