阅读说明：本技术 使用复合梢部硼基预烧结预制件对涡轮机部件的梢部修复 (Tip repair of turbine components using composite tip boron-based pre-sintered preforms ) 是由 阿图尔·L·纳瓦莱 詹姆士·A·亚伯勒 萨默什·J·古纳基卡尔 伊万·F·奥利弗瓦尔加斯 于 2019-03-29 设计创作，主要内容包括：本发明涉及一种用于修复涡轮机叶片(10)的具有结构缺陷的梢部部分(22)的方法。该方法包括在梢部部分(22)中将具有结构缺陷的损坏部分去除和提供预烧结的预制件(60),该预烧结的预制件(60)包括具有第一组合物的第一部分(62)和具有第二组合物的第二部分(64)。预烧结的预制件(60)构造成与涡轮机叶片(10)的剩余部分的上表面配合。预烧结的预制件(60)包括超级合金材料和钎焊材料并且经受钎焊过程以使钎焊材料熔化并且填充在结构缺陷中。第一部分(62)可以是叶片搁板并且第二部分(64)可以是凹槽状部分。(The invention relates to a method for repairing a tip portion (22) of a turbine blade (10) having a structural defect. The method includes removing a damaged portion having a structural defect in the tip portion (22) and providing a pre-sintered preform (60), the pre-sintered preform (60) including a first portion (62) having a first composition and a second portion (64) having a second composition. The pre-sintered preform (60) is configured to mate with an upper surface of a remaining portion of the turbine blade (10). The pre-sintered preform (60) includes a superalloy material and a braze material and is subjected to a brazing process to cause the braze material to melt and fill in structural defects. The first portion (62) may be a blade shelf and the second portion (64) may be a fluted portion.)

1. A method for repairing a tip portion 22 of a turbine component 10 having a structural defect 55, the method comprising:

providing a turbine component 10, the turbine component 10 having a structural defect 55 in a tip portion 22 of the turbine component 10;

removing damaged sections by machining or cutting the tip portion 22 of the turbine component 10;

providing a pre-sintered preform (PSP)60, the pre-sintered preform (PSP)60 configured to mate with an upper surface of a remainder of the turbine component 10;

applying the PSP 60 to the upper surface, wherein the PSP 60 comprises a superalloy material and a braze material; and

subjecting the PSP 60 and the remainder of the turbine component 10 to a brazing process to cause the brazing material to melt and fill in the structural defect 55,

wherein the PSP 60 comprises a first part 62 having a first composition and a second part 64 having a second composition.

2. The method of claim 1, wherein the first portion corresponds to a shelf portion 62 of the tip and the second portion corresponds to a recessed portion 64 of the tip.

3. The method of claim 2, wherein the first composition comprises 60 to 90 wt.% of the superalloy material and 10 to 40 wt.% of the braze material, and wherein the second composition comprises 70 to 90 wt.% of the superalloy material and 10 to 30 wt.% of the braze material.

4. The method of claim 3, wherein the first composition comprises 70 wt.% of the superalloy material and 30 wt.% of the braze material, and wherein the second composition comprises 80 wt.% of the superalloy material and 20 wt.% of the braze material.

5. The method of claims 3 and 4, wherein the superalloy material is alloy 247.

6. The method as claimed in claim 3, wherein the superalloy material of the PSP 60 is the same as the material of the remainder of the turbine component 10.

7. The method of claim 3, wherein the braze material of the PSP 60 comprises boron.

8. The method of claim 1, wherein the applying comprises securing the pre-sintered preform 60 in at least one location of the upper surface by spot welding.

9. The method of claim 1, wherein the applying comprises fixing the pre-sintered preform 60 to the upper surface at only one location by spot welding.

10. A method as claimed in claim 1, wherein the brazing process comprises alternating between a first stage in which an amount of hydrogen is introduced into the environment surrounding the turbine component 10 effective to form a borohydride from boron and hydrogen in the brazing material, and a second stage in which the borohydride formed is removed via negative pressure.

11. The method of claim 3, further comprising applying a paste mixture of superalloy powder and binder to the wide crack 55 in the shelf portion 62.

12. A pre-sintered preform (PSP)60 corresponding to a tip 22 of a turbine component 10, the pre-sintered preform (PSP)60 comprising:

a tip shelf portion 62, the tip shelf portion 62 configured to mate with a top surface of a turbine component airfoil; and

a trough-like portion 64, the trough-like portion 64 extending radially outward from the tip shelf portion 62,

wherein the tip shelf portion 62 comprises a first composition and the recessed portion 64 comprises a second composition.

13. The pre-sintered preform 60 as set forth in claim 12 wherein said first composition and said second composition are different.

14. A PSP 60 as recited in claim 12, wherein the first composition comprises 60-90% by weight superalloy material and 10-40% by weight braze material, and wherein the second composition comprises 70-90% by weight superalloy material and 10-30% by weight braze material.

15. A PSP 60 as recited in claim 13, wherein the first composition comprises 70 wt.% of the superalloy material and 30 wt.% of the braze material, and wherein the second composition comprises 80 wt.% of the superalloy material and 20 wt.% of the braze material.

16. A PSP 60 as recited in claims 14 and 15, wherein the superalloy material is alloy 247.

17. A PSP 60 as in claim 14, wherein the superalloy material of the PSP 60 is the same as the material of the remainder of the turbine component 10.

18. A PSP 60 as recited in claim 14, wherein the braze material of the PSP 60 comprises boron.

Technical Field

The present disclosure relates generally to the field of metallurgy, and more particularly to a process for repairing structural defects in metal substrates, and even more particularly to tip repair of turbine components using composite boron-based pre-sintered preforms.

Background

Gas turbines are well known in the art. Increasing the thermal efficiency of a gas turbine cycle is a continuing quest in the field of gas turbines. One way to achieve this goal is by developing materials that are increasingly resistant to high temperatures or materials that are capable of maintaining their structural integrity over time at high temperatures. To this end, hot gas path components of gas turbine engines are typically formed from superalloy materials. The term "superalloy" is used herein as it is commonly used in the art, referring to a highly corrosion and oxidation resistant alloy that exhibits excellent mechanical strength and creep resistance at high temperatures, e.g., greater than 1000 ℃.

Superalloy components in the hot gas path of a turbine engine, regardless of their strength, are susceptible to damage (defects) due to prolonged exposure to significant thermal and mechanical stresses. It is well known that superalloy materials are one of the most difficult materials to repair. However, welding of many superalloys is difficult because these materials are prone to weld solidification cracking and strain age cracking. Accordingly, repair processes for superalloy materials that eliminate welding while maintaining the structural integrity of the component are desirable.

Disclosure of Invention

Briefly described, aspects of the present disclosure relate to a method for repairing a tip portion of a turbine component having a structural defect and a pre-sintered preform (PSP) corresponding to the tip of the turbine component.

The disclosed embodiments are directed to a method for repairing a tip portion of a turbine component having a structural defect. The method includes grinding a turbine component having a structural defect at its tip portion and then removing the damaged portion by machining or cutting the tip portion. A pre-sintered preform (PSP) configured to mate with an upper surface of a remainder of a turbine component is provided and then applied thereto. The pre-sintered preform may include a superalloy material and a braze material. The combined PSP and turbine component may be subjected to the following brazing (brazing) process: during this brazing process, the brazing material melts and fills in structural defects. The PSP includes a first part having a first composition and a second part having a second composition. The method allows the use of boron in the brazing material to reduce the temperature at which brazing is carried out.

Another disclosed embodiment is directed to a pre-sintered preform (PSP) corresponding to a tip of a turbine component. The PSP includes a tip shelf portion configured to mate with a top surface of the turbine component airfoil and a squealer tip portion extending radially from the tip shelf portion. The tip shelf portion includes a first composition and the trough portion includes a second composition.

Drawings

FIG. 1 is an axial cross-sectional view of a gas turbine engine having a row of turbine blades that may incorporate embodiments of the present invention,

figure 2 is a partial cross-sectional view of the configuration of the tip portion of the turbine component,

figure 3 is a perspective view of a PSP composite tip specimen according to an embodiment of the invention,

FIG. 4 is a graph depicting an embodiment of a brazing heat treatment cycle, an

FIG. 5 is a perspective view of a turbine blade repaired with a composite PSP coupon, according to an embodiment.

Detailed Description

To facilitate an understanding of the embodiments, principles and features of the present disclosure, the embodiments, principles and features of the present disclosure are described below with reference to implementations in illustrative embodiments. However, embodiments of the present disclosure are not limited to use in the described systems or methods.

The components and materials making up the various embodiments described below are intended to be illustrative and not limiting. Many suitable components and materials that will perform the same or similar function as the materials described herein are intended to be included within the scope of embodiments of the present disclosure.

The gas turbine engine may include a compressor section, a combustor, and a turbine section. The compressor section compresses ambient air. The combustor combines the compressed air with fuel and ignites the mixture, thereby generating combustion products that include hot gases that form a working fluid. The working fluid travels to the turbine section. Within the turbine section there are circumferentially alternating rows of blades and vanes, the vanes being coupled to the rotor. Each pair of blades and vanes in the row of blades and vanes forms a stage in the turbine section. The turbine section includes a stationary turbine housing that houses the blades, vanes, and rotor.

The turbine blade includes a radially inner root portion and a radially outer tip portion. The tips of the turbine blades may have tip features to reduce the size of the gap between the annular section and the blades in the gas path of the turbine to prevent tip flow leakage, which reduces the amount of torque generated by the turbine blades. The tip feature may be referred to as a squealer tip and is bonded to the tip of the blade to help reduce aerodynamic losses between turbine stages. These features are designed to minimize leakage between the blade tip and the annular section.

Currently, structural defects affecting the tip region of a turbine component, such as a blade or wheel blade, involve grinding of the squealer tip and weld build-up with filler material. Further, cracks in the tip shelf portion and the airfoil may be removed by weld repairing the damaged portion with a filler material at ambient temperature or at an elevated temperature using a hot box weld repair process. Hot box weld repairs may take eight hours or more to complete, and the requirement to work inside the hot box to maintain elevated temperatures makes it difficult to perform such welds.

Broadly, the inventors propose a brazing process that utilizes pre-sintered preforms (PSPs) of various compositions to repair structural defects of the tip portion of the turbine component. The "braze only" process may be used to repair tip damage of a turbine component without any weld repair process. By not requiring welding, all disadvantages of the welding process, such as the need for overaging heat treatment, the need for skilled welders, and heat affected zone cracking, are eliminated.

A pre-sintered preform (PSP) typically comprises a powder mixture of base alloy particles and brazing alloy particles, which is pre-sintered such that the particles establish a metallurgical bond. Furthermore, the pre-sintered preform does not comprise a binder material that creates voids. The pre-sintered material is formed into a net shape that can be used in a repair process such as that proposed. In the case of the proposed repair procedure, a composite boron-based PSP of the turbine component tip may be utilized.

Referring to FIG. 1, a portion of a turbine engine 32 is shown. Centerline 11 is shown to represent the axial center of turbine engine 32. The radial direction Ra is shown as being in a radially outward direction. Further, the working fluid Wf direction is shown. The turbine blade 10 is formed from a root portion 34 coupled to a rotor disk (not shown) and an elongated portion forming an airfoil 12, the airfoil 12 extending outwardly from a platform 24 coupled to the root portion 34. At the opposite end of the turbine blade 10, the blade 10 is made up of a tip 22, a leading edge 14 and a trailing edge 16 opposite a root portion 34. Radially extending pressure and suction sides 18, 20 of the airfoil 12 connect the leading and trailing edges 14, 16. Tip features are provided in position along the tip end 22 of the turbine blade 10 to reduce the size of the gap between the annular section 26 in the gas path of the turbine and the blade 10 to prevent tip flow leakage, which reduces the amount of torque generated by the turbine blade 10. The tip features are referred to as squealer or squealer tips and are incorporated on the tip of the blade to help reduce aerodynamic losses between turbine stages. These features are designed to minimize leakage between the blade tip 22 and the annular section 26.

FIG. 2 illustrates the location of a conventional squealer tip 36 in which spaced apart tip walls extend directly upward from the pressure and suction sides 18, 20 of the blade 10 and extend the length of the pressure and suction sides 18, 20 of the blade 10. At the tip end 22 between the fluted tip walls 36 there is a tip shelf 40 with a tip shelf surface 50.

As mentioned above, it is understood that during operation, particularly in the early stages of a turbine engine, the blades may be susceptible to significant thermal and mechanical stresses. Thus, particularly with some superalloys, cracks and other defects are often seen to occur on the tip of the blade, particularly in the fluted tip wall 36 and shelf region 40 of the tip 22. For example, fig. 2 shows tip 22 including a crack (discontinuity) 55 extending into recessed tip 36 of the tip and into shelf region 40. Although cracks are shown, other defects such as squealer tip rub or shelf rub may also be considered defects that require repair.

The turbine component may comprise any suitable metallic material. In an embodiment, the turbine component may comprise a superalloy material. For illustrative purposes, the turbine component referred to herein will be a turbine blade. Exemplary superalloys include, but are not limited to, hastelloy, Inconel alloys (e.g., IN100, IN600, IN713), wolpalloy, raney, haynes, Incoloy, MP98T, TMS alloys, and CMSX (e.g., CMSX-4) single crystal alloys. In particular embodiments, the turbine component is formed from an alloy 247 material (such as CM247 or MAR-M247 materials known in the art and commercially available from Praxair Surface Technologies). In an embodiment, the alloy 247 material may have a composition (in weight%) within the following ranges:

C＝0.07-0.15％

Cr＝8.1-8.4％

Co＝9.2-10.0％

Al＝5.5-5.6％

B＝0.015％

W＝9.5-10.0％

Mo＝0.5-0.7％

Ta＝3.0-3.2％

Ti＝0.7-1.0％

Hf＝1.4-1.5％

Zr＝0.015-0.05％

ni as the rest

Fig. 3 shows a composite PSP tip specimen 60 to be used to repair a turbine component. The composite tip specimen 60 includes a tip shelf (cover) portion 62 and a trough-like portion 64. The tip shelf portion 62 includes a first composition and the trough portion 64 includes a second composition. In an embodiment, the first composition and the second composition are different. Each portion of the PSP may include a powder mixture including braze particles and superalloy particles formed into a tip shelf shape and a squealer tip shape, respectively, and configured to mate with a remainder of the turbine component, such as a blade airfoil. In an embodiment, the first thickness of the tip shelf portion 62 may be in the range of 0.030 inches to 0.050 inches, and the second thickness of the trough portion 64 may be in the range of 0.060 inches to 0.140 inches. If the blade shelf is very thin, for example 0.040 inches, the base thickness of the blade shelf can be increased by attaching additional shelf PSP material 62 to the existing shelf portion prior to attaching the composite coupon.

The braze material may include any suitable material known in the art for brazing that includes at least an amount of boron relative to the same braze material without the amount of boron effective to lower the melting temperature of the braze material. In embodiments, the amount of boron may be an amount of boron effective to reduce the melting temperature of the brazing material to a desired degree. In a particular embodiment, the brazing material comprises an amount of boron and a first powder material comprising the same alloy composition as in the damaged area of the component to be brazed/repaired. Suitable braze material compositions may be found in PCT/US2018/020170, Brazing of super alloys with Hydrogen Addition for Boron Capture (Brazing of Superalloy Components by the Addition of Hydrogen to Capture Boron), which is incorporated herein by reference.

Referring now to fig. 1-3, a method for repairing a tip portion of a turbine component having a structural defect is presented. Although the turbine component is depicted in this specification as a turbine blade and as shown in the drawings, it will be understood that the repair process described herein is not limited to blades, but may also be applied to other damaged metal components. The turbine blade 10 is prepared for the repair process by first removing the damaged tip portion 22 from the remaining turbine blade airfoil 12. Removing the damaged portion requires machining and/or cutting at least the squealer portion 36 of the turbine blade airfoil 12 having the damaged portion. Additionally, if the shelf portion 40 includes wide cracks, such as cracks wider than about 0.020 inches, the cracks may be filled with a paste. When the turbine blade 10 includes the alloy 247, the paste may be, for example, a 247 paste formed by mixing the alloy 247 with a suitable binder. In an embodiment, the upper surface of the remaining blade airfoil 12 may then be machined, for example to create a smooth flat surface, to mate with the surface of the composite PSP tip portion 60 that will replace the removed damaged tip portion. One difference between the repair process and other conventional processes is that the application with paste is only required when there are through cracks in the shelf portion. Otherwise, the PSP composition may handle defects during brazing, i.e. the brazing material may flow into and fill the cracks. This in turn allows for complete repair and facilitates the determination of where the paste is needed.

Prior to paste application and brazing, optionally, the area including structural defects of the component may be cleaned. In embodiments, the cleaning step may be performed using Fluoride Ion Cleaning (FIC). In particular embodiments, damaged areas, including defects, may be cleaned via a Fluoride Ion Cleaning (FIC) process to prepare the damaged surface for brazing. In some cases, it may be necessary to physically open the crack prior to the FIC process. In some embodiments, the FIC process includes cleaning with hydrogen fluoride gas. The use of FIC cleaning advantageously removes unwanted oxides and residual coating residues (e.g., diffusion coating residues) within defects and on the surface of components.

In an embodiment, the surface of the PSP tip specimen 60 is applied to the prepared surface of the remaining blade airfoil 12. The PSP tip coupon 60 may be lightly affixed to the surface of the blade shelf surface 50 by spot welding, particularly by spot welding in only one or two locations to avoid binding the PSP tip coupon 60 or to avoid popping off the PSP tip coupon 60 during brazing. There may be a gap between the surface to be brazed and the PSP tip specimen 60. During the brazing heat treatment cycle, the PSP tip coupon 60 will form to the surface being brazed.

Once the PSP tip coupon 60 containing the braze material has been applied as desired or necessary, the turbine blade along with the PSP is subjected to a heat treatment (referred to herein as a "braze" or "brazing process") to at least melt the braze material and allow the melted braze material to flow into the defect. In an embodiment, the Brazing heat treatment may be a controlled heat treatment process as described in PCT/US2018/020170, Brazing of super Components with Hydrogen Addition for Boron Capture (Brazing of Superalloy Components by the Addition of Hydrogen to Capture Boron). The main difference between this heat treatment process and other brazing heat treatment processes is that the components, such as the turbine blade and the secured PSP, are subjected to alternating stages in a hydrogen environment ("hydrogen stage") and in a vacuum environment ("vacuum stage") while heating the brazing material and at least a portion of the turbine blade. This alternating process 70 can be seen in the brazing heat treatment diagram shown in fig. 4. The alternation between the hydrogen phase and the vacuum phase helps to eliminate centerline eutectic and improve the post-braze re-melting properties due to the occurrence of boron depletion of the low melting fraction of the braze mixture. Eliminating centerline eutectics avoids brittle areas in the repair area that are prone to cracking during service conditions.

FIG. 5 illustrates a perspective view of a turbine blade 10 being repaired using a composite PSP coupon 60. FIG. 5 shows the tip 22 after brazing. In certain embodiments, finishing processes, such as mixing, machining, cooling hole drilling, and coating operations, may be performed where applicable, depending on the desired final blade configuration.

The present disclosure provides a process for repairing tip portions of turbine components without the need for welds that are expensive, time consuming, and may cause weld-related cracking and distortion. For example, the composite PSP tip specimen allows for one material composition for the squealer tip portion and a different material composition for the shelf portion of the turbine airfoil. PSP composition selection is based on operating conditions and the damage mode requiring repair. Having a squealer portion with a higher percentage of base alloy material and less braze material allows the squealer portion to have better oxidation and wear properties, while a higher percentage of braze material may be required in the shelf portion than in the tip portion to fill cracks in the blade shelf. Finally, the PSP tip specimen is used in combination with minimal paste application, among other benefits, resulting in a part that better conforms to existing and/or desired final geometries. This in turn reduces the amount of post-processing (mixing or machining) required after the process is complete. Since the brazing work is based on capillary action, the possibility of clogging the lumen is also minimized by appropriate treatment and measures. Although the described embodiments are directed to turbine blade repair, the proposed method may also be extended to repair of other superalloy components.

Although the embodiments of the present disclosure have been disclosed in exemplary forms, it will be apparent to those skilled in the art that many modifications, additions and deletions can be made in the embodiments of the disclosure without departing from the spirit and scope of the disclosure and its equivalents as set forth in the appended claims.