阅读说明：本技术 用于以更高热稳定性粘合的水性预处理 (Aqueous pretreatment for bonding with increased thermal stability ) 是由 R·多尼尔 S·福奈拉 于 2018-05-09 设计创作，主要内容包括：本发明涉及水性组合物,所述水性组合物包含：a)至少一种具有至少一个环氧基团和至少一个与Si键合的可水解基团的环氧硅烷,b)至少一种非离子润湿剂,和c1)0.2重量％至2重量％的至少一种具有至少一个巯基和至少一个与Si键合的可水解基团的巯基硅烷,以及足以使所得组合物的pH介于1和6之间的水溶性酸,前提是环氧硅烷以0.2重量％至1重量％的量存在；或c2)以水性组合物的总重量计0.1重量％至1重量％的水溶性有机钛酸酯,以及足以使所得组合物的pH介于8和14之间的水溶性碱,前提是环氧硅烷以0.2重量％至0.5重量％的量存在。根据本发明的组合物可以配制成储存稳定的单组份组合物并且作为增粘剂能够实现具有特别高热稳定性的粘合。(The present invention relates to an aqueous composition comprising: a) at least one epoxy silane having at least one epoxy group and at least one Si-bonded hydrolysable group, b) at least one non-ionic wetting agent, and c1)0.2 to 2 weight percent of at least one mercaptosilane having at least one mercapto group and at least one Si-bonded hydrolysable group, and sufficient water soluble acid to provide a pH of the resulting composition of between 1 and 6, with the proviso that the epoxy silane is present in an amount of 0.2 to 1 weight percent; or c2) from 0.1 to 1% by weight, based on the total weight of the aqueous composition, of a water-soluble organic titanate, and a water-soluble base sufficient to provide a pH of the resulting composition of between 8 and 14, provided that the epoxy silane is present in an amount of from 0.2 to 0.5% by weight. The compositions according to the invention can be formulated as single-component compositions which are stable in storage and as adhesion promoters enable adhesion with particularly high thermal stability.)

1. An aqueous composition comprising

a) At least one epoxy silane having at least one epoxy group and at least one Si-bonded hydrolysable group,

b) At least one non-ionic wetting agent, wherein,

And

c1) From 0.2 to 2 weight percent, based on the total weight of the aqueous composition, of at least one mercaptosilane having at least one mercapto group and at least one Si-bonded hydrolyzable group, and sufficient water soluble acid to provide a pH of the resulting composition of between 1 and 6, provided that the epoxysilane is present in an amount of from 0.2 to 1 weight percent, based on the total weight of the aqueous composition; or

c2) From 0.1 to 1 weight percent, based on the total weight of the aqueous composition, of a water-soluble organotitanate, and a water-soluble base sufficient to provide a pH of the resulting composition of between 8 and 14, provided that the epoxy silane is present in an amount of from 0.2 to 0.5 weight percent, based on the total weight of the aqueous composition.

2. the composition according to claim 1, characterized in that said at least one wetting agent is chosen from the following emulsifiers or surfactants: polyethers, polyether siloxanes, pyrrolidones and modified natural oils.

3. the composition of claim 1 or claim 2, wherein the epoxy silane comprises glycidoxypropyltrimethoxysilane and/or glycidoxypropyltriethoxysilane.

4. Composition according to any one of claims 1 to 3, characterized in that it comprises further organosilanes or oligomers of these organosilanes which have at least one Si-bonded hydrolysable group and which have at least one further functional group selected from the group consisting of primary amino groups, secondary amino groups, hydroxyl groups and isocyanurate groups.

5. The composition according to any one of claims 1 to 4, wherein the composition comprises component c1), and the mercaptosilane comprises mercaptopropyltrimethoxysilane and/or mercaptopropyltriethoxysilane.

6. Composition according to any one of claims 1 to 5, characterized in that it comprises ingredient c1) and in that the acid comprises a carboxylic acid, in particular acetic acid.

7. Composition according to any one of claims 1 to 4, characterized in that it comprises component c2) and in that the organotitanate comprises a tetraalkoxytitanate, in particular 2-propoxy-tris (3, 6-diaza) hexyloxytitanium (IV).

8. composition according to any one of claims 1 to 4 or 7, characterized in that it comprises component c2) and in that the base comprises a compound having at least one tertiary amine group, in particular an N-alkylated guanidine compound.

9. Composition according to any one of claims 1 to 8, characterized in that it is a one-component aqueous composition comprising from 90 to 98% by weight of water, based on the total composition.

10. composition according to any one of claims 1 to 5, characterized in that it comprises water and:

From 0.3 to 1% by weight, based on the total weight of the aqueous composition, of glycidoxypropyltrimethoxysilane,

0.1 to 2% by weight of at least one wetting agent selected from the group consisting of polyethers, polyether siloxanes, pyrrolidones and modified natural oils,

0.3 to 1% by weight, based on the total weight of the aqueous composition, of mercaptopropyltrimethoxysilane,

From 0 wt% to 0.3 wt%, based on the total weight of the aqueous composition, of at least one aminosilane or isocyanuratesilane, and a water-soluble acid sufficient to provide a pH of the resulting composition of between 2.5 and 5.

11. Composition according to any one of claims 1 to 4 or 7, characterized in that it comprises water and:

From 0.2 to 0.4% by weight, based on the total weight of the aqueous composition, of glycidoxypropyltrimethoxysilane,

0.1 to 2.5% by weight of at least one wetting agent selected from polyethers and pyrrolidones,

0.3 to 0.6% by weight of a tetraalkoxytitanate, in particular 2-propoxy-tris (3, 6-diaza) hexyloxytitanium (IV),

0 to 1.5 wt%, based on the total weight of the aqueous composition, of at least one aminosilane, and a water-soluble base sufficient to provide a pH of the resulting composition of between 9 and 11.5.

12. Use of an aqueous composition according to any one of claims 1 to 11 as an adhesion promoter or primer.

13. Use according to claim 12, wherein the substrate to be treated is a glass substrate or a glass ceramic substrate.

14. Use according to claim 12 or 13 for frameless mounting in automotive manufacturing.

15. Use according to any one of claims 12 to 14, with a polyurethane adhesive.

Technical Field

The present invention relates to compositions suitable as adhesion promoter compositions, in particular aqueous one-component or two-component compositions, to a process for the preparation of the compositions and to their use.

Background

Bonding is a widely used bonding technique. However, some substrates (adhesive substrates) can be problematic in bonding because they do not or only insufficiently establish adhesion with certain adhesives, or lose adhesion over time, particularly under demanding environmental conditions. For this reason, tackifier compositions have long been used which are applied to a substrate prior to an adhesive to form an intermediate layer between the substrate and the adhesive to improve adhesion. One particularly important field of application for adhesion promoter compositions is automotive construction, in particular for bonding window panes to vehicle bodies in "frameless installations".

Typically, such compositions are based on organosilanes which are capable of providing a desirable interlayer for the adhesion of glass and other materials. In particular, such adhesion promoter compositions are used as primers and activators, i.e., as primers to improve adhesion. To ensure rapid flashing, such compositions typically contain an inert, volatile solvent. However, the inclusion of an organic solvent is disadvantageous in terms of environmental compatibility and work safety. Aqueous tackifier compositions based on organosilanes and containing water as solvent are known. They have some drawbacks. A problem with silane-based aqueous tackifier compositions is that they either have relatively low storage stability and sufficient reactivity or have insufficient reactivity and sufficient stability. This is because the silanes used have hydrolyzable functional groups which, when mixed with water, hydrolyze to form silanol groups (Si-OH). Such silanol groups are often reactive and spontaneously condense with each other and form high molecular weight condensation products, which lead to insoluble precipitates and impaired function in the tackifier composition.

Additionally, the use of aminosilanes and/or mercaptosilanes in such aqueous tackifier compositions is known. Emulsification of mercaptosilanes or aminosilane-mercaptosilane mixtures in water is particularly difficult because mercaptosilanes are insoluble in water before the hydrolysis of the silane groups. In order to introduce these silanes into water, it is necessary to ensure a completely homogeneous distribution before hydrolysis. In addition, the pH must be adjusted with an acid (e.g., acetic acid) to slow down the condensation that occurs as a subsequent reaction as much as possible. Therefore, the silane and water must be mixed rapidly and uniformly, which requires a special mixing device.

The result is that aqueous tackifier compositions are typically sold as two-component systems (e.g., Sika-100 from Sika Schweiz AG) and require an in-situ mixing process to mix the two components prior to use. Importantly, the two components need to be mixed uniformly very rapidly with vigorous agitation. For this purpose, specially developed devices ("vibrators") are required. After formulation, the storage stability ("pot life") of the mixed finished product does not exceed 30 days.

However, this problem is likely to have been solved by the specific formulations taught in EP 2951244. The aqueous tackifier composition disclosed in this document has excellent storage stability even in the form of a one-component formulation.

However, despite these advances, aqueous organosilane based adhesion promoter compositions still have several drawbacks that limit their application to demanding adhesion. In particular, bonds based on such tackifiers generally have poorer thermal stability than tackifiers based on organic solvents. If used in combination with a specific adhesive, problems may result when the adhesive is exposed to high temperature climates for a long time, since in this case certain substrates, in particular glass, lose stability over time.

disclosure of Invention

It was therefore an object of the present invention to provide aqueous silane-based tackifier compositions having excellent storage stability, so that they can also be sold in the form of one-component aqueous tackifier systems, and can also be mixed more simply without special mixing devices, and furthermore achieve a significantly improved thermal stability of the adhesive bond.

It has now surprisingly been found that storage-stable one-component compositions which enable adhesion with high thermal stability can be prepared by adding at least one mercaptosilane to an aqueous composition comprising an epoxysilane and adjusting the pH of the resulting mixture to the acidic range or by adding at least one organotitanate and adjusting the pH of the resulting mixture to the basic range. Both alternatives unexpectedly lead to the same technical result, so that the aqueous composition can be used in a variety of applications even in the presence of acid-or base-sensitive substrates and/or binders.

Accordingly, the present invention relates to an aqueous composition comprising

a) At least one epoxy silane having at least one epoxy group and at least one Si-bonded hydrolysable group,

b) At least one non-ionic wetting agent, wherein,

And

c1) From 0.2 to 2 weight percent, based on the total weight of the aqueous composition, of at least one mercaptosilane having at least one mercapto group and at least one Si-bonded hydrolyzable group, and sufficient water soluble acid to provide a pH of the resulting composition of between 1 and 6, provided that the epoxysilane is present in an amount of from 0.2 to 1 weight percent, based on the total weight of the aqueous composition;

Or

c2) From 0.1 to 1 weight percent, based on the total weight of the aqueous composition, of a water-soluble organotitanate, and a water-soluble base sufficient to provide a pH of the resulting composition of between 8 and 14, provided that the epoxy silane is present in an amount of from 0.2 to 0.5 weight percent, based on the total weight of the aqueous composition.

It has surprisingly been found that the use of the composition according to the invention and of an adhesive can lead to extremely thermally stable bonds. The resulting bond can be stored at 90 ℃ for several weeks (e.g., 5 weeks) without loss of bond. It has also surprisingly been found that the improved miscibility of the reactive components in water significantly simplifies the mixing process and enables problem-free preparation in standard reactors. The present invention thus enables easier handling since the product can be sold in the form of a one-component system rather than a complex two-component system. The present invention thus meets the need to be able to provide aqueous one-component systems.

The aqueous compositions according to the invention are suitable in general for reactive, invisible adhesive pretreatment of substrates, in particular glass and glass ceramics, or for adhesive pretreatment in the "windowless mount" of automobile construction, in particular in combination with polyurethane adhesives, preferably one-component polyurethane adhesives.

Detailed Description

In the present context, the term "silane" or "organosilane" denotes a compound having on the one hand at least one, usually two or three, hydrolysable group, preferably an alkoxy or acyloxy group bonded directly to the silicon atom via a Si-O-bond, and on the other hand at least one organic group bonded directly to the silicon atom via a Si-C-bond. Such silanes having alkoxy or acyloxy groups are also known to those skilled in the art as organoalkoxysilanes or organoacyloxysilanes.

Silanes have the property of hydrolyzing upon contact with moisture. The organosiloxanes, i.e. organosilicon compounds containing one or more silanol groups (Si-OH-groups), are formed here and the organosiloxanes, i.e. organosilicon compounds containing one or more siloxane groups (Si-O-Si-groups), are formed by subsequent condensation reactions.

"epoxy silane", "amino silane" or "mercapto silane" means an organosilane whose organic group has an epoxy group, an amino group or a mercapto group. Organosilicon compounds having amino, mercapto or epoxy groups are also referred to as "aminosilanes", "mercaptosilanes" or "epoxysilanes".

"Primary aminosilane" means an aminosilane having a primary amino group (i.e., NH 2-group) bonded to one organic group. "secondary aminosilane" means an aminosilane having a secondary amino group (i.e., an NH-group) bonded to two organic groups.

The Si-bonded hydrolysable groups are groups that can be hydrolyzed to silanol groups by hydrolysis, optionally in the presence of a catalyst. The hydrolysis product is a silane, the hydrolysable groups of which have been at least partially hydrolysed, i.e. at least a part of the hydrolysable groups have been replaced by OH-groups.

The condensation product comprises a condensate of two or more such hydrolyzed silanes. These hydrolysis and condensation products of silanes are known to those skilled in the art.

The expression "independently of each other" in this document always means independently of each other in the same molecule, if there are different possibilities.

By "storage stable" or "storable" is meant that a substance or composition can be stored in a suitable container at room temperature for an extended period of time, typically at least 3 months to 6 months and longer, without its application or use properties changing during storage to the extent associated with its use.

The terms "mass" and "weight" are used synonymously herein. "weight percent" (wt%) thus denotes the percentage mass content, in terms of mass (weight) of all compositions or (depending on the context) all molecules, without further indication.

"Room temperature" means a temperature of 23. + -. 2 ℃ and particularly 23 ℃.

All industry standards and specifications mentioned herein represent valid versions at the time of first filing of the application, if not otherwise stated.

The composition according to the invention comprises one or more organosilanes, at least one of which is an epoxysilane. The organosilanes in the composition according to the invention each have at least one Si-bonded hydrolysable group. These hydrolyzable groups may be any conventional hydrolyzable groups, of which alkoxy and acyloxy groups are preferred, and C1-C4-alkoxy groups are particularly preferred. Hydrolysis of the hydrolyzable groups may occur over time after mixing with water. Thus producing a hydrolysate in which at least a portion of the hydrolysable groups are replaced by OH groups. As a subsequent reaction, condensation products can be formed by silanol groups formed in the hydrolysis products. Thus, the organosilanes comprised may also be present in fully hydrolyzed or partially hydrolyzed or even partially condensed form.

the epoxy silane contained in the composition according to the invention has at least one epoxy group and at least one Si-bonded hydrolysable group. The epoxide group is preferably a glycidyloxy group or an epoxycyclohexyl group, in particular a glycidyloxy group.

Preferred epoxy silanes are (epoxyalkoxy) alkyltrialkoxysilanes and 3-glycidoxypropyltrialkoxysilanes. Particularly preferred is gamma-glycidoxypropyltrimethoxysilane. Preferred representatives of these substance classes are beta- (3, 4-epoxycyclohexyl) ethyltrimethoxysilane and beta- (3, 4-epoxycyclohexyl) ethyltriethoxysilane, and also 3-glycidoxypropyltrimethoxysilane and/or 3-glycidoxypropyltriethoxysilane. Particularly preferably, 3-glycidoxypropyltrimethoxysilane and/or 3-glycidoxypropyltriethoxysilane is present in the composition according to the invention.

For the composition, one or more epoxy silanes may be included.

The composition according to the invention also comprises at least one nonionic wetting agent. By "non-ionic wetting agent" is understood all substances which are not present in water predominantly in ionic form and which are capable of reducing the surface tension of water and/or stabilizing emulsions. Including nonionic surfactants, surface active materials, emulsifiers, and the like having these properties.

Suitable nonionic surfactants (so-called Niotensiden) include, for example, ethoxylates, for example ethoxylated addition products of alcohols, for example polyethers, glycol ethers, polyoxyalkylene polyols, amines, fatty acids, fatty acid amides, alkylphenols, ethanolamides, fatty amines, polysiloxanes, polyether siloxanes or fatty acid esters, and also alkyl-or alkylphenyl polyglycol ethers, for example fatty alcohol polyglycol ethers, or fatty acid amides, alkyl glycosides, sugar esters, sorbitan esters, polysorbates or trialkylamine oxides, and also esters and amides of poly (meth) acrylic acid with polyalkylene glycols or aminopolyalkylene glycols, which may be terminated at one end by alkyl groups.

Such surfactants are widely commercially available. Particularly suitable are alkoxylated alcohols, alkoxylated nonionic fluorosurfactants, especially FSO-100, commercially available from ABCR, germany, alkoxylated alcohols or alkoxylated alkylphenols, especially antrarox FM 33, commercially available from Rhodia. Also preferred are alkoxylated fatty alcohols, such as 120 from Cognis. Particular preference is given to using 3037 from Cognis as nonionic wetting agent. Polyethers, in particular short-chain polyethers, such as glycol ethers, having a molar mass of at most 300g/mol, in particular at most 205g/mol, preferably at most 200g/mol, are also very preferred. Preferred polyethers are polypropylene glycol, polyethylene glycol and also triethylene glycol dimethyl ether ("Triglyme"), bis (2-methoxyethyl) ether ("Diglyme"), very particularly preferably 2,5,7, 10-tetraoxyundecane.

suitable emulsifiers also include in particular those selected from the group consisting of pyrrolidone, propionamide and amino alcohol reaction products. Pyrrolidone is a cyclic carboxylic acid amide and propionamide is a linear carboxylic acid amide. The amino alcohol is used as an integral emulsifier in the form of a reaction product with at least a portion of the amino silane and/or mercaptosilane in the composition. Preference is given to using pyrrolidone or aminoalcohol reaction products. Emulsifiers cause better miscibility with water and slow down the condensation reaction after water addition.

Useful pyrrolidones are in particular 2-pyrrolidones. 2-pyrrolidone is a cyclic carboxylic acid amide. Useful pyrrolidones can be 2-pyrrolidones, also known as γ -butyrolactams, or derivatives of 2-pyrrolidones having substituents on at least one of the three methylene ring groups and/or on the nitrogen atom.

suitable substituents on the nitrogen atom are alkyl radicals, for example C1-C12-alkyl radicals, preferably C1-C7-alkyl radicals, particularly preferably C1-C4-alkyl radicals, in particular methyl or ethyl radicals, or cycloalkyl radicals, preferably cyclopentyl and cyclohexyl radicals, in particular cyclohexyl radicals. Suitable substituents on methylene are, for example, alkyl, preferably C1-C4 alkyl, in particular methyl or ethyl.

Preference is given to N-substituted 2-pyrrolidones. They may optionally have a substituent on at least one methylene ring group, but this is not preferred. Examples are N-C1-C12 alkyl-2-pyrrolidones and polyvinylpyrrolidones. Examples of compounds having longer-chain alkyl radicals are 1-octyl-2-pyrrolidone and 1-dodecylpyrrolidone. Particular preference is given to N-C1-C7-alkyl-2-pyrrolidones or N-C1-C6-alkyl-2-pyrrolidones, in particular N-C1-C4-alkyl-2-pyrrolidones and N-cycloalkyl-2-pyrrolidones, for example N-cyclohexyl-2-pyrrolidone. Most preferred are N-methyl-2-pyrrolidone (NMP), N-ethyl-2-pyrrolidone (NEP), especially N-cyclohexyl-2-pyrrolidone (CHP).

Suitable as propionamide are propionamide itself and derivatives of propionamide. An example of a suitable propanamide is a propanamide of the formula

R-C(O)NR

Wherein R6 is a substituted or unsubstituted ethyl group and R7 independently of one another are H or C1-4-alkyl, in particular methyl or ethyl. Preferably, at least one group R7 is C1-4 alkyl, particularly preferably both groups R7 are C1-4 alkyl, of which methyl and ethyl are preferred.

The group R6 may preferably have at least one substituent, preferably exactly one substituent, on the ethyl group. The substituents are preferably located at the end of the ethyl group, i.e.on the C3-atom of the propionamide. Examples of suitable substituents are C1-C4 alkoxy groups, such as methoxy, ethoxy, propoxy and butoxy.

Specific examples are 3-methoxy-N, N-dimethylpropionamide and 3-butoxy-N, N-dimethylpropionamide.

the amino alcohol forming the amino alcohol-reaction product is a compound having at least one amino group and at least one hydroxyl group. The amino alcohol may, for example, have one or two hydroxyl groups, of which one is preferred. The amino alcohol may, for example, have one or two or more amino groups, where the amino groups may, for example, be primary or secondary amino groups.

Examples of aminoalcohols suitable for use as emulsifier precursors for forming the aminoalcohol-reaction product are ethanolamine, diglycolamine, N- (β -aminoethyl) aminoethanol, diethanolamine and N-methyldiethanolamine, with diglycolamine being most preferred. Diethylene glycol amine is also known as 2- (2-aminoethoxy) ethanol.

When at least one amino alcohol reaction product is used as emulsifier, the amino alcohol and at least a part of the epoxy silane and possibly further organosilanes are present in the form of reaction products in which at least a part of the hydrolyzable groups of the at least one epoxy silane and possibly further organosilanes are replaced by aminoalkoxy groups of the amino alcohol.

The reaction product is obtained by transesterification or esterification of at least a portion of the Si-bonded hydrolysable groups of the silane contained in the composition with an amino alcohol.

The degree of transesterification or esterification can be selected within wide limits. All Si-bonded hydrolysable groups in the epoxy silane and other organosilanes that may be included in the composition may also be replaced by aminoalkoxy groups. Preferably, the degree of transesterification or esterification is selected such that the molar ratio of Si-bonded hydrolysable groups and Si-bonded aminoalkoxy groups to Si-bonded aminoalkoxy groups present in the silane, based on the total amount of silane included in the composition, is in the range of 1: 1 to 10: 1, preferably 10: 5 to 10: 2.

For example, when one hydrolyzable group is replaced by one aminoalkoxy group in a silane having three hydrolyzable groups (e.g., methoxy groups), the reaction product contains two hydrolyzable groups and one aminoalkoxy group. The molar ratio of silicon-bonded hydrolysable groups (2) and silicon-bonded aminoalkoxy groups (1) to silicon-bonded aminoalkoxy groups (1) was then 3: 1. Although aminoalkoxy groups are also hydrolyzable groups in principle, they are not considered here.

Obviously, this molar ratio relates to the composition before hydrolysis and/or condensation reactions occur. It is also understood that the composition comprising the reaction product may be a mixture of different compounds, such as unreacted epoxy silane and other organosilanes having one, two or three aminoalkoxy groups that may be included. Therefore, the above molar ratios should be regarded as average values. After the addition of water, hydrolysis products and/or condensation products may additionally be formed.

Furthermore, epoxy silanes and other silanes which may be contained, which have an aminoalkoxy group as a result of transesterification or esterification, are also considered epoxy silanes or other organosilanes which may be contained herein. The methods for preparing the mixture or reaction product are described in further detail below.

In a preferred embodiment, a further emulsifier selected from the group consisting of pyrrolidones and propionamides (preferably pyrrolidones, especially N-cyclohexyl-2-pyrrolidone) is also added to the composition containing the amino alcohol reaction product. In this way, the miscibility of the composition and the storage stability of the resulting aqueous composition can be further improved.

In a preferred embodiment, at least one nonionic wetting agent is included selected from the following emulsifiers or surfactants: polyethers, polyether siloxanes, pyrrolidones and modified natural oils.

In a first preferred main embodiment, the composition according to the invention further comprises from 0.2% to 2% by weight, preferably from 0.25% to 1% by weight, based on the total weight of the aqueous composition, of at least one mercaptosilane having at least one mercapto group and at least one hydrolyzable group bonded to Si, and a water-soluble acid sufficient to give a pH of the resulting composition of between 1 and 6, preferably between 2.5 and 5, with the proviso that the epoxysilane is present in an amount of from 0.2% to 1% by weight, preferably from 0.3% to 0.8% by weight, based on the total weight of the aqueous composition.

The embodiments enable particularly thermally stable bonds, exhibit excellent bonding properties even at room temperature and are particularly suitable for base-sensitive or acid-stable substrates and/or adhesives.

In this embodiment, preference is given to using polyethers as nonionic wetting agents, particular preference being given to using 2,5,7, 10-tetraoxaundecane.

Also particularly preferred as nonionic wetting agents in this embodiment are pyrrolidones, in particular N-cyclohexyl-2-pyrrolidone, and/or polyether-modified siloxanes, in particular BYK-349 from BYK Chemie GmbH, Germany, and/or modified natural oils, in particular 3037 from Cognis, Germany. In this embodiment, preferred amounts of these nonionic wetting agents are from 0.1 to 2.0% by weight of the total composition of pyrrolidone and/or polyether, from 0.1 to 0.5% by weight of the total composition of polyether modified silicone, and from 0.25 to 0.75% by weight of the total composition of modified natural oil.

The mercaptosilane contained in this embodiment having at least one Si-bonded hydrolyzable group is preferably a mercapto-functional organoalkoxysilane, i.e., a mercaptosilane bearing one C1 to C4 alkoxy group on the hydrolyzable silane group. Particularly preferred are mercapto-functional organomethoxysilanes and mercapto-functional organoethoxysilanes. Mercaptosilanes having three alkoxy groups, in particular three methoxy groups, have proven particularly advantageous.

Particularly preferred mercaptosilanes are 3-mercaptopropyltrimethoxysilane and 3-mercaptopropyltriethoxysilane and 3-mercaptopropylmethyldimethoxysilane, in particular 3-mercaptopropyltrimethoxysilane and 3-mercaptopropyltriethoxysilane, particularly preferably 3-mercaptopropyltrimethoxysilane.

However, mercaptosilanes having multiple mercapto groups and/or multiple silane groups may also be used.

In this embodiment, the at least one mercaptosilane is contained in the composition according to the invention in an amount of from 0.2% to 2% by weight, preferably from 0.25% to 1% by weight, particularly preferably from 0.3% to 0.75% by weight, based on the entire composition.

This embodiment of the invention also comprises at least one water soluble acid. In this embodiment, the acid is present in an amount such that the pH of the resulting composition is between 3 and 6, preferably between 2.5 and 5. Without the use of an acid, it is not possible in this embodiment of the invention to obtain a stable composition with acceptable storage stability without showing cloudiness and precipitation. The acid may be organic or inorganic. In one aspect, the organic acid is a carboxylic acid, particularly a carboxylic acid selected from formic acid, acetic acid, propionic acid, trifluoroacetic acid, oxalic acid, malonic acid, succinic acid, maleic acid, fumaric acid, and citric acid, and an amino acid, particularly aspartic acid and glutamic acid. Preferred as carboxylic acid is acetic acid.

On the other hand, the organic acids are particularly those containing a sulfur atom or a phosphorus atom. Such organic acids are in particular organic sulfonic acids. By organic sulfonic acid is understood a compound having an organic group containing carbon atoms and at least one functional group-SO 3H. Aromatic sulfonic acids are preferred.

The aromatic sulfonic acid may be monocyclic or polycyclic and one or more sulfo groups may be present. For example, it may be 1-or 2-naphthalenesulfonic acid, 1, 5-naphthalenedisulfonic acid, benzenesulfonic acid or alkylbenzenesulfonic acid.

The acid may also be an inorganic acid. Suitable as mineral acids are, for example, those having sulfur or phosphorus atoms. Suitable acids having phosphorus atoms are, in particular, phosphoric acid, phosphorous acid, phosphonic acid, phosphonous acid. Particularly suitable as acids having a sulfur atom are sulfur-containing acids, in particular sulfuric acid, sulfurous acid, persulfuric acid, disulfuric acid (═ pyrosulfuric acid), pyrosulfurous acid, dithionic acid, dithionous acid, thiosulfuric acid or thiosulfurous acid.

Acids with pKa between 4.0 and 5 are preferred. Chemists know to understand pKa as meaning the negative base ten logarithm of the acid dissociation constant Ka: pKa-log 10 Ka.

The usual amount of acid used to adjust the pH to the desired range will of course depend on the acid used and its concentration. Suitable amounts for the carboxylic acid, in particular acetic acid, are typically between 0.15 and 2.5% by weight, based on the total composition.

In a second preferred main embodiment, the composition according to the invention further comprises from 0.1 to 1% by weight, preferably from 0.3 to 0.6% by weight, based on the total weight of the aqueous composition, of a water-soluble organic titanate, and a water-soluble base sufficient to bring the pH of the resulting composition between 8 and 14, preferably between 9 and 11.5, with the proviso that the epoxysilane is present in an amount of from 0.2 to 0.5% by weight, preferably from 0.2 to 0.4% by weight, based on the total weight of the aqueous composition.

The embodiments enable particularly thermally stable bonds, exhibit excellent bonding properties even at room temperature and are particularly suitable for acid-sensitive or alkali-stable substrates and/or adhesives.

In this embodiment, preference is given to using polyethers as nonionic wetting agents, particular preference being given to using 2,5,7, 10-tetraoxaundecane.

Also particularly preferred as nonionic wetting agents in this embodiment are pyrrolidones, in particular N-cyclohexyl-2-pyrrolidone. In this embodiment, the preferred amount of these nonionic wetting agents is from 1.0 to 3.0 weight percent pyrrolidone and/or polyether based on the total composition.

This embodiment comprises from 0.3 to 0.6% by weight of a water-soluble organic titanate as a first additional ingredient, based on the total weight of the aqueous composition. Suitable water-soluble organotitanates are preferably those of the formula ti (or)4, i.e. comprising substituents bonded via oxygen-titanium-bonds, which also include chelating substituents (polydentate ligands). Particularly suitable as substituents bonded to the titanium atom via an oxygen-titanium bond are those selected from the group consisting of alkoxy groups, sulfonate groups, carboxylate groups, dialkyl phosphate groups, dialkyl pyrophosphate groups and acetylacetonate groups.

Particularly suitable compounds are those in which all substituents bonded to the titanium are selected from the group consisting of alkoxy groups, sulfonate groups, carboxylate groups, dialkyl phosphate groups, dialkyl pyrophosphate groups and acetylacetonate groups, where all substituents may be identical to or different from one another.

methoxy, ethoxy, propoxy, isopropoxy, butoxy and isobutoxy substituents have proven particularly suitable as alkoxy groups.

Suitable organotitanium compounds are commercially available, for example from Kenrich Petrochemicals or DuPont. Examples of suitable organotitanium compounds are, for example, KR TTS, KR 7, KR 9S, KR, KR 26S, KR DS, KR 38S, KR DS, KR44, KR 134S, KR 138S, KR FS, KR212, KR 238S, KR ES, KR 138D, KR 158D, KR T, KR 238M, KR A, KR238J, KR262A, LICA 38J, KR, KR 55, LICA 01, LICA 09, LICA 12, LICA 38, LICA 44, LICA 97, LICA 99, KR OPPR, KR OPP2 or ET, TPT, NPT, BTM, AA-75, AA-95, AA-105, TE, ETAM, OGT from Kenrich Petrochemicals.

KR 7, KR 9S, KR 12, KR 26S, KR 38S, KR44, LICA 09, LICA 44, NZ 44, and ET, TPT, NPT, BTM, AA-75, AA-95, AA-105, TE, ETAM from DuPont are preferably suitable.

particular preference is given to organotitanium compounds having substituents of the formulae (II) and/or (III) bonded to the titanium atom via an oxygen-titanium bond.

Most preferred as the organotitanate is 2-propoxy (Popanolato) -tris (3, 6-diaza) hexyloxy (hexanolato) titanium (IV) available under the trade name KR 44.

this embodiment of the invention also comprises at least one water-soluble base. In this embodiment, the base is present in an amount such that the pH of the resulting composition is between 8 and 14, preferably 9 and 11.5. The base may be organic or inorganic. In one aspect, the organic bases are amines, particularly tertiary amines, and amidines and guanidines, which may also have a monocyclic or polycyclic structure.

Suitable amines are in particular alkylamines, cycloalkylamines or aralkylamines, for example triethylamine, triisopropylamine and other such water-soluble amines.

suitable biguanides are in particular biguanides, 1-butylbiguanides, 1-dimethylbiguanides, 1-butylbiguanides, 1-phenylbiguanides or 1- (o-tolyl) biguanides (OTBG).

Suitable amidines are in particular 1, 8-diazabicyclo [5.4.0] undec-7-ene (DBU), 1, 5-diazabicyclo [4.3.0] non-5-ene (DBN), 6-dibutylamino-1, 8-diazabicyclo [5.4.0] undec-7-ene, N' -di-N-hexylacetamidine (DHA), 2-methyl-1, 4,5, 6-tetrahydropyrimidine, 1, 2-dimethyl-1, 4,5, 6-tetrahydropyrimidine, 2,5, 5-trimethyl-1, 4,5, 6-tetrahydropyrimidine, N- (3-trimethoxysilylpropyl) -4, 5-dihydroimidazole or N- (3-triethoxysilylpropyl) -4, 5-dihydroimidazole.

Suitable guanidines are, in particular, 1-butylguanidine, 1-dimethylguanidine, 1, 3-dimethylguanidine, 1,3, 3-Tetramethylguanidine (TMG), 2- (3- (trimethoxysilyl) propyl) -1,1,3, 3-tetramethylguanidine, 2- (3- (methyldimethoxysilyl) propyl) -1,1,3, 3-tetramethylguanidine, 2- (3- (triethoxysilyl) propyl) -1,1,3, 3-tetramethylguanidine, 1,5, 7-triazabicyclo [4.4.0] dec-5-ene (TBD), 7-methyl-1, 5, 7-triazabicyclo [4.4.0] dec-5-ene, 7-cyclohexyl-1, 5, 7-triazabicyclo [4.4.0] dec-5-ene, 1-phenylguanidine, 1- (o-tolyl) guanidine (OTG), 1, 3-diphenylguanidine, 1, 3-di (o-tolyl) guanidine, or 2-guanidinobenzimidazole.

suitable inorganic bases are in particular hydroxides, for example sodium hydroxide or potassium hydroxide.

The base is preferably a compound having at least one tertiary amine group, in particular an N-alkylated guanidine compound. Tetramethyl guanidine is particularly preferred.

The usual amount of base used to adjust the pH to the desired range will of course depend on the base used and its concentration. For N-alkylated guanidine compounds, particularly tetramethylguanidine, suitable amounts are generally between 0.25 and 0.55 weight percent, based on the total composition.

All embodiments of the composition according to the invention optionally but preferably comprise further organosilanes. In particular, the compositions according to the invention comprise further organosilanes or oligomers of these organosilanes which have at least one Si-bonded hydrolysable group and which have at least one further functional group selected from primary amino groups, secondary amino groups, hydroxyl groups and isocyanurate groups.

Particularly suitable as further organosilanes are organosilicon compounds of the formula (I) or (II) or (III)

R1 denotes here a linear or branched, optionally cyclic, alkylene radical having from 1 to 20 carbon atoms, optionally having aromatic moieties and optionally having one or more heteroatoms, in particular nitrogen atoms.

R2 here denotes H or an alkyl radical having 1 to 5 carbon atoms, in particular a methyl or ethyl radical, or an acyl radical, in particular an acetyl radical.

R3 denotes here an alkyl radical having 1 to 8 carbon atoms, in particular methyl.

X here represents H or a functional group selected from OH, (meth) propionyloxy, amine, acylthio and vinyl (preferably amine). For the sake of completeness, thioacyl is herein understood as a substituent wherein R4 represents an alkyl group, in particular an alkyl group having 1 to 20 carbon atoms, and the dashed line represents a bond to the substituent R1.

X1 herein represents a functional group selected from NH, S2 and S4.

X2 herein represents a functional group selected from N and isocyanurate.

a here denotes the value 0,1 or 2, preferably 0.

The substituent R1 denotes in particular methylene, propylene, methylpropylene, butylene or dimethylbutylene. Particularly preferred as substituent R1 is propylene.

Suitable as organosilicon compounds of the formula (I) are, for example, organosilicon compounds selected from the group consisting of: octyltrimethoxysilane, dodecyltrimethoxysilane, hexadecyltrimethoxysilane, methyl-octyldimethoxysilane; 3-methacryloxypropyltrialkoxysilane, 3-methacryloxypropyltriethoxysilane, 3-methacryloxypropyltrimethoxysilane; 3-aminopropyltrimethoxysilane, 3-aminopropyltriethoxysilane, 3-aminopropyl-dimethoxymethylsilane, 3-amino-2-methylpropyl-trimethoxysilane, N- (2-aminoethyl) -3-aminopropyl-triethoxysilane, N- (2-aminoethyl) -3-aminopropyl-dimethoxymethylsilane, 4-aminobutyltrimethoxysilane, 4-aminobutyl-dimethoxymethylsilane, 4-amino-3-methylbutyl-trimethoxysilane, 4-amino-3, 3-dimethylbutyl-trimethoxysilane, 4-amino-3, 3-dimethylbutyl-dimethoxymethylsilane, [3- (2-aminoethylamino) propyl ] trimethoxysilane (═ 4,7, 10-triazadecyl-trimethoxysilane), 2-aminoethyl-trimethoxysilane, 2-aminoethyl-dimethoxymethylsilane, aminomethyl-trimethoxysilane, aminomethyl-dimethoxymethylsilane, aminomethyl-methoxydimethylsilane, 7-amino-4-oxaheptyldimethoxymethylsilane, N- (methyl) -3-aminopropyltrimethoxysilane, N- (N-butyl) -3-aminopropyltrimethoxysilane; 3-acylthiopropyltrimethoxysilane; vinyltrimethoxysilane and vinyltriethoxysilane.

Preference is also given to the just-mentioned organosilicon compounds whose alkoxy groups are replaced by acetoxy groups, for example octyltriacetoxysilane (octyl-Si (O (C) CH3) 3). Such organosilicon compounds eliminate acetic acid upon hydrolysis.

Preferred for the organosilicon compounds mentioned are those having an organic substituent bonded to the silicon atom, which also has a functional group other than an alkyl group and corresponds to formula (I) in which X is other than H.

Suitable as organosilicon compounds of the formula (II) are, for example, organosilicon compounds selected from bis- [3- (trimethoxysilyl) -propyl ] -amine, bis- [3- (triethoxysilyl) -propyl ] -amine, 4,15, 15-tetraethoxy-3, 16-dioxa-8, 9,10, 11-tetrasulfane-4-15-disiloxaoctadecane (bis (triethoxysilylpropyl) polysulfide or bis (triethoxysilylpropyl) tetrasulfane), bis (triethoxysilylpropyl) disulfide.

Suitable as organosilicon compounds of the formula (III) are, for example, those selected from the group consisting of tris- [3- (trimethoxysilyl) -propyl ] -amine, tris- [3- (triethoxysilyl) -propyl ] -amine, 1,3, 5-tris- [3- (trimethoxysilyl) -propyl ] -1,3, 5-triazine-2, 4,6(1H,3H,5H) -triketourea (═ tris- (3- (trimethoxysilyl) propyl) isocyanurate) and 1,3, 5-tris [3- (triethoxysilyl) propyl ] -1,3, 5-triazine-2, 4,6(1H,3H,5H) -triketourea (═ tris (3- (triethoxysilyl) propyl) isocyanurate).

Optionally, the composition may further comprise at least one tetraalkoxysilane of formula (IV)

Si(OR)(IV)

Wherein R4 independently of one another denote alkyl having 1 to 4 carbon atoms or denote acyl, in particular acetyl. Examples of such tetraalkoxysilanes are tetramethoxysilane, tetraethoxysilane, tetraisopropoxysilane, tetrapropoxysilane, tetrabutoxysilane and tetraacetoxysilane. Tetraethoxysilane is particularly preferred. Like aminosilanes and mercaptosilanes, tetraalkoxysilanes can be hydrolyzed in the presence of water and optionally condensed with other silanes.

preferred further organosilanes are aminosilanes, in particular aminosilanes of X ═ NH2 or NH2 — CH2 — CH2 — NH, X1 ═ NH and X2 ═ N.

Particularly preferred are 3-aminopropyltrimethoxysilane, N- (2-aminoethyl) -3-aminopropyltrimethoxysilane, bis [3- (trimethoxysilyl) -propyl ] -amine, 3-aminopropyltriethoxysilane, N- (2-aminoethyl) -3-aminopropyltriethoxysilane and bis [3- (triethoxysilyl) -propyl ] -amine and mixtures thereof with one another.

Suitable aminosilanes are in particular those selected from the group consisting of: 3-aminopropyl-trimethoxysilane, 3-aminopropyl-dimethoxymethylsilane, 3-amino-2-methylpropyl-trimethoxysilane, 4-aminobutyl-dimethoxymethylsilane, 4-amino-3-methylbutyl-trimethoxysilane, 4-amino-3, 3-dimethylbutyl-dimethoxymethylsilane, 2-aminoethyl-trimethoxysilane, 2-aminoethyl-dimethoxymethylsilane, aminomethyl-trimethoxysilane, aminomethyl-dimethoxymethylsilane, Aminomethyl methoxydimethylsilane, N-methyl-3-aminopropyl-trimethoxysilane, N-ethyl-3-aminopropyl-trimethoxysilane, N-butyl-3-aminopropyl-trimethoxysilane, N-cyclohexyl-3-aminopropyl-trimethoxysilane, N-phenyl-3-aminopropyl-trimethoxysilane, N-methyl-3-amino-2-methylpropyl-trimethoxysilane, N-ethyl-3-aminopropyl-dimethoxy-methylsilane, N-phenyl-4-aminobutyl-trimethoxysilane, N-methyl-3-aminopropyl-trimethoxysilane, N-ethyl-3-aminopropyl-dimethoxy-methylsilane, N-methyl-3-aminopropyl-trimethoxysilane, N-methyl, N-phenyl-aminomethyl-dimethoxymethylsilane, N-cyclohexyl-aminomethyl-dimethoxymethylsilane, N-methyl-aminomethyl-dimethoxymethylsilane, N-ethyl-aminomethyl-dimethoxymethylsilane, N-propyl-aminomethyl-dimethoxymethylsilane, N-butyl-aminomethyl-dimethoxymethylsilane; n- (2-aminoethyl) -3-aminopropyl-trimethoxysilane, 3- [2- (2-aminoethylamino) -ethylamino ] -propyl-trimethoxysilane, bis (trimethoxysilylpropyl) amine and its analogs having three ethoxy or three isopropoxy groups on silicon instead of three methoxy groups.

In one embodiment, the aminosilane of formula (I) is an aminosilane of formula (V)

HN-R-Si(OR)(R) (V)

Wherein R5 represents a linear or branched alkylene group having 1 to 6 carbon atoms, in particular propylene, and the other substituents and indices are as defined for formula (I). 3-aminopropyltrimethoxysilane is particularly preferred here.

In a preferred embodiment, the aminosilanes of the formula (I) have secondary amino groups, in particular aminosilanes of the formulae (VI) or (VII) or (VIII).

Wherein R5 represents a linear or branched alkylene group having 1 to 6 carbon atoms, in particular propylene, and the other substituents and indices are as defined for formula (I). It has been found that N- (2-aminoethyl) -3-aminopropyl-trimethoxysilane, 3- [2- (2-aminoethylamino) -ethylamino ] -propyl-trimethoxysilane and bis (trimethoxysilylpropyl) amine are particularly preferred.

It has proven particularly advantageous for two or more aminosilanes of the formula (I) to be present in the composition, of which preferably at least one is an aminosilane of the formula (VI). A particularly preferred combination in the composition is an aminosilane of formula (VI) and an aminosilane of formula (VIII).

All compositions according to the invention are aqueous, i.e. the composition further comprises water.

the composition according to the invention is in particular a one-component aqueous composition comprising from 90 to 98% by weight of water, based on the total composition. In the case of a multicomponent composition, water is preferably included in an amount of 90 to 98% by weight of the total composition after all components have been mixed.

A particularly preferred first main embodiment of the composition according to the invention comprises water, and:

From 0.3 to 1% by weight, based on the total weight of the aqueous composition, of glycidoxypropyltrimethoxysilane,

0.1 to 2% by weight of at least one wetting agent selected from the group consisting of polyethers, polyether siloxanes, pyrrolidones and modified natural oils,

0.3 to 1% by weight, based on the total weight of the aqueous composition, of mercaptopropyltrimethoxysilane,

From 0 wt% to 0.3 wt%, based on the total weight of the aqueous composition, of at least one aminosilane or isocyanuratesilane, and a water-soluble acid sufficient to provide a pH of the resulting composition of between 2.5 and 5.

A particularly preferred first main embodiment of the composition according to the invention comprises water, and:

From 0.2 to 0.4% by weight, based on the total weight of the aqueous composition, of glycidoxypropyltrimethoxysilane,

0.1 to 2.5% by weight of at least one wetting agent selected from polyethers and pyrrolidones,

0.3 to 0.6% by weight of a tetraalkoxytitanate, in particular 2-propoxy-tris (3, 6-diaza) hexyloxytitanium (IV),

0 to 1.5 wt.%, based on the total weight of the aqueous composition, of at least one aminosilane, and a water-soluble base sufficient to provide a pH of the resulting composition of between 9 and 11.5.

The one-or multi-component compositions may comprise other optional ingredients. Such additional ingredients are, for example, anionic, cationic or amphoteric surfactants, adhesion promoter additives, catalysts, cosolvents, biocides, antisettling agents, stabilizers, inhibitors, pigments, dyes, preservatives, odorants, UV indicators, thixotropic agents, fillers, defoamers and other additives known to the person skilled in the art of aqueous adhesion promoter compositions.

For example, ionic or amphoteric surfactants are possible additional components of the one-component or two-component aqueous tackifier compositions. As such a surfactant, a natural substance or a synthetic substance that reduces the surface tension of water or other liquid in a solution can be used. As surfactants (also referred to as wetting agents) anionic, cationic or amphoteric surfactants or mixtures thereof can be used.

examples of anionic surfactants are surfactants having a carboxylate, sulfate, phosphate or sulfonate group, such as amino acid derivatives, fatty alcohol ether sulfates, fatty alcohol sulfates, soaps, alkylphenol ethoxylates, fatty alcohol ethoxylates, and alkanesulfonates, alkene sulfonates or alkylphosphates.

Examples of cationic surfactants are quaternary ammonium compounds or phosphonium compounds, such as tetraalkylammonium salts, N-dialkylimidazoline compounds, dimethyldistearoyl-ammonium compounds or N-alkylpyridine compounds, in particular ammonium chloride. Amphoteric or ampholytic surfactants include ampholytes known as ampholytes, such as aminocarboxylic acids and betaines.

Another optional ingredient preferably used is a water-soluble adhesion promoter additive, preferably a water-soluble amine-containing adhesion promoter additive. Adhesion performance is generally improved by the use of water soluble tackifier additives. Water soluble tackifier additives are commercially available.

Examples of suitable water-soluble tackifier additives are reactive organofunctional siloxane-oligomers. Examples are condensed aminosiloxanes and/or phenylsiloxanes. The degree of condensation of the siloxane may vary. It may be a dimer, trimer or oligomer composed of four or more monomeric silanes or mixtures thereof. Such siloxanes, in particular aminosilicones, are also commercially available, for example HDYROSIL 2627, HDYROSIL 2776 or HDYROSIL 2929 from Degussa AG, Germany.

By co-solvent is understood a solvent which is miscible with water, such as alcohols or ethers or ketones. Preferably, however, such solvents are used in only small amounts (i.e. typically less than 10% by weight based on water). It is particularly preferred that the aqueous composition be free of such co-solvents except for trace amounts of alcohol resulting from hydrolysis of the alkoxysilane used in the composition. The VOC-problem is rather exacerbated if more amounts of solvent are used, and avoidance of VOC-problem is of course a major reason for the use of aqueous compositions.

The composition may be a one-component or two-component aqueous tackifier composition, with one-component aqueous tackifier compositions being particularly preferred.

For the preferred one-component aqueous tackifier compositions, the above-described silanes, wetting agents and water are contained in the sole component. The two-component aqueous tackifier composition consists of a silane component a (also referred to as silane premix) comprising the above-mentioned silanes and optionally a wetting agent and an aqueous component B (also referred to as aqueous premix) comprising water. The one-component aqueous tackifier composition is characterized by excellent storage stability.

When water is added to a composition containing the silane, the silane will hydrolyze and/or condense over time, typically within minutes. The composition may then comprise, in addition to the silanes contained therein, hydrolysis and/or condensation products of these silanes, or as the reaction progresses, may comprise only hydrolysis and/or condensation products of the contained silanes as described above.

Preferred one-component aqueous compositions are preferably prepared as follows. The water is first pre-set and additional ingredients, such as at least one wetting agent, and other ingredients according to embodiments, are added to the water, preferably with agitation. The addition is suitably carried out at room temperature; if appropriate, the stirring process can also be carried out at elevated temperature.

The additional ingredients are preferably added sequentially and preferably stirred for a sufficient period of time until the ingredients are dissolved in water or uniformly distributed before the next ingredient is added. The order of addition of the possible additional ingredients is arbitrary.

Stirring is suitably carried out for a certain period of time to obtain a homogeneous mixture.

The one-or two-component aqueous compositions according to the invention are particularly suitable as adhesion promoters or primers, preferably as primers for adhesives and sealants. Adhesion is improved by the use of such primers.

As binder, in principle any binder can be used. In particular in the case of polyurethane adhesives, in particular polyurethane adhesives containing polyurethane prepolymers having isocyanate groups, favorable adhesion improvements are shown. Such polyurethane adhesives are widely commercially available, for example the aqueous compositions according to the invention from Sika Schweiz AG are particularly suitable for use in 1K polyurethane adhesives.

Thus, suitable methods for bonding or sealing two or more substrates are: the aqueous tackifier composition according to the present invention is applied to at least one substrate in a pre-treated manner and flashed off. Subsequently, the substrates are bonded or sealed with an adhesive or sealant (preferably a 1K polyurethane-adhesive).

The tackifier composition may be used in various ways. In a particularly preferred embodiment, it is a primer or adhesion promoter primer.

In another aspect, the present invention relates to a method for bonding or sealing. The method comprises the following steps:

i) Application of the adhesion promoter composition as described above to the substrate S1 to be bonded or sealed

ii) applying an adhesive or sealant to the composition present on the substrate S1

iii) contacting the adhesive or sealant with a second substrate S2;

Or

i') applying the tackifier composition as described above to the substrate S1 to be bonded or sealed

ii') applying an adhesive or sealant to the surface of the second substrate S2

iii') contacting the adhesive or sealant with the composition present on the substrate S1;

Or

i') applying the tackifier composition as described above to the substrate S1 to be bonded or sealed

ii ") applying an adhesive or sealant between the surfaces of the substrates S1 and S2.

The second substrate S2 here consists of the same or different material as the substrate S1.

Typically, step iii), iii') or ii ") is followed by step iv) of curing the adhesive or sealant.

as the adhesive or sealant, basically any adhesive or sealant can be used. The choice depends inter alia on the open time and the mechanical requirements for the bond formed. It has been found that the process is particularly suitable for polyurethane adhesives or sealants, in particular polyurethane adhesives comprising at least one polyurethane prepolymer having isocyanate groups.

such polyurethane adhesives cure under the influence of atmospheric moisture by crosslinking reactions of isocyanate groups and are widely commercially available, in particular under the name from Sika Schweiz AG

before steps ii), ii') or ii "), a step of wiping with a dry cloth (often referred to in specialist jargon as" wiping off ") may be carried out. Application, often by means of a wet cloth or similar method, is referred to as "rubbing on". Accordingly, the combination of application and wiping is referred to as "rub-on/rub-off.

For application of the adhesive or sealant, one may wait until the tackifier composition flashes off. Surprisingly, however, it has been found that in most cases it is also possible to apply the adhesive or sealant directly to a still moist film of the tackifier composition, i.e. "wet on wet", without causing significant disadvantages in terms of adhesion or mechanics of the cured sealant or adhesive.

the substrate S1 may be the same as or different from the substrate S2.

Suitable substrates S1 or S2 are, for example, inorganic substrates such as glass, glass ceramics, concrete, mortar, bricks, tiles, plaster and natural stone, for example granite or marble; metals or alloys such as aluminum, steel, non-ferrous metals, precious metals such as silver, galvanized metals; organic substrates such as wood, plastics such as PVC, polycarbonate, PMMA, polyester, epoxy; coated substrates such as powder coated metals or alloys; and dyes and lacquers. Particularly preferred as substrates S1 or S2 are glass, glass ceramic, screen printing or silver printing on glass or glass ceramic, aluminum and lacquers, in particular in the form of automotive lacquers.

the substrate may be pretreated if desired before application of the adhesive or sealant material. Such pre-treatments include, inter alia, physical and/or chemical cleaning methods, such as sanding, sandblasting, carding, etc., or treatment with a cleaning agent or solvent, or application of adhesion promoters, adhesion promoter solutions or primers.

Articles are produced by this method of bonding or sealing. The properties of the product may also be varied, since the method can be used widely, for example for industrial manufacture or underground or above ground construction.

In particular, the article is a building structure, an industrial article or a vehicle. In particular, it is a building or a part thereof. Or the object is in particular a means of transport, in particular a car, bus, truck, rail vehicle, ship or aircraft.

The aqueous compositions according to the invention are particularly suitable for use as a pretreatment for the adhesion of window panes, in particular in the production of automobiles, or for frameless installations. Thus in a preferred embodiment one substrate is glass or glass ceramic and the second substrate is lacquer or painted metal alloy.

The use of mercaptosilanes in aqueous compositions results in a significant improvement in the adhesion of the 1K polyurethane adhesive to silver or to silver-based compositions or alloys. The described method has been found to be particularly suitable for bonding glazing panes to integrated antennas or other electronic components. Such antenna connection contacts or other electronic components are typically made of silver or silver-based compositions or alloys and are located on the glazing.