Compatibility evaluation method of tetrazole-based energetic material based on gas product
阅读说明：本技术 一种基于气体产物的四唑类含能材料的相容性评价方法 (Compatibility evaluation method of tetrazole-based energetic material based on gas product ) 是由 赵川德 于谦 彭强 杨芳 范桂娟 于 2019-10-14 设计创作，主要内容包括：本发明公开了一种基于气体产物的四唑类含能材料的相容性评价方法,涉及含能材料分析技术领域。通过考察含能材料在热分解过程中的气体产物与混合含能材料在热分解过程中形成的气体产物的气体量的变化,分析多种含能材料混合后受热分解产生的气体产物的变化,通过不完全燃烧气体、完全燃烧气体和不完全分解气体的含量判断含能材料混合后是否有利于组分的完全分解,利用在线气体分解数据,判断含能材料混合后是否影响每种组份的分解速率；通过比较单独组分与混合组分热分解气体区别,判断炸药混合后是否有利于所含炸药能量释放,最终建立一种基于气体产物评价含能材料相容性的评价方法。(The invention discloses a compatibility evaluation method of a tetrazole-based energetic material based on a gas product, and relates to the technical field of energetic material analysis. The method comprises the steps of analyzing the change of gas products generated by thermal decomposition after various energetic materials are mixed by investigating the change of gas quantity of gas products of the energetic materials in the thermal decomposition process and gas products formed by the mixed energetic materials in the thermal decomposition process, judging whether the energetic materials are mixed to be beneficial to complete decomposition of components or not according to the content of incomplete combustion gas, complete combustion gas and incomplete decomposition gas, and judging whether the decomposition rate of each component is influenced or not after the energetic materials are mixed by utilizing online gas decomposition data; by comparing the difference between the single component and the mixed component of the thermal decomposition gas, whether the mixed explosive is beneficial to the energy release of the contained explosive is judged, and finally, the evaluation method for evaluating the compatibility of the energetic material based on the gas product is established.)
1. A compatibility evaluation method of tetrazole-based energetic material based on gas product is characterized in that the change of gas product generated by thermal decomposition after mixing of multiple energetic materials is analyzed by investigating the change of gas quantity of gas product of energetic material in the thermal decomposition process and gas product formed by mixing energetic materials in the thermal decomposition process, whether the energetic materials are favorable for complete decomposition of components after mixing is judged according to the content of incomplete combustion gas, complete combustion gas and incomplete decomposition gas, and whether the decomposition rate of each component is influenced after mixing of energetic materials is judged by utilizing online gas decomposition data; by comparing the difference between the single component and the mixed component of the thermal decomposition gas, whether the mixed explosive is beneficial to the energy release of the contained explosive is judged, and finally, the evaluation method for evaluating the compatibility of the energetic material based on the gas product is established.
2. The method of claim 1, comprising the steps of:
step 1: weighing a tetrazole energetic material A, an energetic material B and a mixture C of the energetic material A and the energetic material B in equal mass;
step 2: respectively heating the energetic material A, the energetic material B and the mixture C for thermal decomposition, and respectively classifying gases generated by the energetic material A, the energetic material B and the mixture C under the thermal decomposition into a final product gas and an intermediate product gas;
and step 3: respectively carrying out on-line analysis on final product gas and intermediate product gas generated under the thermal decomposition condition by adopting a gas component analyzer;
and 4, step 4: based on the compatibility evaluation standard of the gas product, the specific values are as follows: Δ V is not less than 0, Δ VCxNy<0, good compatibility; Δ V<0,ΔVCxNyNot less than 0, poor compatibility, and Δ V is the difference between the final product gas and the intermediate product gas volume of the thermal decomposition gas after mixing and before mixing the energetic material, i.e. the volume of the gas generated by thermal decomposition of the mixture C and the volume of the intermediate product gasThe difference of the sum of the gas generated by the thermal decomposition of the energetic material A and the gas generated by the thermal decomposition of the energetic material B; Δ VCxNyIs the difference in the intermediate product gas volume of the thermally decomposed gas after mixing and before mixing the energetic material.
3. The method of claim 2, wherein the tetrazole-based energetic material comprises TKX-50 or ABTOX or HMX in step 1.
4. The method of claim 2, wherein in step 2, the final product gas comprises N2、H2、CO2、H2O; the intermediate product gas comprises NO and N2O、CO、CxNy。
5. The method of claim 4, wherein the CO is selected from the group consisting of2、N2O、CxNySeparating with 19091P-QO4LTM chromatographic column, N2NO, CO and H2Mainly adopts CP-MolsieveSeparating with an isochromatograohic column.
6. The method for evaluating the compatibility of tetrazole-based energy-containing material according to claim 2, wherein in step 2, the thermal decomposition is performed by using a sealable gas tank, and the energy-containing material is placed in Al2O3And (3) putting the sample cell into a gas tank, vacuumizing to ensure that the vacuum degree is less than or equal to 0.01Kpa, and heating the gas tank.
7. The method of claim 6, wherein the temperature-rising heating is divided into two modes of slow temperature-rising and fast temperature-rising, the slow temperature-rising is performed by placing the gas tank into a heating table capable of performing temperature-controlled heating, and the heating rate of the heating table is 1-20 ℃/min; the rapid temperature rise is to place the sample tank in a wood's alloy bath, the temperature range of which is between 300 ℃ and 420 ℃.
8. The method for evaluating the compatibility of tetrazole-based energy-containing material of claim 2, wherein in the step 3, the gas composition analyzer is analyzed by TG/DSC-MS or TG/DSC-GC-MS.
Technical Field
The invention relates to the technical field of energetic material analysis, in particular to a compatibility evaluation method of a tetrazole energetic material based on a gas product.
Background
In recent years, the molecular structure of energetic materials is being converted from traditional CHON to high nitrogen and total nitrogen, a series of tetrazole energetic materials with practical application potential, such as TKX-50, consisting of two tetrazole rings, and breaking through the limitation of traditional nitro-explosive groups, and the research and evaluation of the compatibility of the energetic materials with traditional energetic materials and adhesives are necessary contents for formulation design and screening, and have important significance for promoting the practical application of the energetic materials.
The compatibility test of the traditional energetic material is mainly based on the method specified in the national military standard 772A, such as a vacuum stability test method, a 100 ℃ heating method, a TG-DSC method, a micro-heating calorimetry method and the like. These methods are mainly used for evaluating compatibility by using the total amount of outgas (converted from air pressure) under heating conditions after mixing of target materials, and changes in quality and heat as indices. However, these methods only give a measure of compatibility of materials under storage conditions and cannot determine compatibility during energy release, which limits the knowledge of whether mixing two or more energetic materials is more beneficial for energy release.
Disclosure of Invention
The invention aims to provide a method for evaluating compatibility of tetrazole-based energetic material based on gas product, which inspects the gas product of the energetic material at the temperature rise rate and inspects the N formed by the mixed energetic material in the thermal decomposition process2、NO、N2O、H2O、CO、CO2、CxNyAnd H2When the gas quantity changes, the change of gas products generated by thermal decomposition after the mixing of various energetic materials is analyzed, and the gas N is completely combusted through incomplete combustion gas such as CO and NO2、N2O、H2O、CO2Incompletely decomposed gas CxNyJudging whether the energetic material is beneficial to complete decomposition of the components after mixing, and establishing an evaluation method for evaluating the compatibility of the tetrazole energetic material based on the decomposition gas by observing the difference between the mixed energetic detonation gas and the decomposition gas.
In order to achieve the purpose, the invention adopts the following technical scheme:
a compatibility evaluation method of tetrazole-based energetic material based on gas product, by investigating the gas quantity change of gas product formed in the thermal decomposition process of the energetic material and the gas product formed in the thermal decomposition process of the mixed energetic material, analyzing the change of the gas product generated by thermal decomposition after mixing a plurality of energetic materials, judging whether the energetic materials are beneficial to complete decomposition of components after mixing by the content of incomplete combustion gas, complete combustion gas and incomplete decomposition gas, and judging whether the decomposition rate of each component is influenced after mixing the energetic materials by utilizing online gas decomposition data; by comparing the difference between the single component and the mixed component of the thermal decomposition gas, whether the mixed explosive is beneficial to the energy release of the contained explosive is judged, and finally, the evaluation method for evaluating the compatibility of the energetic material based on the gas product is established.
The invention is realized by the following steps:
a method for evaluating the compatibility of tetrazole-based energetic material based on gas products comprises the following steps:
step 1: weighing a tetrazole energetic material A, an energetic material B and a mixture C of the energetic material A and the energetic material B in equal mass;
step 2: respectively heating the energetic material A, the energetic material B and the mixture C for thermal decomposition, and respectively classifying gases generated by the energetic material A, the energetic material B and the mixture C under the thermal decomposition into a final product gas and an intermediate product gas;
and step 3: respectively carrying out on-line analysis on final product gas and intermediate product gas generated under the thermal decomposition condition by adopting a gas component analyzer;
and 4, step 4: based on the compatibility evaluation standard of the gas product, the specific values are as follows: Δ V is not less than 0, Δ VCxNy<0, good compatibility; Δ V<0,ΔVCxNyNot less than 0, the compatibility is poor, and the delta V is the difference value of the volumes of the final product gas and the intermediate product gas of the thermal decomposition gas after the energetic material is mixed and before the mixing, namely the difference value of the volume of the gas generated by the thermal decomposition of the mixture C and the sum of the gas generated by the thermal decomposition of the energetic material A and the gas generated by the thermal decomposition of the energetic material B; Δ VCxNyMixing energetic materials and then mixingDifference in intermediate product gas volume of the thermal decomposition gas before synthesis.
The further technical scheme is that in the step 1, the tetrazole-based energetic material comprises TKX-50, ABTOX or HMX.
The further technical proposal is that in the step 2, the final product gas comprises N2、H2、CO2、H2O; the intermediate product gas comprises NO and N2O、CO、CxNy。
The further technical proposal is that the CO is2、N2O、CxNySeparating with 19091P-QO4LTM chromatographic column, N2NO, CO and H2Mainly adopts CP-Molsieve
The further technical scheme is that in the step 2, the thermal decomposition is carried out by utilizing a sealable gas tank, and the energetic material is placed in Al2O3And (3) putting the sample cell into a gas tank, vacuumizing to ensure that the vacuum degree is less than or equal to 0.01Kpa, and heating the gas tank.
The further technical scheme is that the heating mode comprises a slow heating mode and a fast heating mode, wherein the slow heating mode is that a gas tank is placed in a heating table capable of conducting temperature control heating, and the heating rate of the heating table is 1-20 ℃/min; the rapid temperature rise is to place the sample tank in a wood's alloy bath, the temperature range of which is between 300 ℃ and 420 ℃.
The further technical scheme is that in the step 3, a gas component analyzer is used for analyzing by TG/DSC-MS or TG/DSC-GC-MS.
Compared with the prior art, the invention has the beneficial effects that:
the invention discloses a gas-based tetrazole-based energetic material compatibility evaluation method, which mainly evaluates that tetrazole energetic materials are mutually or other materials in an energy release process by observing the change of total decomposed gas and incomplete decomposed gasWhether the materials are compatible or not is more beneficial to the knowledge of energy release. During the test, the formation of N during thermal decomposition was examined by investigating the energy content of the mixture2、NO、N2O、H2O、CO、CO2、CxNyAnd H2The change of the gas quantity is analyzed, the change of the gas product generated by the thermal decomposition after the mixing of a plurality of energetic materials is analyzed, and the gas C is not completely decomposedxNyThe amount of the explosive and the total amount of other gases, and whether the explosive is beneficial to complete decomposition of the components after mixing is judged; judging whether the decomposition rate of each component is influenced after the energetic materials are mixed by utilizing the online gas decomposition data; by comparing the difference between the single component and the mixed component of the thermal decomposition gas, whether the mixed explosive is beneficial to the energy release of the contained explosive is judged, and finally, the evaluation method for evaluating the compatibility of the energetic material based on the gas product is established.
Detailed Description
The present invention will be further described with reference to the following examples, which are intended to illustrate only some, but not all, of the embodiments of the present invention. Based on the embodiments of the present invention, other embodiments used by those skilled in the art without any creative effort belong to the protection scope of the present invention.
A detection instrument:
TG/DSC-GC-MS: the operating conditions of TG/DSC (thermogravimetry/differential scanning calorimeter) were: helium is used as carrier gas at a flow rate of
The invention discloses a compatibility evaluation method of tetrazole-based energetic materials based on gas, which is mainly used for evaluating whether tetrazole energetic materials are compatible with each other or other materials in an energy release process by observing the change of the total amount of decomposed gas and the amount of incompletely decomposed gas, and is more beneficial to the understanding of energy release. During the test, the formation of N during thermal decomposition was examined by investigating the energy content of the mixture2、NO、N2O、H2O、CO、CO2、CxNyAnd H2The change of the gas quantity is analyzed, the change of the gas product generated by the thermal decomposition after the mixing of a plurality of energetic materials is analyzed, and the gas C is not completely decomposedxNyThe amount of the explosive and the total amount of other gases, and whether the explosive is beneficial to complete decomposition of the components after mixing is judged; judging whether the decomposition rate of each component is influenced after the energetic materials are mixed by utilizing the online gas decomposition data; by comparing the difference between the single component and the mixed component of the thermal decomposition gas, whether the mixed explosive is beneficial to the energy release of the contained explosive is judged, and finally, the evaluation method for evaluating the compatibility of the energetic material based on the gas product is established.