阅读说明：本技术 具有优异光学质量的汽车嵌装玻璃 (Automotive glazing with excellent optical quality ) 是由 P·德鲁克斯 F·德康 于 2020-02-12 设计创作，主要内容包括：本发明的一个目的是提供一种具有优异光学质量的汽车嵌装玻璃。本发明的另一个目的是提供一种用于减少包括瓷釉遮蔽罩2的嵌装玻璃中的光学畸变的方法。(It is an object of the present invention to provide an automotive glazing having excellent optical quality. It is another object of the present invention to provide a method for reducing optical distortion in a glazing comprising an enamel shield 2.)

1. A method for producing an automotive glazing 1 comprising an optical sensor device (6), characterized in that it comprises the following steps:

-providing at least one glass sheet (3, 4),

-applying an enamel shield (2) on at least one face of said at least one glass sheet (3, 4) to block the field of view from outside the vehicle, said shield (2) extending to the area where said at least one optical sensor device (6) is to be fixed, said shield comprising at least one opening (7, 7 ', 7 ") on the side of the interior of the vehicle in order to be able to acquire information from said optical sensor device (6) intended to be fixed on said at least one opening (7, 7 ', 7") through said opening (7, 7 ', 7 "),

-drying or firing the enamel screen (2),

-applying a washable cover layer (25) on the surface of said at least one opening (7, 7', 7 "), said washable cover layer withstanding temperatures of at least 620 ℃,

-subjecting the glass sheet to a heat treatment at a temperature higher than 450 ℃, preferably higher than 650 ℃, preferably during bending or tempering,

-removing the cover layer (25) by washing.

2. A method according to claim 1, characterized in that the automotive glazing (1) is a laminated glazing formed by laminating at least one outer glass (3) sheet and one inner glass (4) sheet with a thermoplastic interlayer (5).

3. The method according to claim 1 or 2, wherein the washable cap layer (25) covers the at least one opening (7, 7 ', 7 ") and extends from a peripheral edge (21) of the opening (7, 7 ', 7") partially towards the mask (2) surrounding the opening (7, 7 ', 7 ").

4. Method according to the preceding claim, characterized in that the washable cover layer (25) is a washable frit-free enamel or ink or a suspension of mineral particles, resistant to temperatures of at least 620 ℃.

5. Method according to the preceding claim, characterized in that the washable cover layer (25) is applied by screen printing or spraying.

6. The method according to any of the preceding claims, characterized in that the washable veil layer (25) is applied after the step of drying the enamel masking layer at a temperature between 90 ℃ and 150 ℃.

7. The method according to any of the claims 1 to 5, characterized in that the washable cap layer (25) is applied after the step of firing the enamel screen layer (2) at a temperature higher than 550 ℃ for more than 10 seconds.

8. Method according to any of the preceding claims, characterized in that the enamel screen (2) can be applied on the inner face (P2) of the outer glass sheet (3), or on the inner face (P3) or on the outer face (P4) of the inner glass sheet (3), or on both.

9. Method according to any of the preceding claims, characterized in that the enamel screen (2) is a black enamel.

10. A method according to any of the preceding claims, characterized in that the glazing (1) is a windscreen.

11. A laminated glazing (1) obtained by the method according to any one of claims 1 to (10).

12. The laminated glazing according to claim 11, characterized in that an optical sensor device (6) is arranged on the surface of the glass sheets (3, 4) on the at least one opening (7, 7 ', 7 ") on the vehicle interior side, in order to be able to acquire information through the opening (7, 7', 7").

13. The laminated glazing (1) according to claims 11 and 12, characterized in that the optical sensor (6) is chosen among a camera, an infrared camera, a lidar and a laser pointer.

14. The laminated glazing (1) according to any of the preceding claims, wherein the glazing (1) comprises an outer glass sheet (3), an inner glass sheet (4) arranged opposite the outer glass sheet, and an interlayer (5) arranged between the outer glass sheet (3) and the inner glass sheet (4).

Disclosure of Invention

In order to avoid these difficulties and to meet the masking requirements, the present invention proposes to provide a laminated glazing having excellent optical quality. Another object of the invention is to provide a method for reducing optical distortions in a glazing comprising a shadow mask of black enamel frit surrounding at least one daytime daylight opening for an optical sensor device.

It is an object of the present invention to provide a method for producing an automotive glazing comprising an optical sensor device, characterized in that it comprises the following steps:

-providing at least one glass sheet comprising an inner face and an outer face,

-applying an enamel shield on at least one face of the at least one glass sheet to block the field of view from outside the car, the shield extending to the area to which the at least one optical sensor device is to be fixed, the shield comprising at least one opening on the side of the interior of the car to enable information to be acquired through the opening from the optical sensor device intended to be fixed on the at least one opening,

-drying or firing the enamel shielding cover (2),

-applying a washable cover layer on the surface of the at least one opening, the cover layer being resistant to a temperature of at least 620 ℃,

-subjecting the glass sheet to a heat treatment at a temperature higher than 450 ℃, preferably higher than 650 ℃, preferably during bending or tempering,

-removing the cover layer by washing.

By adding a washable cover layer on the surface of the at least one opening provided in the mask prior to the bending or tempering step, the optical result forms a more uniform heat distribution over the entire component during the bending process, which reduces or even eliminates optical distortion caused by thermal gradients. Thus, an optical sensor device intended to be fixed within the opening will work more efficiently without being affected by optical distortions in the so-called "camera area", since optical distortions caused by the enamel shielding cage are reduced or even eliminated within the at least one opening.

According to the invention, the washable cover layer withstands temperatures of at least 620 ℃ measured on the surface of the glass sheet by well-known techniques.

According to the invention, a glass sheet provided with an enamel screen on at least one face of at least one glass sheet and a washable cover layer according to the invention is subjected to a heat treatment at a temperature higher than 450 ℃, preferably higher than 650 ℃, preferably during a bending or tempering process. The temperature corresponds to the temperature measured in a furnace in which the glass sheet is subjected to such high temperatures.

According to one embodiment of the invention, the automotive glazing is a laminated glazing. The laminated glazing is preferably formed from at least one outer glass sheet and one inner glass sheet laminated with a thermoplastic interlayer.

In the case of laminated glazing, the enamel-masking frit inclusive cap is preferably provided on the inner face (P4) of the inner glass sheet.

According to one embodiment of the invention, a washable cover layer covering at least one opening provided in the enamel screen may extend partially from a peripheral edge of the opening towards the screen surrounding the opening.

In a more specific embodiment, the washable cover layer covering the at least one opening provided in the enamel shield can extend partially from the peripheral edge of the opening towards the shield around the opening in an area corresponding to a range of 5mm to 50mm from the peripheral edge of the opening towards the shield layer around the opening.

According to a preferred embodiment of the invention, the washable cover layer is a washable enamel free of frits or inks or suspensions of mineral particles, resistant to temperatures of at least 620 ℃.

It should be understood that the term "washable" means that the covering layer is made of: this material can be removed after a washing treatment with water or any removal process (such as mechanical brushing on the glass surface), which allows the cover layer to be removed without damaging the enamel masking tape.

According to a particular embodiment, the washable enamel resistant to temperatures of at least 620 ℃ may be an enamel free of frits (a mixture of silica and a flux that melts at high temperatures to make glass), such as a commercial product“Contrast"or" Kontras t". These kinds of enamels may be used in combination with conventional glass enamels. These kinds of enamels are characterized in that they do not fuse to the glass surface during firing, but only to the surface already covered by a conventional enamel with frits.

In a preferred embodiment, the washable enamel is a white enamel without frit. One known commercial white enamel is supplied by the firm Johnson Matthey company, number PG 000-654-63. The washable enamel preferably covers the at least one opening and extends partially from the peripheral edge of the opening towards the screening cover surrounding the opening in an area corresponding to a range of 5mm to 50mm from the peripheral edge of the opening towards the screening cover surrounding the opening.

The inventors have thus surprisingly shown that in the area where the optical sensor device is to be fixed, and more generally in the area surrounding the at least one opening, the optical distortion is significantly reduced. It has been shown that the optical distortion in the "camera area" can be reduced by up to 50% or even more compared to a glazing panel where the opening in the "camera area" is not covered by a washable enamel cover layer without frit before the glazing panel is bent.

It is understood that the washable enamel may contain other pigments in addition to the white pigment. For example, the washable enamel cover layer may contain black pigments.

The washable enamel cover layer may be in the form of a liquid or paste and may be applied by screen printing or by spraying or by any suitable technique.

According to another embodiment of the invention, the washable cover layer that is resistant to temperatures of at least 620 ℃ may be an ink.

According to another embodiment of the invention, the washable cover that is resistant to temperatures of at least 620 ℃ may be a suspension of mineral particles. For example, the suspension of mineral particles may be a graphite-based solution (carbon powder). The graphite solution may preferably be sprayed only on at least the open surfaces within the enamel shield without extending partially over the enamel shield. Thus, it has been shown that the optical distortion in the camera area can be improved by up to 40% or even more compared to a glazing panel where the opening in the "camera area" is not covered by the ink washable cover layer before the glazing panel is bent.

Thus, as described above, the coating may be screen printed or spray coated depending on the type of washable coating used. The washable cover layer may be applied only in the area delimited by the at least one opening provided in the shield and intended to receive the optical sensor device, or may extend partially over the enamel shield.

According to the invention, the step of drying the enamel shield at least at a temperature between 90 ℃ and 150 ℃ is followed by the application of a washable cover layer.

According to one embodiment of the invention, the washable cover layer is applied after the step of curing/firing the enamel cover mask at a temperature above 550 ℃ for more than 10 seconds.

This embodiment is of particular interest when the glazing should be stored before bending. The glazing provided with an enamel screen (having at least one opening for the optical sensor device) can be stored and when the glazing is intended to be bent, a washable cover layer is then applied, so as to avoid damage to the enamel screen.

According to one embodiment of the invention, an enamel cover can be applied on face 2 or face 3 or face 4, or on both face 2 and face 4. The location of the mask will depend on the final aesthetic aspect desired by the customer, or the particular insert or bus bar or element on the glass to be concealed by the black band.

According to the invention, the enamel screen is a black enamel frit comprising a pigment, a carrier, a binder and finely ground glass. Other materials are sometimes added to enhance certain properties: firing temperature, antiblocking, chemical resistance, etc. The black frit is applied to the glass using a screen or inkjet printing process prior to heating and bending. During the bending process, the finely ground glass in the frit softens and fuses with the glass surface. When this occurs, the frit is referred to as "fired".

According to one embodiment of the invention, the glazing produced by the process is an automotive windshield.

It is understood that the method according to the invention may be applied to any laminated glazing unit on which an enamel shield is applied, on which glazing unit an enamel shield is applied and which glazing unit comprises at least one opening on which the optical sensor device is intended to be fixed.

In particular, the invention relates to a laminated glazing and in particular a windscreen, wherein optical distortions are reduced or even eliminated in the region where the optical sensor and in particular the camera is placed in the masking strip and more particularly in the at least one opening in the black ceramic strip.

In particular, the invention relates to a laminated glazing and in particular a windscreen, wherein an optical sensor device is arranged on at least one opening on the surface of the glass pane on the vehicle interior side, in order to be able to acquire information through the opening.

According to the invention, more than one opening may be provided in the enamel screen to receive more than one optical sensor device. The number of openings may depend on the number of optical sensor devices intended to be fixed on the glazing.

According to one embodiment of the invention, the at least one optical sensor device is selected among a camera, an infrared camera, a lidar and a laser pointer.

In a particular embodiment of the invention, the optical sensor device is a camera.

With the advent of vehicles capable of various degrees of autonomous operation, the use of cameras requiring a wide field of view and a high level of optical clarity is also growing rapidly. The resolution of cameras is also increasing at the same fast rate. These must typically be mounted on the windshield in the region of the wipers. Early initial applications were for night vision. Today, camera-based systems are used to provide a wide range of safety functions, including adaptive cruise control, obstacle detection, lane departure warning, and support for autonomous operation. Many of these applications require the use of multiple cameras. A clear undistorted field of view is particularly critical for a camera-based system to perform as intended. These systems must be able to quickly distinguish objects, capture text, recognize landmarks, and operate with minimal illumination. Furthermore, as the resolution of the cameras used increases, the need for a clear, undistorted field of view also increases.

Drawings

Fig. 1 shows a typical automotive windscreen 1 provided with an enamel-masking frit inclusive cap 2 (more specifically a black band).

Fig. 2 shows an automotive windscreen 1 having an enamel-masking frit mask (black band) 2 extending along a side edge 21 of the windscreen, a wiper resident mask 23 and a masking central mask 22 extending downwardly from the black band mask 2, the masking central mask having at least one opening 7 providing a forward field of view for one camera.

Fig. 3 shows an automotive windscreen 1 on which an optical sensor 6 and more particularly a camera is placed behind an enamel-covered frit inclusive cap 2 provided on a face 4 of the windscreen.

Fig. 4 shows an overview of the method according to the invention.

Fig. 5a shows the masking of the camera area comprising three openings 7, 7', 7 "with a white (fig. 5a-1) or black (fig. 5a-1) washable enamel according to an embodiment of the invention, as well as the improvement of the optical distortion in the" camera area ".

Fig. 6a and 6b show a mask of 2 openings 7, 7 ' provided with a solution of dissolved carbon powder sprayed only on the surface of the openings 7, 7 ' (fig. 6a-1) or on the surface covering the openings 7, 7 ' and partially covering the enamel masking strip 2 (fig. 6a-2) and an improvement of the optical distortion in the "camera area" according to one embodiment of the invention.

Fig. 5b and 6b show the results obtained as a result of the present invention.

Reference numerals

1. Laminated glazing

2. Frit cover for shielding enamel

3. Outer glass sheet

4. Inner glass sheet

5. Sandwich layer

6. Optical device

7.7' field of view/opening

21. Peripheral edge cover

22. Center shielding cover

23. Wiper resident shielding cover

25. Washable cover

26. Camera zone

P1: outside of the outer glass sheet

P2: inner face of the outer glass sheet

P3: inner surface of the inner glass sheet

P4: the outside of the inner glass sheet.

Detailed Description

The described embodiments and their advantages are best understood by referring to the following description in conjunction with the accompanying drawings. These drawings in no way limit any changes in form and detail that may be made to the described embodiments by one skilled in the art without departing from the spirit and scope of the described embodiments.

For simplicity, the numbering of the glass sheets in the specification refers to the numbering designation conventionally used for glazing. Therefore, the face of the laminated body that is in contact with the external environment of the vehicle is referred to as face 1, and the surface that is in contact with the interior side (i.e., the passenger compartment of the vehicle) is referred to as face 4.

For the avoidance of any doubt, the terms "exterior" and "interior" refer to the orientation of the glazing during installation as it in a vehicle.

For the avoidance of any doubt, the present invention relates to laminated glazings and tempered glazings, even though the following description is more directed to laminated glazings.

The present invention therefore eliminates the disadvantages associated with the black frit masks of the prior art by masking the openings in the black frit mask with a washable enamel prior to the forming/bending step or tempering step. This allows for a more uniform thermal distribution across the component during bending, thereby reducing residual stresses and optical distortion caused by thermal gradients.

The inventors have surprisingly shown that in the area where the optical sensor device is to be fixed, and more generally in the area surrounding the at least one opening, the optical distortion is significantly reduced, this area is also referred to as "camera area". It has been shown that the optical distortion in the "camera area" can be reduced by up to 50% or even more compared to a glazing panel where the opening in the "camera area" is not covered by a washable enamel cover layer without frit before the glazing panel is bent.

Another benefit of this process is the ability to fine-tune the optical properties of the laminate.

In addition to the benefits to the finished laminate, eliminating the non-uniform heating and high thermal gradients present in the black nugget area also increases throughput through the bending process.

Distortion in windshields is measured in terms of refractive power or optical power. Optical power is the variation of angular deviation with distance. At a sufficiently high level, it can cause significant optical distortion. In the field of automotive glazing, the optical power is expressed in diopters or in particular in millidiopters.

α₁And alpha₂Is the angle of incidence of 2 parallel rays through the glazing. The difference between the 2 angles of incidence is the distortion given in radians.

Δ X is the distance between 2 parallel rays, also referred to as the differential length, in meters.

D is the optical power, representing the distortion in millidiopters (mdpt).

Most large windshield production lines utilize an on-line automated inspection system that scans the glass and generates a heat map that shows optical distortion in diopters.

According to an embodiment of the invention, a windscreen 1 to which a camera 6 or more generally an optical sensor device 6 (as shown in fig. 3) is attached will be described with reference to the drawings. The windscreen 1 according to this embodiment and shown in fig. 1 is a laminated glazing in the form of a windscreen 1 for a motor vehicle. The windscreen comprises an outer pane 3 having an outer face P1 and an inner face P2, and an inner pane 4 having an inner face P3 and an outer face P2 laminated together with a thermoplastic interlayer. A black enamel frit mask (band) 2, referred to below as a "black band", around the periphery of the windscreen 1 is provided on the inner face P4 of the laminated glazing. Black tape is an enamel frit mask typically used in the automotive field to mask out unsightly parts or to protect the glue from u.v. effects. It will be appreciated that the enamel frit masking shield may have a masking colour other than black, for example grey or another suitable colour to meet the requirements of the enamel masking frit shield.

Known glass sheets may be used as the outer glass sheet 3 and the inner glass sheet 4, and these glass sheets may also be made of IR absorbing glass, ordinary transparent glass or green glass or UV green glass. However, glass sheets 3 and 4 are required to achieve visible light transmittance in compliance with safety standards.

Although there is no particular limitation on the thickness of the laminated glass according to this embodiment, the total thickness of the outer glass sheet 3 and the inner glass sheet 4 is preferably set to 2.4mm to 4.2mm, more preferably 2.6mm to 3.4mm, and particularly preferably 2.7mm to 3.2mm from the viewpoint of weight reduction.

Although the thickness of the inner glass sheet 4 can be made equal to the thickness of the outer glass sheet 3, it is also possible to make the thickness of the inner glass sheet 4 smaller than the thickness of the outer glass sheet 3, for example, in order to reduce the weight of the laminated glazing.

Interlayer 5 is a thermoplastic interlayer to laminate together outer glass sheet 3 and inner glass sheet 4. The interlayer 5 may be a well-known acoustic interlayer. The thermoplastic interlayer can be a single or multiple thermoplastic interlayers. Although there is no particular limitation on the material constituting the layer 131, the interlayer 131 may be made of, for example, polyvinyl butyral resin (PVB). The polyvinyl butyral resin is excellent in adhesion to a glass sheet and penetration resistance, and is therefore preferable.

As mentioned above, the laminated glass according to this embodiment is used for a windshield of an automobile, which windshield uses an optical sensor device or more specifically a camera. In the case of a camera, the camera receives visible light or infrared light from a preceding vehicle to capture an image, and measures the speed of the preceding vehicle and the distance to the preceding vehicle. Therefore, laminated glass is required to achieve transmittance with respect to light having a wavelength within a predetermined range.

For example, the camera may be an infrared camera to measure the speed of the preceding vehicle and the distance to the preceding vehicle. In this case, the useful transmittance with respect to light (infrared light) having a wavelength of 700nm to 800nm is 30% or more and 80% or less, and preferably 40% or more and 60% or less.

The present invention proposes a method of manufacturing an automotive laminated glazing or tempered glazing having excellent optical quality on which an optical sensor 6, and more particularly a camera 6, is attached. It is another object of the present invention to provide a method for reducing optical distortion in a glazing comprising an enamel shield.

The method according to the invention can be summarized as figure 4. The method according to the invention comprises the following steps:

a. providing at least one glass sheet;

b. applying an enamel cover having at least one opening in which an optical sensor and more particularly a camera is to be attached;

c. applying a washable cover layer resistant to a temperature of at least 620 ℃ on a surface of the at least one opening;

d. subjecting at least one piece of glass, on which the enamel masking strip has openings recovered by a washable cover layer, to a heat treatment such as a tempering or bending/shaping step; in a furnace, at a temperature higher than 450 ℃ and preferably higher than 750 ℃,

e. the washable cover layer is removed by washing.

According to one embodiment of the invention, the automotive glazing is a laminated windshield 1 provided with an enamel shielding strip 2 on the outer face, i.e. face 4 (P4 in fig. 1), of the inner face of the glazing. As shown in fig. 2, 5 and 6, a cover layer 2 is formed on the edge of the glass sheet, which cover layer holds an opening 7 in the position of the "camera holder" in which the camera is to be attached. According to known techniques, it is contemplated that a glass sheet having a planar shape on which a cap layer has been formed may be subjected to heat bending in a form required by an automobile manufacturer. The glass sheets 3, 4 are molded into a curved shape using a mold. The mould for bending the glass sheet is arranged on a transport base which passes inside a heating furnace at a temperature comprised between 200 ℃ and 750 ℃ to solidify the cover layer and bend the glass sheet. In the case of a laminated glazing, the outer and inner glass sheets can be bent individually (sheet-by-sheet process) or together by superimposing the two glass sheets (full-press process). The curvilinear shape may have curvature in only a single direction, or curvature in multiple directions. Then, the windshield is obtained by performing an annealing treatment outside the heating furnace.

A first cap layer 2, as shown in fig. 2, is formed adjacent to the glass sheet 1. The cover layer 2 serves as a region for masking an adhesive or the like applied to attach the glass sheet 1 to a vehicle body from the outside, and includes a peripheral edge cover layer 21 formed at an outer peripheral edge of the glass sheet 1, and a center cover layer 22 extending downward from the peripheral edge cover layer 21 at the center of an upper edge of the glass sheet 1, which is also called a camera area. The above-mentioned measuring unit 6 is attached to the central cover layer 22. It is sufficient if the measuring unit 6 is arranged such that the light emitted by the sensor 5 passes through the centre of the opening and that the light reflected by the vehicles and obstacles in front can be received. Although the cover layer 2 may be made of various materials, there is no limitation on the material as long as the cover layer 2 can block a view from the outside of the vehicle, and the cover layer 2 may be formed by applying a ceramic of a dark color (such as black) to, for example, the glass sheet 1.

In fig. 2, as an example of the present invention, the center cover layer 22 is formed in a vertically extending "rectangular-like" shape, and the opening 7 is formed in a trapezoidal shape to form a field of view for the optical sensor, more specifically, for the camera 6.

It will be appreciated that the central cover layer 22 may be formed in any suitable form extending vertically and wherein more than one opening (7, 7', 7 ") is formed depending on the number of cameras to be attached to the glazing. In the center cover layer 22, the openings may be arranged in the vertical direction, i.e., the upper and lower openings, or in the horizontal direction as shown in fig. 5 and 6. The opening may have a trapezoidal shape or any form suitable for the field of view of the camera. The opening may have a shape of an "open form" such as an "inverted V shape", or a trapezoidal form (closed form). If more than one opening 7 is provided in the center cover layer 22, these openings can have the same or different forms (closed form). It is to be understood that there is no particular limitation on the size of the opening, and the upper opening 231 may be formed to have a longitudinal length of about 58mm and a lateral length of about 58mm, and the lower opening may be formed to have a longitudinal length of about 52mm and a lateral length of about 27 mm.

According to the invention, once the enamel screen 2 is applied, the glass sheet is subjected to a heat treatment to cure or dry the enamel. Depending on the type of washable cover layer 25 to be used, the enamel cover layer 2 should be dried or cured. In fact, it is better for some washable cover layers 25 to apply them after the enamel screen 2 has cured. However, some washable cover layers 25 can be applied quickly after the enamel screen 2 has dried, allowing a certain time to be obtained. Depending on the composition of the washable cover layer 25 and more particularly on whether it contains some components that interact with the uncured enamel cover 2.

According to the invention, the washable cover layer 25 can be applied to cover only at least one opening, as shown in fig. 6 a. However, the washable cover layer 25 may be applied to cover the at least one opening and extend partially from the peripheral edge of the opening towards the mask cover 2 surrounding the opening 7, 7', 7 ", for example in an area corresponding to the range of 5mm to 50mm from the peripheral edge of the opening towards the mask cover 2 surrounding the opening.

According to the invention, the cover layer 25 may be applied by any suitable and known method, such as by spraying, screen printing.

Fig. 5a-1 shows an embodiment according to which the camera area 26 in the central shield 22 is covered by an enamel containing white pigment, which is free of frit 2. The washable cover layer 25 has been sprayed to cover the openings 7, 7 ', 7 ", the washable cover layer 25 extending from the peripheral edge of the openings partially towards the mask 2 surrounding the openings 7, 7', 7". After the center shield 22 has been applied to the inside face P4 of the inner glass sheet 4 and dried at a minimum temperature of 90 ℃, the washable cover layer 25 is applied to the center shield 22. Once the enamel containing white pigments, free of frit 2, was applied on the face P4, the glass sheet was subjected to a bending process, the temperature of the glass sheet reaching 620 ℃ during a minimum of 40 seconds, to obtain the final shape of the glass sheet. After the bending step, the washable cover layer 25 has been removed by washing/brushing. After the glass sheets on the outer side 3 and the inner side 4 are bent together (full press) or separately (sheet by sheet), the two glass sheets 3, 4 are laminated together with a thermoplastic interlayer such as PVB. The lamination is performed according to well-known techniques. Thus, the laminated glass according to this embodiment is manufactured.

The laminated glazing obtained in the camera zone pair is then subjected to a measurement of the optical distortion and this optical distortion is compared with a typical laminated glazing provided with a black enamel masking strip 2 having openings 7, 7', 7 ".

Fig. 5a-2 show another embodiment of the invention in which a fritless enamel washable cover layer 25 comprising black pigments has been sprayed as in fig. 5a-1 and subjected to a heat treatment during the bending process as in fig. 5 a-1. The optical distortion is also measured in the camera area and compared with a glass sheet provided with a black enamel masking tape 2 with openings 7, 7', 7 ".

Thus, fig. 5b shows the optical distortion results measured from glass provided with a black enamel masking strip 2 having openings 7, 7 ', 7 "not covered by the washable cover layer 25, glass provided with a black enamel masking strip 2 having openings 7, 7', 7" covered by the washable cover layer 25 containing white and black pigments. The values indicated in fig. 5b are expressed in mdpt. Thus, by covering the openings with a black washable cover layer 25, the optical distortion is improved by 15% compared to a glass sheet provided with a black enamel masking strip 2 having openings 7, 7', 7 "not covered by the washable cover layer 25. By covering the openings with a white washable cover layer 25, the optical distortion is improved by up to 50% compared to a glass sheet provided with a black enamel masking strip 2 having openings 7, 7', 7 "not covered by a washable cover layer 25.

According to another embodiment of the invention as shown in fig. 6a-1, the cover layer 25 can be cleaned, for example by spraying a solution containing carbon powder only on the surfaces of the openings 7, 7', 7 ", after the mask 2 has been screen printed and dried as described above (i.e. on the glass sheet P4).

According to another embodiment, as shown in fig. 6a-2, the solution containing carbon powder is sprayed only on the surfaces of the openings 7, 7 ', 7 ", and the washable cover layer 25 extends partly from the peripheral edges of the openings towards the shielding cage 2 surrounding the openings 7, 7', 7".

Thus, fig. 6b shows the optical distortion results measured from glass provided with a black enamel shielding tape 2 having openings 7, 7 ', 7 "not covered by the washable cover layer 25, a black enamel shielding tape 2 provided with openings 7, 7', 7" covered by a suspension of dissolved carbon powder, wherein the glass having openings and a part of the black enamel shielding tape 2 is covered. The values indicated in fig. 5b are expressed in mdpt.

Thus, by covering the openings with a solution containing dissolved carbon powder as the washable cover layer 25, the optical distortion is improved by up to 40% compared to a glass sheet provided with a black enamel shielding tape 2 having openings 7, 7', 7 "not covered by the washable cover layer 25.

The invention also relates to a glazing obtained by the method according to the invention.