阅读说明：本技术 一种基于膜法澄清多元联产的制糖工艺 (Sugar production process based on membrane method clarification poly-generation ) 是由 李凯 陆文德 谢彩锋 杭方学 邓立高 陆海勤 潘莉莉 李文 周昊 梁汉柱 刘文青 于 2021-08-03 设计创作，主要内容包括：本发明公开一种基于膜法澄清多元联产的制糖工艺,混合汁经物理除杂后,先进行第一次浓缩至18～20～(o)Bx,浓缩后的混合汁再经陶瓷膜进行物理澄清,膜法清汁经第二次浓缩至55～65～(o)Bx的糖浆,按照常规白砂糖煮制工艺生产白砂糖和低蔗糖液体糖；第一次和第二次浓缩过程得到的甘蔗原水经活性炭和反渗透膜过滤,制成甘蔗植物水；陶瓷膜过滤后含杂质的浓液经离心澄清,与糖蜜混合生产红糖。本基于无化学助剂添加的膜法澄清工艺,将附产物高值化利用,延长产品链,增加经济效益,第一次浓缩减少了后续进行膜法澄清的混合汁量,从而减少膜法澄清设备的投资,降低生产成本,大大提高甘蔗制糖企业的经济效益。(The invention discloses a sugar production process based on membrane method clarification poly-co-production, which is characterized in that after physical impurity removal, mixed juice is firstly concentrated to 18-20 ℃ for the first time o Bx, physically clarifying the concentrated mixed juice by a ceramic membrane, and concentrating the membrane-method clear juice to 55-65 ℃ for the second time o Bx syrup, and conventional white sugar cooking process to obtain white sugar and low sucrose liquid sugar(ii) a Filtering the sugarcane raw water obtained in the first and second concentration processes by using activated carbon and a reverse osmosis membrane to prepare sugarcane plant water; and after being filtered by the ceramic membrane, the concentrated solution containing impurities is clarified by centrifugation and is mixed with molasses to produce brown sugar. The membrane method clarification process based on no chemical additive addition realizes high-value utilization of by-products, prolongs product chain, increases economic benefit, and reduces the amount of mixed juice for subsequent membrane method clarification by first concentration, thereby reducing investment of membrane method clarification equipment, reducing production cost and greatly improving economic benefit of sugarcane sugar manufacturing enterprises.)

1. A sugar manufacturing process based on membrane method clarification poly-generation is characterized by comprising the following steps:

A. extracting juice from sugarcane: the sugarcane is squeezed by using a conventional five-seat squeezer, and the obtained brix is 13-15^oA mixed juice of Bx;

B. pre-ashing: adding calcium sucrose into the mixed juice, and adjusting the pH value to 6.8-7.2;

C. physical impurity removal: filtering the mixed juice by a drum sieve, heating a skimming device and a microporous filter in sequence, and physically removing impurities to obtain filtered clear juice;

D. first concentration: concentrating the filtered clear juice by using an MVR concentrator to obtain the juice with the brix of 18-20^oThe concentrated juice of Bx and raw sugarcane water;

E. ceramic membrane filtration: filtering the concentrated juice by using a ceramic membrane with the membrane aperture of 20-100 nm to obtain membrane filtration clear liquid and membrane filtration concentrated liquid with the turbidity of less than 1.00 NTU;

F. and (3) second concentration: concentrating the membrane filtrate by adopting a five-effect concentration tank to obtain a liquid with a brix of 55-65^oBx syrup and raw sugar cane water;

G. filtering with activated carbon: filtering the raw sugarcane water obtained in the step D and the step F by using an activated carbon filter;

H. filtering with a reverse osmosis membrane: further purifying and filtering the sugarcane raw water filtered by the activated carbon by using an organic reverse osmosis membrane with the molecular weight cutoff of 100Da to obtain sugarcane plant water;

I. cooking the methyl sugar: boiling the syrup into a massecuite by a crystallization tank according to a conventional white granulated sugar boiling process, and separating honey to obtain white granulated sugar and first raw honey;

J. boiling ethyl sugar: boiling the raw A honey into the B-glucose paste through a crystallizing tank, separating honey to obtain B-glucose and B-raw honey, and re-dissolving the B-glucose to return to the first-glucose boiling;

K. boiling triose: boiling the raw B honey into triose paste through a crystallizing tank, separating honey to obtain triose and raw C honey, and re-dissolving the triose and returning to the cooking of the methyl sugar;

l, producing low-sucrose liquid sugar: respectively decoloring and filling the first raw honey in the step I, the second raw honey in the step J or the third raw honey in the step K to obtain low-sucrose liquid sugar with different sucrose contents;

m, clarifying membrane filtration concentrated solution: e, centrifuging and clarifying the membrane filtration concentrated solution obtained in the step E through a butterfly centrifuge to obtain a centrifugal clear solution;

n, producing brown sugar: and D, mixing any one of the first raw honey in the step I, the second raw honey in the step J or the third raw honey in the step K with the centrifugal clear liquid in the step M according to the mass ratio of 0.1-0.3: 1, and decocting and pouring according to a brown sugar production process to obtain brown sugar.

2. The sugar making process based on membrane-method clarification poly-generation as claimed in claim 1, wherein the calcium sucrose in step B is prepared by mixing syrup and lime milk in a volume ratio of 6:1, the reaction temperature is 55-58 ℃, and the brix of the syrup is 60-65^oBx, the concentration of lime milk is 12-15^oBé。

3. The sugar manufacturing process based on membrane method clarification poly-generation as claimed in claim 1, wherein the aperture of the roller screen in step C is 2-5 mm, the heating temperature for heating and skimming is 85-95 ℃, and the filtering precision of the microporous filter is 20-50 μm.

4. The sugar manufacturing process based on membrane-method clarification poly-generation of claim 1, wherein the filtering temperature of the ceramic membrane in the step E is 80-90 ℃, the operating pressure is 0.1-0.4 MPa, and the membrane surface flow rate is 3.0-5.0 m/s.

5. The sugar manufacturing process based on membrane method clarification poly-generation as claimed in claim 1, wherein granular husk activated carbon with the particle size of 3-5 mm is filled in the activated carbon filter in the step G.

6. The membrane-method-based clarification poly-generation sugar manufacturing process according to claim 1, wherein the operating pressure of the organic reverse osmosis membrane filtration in the step H is 1.5-4.0 MPa, and the operating temperature is 50-55 ℃.

7. The sugar making process based on membrane process clarification poly-generation as claimed in claim 1, wherein in step L, two stages of ion exchange resin are adopted in series to decolorize molasses, the former stage is acrylic acid series strong-base anion resin, and the latter stage is styrene series strong-base anion resin.

8. The sugar manufacturing process based on membrane method clarification poly-generation as well as the production of sugar is characterized in that the separation factor of the butterfly centrifuge in the step M is 5000-6000.

Technical Field

The invention relates to the technical field of sugar production from sugarcane, in particular to a sugar production process based on membrane method clarification poly-generation.

Background

Sugarcane, (academic name:Saccharumofficinarum) Saccharum officinarum, a large and solid herb growing for many years. The root is strong and developed. The height of the stalk is 3-6 m. The sugarcane is suitable for being planted in places with fertile soil, sufficient sunlight and large temperature difference in winter and summer. Sugar cane is a temperate and tropical crop, a raw material for sucrose production, and ethanol can be extracted as an energy substitute. Sugarcane is an important sugar crop in China, is a main source of sugar, is an important product related to the national civilization, and is not only a food, beverage, medicine and other industriesThe indispensable basic raw materials are the living necessities of urban and rural residents and belong to domestic strategic materials of grains, cotton and oil. The sugarcane is also the economic crop with the largest Guangxi planting area, and according to 2018 data of the State statistics office, the Guangxi sugarcane planting area is 88.64 ten thousand hectares (about 1330 ten thousand mu), which accounts for 63.05 percent of the national planting area; the yield of the sugarcane is 7292.76 ten thousand tons, and accounts for 67.46 percent of the total sugarcane yield in China; the sugar yield is 590 ten thousand tons, which accounts for 67.23 percent of the national sugar yield.

Sugarcane is used as a processing raw material of a large quantity of agricultural products, and the main production processes for preparing sugar from the sugarcane are a sulfurous acid method and a carbonic acid method at present. The sulfurous acid method has short process flow and simple equipment, more than 95 percent of domestic cane sugar factories adopt the process, and a large amount of chemical additives such as lime, phosphoric acid and SO are required to be added in the clarification process₂And polyacrylamide (flocculant) and the like, and pigments and impurities in the mixed juice are removed through flocculation, precipitation and filtration, but the process has the problems of low product quality, high product residual sulfur content, potential safety hazards of sugar and the like. The carbonic acid method has high product quality and low color, but the method has long production flow, large equipment investment and high production cost, and a large amount of lime and CO are required to be added in the clarification process₂And a small amount of SO₂And the problems of large amount of alkaline filter mud, environmental pollution and the like which are difficult to solve exist. The sugar production of the sugarcane mainly takes the production of white granulated sugar, the product is single, and the additional value is low; the molasses which is the by-product is only sold as a raw material for producing alcohol or yeast, and the price is low. How to increase the profit growth point of sugarcane sugar manufacturing enterprises and change the dilemma that the whole industry is in loss in recent years is a main problem which is urgently needed to be solved at present.

The sugarcane contains about 70 percent of water, a large amount of water can be generated in the concentration process of the sugarcane sugar production, the possibility of chemical additive residue exists no matter the sulfurous acid method production process or the carbonic acid method production process is adopted, and the conventional treatment method is to directly discharge the sugarcane into rivers after biochemical treatment reaches the standard. The water is raw water in sugarcane plants, and if the water is fully utilized to be processed into drinking water, the added value of the sugarcane is improved, and the economic benefit of sugar manufacturing enterprises is improved. Estimated to about 8000 ten thousand tons of sugar cane which is a sugar cane material entering in China every year, 4000 ten thousand tons of sugarcane plant water and about 1200 hundred million bottles of plant water can be produced every year, and the yield value is over one billion yuan; the sugarcane water is changed into the drinking water, which changes the situation of water resource shortage in China and creates sustainable contribution for global fresh water resources for newly increasing 4000 ten thousand tons of drinking water every year in China.

The sugar cane contains nutrient substances needed by human body, and the production process of the sulfurous acid method and the carbonic acid method mainly extracts the sugar cane from the sugar cane, and because a large amount of chemical additives are added in the clarification process, and part of the chemical additives which are not completely reacted remain in the final molasses (commonly called waste molasses), the molasses is only used as a raw material for producing alcohol and yeast, and the price of the molasses is very low. The final molasses accounts for about 3% of the processed sugarcane in the traditional sugar making process, the sugar in the molasses mainly comprises sucrose, glucose, fructose and glucan, and trace elements, amino acids and other nutrient substances contained in the sugarcane are mostly remained in the final molasses in the processing process, so that the sugar cannot be effectively utilized.

The brown sugar is sugar cane finished product sugar with honey and high sugar content, the contained sugar is mainly composed of cane sugar, glucose and fructose, the brown sugar does not separate the molasses, most of nutrient substances of the cane are reserved, the sugar cane sugar is easier to digest and absorb by human bodies, and the sugar can quickly supplement physical strength and increase vitality, so the sugar is also called oriental chocolate. The brown sugar also contains various elements which are indispensable to the growth and development of human bodies, such as malic acid, riboflavin, carotene, nicotinic acid, trace elements of manganese, zinc, chromium and the like. At present, sugar production of sugarcane mainly comprises white granulated sugar production, and has single product and low additional value; the molasses which is the by-product is only sold as a raw material for producing alcohol or yeast, and the price is low. How to increase the profit growth point of sugarcane sugar manufacturing enterprises and change the dilemma that the whole industry is in loss in recent years is a main problem which is urgently needed to be solved at present.

If the production mode of singly producing white granulated sugar by sugarcane sugaring at present can be changed to the production mode of diversified and high-valued products, the industrial belt is further widened, the industrial chain is further extended, a new way is sought for the development of the sugarcane industry, the situations of few high-added-value products, weak competitiveness and unstable industrial benefit in the sugarcane industry at present are changed, and the method has great significance for promoting the healthy and stable development of the sugarcane sugaring industry.

Disclosure of Invention

The invention aims to provide a multi-component co-production sugar making process based on membrane method clarification, which adopts a membrane method physical clarification technology, does not add chemical additives such as phosphoric acid, sulfur dioxide, flocculating agent and the like in the clarification process, co-produces series products such as white granulated sugar, brown sugar, low-sucrose liquid sugar, sugarcane plant water and the like, turns the production mode of the current sugarcane sugar single production white granulated sugar into the production mode of diversified and high-valued products, further widens the industrial zone, extends the industrial chain, seeks a new way for the development of the sugarcane industry, changes the situation that the current sugarcane industry has few high-added-value products, low competitiveness and unstable industrial benefit, and has great significance for promoting the healthy and stable development of the sugarcane sugar industry.

The invention is realized by adopting the following technical scheme:

a sugar manufacturing process based on membrane method clarification poly-generation comprises the following steps:

A. extracting juice from sugarcane: the sugarcane is squeezed by using a conventional five-seat squeezer, and the obtained brix is 13-15^oBx.

B. Pre-ashing: adding sucrose calcium into the mixed juice, and adjusting the pH value to 6.8-7.2.

C. Physical impurity removal: and (3) filtering the mixed juice through a drum screen, heating a skimming device and a microporous filter in sequence, and physically removing impurities to obtain filtered clear juice.

D. First concentration: concentrating the filtered clear juice by using an MVR concentrator to obtain the juice with the brix of 18-20^oBx concentrated juice and raw sugarcane water.

E. Ceramic membrane filtration: and filtering the concentrated juice by using a ceramic membrane with the membrane aperture of 20-100 nm to obtain membrane filtration clear liquid and membrane filtration concentrated liquid with the turbidity of less than 1.00 NTU.

F. And (3) second concentration: concentrating the membrane filtrate by adopting a five-effect concentration tank to obtain a liquid with a brix of 55-65^oBx syrup and raw sugar cane water.

G. Filtering with activated carbon: and D, filtering the raw sugarcane water obtained in the step D and the step F by using an activated carbon filter.

H. Filtering with a reverse osmosis membrane: and further purifying and filtering the sugarcane raw water filtered by the activated carbon by using an organic reverse osmosis membrane with the molecular weight cutoff of 100Da to obtain sugarcane plant water.

I. Cooking the methyl sugar: and (3) boiling the syrup into a massecuite by a crystallization tank according to a conventional white granulated sugar boiling process, and separating honey to obtain the white granulated sugar and the first raw honey.

J. Boiling ethyl sugar: boiling the raw Mel A into Mel B paste, separating Mel to obtain Mel B and raw Mel B, and re-dissolving the Mel B and returning to the first step for boiling.

K. Boiling triose: and (3) boiling the raw B honey into triose paste through a crystallizing tank, separating honey to obtain triose and raw C honey, and re-dissolving the triose and returning to the boiling of the methyl sugar.

L, producing low-sucrose liquid sugar: and (4) decoloring and filling the first raw honey obtained in the step (I), the second raw honey obtained in the step (J) or the third raw honey obtained in the step (K) respectively to obtain the low-sucrose liquid sugar with different sucrose contents.

M, clarifying membrane filtration concentrated solution: and E, centrifuging and clarifying the membrane filtration concentrated solution obtained in the step E through a butterfly centrifuge to obtain a centrifugal clear solution.

N, producing brown sugar: and D, mixing any one of the first raw honey in the step I, the second raw honey in the step J or the third raw honey in the step K with the centrifugal clear liquid in the step M according to the mass ratio of 0.1-0.3: 1, and decocting and pouring according to a brown sugar production process to obtain brown sugar.

Further preferred is: the calcium sucrose in the step B is prepared by mixing syrup and lime milk according to the volume ratio of 6:1, the reaction temperature is 55-58 ℃, and the brix of the syrup is 60-65^oBx, the concentration of lime milk is 12-15^oBé。

Further preferred is: and C, the aperture of the filter screen of the drum screen in the step C is 2-5 mm, the heating temperature of heating skimming is 85-95 ℃, and the filtering precision of the microporous filter is 20-50 mu m.

Further preferred is: and E, filtering the ceramic membrane at the temperature of 80-90 ℃, operating pressure of 0.1-0.4 MPa, and membrane surface flow rate of 3.0-5.0 m/s.

Further preferred is: and G, filling granular shell activated carbon into the activated carbon filter, wherein the grain size is 3-5 mm.

Further preferred is: and H, filtering the organic reverse osmosis membrane at the operating pressure of 1.5-4.0 MPa and the operating temperature of 50-55 ℃.

Further preferred is: in the step L, two stages of ion exchange resins are adopted for tandem connection to decolor the molasses, wherein the former stage is acrylic acid series strong-base anion resin, and the latter stage is styrene series strong-base anion resin.

Further preferred is: and the separation factor of the butterfly centrifuge in the step M is 5000-6000.

Compared with the prior art, the invention has the following beneficial effects:

(1) the sugarcane mixed juice is subjected to physical impurity removal, and then is concentrated for the first time to extract sugarcane plant water, so that the treatment capacity of subsequent membrane method physical clarification is reduced, the investment of membrane method clarification equipment can be reduced, and the production cost is reduced.

(2) The ceramic membrane physical clarification process is adopted in the sugar preparation clarification process, chemical additives such as phosphoric acid, sulfur dioxide and flocculating agent are not added in the process, the possibility of chemical additive residue in the produced white granulated sugar and the byproduct molasses is avoided, the green safety of the product is ensured, and the additional value of the white granulated sugar and the molasses is improved.

(3) Due to the adoption of a physical clarification process, most of nutrient substances such as trace elements, glucose, fructose, glucan, amino acids, polyphenol and the like contained in the sugarcane are not removed in the clarification process, but are retained in the molasses, so that the sugar cane sugar has high nutritional value, can be used as a liquid sugar product with low sucrose content and is sold to a high-end market.

(4) The concentrated solution filtered by the ceramic membrane is subjected to centrifugal clarification and then is mixed with part of molasses to produce brown sugar, so that the problem of treatment of the concentrated solution filtered by the membrane is solved, and most of nutrient substances in the sugarcane juice are concentrated in the molasses in the production process of the white granulated sugar.

(5) The sugarcane plant water is extracted by adopting a physical clarification process, the possibility of chemical additive residue is avoided, the water has the unique flavor of sugarcane, the inlet is smooth, and the quality is high.

(6) The sugarcane plant water is produced by using the raw sugarcane water obtained in the sugar production concentration process, and the extraction efficiency is high, the production cost is low, and the equipment investment is low.

(7) The sugarcane plant water is produced, the original sugarcane water which is discharged after biochemical treatment is changed into high-added-value domestic drinking water, so that the economic benefit of sugar manufacturing enterprises is improved, the discharge amount of water can be reduced, the environmental protection pressure is relieved, and the resource utilization of the water in the sugarcane is realized.

(8) The produced sugarcane plant water is derived from plant cells, has the quality superior to various bottled drinking water derived from underground water sources or surface water sources in the current market, is more suitable for high-end markets, and has extremely high market development potential.

(9) Based on a membrane method clarification technology, series products such as white granulated sugar, brown sugar, low-sucrose liquid sugar, sugarcane plant water and the like are co-produced, the production mode of singly producing white granulated sugar by sugarcane sugaring at present is changed to the production mode of diversified and high-valued products, the industrial zone is further widened, the industrial chain is extended, a new way is developed for the development of the sugarcane industry, the situations of few high-added-value products, low competitiveness and unstable industrial benefit of the sugarcane industry at present are changed, and the method has great significance for promoting the healthy and stable development of the sugarcane sugaring industry.

Drawings

FIG. 1 is a process flow diagram of a sugar manufacturing process based on membrane process clarification poly-generation in example 1;

FIG. 2 is a process flow diagram of a sugar manufacturing process based on membrane process clarification poly-generation in example 2;

FIG. 3 is a process flow diagram of a sugar manufacturing process based on membrane process clarification poly-generation in example 3;

after physical impurity removal, the mixed juice is firstly concentrated for the first time to produce sugarcane plant water, and after physical filtration of the concentrated mixed juice by a ceramic membrane, the concentrated mixed juice is concentrated for the second time to produce white granulated sugar, brown sugar, low-sucrose liquid sugar and sugarcane plant water; according to the market and development requirements of low-sucrose liquid sugar products, white granulated sugar can be produced by adopting any one of three sugar boiling systems of 'cooking with methyl sugar', 'cooking with methyl sugar and cooking with ethyl sugar' or 'cooking with methyl sugar, cooking with ethyl sugar and cooking with propyl sugar', so that white granulated sugar with different yields and molasses with different sucrose contents can be obtained.

Detailed Description

The technical solution of the present invention is described clearly and completely with reference to the following embodiments, which are only a part of the present invention, but not all of the embodiments.

Example 1

A sugar production process based on membrane method clarification poly-generation comprises the following steps:

A. extracting juice from sugarcane: the sugarcane is squeezed by adopting a conventional five-seat squeezer, and the obtained brix is 13-15^oA mixed juice of Bx;

B. pre-ashing: adding sucrose calcium into the mixed juice, and adjusting the pH value to 6.8-7.2.

C. Physical impurity removal: and (3) physically removing impurities of the pre-ashed mixed juice through a drum screen, a heating and foam skimming device and a microporous filter in sequence to obtain filtered clear juice.

D. First concentration: concentrating the filtered clear juice by using an MVR concentrator to obtain the juice with the brix of 18-20^oBx concentrated juice and raw sugarcane water.

E. Ceramic membrane filtration: filtering the concentrated juice with ceramic membrane with membrane pore diameter of 20nm to obtain membrane filtrate solution and membrane filtrate concentrated solution with turbidity less than 1.00 NTU.

F. And (3) second concentration: concentrating the membrane filtrate by adopting a five-effect concentrator to obtain a liquid with a brix of 55-65^oBx syrup and raw sugar cane water.

G. Filtering with activated carbon: and filtering the sugarcane raw water obtained by the first concentration and the second concentration by using an activated carbon filter.

H. Filtering with a reverse osmosis membrane: and (3) further purifying and filtering the sugarcane raw water filtered by the activated carbon by using an organic reverse osmosis membrane with the molecular weight cutoff of 100Da, and aseptically filling to obtain the sugarcane plant water.

I. Cooking the methyl sugar: and (3) boiling the syrup into a massecuite by a crystallization tank according to a conventional white granulated sugar boiling process, and separating honey to obtain the white granulated sugar and the first raw honey.

J. Production of low sucrose liquid sugar: the raw first honey is decolorized and filled to obtain the low-sucrose liquid sugar with higher sucrose content.

K. Clarifying membrane filtration concentrated solution: and E, centrifuging and clarifying the membrane filtration concentrated solution obtained in the step E through a butterfly centrifuge to obtain a centrifugal clear solution.

L, producing brown sugar: and (3) mixing the raw first honey obtained in the step I and the centrifugal clear liquid obtained in the step K according to a mass ratio of 0.3:1, mixing, decocting and pouring according to a brown sugar production process to obtain the brown sugar.

In the step B, the sucrose calcium is prepared from syrup and lime milk according to the ratio of 6:1, the reaction temperature is 55-58 ℃, and the brix of the syrup is 60-65^oBx, the concentration of lime milk is 12-15^oBé。

In the step C, the aperture of the filter screen of the roller screen is 2mm, the heating temperature for heating and skimming is 85-88 ℃, and the filtering precision of the microporous filter is 20 microns.

In the step F, the filtering temperature of the ceramic membrane is 80-90 ℃, the operating pressure is 0.1-0.4 MPa, and the membrane surface flow rate is 3.0-5.0 m/s.

And in the step H, granular shell activated carbon is filled in the activated carbon filter, and the grain size is 3-5 mm.

In the step I, the operating pressure of the organic reverse osmosis membrane is 1.5-4.0 MPa, and the operating temperature is 50-55 ℃.

In step L, the separation factor of the butterfly centrifuge is 5000. A butterfly centrifuge manufactured by Liaoyang Zhonglian pharmaceutical machinery, Inc. is adopted, the model is DRY530, and the rotating speed is 4150 r/min.

And step J, two stages of ion exchange resins are adopted for carrying out series connection to carry out decoloration on the raw methyl, the former stage is acrylic acid series strong-base anion resin, and the latter stage is styrene series strong-base anion resin.

In this embodiment, a "methyl sugar cooking" sugar cooking system is used to produce white granulated sugar, and a lower yield of white granulated sugar and molasses with higher sucrose content is obtained.

Example 2

A sugar making process for clarifying and co-producing sugarcane plant water based on a membrane method comprises the following steps:

A. extracting juice from sugarcane: the sugarcane is squeezed by adopting a conventional five-seat squeezer, and the obtained brix is 13-15^oBx.

B. Pre-ashing: adding sucrose calcium into the mixed juice, and adjusting the pH value to 6.8-7.2.

C. Physical impurity removal: and (3) physically removing impurities of the pre-ashed mixed juice through a drum screen, a heating and foam skimming device and a microporous filter in sequence to obtain filtered clear juice.

D. First concentration: concentrating the filtered clear juice by using an MVR concentrator to obtain the juice with the brix of 18-20^oBx concentrated juice and raw sugarcane water.

E. Ceramic membrane filtration: filtering the concentrated juice by using a ceramic membrane with the membrane aperture of 50nm to obtain membrane filtrate liquid and membrane filtrate concentrated solution with the turbidity of less than 1.00 NTU;

F. and (3) second concentration: concentrating the membrane filtrate by adopting a five-effect concentrator to obtain a liquid with a brix of 55-65^oBx syrup and raw sugar cane water.

G. Filtering with activated carbon: and filtering the sugarcane raw water obtained by the first concentration and the second concentration by using an activated carbon filter.

H. Filtering with a reverse osmosis membrane: and (3) further purifying and filtering the sugarcane raw water filtered by the activated carbon by using an organic reverse osmosis membrane with the molecular weight cutoff of 100Da, and aseptically filling to obtain the sugarcane plant water.

I. Cooking the methyl sugar: and (3) boiling the syrup into a massecuite by a crystallization tank according to a conventional white granulated sugar boiling process, and separating honey to obtain the white granulated sugar and the first raw honey.

J. Boiling ethyl sugar: boiling the raw Mel A into Mel B paste, separating Mel to obtain Mel B and raw Mel B, and re-dissolving the Mel B and returning to the first step for boiling.

K. Production of low sucrose liquid sugar: and D, decoloring and filling the ethyl raw honey obtained in the step J to obtain the low-sucrose liquid sugar with low sucrose content.

L, clarifying membrane filtration concentrated solution: and E, centrifuging and clarifying the membrane filtration concentrated solution obtained in the step E through a butterfly centrifuge to obtain a centrifugal clear solution.

M, brown sugar production: and D, mixing the ethyl raw honey obtained in the step J with the centrifugal clear liquid obtained in the step M according to a mass ratio of 0.2: 1, mixing, decocting and pouring according to a brown sugar production process to obtain the brown sugar.

In the step B, the sucrose calcium is prepared from syrup and lime milk according to the ratio of 6:1, the reaction temperature is 55-58 ℃, and the brix of the syrup is 60-65^oBx, the concentration of lime milk is 12-15^oBé。

In the step C, the aperture of the filter screen of the roller screen is 3mm, the heating temperature for heating and skimming is 85-95 ℃, and the filtering precision of the microporous filter is 30 microns.

In the step E, the filtering temperature of the ceramic membrane is 80-90 ℃, the operating pressure is 0.1-0.4 MPa, and the membrane surface flow rate is 3.0-5.0 m/s;

and G, filling granular shell activated carbon into the activated carbon filter, wherein the grain size is 3-5 mm.

In the step H, the operation pressure of the organic reverse osmosis membrane filtration is 1.5-4.0 MPa, and the operation temperature is 50-55 ℃.

In the step K, two stages of ion exchange resins are adopted for series connection to decolor the molasses, wherein the former stage is acrylic acid series strong-base anion resin, and the latter stage is styrene series strong-base anion resin.

In step L, the separation factor of the butterfly centrifuge is 5100. A butterfly centrifuge manufactured by Liaoyang Zhonglian pharmaceutical machinery, Inc. is adopted, the model is DRY500, and the rotating speed is 4170 r/min.

In the embodiment, a sugar boiling system of 'boiling with methyl sugar and boiling with ethyl sugar' is adopted to produce white granulated sugar, so that high-yield white granulated sugar and molasses with low sucrose content are obtained.

Example 3

A sugar making process for clarifying and co-producing sugarcane plant water based on a membrane method comprises the following steps:

A. extracting juice from sugarcane: the sugarcane is squeezed by adopting a conventional five-seat squeezer, and the obtained brix is 13-15^oBx.

B. Pre-ashing: adding sucrose calcium into the mixed juice, and adjusting the pH value to 6.8-7.2.

C. Pretreatment: and (3) physically removing impurities of the pre-ashed mixed juice through a drum screen, a heating and foam skimming device and a microporous filter in sequence to obtain filtered clear juice.

D. First concentration: concentrating the filtered clear juice by using an MVR concentrator to obtain the juice with the brix of 18-20^oBx concentrated juice and raw sugarcane water.

E. Ceramic membrane filtration: filtering the concentrated juice with ceramic membrane with membrane pore diameter of 100nm to obtain membrane filtrate solution and membrane filtrate concentrated solution with turbidity less than 1.00 NTU.

F. And (3) second concentration: concentrating the membrane filtrate by adopting a five-effect concentrator to obtain a liquid with a brix of 55-65^oBx syrup and raw sugar cane water.

G. Filtering with activated carbon: and filtering the sugarcane raw water obtained by the first concentration and the second concentration by using an activated carbon filter.

H. Filtering with a reverse osmosis membrane: and (3) further purifying and filtering the sugarcane raw water filtered by the activated carbon by using an organic reverse osmosis membrane with the molecular weight cutoff of 100Da, and aseptically filling to obtain the sugarcane plant water.

I. Cooking the methyl sugar: and (3) boiling the syrup into a massecuite by a crystallization tank according to a conventional white granulated sugar boiling process, and separating honey to obtain the white granulated sugar and the first raw honey.

J. Boiling ethyl sugar: boiling the raw Mel A into Mel B paste, separating Mel to obtain Mel B and raw Mel B, and re-dissolving the Mel B and returning to the first step for boiling.

K. Boiling triose: and (3) boiling the raw B honey into triose paste through a crystallizing tank, separating honey to obtain triose and raw C honey, and re-dissolving the triose and returning to the boiling of the methyl sugar.

L, producing low-sucrose liquid sugar: and D, decoloring and filling the raw honey obtained in the step K to obtain the low-sucrose liquid sugar with low sucrose content.

M, clarifying membrane filtration concentrated solution: and E, centrifuging and clarifying the membrane filtration concentrated solution obtained in the step E through a butterfly centrifuge to obtain a centrifugal clear solution.

N, producing brown sugar: and D, mixing the raw honey obtained in the step K with the centrifugal clear liquid obtained in the step M according to the mass ratio of 0.1:1, and decocting and pouring according to a brown sugar production process to obtain brown sugar.

In the step B, the sucrose calcium is prepared from syrup and lime milk according to the ratio of 6:1, the reaction temperature is 55-58 ℃, and the brix of the syrup is 60-65^oBx, the concentration of lime milk is 12-15^oBé。

In the step C, the aperture of the filter screen of the roller screen is 4mm, the heating temperature for heating and skimming is 85-95 ℃, and the filtering precision of the microporous filter is 40 mu m.

In the step E, the filtering temperature of the ceramic membrane is 80-90 ℃, the operating pressure is 0.1-0.4 MPa, and the membrane surface flow rate is 3.0-5.0 m/s.

And G, filling granular shell activated carbon into the activated carbon filter, wherein the grain size is 3-5 mm.

In the step H, the operation pressure of the organic reverse osmosis membrane filtration is 1.5-4.0 MPa, and the operation temperature is 50-55 ℃.

In the step L, two stages of ion exchange resins are adopted for tandem connection to decolor the molasses, wherein the former stage is acrylic acid series strong-base anion resin, and the latter stage is styrene series strong-base anion resin.

In step M, the separation factor of the butterfly centrifuge is 5500. A butterfly centrifuge manufactured by Liaoyang Zhonglian pharmaceutical machinery Limited company is adopted, the model is DHC500, and the rotating speed is 4450 r/min.

In this embodiment, a sugar boiling system of "cooking methyl sugar, cooking ethyl sugar and cooking propyl sugar" is adopted to produce white granulated sugar, so as to obtain the highest yield of white granulated sugar and molasses with very low sucrose content.

Comparative example

At present, most of sugar cane sugar factories in China adopt a sulfurous acid method sugar making process, the clarification process mainly comprises the steps of adding chemical additives such as lime, phosphoric acid, sulfur dioxide, flocculating agent and the like to remove impurities and pigments in sugar cane mixed juice and producing white granulated sugar meeting the national standard, and the method comprises the following specific steps:

A. extracting juice from sugarcane: the sugarcane is squeezed by adopting a conventional five-seat squeezer,the obtained hammering degree is 13-15^oBx.

B. Pretreatment: and filtering the mixed juice through a drum sieve and a curved sieve in sequence to remove large granular fibers and impurities.

C. Pre-ashing: adding phosphoric acid into the mixed juice, and then adding lime milk to adjust the pH value to 6.8-7.2.

D. Heating for the first time: and heating the pre-ashed mixed juice to 60-70 ℃.

E. And (3) stoving neutralization: and (3) adding sulfur dioxide into the once-heated mixed juice through a sulfitation neutralizer, and then adding lime milk to adjust the pH value to 6.8-7.3 to obtain the neutralized juice.

F. And (3) heating for the second time: heating the neutralized juice to 100-105 ℃.

G. And (3) settling: and adding a flocculating agent into the heated neutralized juice, and introducing into a settler for sedimentation separation to obtain clarified clear juice.

H. Concentration: concentrating the clear juice through a five-effect concentration tank to obtain the juice with the brix of 55-65^oBx syrup.

I. Cooking the methyl sugar: and (3) boiling the syrup into a first syrup by a crystallizing tank according to a three-section sugar boiling system in the conventional white sugar boiling process, and separating honey to obtain the white sugar and first raw honey.

J. Boiling ethyl sugar: boiling the raw Mel A into Mel B paste, separating Mel to obtain Mel B and raw Mel B, and re-dissolving the Mel B and returning to the first step for boiling.

K. Boiling triose: and (3) boiling the raw ethyl honey into the triose paste through a crystallizing tank, separating honey to obtain triose and raw propyl honey, redissolving the triose, returning the triose to the boiling of the methyl sugar, and taking the raw propyl honey as the final molasses.

And step B, the aperture of the filter screen of the roller screen is 2-5 mm, and the filter screen of the curved screen is 20-80 meshes.

And C, adding the phosphoric acid in the step C in an amount of 300-350 ppm of the effective P2O5 to sugarcane ratio, wherein the folded phosphoric acid to sugarcane ratio is 0.05-0.06%.

And E, converting the addition amount of the sulfur dioxide into a sulfur-to-sugarcane ratio of 0.12-0.14%.

And D, the adding amount of the lime milk in the step C and the step E is converted into that the ratio of lime to sugarcane is 0.2% -0.3%.

And G, the addition amount of the flocculating agent to the sugarcane ratio is 3-5 ppm.

And D, the final molasses obtained in the step K is only used as a raw material for producing products such as alcohol, yeast and the like, and the price is very low.

The comparative example adopts a sugar boiling system of 'boiling of methyl sugar, boiling of ethyl sugar and boiling of propyl sugar' to produce white granulated sugar, and the molasses with the highest yield and very low content of white granulated sugar and cane sugar is obtained.

Table 1 shows the results of testing the indexes of the juice process in examples 1, 2, 3 and comparative examples.

Table 2 shows the results of the physical and chemical index tests of the white granulated sugar of examples 1, 2, 3 and comparative examples.

Table 3 shows the results of measuring the sulfur dioxide content of white granulated sugar in examples 1, 2, 3 and comparative examples.

Table 4 shows sensory index detection results of the sugarcane vegetation waters of example 1, example 2, and example 3.

Table 5 shows the results of the physicochemical indices of the sugarcane vegetation waters of examples 1, 2, and 3.

The above description is not intended to limit the present invention, and the present invention is not limited to the above examples, and those skilled in the art should understand that they can make various changes, modifications, additions and substitutions within the spirit and scope of the present invention.