阅读说明：本技术 自行车轮胎用加强部件及自行车轮胎 (Reinforcing member for bicycle tire and bicycle tire ) 是由 竹本慎一 赖光周平 铃木潮 中村卓志 于 2020-04-23 设计创作，主要内容包括：本发明提供一种自行车轮胎用的加强部件及自行车轮胎。自行车轮胎(100)至少具备配设于自行车轮胎(100)的接地面的胎面部(12)、及配设于胎面部(12)的内侧的胎体部(16),在从所述胎面部(12)与所述胎体部(16)之间、所述胎体部(16)的内部、及所述胎面部(12)的内部中选择的至少一处配设有加强部件(14)。所述加强部件(14)含有由液晶聚酯纤维线构成的织物,且所述纤维线由3根以上的单纤维构成,所述单纤维的平均纤维径为25μm以上,所述纤维线中的单纤维根数(根)与所述平均纤维径(μm)的积为1700以下。(The invention provides a reinforcing member for a bicycle tire and a bicycle tire. A bicycle tire (100) is provided with at least a tread portion (12) disposed on a ground contact surface of the bicycle tire (100) and a carcass portion (16) disposed inside the tread portion (12), and a reinforcing member (14) is disposed at least at one position selected from between the tread portion (12) and the carcass portion (16), inside the carcass portion (16), and inside the tread portion (12). The reinforcing member (14) comprises a woven fabric made of liquid crystal polyester fiber yarns, the fiber yarns are made of 3 or more filaments, the average fiber diameter of the filaments is 25 [ mu ] m or more, and the product of the number of filaments (root) and the average fiber diameter ([ mu ] m) in the fiber yarns is 1700 or less.)

1. A reinforcing member for a bicycle tire, comprising a woven fabric made of a liquid crystal polyester fiber yarn, wherein the fiber yarn is made of 3 or more filaments, the filaments have an average fiber diameter of 25 [ mu ] m or more, and the product of the number of filaments (number) and the average fiber diameter ([ mu ] m) in the fiber yarn is 1700 or less.

2. The reinforcing member according to claim 1, wherein a sample having a thickness of 2mm and formed by vulcanizing and integrating unvulcanized rubber sheets arranged above and below the woven fabric together with the woven fabric under heat and pressure has a maximum load of 850N or more in a through test.

3. A reinforcing component as claimed in claim 1 or 2, wherein the fabric is a flat fabric or a curtain fabric.

4. The reinforcing member according to any one of claims 1 to 3, wherein flat warp and/or weft threads made of the liquid crystal polyester fiber thread are provided.

5. The reinforcing member as claimed in claim 4, wherein the width of the warp and/or weft is 0.1 to 3.0 mm.

6. A reinforcing component as claimed in any one of claims 1 to 5, wherein said liquid crystal polyester fiber yarns are interwoven fabrics.

7. The reinforcing member as claimed in any one of claims 1 to 6, wherein the number of twists of the liquid crystal polyester fiber yarn is 1 to 30 times/10 cm.

8. A reinforcing component as claimed in any one of claims 1 to 7, wherein the number of the single fibers is 29 or less.

9. A reinforcing member as claimed in any one of claims 1 to 8, wherein the average fiber diameter of the single fibers is 40 μm or more.

10. The reinforcing member according to any one of claims 1 to 9, further comprising a woven fabric of a polyvinyl alcohol-based fiber yarn composed of a plurality of single fibers having an average fiber diameter of the single fibers of 45 μm or less.

11. A bicycle tire comprising at least a tread portion disposed on a ground contact surface of the bicycle tire and a carcass portion disposed inside the tread, wherein a reinforcing member according to any one of claims 1 to 10 is disposed at least at one position selected from between the tread portion and the carcass portion, inside the carcass portion and inside the tread portion.

Technical Field

The present invention relates to a reinforcing member for improving the breakage resistance of a bicycle tire and a bicycle tire having excellent breakage resistance.

Background

The bicycle tire is provided with a carcass portion forming a tire frame therein, and a tread portion on a ground surface and a ground contact surface side of the tire. In addition, in order to protect the tire from stones, glass, metal pieces, and the like existing on the ground, a reinforcing member is provided in the bicycle tire. On the other hand, if a reinforcing member is present, there is a problem that the lightweight property required for a bicycle tire cannot be achieved, and therefore, for example, patent document 1 (european patent No. 682362 specification) discloses a bicycle tire including: a reinforcing member, a tread portion, and a carcass portion, each of which is composed of a multifilament comprising more than 30 thermoplastic liquid crystal polyester fibers.

This document describes that the use of multifilaments containing more than 30 thermoplastic liquid crystal polyester fibers as a reinforcing member improves the cut resistance while achieving weight reduction of the tire.

Documents of the prior art

Patent document

Patent document 1: european patent specification No. 682362

Disclosure of Invention

Technical problem to be solved by the invention

However, patent document 1 only confirms the cut resistance by pressing a blade-shaped stylus (stick) against the tire. On the other hand, there are many causes for the flat tire. For example, when a bicycle runs on uneven road surfaces, there are cases where a tire burst, i.e., a tire burst due to a rim crush, or a tire itself is broken, but such a tire burst or breakage occurs because the bicycle tire does not have sufficient resistance to breakage. Therefore, there is a demand for a tire which is less likely to fail even when running on a rough road having stones, projections, or the like, i.e., a tire having high breakage resistance.

Accordingly, an object of the present invention is to provide a reinforcing member for improving the breakage resistance of a bicycle tire, and a bicycle tire having excellent breakage resistance.

Means for solving the problems

As a result of diligent research directed toward achieving the above object, the inventors of the present invention have found that a fabric comprising a liquid crystal polyester fiber yarn is used as a reinforcing member for a bicycle tire, and that not only is the average fiber diameter of the single fibers constituting the liquid crystal polyester fiber yarn set to a specific value, but also when the fiber diameter and the number of single fibers in the fiber yarn have a specific relationship, the fabric comprising the liquid crystal polyester fiber yarn unexpectedly improves the breakage resistance of the bicycle tire, and have completed the present invention.

That is, the present invention can be constituted as follows.

[ means 1]

A reinforcing member for a bicycle tire, comprising a woven fabric made of liquid crystal polyester fiber yarns, wherein the fiber yarns are made of single fibers of 3 or more (preferably 5 or more, more preferably 7 or more, for example 60 or less, preferably 40 or less, more preferably 29 or less), the single fibers have an average fiber diameter of 25 μm or more (preferably 28 μm or more, more preferably 35 μm or more, further preferably 40 μm or more, particularly preferably 42 μm or more, for example 500 μm or less, preferably 300 μm or less, more preferably 100 μm or less, further preferably 60 μm or less), and the product of the number (root) of the single fibers in the fiber yarns and the average fiber diameter (μm) is 1700 or less (preferably 250 to 1700, more preferably 300 to 1500).

[ means 2]

The reinforcing member according to mode 1, wherein a specimen having a thickness of 2mm and vulcanized by heat pressure bonding is present above and below the woven fabric, and the maximum load in a penetration test is 850N or more (preferably 870N or more, more preferably 900N or more, for example 3000N or less).

[ means 3]

The reinforcing component according to mode 1 or 2, wherein the fabric is a flat fabric or a curtain fabric.

[ means 4]

The reinforcing member according to any one of aspects 1 to 3, which comprises flat warp and/or weft threads made of the liquid crystal polyester fiber thread.

[ means 5]

The reinforcing member according to mode 4, wherein the width of the warp and/or weft is 0.1 to 3.0mm (preferably 0.15 to 2.0 mm).

[ means 6]

The reinforcing member according to any one of aspects 1 to 5, wherein the liquid crystal polyester fiber yarn is a woven fabric that is crossed with each other.

[ means 7]

The reinforcing member according to any one of aspects 1 to 6, wherein the number of twists of the liquid crystal polyester fiber yarn is 1 to 30 times/10 cm (preferably 2 to 20 times/10 cm, more preferably 3 to 18 times/10 cm).

[ means 8]

The reinforcing member according to any one of aspects 1 to 7, wherein the number of the single fibers is 29 or less.

[ means 9]

The reinforcing member according to any one of aspects 1 to 8, wherein the average fiber diameter of the single fibers is 40 μm or more.

[ means 10]

The reinforcing member according to any one of aspects 1 to 9, further comprising a woven fabric of a polyvinyl alcohol-based fiber yarn composed of a plurality of single fibers, the single fibers having an average fiber diameter of 45 μm or less.

[ means 11]

A bicycle tire comprising at least a tread portion disposed on a ground contact surface of the bicycle tire and a carcass portion disposed on an inner side of the tread, wherein a reinforcing member as set forth in any one of embodiments 1 to 10 is disposed at least at one position selected from a space between the tread portion and the carcass portion, an inside of the carcass portion and an inside of the tread portion.

In addition, any combination of at least two constituent elements disclosed in the scope of claims and/or the specification and/or the drawings is also included in the present invention. In particular, any combination of two or more of the claims described in the claims is also included in the present invention.

Effects of the invention

According to the reinforcing member of the present invention, by forming the fabric using the liquid crystal polyester fiber yarn having the specific average fiber diameter of the single fibers and the specific relationship between the average fiber diameter and the number of the single fibers, it is possible to improve the breakage resistance of the bicycle tire, and as a result, it is possible to favorably prevent the occurrence of a tire burst, particularly a rim pinch tire burst, due to insufficient breakage resistance of the bicycle tire. In particular, the reinforcing member of the present invention can further improve the breakage resistance of the bicycle tire when the single fiber diameter of the liquid crystal polyester fiber is large.

Drawings

The invention will be more clearly understood from the following description of suitable embodiments with reference to the accompanying drawings. However, the embodiments and drawings are for illustrative purposes only and are not intended to be used to determine the scope of the present invention. The scope of the invention is to be determined by the appended claims.

Fig. 1 is a schematic cross-sectional view showing a bicycle tire according to an embodiment of the present invention.

Fig. 2 is a schematic cross-sectional view showing a bicycle tire according to another embodiment of the present invention.

Fig. 3 is a schematic cross-sectional view showing a bicycle tire according to another embodiment of the present invention.

Fig. 4 is a partial schematic cross-sectional view of a constant speed penetration tester for explaining a penetration test of a reinforcing member.

Detailed Description

[ Reinforcement Member ]

The reinforcing member of the present invention is a reinforcing member for a bicycle tire comprising at least a woven fabric of liquid crystal polyester fiber yarns, wherein the fiber yarns are composed of 3 or more filaments. In addition, the reinforcing component may be constructed from one or more layers of fabric. In the case of a multilayer woven fabric, the fabric may be composed of only the liquid crystal polyester fiber yarn, or may be composed of a combination of the fabric of the liquid crystal polyester fiber yarn and a fabric other than the liquid crystal polyester fiber yarn.

(liquid crystal polyester fiber yarn)

The liquid crystal polyester fiber yarn is composed of 3 or more single fibers. The liquid crystal polyester fiber may be a fiber composed of a thermoplastic polymer capable of forming a melt phase having optical anisotropy, and is preferably a thermoplastic wholly aromatic polyester fiber (polyarylate fiber), for example.

The liquid crystal polyester fiber (e.g., wholly aromatic polyester fiber) can be obtained by melt spinning a liquid crystal polyester (e.g., wholly aromatic polyester). The wholly aromatic polyester is formed of, for example, a repeating structural unit derived from an aromatic diol, an aromatic dicarboxylic acid, an aromatic hydroxycarboxylic acid, or the like, and the chemical structure of the structural unit derived from an aromatic diol, an aromatic dicarboxylic acid, or an aromatic hydroxycarboxylic acid is not particularly limited, as long as the effect of the present invention is not impaired. The wholly aromatic polyester may contain a structural unit derived from an aromatic diamine, an aromatic hydroxylamine or an aromatic aminocarboxylic acid, within a range not to inhibit the effect of the present invention. For example, the preferable structural units are shown in table 1.

[ Table 1]

(wherein X in the formula is a structure selected from the group consisting of

(wherein m is 0 to 2, and Y is a substituent selected from the group consisting of hydrogen, a halogen atom, an alkyl group, an aryl group, an aralkyl group, an alkoxy group, an aryloxy group, and an aralkyloxy group)

In the structural units in table 1, m is an integer of 0 to 2, and Y in the formula, independently of each other, is in the range of 1 to the maximum number of substitutable groups, and includes a hydrogen atom, a halogen atom (e.g., a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, etc.), an alkyl group (e.g., an alkyl group having 1 to 4 carbon atoms such as a methyl group, an ethyl group, an isopropyl group, a tertiary butyl group, etc.), an alkoxy group (e.g., a methoxy group, an ethoxy group, an isopropoxy group, an n-butoxy group, etc.), an aryl group (e.g., a phenyl group, a naphthyl group, etc.), an aralkyl group [ benzyl group (phenylmethyl group), phenethyl group (phenylethyl group), etc. ], an aryloxy group (e.g., a phenoxy group, etc.), an aralkyloxy group (e.g., benzyloxy group, etc.), and the like.

Preferable examples of the structural units include those described in examples (1) to (18) shown in tables 2, 3 and 4 below. When the structural unit in the formula is a structural unit capable of expressing a plurality of structures, two or more of these structural units may be combined and used as a structural unit constituting the polymer.

[ Table 2]

[ Table 3]

[ Table 4]

In the structural units in tables 2, 3 and 4, n is an integer of 1 or 2, each of the structural units n ═ 1 and n ═ 2 may be present alone or in combination, and Y1 and Y2 may each independently be a hydrogen atom, a halogen atom (e.g., a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, etc.), an alkyl group (e.g., an alkyl group having 1 to 4 carbon atoms such as a methyl group, an ethyl group, an isopropyl group, a tertiary butyl group, etc.), an alkoxy group (e.g., a methoxy group, an ethoxy group, an isopropoxy, a n-butoxy group, etc.), an aryl group (e.g., a phenyl group, a naphthyl group, etc.), an aralkyl group [ benzyl (phenylmethyl) group, phenylethyl (phenylethyl) etc. ], an aryloxy group (e.g., a phenoxy group, etc.), an aralkyloxy group (e.g., benzyloxy, etc.). Of these, a hydrogen atom, a chlorine atom, a bromine atom, or a methyl group is preferable.

In addition, Z may be a substituent represented by the following formula.

[ solution 1]

The wholly aromatic polyester preferably has a naphthalene skeleton as a constituent unit. In addition, it is particularly preferable that both the structural unit (a) derived from hydroxybenzoic acid and the structural unit (B) derived from hydroxynaphthoic acid are contained. For example, the structural unit (a) may be represented by the following formula (a), the structural unit (B) may be represented by the following formula (B), and the ratio of the structural unit (a) to the structural unit (B) is preferably 9/1 to 1/1, more preferably 7/1 to 1/1, and still more preferably 5/1 to 1/1, from the viewpoint of improving melt moldability.

[ solution 2]

[ solution 3]

The total of the structural unit of (a) and the structural unit of (B) may be, for example, 65 mol% or more, more preferably 70 mol% or more, and still more preferably 80 mol% or more based on the total structural units. Among the polymers, a wholly aromatic polyester having a structural unit of (B) of 4 to 45 mol% is particularly preferable.

The melting point of the wholly aromatic polyester suitably used in the present invention is preferably in the range of 250 to 360 ℃, more preferably 260 to 320 ℃. The melting point here is a main absorption peak temperature observed by measurement with a Differential Scanning Calorimeter (DSC) according to the test method of JIS K7121. Specifically, in the DSC apparatus, 10 to 20mg of a sample was collected and sealed in an aluminum pan, and then nitrogen gas as a carrier gas was introduced at 100 mL/min to measure the endothermic peak at a temperature rise of 20 ℃/min. When a distinct peak is not observed in a 1st run in the DSC measurement depending on the type of polymer, the temperature is raised at 50 ℃/min to a temperature 50 ℃ higher than the predicted flow temperature, the temperature is completely melted for 3 minutes, then the temperature is lowered at a temperature lowering rate of 80 ℃/min to 50 ℃, and then the endothermic peak is measured at a temperature raising rate of 20 ℃/min.

In the liquid crystal polyester (particularly, wholly aromatic polyester), a thermoplastic polymer such as polyethylene terephthalate, modified polyethylene terephthalate, polyolefin, polycarbonate, polyamide, polyphenylene sulfide (polyphenylene sulfide), polyether ether ketone, or fluororesin may be added within a range not to impair the effects of the present invention. In addition, various additives such as inorganic substances such as titanium oxide, kaolin, silica, and barium oxide, colorants such as carbon black, dyes, and pigments, antioxidants, ultraviolet absorbers, and light stabilizers may be contained.

The liquid crystal polyester fiber in the present invention is not limited in the method of forming the fiber as long as it has a property that a part of the surface of the fiber can be melted by heating, but a fiber obtained by melt spinning can be generally used. The melt spinning can be carried out by a known or conventional method, and for example, a fiber-forming resin for obtaining a liquid crystal polyester fiber is melted in an extruder and then discharged from a nozzle at a predetermined spinning temperature.

The liquid crystal polyester fiber yarn is composed of 3 or more filaments, and the average fiber diameter of the filaments is 25 [ mu ] m or more. However, in order to impart the liquid crystal polyester fiber yarn with resistance to breakage in the reinforcing member, there is a predetermined relationship between the average fiber diameter and the number of single fibers constituting the liquid crystal polyester fiber yarn, and the product of the number (root) of single fibers and the average fiber diameter (μm) in the fiber yarn is 1700 or less. This indicates that when the reinforcing member exhibits fracture resistance, the average fiber diameter and the number of single fibers are in inverse proportion to each other.

That is, in the present invention, if the average fiber diameter of the single fibers is 25 μm or more, the load that can be supported by the fiber yarn composed of these single fibers can be increased, but on the other hand, because of the relationship with the reinforcing member for a bicycle tire, there is an upper limit to the size of the average fiber diameter or the number of the single fibers constituting the fiber yarn in the case of constituting the fiber yarn. However, if the size of the average fiber diameter and the number of single fibers constituting the fiber yarn are adjusted within a predetermined range, the fabric can be favorably formed as the fiber yarn, and the resistance to breakage as the reinforcing member can be improved.

The average fiber diameter of the liquid crystal polyester single fibers constituting the liquid crystal polyester fiber yarn is preferably 28 μm or more, more preferably 35 μm or more, further preferably 40 μm or more, and particularly preferably 42 μm or more. The upper limit of the average fiber diameter of the liquid crystal polyester single fibers may be appropriately set in accordance with the relationship with the number of the single fibers of the liquid crystal polyester single fibers, and may be, for example, 500 μm or less, preferably 300 μm or less, more preferably 100 μm or less, and still more preferably about 60 μm or less. The average fiber diameter is a value measured by the method described in the examples described below. In the case where the liquid crystal polyester single fiber has a deformed cross section, the fiber diameter of the single fiber may be a value measured by the circumscribed circle diameter of the cross-sectional shape.

The number of liquid crystal polyester single fibers constituting the liquid crystal polyester fiber yarn can be appropriately set in accordance with the average fiber diameter of the liquid crystal polyester single fibers, but is preferably 5 or more, and more preferably 7 or more. The upper limit of the number of the single fibers may be appropriately set in relation to the average fiber diameter of the liquid crystal polyester single fibers, but may be, for example, 60 or less, preferably 40 or less, and more preferably 29 or less.

The product of the number (root) of the single fibers in the fiber yarn and the average fiber diameter (μm) may be appropriately set according to the value of the average fiber diameter and the number of the single fibers, but is preferably about 250 to 1700, and more preferably about 300 to 1500.

The fiber yarn is not particularly limited as long as it can be used as a knitting yarn, and may be any of a fiber yarn, a spun yarn, a composite yarn, and the like, but is preferably a fiber yarn.

The fiber yarn may be untwisted yarn or twisted yarn. In the case of twisted yarn, the number of twists may be, for example, 1 to 30 times/10 cm, preferably 2 to 20 times/10 cm, and more preferably 3 to 18 times/10 cm. The warp and weft may be the same or different in twisting direction, but preferably are the same. Here, the number of twists (times/10 cm) represents the number of twists of the fiber line between 10cm, and is a value measured by the method described in the following examples.

For example, the liquid crystal polyester fiber yarn can have a fiber strength of, for example, 15cN/dtex or more, preferably 18cN/dtex or more, and more preferably 20cN/dtex or more. The upper limit of the fiber strength is not particularly limited, but the fiber strength may be, for example, 50cN/dtex or less or 40cN/dtex or less. The fiber strength is a value measured by the method described in the examples described below.

The liquid crystal polyester fiber yarn may be post-processed as needed. As the post-processing, a bulking processing is preferable, and examples of the bulking processing include twisting, heat setting, untwisting, false twisting, indentation, shaping, friction processing, taslon processing, and the like. Among these processes, taslon processing in which fibers are not stretched is preferable, and in taslon processing, high-pressure air in a turbulent flow is supplied to a multifilament in an aligned state to disorder the arrangement of the yarns, thereby imparting bulkiness to the yarns.

The woven fabric may be a sheet-like fabric in which the warp and weft are crossed at a certain regular angle, and examples of the weave include plain weave, twill weave, satin weave, and curtain weave. Preferred fabrics include flat fabrics and curtain fabrics. The liquid crystal polyester fiber yarn may be used for both the warp and the weft, or may be used for only one. Preferably, the liquid crystal polyester fiber yarn is used at least for the warp yarn, more preferably, the liquid crystal polyester fiber yarns cross each other, and most preferably, the fabric is entirely composed of the liquid crystal polyester fiber yarns.

The warp and/or weft constituting the woven fabric is preferably in a flat shape [ e.g., a shape in which the width of the warp and/or weft (the maximum diameter of the fiber yarn) is 2 to 10 times the thickness of the warp and/or weft (the minimum diameter of the fiber yarn) ]. For example, the width of the warp and/or weft may be about 0.1 to 3.0mm, and more preferably about 0.15 to 2.0 mm.

The warp density of the woven fabric may be, for example, 40 threads/2.54 cm or more, preferably 45 threads/2.54 cm or more, from the viewpoint of suppressing the occurrence of gaps in the woven fabric structure. The upper limit of the warp yarn density may be appropriately set according to the kind of the woven fabric, but may be, for example, 90 yarns/2.54 cm or less. The warp density is a value measured by the method described in the examples below.

The basis weight of the woven fabric is preferably 70g/m2 or more, more preferably 80g/m2 or more, and still more preferably 90g/m2 or more, from the viewpoint of resistance to breakage. On the other hand, from the viewpoint of weight reduction of the tire, the weight per unit area of the fabric is preferably 300g/m2 or less, more preferably 250g/m2 or less, and still more preferably 200g/m2 or less. Here, the basis weight is a value measured by a method described in examples to be described later.

In addition, the weight (unit: g) of the fabric used for each tire may be, for example, 15 × L or less, preferably 10 × L or less, more preferably 5 × L or less, and for example, 2 × L or more, when the circumferential length (unit: m) of the tire is L, from the viewpoint of light weight. In a typical bicycle, the weight of the fabric may be, for example, 30g or less, more preferably 20g or less, still more preferably 10g or less, and may be, for example, 5g or more.

The thickness of the woven fabric may be, for example, about 0.10 to 1.00mm, preferably about 0.15 to 0.80mm, and more preferably about 0.20 to 0.60mm from the viewpoint of achieving both the fracture resistance and the thinness.

The reinforcing member may further comprise a woven fabric of a polyvinyl alcohol-based fiber yarn composed of a plurality of single fibers having an average fiber diameter of the single fibers of 45 μm or less, in addition to the woven fabric composed of the liquid crystal polyester fiber yarn. Since the polyvinyl alcohol-based fiber yarn is excellent in the puncture resistance of the woven fabric, the reinforcing member can achieve both the breakage resistance and the puncture resistance. The fabric of the polyvinyl alcohol based fiber yarn can be produced by matching the production conditions of the fabric of the liquid crystal polyester fiber yarn.

The obtained woven fabric can be used as it is as a reinforcing member, and if necessary, (i) the woven fabric may be subjected to a pretreatment such as resorcinol ■ formalin (formaldehyde) ■ latex (RFL) treatment, and/or (ii) a rubber layer may be provided on at least one surface of the woven fabric. By performing the pretreatment of (i) above, the adhesion to the rubber layer can be improved.

The RFL treatment may be performed by dipping the fabric, applying an RFL treatment liquid, or the like. The treating liquid may contain a tackiness improver for polyester fibers such as a chlorophenol-based tackiness agent. Such a tackiness improver for polyester fibers is commercially available, for example, as Denabond (trade name) from Nagase ChemteX corporation. In the RFL treatment liquid, the molar ratio of R (resorcinol)/F (formalin) may be, for example, 1.0/1.0 to 1.0/4.5, preferably 1.0/1.3 to 1.0/3.5, and more preferably 1.0/1.5 to 1.0/2.0. The weight ratio of RF (resorcinol ■ formalin)/L (latex) may be, for example, 1/2 to 1/8, preferably 1/3 to 1/7, and more preferably 1/4 to 1/6. The solid content weight ratio of the tackiness improver for RFL/polyester fibers is, for example, 10/1 to 10/10, preferably 10/2 to 10/7.

As the latex, various rubber latex can be used, and examples thereof include natural rubber latex, styrene ■ butadiene rubber latex, acrylonitrile ■ butadiene rubber latex, chloroprene rubber latex, vinylpyridine ■ styrene ■ butadiene rubber latex, ethylene ■ propylene ■ non-conjugated diene terpolymer rubber latex, and the like, and these can be used alone or in combination. Among them, styrene ■ butadiene rubber latex and vinylpyridine ■ styrene ■ butadiene terpolymer rubber latex are preferable.

In addition, pretreatment with an epoxy compound or an isocyanate compound may be performed before the RFL treatment, if necessary. In the pretreatment, the epoxy compound and the isocyanate compound may be used by mixing a known or conventional compound with water or an organic solvent to obtain a treatment solution for dipping or coating a fabric. As the water-soluble aliphatic epoxy resin, a Denacol series available from Nagase ChemteX GmbH, or the like can be used.

In the case where the reinforcing member is formed by combining the rubber layer with the woven fabric, the rubber layer may be provided on only one side of the woven fabric, or may be provided on both sides of the woven fabric. The rubber layer may be a sheet having a thickness of, for example, about 0.10 to 1.50mm, preferably about 0.20 to 1.30mm, and more preferably about 0.30 to 1.20 mm. In addition, the rubber layer preferably covers the fabric.

The rubber forming the rubber layer may be, for example, a rubber formed of a monomer or a blend of natural rubber, styrene ■ butadiene rubber, acrylonitrile ■ butadiene rubber, chloroprene rubber, vinylpyridine ■ styrene ■ butadiene rubber, ethylene ■ propylene ■ non-conjugated diene-based terpolymer rubber, or the like. The rubber is preferably a vulcanized rubber, and from the viewpoint of adhesion, a vulcanized rubber layer subjected to heating and pressing is preferred.

When the rubber layer is provided to the RFL-treated fabric, the rubber latex used for the RFL treatment may be the same type or different types from the rubber of the rubber layer forming the reinforcing member, but the same type is preferable.

When the rubber layer is provided, the total thickness of the reinforcing member including the woven fabric and the rubber layer may be, for example, 0.20 to 3.50mm, preferably 0.40 to 3.00mm, and more preferably 0.60 to 2.50 mm.

For example, in the case of a specimen (longitudinal 15cm × lateral 15cm, thickness of about 2mm) obtained by vulcanizing and integrating an unvulcanized rubber sheet arranged above and below a woven fabric together with the woven fabric under heat and pressure, when a penetration test is performed at the center portion of the specimen using a plunger (a cylindrical object having a spherical tip with a diameter of 8mm) in a state in which a circle having a diameter of 40mm at the center portion of the specimen is removed and the periphery is fixed, the maximum load is, for example, preferably 850N or more, more preferably 870N or more, and still more preferably 900N or more. The higher the maximum load, the better, but usually about 3000N. Here, the maximum load may be a value measured by a method described in examples to be described later. The sample can be adjusted to a thickness of about 2mm (1.9 to 2.3mm) by heating and pressing with a mold.

[ bicycle tires ]

The bicycle tire according to the present invention is constituted by at least a tread portion disposed on a ground contact surface of the bicycle tire and a carcass portion disposed inside the tread portion, and the reinforcing member is disposed at least at one position selected from among a space between the tread portion and the carcass portion, an inside of the carcass portion, and an inside of the tread portion. The thickness of the ground contact surface of the bicycle tire may be, for example, 1.0 to 10.0mm, preferably 1.2 to 7.0mm, and more preferably 1.5 to 5.0 mm.

The tread portion is generally formed of rubber. The carcass portion is made of at least a fabric, but the periphery of the fabric may be covered with a rubber layer as necessary. The rubber forming the rubber layer of the reinforcing member and the rubber forming the tread portion and/or the carcass portion with which the reinforcing member is in contact may be the same type or different types, but preferably the same type.

The reinforcing member is preferably arranged such that the warp direction of the woven fabric is inclined with respect to the center line in the circumferential direction of the tire cross section. The warp direction of the fabric may be, for example, 30 to 60 °, preferably 40 to 50 °, with respect to the center line.

Hereinafter, embodiments of the bicycle tire according to the present invention will be described with reference to the drawings. However, the present invention is not limited to the illustrated embodiments. In fig. 1 to 3, common reference numerals are assigned to common embodiments, and the description thereof is omitted.

Fig. 1 is a schematic cross-sectional view showing a bicycle tire according to a first embodiment of the present invention. As shown in fig. 1, a bicycle tire 100 according to a first embodiment of the present invention includes a tread portion 12 that contacts the ground and a carcass portion 16 that corresponds to a skeleton portion of the tire. A carcass portion 16 is provided in a direction from the tread portion 12 toward the rotation axis of the tire for a vehicle, and the reinforcing member 14 is disposed between the tread portion 12 and the carcass portion 16.

The carcass portion 16 may be formed by, for example, covering one or more layers of carcass fabric with a rubber layer having a predetermined thickness. If necessary, the bead wires 18 may be wrapped with a carcass fabric at both ends of the carcass portion 16. The bead wire 18 may be made of a metal steel wire, an organic fiber or inorganic fiber rope, or the like.

For example, the bicycle tire 100 shown in fig. 1 is an open side type tire, and the carcass portion 16 includes a sidewall portion 15 on a side surface of the tire and a bead portion 17 of a fixing portion to a rim (not shown). In the bead portion 17, a carcass fabric (not shown) constituting the carcass portion 16 encloses the bead wire 18, and the carcass fabric and the bead wire 18 are integrated with each other in the bead portion 17 by being covered with rubber from the outside.

The tread portion 12 may be provided in a portion directly contacting the road surface, but may extend toward the side wall portion 15 as needed. From the viewpoint of weight reduction, the tread portion is disposed with the land portion of the tire as the center, and the extension ratio to the side wall portion is preferably equal to or less than half the width of the side wall portion.

In the case where the reinforcing member 14 is disposed outside the carcass portion 16 and inside the tread portion 12 (that is, in the case where the reinforcing member 14 is disposed between the carcass portion 16 and the tread portion 12), the reinforcing member 14 is preferably disposed in a range equal to or smaller than the width of the tread portion 12 with the center line Y in the circumferential direction X of the tire cross section shown in fig. 1 being substantially centered, and for example, the width of the reinforcing member 14 may be in a range of 70 to 100%, preferably 75 to 98%, and more preferably 80 to 95% of the width of the tread portion 12. Each width is a length between both ends of each portion in the circumferential direction X of the tire cross section (i.e., a wide length when the width direction is extended linearly).

Fig. 2 is a schematic cross-sectional view of a bicycle tire according to a second embodiment of the present invention. As shown in fig. 2, a bicycle tire 200 according to a second embodiment of the present invention includes a tread portion 22 that contacts the ground, and a carcass portion 26 that corresponds to a skeleton portion of the tire. The reinforcing member 24 is disposed inside the carcass portion 26.

The carcass portion 26 may include a plurality of carcass fabrics (not shown) at least at a portion where the reinforcing member 24 is disposed, and in this case, the reinforcing member 24 may be sandwiched between the carcass fabrics in the carcass portion 26, and preferably, the reinforcing member 24 is disposed inside the carcass portion 26 with the center line Y in the circumferential direction X of the tire cross section shown in fig. 2 being substantially centered. For example, the width of the reinforcing member 24 may be in the range of 70 to 200%, preferably 75 to 150%, and more preferably 80 to 130% of the width of the tread portion 22. Here, each width means a length between both ends of each portion in the circumferential direction X of the tire cross section.

Fig. 3 is a schematic cross-sectional view of a bicycle tire according to a third embodiment of the present invention. As shown in fig. 3, a bicycle tire 300 according to a third embodiment of the present invention includes a tread portion 32 that contacts the ground, and a carcass portion 36 that corresponds to a skeleton portion of the tire. The reinforcing member 34 is disposed inside the tread portion 32.

The reinforcing member 34 is disposed inside the tread portion 32 substantially centered on a center line Y in the circumferential direction X of the tire cross section shown in fig. 3, and the width of the reinforcing member 34 may be, for example, in the range of 60 to 95%, preferably 65 to 90%, and more preferably 70 to 85% of the width of the tread portion 32. Here, each width is a length between both ends of each portion in the circumferential direction X of the tire cross section.

When the tread portion 32 is formed with the groove portion, the reinforcing member 34 is preferably disposed in a range not exposed from the groove portion.

Examples

The present invention will be described in more detail with reference to the following examples, but the present invention is not limited to these examples at all. In the following examples and comparative examples, various physical properties were measured by the following methods.

[ average fiber diameter (. mu.m) ]

Using an X-ray CT apparatus, a two-dimensional cross-sectional image of 5 fiber threads randomly collected from the warp and weft of the fabric was obtained. In the two-dimensional cross-sectional image, 10 single fibers were randomly selected for 1 fiber line, and the fiber diameter was measured, and the average value of the total 50 fiber diameter data obtained was determined as the average fiber diameter. When the number of the single fibers constituting 1 fiber yarn is less than 10, the fiber diameters of all the single fibers in the fiber yarn are measured, and the average value of all the fiber diameter data obtained for 5 fiber yarns is defined as the average fiber diameter.

[ fiber Strength (cN/dtex) ]

The fiber strength was measured in accordance with JIS L1013 "chemical fiber yarn testing method" 8.5.1.

[ line Width (mm) ]

The fabric was placed on a flat table, the unnatural wrinkles and tension were removed, and the fabric was observed with a digital microscope (VHX-2000, Keyence) having a measurement function for 3 different portions, and the average line width of one fiber line was obtained from the average value of 15 lines in total of 5 line widths measured for each portion.

[ warp yarn Density (root/2.54 cm) ]

The warp density of the fabric was measured according to 8.6.1 of JIS L1096 "general Fabric test method".

[ number of twists (times/10 cm) ]

With reference to 8.13 of JIS L1013 "chemical fiber yarn testing method", the number of twists per 10cm of a fiber yarn was measured with the clamp interval of a twist checker set to 10 cm.

[ weight per unit area (g/m2) ]

The basis weight of the fabric was measured in accordance with JIS L1096 "general Fabric test method" 8.3.2.

[ thickness (mm) ]

The thickness of the fabric was measured in accordance with 8.4 of JIS L1096 "general Fabric test method".

[ maximum load (N) ]

An integrated test piece (15 cm in the vertical direction, 15cm in the horizontal direction, 2mm in thickness) was obtained by sandwiching both sides of a woven fabric with an unvulcanized rubber sheet containing sulfur ((natural rubber RSS #3, SBR rubber trade name "Nipol 1500") at a weight ratio of 1/1, thickness: 1mm), placing in a mold capable of producing a test piece having a thickness of 2mm, heating and pressurizing the rubber sheet at a temperature of 150 ℃ and a pressure of 50kg/cm2 for 30 minutes, and thermally pressing the rubber sheet against the woven fabric while vulcanizing the rubber sheet. The fabric used was a fabric previously treated with RFL (R/F molar ratio 1/1.7, and RF/L weight ratio 1/5). Further, "Vectran" (TM) and "Kevlar" (TM) were treated with an RFL treatment solution in which a Denabond (trade name) manufactured by Nagase ChemteX Co., Ltd was added as a tackiness improver for polyester (the solid content weight ratio of RFL/Denabond was 10/4). Using the obtained specimen, a penetration test was carried out using a constant speed penetration tester equipped with a plunger (diameter of spherical tip: 8mm), as shown in FIG. 4.

Fig. 4 is a schematic cross-sectional view of the constant velocity penetration tester. The specimen 53 includes a woven fabric 51 and vulcanized rubber layers 52 and 52 located on the upper and lower surfaces of the woven fabric 51. On the other hand, the constant speed penetration tester includes a plunger 54 that descends at a constant speed, and fixed disks 56, 56 that fix the specimen 53 from above and below. The circumference of the specimen 53 was fixed by the fixing disks 56 and 56 by removing a circle having a diameter of 40mm around the penetrating portion of the plunger 54, and the strength of the specimen 53 punctured by the plunger 54 decreased at a rate of 5cm per 1 minute was measured and used as the maximum load.

(example 1)

A flat woven fabric was produced by using "Vectran" (TM) fiber (average fiber diameter of single fibers: 49 μm, number of single fibers: 10, number of twists: 10 times/10 cm, fiber strength: 22.9cN/dtex, manufactured by Kuraray GmbH) as a liquid crystal polyester fiber yarn for warp and weft. In the resulting flat fabric, the warp and weft yarns are flat in shape. The performance evaluation of the resulting flat fabric is shown in table 5.

(example 2)

A flat woven fabric was produced by using "Vectran" (TM) fiber (average fiber diameter of single fibers: 30 μm, number of single fibers: 27, number of twists: 10 times/10 cm, fiber strength: 22.9cN/dtex, manufactured by Kuraray GmbH) as a liquid crystal polyester fiber yarn for warp and weft. In the resulting flat fabric, the warp and weft yarns are flat in shape. The performance evaluation of the resulting flat fabric is shown in table 5.

(example 3)

"Vectran" (TM) fiber manufactured by Kuraray GmbH (TM) (average fiber diameter of single fiber: 43 μm, number of single fibers: 27, number of twists: 15 times/10 cm, fiber strength: 22.9cN/dtex) was used as a liquid crystal polyester fiber yarn for warp and weft to produce a curtain fabric. In the resulting shade fabric, the warp yarns are flat in shape. The performance evaluation of the resulting shade fabric is shown in table 5.

(example 4)

"Vectran" (TM) fiber (average fiber diameter of single fibers: 32 μm, number of single fibers: 50, number of twists: 15 times/10 cm, fiber strength: 22.9cN/dtex, manufactured by Kuraray GmbH) was used as a liquid crystal polyester fiber yarn for warp and weft to produce a curtain fabric. In the resulting shade fabric, the warp yarns are flat in shape. The performance evaluation of the resulting shade fabric is shown in table 5.

Comparative example 1

A flat woven fabric was produced by using "Vectran" (TM) fiber (average fiber diameter of single fibers: 23 μm, number of single fibers: 48, number of twists: 10 times/10 cm, fiber strength: 22.9cN/dtex, manufactured by Kuraray GmbH) as a liquid crystal polyester fiber yarn for warp and weft. In the resulting flat fabric, the warp and weft yarns are flat in shape. The performance evaluation of the resulting flat fabric is shown in table 5.

Comparative example 2

Nylon 66 fiber (average fiber diameter of single fiber: 27 μm, number of single fibers: 72, number of twists: 20 times/10 cm, fiber strength: 9.2cN/dtex) manufactured by Dongli Ltd was used as a polyamide fiber yarn for warp and weft to prepare a flat woven fabric. In the resulting flat fabric, the warp and weft yarns are flat in shape. The performance evaluation of the resulting flat fabric is shown in table 5.

Comparative example 3

"Kevlar" (TM) fiber (average fiber diameter of single fibers: 12 μm, number of single fibers: 267, number of twists: 15 times/10 cm, fiber strength: 20.4cN/dtex, manufactured by Toho ■ DuPont GmbH) was used as an aramid fiber yarn for warp and weft to produce a flat woven fabric. In the resulting flat fabric, the warp and weft yarns are flat in shape. The performance evaluation of the resulting flat fabric is shown in table 5.

Comparative example 4

Vinylon fibers (average fiber diameter of single fibers: 16 μm, number of single fibers: 200, number of twists: 15 times/10 cm, fiber strength: 10.2cN/dtex) manufactured by Kuraray Ltd were used as polyvinyl alcohol based fiber threads for warp and weft to prepare a flat woven fabric. In the resulting flat fabric, the warp and weft yarns are flat in shape. The performance evaluation of the resulting flat fabric is shown in table 5.

Comparative example 5

"Vectran" (TM) fiber manufactured by Kuraray GmbH (TM) (average fiber diameter of single fiber: 23 μm, number of single fibers: 100, number of twists: 15 times/10 cm, fiber strength: 22.9cN/dtex) was used as a liquid crystal polyester fiber yarn for warp and weft to produce a curtain fabric. In the resulting shade fabric, the warp yarns are flat in shape. The performance evaluation of the resulting shade fabric is shown in table 5.

[ Table 5]

As shown in table 5, in the case of comparing examples 1 and 2 of the plain woven fabric with comparative example 1, both of the plain woven fabrics were the same level of weight per unit area as the liquid crystal polyester fiber yarn, but examples 1 and 2 had better resistance to breakage than comparative example 1. Patent document 1 describes that the finer the single fiber, the better the adhesion with the rubber compound and therefore the durability is improved, and in examples 1 and 2 using a woven fabric having a larger fiber ratio than in comparative example 1, it is an unexpected effect that the fracture resistance is improved even in a reinforcing member having a vulcanized rubber layer on both sides of the flat woven fabric.

In addition, in the case of comparing examples 3 and 4 of the curtain fabric with comparative example 5, the weight per unit area of the curtain fabric of the liquid crystal polyester fiber yarn was also the same, but examples 3 and 4 had better resistance to breakage than comparative example 5. In particular, in comparative example 5, although the number of single fibers was increased to overcome the fineness of the single fibers, it was an unexpected effect that the fracture resistance of examples 3 and 4 was higher than that of comparative example 5.

In comparative examples 2 and 4, in which the fiber strength was lower than in examples 1 and 2, the fracture resistance was inferior to that of example, but the result of the fracture resistance was also inferior to that of comparative example 3, in which the fiber strength was equal to that of examples 1 and 2, was an unexpected result.

Further, since the fabric formed of the vinylon fiber yarn shown in comparative example 4 had good puncture resistance when the penetration test was carried out by changing the needle to a plunger type (thickness: 18G (outer diameter of needle: 1.2mm), length: 38mm, and needle point shape: regular bevel (angle of blade face of tip portion: 12 degrees), it was considered that the reinforcing member could achieve both of the fracture resistance and the puncture resistance when combined with the fabric formed of the liquid crystal polyester fiber yarn.

[ industrial applicability ]

The reinforcing member of the present invention can be effectively used for the purpose of improving the breakage resistance of a bicycle tire, and can be suitably used for bicycle tires of various bicycles such as public bicycles, electric assist bicycles, road racing bicycles, mountain climbing bicycles, off-road bicycles, travel bicycles, recumbent bicycles, and folding bicycles.

As described above, although the preferred embodiments of the present invention have been described with reference to the drawings, various additions, modifications, and deletions may be made without departing from the scope of the present invention, and such a configuration is also included in the scope of the present invention.

Description of the reference numerals

100. 200 and 300: a bicycle tire;

12. 22, 32: a tread portion;

14. 24, 34: a reinforcing member;

16. 26, 36: a carcass portion;

15: a sidewall portion;

17: a bead portion;

18: a bead wire.