阅读说明：本技术 用于金属热成形的润滑剂 (Lubricant for metal hot forming ) 是由 S·布戈纳 D·马苏拉特 C·朗吉士 M·玛贡 N·魏尔 于 2020-02-21 设计创作，主要内容包括：一种用于金属热成形、特别是用于在无缝管生产中润滑芯棒和/或空心块的润滑剂,其特征在于,相对于固体组分,润滑剂至少含有以下组分：-55-85重量％固体润滑剂,其包含滑石与钾云母的混合物,其中,固体润滑剂中滑石与钾云母的比例为2.0-5.0,-10-30重量％粘合剂,其选自聚乙酸乙烯酯、钠水玻璃和糊精或其混合物,-2-10重量％增稠剂,其选自羟基纤维素、羟乙基纤维素、羟丙基纤维素、羧甲基纤维素、甲基纤维素、乙基纤维素、甲基乙基纤维素、羟乙基甲基纤维素、羟丙基甲基纤维素、乙基羟甲基纤维素、羧甲基羟基纤维素、糊精、淀粉、有机改性膨润土、蒙皂石和黄原胶,-0-10重量％其它助剂,优选选自消泡剂、分散剂和杀生物剂,和-不超过10重量％石墨,优选不超过5重量％石墨,特别优选不含石墨。(Lubricant for hot forming of metals, in particular for lubricating core rods and/or hollow blocks in the production of seamless tubes, characterized in that it contains at least the following components, with respect to the solid components: -55-85 wt% of a solid lubricant comprising a mixture of talc and potassium mica, wherein the ratio of talc to potassium mica in the solid lubricant is 2.0-5.0, -10-30 wt% of a binder selected from polyvinyl acetate, sodium water glass and dextrin or mixtures thereof, -2-10 wt% of a thickener selected from hydroxy cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl cellulose, methyl cellulose, ethyl cellulose, methyl ethyl cellulose, hydroxyethyl methyl cellulose, hydroxypropyl methyl cellulose, ethyl hydroxymethyl cellulose, carboxymethyl hydroxy cellulose, dextrin, starch, organically modified bentonite, smectite and xanthan gum, -0-10 wt% of other auxiliaries, preferably selected from defoamers, dispersants and biocides, and-not more than 10 wt% of graphite, preferably not more than 5% by weight of graphite, particularly preferably free of graphite.)

1. Lubricant for hot forming of metals, in particular for lubricating core rods and/or hollow blocks in the production of seamless tubes, characterized in that it contains at least the following components, with respect to the solid components:

55 to 85% by weight of a solid lubricant comprising a mixture of talc and potassic mica, wherein the ratio of talc to potassic mica in the solid lubricant is from 2.0 to 5.0,

10-30% by weight of a binder selected from polyvinyl acetate, sodium water glass and dextrin or mixtures thereof,

-from 2 to 10% by weight of a thickener selected from the group consisting of hydroxycellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose, methylcellulose, ethylcellulose, methylethylcellulose, hydroxyethylmethylcellulose, hydroxypropylmethylcellulose, ethylhydroxymethylcellulose, carboxymethylhydroxycellulose, dextrin, starch, organically modified bentonite, smectite and xanthan gum,

0 to 10% by weight of other auxiliaries, preferably selected from defoamers, dispersants and biocides, and

not more than 10% by weight of graphite, preferably not more than 5% by weight of graphite, particularly preferably free of graphite.

2. The lubricant according to claim 1, wherein the ratio of talc to potassic mica in the solid lubricant is from 2.5 to 4.5, preferably from 3.0 to 4.0, particularly preferably from 3.3 to 3.8.

3. The lubricant of any of claims 1 and 2, wherein the potassium mica is selected from the group consisting of phlogopite, muscovite, and mixtures of the two.

4. The lubricant according to any of claims 1 to 3, wherein the potassium mica contains at least 60% by weight phlogopite, preferably at least 80% by weight phlogopite, particularly preferably at least 90% by weight phlogopite, more particularly preferably 100% by weight phlogopite.

5. The lubricant according to any of claims 1 to 4, characterized in that the lubricant is an aqueous suspension having 10 to 45% by weight of solid constituents, preferably 15 to 35% by weight of solid constituents, particularly preferably 20 to 30% by weight of solid constituents.

6. The lubricant according to any of claims 1 to 5, wherein the binder is or comprises ethylene vinyl acetate copolymer EVA.

7. The lubricant according to any of claims 1 to 6, wherein the thickener is or comprises xanthan gum.

8. The lubricant according to any of claims 1 to 7, characterized in that the rest of the lubricant contains further auxiliaries, preferably selected from defoamers, dispersants and biocides.

9. The lubricant according to any of claims 1 to 8, characterized in that the lubricant contains 0 to 5 wt.% of a boron-containing compound, preferably 0 to 2.5 wt.% of a boron-containing compound, particularly preferably 0 to 1 wt.% of a boron-containing compound, more particularly preferably no boron-containing compound.

10. Use of a lubricant composition according to any one of claims 1 to 9 for lubricating core rods and/or hollow blocks in the production of seamless tubes by metal hot forming, preferably in a continuous or pipe-jacking process (Sto β bankprozens).

11. Use according to claim 10, wherein the lubricant is in the form of an aqueous suspension in the range of 30 to 150g/m²The amount of surface area is sprayed onto the core rod and/or the hollow block, preferably in an amount of 50 to 120g/m²The surface area of the spray is particularly preferably from 70 to 100g/m²The amount of sprayed surface area is more particularly preferably about 80g/m²The surface area is sprayed.

Technical Field

The invention relates to a substantially graphite-free and boron-free core rod lubricant for use in metal hot forming in the production of seamless tubes, in particular in the so-called continuous or pipe-jacking process (Sto β bankprozens).

Background

In the hot forming process of metals, such as sheet or hollow blocks, it is necessary to use lubricants in the rolling or stamping device, which ensure an optimum sliding movement of the metal between the working tools at higher working temperatures. Temperatures of 1100 ℃ and 1300 ℃ may occur when producing profiled sheets or seamless tubes in a rolling apparatus. When working hard or difficult to form metals, rapid wear of the working tools may result. Furthermore, high friction values between the tool and the workpiece lead to increased energy consumption during machining.

In modern tube mills, in particular in so-called continuous processes with a plurality of driven and individually controlled rolling stands, the shaping of seamless tubes is effected in the main process step by rolling a hollow preform block with a mandrel at about 1200-1300 ℃. After the rolling operation, the mandrel bar is removed from the rolled shell and cooled in a cooling tank or sprayed with water in preparation for the next rolling operation. The preparation of the cooled core rod also includes lubrication, where the lubricant is sprayed on the core rod.

This lubrication is necessary for an optimal sliding movement of the hollow block on the mandrel during the rolling operation and also plays a decisive role for the later quality and dimensional accuracy of the tube, in particular for the inner surface properties of the tube.

The core rod lubricant used must have good lubricating properties while also being able to withstand high processing temperatures. Good lubricating properties include not only that the lubricant is suitable for reducing the friction values between the core rods, but also good wetting properties and the creation of a lubricant film on the core rods which is as continuous as possible and of sufficient layer thickness.

In some cases, the lubricants contain additives which also reduce the formation of scale on the surface of the material being worked, for example boron compounds, such as borates, which, because of their water solubility, can enter the waste water of the rolling operation and, because of their teratogenic action, lead to serious aftertreatment problems.

Known lubricants can be subdivided into graphite-containing lubricants and graphite-free lubricants. Graphite-free lubricants are also referred to as "white" lubricants because they are not colored by the intense inherent color of graphite.

Graphite is a suitable lubricant additive that is precisely targeted for high temperature applications, such as metal thermoforming, because graphite is particularly heat resistant, and has particularly good lubricating properties both by itself and in combination with mineral oils and inorganic salts. One disadvantage of graphite lubricants is that carburization of the metal surface of the workpiece occurs due to the high proportion of carbon. In this case, inferior end products with poor material properties and poor subsequent processability may occur. The result is a high workpiece rejection rate. Furthermore, the use of graphite in a working environment is subject to health problems, which makes it necessary to provide particularly complex and expensive protective measures for persons working in the working environment.

A group of lubricants, which may or may not contain graphite, contains a salt or a mixture of salts which melts on the hot surface of the workpiece and forms a lubricating separation layer between the workpiece and the tool by the melt. However, only certain salts are suitable for this purpose, some of which have so high a melting temperature that the lubricant is fully functional only when the working temperature is reached. This is particularly disadvantageous when starting up the processing machine, since the tool or the workpiece is still cold. In certain lubricants, borax is used as the low melting point salt. In addition to the above-mentioned disadvantages of water-soluble boron compounds, when borax lubricants are used, the work pieces and tools can also stick together, leading to tool damage or machine downtime. In addition, borax-containing lubricants can have a detrimental erosive effect on the metal surfaces of tools or workpieces.

In addition, known lubricants use harsh conventional salts which can cause material ablation and material deposition in another location with respect to the workpiece, resulting in scratches. In addition, conventional salts increase corrosion of the metal on the apparatus, resulting in high maintenance costs. Even water-soluble lubricants based on alkali metal phosphates and alkali metal borates, which are used in combination with various metal oxides such as zinc oxide or iron oxide, corrode the surface of the material to be processed.

Another group of high temperature lubricants contains alkali phosphate or silicate glasses with various additives such as boron or aluminum. These lubricants have good lubricating properties but are poorly water soluble, which makes their removal from the work piece quite difficult and requires a high level of technical implementation.

Particularly, in the continuous process for producing seamless tubes, a mandrel bar lubricant having a high graphite ratio is still the mainstream because of high requirements for lubricity and heat resistance. In this case, graphite-free or low graphite ("white") core rod lubricants are scarcely used, despite the above-mentioned disadvantages and others. Lubricants suitable for this purpose are expensive and require a large amount of use, which has a negative effect on the manufacturing and product costs.

CN-A-104694240 discloses A graphite-free lubricant composition containing 10-90 wt% mineral clay, 0-5 wt% stearate, 0.1-5 wt% thickener, preferably sodium polyacrylate, 5-30 wt% water-soluble borate and/or boric acid and other additives such as surface active substances and polymers.

CN-A-102732367 discloses A graphite-free lubricant composition containing 15-20 wt.% of glass powder, 2.5-8 wt.% of white solid lubricant, 0.5-3.5 wt.% of thickener and other additives such as surface active substances and resins. The white solid lubricant comprises one or more compounds of mica, talc and boron nitride. Gelatin or cellulose are used as thickeners.

The known lubricants for hot forming of metals therefore have, owing to their respective composition, a series of disadvantages, such as health and environmental hazards and the necessary protective measures associated therewith, high consumption due to the high required use, high costs of the components of the composition, harmful friction values, adverse effects on the working process and/or on the properties of the manufactured products, such as bonding or welding of tools and workpieces, carburization or other forms of damage of the workpiece surfaces, unfavorable wetting properties and/or unfavorable layer thicknesses.

Disclosure of Invention

It is therefore an object of the present invention to provide a mandrel lubricant which overcomes the disadvantages of the prior art, which is particularly suitable for use as a lubricant for metal hot forming in the manufacture of seamless tubes in a continuous or pipe-jacking process, which contains no or at most very small amounts of graphite, has good friction values and good wetting properties, compared to graphite-containing lubricants used hitherto in these processes, and which requires lower amounts of lubricant to be used and/or can be produced at lower costs, compared to known lubricants in the same application.

Detailed Description

This object is achieved by a lubricant for hot metal forming, in particular for lubricating a mandrel bar and/or a hollow block in the production of seamless tubes, wherein the lubricant comprises at least the following components, relative to the solid components:

55 to 85% by weight of a solid lubricant comprising a mixture of talc and potassic mica, preferably phlogopite, muscovite or a mixture of both, wherein the ratio of talc to potassic mica in the solid lubricant is 2.0 to 5.0,

10-30% by weight of a binder selected from polyvinyl acetate, sodium water glass and dextrin or mixtures thereof, preferably ethylene vinyl acetate copolymer (EVA),

-from 2 to 10% by weight of a thickener selected from the group consisting of hydroxycellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose, methylcellulose, ethylcellulose, methylethylcellulose, hydroxyethylmethylcellulose, hydroxypropylmethylcellulose, ethylhydroxymethylcellulose, carboxymethylhydroxycellulose, dextrin, starch, organically modified bentonite, smectite and xanthan gum, preferably xanthan gum,

0 to 10% by weight of other auxiliaries, preferably selected from defoamers, dispersants and biocides, and

not more than 10% by weight of graphite, preferably not more than 5% by weight of graphite, particularly preferably free of graphite.

An essential advantage of the lubricant according to the invention is that it has very good friction values and wetting properties, especially when producing seamless pipes in a continuous or pipe-jacking process, which are comparable or even better than the graphite-containing lubricants currently used in these processes, at the same or smaller layer thicknesses or usage. The lubricant according to the invention can thus replace graphite-containing lubricants used hitherto in continuous processes or pipe-jacking processes, while saving costs, post-treatment costs and expenditure on work-safeguards. Preferably, the lubricants of the present invention contain no more than 5% by weight of boron-containing compounds, particularly preferably no boron-containing compounds, such as boric acid, borax, borates or borate-containing minerals, which are commonly used in known metal thermoforming lubricants. Thus, the lubricant of the present invention can overcome the disadvantages of graphite-containing lubricants and boron-containing lubricants.

Applications of

In the production of seamless tubes using a continuous process or a pipe-jacking process, the lubricant is sprayed in the form of an aqueous suspension onto the cooled mandrel bar in preparation for the next rolling step, in which case, however, the mandrel bar is still at a temperature of the order of magnitude of about 100 ℃. In this case, a basic idea is that the good lubricating properties of the lubricant are a completely continuous wetting of the core rod, in particular the thickness of the lubricant layer on the wetted core rod. The inventive lubricant is characterized by good adhesion to the core rod and good uniform wetting of the core rod surface. At the same time, the amount of lubricant used or layer thickness required to achieve good lubrication in these processes is equal to or even less than the graphite-containing lubricants currently used in these processes.

When describing the layer thickness or amount of lubricant used herein, this means the amount of lubricant solids on a given surface area of the tool, i.e. mandrel, in grams of lubricant solids per square meter [ g/m ]²]To represent the table. Suitable layer thicknesses for the lubricants according to the invention are in the order of about 30 to 150g/m²Surface area of the core rod, preferably 50 to 120g/m²Particularly preferably 70 to 100g/m²Depending on the respective composition of the lubricant.

The wettability and layer thickness of the core rod surface can be set by the amount or duration of the lubricant suspension sprayed onto the core rod surface and the viscosity and adhesion of the suspension. It has been found that the lubricants according to the invention can still achieve the same or better lubricating effect at the same or even smaller layer thicknesses or amounts used than commercially customary graphite-containing lubricants for the same purpose of use. Thereby, it can save considerable costs in the production of seamless tubes compared to the graphite-containing lubricants currently used. At the same time, it overcomes other disadvantages of graphite-containing lubricants, such as special work protection measures required for handling graphite-containing lubricants, spot welding of tools and workpieces, and carburization and the resultant embrittlement of the inner surface of the roll tube.

The essential feature of the lubricant according to the invention is the proportion of the solid lubricant, which is a mixture of talc and potassic mica, wherein the proportion of talc to potassic mica is at least 2.0 and not more than 5.0.

In an advantageous embodiment of the invention, the ratio of talc to potassic mica in the solid lubricant is from 2.5 to 4.5, preferably from 3.0 to 4.0, particularly preferably from 3.3 to 3.8.

Talc

The talc according to the invention is one of the main components of the solid lubricant in the lubricant according to the invention, in the form of a powder of mineral talc, layered silicate (multi-layered silicate), more precisely magnesium silicate hydrate. According to different modifications, it crystallizes as talc-1A in the triclinic system or as talc-2M in the monoclinic system.

Potassium mica

The inventive potassium mica constitutes a further essential component of the solid lubricant in the inventive lubricant, but in a smaller amount than the talc present, it is also a layer silicate (multilayer silicate) but with potassium ions.

Basically, the use of layered silicates in lubricants and metal hot forming is known. Surprisingly, however, it is the combination of talc with potassium mica in the proportions claimed herein which contributes to a very large extent to the improved and particularly advantageous properties of the lubricants according to the invention.

Suitable potassium micas according to the invention include the following micas:

-muscovite-green lepidolite series (dioctahedron), specifically muscovite, K Al₂[AlSi₃O₁₀(OH)₂]Alumino-chlorite, K Al (Mg, Fe)²⁺)[Si₄O₁₀(OH)₂]Iron aluminum green scale, K Al (Mg, Fe)²⁺)[Si₄O₁₀(OH)₂]Chlorite, KFe³⁺(Mg，Fe²⁺)[Si₄O₁₀(OH)₂]Iron green scale, K Fe³⁺(Mg，Fe²⁺)[Si₄O₁₀(OH)₂]、K Fe³⁺(Mg，Fe²⁺)[Si₄O₁₀(OH)₂]，

-phlogopite-hydroxomicas series (trioctahedral), specifically hydroxomicas, K Fe²⁺ ₃[AlSi₃O₁₀(OH)₂]Phlogopite, K Mg²⁺ ₃[AlSi₃O₁₀(OH)₂]，

Muscovitum-polysillicit mica series (trioctahedron), i.e. Muscovitum, K-Fe²⁺ ₂Al[Al₂Si₂O₁₀(OH)₂]Polysilicic lepidolite, K-Li₂Al[Si₄O₁₀F₂]，

Group of Muscovitum, K Li Mg₂[Si₄O₁₀F₂]，

-and mixtures of the above potassium micas.

Phlogopite and muscovite, in particular phlogopite, have proven particularly advantageous. In another embodiment of the invention, the potassium mica thus contains at least 60% by weight phlogopite, preferably at least 80% by weight phlogopite, particularly preferably at least 90% by weight phlogopite, in the solid lubricant of the lubricant according to the invention. More particularly preferably, only phlogopite is used as potassium mica.

In the hot forming of metals, in particular for lubricating core rods and/or hollow blocks in the production of seamless tubes, the lubricant according to the invention is sprayed onto the core rod, and possibly also onto the hollow blocks, in the form of a suspension of solid constituents in water. Suitable aqueous suspensions have from 10 to 45% by weight of solids, preferably from 15 to 35% by weight of solids, particularly preferably from 20 to 30% by weight of solids.

In addition to the main components of the solid lubricant consisting of talc and potassic mica, the lubricant of the present invention comprises 10 to 30% by weight of a binder and 2 to 10% by weight of a thickener. Ethylene vinyl acetate copolymer (EVA) has proven to be a particularly advantageous binder, xanthan gum being found to be a particularly advantageous thickener. However, as noted herein, other suitable binders and thickeners may also be used. Within the above-mentioned content ranges, depending on the solid component of the lubricant, the person skilled in the art can easily determine the amounts of binder and thickener which are suitable for the overall composition of the lubricant in order to achieve good processability, usability of the lubricant suspension in each available spraying device, wettability, adhesion and layer thickness build-up on the tool surface for each use case.

The lubricants according to the invention also contain 0 to 10% by weight of further auxiliaries, which can be used advantageously in lubricants of the type described herein, depending on the respective use case. Such adjuvants preferably include defoamers, dispersants and biocides.

The anti-foaming agent is intended to prevent or at least reduce unwanted foaming when the lubricating suspension is sprayed on a tool, such as a core rod. Suitable defoamers include polyglycols, amorphous and/or hydrophobic silicic acids, polysiloxanes, dimethylpolysiloxanes, organomodified polysiloxanes and naphthalene condensates.

The use of dispersants may advantageously improve the distribution of lubricant solids in aqueous suspension and prevent or retard the settling of solids in suspension. Suitable dispersants include C16-C18 alcohols, ethoxy salts, sodium and potassium tripolyphosphates, polyethylene glycols and sodium silicates.

The use of biocides can advantageously prevent or at least reduce the proliferation of microorganisms such as bacteria, fungi and/or yeasts in the lubricant, especially in the case of long-term storage of the lubricant. Suitable biocides include 1, 2-benzisothiazol-3 (2H) -one, 5-chloro-2-methyl-4-isothiazol-3-one, 2-methyl-2H-isothiazol-3-one, 2-octyl-2H-isothiazol-3-one, ethylene dioxydimethanol, tetrahydro-1, 3,4, 6-tetrakis (hydroxymethyl) imidazo [4,5-d ] imidazole-2, 5(1H,3H) -dione, 2-bromo-2-nitropropane-1, 3-diol, 2, 2-dibromo-2-carbamoylacetonitrile, sodium hypochlorite and sodium chlorite.

Another advantage of the lubricant of the present invention is that it can replace the graphite-containing lubricants currently used in continuous and pipe-jacking processes for seamless pipe production, thereby overcoming the disadvantages of using graphite. Graphite is an excellent lubricant, and is particularly suitable for metal hot forming due to its heat resistance. Thus, graphite-containing lubricants used to date for these applications typically contain a high proportion of graphite.

Although the lubricants of the present invention are intended to overcome the disadvantages of graphite-containing lubricants and to replace them, in embodiments of the lubricants of the present invention, it may also be advantageous to add an amount of graphite to adjust and further improve the performance of the lubricant. However, according to the invention, the proportion of graphite in the lubricant may not exceed 10% by weight of graphite, preferably not more than 5% by weight of graphite. Nevertheless, this proportion of graphite in the lubricant according to the invention is significantly less than the high graphite proportions in the graphite-containing lubricants used hitherto and therefore does not involve the disadvantages of the known degree of graphite. However, it is particularly preferred that the lubricant of the present invention does not contain any graphite.

The invention also relates to the use of the lubricant composition according to the invention for lubricating mandrel bars and/or hollow blocks in the production of seamless tubes by metal hot forming, preferably using a continuous process or a pipe-jacking process. In this case, the lubricant is preferably sprayed in the form of an aqueous suspension onto the core rod at about 100 ℃ before it is introduced into the hollow block.

According to various compositions, the lubricant of the invention is used at a rate of 30 to 150g/m²The layer thickness (amount used) of the surface area of the core rod is sprayed. The layer thickness (amount used) is preferably 50 to 120g/m²The surface area for spraying is particularly preferably from 70 to 100g/m²The surface area is sprayed.

The invention is further described below by way of examples and descriptions of the methods and materials used. However, these examples should not be construed as limiting the scope of the invention.

Materials and methods

Viscosity measurement

The viscosity measurement was carried out using a Brookfield (AMETEK corporation-BU Brookfield, Lorch, Germany) rotational rheometer R/S Plus, with coaxial cylinders (40mm spindle), in accordance with DIN 53019 and according to the manufacturer' S instructions, and using the software Rheo3000 at a sample temperature of 20 ℃ +/-0.4 ℃.

Determination of Friction value

The friction value was determined using a "HT-Tribometer Pr ufstand 564" Tribometer (Lohrentz Pr uftechnik, Nidda-Harb, Germany). The tribometer comprises an inductively heatable Thermadur 2342EFS steel rotary disk of 280mm diameter and a hydraulically displaceable table in the direction of the rotary disk, on which a test body of S355MC steel is mounted which can be heated by resistance heating.

To determine the friction value, the discs were heated to 100 ℃ (+10 ℃) and sprayed with lubricant to the desired layer thickness. The distance between the nozzle and the surface of the rotating disc is 10 mm. Unless otherwise stated explicitlyObviously, otherwise the layer thickness of the lubricant is 80g/m²And may be run for about 5 seconds prior to the assay.

In the subsequent measurements, the discs were rotated at a rate of 10 rpm. The test body was heated to 1230 ℃ (+20 ℃) and passed through a hydraulically movable table at a pressure (F) of 32,000N (+2,000N)_N) Pressing on the rotating disc, the radial force (F) acting on the disc perpendicular to the pressure is measured within a few seconds_R). The friction value (. mu.) is the radial force (F)_R) With pressure (F)_N) Ratio of (a) to (b), μ ═ F_R/F_N.6 determinations (6 replicates) were made per sample. In each measurement, the average value of the friction values detected 2 to 6 seconds after the workpiece was brought into contact with the turntable was regarded as the measured friction value. The friction values specified here are likewise the average of six measurements made on each sample.

Layer thickness detection

The layer thickness of the lubricant applied to the tribometer disc under the spraying conditions (spraying duration) was checked by applying a magnetic strip foil to the disc surface before spraying the lubricant, after which the lubricant was sprayed onto the disc. The magnetic foil is removed, the lubricated magnetic foil is weighed and the layer thickness is determined from the difference in weight between it and the foil without the lubricant.

Comparative lubricant

As a comparative lubricant, a graphite-containing core rod lubricant was used120GLW 30 (hereinafter referred to as "PH 120") which is mainly used in continuous processes for the production of seamless tubes, from Chemische Fabrik Budenheim KG, in the form of a 30% suspension.

Lubricant formulations and raw materials

Unless otherwise specified, the following raw materials are used in the lubricant formulation. All percentages are weight percentages and correspond to the details provided by the manufacturer.

Talc: the chemical composition is as follows: SiO 2₂：61.0％、MgO：31.0％、Al₂O₃：0.1％、Fe₂O₃: 1.8%, CaO: 0.6 percent; average particle diameter (D50): 5 μm

Phlogopite: chemical components: SiO 2₂：41％、Al₂O₃：10％、MgO：26％、CaO：2％、 K₂O：10％、Fe₂O₃: 8 percent; average particle diameter (D50): 44 μm

Muscovite 1: the chemical composition is as follows: SiO 2₂：44％，Al₂O₃：31％，K₂O：9％，Fe₂O₃: 3 percent; average particle diameter (D50): 45 μm

Muscovite 2：SiO₂：51.5％，Al₂O₃：27.0％，K₂O：10.0％，Fe₂O₃: 2.9%, MgO: 2.8 percent; average particle diameter (D50): 5 μm

Graphite: natural graphite, carbon content: 95%, average particle diameter (D50): 21 μm

Adhesive agent: vinyl acetate-ethylene copolymer (EVA)

Thickening agent: xanthan gum (E415)

Examples

Optimum talc/phyllosilicate ratio

FIG. 1 shows the friction values of the compositions studied. Formulations C and D with talc to phlogopite ratios of 3.3 and 3.8, respectively, were the most effective. Formulations B and E with talc to phlogopite ratios below 3.3 and above 3.8, respectively, gave similar results to formulation F containing only phlogopite. Formulation A gave similar results to formulation G containing talc only. Compared to formulation F, formulation H, using muscovite (muscovite 1) instead of phlogopite, gave significantly poorer results than formulation F, which contained only phlogopite.

However, the friction values for all formulations A-H were significantly lower than the comparative formulation PH120 containing the prior art graphite-containing product.

Various amounts of talc + phlogopite solid lubricant

FIG. 2 shows the friction values of the compositions studied. It was found that a ratio of talc to phlogopite in the range of 3.3-3.8 is particularly advantageous for the achievable friction values, and in about 13% talc + phlogopite (formulations S and T), better friction values were obtained compared to 19.5% talc + phlogopite (formulations C and D). When 26% and 25.24% talc + phlogopite (formulations R and U), respectively, were used, the friction values were higher, but still significantly lower than the comparative formulation pH120 containing the prior art graphite-containing product.

Comparison of various mica and graphite additions

FIG. 3 shows the friction values of the compositions studied. The alternative micas (muscovite 1 and muscovite 2) in formulations L and M were compared to the phlogopite in formulation C and the same amount of pure graphite used in formulation I in place of talc + mica. With the same amount of phlogopite (formulation C), an optimum friction value was achieved, and the micas (muscovite 1 and muscovite 2) (formulations L and M) also exhibited good friction values, only slightly higher than when an equivalent amount of pure graphite was used instead of talc + mica (formulation I).

In formulations O, P and Q, a portion of the amount of talc + phlogopite was replaced with 1%, 5% and 10% graphite, respectively, while maintaining the talc/phlogopite ratio at 3.3 relative to formulation C.

The results generally show that the lubricants according to the invention achieve the same or even significantly better lubricating effect at the same amount used and at the same layer thickness than the commercially customary graphite-containing lubricants and also the use of pure graphite or a portion of graphite instead of talc plus mica. Thus, the lubricants of the present invention can achieve substantial cost savings in seamless tube production compared to the graphite-containing lubricants currently used, and also overcome the disadvantages of graphite-containing lubricants.

Comparison of the various layer thicknesses

FIG. 4 shows the friction values for different layer thicknesses of PH120 and composition C. Comparison of the formulations C of the various layer thicknesses with the comparative lubricant PH120 again shows that the formulation C according to the invention is used even at the smallest amounts and only 30g/m²Still provides better or at least comparable friction values compared to the use of two to more than three times the amount of the comparative lubricant PH 120.

Composition "C" used in the above comparison contained 25% (wt%) solid components and 75% water. In another test, a higher dilution of the same solid composition was prepared with a lower proportion of solids and was measured for friction values as described above (20% to 10% solids component; hereinafter referred to as "C20", "C17.5", … … "C10"). With increasing dilution (increasing amount of water), the amount used in the test (layer thickness) decreased at the same application time.

Comparison of various concentrations and layer thicknesses of solid compositions of "C

C (fs) percent solids in composition "C" without water.

The results show that sample "C10" even at the highest dilution and minimum usage of only about half the amount of the lubricant of the present invention, still achieved significantly better friction values than the commercially available graphite-containing lubricant. Comparison of the results of this test with the above test results shows that, for the purposes of the present inventionVolume composition "C", a dilution in the order of 20-25% and about 50-80g/m²At the amounts used, particularly advantageous results in terms of friction values are obtained.