阅读说明：本技术 一种高纯化二氧化氯除味剂 (A kind of High Purity chlorine dioxide eliminating smell agent ) 是由 钟洁龙 洪铭杰 周建兰 于 2019-09-27 设计创作，主要内容包括：本发明公开了一种高效清洁除味凝胶,包括凝胶组合物和激活组合物,所述凝胶组合物包括二氧化氯母体和凝胶剂,所述激活组合物包括激活剂、催化剂和吸水材料；所述凝胶组合物以重量份数计包括：二氧化氯母体5～30份,凝胶剂50～70份；所述激活组合物以重量份数计包括：激活剂5～45份,催化剂1～6份,高吸水材料2～15份。本发明具有除味效果佳；产生的二氧化氯气体纯度高；清洁效果佳；绿色环保,制备成本低等优点。(The invention discloses a kind of high-efficiency cleaning taste removal gels, including gel combination and activation composition, and the gel combination includes chlorine dioxide matrix and gelling agent, and the activation composition includes activator, catalyst and water-absorbent material；The gel combination includes: 5~30 parts of chlorine dioxide matrix, 50~70 parts of gelling agent based on parts by weight；The activation composition includes: 5~45 parts of activator, 1~6 part of catalyst, 2~15 parts of high-absorbent material based on parts by weight.The present invention has taste removal effect good；The chlorine dioxide purity is high of generation；Cleaning effect is good；It is environmentally protective, the advantages such as preparation cost is low.)

1. a kind of High Purity chlorine dioxide eliminating smell agent, which is characterized in that including gel combination and activation composition, the gel Composition includes chlorine dioxide matrix and gelling agent, and the activation composition includes activator, catalyst and water-absorbent material；

The gel combination includes: 5~30 parts of chlorine dioxide matrix, 50~70 parts of gelling agent based on parts by weight；

The activation composition includes: 5~45 parts of activator based on parts by weight, and 1~6 part of catalyst, water-absorbing resin 2~15 Part.

2. High Purity chlorine dioxide eliminating smell agent according to claim 1, which is characterized in that the gel combination is with weight Number meter includes: 20~30 parts of chlorine dioxide matrix, 50~60 parts of gelling agent；

The activation composition includes: 30~40 parts of activator based on parts by weight, and 2~4 parts of catalyst, water-absorbent material 8~13 Part.

3. High Purity chlorine dioxide eliminating smell agent according to claim 2, which is characterized in that the gel combination is with weight Number meter includes: 25 parts of chlorine dioxide matrix, 55 parts of gelling agent；

The activation composition includes: 35 parts of activator, 3 parts of catalyst, 11 parts of water-absorbent material based on parts by weight.

4. High Purity chlorine dioxide eliminating smell agent according to any one of claims 1 to 3, which is characterized in that the titanium dioxide Chlorine parent is sodium chlorate, sodium chlorite one of which or mixture.

5. High Purity chlorine dioxide eliminating smell agent according to any one of claims 1 to 3, which is characterized in that the gelling agent It is one of for vesica hydrogel, nanoporous silica aerogel, aminosal colloid.

6. High Purity chlorine dioxide eliminating smell agent according to any one of claims 1 to 3, which is characterized in that the activator For any one in citric acid, oxalic acid, sodium hypochlorite, sulfamic acid or mixture.

7. High Purity chlorine dioxide eliminating smell agent according to any one of claims 1 to 3, which is characterized in that the catalyst For sodium tetrachloropallate.

8. High Purity chlorine dioxide eliminating smell agent according to any one of claims 1 to 3, which is characterized in that the water-absorption material Material is one of water-absorbing resin, porous ceramics, porous graphite, silica solution, silica.

9. according to High Purity chlorine dioxide eliminating smell agent described in claim 9, which is characterized in that the water-absorbing resin is polypropylene One of Barbiturates, polyvinyl alcohol.

10. High Purity chlorine dioxide eliminating smell agent according to any one of claims 1 to 3, which is characterized in that the activation group It after conjunction object matches mixing in parts by weight, is also mountable in plastic tube, both ends sealing, as activation stick.

Technical field

The present invention relates to eliminating smell agent, specially a kind of High Purity chlorine dioxide eliminating smell agent.

Background technique

The dung urine that formaldehyde, dimethylbenzene and ammonia of interior decoration release etc., refrigerator peculiar smell, domestic pets cause disturbs taste, ring Frequently problem during foul smell generated etc. is polluted for people's lives in border, the toxic odor gas substance discharged is to tight Ghost image rings the health and quality of life of people, and chlorine dioxide has strong oxidizing property, connects with sulfurous pollutants frowzy Oxidation reaction occurs with sulfide rapidly after touch, is changed into other materials, to remove foul smell peculiar smell.Therefore, chlorine dioxide ring Border deodorization, purification air, but the application either solid or liquid form of chlorine dioxide, stability is poor, cannot achieve length Time saves, and the overwhelming majority can only be ready-to-use when using, and effect duration is short, is difficult to maintain three days or more, using not It is convenient, and purity of chlorine dioxide at present on the market is low, containing the chlorate and chlorite being largely harmful to the human body, for a long time It is affected using personnel's health to local environment.

To solve the above problems, there is an urgent need to research and develop a kind of chlorine dioxide purification effect good, good stability, holding time It is long, efficacy lasting and taste removal gel that taste removal effect is good.

Summary of the invention

The present invention provides a kind of High Purity chlorine dioxide eliminating smell agents, solve the purifying of prior art chlorine dioxide eliminating smell agent Degree is low, and stability is poor, and the holding time is short, effect duration short problem.

In order to solve the above technical problems, the invention provides the following technical scheme:

A kind of High Purity chlorine dioxide eliminating smell agent, including gel combination and activation composition, the gel combination include two Chlorine monoxid parent and gelling agent, the activation composition includes activator, catalyst and water-absorbent material；

The gel combination includes: 5~30 parts of chlorine dioxide matrix, 50~70 parts of gelling agent based on parts by weight；

The activation composition includes: 5~45 parts of activator based on parts by weight, and 1~6 part of catalyst, water-absorbent material 2~15 Part.

The present invention is divided into gel combination and activation composition in proportion by that will can react the component for generating chlorine dioxide Packing can avoid generating chlorine dioxide because chemical reaction occurs for the improper excitation each component of preservation condition, when extending the preservation of product Between；Wherein chlorine dioxide matrix is dispersed in gelling agent by gel combination using gelling agent as carrier, with gel group when use Closing object will activate composition to be wrapped in the inside, and the chlorine dioxide matrix reaction in composition and gel combination is activated to generate dioxy Change chlorine and extends the time of effective taste removal since the package action of gel makes chlorine dioxide slow release；By in activation composition The water sorption of water-absorbent material, the chlorine dioxide release for promoting reaction to generate, while the hydrogen chloride generated during adsorption reaction Gas, reducing hydrogen chloride influences the purity of chlorine dioxide, and the chlorate and chlorite that simultaneous reactions generate are attracted to gel It is interior to discharge with chlorine dioxide into environment, realize the purifying to chlorine dioxide, and gel has certain viscosity, it can Stick the surfaces such as furniture, keyboard, automobile instrument panel, increases and use contact area, improve property easy to use.

Further, the gel combination includes: 20~30 parts of chlorine dioxide matrix based on parts by weight, gelling agent 50 ~60 parts；

The activation composition includes: 30~40 parts of activator based on parts by weight, and 2~4 parts of catalyst, water-absorbent material 8~13 Part.The gel combination and activation composition configured according to above-mentioned parts by weight range has the longer holding time, and Since the package action of gelling agent effectively extends chlorine dioxide action time when gel combination and activation composition reaction, activate Water-absorbent material in composition reduces saturated concentration of the chlorine dioxide in gel, releases chlorine dioxide, and effectively Byproduct hydrogen chloride, chlorate and the chlorite that adsorption reaction generates, realize the purifying of chlorine dioxide, obtain high-purity dioxy Change chlorine.

Further, the gel combination includes: 25 parts of chlorine dioxide matrix, 55 parts of gelling agent based on parts by weight；

The activation composition includes: 35 parts of activator, 3 parts of catalyst, 11 parts of water-absorbent material based on parts by weight.According to above-mentioned The gel combination and activation composition that parts by weight configure have longer holding time, and gel combination and activation Since the package action of gelling agent effectively extends its action time when composition reacts, the water-absorbent material in composition is activated to reduce Saturated concentration of the chlorine dioxide in gel, releases chlorine dioxide, and the by-product chlorine of effectively adsorption reaction generation Change hydrogen, chlorate and chlorite, realizes the purifying of chlorine dioxide, obtain chlorine dioxide with high purity.

Further, the chlorine dioxide matrix is sodium chlorate, sodium chlorite one of which or mixture.Sodium chlorate and Asia Sodium chlorate is as chlorine dioxide matrix, and fast reaction generates chlorine dioxide after contacting with activator, shortens the reaction time.

Further, the gelling agent is vesica hydrogel, nanoporous silica aerogel, aminosal colloid wherein one Kind.Wherein the specific preparation process of vesica hydrogel is configuration 4'- p- benzoic acid -2,2':6'2 "-terpyridyl molar concentration For 20~50mmol/L, potassium hydroxide molar concentration be 500~600mmol/L water be easy, by its room temperature with 60~100 turns/ Minute revolving speed stir 4~6 hours, obtain mixed liquor, by mixed liquor be placed in 23~25 DEG C of constant temperature place 5~7 days to get.Capsule Soaked gel, nanoporous silica aerogel and aminosal colloid can will be caused by reactions with solid space structure because of it Chlorine Dioxide Molecules absorption and slow release chlorine dioxide, to prolong its service life；And above-mentioned gel has certain glue Property, it can be directly adhered to the body surface for needing taste removal, increase the area contacted with object, improve taste removal effect, it is also available The dust and spot of its sticky purge body surface.

Further, the activator is citric acid, oxalic acid, sodium hypochlorite, any one in sulfamic acid or mixture. Above-mentioned acidic materials can quickly activate chlorine dioxide matrix reaction to generate chlorine dioxide, and oxalic acid and sulfamic acid can be eliminated less The chlorine generated in the reaction process of amount improves the purity of chlorine dioxide.

Further, the catalyst is sodium tetrachloropallate.Sodium tetrachloropallate effectively improves activator and chlorine dioxide is female The catalytic rate of body realizes quick release chlorine dioxide.

Further, the water-absorbent material is water-absorbing resin, in porous ceramics, porous graphite, silica solution, silica It is a kind of.Above-mentioned water-absorbent material has good absorbent function, by absorbing moisture to reduce chlorine dioxide in aqueous gel Solubility, so that chlorine dioxide be promoted to discharge, and its rate of water absorption can be controlled by controlling the additive amount of water-absorbent material, thus It realizes the rate of release of control chlorine dioxide, while the chlorate and chlorite generated during adsorption reaction, reduces by-product The generation of object improves the purity of chlorine dioxide.

Further, the water-absorbent material is one of polyacrylate, polyvinyl alcohol.Polyacrylate is excellent Select Sodium Polyacrylate, and polyvinyl alcohol preferred degree of polymerization is 1700~1800, polyvinyl alcohol, contain strongly hydrophilic group And the functional high molecule material with certain degree of cross linking can absorb generated chlorate and chlorite in reaction process, subtracts The generation of few by-product, improves the purity of chlorine dioxide.

Further, it after the activation composition matches mixing in parts by weight, is also mountable in plastic tube, both ends envelope Mouthful, as activation stick.Composition will be activated to mix and be placed in plastic tube convenient for the preservation of activation composition, when use only needs to mould One of expects pipe cuts off and is inserted into gel combination, can react generation chlorine dioxide, also can adjust activation stick internal diameter from And activation composition rate of release in activation stick is adjusted, realize controlled-release effect.

Compared with prior art, advantageous effects of the invention:

The first, taste removal effect is good；The present invention is by the chlorine dioxide matrix in setting gel combination and activates sharp in composition The chlorine dioxide that agent reaction living generates, aoxidizes malodorous elements using its strong oxidizing property, taste removal effect is good；

The second, highly purified chlorine dioxide is realized；Activator of the invention selects oxalic acid and sulfamic acid can elimination reaction generation A small amount of chlorine, and water-absorbent material can effecting reaction generate hydrogen chloride, and using its bridging property absorbing reaction process generate Chlorate and chlorite, reduce the generation of by-product, realize highly purified chlorine dioxide, obtain chlorine dioxide with high purity；

Third realizes sustained release taste removal；Chlorine dioxide matrix is dispersed in by gel combination of the invention using gelling agent as carrier In gelling agent, composition will be activated to be wrapped in the inside with gel combination when use, activated in composition and gel combination Chlorine dioxide matrix reaction generates chlorine dioxide, since the package action of gel makes chlorine dioxide slow release, while passing through tune The rate of release of the additive amount control chlorine dioxide of whole water-absorbent material, extends the time of effective taste removal, realizes sustained release taste removal；

4th, shelf stability is good；The present invention is divided into gel combination and swashs by that will can react the component of generation chlorine dioxide Composition living dispenses in proportion, can avoid generating chlorine dioxide because chemical reaction occurs for the improper excitation each component of preservation condition, prolong The holding time of long products；

5th, environmentally protective, preparation cost is low；The equal environmental sound of component used in the present invention, will not remaining influence human health, And be easy purchase and obtain, cheap, preparation cost is low, and process flow is simple, and cost is relatively low, is suitble to large-scale production.

Specific embodiment