阅读说明：本技术 用于吸烟制品的大麻包装物 (Hemp wrapper for smoking articles ) 是由 C·卢梭 J·阿库 A·古斯 L·龚伯特 于 2020-02-11 设计创作，主要内容包括：用于吸烟制品的包装材料,其由幅材形成,所述幅材包括提取的大麻片与幅材构建纤维的组合。所述幅材具有约20gsm至约80gsm的基重和约10Coresta至约100coresta的渗透率。所述包装材料具有天然的大麻气味和味道。所述包装材料是不含烟草和尼古丁的,且可以用作调味剂或气溶胶递送组合物的载体。(A wrapper for a smoking article formed from a web comprising a combination of extracted hemp sheets and web building fibers. The web has a basis weight of about 20gsm to about 80gsm and a permeability of about 10Coresta to about 100 Coresta. The packaging material has a natural cannabis odor and taste. The packaging material is free of tobacco and nicotine and can be used as a carrier for a flavor or aerosol delivery composition.)

1. A wrapper for a smoking article comprising:

a web comprising (1) extracted hemp fibers comprising hemp leaf, hemp stem, hemp sprout, hemp flower, or byproducts from hemp extraction, or mixtures thereof, in combination with (2) web building fibers, the web having a basis weight of from about 20gsm to about 80gsm and having a permeability of from about 10Coresta to about 100 Coresta.

2. The packaging material as defined in claim 1, wherein said web-forming fibers comprise delignified cellulose fibers.

3. The packaging material as defined in any one of the preceding claims, wherein the extracted hemp fibers comprise from about 10% to about 100% by weight of extracted hemp leaves or hemp stalks, from about 10% to about 100% by weight of extracted hemp sprouts and/or hemp flowers, and wherein the web comprises from about 1% to about 70% by weight of web building fibers.

4. The packaging material as defined in claim 3, wherein the web comprises from about 1% to about 50% by weight of web-building fibers.

5. The packaging material as defined in any one of the preceding claims, wherein the web is formed from a cannabis plant material comprising less than 0.3 wt% tetrahydrocannabinol.

6. The packaging material as defined in any one of the preceding claims, wherein the extracted hemp fibers further comprise hemp stalks.

7. The packaging material as defined in any one of the preceding claims, wherein the web further comprises a filler in combination with the extracted hemp fibers and the web building fibers.

8. The packaging material as defined in claim 7, wherein the web comprises a filler in an amount of about 1% to about 40% by weight, such as in an amount of about 5% to about 20% by weight.

9. The packaging material as defined in claim 7 or claim 8, wherein the filler comprises calcium carbonate particles, titanium dioxide particles, magnesium oxide particles, kaolin particles, talc particles, barium sulfate particles, bentonite particles, zeolite particles, silicate particles, or mixtures thereof.

10. The packaging material as defined in any one of claims 7 to 9, wherein the filler contained in the package has an average particle size of about 0.1 microns to about 10 microns.

11. The wrapper as defined in any of the preceding claims, wherein the web has a permeability of from about 30Coresta to about 80Coresta, such as from about 40Coresta to about 60 Coresta.

12. The wrapper material as defined in any of the preceding claims, wherein the web has a basis weight of from about 30gsm to about 50 gsm.

13. A packaging material as defined in any of the preceding claims, wherein the web comprises the web-building fibers in an amount sufficient for the web to have a tensile strength of greater than about 1000cN/15mm, such as greater than about 1250cN/15mm, such as greater than about 1500cN/15mm, and less than about 4000cN/15mm when tested according to ASTM test D828-97.

14. The packaging material as defined in any one of the preceding claims, wherein the web has been calendered.

15. The packaging material as defined in any one of the preceding claims, wherein the extracted hemp fibers comprise hemp extraction byproducts that have been subjected to additional water soluble extraction.

16. The packaging material as defined in any of the preceding claims, further comprising an aerosol delivery composition applied to the web, the aerosol delivery composition comprising an aerosol delivery agent.

17. The packaging material as defined in claim 16, wherein the aerosol delivery agent comprises a drug or a flavorant.

18. The packaging material as defined in claim 16, wherein the aerosol delivery composition comprises an oil.

19. The packaging material as defined in claim 16, wherein the aerosol delivery composition comprises a solid.

20. The packaging material as defined in claim 16, wherein the aerosol delivery agent comprises nicotine.

21. The packaging material as defined in claim 16, wherein said aerosol delivery agent comprises a cannabinoid.

22. The packaging material as defined in claim 15, wherein the aerosol delivery agent comprises tetrahydrocannabinol.

23. The packaging material as defined in claim 16, wherein the aerosol delivery agent comprises cannabidiol.

24. The packaging material as defined in claim 16, wherein the aerosol delivery agent comprises sugar, licorice extract, honey, coffee extract, maple syrup, tea extract, plant extract, regional plant extract, tobacco extract, or fruit extract.

25. The packaging material as defined in claim 16, wherein the aerosol delivery composition comprises a mixture of terpenes.

26. A packaging material as defined in claim 16, wherein the aerosol delivery composition is present on the web in an amount of greater than about 1 wt.%, such as greater than about 3 wt.%, such as greater than about 5 wt.%, such as greater than about 10 wt.%, such as greater than about 15 wt.%, such as greater than about 20 wt.%, such as greater than about 25 wt.%, such as greater than about 30 wt.%, such as greater than about 35 wt.%, such as greater than about 40 wt.%, and less than about 50 wt.%.

27. The packaging material as defined in any one of the preceding claims, wherein the web comprises a water-soluble cannabis component in an amount of less than about 40% by weight.

28. The packaging material as defined in any one of claims 1 to 26, wherein the web comprises a water-soluble cannabis component in an amount of less than about 20% by weight.

29. The packaging material as defined in any one of the preceding claims, wherein the web building fibers comprise softwood fibers.

30. The packaging material as defined in any one of the preceding claims, wherein the web building fibers comprise flax fibers, abaca fibers, wood pulp fibers, bamboo fibers, coconut fibers, ramie fibers, jute fibers, or mixtures thereof.

31. The packaging material as defined in any one of the preceding claims, wherein the web building fibers comprise hemp pulp fibers.

32. The packaging material as defined in any one of the preceding claims, wherein the web building fibers are present in the web in an amount of greater than about 3 wt.%, such as in an amount of greater than about 10 wt.%, such as in an amount of greater than about 20 wt.%, and in an amount of less than about 40 wt.%.

33. The packaging material as defined in any one of the preceding claims, wherein the packaging material is free of tobacco.

34. The packaging material as defined in any one of the preceding claims, wherein the web has been treated with a burn control agent.

35. A packaging material as defined in claim 34, wherein the burn control agent comprises a salt of a carboxylic acid, such as a citrate salt or a succinate salt, the burn control agent being present in the web in an amount of from about 0.3% to about 3% by weight, such as in an amount of from about 1% to about 2% by weight.

36. The packaging material as defined in any one of the preceding claims, wherein said web has been treated with a humectant.

37. The packaging material as defined in claim 36, wherein said humectant comprises glycerin, propylene glycol, or mixtures thereof.

38. The packaging material as defined in any one of the preceding claims, wherein said web has been treated with a gum.

39. The packaging material as defined in claim 38, wherein the gum comprises guar gum, alginate, carboxymethyl cellulose, or a mixture thereof.

40. A packaging material as defined in claim 38 or 39, wherein said gum is present on said web in an amount of about 0.1% to about 2% by weight.

41. The packaging material as defined in any one of the preceding claims, wherein the packaging material includes a plurality of discrete reduced burn regions spaced apart along a first direction of the packaging material, the reduced burn regions having a diffusivity of less than about 0.5cm/s at 23 ℃.

42. The packaging material as defined in claim 41, wherein the plurality of reduced burn zones are formed by applying a reduced burn composition to the web.

43. A wrapper as defined in any preceding claim, wherein at least 75% of the smoking articles self-extinguish when the wrapper is incorporated into a smoking article and tested according to ASTM test E2187-09.

44. A smoking article comprising a smokable rod surrounded by the wrapping material according to any one of the preceding claims.

Background

Cannabis or cannabis plants may refer to either marijuana, which is commonly used for recreational purposes, or to china hemp (hemp), which is commonly used for industrial applications. Cannabis sativa (Cannabis) is a green and/or brown mixture of dried, chopped leaves, stems, seeds and flowers of plants, and may refer to the leaves, stems, seeds and flowers of Cannabis sativa, and its varieties include Cannabis sativa (Cannabis sativa) or Cannabis sativa indica (Cannabis indica). Hemp (hema), especially the industrial hemp (hema) variety, has a very similar appearance to marijuana, but unlike the hemp plant variety referred to by marijuana, hemp (hema) usually contains only small amounts of Tetrahydrocannabinol (THC), whereas both hemp (hema) and marijuana can contain large amounts of Cannabidiol (CBD). For example, hemp (hemp), and in particular industrial hemp (hemp), can contain less than about 0.3% THC, while marijuana refers to a variety of hemp that can contain 5% to 30% THC. Cannabis (including both marijuana and hemp (hemp)) is a known analgesic, but generally only hemp (hemp) or industrial hemp (hemp) is used for food, paper, clothing, fabric and CBD extraction due to their low THC content. Recently, the use of cannabis for at least medical purposes has been legalized in more than 25 states in the united states. In addition, canada has now legalized the use of cannabis for medical and recreational use. In view of these recent developments, the commercialization of cannabis has increased dramatically.

For example, cannabis is becoming a popular analgesic drug to replace conventional analgesic drugs such as opioids, as more and more people in the medical community are beginning to consider cannabis as a legitimate substitute for the use of opioids for analgesia. For example, cannabis contains two different drugs that can help alleviate pain, nausea, and other symptoms. For example, cannabis contains Tetrahydrocannabinol (THC). THC acts on specific receptors in the brain, resulting in euphoria and a state of relaxation. The highest THC concentration was found in the dried flowers or shoots of cannabis. Cannabis is often regulated according to the amount of THC found in the material. In addition to THC, cannabis may also contain Cannabidiol (CBD). While CBD does interact with pain receptors in the brain, CBD does not produce the same euphoric effects that THC causes. However, CBD exhibits analgesic and anti-inflammatory effects. Cannabinoids, especially CBD, do not have the same addictive effects as many opioids. Thus, cannabis is becoming increasingly accepted for medical and recreational use, which has led to legitimization in many areas.

Inhalation of burning cannabis is the most common, most effective and least expensive method of introducing THC and CBD into the body. However, while other methods are becoming increasingly popular, inhalation-burned cannabis often use cannabis wrapped in a wrapper to burn and inhale the cannabis by smoking.

It has long been recognized in the industry that wrappers for smoking articles have a significant impact on the smoking characteristics of the smoking articles. In this regard, various attempts have been made in the art to modify or improve the wrapper for a smoking article to obtain a wrapper that improves the overall smoking experience of the smoking article. Wrapper paper for smoking articles is typically formed from pulp fibres, such as wood fibres or flax fibres, in combination with filler particles. However, such wrappers tend to produce a taste that is perceived by the user as unpleasant and unnatural "paper" and have a taste that may alter the original aroma of the hemp.

Furthermore, pulp fibers are mainly composed of delignified fibers from hardwood and coniferous trees (softwood trees), which raises concerns about the sustainability of packages made mainly of pulp fibers, as it depends to a large extent on the trees that are felled. In particular, two to three tons of wood are required to produce one ton of conventional paper. Global paper consumption has increased dramatically since 1950. This increase in consumption has an impact on forests on earth, of which 80% will disappear due to human activity.

On the other hand, a homogeneous wrapper tobacco material is typically made from processed tobacco by-products in an amount in excess of 50%. As a result, such packaging materials also typically contain large amounts of nicotine and produce a characteristic tobacco aroma, which may not be suitable for sensory acceptance of inhaled, burned cannabis.

In addition, some homogeneous packaging materials made from hemp materials have been prepared using a technique commonly referred to as "serosity," but generally have too low a tensile strength (<1,000cN/15mm) to form a suitable packaging material. Such materials are therefore unsuitable for mass production of cannabis smoking articles, such as booklets (for hand-rolled), tubular cigarettes (tube), cone cigarettes (con) or cigarettes (cigarettes) which require higher tensile strength.

In view of the above, there is a need for a package for smoking articles that has a more neutral or natural cannabis odor and/or taste, e.g., for use with legitimate cannabis products or other aerosol-releasing articles, and that has sufficient tensile strength to enable mass production. Similarly, there is a need to provide a package for smoking articles which has sufficiently good burn characteristics in addition to a pleasant or natural cannabis taste. It would also be beneficial to provide a package for a smoking article with improved smoking characteristics and which is nicotine-free. In addition, it would be beneficial to provide a smoking article that has improved smoking characteristics and that can also serve as a carrier for one or more aerosol delivery compositions. Furthermore, it would also be advantageous to provide a package that is at least partially formed from a sustainable source. Finally, it would also be advantageous to form a package that is itself free of tobacco and/or nicotine that can serve as a carrier for an aerosol delivery composition.

Disclosure of Invention

In general, the present disclosure relates to a wrapper for a smoking article comprising a web. The web comprises a combination of extracted hemp fibers comprising hemp leaves, hemp stems (also known as stalks (hurd)), hemp sprouts, hemp flowers, hemp extracted residues or mixtures thereof and web building fibers. The web has a basis weight of about 20gsm to about 80gsm and has a permeability of about 10Coresta to about 100 Coresta.

In one embodiment, the web building fibers comprise delignified cellulose fibers. In another embodiment, the extracted hemp fibers comprise about 10% to about 100% by weight of extracted hemp leaves, about 10% to about 100% by weight of extracted hemp sprouts and/or flowers, and the web comprises about 1% to about 70% by weight of web building fibers. Additionally or alternatively, the web includes the web-building fibers in an amount of about 1 wt% to about 50 wt%. In yet another embodiment, the web is formed from a cannabis plant material comprising less than 0.3 wt% tetrahydrocannabinol. Additionally or alternatively, the extracted hemp fibers also include hemp stalks (talk).

In further embodiments, the web includes a filler in combination with the extracted hemp fibers and the web construction fibers. Additionally, in one embodiment, the web comprises a filler in an amount from about 5 wt% to about 40 wt%, for example in an amount from about 8 wt% to about 20 wt%. In one embodiment, the filler comprises calcium carbonate particles, titanium dioxide particles, kaolin clay particles, talc particles, barium sulfate particles, bentonite particles, zeolite particles, silicate particles, or mixtures thereof. Additionally or alternatively, the filler contained in the package has an average particle size of about 0.1 microns to about 10 microns.

In one embodiment, the web has a permeability of from about 30Coresta to about 80Coresta, for example from about 40Coresta to about 60 Coresta. In another embodiment, the web has a basis weight of from about 30gsm to about 50 gsm. Further, in one embodiment, the web comprises web-building fibers in an amount sufficient for the web to have a tensile strength of greater than about 1000cN/15mm, such as greater than about 1250cN/15mm, such as greater than about 1500cN/15mm, and less than about 4000cN/15mm when tested according to ASTM test D828-97.

In one embodiment, a web according to the present disclosure may be calendered.

In another embodiment, the packaging material comprises an aerosol delivery composition applied to the web, and the aerosol delivery composition comprises an aerosol delivery agent. In one embodiment, the aerosol delivery agent comprises a drug or a flavoring agent. In yet another embodiment, the aerosol delivery composition comprises an oil or a solid. Further, in one embodiment, the aerosol delivery agent comprises nicotine, cannabinoid, tetrahydrocannabinol, or cannabidiol. In yet another embodiment, the aerosol delivery agent comprises sugar, licorice extract, honey, coffee extract, maple syrup, tea extract, plant extract, botanical (botanic) extract, tobacco extract, or fruit extract. In one aspect, the aerosol delivery agent may comprise one or more terpenes. Terpenes or terpene blends may be added to packaging materials to impart a unique aroma that is indicative of a high quality hemp product. Terpenes that may be added to the packaging material include pinene, humulene, b-caryophyllene, isopulegol, guaiol, neryl acetate, neomenthyl acetate, limonene, menthone, dihydrojasmone, terpinolene, menthol, phellandrene, terpinene, geranyl acetate, ocimene, myrcene, 1, 4-cineol, 3-carene, linalool, menthofuran, perillyl alcohol, pinane, neomenthyl acetate (neomenthyllaceta), and a wide variety of others.

Additionally or alternatively, the aerosol delivery composition is present on the web in an amount of greater than about 1 wt%, such as greater than about 3 wt%, such as greater than about 5 wt%, such as greater than about 10 wt%, such as greater than about 15 wt%, such as greater than about 20 wt%, such as greater than about 25 wt%, such as greater than about 30 wt%, such as greater than about 35 wt%, such as greater than about 40 wt%, and less than about 50 wt%.

In another embodiment, the web comprises a water-soluble hemp component in an amount of less than about 40% by weight.

Additionally or alternatively, in one embodiment, the web building fibers comprise softwood fibers. In another embodiment, the web building fibers comprise flax fibers, hemp fibers, abaca fibers, wood pulp fibers, bamboo fibers, coconut fibers, ramie fibers, jute fibers, or mixtures thereof. In one embodiment, the web-building fibers are present in the web in an amount greater than about 5 wt.%, such as in an amount greater than about 10 wt.%, such as in an amount greater than about 20 wt.%, and in an amount less than about 40 wt.%.

In another embodiment, the packaging material is free of tobacco.

In yet another embodiment, the web has been treated with a burn control agent. In another embodiment, the burn control agent comprises a carboxylate salt, such as a citrate salt or a succinate salt, and the burn control agent is present in the web in an amount of about 0.3 wt% to about 3 wt%, such as in an amount of about 1 wt% to about 2 wt%.

Further, in one embodiment, the web has been treated with a humectant. In further embodiments, the humectant comprises glycerin, propylene glycol, or mixtures thereof.

Additionally or alternatively, in one embodiment, the web is treated with a gum. In one embodiment, the gum comprises guar gum, alginate, cellulose derivatives such as carboxymethyl cellulose, gum arabic or mixtures thereof. In one embodiment, the gum is present on the web in an amount of about 0.1% to about 2% by weight.

In another embodiment, the packaging material includes a plurality of discrete reduced burn zones spaced apart along a first direction of the packaging material, the reduced burn zones having a diffusivity of less than about 0.5cm/s at 23 ℃. In one embodiment, the plurality of reduced velocity combustion zones are formed by applying a reduced velocity combustion composition to the web.

The present disclosure also generally relates to a wrapper according to the present disclosure for incorporation into a smoking article. When smoking articles are tested according to ASTM test E2187-09, at least 75% of smoking articles self-extinguish.

In general, the present disclosure also relates to smoking articles comprising a smokable rod surrounded by the wrapper of the present disclosure.

Other features and aspects of the present invention are discussed in more detail below.

Drawings

A full and enabling disclosure of the present disclosure, including the reference to the accompanying figures, is set forth more particularly in the remainder of the specification, in which:

figure 1 is a perspective view of one embodiment of a smoking article comprising a wrapper of the present disclosure;

figure 2 is an exploded view of the smoking article shown in figure 1;

fig. 3A illustrates an article according to the present disclosure;

figure 3B shows a piece of the article of figure 3 a.

Repeat use of reference characters in the present specification and drawings is intended to represent same or analogous features or elements of the invention.

Definition of

As used herein, "Cannabis" may refer to any variety of Cannabis plant, such as Cannabis sativa (canabis sativa) or Cannabis indica (canabis indica). More specifically, the present disclosure may refer to the leaves, stems, seeds, and flowers or any other part of the cannabis plant as cannabis. Nonetheless, reference herein to cannabis includes cannabis containing average or high levels of THC and/or CBD (commonly referred to as marijuana), hemp (hemp) which may contain low or very low levels of THC, industrial hemp (hemp) (which may refer to a cannabis plant containing less than 0.3% THC), or combinations thereof.

As used herein, "reconstituted plant material" refers to material formed by a process in which plant material, such as plant material from the cannabis plant, is extracted with a solvent to form a soluble extract, such as a hydrosoluble extract, and an extracted insoluble fraction or residue comprising fibrous material. The extracted insoluble fibrous material is then formed into a sheet or web by any suitable method, and the extract can be discarded or reapplied to the formed sheet. The extract may be fed by various methods for concentrating the extract and optionally removing or adding various components prior to recombination with the fibrous material. In the present disclosure, reconstituted plant material is formed from extracted hemp fibers, optionally in combination with web building fibers, such as cellulose fibers. The soluble extract obtained from hemp fibers is optionally reapplied to the sheet.

As used herein, "aerosol-generating material" is intended to include both combustible materials that undergo combustion in a smoking article and aerosol-forming materials that are heated but do not combust to form an inhalable aerosol. Combustible smoking articles may include cigarettes, cigarillos and cigars, pre-cones, and the like. In cigarettes, the aerosol generating material is typically surrounded by a wrapper to form a smokable rod, but may also be contained within the wrapper itself. Aerosol-generating devices for generating an aerosol include, for example, devices in which an aerosol is generated by electrical heating or by transferring heat from a combustible fuel element or heat source to heat, but not burn, an aerosol-generating material that releases volatile compounds. As the released compounds cool, they condense to form an aerosol that is inhaled by the consumer.

As used herein, "extracted hemp fibers" refers to hemp fibers that have been subjected to an extraction process in which hemp has been contacted with an aqueous solution to remove greater than 75% of the water soluble components contained in the hemp. The extraction process is different from the delignification process and the bleaching treatment.

As used herein, "extracted by-products" refers to cannabis biomass that has undergone an extraction process to remove selected components (e.g., cannabinoids) without removing substantial amounts of water soluble components. The extracted by-products can be referred to as biomass resulting from the extraction process, wherein the extractant is a solvent, such as ethanol, a supercritical fluid, such as carbon dioxide, a lipid, such as vegetable oil, and the like. In accordance with the present disclosure, the extracted byproducts may undergo a second extraction process to remove water soluble components during the process of preparing the reconstituted cannabis material. Extraction byproducts well suited for use in the present disclosure include those that include water soluble components in an amount greater than about 8 wt.%, such as in an amount greater than about 12 wt.%, such as in an amount greater than about 18 wt.%, such as in an amount greater than about 24 wt.%.

As used herein, "delignified" cellulose fibers refer to fibers that have been subjected to a pulping or delignification process by which the cellulose fibers are separated from the plant material by chemical means, mechanical means, or by a combination of chemical and mechanical means.

As used herein, the term "refining" is used to indicate mechanical treatment of the plant material that modifies the fibers of the material so that they are more suitable for forming a fibrous sheet or substrate. Refining can be accomplished using a conical refiner or a disc refiner or a Valley beater. The mechanical process imparts an abrasive and grazing action to the plant material, causing the plant material to defibrillate. Refining is a different process than delignification and pulping.

As used herein, the "amount of water-soluble extract" present in the substrate or reconstituted plant material or aerosol-generating material is determined by placing a 5 gram sample in boiling distilled water for 10 minutes to obtain an extract comprising water-soluble components. The weight of dry matter of the solvent-soluble extract is calculated by the difference between the dry weight of the sample and the dry weight of the sample after extraction. The difference in dry weight is then used to determine the percentage of water soluble extract in the sample.

Detailed description of the invention

It is to be understood by one of ordinary skill in the art that the present discussion is a description of exemplary embodiments only, and is not intended as limiting the broader aspects of the present invention.

The present invention generally relates to a wrapper for a smoking article, which is formed from a web. The web comprises hemp and optionally web building fibers. In this way, a web for a packaging material according to the present disclosure may be formed at least partially or even completely of a sustainable material. Furthermore, it has been unexpectedly found that webs formed from extracted hemp have a pleasant natural hemp taste and act as excellent carriers, even when combined with web building fibers that may include pulp fibers. Furthermore, it was found that a packaging material formed at least in part from hemp surprisingly has good burn characteristics in addition to a pleasant natural hemp taste and good carrier properties.

Because reconstituted cannabis materials have a natural cannabis taste and are nicotine-free when smoked, such packaging materials can be used to prepare nicotine-free smoking articles that complement and/or mimic the cannabis odor and taste. For example, a wrapper formed from cannabis may enhance or enhance the taste and/or smell of a smoking article containing cannabis, or may mimic the taste and/or smell of cannabis when smoking of cannabis is not desired, but is also desired. Thus, packaging materials according to the present disclosure may provide an alternative to wrapping paper for use with cannabis or cannabis smokeable products, or may also provide a better sensory experience when it is desired to mimic the taste and/or odor of cannabis or cannabis smokeable products.

In addition, the packaging material is well suited for combination with other fibers and/or topical additives having aerosol delivery functionality, which may be collectively referred to as aerosol delivery agents, and will be discussed in more detail below. For example, the packaging material may also be combined with or have an aerosol delivery agent applied thereto, due to its good carrier properties. When combined with tobacco or cannabis materials, the packaging materials of the present disclosure, due to their natural odor and taste characteristics, can better retain the taste of the aerosol delivery composition, and can actually enhance the smoking experience by diluting and reducing irritants.

However, as will be discussed in more detail below, an additional benefit of the packaging material according to the present disclosure is that, when used, the aerosol delivery composition can be applied in metered amounts after the package is formed. Thus, the aerosol delivery composition (e.g., nicotine, THC, or CBD) is not characterized solely by the inherent properties of the material used to form the package, but rather, the amount of aerosol delivery composition can be carefully controlled and metered when applied to the packaging material. Thus, the amount of aerosol delivery composition on the packaging material can be measured, known and evenly distributed compared to the natural form of the aerosol delivery composition.

As noted above, the packaging materials of the present disclosure are typically formed from extracted hemp, optionally in combination with web-building fibers. The cannabis material used in the present disclosure is obtained from the cannabis plant and may therefore be referred to as cannabis. Hemp material for use in the present disclosure may include all parts of the plant, such as stalks, fibers, buds, flowers, leaves, seeds, and optionally stalk components, or may include residue from hemp extraction. Further, as will be discussed herein, during the formation of reconstituted cannabis material, some or all of the THC, CBD or other soluble components may be extracted from the cannabis, and the soluble components including, for example, THC or CBD may optionally be reapplied to the web. Thus, in one embodiment, the packaging material of the present disclosure is formed from hemp stalks or stalks, fibers, leaves, seeds, flowers and buds, and residues from hemp extracts, and thus may generally include all parts of the plant material obtained from hemp.

In one embodiment, the cannabis component is obtained from cannabis plants having relatively low THC content. For example, the amount of THC in the cannabis component may be less than about 1 wt% THC, such as less than about 0.3 wt% THC, such as less than about 0.2 wt% THC, such as less than about 0.1 wt% THC. The use of cannabis ingredients from low THC plants may provide various advantages and benefits. For example, when THC is applied topically to the material, making a low THC reconstituted cannabis material allows for better control of THC delivery. In addition, reconstituted materials containing undetectable amounts of THC can be prepared so that the materials can deliver other active agents, such as CBD, flavors, nicotine, and the like. However, it should be understood that in other embodiments, the reconstituted cannabis material may be made from plants comprising THC, for example from the indian cannabis species.

Additionally or alternatively, reconstituted hemp materials of the present disclosure can be prepared from various parts of the hemp plant, including stems or stalks, fibers, leaves, seeds, flowers, and buds. These different parts of the plant can be combined in different proportions and amounts depending on the specific application and the desired result. While the reconstituted cannabis material may be made from cannabis leaves and stems alone, or from cannabis buds and flowers alone, in one embodiment, the reconstituted material is made from a mixture of leaves and stems in combination with buds and/or flowers. For example, in one embodiment, the weight ratio between the leaves and the stalks to the buds and/or flowers is from about 1:8 to about 8:1, for example from about 1:5 to about 5:1, for example from about 1:4 to about 4:1, for example from about 2:1 to about 1: 2. In one embodiment, the ratio may be about 1: 1.

In one embodiment, the reconstituted cannabis material may comprise cannabis leaf and stem in an amount greater than about 10% by weight, for example in an amount greater than about 20% by weight, for example in an amount greater than about 30% by weight, typically in an amount up to 100% by weight. Similarly, the reconstituted cannabis material may comprise buds and/or flowers in an amount of greater than about 10% by weight, for example in an amount of greater than about 20% by weight, for example in an amount of greater than about 30% by weight, for example in an amount of greater than about 40% by weight, for example in an amount of greater than about 50% by weight, for example in an amount of greater than about 60% by weight, and typically in an amount of up to 100% by weight.

In one aspect, at least a portion of the cannabis components collected for use in preparing reconstituted cannabis materials are cannabis extraction byproducts. Hemp extraction byproducts include hemp biomass that has been subjected to a first extraction process to remove desired components from the plant, but without removing substantial amounts of water soluble components. For example, the cannabis extraction byproduct may be biomass, such as THC and/or CBD, remaining after extraction of one or more cannabinoids from cannabis plant material. These types of extraction processes can use different solvents and supercritical fluids. For example, in one embodiment, the extraction byproducts are from a cannabis extraction process, wherein cannabis material is ground and mixed with a solvent. For example, the solvent may be an alcohol such as ethanol, an organic ester, a petroleum-derived hydrocarbon such as toluene or trimethylpentane, or a lipid such as a vegetable oil. Examples of vegetable oils include safflower oil, coconut oil and the like. In an alternative embodiment, the cannabis plant material may be contacted with a supercritical fluid, such as carbon dioxide, during the extraction process. Generally, extraction methods involve grinding or cutting the plant material to a desired size, and then contacting the material with an extractant, such as a solvent or supercritical fluid. The material may be heated during contact with the solvent. For example, when contacted with a supercritical fluid, the temperature can be from about 31 ℃ to about 80 ℃, and the pressure can be from about 75 bar to about 500 bar.

The use of extraction byproducts as part of the cannabis component may provide various advantages. For example, hemp extraction byproducts may produce milder aerosols and may be easier to handle than the original plant material. To prepare reconstituted cannabis material, the cannabis extraction by-products may be subjected to a second extraction process to remove water soluble components. For example, the cannabis extraction by-products may comprise water soluble components in an amount greater than about 8 wt%, such as in an amount greater than about 12 wt%, for example in an amount greater than about 18 wt%, for example in an amount greater than about 24 wt%, for example in an amount greater than about 28 wt%, and typically in an amount less than about 60 wt%, for example in an amount less than about 50 wt%.

In particular, the present invention has discovered that by selectively forming webs according to the present disclosure, fibers or pieces of plant material obtained from hemp can be combined with cellulosic web building fibers to form packaging materials that exhibit good, natural hemp taste, as well as good tensile strength and burn performance.

In one embodiment, cannabis is optionally fractionated or milled, followed by an extraction process to remove water soluble components. The extracted hemp can then optionally be combined with web building fibers and formed into a substrate, such as a reconstituted sheet or web. The substrate may optionally be treated with an extract obtained from cannabis. Alternatively, the extract obtained from cannabis may be discarded and not recombined with water-insoluble fibers and other materials. The reconstituted material is then dried and formed into a web and/or packaging material. The web and/or packaging material may then optionally be combined with various other components. For example, the packaging material may be treated with various aerosol delivery agents, and/or combined with various other aerosol delivery compounds, such as tobacco material or other herbal fillers, during or after an initial refining process, such that the packaging material itself is formed from a combination of hemp fibers and at least one additional aerosol delivery compound. Alternatively, the packaging material may be used to surround or surround only the aerosol delivery agent and the compound, or in one embodiment, may both be treated with and surround the aerosol delivery compound.

In forming the packaging material of the present disclosure, hemp material (e.g., stalks or stalks, fibers, leaves, seeds, flowers, and buds) is first collected and optionally reduced in size. For example, in one embodiment, the hemp material can be subjected to a grinding operation, a milling operation, or a beating operation that can reduce the size of the hemp material and/or reduce the hemp into individual fibers. For example, in one embodiment, the hemp material can be fed to a hammer mill that beats the hemp material against a screen to prepare a fibrous material.

Nonetheless, cannabis may then undergo a mild extraction process to remove water soluble components. In particular, solvent-soluble compounds naturally present in cannabis may cause problems, such as sticking to drying cylinders, difficulty in draining or fermentation problems in tanks. In one embodiment, the extraction process may simply comprise placing the cannabis material in water and allowing the water soluble portion to be extracted into the water. In alternative embodiments, various water-miscible solvents, such as alcohols (e.g., ethanol) and/or suitable oils and fats, may be combined with water to form an aqueous solvent. For example, suitable oils and fats may be those in which THC and/or CBD is soluble, in order to extract THC and/or CBD from the plant fibre in the extraction stage. In some cases, the aqueous solvent has a water content greater than 50% by weight of the solvent, particularly greater than 90% by weight of the solvent. Deionized, distilled or tap water may be used. The amount of solvent in the suspension may vary widely, but is typically added in an amount of from about 50% to about 99%, in some embodiments from about 60% to about 95%, and in some embodiments, from about 75% to about 90% by weight of the suspension. However, the amount of solvent may vary with the nature of the solvent and the temperature at which the extraction is carried out. In one embodiment, the solvent may be heated. Of course, while a variety of solutions may be used, the extraction solution should also be selected so as to effectively remove soluble compounds while leaving the hemp fibers unharmed. In one embodiment, for example, the extraction solution may be a hot aqueous solution that may include water.

The cannabis material in the solvent may optionally be agitated by stirring, shaking or otherwise mixing the mixture to increase the rate of dissolution. Typically, the process is carried out for about 10 minutes to about 6 hours. The process temperature may be from about 10 ℃ to about 100 ℃, for example from about 40 ℃ to about 80 ℃.

After steeping and optionally agitating the cannabis material, an extruder or centrifuge may be used to mechanically separate the insoluble portion of the cannabis material from the soluble portion of the cannabis material, or otherwise separate from the solvent that currently contains the soluble portion of cannabis. Once the soluble fraction is separated from the insoluble fraction, the soluble fraction can be discarded or further processed, e.g., by concentration. The soluble fraction can be concentrated using any known type of concentrator, for example a vacuum evaporator. In one embodiment of the present disclosure, the soluble fraction may be highly concentrated. In one embodiment, for example, the soluble fraction may be evaporated so as to have a final brix (brix) or dry matter of about 10% to about 60%, such as about 20% to about 40%, such as about 25% to about 35%.

While the extraction process removes soluble compounds in order to facilitate processing of the packaging material, the extraction process may also be used to remove other undesirable compounds. For example, pesticides and other compounds may be removed from cannabis in the soluble fraction by an extraction process, and then pesticides and other compounds may be further eliminated from the soluble fraction prior to optional concentration of the soluble fraction. While this process is discussed with respect to pesticides, it should be understood that the extraction process may be used to remove undesirable compounds, such as tobacco, nicotine, and caffeine, and any other undesirable compounds from other plants used in web building fibers. Furthermore, the present disclosure also contemplates minimizing or reducing, but not eliminating, any undesirable compounds, such as caffeine or nicotine, by purifying or concentrating the soluble fraction as discussed herein.

The resulting concentrated soluble fraction may be discarded, used in a separate process, or may be applied later on to the packaging material of the present disclosure, as will be described in more detail below.

The resulting water-insoluble cannabis fraction is typically in an unrefined state. Hemp material can include particles and fibers. In one embodiment, the insoluble and extracted cannabis fraction may be subjected to a refining process. For example, the extracted hemp material can be fed through any suitable refining device, such as a conical refiner or a disc refiner. Other refining apparatus that may be used include beaters, such as Valley beaters. After the hemp material is wetted or combined with water, it can be refined. For example, in one embodiment, refining may be performed at a consistency of the hemp material of less than about 10%, such as less than about 5%, for example less than about 3%.

In accordance with the present disclosure, extracted hemp material can be optionally combined with web-building fibers to form a fibrous substrate. For example, extracted hemp may be combined with water or an aqueous solution to form a slurry. Web-building fibers, such as delignified cellulosic fibers, may be combined with hemp material to form a slurry. The fiber slurry is then used to form a continuous reconstituted sheet or web. For example, in one embodiment, the fiber slurry is fed to a papermaking process, which may include a forming wire, a gravity drain (gravity drain), a suction drain (suction drain), a felt press and a dryer, such as a Yankee dryer, a drum dryer, and the like. Similarly, in one embodiment, the fiber slurry is formed into a continuous sheet on a fourdrinier machine.

In one embodiment, the fiber slurry is laid onto a porous forming surface and formed into a sheet. Excess water is removed by gravity drains and/or suction drains. In addition, various extruders may be used to facilitate water removal. The formed sheet may be dried and further processed.

Optionally, the resulting packaging material may also be treated with a soluble cannabis fraction, e.g., a concentrated soluble cannabis fraction separated from an insoluble fraction. The soluble portion may be applied to the web using various application methods, such as, for example, gumming, coating, and the like. The amount of water-soluble cannabis extract applied to the reconstituted material may depend on various factors and the intended end-use application. For example, the soluble cannabis extract may be applied to the packaging material in an amount insufficient to adversely interfere with the inherent taste of the underlying material. For example, in one embodiment, the water-soluble cannabis extract is applied to the reconstituted material such that the reconstituted material comprises the water-soluble cannabis extract in an amount of up to about 10% by weight, such as in an amount of less than about 8% by weight, such as in an amount of less than about 6% by weight, such as in an amount of less than about 4% by weight, such as in an amount of less than about 2% by weight, such as in an amount of less than about 1% by weight, and typically in an amount of greater than about 0.5% by weight. However, in another embodiment of the invention, the water-soluble cannabis extract may be reapplied to the reconstituted material in an amount greater than 10%, such as 15% or 20% or 25%, or up to 35%, in order to provide a noticeable cannabis aroma to the final smoking article.

While heretofore, the formation of packaging materials has been described by first extracting and refining hemp material and then mixing with refined pulp fibers, it should be understood that one or more types of plant fibers, as will be discussed in more detail below, may be mixed with the hemp material at the extraction stage such that the hemp and optional web building fibers are simultaneously subjected to extraction and refining. Of course, as discussed above, the hemp may be extracted separately and then mixed with the web building fibers during the pulping process.

Although there are methods for forming a web or sheet, and while the web building fibers may be fibers from any plant having one or more characteristics desired to be included in the web or sheet, in one embodiment, the web building fibers may be fibers of a plant that have been subjected to extraction in a solvent, for example to produce pulp. While the web building fibers may be obtained from any type of plant, in one embodiment, the web building fibers are delignified cellulosic fibers. For example, the web building fibers may preferably comprise hemp pulp fibers. The hemp pulp fibers can have an average fiber length of typically greater than about 0.5mm, such as greater than about 1mm, such as greater than about 1.5mm, such as greater than about 1.8mm, typically less than about 4mm, such as less than about 3mm, such as less than about 2.5mm, such as less than about 2.35 mm.

Other cellulosic fibers that may be used include wood pulp fibers, such as softwood or hardwood fibers, flax fibers, abaca fibers, bamboo fibers, coconut fibers, cotton fibers, kapok fibers, ramie fibers, jute fibers, or mixtures thereof. In a particular embodiment, the reconstituted plant material comprises hemp pulp fibers alone or in combination with other fibers, such as softwood fibers or flax fibers and the like.

Regardless of the fibers selected to form the web-building fibers, the web or packaging material may include from about 1 to about 100 wt%, such as from about 20 wt% to about 95 wt%, such as from about 30 wt% to about 90 wt%, such as from about 40 wt% to about 80 wt% of the hemp fibers, or any range of amounts therebetween, based on the weight of the web or packaging material.

Further, the web or packaging material may comprise from about 0% to about 99% by weight, such as from about 5% to about 80% by weight, such as from about 10% to about 50% by weight, such as from about 15% to about 30% by weight, of the web-building fibers, or any range therebetween, based on the weight of the packaging material or web.

In one embodiment, the web building fibers incorporated into the reconstituted plant material comprise a combination of longer fibers and shorter fibers. The longer fibers may generally have a length greater than about 2mm, while the shorter fibers may generally have a length less than about 1.5 mm. Longer fibers may be used to improve strength and integrity, while shorter fibers may better retain the hemp fibers and other components within the fibrous substrate. In one embodiment, for example, the staple fibers can be present in the reconstituted plant material in an amount greater than about 5% by weight, such as in an amount greater than about 10% by weight, and typically in an amount less than about 20% by weight. On the other hand, longer fibers may be present in the reconstituted web material in an amount greater than about 10% by weight, such as in an amount greater than about 20% by weight, and typically in an amount less than about 50% by weight, such as in an amount less than about 40% by weight. In one embodiment, the shorter fibers comprise hardwood fibers and the longer fibers comprise hemp pulp fibers, flax fibers, or softwood fibers.

In particular, the present inventors have discovered that by forming a packaging material according to the present disclosure, a web or sheet can be formed using hemp having good strength, suitable smoothness, basis weight, and adjustable permeability. Thus, the packaging material according to the present disclosure may be able to withstand the mechanical stresses of the paper making process as well as mass produced smoking articles, and may also have good sensory characteristics and burn performance. Furthermore, as will be discussed in more detail below, the packaging material has also been found to function well as a carrier for other taste or aerosol delivery compositions.

For example, packaging materials made according to the present disclosure have excellent mechanical characteristics, and have a very desirable and aesthetically pleasing appearance. Typically, the wrapper has a basis weight of greater than about 20gsm, such as greater than about 30gsm, such as greater than about 40gsm, such as greater than about 50gsm, such as greater than about 60gsm, such as greater than about 70gsm, such as greater than about 80gsm, such as greater than about 85 gsm. The basis weight of the wrapper material is typically less than about 100gsm, such as less than about 90gsm, such as less than about 80gsm, such as less than about 70gsm, such as less than about 60gsm, such as less than about 50gsm, or any range therebetween. Within the above basis weight ranges, the packaging material is very strong and may exhibit a tensile strength of greater than about 1,000cN/15mm, for example greater than about 1,500cN/15mm, and typically less than about 3,000cN/15 mm. Tensile strength can be measured using ASTM test D828-97.

The wrapper according to the present disclosure may also have a permeability that is favorable for suitable smoking performance, such as good mainstream smoke control or good smoking comfort. For example, a wrapper according to the present disclosure may have a permeability measured in Coresta units of about 0Coresta to about 100Coresta, such as about 20Coresta to about 90 Coresta, such as about 30Coresta to about 80Coresta, such as about 35Coresta to about 60Coresta, or any range therebetween.

While the packaging material according to the present disclosure may naturally or inherently have a desired permeability, in one embodiment, it may be desirable to perforate the packaging material after formation. The perforations may be performed as known in the art, and the number and size of perforations may be selected as required by the desired application.

In addition to the physical properties described above, packaging materials made according to the present disclosure may exhibit a unique natural appearance with natural speckles and/or coloration from one or more hemp fibers or particles. Optionally, the packaging material may be formulated with pigments (natural or synthetic) to adjust its final coloration.

Furthermore, in addition to having a natural appearance, the packaging material according to the present disclosure may also have a pleasant texture. The packaging material may have a relatively rough surface to emphasize its natural appearance, or may be further calendered to provide a smoother feel.

The packaging material of the present disclosure may also be used to prepare smoking articles with better taste and sensory characteristics. For example, the packaging material of the present disclosure produces a paper taste that is less than conventional smoking paper. In contrast, a pleasant neutral or distinctive natural hemp taste has been observed even when the packaging material comprises a cellulosic web building fiber. Although the packaging material according to the present disclosure may have more or less weight of web-building fibers, surprisingly, a pleasant natural hemp taste is maintained even when a portion of the packaging material is formed from cellulosic web-building fibers.

In addition, the packaging material produces a viscous ash having an ash appearance similar to or improved over conventional packaging materials.

Although the packaging material may have suitable taste and burn properties, as discussed above, it has also been surprisingly found that the packaging material is a good carrier for other aerosol delivery agents, such as aerosol-generating fillers and topical additives, which may include flavors, active ingredients, oils and extracts. For example, as discussed above, one example of a topical additive may be a soluble portion of extracted hemp material, which may optionally be concentrated, which may be reapplied to the packaging material after web formation to impart additional taste and smoke characteristics. However, the aerosol-generating filler may be fibers from fibrous plants or herbs that are incorporated into the reconstituted web to add flavors or components. Thus, as used herein, aerosol delivery agents may be used to refer to both aerosol generating fillers and/or topical additives.

In particular, once the reconstituted plant material has been formed into a fibrous substrate, e.g., a wrapper, as described above, the material can be used as a wrapper for use with any suitable smoking article. The packaging material of the present disclosure produces an aerosol or smoke having a pleasant taste. It is particularly advantageous that the packaging material of the present disclosure is nicotine-free and can therefore be used for producing nicotine-free smoking articles or nicotine-free aerosol-generating products, or can be used for controlling nicotine delivery in such products.

In one embodiment of the invention, the hemp fibers used to make the packaging material of the present disclosure can also be mixed with tobacco material, optionally in addition to web building fibers, for forming aerosol-generating materials with reduced nicotine delivery and desirable taste and odor. The tobacco material mixed with the hemp fibers of the present disclosure may comprise, for example, cut tobacco, stems, scraps (scraps), dust (dust), or any other by-product from tobacco plants.

For example, the wrapper of the present disclosure may be combined with tobacco during manufacture of the wrapper or may be used to surround a tobacco material to form an aerosol-generating material that produces an aerosol or smoke having a controlled amount of nicotine as compared to the aerosol produced by the tobacco material itself. For example, the packaging material of the present disclosure can be combined with, or surround, any suitable tobacco material in an amount sufficient to produce an aerosol comprising a controlled amount of nicotine or tobacco flavoring. For example, in one embodiment, the packaging material can contain a small amount of nicotine, particularly as compared to natural tobacco products, and can contain about 0.5% or less nicotine by weight of the packaging material. Alternatively, the packaging material can be formed to contain a "high" amount of nicotine as compared to the low nicotine embodiments described above, such that the packaging material contains greater than about 0.5% nicotine by weight of the packaging material.

In yet another embodiment, the packaging material of the present disclosure, as opposed to or in addition to being combined with or surrounding a tobacco material, can also be treated with an aerosol delivery composition comprising nicotine or a tobacco flavoring agent. For example, the aerosol delivery composition may be topically applied to a packaging material to incorporate a controlled amount of nicotine into the material. Applying nicotine to a packaging material can provide a number of benefits and advantages. For example, applying nicotine to the packaging material allows for the delivery of a precise amount of nicotine when the packaging material is converted to an aerosol and inhaled. In addition, nicotine may be applied to the packaging material in such a way that the amount of nicotine contained in the aerosol generated by the material is uniform and consistent between each puff. Thus, in one embodiment, the packaging materials of the present disclosure can be used to produce aerosol-producing materials that are taste neutral and pleasant, while still being able to deliver controlled amounts of nicotine.

For example, in one embodiment, the aerosol delivery composition applied to the packaging material may comprise a small amount of nicotine, particularly as compared to natural tobacco products, and may comprise about 0.5% or less nicotine by weight of the packaging material. Alternatively, the packaging material can be formed to contain a "high" amount of nicotine as compared to the low nicotine embodiments described above, such that the packaging material contains greater than about 0.5% nicotine by weight of the packaging material. Additionally or alternatively, a tobacco material that can have all or a portion of the nicotine extracted therefrom can be used to produce tobacco taste and odor, and the nicotine can be separately applied to the packaging material in the form of an aerosol delivery composition to better control nicotine levels. In this embodiment, the amount of tobacco material in the aerosol-generating material may be less than about 50 wt%, for example less than about 40 wt%, for example less than about 30 wt%, for example less than about 20 wt%, such as less than about 10 wt%, and typically greater than about 2 wt%.

In addition to being combined with tobacco material, it will be appreciated that the wrapper of the present disclosure may be combined with any suitable aerosol-generating fibres, or may surround any suitable aerosol-generating filler. For example, the packaging material of the present disclosure may also be combined with aerosol-generating fillers made from other plant materials, such as herbs, geographical plants (botanic plants) and trees, including herbs, plants and trees that may be used to form smokable fibers or herbal smokable products, such as cocoa, coffee or coffee beans, tea or tea, vines, ginger, ginkgo biloba, chamomile, tomato, ivy, yerba mate, leja tea, cucumber, mint, grains such as wheat, barley or rye, or other trees such as broad leaf or resin trees, and combinations thereof.

In addition to nicotine, the packaging materials of the present disclosure are well suited for receiving other aerosol delivery agents. For example, the packaging material is highly absorbable and may contain up to 40% by weight of topical additives. In this regard, the packaging materials of the present disclosure are also well suited to serve as carriers for a variety of different aerosol delivery compositions. For example, each aerosol delivery composition may comprise one or more aerosol delivery agents.

Aerosol delivery compositions that can be applied to the packaging material of the present disclosure include solutions, suspensions, oils, and the like. For example, the solution and suspension may be applied to the packaging material and subsequently dried, leaving a solid residue within the fibrous substrate.

In one embodiment, the aerosol delivery composition may be obtained by extracting plant matter from a plant for application to a packaging material. Additionally or alternatively, the present disclosure may comprise a step for isolating at least one compound from the plant matter, concentrating the plant matter, or even purifying or eliminating the compound from the plant matter, to obtain a modified plant matter to be applied to the packaging material. Although optional, such methods can result in the conversion of the original raw plant matter into modified plant matter, in the form of a dry extract, a liquid extract, a solution, or an isolated substance, based on the desired final properties of the plant matter to be applied to the packaging material. Of course, while the plant matter may be original plant matter or modified plant matter, in one embodiment, the plant matter is applied to the packaging material after extraction without undergoing any further processing. Further, while the aerosol delivery composition has been described as being extracted from a plant, it is to be understood that synthetic or naturally occurring aerosol delivery compositions may also be used (e.g., extraction is not required).

Examples of aerosol delivery agents that may be included in the aerosol delivery composition include or may be extracts of (in addition to nicotine): sugar, licorice extracts, menthol, honey, coffee extracts, maple syrup, tobacco extracts, regional plant extracts, tea extracts, fruit extracts, flavourings such as clove, anise, cinnamon, sandalwood, geranium, rose oil, vanilla, caramel, cocoa, lemon oil, cinnamon, spearmint, fennel or ginger, flavourings or aromas such as cocoa, vanilla and caramel, medicinal plants, vegetables, spices, roots, berries, bar, seeks, essential oils and extracts thereof such as anise oil, clove oil, carvone and the like, artificial flavourings and flavouring materials such as vanillin and mixtures thereof. The extract applied to the packaging material may be water soluble or water dispersible. Thus, a variety of different carrier liquids may be used to apply the aerosol delivery agent to the packaging material.

In one embodiment, the packaging material of the present disclosure may be used as a carrier for components obtained from cannabis. For example, cannabis has recently been legalized in many states of the united states for medical and recreational use. In addition, the various chemicals and compounds contained in cannabis are becoming increasingly popular analgesic drugs to replace conventional analgesic drugs, such as opioids. For example, cannabis contains a variety of cannabinoids which may be used for analgesia. Inhalation of aerosols generated from cannabis is the most common and least expensive method for delivering drugs contained in cannabis to users. Unfortunately, however, inhalation of only aerosols generated by dried cannabis buds or leaves can result in uneven delivery of analgesic drugs contained in the plant. For example, the delivery of cannabinoids may vary significantly depending on the particular plant and particular plant parts used to generate the aerosol. In addition, cannabinoid delivery can vary significantly depending on other factors such as the packing density of the material, the particular type of aerosol-generating device or smoking article used to generate the aerosol, and so forth. Additionally, aerosols produced by the cannabis plant may contain irritants and produce a relatively irritating (hash) aerosol or smoke. For example, the aerosol produced by the packaging material of the present disclosure is non-irritating and has a neutral taste. Cannabinoids that may be incorporated into the packaging material of the present disclosure include Cannabidiol (CBD) and Tetrahydrocannabinol (THC). THC contained in cannabis acts on specific receptors in the brain, resulting in euphoria and a relaxed state. CBD, on the other hand, also interacts with pain receptors in the brain, but does not produce the same euphoric effects as THC does. In accordance with the present disclosure, in one embodiment, THC may be applied to the packaging material of the present disclosure, CBD may be applied to the packaging material, or alternatively, both THC and CBD may be applied to the packaging material.

In addition to THC and CBD, various other cannabinoids may be incorporated into aerosol delivery compositions and applied to packaging materials in accordance with the present disclosure. For example, other cannabinoids contained in cannabis include cannabichromene, cannabinol, cannabigerol, tetrahydrocannabivarin, cannabidivarin, cannabidiolic acid, other cannabidiol derivatives and other tetrahydrocannabinol derivatives. The cannabinoids may be used alone or in any combination and applied to the packaging material.

The cannabinoids described above may be applied to the packaging material using a variety of different methods. For example, in one embodiment, the cannabinoid, e.g., CBD, can be formulated as a water-soluble form or powder that can be applied to the packaging material as a solution or aqueous suspension. Alternatively, the cannabis oil extract may be obtained from unprocessed cannabis plants. The oil extract may comprise THC alone, CBD alone, or a combination of THC and CBD. The oil extract can be applied to a packaging material such that an aerosol produced from the material contains a controlled amount of cannabinoid. In addition to containing controlled amounts of cannabinoids, the packaging material may also be designed to provide uniform delivery of cannabinoids in an aerosol generated by the material.

Additional components that may be added to the reconstituted cannabis material are various flavorants, particularly terpenes. For example, a terpene or mixture of terpenes may be used to produce a desired aroma and indicate to the user the quality of the product. The one or more terpenes may also improve the sensory response to inhalation of aerosols generated by the reconstituted material.

Various terpenes can be applied to reconstituted plant material. Such terpenes include, but are not limited to, pinene, humulene, b-caryophyllene, isopulegol, guaiol, neryl acetate, neomenthyl acetate, limonene, menthone, dihydrojasmone, terpinolene, menthol, phellandrene, terpinene, geranyl acetate, ocimene, myrcene, 1, 4-cineole, 3-carene, linalool, menthofuran, perillyl alcohol, pinane, neomenthyl acetate (neomentha), alpha-bisabolol, borneol, camphene, camphor, caryophyllene oxide, alpha-cedrene, beta-geraniol, fenchyl, geraniol, isoborneol, nerol, sabinene, alpha-terpineol, and mixtures thereof.

In one embodiment, various terpenes may be mixed together in order to mimic the proportion of terpenes found in natural cannabis plants. For example, from about 2 to about 12 terpenes can be mixed together and applied to the reconstituted plant material. Each terpene may be applied to the reconstituted plant material in an amount greater than about 0.001% by weight and typically less than about 2% by weight. For example, each terpene may be applied in an amount of about 0.01% to about 1.5% by weight. For example, each terpene may be applied in an amount of about 0.1 wt% to about 1.1 wt%.

Exemplary mixtures of terpenes include α -pinene, β -caryophyllene, and β -pinene; alpha-humulene, alpha-pinene, beta-caryophyllene, beta-pinene and guaiol; beta-caryophyllene, beta-pinene and d-limonene; beta-caryophyllene, beta-pinene and nerolidol; beta-caryophyllene, beta-pinene, d-limonene and terpinolene; alpha-bisabolol, alpha-pinene, beta-caryophyllene, beta-myrcene, beta-pinene and d-limonene; beta-caryophyllene, beta-pinene and p-cymene; alpha-humulene, beta-caryophyllene, beta-pinene, d-limonene, linalool and nerolidol; beta-caryophyllene and beta-pinene; beta-caryophyllene, beta-myrcene and terpinolene; alpha-pinene, beta-caryophyllene, beta-pinene and d-limonene; alpha-humulene, alpha-pinene, beta-caryophyllene, beta-myrcene, beta-pinene, d-limonene and guaiol.

Regardless of the aerosol delivery composition and aerosol delivery agent selected, the packaging material according to the present disclosure may be used as a carrier for the aerosol delivery composition and aerosol agent. The packaging material may also exhibit the taste and odor imparted by the aerosol delivery composition and aerosol delivery agent due to the pleasant natural cannabis taste and odor of the packaging material. The aerosol delivery composition and aerosol delivery agent may be included in the packaging material in an amount greater than about 0.1%, such as at least about 1% or more, such as at least about 5% or more, such as at least about 10% or more, such as at least about 15% or more, such as at least about 20% or more, such as at least about 25% or more, such as at least about 30% or more, such as at least about 35% or more, such as 40% or less, or any range therebetween, by weight. Of course, in one embodiment, the soluble portion of the cannabis material may be reapplied to the packaging material. While the soluble portion may be applied in any amount as discussed above for the aerosol delivery compositions, the soluble portion of the cannabis material may be included in the packaging material in an amount of greater than about 0.1%, such as at least about 1% or higher, such as at least about 5% or higher, such as at least about 10% or higher, such as at least about 15% or higher, such as at least about 20% or higher, such as at least about 25% or higher, such as at least about 30% or higher, such as at least about 35% or higher, such as 40% or lower, by weight.

The wrapper made according to the present disclosure may be incorporated into all different types of smoking articles and aerosol-generating materials. For illustrative purposes only, one such smoking article is shown in fig. 1 and 2. As shown, the smoking article 10 includes a smokeable column 12. The smoking article 10 may also include a wrapper 100 that defines an outer peripheral surface 16 when wrapped around the smokable rod 12. The article 10 may also include a filter 26 which may be surrounded by tipping paper, however, depending on the smokable column material, the filter may be optional or may be omitted.

The smoking articles shown in figures 1 and 2 typically comprise cannabis cigarettes. However, in other embodiments, the packaging materials of the present disclosure may be used to prepare other cannabis and cannabis products, as well as herbal cigarettes, cigarillos and cigarillos, or pre-rolled cones or even conventional tobacco smoking articles. Although not shown, for example, a cigarillo may include a plastic tip.

While articles of manufacture may employ packaging material 100 according to the present disclosure, fig. 3a illustrates one embodiment of the present disclosure in which the packaging material 100 is formulated as a booklet of individual packaging materials, the individual packaging materials 100 being affixed to one or more adjacent packaging materials 100 by natural or at least smokable or edible adhesive 104. As shown in fig. 3b, in one embodiment, the adhesive 104 may be located on only a portion of the packaging material 100, such as on one edge 106 thereof. Additionally or alternatively, the adhesive may be located only on the first side 108 opposite the second side 110. In such embodiments, the first side 108 of the first wrapper 100 may have the adhesive 104 located thereon, and may be oriented so as to be placed in contact with the second side 110 of an adjacent piece of wrapper 100. Thus, each sheet of packaging material 100 may have adhesive on a single side for adhering to an immediately adjacent sheet of packaging material 100 or backing material 112. However, it should be understood that in alternative embodiments, the adhesive 104 may be located on both sides 108 and 110, or on one or more portions on either side 108 and 110.

Regardless of the manner in which the adhesive is applied, the adhesive may be selected to be "resealable" in that the adhesive may be used to releasably affix a piece of packaging material 100 to an adjacent piece of packaging material 100 until such time as the user desires to remove a piece of packaging material 100 from the adjacent piece of packaging material. At this point, the adhesive 104 may retain its adhesive properties and may adhere to the portion of the packaging material 100 to which the adhesive 104 has been applied, e.g., with reference to fig. 2, the adhesive 104 may adhere the first edge 114 of the packaging material 100, or an area of the packaging material adjacent to the first edge 114, to the second edge 116, or an area of the packaging material adjacent to the second edge 116, when forming the smoking article. Of course, the adhesive 104 may also be used to attach the packaging material 100 to a second sheet of packaging material 100, or any portion on either side of the packaging material 100 to which the adhesive 104 has been applied. For example, embodiments of the adhesive 104 that may be used or desired are for hand-rolled smoking articles.

Regardless, while the sealable or resealable material, such as an adhesive, may be applied by a number of different methods, in one embodiment, the sealable material or adhesive may be applied by an off-line method or an in-line gumming method. The adhesive 104 may be applied to at least one portion, e.g., at least two portions, at least three portions, or more, of the packaging material using either method or another method, and in one embodiment, the adhesive 104 may be applied to all or most of at least one side of the packaging material using either method or another method. Nonetheless, when the adhesive 104 is applied using off-line glue, the adhesive 104 may be applied by various techniques including coating, spraying, and printing. Rather, as described in the present disclosure, in-line sizing may include adding one or more adhesives 104 to the size press during the packaging material production process.

Regardless of the manner in which the binder 104 is applied to the packaging material 100, in one embodiment, the binder may include alginate, gum arabic, guar gum, pectin, polyvinyl alcohol, polyvinyl acetate, cellulose derivatives such as ethyl cellulose, methyl cellulose, and carboxymethyl cellulose, starch derivatives, and the like.

In a particular embodiment, the binder material may include gum arabic, cellulose, and/or cellulose derivatives. In one embodiment, the cellulose derivative comprises carboxymethyl cellulose (CMC), methyl Cellulose (CM), hydroxypropyl methyl cellulose (HPMC). Of course, it should be understood that other adhesive materials may be used as known in the art.

Regardless of the adhesive used, the adhesive may be present on the packaging material or web in an amount of about 0.1% to about 15% by weight, for example about 2% to about 5% by weight. In one embodiment, the binder may be applied by spraying, such as micro-spraying, or may be otherwise applied to form a thin coating on the desired area.

In one embodiment, smoking articles made according to the present disclosure may also have a reduced burn propensity feature. For example, the wrapper of the present disclosure may be used as an outer wrapper for a smoking article and may comprise a plurality of discrete reduced burn zones spaced apart in the axial direction of the smoking article. For example, in one embodiment, the discrete retarded combustion zone may be in the form of a circular band. The strip may have a width such that if the smoking article is in a static burning state, oxygen is limited only to extinguishing embers for a sufficient length or period of time to retain burning embers (coal). For example, the strip may have a width of typically more than about 3mm, such as more than about 4mm, such as more than about 5mm, and typically less than about 10mm, such as less than about 8mm, such as less than about 7 mm.

The spacing between the retarded combustion zones may also vary depending on a number of variables. The spacing should not be so great as to allow the cigarette to burn for a sufficient time to ignite the substrate before the coal burns into the reduced velocity combustion zone. This spacing can also affect the thermal inertia of the burning coal, or the ability of the coal to burn through the retarded combustion zone without self-extinguishing. Typically, the strip pitch should be greater than about 5mm, such as greater than about 10mm, such as greater than about 15mm, and typically less than about 50mm, such as less than about 40mm, such as less than about 30 mm. Each smoking article may comprise from about 1 to about 3 strips.

In general, any suitable reduced combustion composition may be applied to the outer wrapper/wrapper of the smoking article. In one embodiment, for example, the retarded combustion composition comprises a film-forming material. For example, film-forming materials that may be used in accordance with the present invention include alginates, guar gum, pectin, polyvinyl alcohol, polyvinyl acetate, cellulose derivatives such as ethyl cellulose, methyl cellulose, and carboxymethyl cellulose, starch derivatives, and the like.

In one embodiment, the film-forming material may comprise alginate alone or in combination with starch. Generally, alginates are derivatives of acidic polysaccharides or gums that are present in brown algae of the phaeophyceae class as insoluble mixed calcium, sodium, potassium and magnesium salts. In general, these derivatives are calcium, sodium, potassium and/or magnesium salts of high molecular weight polysaccharides composed of D-mannuronic acid and L-guluronic acid in varying proportions. Exemplary salts or derivatives of alginic acid include ammonium alginate, potassium alginate, sodium alginate, propylene glycol alginate, and/or mixtures thereof.

In one embodiment, relatively low molecular weight alginates may be used. For example, an alginate may have a viscosity of less than about 500cP when contained in a 3 wt% aqueous solution at 25 ℃. More particularly, the alginate may have a viscosity of less than 250cP, particularly less than 100cP, and in one embodiment about 20-60cP under the conditions described above. As used herein, viscosity is determined by a Brookfield LVF viscometer with appropriate spindle depending on the viscosity. At the lower viscosity levels described above, the alginate composition may be formed at a higher solids content, but still at a sufficiently low solution viscosity to allow the composition to be applied to a paper wrapper using conventional techniques. For example, the solids content of the alginate solution prepared according to the invention may be greater than about 6% by weight, particularly greater than about 10% by weight, more particularly from about 10% to about 20% by weight.

At the solids levels described above, the alginate compositions used according to the invention may have a solution viscosity of greater than about 250cP, particularly greater than about 500cP, more particularly greater than about 800cP at 25 ℃, and in one embodiment greater than about 1,000 cP. In general, the solution viscosity of the alginate film-forming composition can be adjusted depending on the manner in which the composition is applied to the package. For example, the solution viscosity of the composition can be adjusted depending on whether the composition is sprayed onto paper or printed onto paper.

In other embodiments, it is also understood that relatively high molecular weight alginates may be used, depending on the application. For example, an alginate may have a viscosity greater than about 500cP when contained in a 3 wt% aqueous solution at 25 ℃.

In addition to the film-forming material, the reduced-velocity combustion composition applied to the package may comprise various other ingredients.

For example, in one embodiment, a filler may be included in the composition. The filler may be, for example, calcium carbonate, calcium chloride, calcium lactate, calcium gluconate, or the like. In addition to the calcium compound, other various particles may be used, including magnesium compounds such as magnesium oxide, clay particles, and the like.

In one embodiment, the retarded combustion composition can be water-based. In particular, the retarded combustion composition may comprise an aqueous dispersion or an aqueous solution. Alternatively, the reduced velocity combustion composition may comprise a non-aqueous solution or dispersion prior to application to the paper wrapper. In this embodiment, for example, an alcohol may be present to apply the composition to the package.

In contrast to the film-forming composition, the retarded combustion composition may also comprise a cellulose pulp (a dispersion). As used herein, a slurry comprising a papermaking material is not a film-forming composition. The cellulose pulp applied to the paper substrate may comprise fibrous cellulose, one or more fillers and/or cellulose particles. As used herein, cellulose fibers and cellulose particles are distinct from derivatized cellulose, such as carboxymethyl cellulose. For example, cellulose fibers and cellulose particles are insoluble in water. In one embodiment, the cellulose pulp applied to the paper substrate may comprise microcrystalline cellulose.

Once the reduced burn composition is formulated, the composition may be applied to discrete areas of the paper wrapper. The manner in which the composition is applied to the paper wrapper may vary. For example, the composition can be sprayed, brushed, applied with a moving orifice, or printed onto the package. The composition may be applied in a single or multiple passes in order to form the treated region. For example, the composition may be applied to the wrapper paper in successive steps to form regions on the paper having a propensity to retard burning. Generally, in a multiple pass process, the treated region can be formed by applying the composition from about 2 to about 8 times.

The amount of the reduced burn composition applied to the wrapper can also vary. For example, the composition may be applied to the wrapper in an amount of less than about 15% by weight, such as less than about 10% by weight, such as less than about 8% by weight. Typically, the composition is applied in an amount greater than 1% by weight based on the weight of the composition within the retarded combustion region.

As used herein, the above weight percentages are based on the area treated with the chemical component. In other words, the weight percentage of the retarded combustion composition described above is the amount applied in the treated area, and not the total amount applied over the entire surface of the wrapper.

By the method of the present disclosure, a retarded combustion zone having a relatively high permeability while also having a relatively low diffusivity may be created. For example, the region of retarded combustion may have a permeability greater than 10CORESTA while still being able to produce a smoking article that passes ASTM test E2187-09 at least 75% of the time.

Generally, the retarded combustion region has a relatively low diffusivity. The diffusivity can be measured at room temperature (23 ℃). Typically, the diffusion rate of the retarded combustion zone at 23 ℃ is less than about 0.5cm/s, such as less than 0.4cm/s, such as less than 0.3 cm/s. In one embodiment, the retarded combustion zone can have a diffusivity greater than about 0.05cm/s, such as greater than about 0.15cm/s, such as greater than 0.16cm/s, such as greater than 0.17cm/s, while still having the desired retarded combustion propensity characteristics. Using Sodim CO₂The diffusivity tester measures diffusivity.

While additives in the packaging material may not be necessary, because the packaging material according to the present disclosure naturally has good manufacturing properties (e.g., tensile strength) and organoleptic properties, generally, the packaging material according to the present disclosure may include one or more additives. Additives may be used in the manufacture of packaging paper to facilitate the development or to impart new properties to the packaging material, such as chemical, optical, organoleptic or mechanical properties such as tear strength or fracture resistance. In one embodiment, the additive may be a humectant, filler, combustion control additive, gum, wet strength agent, oil and fat barrier agent, antiblock agent, dry strength agent, softener, wetting agent, or lattice (lattice).

In one embodiment, the reconstituted web material may also include a humectant. Humectants can be incorporated into packaging materials for a variety of different reasons to provide different benefits and advantages. For example, in one embodiment, a humectant may be incorporated into the packaging material to improve the processability and handleability of the resulting fibrous substrate.

While various humectants can be incorporated into the packaging materials of the present invention, the humectant can include polyhydric alcohols, non-polyhydric alcohols, or mixtures thereof. Typically the polyol generator may be sorbitol, glycerol, propylene glycol, triethylene glycol or mixtures thereof. Typically, the non-polyol generator may be lactic acid, diacetin, triacetin, triethyl citrate or isopropyl myristate or mixtures thereof. In one embodiment, the humectant is glycerin, propylene glycol or a mixture of glycerin and propylene glycol, with glycerin preferably being glycerin, propylene glycol or a mixture thereof. Regardless of the humectant chosen, the humectant may be present in the packaging material in an amount of from 0.1% to about 20% by weight of the packaging material, such as from about 1% to about 10%, for example from about 2% to about 8%, or any range therebetween, by weight of the packaging material.

The packaging material of the present disclosure may also optionally comprise a filler. The filler may comprise particles incorporated into the reconstituted web material for any desired purpose, such as for facilitating formation of the packaging material and/or for affecting the appearance or strength of the material. The filler may include kaolin, magnesium oxide, titanium dioxide, calcium carbonate, talc, barium sulfate, bentonite, zeolite, silicates, mica, or mixtures thereof. Furthermore, since the packaging material according to the present disclosure has a natural color and appearance, it is not necessary to select a white filler. Thus, additional fillers known in the art may be used. The addition of such fillers can alter some of the mechanical properties of the packaging material, in particular the properties allowing printing or writing thereon. Such fillers may also impart certain organoleptic properties to the packaging material.

The amount of filler in the packaging material according to the invention is from 0% to 40%, preferably from 5% to 20%, even more preferably from 10% to 20% by weight of the packaging material.

Further, in one embodiment, the particle size of the filler may be carefully controlled such that the average particle size of the filler is about 10 microns or less, for example about 7.5 microns or less, for example about 5 microns or less, and may also be about 0.1 microns or greater. Of course, in alternative embodiments, the particle size may be varied more based on the desired characteristics obtained from the filler.

For example, the combustion control agent may comprise a salt of a carboxylic acid. For example, the combustion control agent may comprise an alkali metal salt of a carboxylic acid, an alkaline earth metal salt of a carboxylic acid, or mixtures thereof. Examples of combustion control agents that may be used include acetates, citrates, malates, lactates, tartrates, carbonates, formates, propionates, glycolates, fumarates, oxalates, malonates, succinates, nitrates, phosphates or mixtures thereof. Specific burn control agents that may be used include potassium citrate, sodium citrate, potassium succinate, sodium succinate or mixtures thereof. When present, the burn control agent may typically be applied to the wrapper in an amount of greater than about 0.1% by weight, such as in an amount of greater than about 0.5% by weight, such as in an amount of greater than about 1% by weight, and typically in an amount of less than about 5% by weight, such as less than about 4% by weight, such as less than about 3% by weight, such as less than about 2% by weight.

Gums may include alginates, gum arabic, guar gum, pectin, polyvinyl alcohol, polyvinyl acetate, cellulose derivatives such as ethyl cellulose, methyl cellulose and carboxymethyl cellulose, starch derivatives, and the like. In a particular embodiment, the gum may comprise alginate alone or in combination with starch. Generally, alginates are derivatives of acidic polysaccharides or gums that are present in brown algae of the phaeophyceae class as insoluble mixed calcium, sodium, potassium and magnesium salts. In general, these derivatives are calcium, sodium, potassium and/or magnesium salts of high molecular weight polysaccharides consisting of D-mannuronic acid and L-guluronic acid in varying proportions. Exemplary alginates or derivatives include ammonium alginate, potassium alginate, sodium alginate, propylene glycol alginate, and/or mixtures thereof. In addition to the adhesive, a gum may be used, or in one embodiment, the gum may act as an adhesive and be provided as part of the web, rather than being applied to the exterior of the packaging material as discussed above.

The moisture enhancer may reduce the likelihood of degradation of the packaging material if the packaging material is placed in contact with a liquid, such as water. Generally, the wet strength agent may be selected from polyamides, such as epichlorohydrin resins, polyamine-epichlorohydrin resins, poly (aminoamide) -epichlorohydrin resins, urea-formaldehyde resins, melamine-formaldehyde resins; an alkyl ketene dimer; alkyl succinic anhydrides; a polyvinylamine; oxidizing the polysaccharide. Typically, the amount of wet strength agent is from 0.1% to 30%, preferably from 1% to 15%, even more preferably from 5% to 10% by dry weight of the packaging material.

Oil and fat blockers can reduce the absorption of fat by the paper. Generally, the oil and fat barriers may be selected from carboxymethylcellulose, polyacrylamide, acrylates, and latex.

Antiblocking agents can limit the adhesion of materials to paper. In general, the anti-blocking agent may be selected from the group consisting of carboxymethylcellulose, polyacrylamide, acrylates, silicones and latexes.

Dry strength agents can increase the resistance of the packaging material if it is subjected to large mechanical stresses. The dry strength agent may be selected from starches and modified gums, cellulosic polymers, synthetic polymers, such as carboxymethyl cellulose and polyacrylamide. Typically, the amount of dry strength agent is from 0.1% to 15%, preferably from 1% to 10%, even more preferably from 1% to 5% by dry weight of the packaging material.

The softener may improve the softness of the packaging material. Typically, the emollient is a fatty acid, a silicone compound, an aminosilicone compound, an aloe vera extract, a sweet almond extract, a chamomile extract, a quaternary ammonium compound. Typically, the amount of softener is from 0.1% to 30%, preferably from 1% to 15%, even more preferably from 5% to 10% by dry weight of the packaging material.

The finished web or package is dried and wound into a roll. For example, in one embodiment, the dried sheet is wound into a spool having a width of about 15mm to about 54mm, such as about 19mm to about 28 mm. Before winding the web into a reel, the web may be calendered to increase the smoothness and runnability of the material. In one embodiment, for example, a multi-nip calendering apparatus can be used.

The packaging material prepared according to the present disclosure has excellent mechanical properties and has a very desirable and aesthetic appearance. The aesthetic appearance can be further improved by adding dyes (synthetic and/or natural) and filigree (filigreeing) technology.

The invention may be better understood by reference to the following examples.

Examples

Example 1

A hemp wrapping paper using hemp fibers according to the present invention was prepared according to the following method: the hemp stems were ground to a particle size of 250-500 μm. The ground hemp material was then slurried in water at 70 ℃ for 30 minutes at a hemp to water ratio of 1: 20. The mixture was then processed through a centrifuge to separate the soluble fraction (hemp hydrosoluble) from the insoluble fraction (insoluble hemp fiber residue). The insoluble fraction was mixed with bleached hemp pulp in a ratio of 3:1 (dry weight: dry weight) of insoluble fraction to hemp pulp for use as a web building fiber from hemp, and then the mixed pulp was refined by a disc refiner. After refining, a base sheet is formed from the refined slurry. The water soluble fraction from the cannabis plant (also referred to herein as cannabis water solubles) is then mixed with various additives, including aerosol generating agents and/or pigments. The resulting reconstituted hemp material is finally dried to a web and formed into a hemp packaging material:

-sample a: a coating of 6% by weight of glycerol and about 2% by weight of dye, diluted in extracted hemp solubles.

-sample B: a coating of 6% by weight glycerin, about 2% by weight dye and 0.5% by weight flavoring (commonly referred to as irritation reducing flavoring) was diluted in extracted hemp solubles.

-sample C: a coating of 6% by weight of glycerin, about 2% by weight of a dye and 0.5% by weight of herbal flavors was diluted in extracted hemp solubles.

Manually forming samples A, B and C into smoking articles; empty tubes were filled with each sample individually and aspirated by a panel of 3 people.

Evaluation: all samples showed a uniform appearance with a hemp-like color. Sample a showed slightly lower irritating smoke and less spicy aftertaste than the reference cigarette paper made from 100% hemp pulp. The aroma is neutral to slightly papery.

Sample B exhibited even lower irritation than sample a.

Sample C exhibited a subtle and pleasant herbal fragrance as compared to sample A.

Example 2

Hemp packages were prepared according to the conditions described in example 1, except that variants were prepared with different types and levels of pigments. The color of the samples was measured according to the CIE Hunter L a b scale. The Hunter Lab color scale was created by Richard S.Hunter in 1948 and is described in "The Measurement of apparatus, edition 2, John Wiley and Sons, New York, New York, 1987. It describes all colors visible to the human eye and is created to serve as a device independent model for reference.

The three coordinates of the Hunter Lab scale represent the brightness of the color (L-0 yields black and L-100 represents diffuse white; specular white may be higher), its position between red/magenta and green (a, negative values represent green and positive values represent magenta), its position between yellow and blue (b, negative values represent blue and positive values represent yellow).

The results are shown below:

the results show that many colors can be achieved with hemp packaging materials and, in addition, that the hue can be adjusted to the desired target using a specific combination of pigments.

Example 3

A hemp package using hemp fibers according to the present invention was prepared according to the following method: hemp leaf and hemp flower were mixed in a ratio of 1:1 and ground to a particle size of 10 mm. The milled hemp mixture was then slurried in water at a 1:20 hemp to water ratio at 70 ℃ for 30 minutes. The mixture is then processed through a centrifuge to separate the soluble fraction (hemp hydrosoluble) from the insoluble fraction (insoluble hemp fiber residue). The insoluble fiber fraction was mixed with bleached hemp pulp in a ratio of 4:1 (dry weight: dry weight) of the insoluble fiber fraction to hemp pulp, used as a web building fiber from hemp, and the mixed pulp was refined by a disc refiner. After refining, a web or sheet is formed from the refined slurry. The soluble fraction derived from the hemp plant (also referred to herein as hemp hydrosoluble) is mixed with a solution of glycerol and methylcellulose. The final solution was coated on the web or sheet such that the final amount of methylcellulose contained on the dried web or sheet was 2.5 wt.% of the final product. Finally, the resulting material is dried.

After drying, the samples were tested for seal strength. The cannabis wrapper is tapped or moistened with an aqueous solution on one side and the moistened portion is adhered to the non-moistened portion of the cannabis wrapper to simulate a hand-rolled conventional smoking article. It was unexpectedly found that a very effective seal was created between the wet and non-wet portions of the hemp package prepared according to this example. Thus, the seal formed between the wet and non-wet portions of the hemp wrapper exhibits the desired properties of the alternative wrapper or hand-rolled smoking article.

Example 4

A hemp package using hemp fibers according to the present invention was prepared according to the following method: hemp leaf and hemp flower were mixed in a ratio of 1:1 and ground to a particle size of 10 mm. The milled hemp mixture was then slurried in water at 70 ℃ for 30 minutes at a 1:20 hemp to water ratio. The mixture is then processed through a centrifuge to separate the soluble fraction (hemp hydrosoluble) from the insoluble fiber fraction (insoluble hemp fiber residue). The fiber fraction was mixed with bleached hemp pulp in a ratio of 4:1 (dry weight: dry weight) of insoluble fiber fraction to hemp pulp, used as web building fiber from hemp, for the mixed pulp to then be refined by a disc refiner. After refining, a web or sheet is formed from the refined slurry. The soluble fraction derived from the cannabis plant (also referred to herein as cannabis water-solubles) is further concentrated in an evaporator to reach about 35% brix, then mixed with glycerol to form a solution. The final solution was then coated on a web or sheet to a solubles level of about 30 wt% (including 6 wt% glycerin) upon drying, based on the dry weight of the final product.

Evaluation: the web or sheet before coating with the solution showed a pleasant green color with noticeable spots, thereby showing a very natural appearance. It unexpectedly exhibited very good burning performance and a slightly noticeable hemp odor.

After coating the web or sheet with the solution, the final material exhibits a similar natural appearance, but a more yellow color and a more shiny appearance than the web or sheet before coating. The burning rate was observed to be rather slow, but not self-extinguishing, and exhibited a very pleasant hemp odor upon burning.

Example 5

A hemp wrapping paper using hemp fibers according to the present invention was prepared according to the following method: the mixture of hemp fibres and hemp leaves was ground to a particle size of 0.5 mm. The milled hemp mixture was then slurried in water at 70 ℃ for 30 minutes at a 1:10 hemp to water ratio. The mixture is then processed through a centrifuge to separate the soluble fraction (hemp hydrosoluble) from the insoluble fiber fraction (insoluble hemp fiber residue). The fiber fraction was mixed with bleached hemp pulp in a ratio of 4:1 (dry weight: dry weight) of insoluble fiber fraction to hemp pulp, used as web building fiber from hemp, for the mixed pulp to then be refined by a disc refiner. After refining, a base web or sheet is formed from the refined liquor. The soluble fraction derived from the cannabis plant (also referred to herein as cannabis water-solubles) is further concentrated in an evaporator to reach about 30% brix, then mixed with glycerol to form a solution. The final solution was then coated on a web or sheet to a solubles level of about 30 wt% upon drying, based on the dry weight of the final product. (in contrast, sample A contained 3% glycerol and sample B contained 8% glycerol)

Evaluation: before coating the solution web or sheet with the solution, the web or sheet showed a light yellow color with a very uniform distribution of hemp particles. It unexpectedly shows good burning properties and a pleasant, slightly aromatic taste.

After coating the web or sheet with the solution, the final material exhibited an appearance similar to the web or sheet before coating, but a darker and brighter yellow tint was observed. It was observed that the burning rate was rather slow, but did not self-extinguish, and the sample exhibited a mild and pleasant hemp odor upon burning. While not wishing to be bound by theory, the inventors believe that applying a higher level of glycerin in sample B provides a softer product texture.

Various packaging materials can be prepared according to the present invention. In one embodiment, the packaging material comprises a web containing a combination of extracted hemp fibers and web building fibers. The web may have a basis weight of about 20gsm to about 80gsm and may have a permeability of about 10Coresta to about 100 Coresta.

In any of the embodiments described above, the web building fibers combined with the extracted hemp fibers may vary. In one embodiment, the web building fibers are pulp fibers, such as softwood fibers, hardwood fibers, or mixtures thereof. In one embodiment, the web building fibers comprise softwood fibers and hardwood fibers in a ratio of 1:2 to 2: 1. In one embodiment, the web building fibers comprise flax fibers. In one embodiment, the web building fibers are abaca fibers. In one embodiment, the web building fibers are bamboo fibers. In one embodiment, the web building fibers are coconut fibers. In one embodiment, the web building fibers are ramie fibers. In one embodiment, the web building fibers are jute fibers. In one embodiment, the web building fibers are hemp pulp fibers. The hemp pulp fibers can be used alone or in combination with wood pulp fibers, such as softwood fibers, hardwood fibers, or mixtures thereof. In one embodiment, the web-building fibers are present in the packaging material in an amount greater than about 3% by weight. In one embodiment, the web-building fibers are present in the packaging material in an amount greater than about 5% by weight. In one embodiment, the web-building fibers are present in the packaging material in an amount greater than about 8 weight percent. In one embodiment, the web-building fibers are present in the packaging material in an amount greater than about 12% by weight. In one embodiment, the web-building fibers are present in the packaging material in an amount greater than about 18 weight percent. In one embodiment, the web-building fibers are present in the packaging material in an amount of less than about 50 weight percent, such as less than about 40 weight percent.

Extracted hemp fibers combined with web building fibers can be obtained from different sources. In one embodiment, the extracted hemp fibers comprise hemp leaves. In one embodiment, the extracted hemp fibers comprise hemp stems. In one embodiment, the hemp fibers comprise hemp sprouts. In one embodiment, the hemp fiber comprises hemp flowers. In one embodiment, the extracted hemp fibers comprise hemp sprouts and/or hemp flowers in combination with hemp leaves and/or hemp stems.

In one embodiment, the extracted hemp fibers can be obtained from raw materials. In one embodiment, the extracted hemp fiber can be obtained from hemp extraction byproducts, wherein the byproducts undergo additional water soluble extraction to form extracted hemp fiber. In one embodiment, the extracted hemp fibers can be obtained from a mixture of raw hemp material and hemp extraction byproducts.

In any of the embodiments described above, the packaging material may comprise a filler. The filler is combined with extracted hemp fibers and web building fibers. The filler may be present in an amount of about 1 wt% to about 40 wt%. The filler may comprise calcium carbonate particles. In one embodiment, the filler is magnesium oxide particles. In one embodiment, the filler is a combination of calcium carbonate particles and magnesium oxide particles.

In one embodiment, the web may be treated with a gum. In one embodiment, the web may be treated with a gum and a humectant.

In any of the embodiments described above, the wrapper may further comprise a plurality of discrete reduced burn zones spaced apart along the first direction of the wrapper. The retarded combustion zone can have a diffusivity of less than about 0.5cm/s at 23 ℃. In one embodiment, a plurality of reduced velocity combustion zones may be formed by applying a reduced velocity combustion composition to a web.

These and other modifications and variations to the present invention may be practiced by those of ordinary skill in the art, without departing from the spirit and scope of the present invention, which is more particularly set forth in the appended claims. Additionally, it should be understood that aspects of the various embodiments may be interchanged both in whole or in part. Furthermore, those of ordinary skill in the art will appreciate that the foregoing description is by way of example only, and is not intended to limit the invention so further described in such appended claims.