阅读说明：本技术 建筑用一体成型复合保温板材及其制备方法 (Integrally-formed composite heat-insulation board for building and preparation method thereof ) 是由 张继承 董会娜 何凤霞 李帅帅 张东生 姚栋嘉 刘喜宗 吴恒 于 2021-10-08 设计创作，主要内容包括：本发明提供了建筑用一体成型复合保温板材及其制备方法,包括保温层、设置于所述保温层表面的第一表面层和包覆于第一表面层外部的固化浆料,所述第一表面层为设有多个孔的板状；所述保温层通过粉料压制成型,所述第一表面层设置于所述粉料的表面,所述第一表面层随所述粉料通过压制模具一体压制成型,压制成型后还注入浆料并固化。其中的压制成型包括对模具中的粉料和第一表面层进行常温压制和对常温压制得到的预压板料进行升温压制成型两个压制阶段。本发明在压制成型过程中能够排出粉料内部的空气,得到的复合保温板材,制备方法简单,板材性能得到提升。(The invention provides an integrally formed composite heat-insulating board for buildings and a preparation method thereof, wherein the integrally formed composite heat-insulating board comprises a heat-insulating layer, a first surface layer and solidified slurry, wherein the first surface layer is arranged on the surface of the heat-insulating layer, and the solidified slurry is coated outside the first surface layer; the heat-insulating layer is formed by pressing powder, the first surface layer is arranged on the surface of the powder, the first surface layer is integrally formed by pressing along with the powder through a pressing die, and slurry is injected and solidified after the pressing. The compression molding comprises two compression stages of normal-temperature compression of powder and the first surface layer in the mold and heating compression molding of a pre-pressed plate obtained by the normal-temperature compression. The invention can discharge the air in the powder in the compression molding process, and the obtained composite heat-insulating board has simple preparation method and improved board performance.)

1. An integrated into one piece composite insulation panel for building, its characterized in that: the heat-insulating layer is arranged on the surface of the heat-insulating layer, and the first surface layer is a plate provided with a plurality of holes; the heat-insulating layer is formed by pressing powder, the first surface layer is arranged on the surface of the powder, the first surface layer is integrally formed by pressing along with the powder through a pressing die, and the pressing and forming sequentially comprises normal-temperature pressing and forming and heating pressing and forming.

2. The integrally formed composite heat insulation board for buildings according to claim 1, characterized in that: the first surface layer is externally coated with cured slurry.

3. The integrally formed composite heat insulation board for buildings according to claim 1, characterized in that: the first surface layer is arranged on the upper surface, the lower surface or both the upper surface and the lower surface of the powder.

4. The integrally formed composite heat insulation board for buildings according to claim 3, characterized in that: the first surface layer comprises a single-layer, a double-layer or a multi-layer, each layer is in a plate shape provided with a plurality of through holes, and each layer of the double-layer and the multi-layer is sequentially stacked on the surface of the powder; the paving layer is one or two of glass and fiber reinforced resin base plates.

5. The integrally formed composite heat insulation board for building of claim 4, characterized in that: in the first surface layer on the same side, the aperture of the layer laying through hole is 1 mm-10 mm, and the aperture of the layer laying through hole on the outermost layer is 1 mm-2 mm.

6. The integrally formed composite heat insulation board for building of claim 4, characterized in that: the glass is one of toughened glass, regional toughened glass, semi-toughened glass, ultra-white glass, float glass, coated glass and film-coated glass; the fiber reinforced resin-based plate comprises a resin matrix and reinforcing fibers added into the resin matrix, wherein the reinforcing fibers are one or more of quartz fibers, glass fibers, high silica fibers, carbon fibers, boron fibers, mullite fibers, basalt fibers, silicon carbide fibers, silicon nitride fibers, alumina fibers, boron nitride fibers, aramid fibers, spandex fibers and asbestos fibers; the resin matrix is any one of unsaturated polyester resin, epoxy resin, phenolic resin, urea resin, melamine resin, furan resin, polybutadiene resin, organic silicon resin, polyurethane resin and polyimide resin; the slurry is clean slurry, mortar or functional coating for buildings.

7. A preparation method of the integrally formed composite heat insulation board for the building as claimed in any one of claims 1 to 6, characterized by comprising the following steps: the method comprises the following specific steps:

firstly, mixing powder of the heat-insulating layer in proportion;

placing a first surface layer on the surface of the powder in the mould;

thirdly, pressing the powder and the first surface layer in the die at normal temperature through a pressing forming die to obtain a pre-pressed plate;

heating a pressing forming die, and heating and pressing the pre-pressed plate obtained in the step three to form so as to obtain a pressed plate;

the pressure for compression molding is 2-10Mpa, and the temperature for heating and compression molding is 60-180 ℃.

8. The method for preparing the integrally formed composite heat-insulating board for the building as claimed in claim 7, wherein the method comprises the following steps: and step five is further included after the step four, specifically, the pressed plate obtained in the step four is injected into slurry, and the composite heat-insulating plate is obtained after the slurry is solidified.

9. The method for preparing the integrally formed composite heat-insulating board for the building as claimed in claim 7, wherein the method comprises the following steps: in the first step, the powder material comprises nano powder, micron powder, fiber and infrared opacifier; the preparation method of the powder comprises the following steps:

a. adding the nano powder and the micron powder into a crusher to be crushed to obtain mixed powder A, wherein the nano powder comprises the following components in parts by mass: micron powder = (5-15): (0-2);

b. adding fibers into a crusher, and mixing and dispersing the fibers and the powder A in the step a to obtain a mixture B, wherein the mass parts of the mixed powder A: fiber = 90: (15-30);

c. adding an infrared opacifier into the mixture B obtained in the step B, mixing, and then pouring into a dispersing barrel for dispersing to obtain a mixture C, wherein the mixture B comprises the following components in parts by mass: infrared opacifier = 100: (40-50);

the nano powder in the step a is one or more of nano fumed silica powder, nano fumed alumina powder, nano fumed zirconia powder, nano silica aerogel powder, nano alumina aerogel powder and nano zirconia aerogel powder; the micron powder is one or more of micron fumed alumina powder, micron fumed silica powder, micron alumina aerogel powder and micron silica aerogel powder; the infrared opacifier is one of nano silicon carbide, micron silicon carbide, nano titanium dioxide, micron titanium dioxide, nano zirconia and micron zirconia; the fiber is one or more of quartz fiber, glass fiber, high silica fiber, carbon fiber, boron fiber, mullite fiber, basalt fiber, silicon carbide fiber, silicon nitride fiber, alumina fiber, boron nitride fiber, aramid fiber and spandex fiber.

10. The method of claim 7, wherein: in the second step, a second surface layer can be placed between the side wall of the pressing mould and the powder in advance, and the second surface layer is a single-layer laying layer.

Technical Field

The invention belongs to the technical field of heat preservation, and particularly relates to an integrally-formed composite heat preservation plate for a building and a preparation method thereof.

Background

The heat-insulating material has wide application, the traditional materials such as rock wool, glass wool, expanded perlite and the like still occupy the main market, although the materials have lower price, the materials have high density, short service life, large loss of laid thicker materials, high hygroscopicity, poor earthquake resistance and poor environmental protection performance, and the energy-saving standard cannot be reached by using the heat-insulating materials. In addition, the building heat-insulating materials such as asbestos and glass wool have a large amount of harmful substances and cannot meet the health requirements of human beings.

Compared with the traditional heat insulation material, the aerogel has great superiority as the heat insulation material, is the solid material with the best performance of the current heat insulation material, and is the preferred material for saving energy and reducing consumption. The aerogel is a nano porous material formed by mutually accumulating colloidal particles, has the characteristics of large specific surface area, low density, small average pore diameter, high porosity and low heat conductivity coefficient, obtains good application effect on heat insulation, and has wide application prospect and huge practical value.

The aerogel still faces some problems in the use at present, in the aspect of the utilization of aerogel powder, the powder is pressed, the contained air can be rapidly gathered under huge pressure to form air groups, the air groups are further compressed along with the increase of the pressure, when the pressure of the air groups is larger than the condensation force among the materials, the air groups can damage the condensation among the materials and are further connected with the adjacent air groups at the periphery, the gradually-increased air groups form an air layer for separating the peripheral materials, so that the core material is provided with an interlayer, and the forming strength and the quality of the core material are influenced. After the aerogel powder is pressed and formed, the phenomenon of frangibility and powder falling also occurs, and the safety and the transportation of operating personnel are influenced to a certain extent.

Disclosure of Invention

In order to solve the problems, the invention provides the integrally formed composite heat insulation board for the building and the preparation method thereof.

In order to achieve the purpose, the invention adopts the technical scheme that:

an integrated into one piece composite insulation panel for building, its characterized in that: the heat-insulating layer is arranged on the surface of the heat-insulating layer, and the first surface layer is a plate provided with a plurality of holes; the heat-insulating layer is formed by pressing powder, the first surface layer is arranged on the surface of the powder, the first surface layer is integrally formed by pressing along with the powder through a pressing die, and the pressing and forming sequentially comprises normal-temperature pressing and forming and heating pressing and forming.

Further, the first surface layer is externally coated with the cured slurry.

Further, the first surface layer is arranged on the upper surface, the lower surface or both the upper surface and the lower surface of the powder.

Further, the first surface layer comprises a single-layer, a double-layer or a multi-layer, each layer is in a plate shape provided with a plurality of through holes, and each layer of the double-layer and the multi-layer is sequentially stacked on the surface of the powder; the paving layer is one or two of glass and fiber reinforced resin base plates.

Furthermore, in the first surface layer on the same side, the aperture of the through hole of the paving layer is 1 mm-10 mm, and the aperture of the through hole of the paving layer on the outermost layer is 1 mm-2 mm.

Further, the glass is one of tempered glass, zone tempered glass, semi-tempered glass, ultra-white glass, float glass, coated glass and film-coated glass; the fiber reinforced resin-based plate comprises a resin matrix and reinforcing fibers added into the resin matrix, wherein the reinforcing fibers are one or more of quartz fibers, glass fibers, high silica fibers, carbon fibers, boron fibers, mullite fibers, basalt fibers, silicon carbide fibers, silicon nitride fibers, alumina fibers, boron nitride fibers, aramid fibers, spandex fibers and asbestos fibers; the resin matrix is any one of unsaturated polyester resin, epoxy resin, phenolic resin, urea resin, melamine resin, furan resin, polybutadiene resin, organic silicon resin, polyurethane resin and polyimide resin; the slurry is clean slurry, mortar or functional coating for buildings.

A preparation method of an integrally formed composite heat-insulation board for buildings is characterized by comprising the following steps: the method comprises the following specific steps:

firstly, mixing powder of the heat-insulating layer in proportion;

placing a first surface layer on the surface of the powder in the mould;

thirdly, pressing the powder and the first surface layer in the die at normal temperature through a pressing forming die to obtain a pre-pressed plate;

heating a pressing forming die, and heating and pressing the pre-pressed plate obtained in the step three to form so as to obtain a pressed plate;

the pressure for compression molding is 2-10Mpa, and the temperature for heating and compression molding is 60-180 ℃.

And further, a fifth step is included after the fourth step, specifically, the pressed plate obtained in the fourth step is injected with slurry, and the composite heat-insulating plate is obtained after the slurry is cured.

Further, in the first step, the powder material comprises nano powder, micron powder, fiber and infrared opacifier; the nano powder is one or more of nano fumed silica powder, nano fumed alumina powder, nano fumed zirconia powder, nano silica aerogel powder, nano alumina aerogel powder and nano zirconia aerogel powder; the micron powder is one or more of micron fumed alumina powder, micron fumed silica powder, micron alumina aerogel powder and micron silica aerogel powder; the infrared opacifier is one of nano silicon carbide, micron silicon carbide, nano titanium dioxide, micron titanium dioxide, nano zirconia and micron zirconia; the fiber is one or more of quartz fiber, glass fiber, high silica fiber, carbon fiber, boron fiber, mullite fiber, basalt fiber, silicon carbide fiber, silicon nitride fiber, alumina fiber, boron nitride fiber, aramid fiber and spandex fiber.

Further, the preparation method of the powder comprises the following steps:

a. adding the nano powder and the micron powder into a crusher to be crushed to obtain mixed powder A, wherein the nano powder comprises the following components in parts by mass: micron powder = (5-15): (0-2);

b. adding fibers into a crusher, and mixing and dispersing the fibers and the powder A in the step a to obtain a mixture B, wherein the mass parts of the mixed powder A: fiber = 90: (15-30);

c. adding an infrared opacifier into the mixture B obtained in the step B, mixing, and then pouring into a dispersing barrel for dispersing to obtain a mixture C, wherein the mixture B comprises the following components in parts by mass: infrared opacifier = 100: (40-50).

Furthermore, in the second step, a second surface layer can be placed between the side wall of the pressing die and the powder in advance, and the second surface layer is a single-layer laying layer.

Furthermore, the pressure of the compression molding is 2-10Mpa, and the temperature of the heating compression molding is 60-180 ℃.

The density of the heat-insulating layer of the composite heat-insulating plate is 0.27-0.50 g/cm³The thermal conductivity is 0.025 to 0.028W/m.K.

The invention has the beneficial effects that:

1. the integrally formed composite heat-insulation board for the building is formed by a mode that the first surface layer is placed in a die and pressed together with powder, normal-temperature prepressing is carried out in the powder pressing process, the first surface layer serves as an exhaust plate at the moment, and air in the powder is extruded into through holes of the first surface layer, so that the prepressed powder is more compact; the first surface layer and the heat-insulating layer are formed into a whole body firmly combined by hot-press forming after being pressed and molded at normal temperature, and the mechanical property of the heat-insulating layer can be improved by the first surface layer;

2. and grouting building slurry on the pressed plate obtained after normal-temperature prepressing and hot press molding, wherein the slurry is tightly connected with the pressed plate through the slurry poured into the through hole of the first surface layer, so that the composite heat-insulating plate coated by various slurries can be conveniently prepared.

Drawings

FIG. 1 is a first schematic structural diagram of the present invention;

FIG. 2 is a second schematic structural view of the present invention;

FIG. 3 is a third schematic structural view of the present invention;

FIG. 4 is a fourth schematic structural view of the present invention;

FIG. 5 is a fifth schematic structural view of the present invention;

FIG. 6 is a sixth schematic structural view of the present invention;

FIG. 7 is a seventh schematic structural view of the present invention;

FIG. 8 is a structural diagram eight of the present invention;

FIG. 9 is a schematic structural view of comparative example 1;

fig. 10 is a schematic structural view of comparative example 2.

Wherein, each reference number in the figure is: 1. a heat-insulating layer; 2. a first surface layer; 201. a first ply, 202, a second ply; 203. a third layer is laid; 3. curing the slurry; 4. a second surface layer; 5. a through hole; 6. a through hole; 7. a nonporous surface layer; 8. a foraminous layer.

Detailed Description

In order that those skilled in the art will be able to better understand the technical solutions provided by the present invention, the following description is provided in connection with specific embodiments.

Example 1

Referring to fig. 1, the integrally formed composite heat insulation board for buildings sequentially comprises a cured slurry 3, first surface layers 2, a heat insulation layer 1, the first surface layers 2 and the cured slurry 3 from top to bottom, wherein the two first surface layers 2 are single-layer laying layers, the single-layer laying layers are first laying layers 201, the first laying layers 201 at the moment are the first surface layers 2, holes of the first surface layers 2 are through holes 5 in the first laying layers 201, the first surface layers 2 are plane toughened glass plates with a plurality of through holes which are through up and down, and the aperture of the through holes 5 in the first laying layers 201 is 1-2 mm. The method comprises the steps of putting a first surface layer 2 into a mold, adding powder of a heat-insulating layer 1 into the mold, laying a first surface layer 2 on the surface of the finished and flat powder, pre-pressing the laid first surface layer 2 and the powder at normal temperature and 5MPa for 100s at normal temperature, and then hot-press forming at 180 ℃ and 10MPa for 10min to enable the first surface layer 2 and the heat-insulating layer 1 to be a firmly combined whole. The heat-insulating layer 1 and the first surface layer 2 after being pressed and formed are also filled with slurry without particles or fine particles for construction, and if the heat-insulating layer 1 and the first surface layer 2 are wrapped by cement paste required by engineering, the cement paste is filled and then is statically cured.

The heat-insulating layer 1 is formed by pressing and molding the mixture of nano fumed silica powder, nano fumed alumina powder, micron fumed alumina powder, superfine carbon fiber, superfine silicon carbide fiber and nano silicon carbide powder.

The preparation method of the integrally formed composite heat-insulation board for the building comprises the following steps:

(1) adding nano fumed silica powder, nano fumed alumina powder and micron fumed alumina powder into a crusher to be crushed to obtain mixed powder A, wherein the nano fumed silica powder comprises the following components in parts by mass: nano gas-phase alumina powder: micron fumed alumina powder = 2: 3: 0.5;

(2) adding superfine carbon fibers and superfine silicon carbide fibers into a crusher, wherein the superfine fibers refer to fibers with the diameter of 220 nm-1 mu m and the length-diameter ratio of more than 5000, and mixing and dispersing the fibers and the mixed powder A in the step (1) together to obtain a mixture B, wherein the mass parts of the mixed powder A: superfine carbon fiber: ultra-fine silicon carbide fiber = 90: 10: 5;

(3) adding nano silicon carbide powder infrared opacifier into the mixture B obtained in the step (2), mixing, then pouring into a dispersing barrel, and dispersing for 30min at 500 revolutions per minute to obtain a mixture C, wherein the mass parts of the mixture B are as follows: nano silicon carbide powder infrared opacifier = 100: 40;

(4) paving a first surface layer 2 arranged on the bottom surface of the powder at the bottom end of a mould, then pouring the mixture C obtained in the step (3) into the mould, then paving another first surface layer 2 on the upper surface of the powder, performing compression molding at normal temperature and 5MPa, maintaining the pressure for 100s, and then performing hot-press molding at 180 ℃ and 10MPa for 10min to obtain a pressed plate;

(5) and (4) grouting the pressed board obtained in the step (4) by using cement paste, standing and curing after grouting, and injecting the paste into the holes of the first surface layer 2 and spreading the paste to the surface of the first surface layer 2 to obtain the heat insulation board for the building.

In this example, the density of the insulating layer 1 was measured to be 0.4g/cm³The thermal conductivity was 0.027W/mK.

Example 2

Referring to fig. 2, the integrally formed composite heat insulation board for buildings sequentially comprises a curing slurry 3, a first surface layer 2, a heat insulation layer 1, a first surface layer 2 and a curing slurry 3 from top to bottom, wherein the two first surface layers 2 are double-layer laying layers, the double-layer laying layers sequentially comprise a first laying layer 201 and a second laying layer 202 according to the sequence from large to small from the heat insulation layer 1, each laying layer is a glass fiber reinforced epoxy resin-based planar board with a plurality of through holes 5 which are through up and down, the aperture of the through hole of the first laying layer 201 is 1mm, and the aperture of the through hole of the second laying layer 202 is 1 cm. In the preparation process, a first layer 201 and a second layer 202 are sequentially placed in a mould, then powder of the heat-insulating layer 1 is added in the mould, finally the second layer 202 and the first layer 201 are sequentially laid on the surface of the finished and smooth powder, the laid first surface layer 2 and the powder are firstly subjected to compression molding at normal temperature and 6MPa, the pressure is maintained for 70s, and then the first surface layer 2 and the heat-insulating layer 1 are subjected to hot-press molding at 80 ℃ and 6MPa for 20min to form a firmly-combined whole. The heat-insulating layer 1 and the first surface layer 2 after being pressed and formed are also filled with slurry without particles or fine particles for construction, and if the heat-insulating layer 1 and the first surface layer 2 are wrapped by waterproof slurry, the waterproof slurry can be filled and then is statically cured.

The preparation method of the integrally formed composite heat-insulation board for the building comprises the following steps:

(1) adding the nano-silica aerogel powder and the micron fumed alumina powder into a crusher to be crushed to obtain mixed powder A, wherein the nano-silica aerogel powder comprises the following components in parts by mass: micron fumed alumina powder = 10: 1;

(2) adding superfine carbon fibers, superfine silicon carbide fibers and high silica fibers into a crusher, wherein the superfine fibers refer to fibers with the diameter of 220 nm-1 mu m and the length-diameter ratio of more than 5000, the length of the fibers which are not marked with the superfine fibers is 50-500 mu m, and mixing and dispersing the fibers and the mixed powder A in the step (1) together to obtain a mixed material B, wherein the mixed powder A comprises the following components in parts by mass: superfine carbon fiber: ultra-fine silicon carbide fiber: high silica fiber = 90: 15: 7: 3;

(3) adding a nano titanium dioxide infrared opacifier into the mixture B obtained in the step (2), mixing, then pouring into a dispersing barrel, and dispersing for 25min at 700 r/min to obtain a mixture C, wherein the mixture C is powder of the heat-insulating layer 1, and the mixture B comprises the following components in parts by mass: nano titanium dioxide infrared opacifier = 100: 47;

(4) paving the first surface layer 2 arranged on the bottom surface of the powder at the bottom end of a mould, then pouring the mixture C obtained in the step (3) into the mould, then paving the other first surface layer 2 on the upper surface of the powder, after paving, firstly performing compression molding at normal temperature and 6MPa, keeping the pressure for 70s, and then performing hot-press molding at 80 ℃ and 6MPa for 20min to obtain a pressed plate;

(5) and (3) grouting the pressed plate obtained in the step (4) with waterproof slurry, injecting the slurry into the through holes 5 of the first layer 201 and the second layer 202 and spreading to the surface of the first layer 201, and after the slurry is statically solidified, obtaining the heat insulation plate for the building.

In this example, the density of the insulating layer 1 was measured to be 0.5g/cm³The thermal conductivity coefficient is 0.026W/m.K.

Example 3

Referring to fig. 3, integrated into one piece composite insulation panel for building includes solidification thick liquids 3, first superficial layer 2, heat preservation 1, first superficial layer 2 and solidification thick liquids 3 from last to down in proper order, and in addition, the lateral wall of heat preservation 1 still wraps up through second superficial layer 4, first superficial layer 2 and second superficial layer 4 are the individual layer and spread the layer, and both set up to glass fiber reinforced phenolic resin base plane panel, and the aperture size of the hole of first superficial layer 2 and the perforating hole 6 of second superficial layer 4 is 1~2 mm. In the preparation process, a first surface layer 2 and a second surface layer 4 are paved at the bottom and the side wall of a mold cavity, then powder of a heat-insulating layer 1 is poured into the mold where the first surface layer 2 and the second surface layer 4 are paved, finally the first surface layer 2 is paved on the surface of the powder which is arranged flatly, the paved first surface layer 2, the second surface layer 4 and the powder are pressed and molded at normal temperature and 7MPa together, the pressure is maintained for 50s, and then the hot-press molding is carried out at 160 ℃ and 5MPa for 15min, so that the first surface layer 2, the second surface layer 4 and the heat-insulating layer 1 are combined into a firm whole. And grouting the outer parts of the first surface layer 2 and the second surface layer 4 after compression molding by using cement paste mixed with 200-mesh quartz sand, and standing and solidifying after grouting to obtain the composite heat-insulating board.

A heat insulation plate for building and a preparation method thereof comprise the following steps:

(1) adding nano fumed silica powder and nano alumina aerogel powder into a crusher to be crushed to obtain mixed powder A, wherein the nano fumed silica powder comprises the following components in parts by mass: nano alumina aerogel powder = 1: 6;

(2) adding alumina fibers and high silica fibers into a crusher, and mixing and dispersing the alumina fibers and the high silica fibers with the mixed powder A in the step (1) to obtain a mixture B, wherein the mass parts of the mixed powder A: alumina fiber: high silica fiber = 90: 20: 10;

(3) adding a micron silicon carbide infrared opacifier into the mixture B obtained in the step (2), mixing, then pouring into a dispersing barrel, and dispersing for 20min at 900 revolutions per minute to obtain a mixture C, wherein the mixture B comprises the following components in parts by mass: micron silicon carbide infrared opacifier = 100: 42;

(4) respectively paving one first surface layer 2 and one second surface layer 4 at the bottom end and the inner wall of a mold, pouring the mixture C obtained in the step (3) into the mold, then paving the other first surface layer 2 on the upper surface of the material distribution layer, performing compression molding at normal temperature and 7MPa, maintaining the pressure for 50s, and performing hot-press molding at 160 ℃ and 5MPa for 15min to obtain the heat-insulating plate for the building;

(5) and (4) grouting the pressed plate obtained in the step (4) by using cement paste mixed with quartz sand, injecting the slurry into the holes of the first surface layer 2 and the through holes 6 of the second surface layer 4, spreading the slurry to the surfaces of the first surface layer 2 and the second surface layer 4, and after the slurry is statically solidified, obtaining the heat-insulating plate for the building.

In this example, the density of the insulating layer 1 was measured to be 0.45g/cm³The thermal conductivity was 0.028W/m.K.

Example 4

Referring to fig. 4, the integrally formed composite insulation board for buildings sequentially comprises a cured slurry 3, a first surface layer 2 and an insulation layer 1 from top to bottom, wherein the first surface layer 2 is a single-layer paving layer formed by a first paving layer 201, the first paving layer 201 is a planar toughened glass plate with a plurality of through holes 5 which are through up and down, and the aperture of the through hole 5 of the first paving layer 201 is 2 mm. Specifically, powder of the heat preservation layer 1 is added into a mold, then a layer of first paving layer 201 is paved on the surface of the smooth powder, the paved first paving layer 201 and the powder are firstly pressed and molded at normal temperature and 5MPa for normal-temperature prepressing, the pressure is maintained for 100s, and then hot-press molding is carried out at 180 ℃ and 10MPa for 10min, so that the first paving layer 201 and the heat preservation layer 1 are formed into a firmly combined whole. The heat preservation layer 1 and the first layer 201 after the press forming are further filled with cement paste for reinforcement, the cement paste can specifically wrap any one of the first surface layer 2 and the heat preservation layer 1, and the heat preservation layer 1 and the first layer 201 are still solidified statically after being filled with the cement paste.

The preparation method of the integrally formed composite heat-insulation board for the building comprises the following steps:

(1) mixing and dispersing nano fumed silica powder and superfine carbon fibers together to obtain a mixture B, wherein the nano fumed silica powder comprises the following components in parts by mass: ultrafine carbon fibers = 90: 15, the superfine fibers refer to fibers with the diameter of 220 nm-1 μm and the length-diameter ratio of more than 5000;

(2) adding a nano zirconia powder infrared opacifier into the mixture B obtained in the step (2), mixing, then pouring into a dispersing barrel, and dispersing for 30min at 500 revolutions per minute to obtain a mixture C, wherein the mixture B comprises the following components in parts by mass: nano zirconia powder infrared opacifier = 100: 40;

(3) pouring the mixture C obtained in the step (3) into a mold, then paving the first surface layer 2 arranged on the top surface of the powder on the upper surface of the powder, then performing compression molding at normal temperature and 5MPa, maintaining the pressure for 100s, and then performing hot-press molding at 180 ℃ and 10MPa for 10min to obtain a compressed plate;

(4) and (3) grouting the pressed board obtained in the step (4) by using cement paste, standing and curing after grouting, injecting the slurry into the holes of the first surface layer 2 and spreading to the surface of the first surface layer 2, and wrapping the rest surfaces of the heat-insulating layer 1 without the first surface layer 2 according to engineering requirements to obtain the heat-insulating board for the building.

In this example, the density of the insulating layer 1 was measured to be 0.3g/cm³The thermal conductivity was 0.025W/mK.

Example 5

Referring to fig. 5, the integrally formed composite insulation board for buildings sequentially comprises a cured slurry 3, an insulation layer 1, a first surface layer 2 and the cured slurry 3 from top to bottom, wherein the first surface layer 2 is a single-layer laying layer formed by a first laying layer 201, the first laying layer 201 is a glass fiber reinforced epoxy resin-based planar board with a plurality of through holes 5 which are through up and down, and the aperture of the through hole 5 of the first laying layer 201 is 2 mm. Specifically, a first layer 201 is paved at the bottom of a mold, then powder of the heat preservation layer 1 is added, the paved first layer 201 and the powder are pressed and molded at normal temperature and 6MPa, the pressure is maintained for 70s, and then the first layer 201 and the heat preservation layer 1 are formed for 20min in a hot pressing mode at 100 ℃ and 6MPa, so that the first layer 201 and the heat preservation layer 1 are combined firmly into a whole. The insulation layer 1 and the first layer 201 after press forming are further filled with functional coating for reinforcement, the functional coating can specifically wrap the first surface layer 2 and any surface of the exposed insulation layer 1, and the insulation layer 1 and the first layer are still solidified statically after being filled with the functional coating.

The preparation method of the integrally formed composite heat-insulation board for the building comprises the following steps:

(1) adding nano fumed silica powder, nano fumed alumina powder and micron fumed alumina powder into a crusher to be crushed to obtain mixed powder A, wherein the nano fumed silica powder comprises the following components in parts by mass: nano gas-phase alumina powder: micron fumed alumina powder = 1: 8: 0.5;

(2) adding boron nitride fibers into a crusher, and mixing and dispersing the fibers and the mixed powder A in the step (1) to obtain a mixed material B, wherein the mass parts of the mixed powder A: boron nitride fiber = 90: 15;

(3) adding a micron zirconia powder infrared opacifier into the mixture B obtained in the step (2), mixing, then pouring into a dispersing barrel, and dispersing for 30min at 500 revolutions per minute to obtain a mixture C, wherein the mixture B comprises the following components in parts by mass: micron silicon carbide powder infrared opacifier = 100: 45, a first step of;

(4) paving the first surface layer 2 arranged on the bottom surface of the powder on the bottom of a mold cavity, then pouring the mixture C obtained in the step (3) into the mold, then performing compression molding at normal temperature and 6MPa, maintaining the pressure for 70s, and then performing hot-press molding at 100 ℃ and 6MPa for 20min to obtain a compressed plate;

(5) and (4) grouting the pressed board obtained in the step (4) by using a functional coating, standing and curing after grouting, injecting the slurry into the holes of the first surface layer 2 and extending to the surface of the first surface layer 2, and wrapping the rest surfaces of the heat-insulating layer 1 without the first surface layer 2 according to engineering requirements to obtain the heat-insulating board for the building.

In this example, the density of the insulating layer 1 was measured to be 0.4g/cm³The thermal conductivity was 0.027W/mK.

Example 6

Referring to fig. 6, the integrally formed composite heat insulation board for buildings sequentially comprises a cured slurry 3, a first surface layer 2, a heat insulation layer 1, a first surface layer 2 and a cured slurry 3 from top to bottom, wherein the two first surface layers 2 are three-layer paving layers, the three-layer paving layers sequentially comprise a first paving layer 201, a second paving layer 202 and a third paving layer 203 according to the sequence from large distance to small distance from the heat insulation layer 1, the first paving layer 201 and the third paving layer 203 are aramid fiber reinforced unsaturated polyester plane boards with a plurality of through holes 5, the second paving layer 202 is a semi-toughened glass plane board with the through holes 5, the aperture of the through hole of the first paving layer 201 is 1 mm-2 mm, the aperture of the through hole of the second paving layer 202 is 0.5cm, and the aperture of the third paving layer 203 is 1 cm. If the number of the layers of the first surface layer 2 is more than two, the through holes 5 of each layer include through holes communicated with the through holes 5 of the other layers, including all the through holes 5 and part of the through holes 5, wherein the through holes are completely communicated from top to bottom, and the through holes of different layers are in a step shape, like the embodiment, part of the through holes 5 of the first layer 201 are communicated with the through holes 5 of the second layer 202 and the third layer 203, and all the through holes 5 of the second layer 202 are communicated with all the through holes 5 of the third layer 203; also as in embodiment 2, the through holes 5 of all the first layers 201 are communicated with the through holes 5 of all the second layers 202, and in both cases, the insulation layer 1 (powder) can be communicated with the outside. In the preparation process, a first layer 201, a second layer 202 and a third layer 203 are sequentially placed in a mold, then powder of a heat-insulating layer 1 is added into the mold, finally the third layer 203, the second layer 202 and the first layer 201 are sequentially laid on the surface of the finished and smooth powder, the laid first surface layer 2 and the powder are firstly subjected to compression molding at normal temperature and 7MPa, the pressure is maintained for 70s, and then the first surface layer 2 and the heat-insulating layer 1 are subjected to hot-press molding at 180 ℃ and 5MPa for 25min, so that the first surface layer 2 and the heat-insulating layer 1 are combined firmly. And fire retardant coating is further injected into the heat-insulating layer 1 and the first surface layer 2 after the press forming so as to wrap and solidify the heat-insulating layer 1 and the first surface layer 2.

The preparation method of the integrally formed composite heat-insulation board for the building comprises the following steps:

(1) adding nano gas-phase zirconia powder and micron gas-phase alumina powder into a crusher to be crushed to obtain mixed powder A, wherein the nano gas-phase zirconia powder comprises the following components in parts by mass: micron fumed silica powder = 6: 0.2;

(2) adding superfine carbon fibers and high silica fibers into a crusher, and mixing and dispersing the superfine carbon fibers and the high silica fibers together with the mixed powder A in the step (1) to obtain a mixture B, wherein the mixed powder A comprises the following components in parts by mass: superfine carbon fiber: high silica fiber = 90: 15: 3;

(3) adding a micron titanium dioxide infrared opacifier into the mixture B obtained in the step (2), mixing, then pouring into a dispersing barrel, and dispersing for 25min at 700 rpm to obtain a mixture C, wherein the mixture C is powder of the heat-insulating layer 1, and the mixture B comprises the following components in parts by mass: micron titanium dioxide infrared opacifier = 100: 47;

(4) paving the first surface layer 2 arranged on the bottom surface of the powder at the bottom end of a mould, then pouring the mixture C obtained in the step (3) into the mould, then paving the other first surface layer 2 on the upper surface of the powder, after paving, firstly performing compression molding at normal temperature and 7MPa, keeping the pressure for 70s, and then performing hot-press molding at 180 ℃ and 5MPa for 25min to obtain a pressed plate;

(5) and (3) grouting the pressed plate obtained in the step (4) by using a fireproof coating, injecting the slurry into the through holes 5 of the first layer 201, the second layer 202 and the third layer 203, spreading the slurry to the surface of the first layer 201, and obtaining the heat insulation plate for the building after the slurry is statically solidified.

In this example, the density of the insulating layer 1 was measured to be 0.48g/cm³The thermal conductivity was 0.027W/mK.

Example 7

Referring to fig. 7, the integrally formed composite heat insulation board for buildings sequentially comprises a curing slurry 3, a heat insulation layer 1, a first surface layer 2 and the curing slurry 3 from top to bottom, wherein the first surface layer 2 is a double-layer paving layer and sequentially comprises a first paving layer 201 and a second paving layer 202 from large to small according to the distance from the heat insulation layer 1, each paving layer is an alumina fiber reinforced polyimide resin matrix planar board with a plurality of through holes 5 which are through up and down, and the aperture of the through holes of the first paving layer 201 and the aperture of the through holes of the second paving layer 202 are both 1 mm. In the preparation process, a first layer 201 and a second layer 202 are sequentially placed in a mould, then powder of the heat-insulating layer 1 is added in the mould, finally the second layer 202 and the first layer 201 are sequentially laid on the surface of the finished and smooth powder, and the laid first surface layer 2 and the powder are pressed together. And injecting waterproof slurry into the heat-insulating layer 1 and the first surface layer 2 after the press forming to wrap the heat-insulating layer 1 and the first surface layer 2, and standing and curing.

The preparation method of the integrally formed composite heat-insulation board for the building comprises the following steps:

(1) adding nano gas-phase zirconia powder and nano silicon dioxide aerogel powder into a crusher to be crushed to obtain mixed powder A, wherein the nano gas-phase zirconia powder comprises the following components in parts by mass: nano silica aerogel powder = 1: 7;

(2) adding superfine carbon fibers, superfine silicon carbide fibers and glass fibers into a crusher, and mixing and dispersing the superfine carbon fibers, the superfine silicon carbide fibers and the glass fibers with the mixed powder A in the step (1) to obtain a mixture B, wherein the mixed powder A comprises the following components in parts by mass: superfine carbon fiber: ultra-fine silicon carbide fiber: glass fiber = 90: 15: 7: 3;

(3) adding a nano titanium dioxide infrared opacifier into the mixture B obtained in the step (2) and mixing to obtain a mixture C, wherein the mass parts of the mixture B: nano titanium dioxide infrared opacifier = 100: 43;

(4) paving the first surface layer 2 arranged on the bottom surface of the powder at the bottom end of a mould, then pouring the mixture C obtained in the step (3) into the mould, after paving is finished, firstly performing compression molding at normal temperature and under 8MPa, maintaining the pressure for 70s, and then performing hot-press molding at 70 ℃ and under 10MPa for 20min to obtain a compressed plate;

(5) and (5) grouting the pressed plate obtained in the step (4) by using waterproof slurry.

In this example, the density of the insulating layer 1 was measured to be 0.47g/cm³The thermal conductivity was 0.028W/m.K.

Example 8

Referring to fig. 8, the integrally formed composite thermal insulation board for buildings sequentially comprises a thermal insulation layer 1 and a first surface layer 2 from top to bottom, wherein the first surface layer 2 is a single-layer laying layer formed by a first laying layer 201, the first laying layer 201 is a glass fiber reinforced epoxy resin-based plane board with a plurality of through holes 5 which are through up and down, and the aperture of the through hole 5 of the first laying layer 201 is 1.5 mm. Specifically, a first layer 201 is laid at the bottom of a mold, then powder of the heat insulation layer 1 is added, the laid first layer 201 and the powder are pressed and molded at room temperature and 6MPa, the pressure is maintained for 70s, and then hot press molding is carried out at 140 ℃ and 6MPa for 20min, so that the first layer 201 and the heat insulation layer 1 are combined into a firmly-combined whole.

The preparation method of the integrally formed composite heat-insulation board for the building comprises the following steps:

(1) adding the nano-alumina aerogel powder and the micron fumed alumina powder into a crusher to be crushed to obtain mixed powder A, wherein the nano-alumina aerogel powder comprises the following components in parts by mass: micron fumed alumina powder = 15: 1;

(2) adding quartz fibers into a crusher, and mixing and dispersing the fibers and the mixed powder A in the step (1) to obtain a mixed material B, wherein the mass parts of the mixed powder A: quartz fiber = 90: 25;

(3) adding a micron zirconia powder infrared opacifier into the mixture B obtained in the step (2), mixing, then pouring into a dispersing barrel, and dispersing for 30min at 500 revolutions per minute to obtain a mixture C, wherein the mixture B comprises the following components in parts by mass: micron zirconia powder infrared opacifier = 100: 50;

(4) and (3) paving the first surface layer 2 arranged on the bottom surface of the powder on the bottom of a mold cavity, then pouring the mixture C obtained in the step (3) into the mold, then performing compression molding at normal temperature and 6MPa, maintaining the pressure for 70s, and then performing hot-press molding at 140 ℃ and 6MPa for 20min to obtain the heat-insulating and heat-preserving plate for the building.

In this example, the density of the insulating layer 1 was measured to be 0.4g/cm³The thermal conductivity was 0.027W/mK.

Comparative example 1

Arrangement of comparative example 1 referring to fig. 9, the upper and lower surfaces of the heat insulating layer 1 were provided with the non-porous surface layers 7, the material was selected from a flat tempered glass plate, and the non-porous surface layers 7 were not provided with through holes. The two nonporous surface layers 7 are respectively laid on the upper surface and the lower surface of the powder before the powder of the heat preservation layer 1 is pressed and molded, namely, the nonporous surface layer 7 on the lower surface of the powder is firstly placed in a mold, then the powder of the heat preservation layer 1 mixed according to the proportion is placed in the mold, and finally the nonporous surface layer 7 on the upper surface of the powder is placed. The laid non-porous surface layer 7 and the powder are pre-pressed at normal temperature and 5MPa, the pressure is maintained for 100s, and then hot press molding is carried out at 180 ℃ and 10MPa for 10min, so as to obtain a first comparative sample. Taking the heat-insulating layer 1 in the middle of the comparison sample I for performance test, removing the nonporous surface layers 7 on the upper and lower surfaces, making the heat-insulating layer 1 fragile, and measuring the density of the heat-insulating layer 1 to be 0.15g/cm³The thermal conductivity is 0.029W/m.K.

Comparative example 2

The structural arrangement is as shown in fig. 10, and the difference from example 8 is that a plurality of through holes 5 with a hole diameter of 1.5cm are formed in the porous layer 8, and a second comparative sample is prepared in the same manner as in comparative example 8 in other preparation processes. Taking the insulating layer 1 of the second comparative sample for performance test, removing the porous layer, making the insulating layer 1 fragile, making visible large concave holes on the fracture surface, and measuring the density to be 0.18g/cm³The thermal conductivity was 0.032W/m.K.

The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention. The present invention is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.