阅读说明：本技术 一种钮扣浆料、钮扣及其制备方法 (A kind of button slurry, button and preparation method thereof ) 是由 吴慧群 于 2018-05-22 设计创作，主要内容包括：本发明提供了一种钮扣浆料、钮扣及其制备方法。本发明提供的钮扣浆料,包括A料、B料和C料；以质量分数计,A料包括：0％～70％的不饱和聚酯树脂,30％～100％的树脂废液；以各组分占A料的质量比计,B料包括：0.6％～1.5％的钴盐,0.8％～1.5％的酮类引发剂和4％～8％的第一有机稀释剂；C料包括：阻聚剂和第二有机稀释剂；阻聚剂与第二有机稀释剂的用量比为(30～100)g∶(50～1000mL)；C料与树脂废液的用量比为(12～18)mL∶1kg。采用本发明提供的上述钮扣浆料,能够成功制备钮扣,实现了树脂液废料的再利用,且采用该钮扣浆料所制得钮扣的品质和物理机械性能符合业内标准要求。(The present invention provides a kind of button slurries, button and preparation method thereof.Button slurry provided by the invention, including A material, B material and C material；Based on mass fraction, A material includes: 0%~70% unsaturated polyester resin, 30%~100% resin waste liquid；By each component account for A material mass ratio in terms of, B material include: 0.6%~1.5% cobalt salt, 0.8%~1.5% ketone initiator and 4%~8% the first organic diluent；C material includes: polymerization inhibitor and the second organic diluent；The amount ratio of polymerization inhibitor and the second organic diluent is (30~100) g: (50~1000mL)；The amount ratio of C material and resin waste liquid is (12~18) mL: 1kg.Using above-mentioned button slurry provided by the invention, button can be successfully prepared, realizes the recycling of resin liquid waste material, and standard requirements in the industry are met using the quality and physical mechanical property of button obtained by the button slurry.)

1. a kind of button slurry, which is characterized in that including A material, B material and C material；

Based on mass fraction, the A material includes:

Unsaturated polyester resin 0%~70%；

Resin waste liquid 30%~100%；

In terms of the mass ratio that each component accounts for A material, the B material includes:

Cobalt salt 0.6%~1.5%；

Ketone initiator 0.8%~1.5%；

First organic diluent 4%~8%；

The C material includes: polymerization inhibitor and the second organic diluent；

The amount ratio of the polymerization inhibitor and the second organic diluent is (30~100) g: (50~1000mL)；

The amount ratio of the C material and resin waste liquid is (12~18) mL: 1kg.

2. button slurry according to claim 1, which is characterized in that in C material, polymerization inhibitor is selected from hydroquinone, right Benzoquinones, to one or more of benzene hydroxyanisol, 2- tert-butyl hydroquinone and 2,5 di tert butyl hydroquinone.

3. button slurry according to claim 1, which is characterized in that in B material, cobalt salt is selected from cobalt naphthenate and different pungent One or more of sour cobalt.

4. button slurry according to claim 1, which is characterized in that in the B material, ketone initiator is selected from peroxidating first One or more of ethyl ketone and cyclohexanone peroxide.

5. button slurry according to claim 1, which is characterized in that in the B material, the first organic diluent is selected from benzene second One or more of alkene, α-methylstyrene and methacrylic acid.

6. button slurry according to claim 1, which is characterized in that in the C material, the second organic diluent is selected from benzene second One or more of alkene, α-methylstyrene, methacrylic acid and alcohol.

7. button slurry according to claim 1, which is characterized in that in the A material, the viscosity of unsaturated polyester resin is 0.5~3.0Pa.s.

8. button slurry according to claim 1, which is characterized in that in the A material, resin waste liquid is stick flower button production The liquid resin waste material generated in the process.

9. a kind of button, which is characterized in that be made by button slurry according to any one of claims 1 to 8.

10. a kind of preparation method of button as claimed in claim 9, which comprises the following steps:

A) A is expected to mix with C material, obtains base-material；

B) base-material is mixed with B material, obtains button slurry；

C) by the button slurry shaping forming, button base is obtained；

D) the button base is post-processed, obtains button.

Technical field

The present invention relates to button technical field, in particular to a kind of button slurry, button and preparation method thereof.

Background technique

Harmful substance zero-emission plan is realized since harmful chemicals zero-emission tissue (ZDHC) proposes the year two thousand twenty, Major brand and the retail of the clothes such as Adidas Group, Nike, C&A, Gap Inc, H&M, NB, Burberry and footwear industry Quotient, chemicals used in the raw material process to clothes and shoes industry supply chain are managed, and advocate recyclable material Material recycles, and reduces environmental pollution.

Currently, global resource consumption is huge, if waste and scrap recycling and reusing is advantageously implemented sustainable development Exhibition.Waste and scrap recycles compared with developing Resources, and cost is relatively low, therefore, can be effective by waste and scrap recycling and reusing Solve the wasting of resources and environmental pollution.

Button is a kind of common haberdashery, belongs to the fastener of clothes, is used primarily for the Chinese-style jacket with buttons down the front of connecting clothing, with The progress of living standard is developing progressively in addition to keeping original function as with more artistry and decorative representative. Button is a big auxiliary material of apparel industry, by that will obtain comprising the button slurry shaping forming of unsaturated-resin.It is unsaturated In resin button production process, some offals or waste material will form, it, can if these offals or waste material carry out burning disposal Atmosphere is polluted, landfill disposal can have some impact on soil.In order to effectively solve the wasting of resources and environmental pollution, how by this The problem of a little waste recovery recyclings have become extensive concern in the industry.

Two kinds of waste materials would generally be generated in unsaturated-resin button production process:

One is production offal or waste products, and reproduction button or other techniques can be directly brought by adjusting color Product.Such as the patent application of Publication No. CN105754312A just discloses and a kind of button leftover pieces and defect ware is recycled duplicate removal The method of freshly prepared button, but button particle point made from this kind of recycling and reusing mode is obvious, and compared to the button routinely produced Button, quality and physical property be not good enough, if launching as in a kind of button of particle point effect, market demand is little, cannot By in production process offal and waste product completely consume.

The resin waste liquid that another waste material generates in stick flower button base production process, stick flower button base is cast using resin liquid It forms and obtains, when resin liquid to be cast in aluminum pipe or plastic tube, part resin can be overflowed during exchanging pipe, at For resin waste liquid.This partially liq waste material, if it is useless to will form large volume solid without processing, in the short time (30~60 minutes) Material, recycling cannot be crushed again by being different from former production offal and defect ware, these solid wastes, can only be by burning Burning or landfill disposal, pollute atmosphere and soil.It is every to use 1 ton of resin raw material during producing stick flower button base, it will produce The production of raw 5%~8% resin liquid waste material, big length bar flower button can generate a large amount of resin liquid waste material, if cannot be preferable Processing, can cause larger harm to atmospheric environment and soil.Since the processing time that this resin liquid waste material allows is shorter, and it is difficult With processing, there is no preferable treating methods at present.

Summary of the invention

In view of this, the object of the present invention is to provide a kind of button slurries, button and preparation method thereof.The present invention will The resin liquid waste material and specific components of stick flower button base are arranged in pairs or groups, and obtain the button slurry that can prepare button, it is useless to realize resin liquid The recycling of material, and standard requirements in the industry are met using the quality and physical mechanical property of button obtained by the button slurry, it reaches The comparable level of conventional button is arrived.

The present invention provides a kind of button slurries, including A material, B material and C material；

Based on mass fraction, the A material includes:

Unsaturated polyester resin 0%~70%；

Resin waste liquid 30%~100%；

In terms of the mass ratio that each component accounts for A material, the B material includes:

Cobalt salt 0.6%~1.5%；

Ketone initiator 0.8%~1.5%；

First organic diluent 4%~8%；

The C material includes: polymerization inhibitor and the second organic diluent；

The amount ratio of the polymerization inhibitor and the second organic diluent is (30~100) g: (50~1000mL)；

The amount ratio of the C material and resin waste liquid is (12~18) mL: 1kg.

Preferably, in the C material, polymerization inhibitor is selected from hydroquinone, 1,4-benzoquinone, to benzene hydroxyanisol, 2- tert-butyl pair One or more of benzenediol and 2,5 di tert butyl hydroquinone.

Preferably, in the B material, cobalt salt is selected from one or more of cobalt naphthenate and cobalt iso-octoate.

Preferably, in the B material, ketone initiator is selected from one of methyl ethyl ketone peroxide and cyclohexanone peroxide or several Kind.

Preferably, in the B material, the first organic diluent is in styrene, α-methylstyrene and methacrylic acid One or more.

Preferably, in the C material, the second organic diluent is selected from styrene, α-methylstyrene, methacrylic acid and wine One or more of essence.

Preferably, in the A material, the viscosity of unsaturated polyester resin is 0.5~3.0Pa.s.

Preferably, in the A material, resin waste liquid is the liquid resin waste material generated in stick flower button production process.

The present invention also provides a kind of button, the button slurry as described in above-mentioned technical proposal is made.

The present invention also provides a kind of preparation methods of button described in above-mentioned technical proposal, comprising the following steps:

A) A is expected to mix with C material, obtains base-material；

B) base-material is mixed with B material, obtains button slurry；

C) by the button slurry shaping forming, button base is obtained；

D) the button base is post-processed, obtains button

The present invention provides a kind of button slurries, including A material, B material and C material；Based on mass fraction, the A material includes: 0%~70% unsaturated polyester resin, 30%~100% resin waste liquid；In terms of the mass ratio that each component accounts for A material, the B Material includes: 0.6%~1.5% cobalt salt, 0.8%~1.5% ketone initiator and 4%~8% the first organic diluent； The C material includes: polymerization inhibitor and the second organic diluent；The amount ratio of the polymerization inhibitor and the second organic diluent be (30~ 100) g: (50~1000mL)；The amount ratio of the C material and resin waste liquid is (12~18) mL: 1kg.Using provided by the invention Above-mentioned button slurry, can successfully prepare button, realize the recycling of resin liquid waste material, reduce environmental pollution, and use The quality and physical mechanical property of button obtained by the button slurry meet standard requirements in the industry, and it is comparable to have reached conventional button It is horizontal.

Specific embodiment

The present invention provides a kind of button slurries, including A material, B material and C material；

Based on mass fraction, the A material includes:

Unsaturated polyester resin 0%~70%；

Resin waste liquid 30%~100%；

In terms of the mass ratio that each component accounts for A material, the B material includes:

Cobalt salt 0.6%~1.5%；

Ketone initiator 0.8%~1.5%；

First organic diluent 4%~8%；

The C material includes: polymerization inhibitor and the second organic diluent；

The amount ratio of the C material and resin waste liquid is (12~18) mL: 1kg.

Using above-mentioned button slurry provided by the invention, button can be successfully prepared, realizes the sharp again of resin liquid waste material With, and standard requirements in the industry are met using the quality and physical mechanical property of button obtained by the button slurry, reach routine The comparable level of button.

According to the present invention, button slurry includes A material, B material and C material, wherein A material includes: unsaturated polyester resin and resin Waste liquid.

In the present invention, the type of the unsaturated polyester resin is not particularly limited, and is well known to those skilled in the art The conventional unsaturated polyester resin for preparing button, generally includes m-phthalate unsaturated polyester resin and metaphenylene is unsaturated It is one or more of in polyester resin.In the present invention, the unsaturated polyester resin be preferably viscosity 0.5~3.0Pa.s not Saturated polyester resin is selected in the range of viscosities according to different pattern types.The present invention is to the unsaturated polyester (UP) tree The source of rouge is not particularly limited, and is general commercially available product or is obtained according to preparation method well known to those skilled in the art. In the present invention, the content of unsaturated polyester resin is 0%~70% in A material.

In the present invention, the resin waste liquid is the liquid resin waste material generated in stick flower button base production process.The present invention In, the content of resin waste liquid is 30%~100% in A material, using the resin waste liquid of the ratio, be both able to satisfy button quality and The requirement of physical property, and all kinds of color demands are able to satisfy, it can need accordingly to adjust tree in above-mentioned amount ranges according to color The ratio of rouge waste liquid；The color for the resin waste liquid usually collected is deeper, if the shallower button of color need to be made, can accordingly reduce tree 100% resin waste liquid can be used if saturate button such as black magnetic monochrome button need to be made in the ratio of rouge waste liquid.

According to the present invention, the B material includes: cobalt salt, ketone initiator and the first organic diluent.

In the present invention, the cobalt salt promotes resin to form gel as promotor.In the present invention, the cobalt salt is preferably One or more of cobalt naphthenate and cobalt iso-octoate.The present invention is not particularly limited the source of the cobalt salt, is general city Sell product.In the present invention, the mass ratio of the cobalt salt and A material is 0.6%~1.5%.

In the present invention, the ketone initiator promotes resin solidification molding as curing agent.In the present invention, the ketone Initiator is preferably one or more of methyl ethyl ketone peroxide and cyclohexanone peroxide.The present invention does not have the source of the cobalt salt Have it is specifically limited, be general commercially available product.In the present invention, the ketone initiator and A material mass ratio be 0.8%~ 1.5%.

In the present invention, first organic diluent is to adjust resin viscosity, the mobility of control system.The present invention In, first organic diluent is preferably one or more of styrene, α-methylstyrene and methacrylic acid, more excellent It is selected as styrene.The present invention is not particularly limited the source of first organic diluent, is general commercially available product.This hair In bright, the mass ratio of first organic diluent expected with A is 4%~8%, in the proportional region, is help to obtain The suitable slurry system such as viscosity and mobility and the excellent button of physical mechanical property, if content is lower than 4%, mobility compared with Difference, it is difficult to which machine-shaping easily leads to that button is more crisp and the pulling force characteristic of buttonhole reduces if content is higher than 8%, makes button watch Reveal poor mechanical performance.

According to the present invention, the C material includes: polymerization inhibitor and the second organic diluent.

In the present invention, the polymerization inhibitor is preferably hydroquinone (i.e. HQ), 1,4-benzoquinone (i.e. PBQ), to benzene hydroxyanisol One in (i.e. HQMME), 2- tert-butyl hydroquinone (i.e. MTBHQ) and 2,5 di tert butyl hydroquinone (i.e. 2,5-DTBHQ) Kind is several.The present invention is not particularly limited the source of the polymerization inhibitor, is general commercially available product.

In the present invention, second organic diluent is to dissolve polymerization inhibitor.In the present invention, second organic diluent Preferably one or more of styrene, α-methylstyrene, methacrylic acid and alcohol, more preferably styrene.This hair The bright source to second organic diluent is not particularly limited, and is general commercially available product.

In the present invention, the amount ratio of polymerization inhibitor and the second organic diluent is preferably (30~100) g in C material: (50~ 1000mL)；It in some embodiments, can be 50g: 800mL, 80g:900mL or 100g:1000mL etc..In the present invention, C material Amount ratio with resin waste liquid is that (12~18) mL: 1kg can guarantee that slurry prepares the life of button in the proportional region It produces and carries out, and guarantee the quality of button, be lower than 12mL: 1kg with ratio, then can shorten the pot-life of resin waste liquid, it is difficult into Row subsequent production will affect the subsequent gelatinization of resin waste liquid, curing molding, influence product product if ratio is higher than 18mL: 1kg Matter.In one embodiment, the amount ratio of C material and resin waste liquid is 15mL: 1kg.

In the present invention, pigment can also be added in Xiang Shangshu button slurry according to the demand of button color；It is specific as follows: After collecting resin waste liquid, the color component in resin waste liquid first can be tested with colour photometer, further according to the face in product to be produced Containing the residual quantity of pigment in doses and resin waste liquid, to supplement pigment.

Button slurry provided by the invention includes above-mentioned specific components, and is arranged in pairs or groups with certain proportion, using above-mentioned button Button slurry can successfully prepare button, realize the recycling of resin liquid waste material, reduce environmental pollution, can also save insatiable hunger With the use of resin, cost is substantially reduced, and is met using the quality and physical mechanical property of button obtained by the button slurry Standard requirements in the industry have reached the comparable level of conventional button.

The present invention also provides a kind of button, the button slurry as described in above-mentioned technical proposal is made.Using above-mentioned button Slurry can successfully prepare button, realize the recycling of resin liquid waste material, and the quality and Physical Mechanical of obtained button Standard requirements in the industry can be met.

The present invention also provides a kind of preparation methods of button described in above-mentioned technical proposal, comprising the following steps:

A) A is expected to mix with C material, obtains base-material；

B) base-material is mixed with B material, obtains button slurry；

C) by the button slurry shaping forming, button base is obtained；

D) the button base is post-processed, obtains button.

According to the present invention, first A is expected to mix with C material, obtain base-material.Wherein, A material and C material ingredient and ratio with it is upper It states described in technical solution unanimously, details are not described herein.

The A material can obtain in the following manner: unsaturated polyester resin being mixed with resin waste liquid, obtains A material.This hair It is bright that the mixed mode is not particularly limited, raw material can be mixed, can such as be mixed by stirring.The C Material can obtain in the following manner: polymerization inhibitor being mixed with the second organic diluent, obtains C material.The present invention is to the mixing Mode is not particularly limited, and can mix raw material, can such as be mixed by stirring.After obtaining A material and C material, by A Material is mixed with C material, forms base-material.The mixing periods are preferably stirred continuously, and are uniformly mixed A material with C material.

According to the present invention, after obtaining base-material, the base-material is mixed with B material, obtains button slurry.The present invention is by base-material When being mixed with B material, base-material can successively be mixed with each component in B material.The present invention does not have special limit to the mixed mode System, can mix raw material, can such as be mixed by stirring.If being required supplementation with according to the color demand of button product Pigment can be added in the mixed process in pigment.

According to the present invention, after obtaining button slurry, by the button slurry shaping forming, button base is obtained.The present invention couple The mode of the shaping forming is not particularly limited, and is carried out according to mode well known to those skilled in the art, can such as be passed through The modes shaping forming such as casting or centrifugation.After shaping forming, button base is obtained.

According to the present invention, after obtaining button base, the button base is post-processed, button is obtained.In the present invention, after described Processing solidifies after preferably including.In the present invention, the rear cured temperature is preferably 85~95 DEG C, and the cured time is preferably 30 ~60h.In the present invention, it is also preferable to include cuttings and polishing for the post-processing；Different shaping is manufactured by cutting, is made by polishing Button smooth surface.The present invention is not particularly limited the condition of the cutting and polishing, according to normally producing button in this field The operation of button carries out.

For a further understanding of the present invention, the preferred embodiment of the invention is described below with reference to embodiment, still It should be appreciated that these descriptions are only further explanation the features and advantages of the present invention, rather than to the claims in the present invention Limitation.