阅读说明：本技术 一种高强度抗冲刷侵蚀钢包自流浇注料及其制备方法 (High-strength anti-erosion ladle self-flow castable and preparation method thereof ) 是由 王团收 刘琳琳 刘丽 颜浩 任林 贾祥超 刘靖轩 崔志强 李健 张盛 于 2021-02-05 设计创作，主要内容包括：本发明提供一种高强度抗冲刷侵蚀钢包自流浇注料及其制备方法,钢包自流浇注料按照质量份数计算,其制备原料包括以下组分：铬刚玉骨料5-40份、水洗刚玉骨料20-70份、白刚玉细粉5-40份、电熔镁砂细粉1-15份、低钠α氧化铝微粉1-25份、纯铝酸钙水泥1-10份、锆复合硅微粉0.1-5份、缓凝型减水剂0.1-5份、有机纤维0.01-0.5份。该自流浇注料具有较高的强度、良好的抗冲刷性能和抗渣侵蚀性能,可解决刚玉质自流浇注料在使用过程中存在的流动性差、偏析、不耐冲刷和侵蚀等问题。(The invention provides a high-strength anti-erosion ladle self-flowing castable and a preparation method thereof, wherein the ladle self-flowing castable comprises the following preparation raw materials in parts by mass: 5-40 parts of chrome corundum aggregate, 20-70 parts of water-washed corundum aggregate, 5-40 parts of white corundum fine powder, 1-15 parts of fused magnesia fine powder, 1-25 parts of low-sodium alpha alumina micro powder, 1-10 parts of pure calcium aluminate cement, 0.1-5 parts of zirconium composite silicon micro powder, 0.1-5 parts of retarding water reducer and 0.01-0.5 part of organic fiber. The self-flowing castable has higher strength, good anti-scouring performance and slag erosion resistance, and can solve the problems of poor fluidity, segregation, no erosion and erosion resistance and the like in the use process of the corundum self-flowing castable.)

1. The high-strength anti-erosion ladle gravity flow castable is characterized by comprising the following preparation raw materials in parts by mass:

5-40 parts of chrome corundum aggregate, 20-70 parts of water-washed corundum aggregate, 5-40 parts of white corundum fine powder, 1-15 parts of fused magnesia fine powder, 1-25 parts of low-sodium alpha alumina micro powder, 1-10 parts of pure calcium aluminate cement, 0.1-5 parts of zirconium composite silicon micro powder, 0.1-5 parts of retarding water reducer and 0.01-0.5 part of organic fiber.

2. The high-strength erosion-resistant ladle self-flowing castable according to claim 1, wherein the preparation raw materials comprise the following components in parts by weight:

15-25 parts of chrome corundum aggregate, 45-55 parts of water-washed corundum aggregate, 10-20 parts of white corundum fine powder, 3-8 parts of fused magnesia fine powder, 5-15 parts of low-sodium alpha alumina micro powder, 2-5 parts of pure calcium aluminate cement, 0.5-1 part of zirconium composite silicon micro powder, 0.4-1 part of retarding water reducer and 0.03-0.1 part of organic fiber.

3. The high-strength erosion-resistant ladle self-flowing castable according to claim 1, wherein:

the grain size of the chrome corundum aggregate is 3-5 mm; al in the chrome corundum aggregate₂O₃Content of more than 80wt%, Cr₂O₃The content of (B) is more than 15 wt%.

4. The high-strength erosion-resistant ladle self-flowing castable according to claim 2, wherein:

the water-washed corundum aggregate comprises the following components in parts by mass: 20-30 parts of water-washed corundum particles with the particle size of 1-3mm and 15-25 parts of water-washed corundum particles with the particle size of 0-1 mm; what is needed isAl in the water-washed corundum aggregate₂O₃The content of (B) is more than 86 wt%.

5. The high-strength erosion-resistant ladle self-flowing castable according to claim 2, wherein:

the white corundum fine powder comprises the following components in parts by mass: 5-15 parts of white corundum fine powder with the grain diameter of 0.074-0.083mm and 5-15 parts of white corundum fine powder with the grain diameter of 0.044-0.074 mm; al in the white corundum fine powder₂O₃The content of (B) is more than 99 wt%.

6. The high-strength erosion-resistant ladle self-flowing castable according to claim 2, wherein:

the low-sodium alpha alumina micro powder comprises the following components in parts by mass: 4-10 parts of low-sodium alpha alumina micro powder with the particle size of 1.5-2 mu m and 1-5 parts of low-sodium alpha alumina micro powder with the particle size of 3-5 mu m; al in the low-sodium alpha alumina micro powder₂O₃Has a content of more than 99wt%, Na₂The content of O is less than 0.20 wt%.

7. The high-strength erosion-resistant ladle self-flowing castable according to claim 1, wherein:

SiO in the zirconium composite silicon micro powder₂Is greater than 94wt%, ZrO₂The content of the zirconium composite silicon micro powder is more than 2wt%, and the pH value of the zirconium composite silicon micro powder is 3-5.

8. The high-strength erosion-resistant ladle self-flowing castable according to claim 1, wherein:

the retarding water reducer is superfine alumina, and Al in the retarding water reducer₂O₃The content of the retarding water reducer is more than 90wt%, and the pH value of the retarding water reducer is 2-4.

9. The high-strength erosion-resistant ladle self-flowing castable according to claim 1, wherein:

the particle size of the fused magnesia fine powder is 0.074-0.083mm, and the MgO content in the fused magnesia fine powder is more than 98 wt%.

10. A method of preparing a high strength erosion resistant ladle casting material according to any one of claims 1 to 9, comprising: and mixing the preparation raw materials of the high-strength anti-erosion ladle self-flowing castable according to the selected mass portion to obtain the high-strength anti-erosion ladle self-flowing castable.

Technical Field

The invention belongs to the technical field of refractory materials, and particularly relates to a high-strength erosion-resistant ladle gravity-flow castable and a preparation method thereof.

Background

The self-flow ladle casting material is developed through micro powder technology and reasonable size distribution on the basis of low cement and ultra-low cement casting material, and is one castable refractory material capable of flowing and degassing without vibration. At present, corundum self-flow casting materials are commonly used in domestic brick ladles and are used for filling joints around ladle nozzle seat bricks and air brick seat bricks and filling irregular gaps between ladle walls and ladle bottom bricks. The castable has the advantages that the used raw materials are single, the problems of poor fluidity, segregation and bleeding, erosion and corrosion resistance and the like are easily caused in the using process, the service life required by the design cannot be reached, the normal turnover of the steel ladle is influenced, the unplanned offline is caused, and the steel ladle turnover shortage, the resource waste and the cost increase of a steel mill are caused.

Therefore, in order to adapt to the increasingly harsh steelmaking smelting environment at present and prolong the service life of the ladle, the development of the ladle gravity flow castable which is resistant to molten steel erosion and corrosion, free of segregation and good in flowing property is urgently needed.

Disclosure of Invention

The invention aims to provide a high-strength anti-erosion ladle self-flowing castable and a preparation method thereof, the self-flowing castable has higher strength, good anti-erosion performance and slag erosion resistance, and can solve the problems of poor fluidity, segregation, no erosion and erosion resistance and the like existing in the use process of a corundum self-flowing castable.

In order to solve the problems, one aspect of the invention provides a high-strength erosion-resistant ladle gravity-flow castable, which comprises the following preparation raw materials in parts by mass:

5-40 parts of chrome corundum aggregate, 20-70 parts of water-washed corundum aggregate, 5-40 parts of white corundum fine powder, 1-15 parts of fused magnesia fine powder, 1-25 parts of low-sodium alpha alumina micro powder, 1-10 parts of pure calcium aluminate cement, 0.1-5 parts of zirconium composite silicon micro powder, 0.1-5 parts of retarding water reducer and 0.01-0.5 part of organic fiber.

The chrome corundum aggregate is used as the aggregate of the self-flowing castable, compared with white corundum, the chrome corundum has uniform particle size and micro-expansion characteristic under high temperature condition, and can improve the strength and the anti-erosion performance of the self-flowing castable; the chrome corundum does not need to be subjected to electric melting high-temperature treatment, so that the cost can be greatly saved.

The water-washed corundum is pure water-washed corundum particles obtained by the processes of recovering, removing impurities, crushing, washing, drying and screening used carbon-free corundum precast blocks, and the water-washed corundum is used for replacing corundum raw materials such as white corundum, tabular corundum and the like and has the following two advantages: on one hand, the washed corundum particles contain part of magnesia-alumina spinel and a small amount of unreacted fused magnesia, the fused magnesia can continue to generate magnesia-alumina spinel through in-situ reaction, the strength and the erosion resistance of the self-flowing castable are improved, on the other hand, the washed corundum realizes the recycling of resources, the resources are saved, corundum raw materials such as white corundum and plate-shaped corundum are replaced, and the energy and the cost are greatly saved.

The fused magnesia fine powder and the low-sodium alpha alumina micro powder and the white corundum fine powder in the casting material are subjected to in-situ reaction at high temperature to produce magnesia-alumina spinel, so that the strength and the erosion resistance of the self-flowing casting material are greatly improved.

The low-sodium alpha alumina micro powder is mainly distinguished from non-low-sodium alpha alumina micro powder by the following steps: low sodium alpha aluminaAlkali metal oxide Na in the micropowder₂O content less than 0.20%, and alkali metal oxide Na in non-low-sodium alpha alumina micropowder₂The content of O is generally between 0.2 and 0.30 percent, and the alkali metal oxide Na₂O belongs to a low-melting-point substance in the ladle self-flowing castable, a low-melting-point liquid phase is easily generated under the high-temperature condition, the erosion resistance and the erosion resistance of the ladle self-flowing castable are reduced, and the low-sodium alpha alumina micro powder has good dispersibility. The zirconium composite silicon powder is also called zirconium silica fume, is a byproduct produced in the process of smelting desilicated zirconium, has the main component of silicon dioxide, contains a small amount of zirconium oxide, has low price and is suitable for common unshaped refractory materials. The zirconium composite silicon powder is different from the zirconium and silicon powder in mixing, and the zirconium and silicon powder are mixed by two raw materials, so that the difficulty of the production process of the product is increased, the mixing is easy to be uneven, and the cost is increased. The low-sodium alpha alumina micro powder has good dispersibility, the zirconium composite silicon micro powder has good fluidity due to the self spherical structure, and the fluidity of the castable can be obviously improved by introducing the two raw materials, so that the castable can achieve the self-flowing effect under the action of self gravity.

The retarding water reducer can quickly open water wrapped in a flocculation structure in the castable, reduce the water adding amount and avoid segregation of the castable caused by large water adding amount; meanwhile, the retarding water reducer has a good retarding effect, can delay the hardening time of the binder in the castable, avoids the over-quick setting time of the self-flowing castable caused by high ambient temperature in the construction process, and ensures smooth construction.

Preferably, the preparation raw materials comprise the following components in parts by weight:

15-25 parts of chrome corundum aggregate, 45-55 parts of water-washed corundum aggregate, 10-20 parts of white corundum fine powder, 3-8 parts of fused magnesia fine powder, 5-15 parts of low-sodium alpha alumina micro powder, 2-5 parts of pure calcium aluminate cement, 0.5-1 part of zirconium composite silicon micro powder, 0.4-1 part of retarding water reducer and 0.03-0.1 part of organic fiber.

Preferably, the grain diameter of the chrome corundum aggregate is 3-5 mm; al in the chrome corundum aggregate₂O₃The content of (A) is more than 80wt%,Cr₂O₃the content of (B) is more than 15 wt%.

Preferably, the water-washed corundum aggregate consists of the following components in parts by mass: 20-30 parts of water-washed corundum particles with the particle size of 1-3mm and 15-25 parts of water-washed corundum particles with the particle size of 0-1 mm; al in the water-washed corundum aggregate₂O₃The content of (B) is more than 86 wt%.

Preferably, the white corundum fine powder consists of the following components in parts by mass: 5-15 parts of white corundum fine powder with the grain diameter of 0.074-0.083mm and 5-15 parts of white corundum fine powder with the grain diameter of 0.044-0.074 mm; al in the white corundum fine powder₂O₃The content of (B) is more than 99 wt%.

Preferably, the low-sodium alpha alumina micropowder consists of the following components in parts by mass: 4-10 parts of low-sodium alpha alumina micro powder with the particle size of 1.5-2 mu m and 1-5 parts of low-sodium alpha alumina micro powder with the particle size of 3-5 mu m; al in the low-sodium alpha alumina micro powder₂O₃Has a content of more than 99wt%, Na₂The content of O is less than 0.20 wt%.

The proportion of particles and fine powder in the design of the castable can be greatly met by adopting the particle size grading, and the volume density of the castable reaches the optimal value by planning the mass fractions of raw materials with different particle sizes according to the closest packing principle, so that the strength and the erosion resistance of the self-flowing castable can be improved.

Preferably, SiO in the zirconium composite silicon micropowder₂Is greater than 94wt%, ZrO₂The content of the zirconium composite silicon micro powder is more than 2wt%, and the pH value of the zirconium composite silicon micro powder is 3-5.

Preferably, the retarding water reducer is superfine alumina, and Al in the retarding water reducer₂O₃The content of the retarding water reducer is more than 90wt%, and the pH value of the retarding water reducer is 2-4.

Preferably, the particle size of the fused magnesia fine powder is 0.074-0.083mm, and the MgO content in the fused magnesia fine powder is more than 98 wt%.

Preferably, Al in the pure calcium aluminate cement₂O₃The content of (B) is more than 70 wt%.

Preferably, the melting point of the organic fiber is 105 ℃ +/-5 ℃, and the organic fiber acts as an explosion-proof agent.

In another aspect, the invention provides a method for preparing the high-strength erosion-resistant ladle self-flowing castable, which comprises the following steps: and mixing the preparation raw materials of the high-strength anti-erosion ladle self-flowing castable according to the selected mass portion to obtain the high-strength anti-erosion ladle self-flowing castable.

Compared with the prior art, the invention has the following beneficial effects:

1. according to the high-strength erosion-resistant ladle self-flowing castable, in the preparation raw materials, the low-sodium alpha alumina micro powder has good dispersibility, the spherical structure of the zirconium composite silica micro powder has good fluidity, and the fluidity of the castable can be obviously improved by introducing the two raw materials, so that the castable can achieve the self-flowing effect under the action of self gravity; the fused magnesia fine powder and the low-sodium alpha alumina micro powder and the white corundum fine powder in the casting material are subjected to in-situ reaction to produce magnesia-alumina spinel at high temperature, so that the strength and the erosion resistance of the self-flowing casting material are greatly improved; the retarding water reducer can quickly open water wrapped in a flocculation structure in the castable, reduce the water adding amount and avoid segregation of the castable caused by large water adding amount; meanwhile, the retarding superplasticizer has a good retarding effect, can delay the hardening time of the binder in the castable, avoids the over-fast setting time of the self-flowing castable caused by high ambient temperature in the construction process, and ensures smooth construction. The ladle self-flow castable has high strength and good erosion resistance, and can prolong the service life of the ladle;

2. the high-strength erosion-resistant ladle self-flowing castable disclosed by the invention takes industrial byproducts such as chrome corundum aggregate and washing corundum aggregate and reclaimed materials as aggregates, realizes the recycling of resources on the premise of not influencing the service performance of the ladle self-flowing castable, and can save resources and reduce cost.

Detailed Description

The technical solutions of the present invention will be described clearly and completely with reference to the following embodiments of the present invention, and it should be understood that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

Example 1

The high-strength anti-erosion ladle self-flowing castable provided by the embodiment is prepared from the following raw materials in parts by mass:

20 parts of chrome corundum aggregate with the particle size of 3-5mm, 25 parts of water-washed corundum aggregate with the particle size of 1-3mm, 20 parts of water-washed corundum aggregate with the particle size of 0-1mm, 7.5 parts of white corundum fine powder with the particle size of 0.074-0.083mm, 7.5 parts of white corundum fine powder with the particle size of 0.044-0.074mm, 5 parts of 98-fused magnesia fine powder with the particle size of 0.074-0.083mm, 7 parts of low-sodium alpha alumina micro powder with the particle size of 1.5-2 mu m, 3 parts of low-sodium alpha alumina micro powder with the particle size of 3-5 mu m, 3.5 parts of pure calcium aluminate cement, 1 part of zirconium composite silicon micro powder, 0.6 parts of retarding type water reducer ultrafine alumina (the production company of Chongqing chemical products, the model: KF 51S), and 0.05 parts of high molecular weight polyethylene organic fiber.

Al in chrome corundum aggregate₂O₃Content of more than 80wt%, Cr₂O₃Is greater than 15 wt%; al in the water-washed corundum aggregate₂O₃Is greater than 86 wt%; al in fine white corundum powder₂O₃Is greater than 99 wt%; the MgO content in the fused magnesia fine powder is more than 98 wt%; al in low-sodium alpha alumina micro powder₂O₃Has a content of more than 99wt%, Na₂The content of O is less than 0.20 wt%; al in pure calcium aluminate cement₂O₃Is greater than 70 wt%; SiO in zirconium composite silicon micropowder₂Is greater than 94wt%, ZrO₂The content of the zirconium composite silicon micro powder is more than 2wt%, and the pH value of the zirconium composite silicon micro powder is 3-5; al in retarding water reducer₂O₃The content of the water reducing agent is more than 90wt%, and the pH value of the retarding water reducing agent is 2-4.

The method for preparing the high-strength erosion-resistant ladle self-flowing castable comprises the following steps: and mixing the prepared raw materials according to the selected mass parts, and then carrying out dry mixing for 3 minutes to obtain the high-strength anti-erosion ladle self-flowing castable.

And adding 5.0wt% of water into the obtained high-strength anti-erosion ladle self-flowing castable, stirring for 5 minutes, measuring the flowing property of the high-strength anti-erosion ladle self-flowing castable, wherein the flowing value is 85%, carrying out vibration casting molding, preparing a standard strip-shaped sample of 160mm multiplied by 40mm, naturally curing for 24 hours, demoulding, and drying the sample in an oven at the temperature of 110 +/-5 ℃ for 24 hours to obtain a finished product detection sample block of the ladle self-flowing castable.

Through tests, the prepared detection sample block of the ladle self-flowing castable is detected at normal temperature, and the physical and chemical indexes of the finished detection sample block are as follows: bulk density 3.19g/cm³The normal-temperature compressive strength is 115.8MPa, the normal-temperature rupture strength is 13.5MPa, and the scouring resistance and the erosion resistance are good.

Through tests, the prepared detection sample block of the finished product of the steel ladle self-flow injection material is sintered at the temperature of 1550 ℃, the heat is preserved for 3 hours, and the physicochemical indexes of the cooled detection sample block of the finished product are as follows: bulk density 3.14g/cm³The normal-temperature compressive strength is 175.6MPa, the normal-temperature rupture strength is 24.6MPa, and the scouring resistance and the erosion resistance are good.

Example 2

The high-strength anti-erosion ladle self-flowing castable provided by the embodiment is prepared from the following raw materials in parts by mass:

23 parts of chrome corundum aggregate with the particle size of 3-5mm, 20 parts of water-washed corundum aggregate with the particle size of 1-3mm, 22 parts of water-washed corundum aggregate with the particle size of 0-1mm, 9 parts of white corundum fine powder with the particle size of 0.074-0.083mm, 5 parts of white corundum fine powder with the particle size of 0.044-0.074mm, 6 parts of 98-fused magnesia fine powder with the particle size of 0.074-0.083mm, 6 parts of low-sodium alpha alumina micro powder with the particle size of 1.5-2 mu m, 4 parts of low-sodium alpha alumina micro powder with the particle size of 3-5 mu m, 4 parts of pure calcium aluminate cement, 0.8 part of zirconium composite silicon micro powder, 0.5 part of retarding type water reducer ultrafine alumina (the production factory is Leketer (Chongqing chemical products Co., type: KF 51S), and 0.08 part of high molecular weight polyethylene organic fiber.

Al in chrome corundum aggregate₂O₃Content of more than 80wt%, Cr₂O₃Is greater than 15 wt%; al in the water-washed corundum aggregate₂O₃Is greater than 86 wt%; al in fine white corundum powder₂O₃Is greater than 99 wt%; the MgO content in the fused magnesia fine powder is more than 98 wt%; al in low-sodium alpha alumina micro powder₂O₃Has a content of more than 99wt%, Na₂The content of O is less than 0.20 wt%; al in pure calcium aluminate cement₂O₃Is greater than 70 wt%; SiO in zirconium composite silicon micropowder₂Is greater than 94wt%, ZrO₂The content of the zirconium composite silicon micro powder is more than 2wt%, and the pH value of the zirconium composite silicon micro powder is 3-5; al in retarding water reducer₂O₃The content of the water reducing agent is more than 90wt%, and the pH value of the retarding water reducing agent is 2-4.

The method for preparing the high-strength erosion-resistant ladle self-flowing castable comprises the following steps: and mixing the prepared raw materials according to the selected mass parts, and then carrying out dry mixing for 3 minutes to obtain the high-strength anti-erosion ladle self-flowing castable.

And adding 5.0wt% of water into the obtained high-strength anti-erosion ladle self-flowing castable, stirring for 5 minutes, measuring the flowing property of the high-strength anti-erosion ladle self-flowing castable, wherein the flowing value is 80%, carrying out vibration casting molding, preparing a standard strip-shaped sample of 160mm multiplied by 40mm, naturally curing for 24 hours, demoulding, and drying the sample in an oven at the temperature of 110 +/-5 ℃ for 24 hours to obtain a finished product detection sample block of the ladle self-flowing castable.

Through tests, the prepared detection sample block of the ladle self-flowing castable is detected at normal temperature, and the physical and chemical indexes of the finished detection sample block are as follows: bulk density 3.18g/cm³The normal-temperature compressive strength is 100.4MPa, the normal-temperature rupture strength is 14.7MPa, and the scouring resistance and the erosion resistance are good.

Through tests, the prepared finished product detection sample block of the ladle permanent layer castable is sintered at the temperature of 1550 ℃, the temperature is kept for 3 hours, and the physicochemical indexes of the cooled finished product detection sample block are as follows: bulk density 3.13g/cm³The normal-temperature compressive strength is 161.3MPa, the normal-temperature rupture strength is 23.8MPa, and the scouring resistance and the erosion resistance are good.

Example 3

The high-strength anti-erosion ladle self-flowing castable provided by the embodiment is prepared from the following raw materials in parts by mass:

17 parts of chrome corundum aggregate with the particle size of 3-5mm, 30 parts of water-washing corundum aggregate with the particle size of 1-3mm, 18 parts of water-washing corundum aggregate with the particle size of 0-1mm, 11 parts of white corundum fine powder with the particle size of 0.074-0.083mm, 4 parts of white corundum fine powder with the particle size of 0.044-0.074mm, 7 parts of 98 electric smelting magnesia fine powder with the particle size of 0.074-0.083mm, 8 parts of low-sodium alpha alumina micro powder with the particle size of 1.5-2 mu m, 2 parts of low-sodium alpha alumina micro powder with the particle size of 3-5 mu m, 3.7 parts of pure calcium aluminate cement, 0.6 part of zirconium composite silicon micro powder, 0.7 parts of retarding water reducer ultrafine alumina (the manufacturer is Lekete (Chongqing chemical products Limited company, model: KF 51S), and 0.09 parts of high molecular weight polyethylene organic fiber.

Al in chrome corundum aggregate₂O₃Content of more than 80wt%, Cr₂O₃Is greater than 15 wt%; al in the water-washed corundum aggregate₂O₃Is greater than 86 wt%; al in fine white corundum powder₂O₃Is greater than 99 wt%; the MgO content in the fused magnesia fine powder is more than 98 wt%; al in low-sodium alpha alumina micro powder₂O₃Has a content of more than 99wt%, Na₂The content of O is less than 0.20 wt%; al in pure calcium aluminate cement₂O₃Is greater than 70 wt%; SiO in zirconium composite silicon micropowder₂Is greater than 94wt%, ZrO₂The content of the zirconium composite silicon micro powder is more than 2wt%, and the pH value of the zirconium composite silicon micro powder is 3-5; al in retarding water reducer₂O₃The content of the water reducing agent is more than 90wt%, and the pH value of the retarding water reducing agent is 2-4.

The method for preparing the high-strength erosion-resistant ladle self-flowing castable comprises the following steps: and mixing the prepared raw materials according to the selected mass parts, and then carrying out dry mixing for 3 minutes to obtain the high-strength anti-erosion ladle self-flowing castable.

And adding 5.0wt% of water into the obtained high-strength anti-erosion ladle self-flowing castable, stirring for 5 minutes, measuring the flowing property of the high-strength anti-erosion ladle self-flowing castable, wherein the flowing value is 82%, carrying out vibration casting molding, preparing a standard strip-shaped sample of 160mm multiplied by 40mm, naturally curing for 24 hours, demoulding, and drying the sample in an oven at the temperature of 110 +/-5 ℃ for 24 hours to obtain a finished product detection sample block of the ladle self-flowing castable.

After the experimentAccording to the test, the prepared detection sample block of the ladle self-flowing castable is detected at normal temperature, and the physicochemical indexes of the finished detection sample block are as follows: bulk density 3.19g/cm³The normal-temperature compressive strength is 121.6MPa, the normal-temperature rupture strength is 11.9MPa, and the anti-scouring performance and the anti-erosion performance are good.

Through tests, the prepared finished product detection sample block of the ladle permanent layer castable is sintered at the temperature of 1550 ℃, the temperature is kept for 3 hours, and the physicochemical indexes of the cooled finished product detection sample block are as follows: bulk density 3.15g/cm³The normal-temperature compressive strength is 152.1MPa, the normal-temperature rupture strength is 25.2MPa, and the scouring resistance and the erosion resistance are good.

Example 4

The high-strength anti-erosion ladle self-flowing castable provided by the embodiment is prepared from the following raw materials in parts by mass:

15 parts of chrome corundum aggregate with the particle size of 3-5mm, 28 parts of water-washing corundum aggregate with the particle size of 1-3mm, 24 parts of water-washing corundum aggregate with the particle size of 0-1mm, 5 parts of white corundum fine powder with the particle size of 0.074-0.083mm, 10 parts of white corundum fine powder with the particle size of 0.044-0.074mm, 6.5 parts of 98-fused magnesia fine powder with the particle size of 0.074-0.083mm, 9 parts of low-sodium alpha alumina micro powder with the particle size of 1.5-2 mu m, 1 part of low-sodium alpha alumina micro powder with the particle size of 3-5 mu m, 4.2 parts of pure calcium aluminate cement, 0.9 part of zirconium composite silicon micro powder, 0.55 part of retarding water reducer ultrafine alumina (the manufacturer is Lekete (Chongqing chemical products Co., model: KF 8951 51S), and 0.07 part of high molecular weight polyethylene organic fiber.

Al in chrome corundum aggregate₂O₃Content of more than 80wt%, Cr₂O₃Is greater than 15 wt%; al in the water-washed corundum aggregate₂O₃Is greater than 86 wt%; al in fine white corundum powder₂O₃Is greater than 99 wt%; the MgO content in the fused magnesia fine powder is more than 98 wt%; al in low-sodium alpha alumina micro powder₂O₃Has a content of more than 99wt%, Na₂The content of O is less than 0.20 wt%; al in pure calcium aluminate cement₂O₃Is greater than 70 wt%; SiO in zirconium composite silicon micropowder₂Is greater than 94wt%, ZrO₂In an amount of more than2wt% and the pH of the zirconium composite silicon micro powder is 3-5; al in retarding water reducer₂O₃The content of the water reducing agent is more than 90wt%, and the pH value of the retarding water reducing agent is 2-4.

The method for preparing the high-strength erosion-resistant ladle self-flowing castable comprises the following steps: and mixing the prepared raw materials according to the selected mass parts, and then carrying out dry mixing for 3 minutes to obtain the high-strength anti-erosion ladle self-flowing castable.

And adding 5.0wt% of water into the obtained high-strength anti-erosion ladle self-flowing castable, stirring for 5 minutes, measuring the flowing property of the high-strength anti-erosion ladle self-flowing castable, wherein the flowing value is 78%, carrying out vibration casting molding, preparing a standard strip-shaped sample of 160mm multiplied by 40mm, naturally curing for 24 hours, demoulding, and drying the sample in an oven at the temperature of 110 +/-5 ℃ for 24 hours to obtain a finished product detection sample block of the ladle self-flowing castable.

Through tests, the prepared detection sample block of the ladle self-flowing castable is detected at normal temperature, and the physical and chemical indexes of the finished detection sample block are as follows: bulk density 3.14g/cm³The normal-temperature compressive strength is 165.9MPa, the normal-temperature rupture strength is 28.4MPa, and the scouring resistance and the erosion resistance are good.

Through tests, the prepared finished product detection sample block of the ladle permanent layer castable is sintered at the temperature of 1550 ℃, the temperature is kept for 3 hours, and the physicochemical indexes of the cooled finished product detection sample block are as follows: bulk density 3.14g/cm³The normal-temperature compressive strength is 165.9MPa, the normal-temperature rupture strength is 28.4MPa, and the scouring resistance and the erosion resistance are good.

Example 5

The high-strength anti-erosion ladle self-flowing castable provided by the embodiment is prepared from the following raw materials in parts by mass:

25 parts of chrome corundum aggregate with the particle size of 3-5mm, 23 parts of water-washing corundum aggregate with the particle size of 1-3mm, 16 parts of water-washing corundum aggregate with the particle size of 0-1mm, 3 parts of white corundum fine powder with the particle size of 0.074-0.083mm, 12 parts of white corundum fine powder with the particle size of 0.044-0.074mm, 5.5 parts of 98 electric smelting magnesia fine powder with the particle size of 0.074-0.083mm, 6.5 parts of low-sodium alpha alumina micro powder with the particle size of 1.5-2 mu m, 3.5 parts of low-sodium alpha alumina micro powder with the particle size of 3-5 mu m, 4.5 parts of pure calcium aluminate cement, 0.7 part of zirconium composite silicon micro powder, 0.65 part of retarding superfine alumina (the production is a Lekete (Chongqing chemical product company, the manufacturer: KF 51S), and 0.06 part of high molecular weight polyethylene organic fiber.

Al in chrome corundum aggregate₂O₃Content of more than 80wt%, Cr₂O₃Is greater than 15 wt%; al in the water-washed corundum aggregate₂O₃Is greater than 86 wt%; al in fine white corundum powder₂O₃Is greater than 99 wt%; the MgO content in the fused magnesia fine powder is more than 98 wt%; al in low-sodium alpha alumina micro powder₂O₃Has a content of more than 99wt%, Na₂The content of O is less than 0.20 wt%; al in pure calcium aluminate cement₂O₃Is greater than 70 wt%; SiO in zirconium composite silicon micropowder₂Is greater than 94wt%, ZrO₂The content of the zirconium composite silicon micro powder is more than 2wt%, and the pH value of the zirconium composite silicon micro powder is 3-5; al in retarding water reducer₂O₃The content of the water reducing agent is more than 90wt%, and the pH value of the retarding water reducing agent is 2-4.

The method for preparing the high-strength erosion-resistant ladle self-flowing castable comprises the following steps: and mixing the prepared raw materials according to the selected mass parts, and then carrying out dry mixing for 3 minutes to obtain the high-strength anti-erosion ladle self-flowing castable.

And adding 5.0wt% of water into the obtained high-strength anti-erosion ladle self-flowing castable, stirring for 5 minutes, measuring the flowing property of the high-strength anti-erosion ladle self-flowing castable, wherein the flowing value is 83%, carrying out vibration casting molding, preparing a standard strip-shaped sample of 160mm multiplied by 40mm, naturally curing for 24 hours, demoulding, and drying the sample in an oven at the temperature of 110 +/-5 ℃ for 24 hours to obtain a finished product detection sample block of the ladle self-flowing castable.

Through tests, the prepared detection sample block of the ladle self-flowing castable is detected at normal temperature, and the physical and chemical indexes of the finished detection sample block are as follows: bulk density 3.19g/cm³The normal-temperature compressive strength is 90.8MPa, the normal-temperature rupture strength is 12.6MPa, and the scouring resistance and the erosion resistance are good.

Through tests, the prepared detection sample block of the ladle permanent layer castable finished product is sintered at the temperature of 1550 ℃, is subjected to heat preservation for 3 hours, and is subjected to finished product detection after coolingThe physical and chemical indexes of the sample block are as follows: bulk density 3.13g/cm³The normal-temperature compressive strength is 158.4MPa, the normal-temperature rupture strength is 27.7MPa, and the scouring resistance and the erosion resistance are good.

Example 6

The high-strength anti-erosion ladle self-flowing castable provided by the embodiment is prepared from the following raw materials in parts by mass:

25 parts of chrome corundum aggregate with the particle size of 3-5mm, 20 parts of water-washed corundum aggregate with the particle size of 1-3mm, 25 parts of water-washed corundum aggregate with the particle size of 0-1mm, 5 parts of white corundum fine powder with the particle size of 0.074-0.083mm, 5 parts of white corundum fine powder with the particle size of 0.044-0.074mm, 3 parts of 98-fused magnesia fine powder with the particle size of 0.074-0.083mm, 4 parts of low-sodium alpha alumina micro powder with the particle size of 1.5-2 mu m, 1 part of low-sodium alpha alumina micro powder with the particle size of 3-5 mu m, 2 parts of pure calcium aluminate cement, 1 part of zirconium composite silicon micro powder, 1 part of slow setting type water reducing agent superfine alumina (the manufacturer is Lekott (Chongqing) product Co., model number: KF 51S), and 0.03 part of high molecular weight polyethylene organic fiber.

Al in chrome corundum aggregate₂O₃Content of more than 80wt%, Cr₂O₃Is greater than 15 wt%; al in the water-washed corundum aggregate₂O₃Is greater than 86 wt%; al in fine white corundum powder₂O₃Is greater than 99 wt%; the MgO content in the fused magnesia fine powder is more than 98 wt%; al in low-sodium alpha alumina micro powder₂O₃Has a content of more than 99wt%, Na₂The content of O is less than 0.20 wt%; al in pure calcium aluminate cement₂O₃Is greater than 70 wt%; SiO in zirconium composite silicon micropowder₂Is greater than 94wt%, ZrO₂The content of the zirconium composite silicon micro powder is more than 2wt%, and the pH value of the zirconium composite silicon micro powder is 3-5; al in retarding water reducer₂O₃The content of the water reducing agent is more than 90wt%, and the pH value of the retarding water reducing agent is 2-4.

The method for preparing the high-strength erosion-resistant ladle self-flowing castable comprises the following steps: and mixing the prepared raw materials according to the selected mass parts, and then carrying out dry mixing for 3 minutes to obtain the high-strength anti-erosion ladle self-flowing castable.

And adding 5.0wt% of water into the obtained high-strength anti-erosion ladle self-flowing castable, stirring for 5 minutes, measuring the flowing property of the high-strength anti-erosion ladle self-flowing castable, wherein the flowing value is 82%, carrying out vibration casting molding, preparing a standard strip-shaped sample of 160mm multiplied by 40mm, naturally curing for 24 hours, demoulding, and drying the sample in an oven at the temperature of 110 +/-5 ℃ for 24 hours to obtain a finished product detection sample block of the ladle self-flowing castable.

Through tests, the prepared detection sample block of the ladle self-flowing castable is detected at normal temperature, and the physical and chemical indexes of the finished detection sample block are as follows: the bulk density is 3.18g/cm³The normal-temperature compressive strength is 106.2MPa, the normal-temperature rupture strength is 13.1MPa, and the scouring resistance and the erosion resistance are good.

Through tests, the prepared finished product detection sample block of the ladle permanent layer castable is sintered at the temperature of 1550 ℃, the temperature is kept for 3 hours, and the physicochemical indexes of the cooled finished product detection sample block are as follows: the bulk density is 3.14g/cm³The normal-temperature compressive strength is 150.8MPa, the normal-temperature rupture strength is 25.8MPa, and the scouring resistance and the erosion resistance are good.

Example 7

The high-strength anti-erosion ladle self-flowing castable provided by the embodiment is prepared from the following raw materials in parts by mass:

25 parts of chrome corundum aggregate with the particle size of 3-5mm, 30 parts of water-washing corundum aggregate with the particle size of 1-3mm, 25 parts of water-washing corundum aggregate with the particle size of 0-1mm, 10 parts of white corundum fine powder with the particle size of 0.074-0.083mm, 10 parts of white corundum fine powder with the particle size of 0.044-0.074mm, 8 parts of 98-fused magnesia fine powder with the particle size of 0.074-0.083mm, 10 parts of low-sodium alpha alumina micro powder with the particle size of 1.5-2 mu m, 5 parts of low-sodium alpha alumina micro powder with the particle size of 3-5 mu m, 5 parts of pure calcium aluminate cement, 0.5 part of zirconium composite silicon micro powder, 0.4 parts of retarding type water reducing agent superfine alumina (the manufacturer is Leketer (Chongqing chemical products Co., type: KF 51S), and 0.1 part of high molecular weight polyethylene organic fiber.

Al in chrome corundum aggregate₂O₃Content of more than 80wt%, Cr₂O₃Is greater than 15 wt%; al in the water-washed corundum aggregate₂O₃Is greater than 86 wt%; white steelAl in jade fine powder₂O₃Is greater than 99 wt%; the MgO content in the fused magnesia fine powder is more than 98 wt%; al in low-sodium alpha alumina micro powder₂O₃Has a content of more than 99wt%, Na₂The content of O is less than 0.20 wt%; al in pure calcium aluminate cement₂O₃Is greater than 70 wt%; SiO in zirconium composite silicon micropowder₂Is greater than 94wt%, ZrO₂The content of the zirconium composite silicon micro powder is more than 2wt%, and the pH value of the zirconium composite silicon micro powder is 3-5; al in retarding water reducer₂O₃The content of the water reducing agent is more than 90wt%, and the pH value of the retarding water reducing agent is 2-4.

The method for preparing the high-strength erosion-resistant ladle self-flowing castable comprises the following steps: and mixing the prepared raw materials according to the selected mass parts, and then carrying out dry mixing for 3 minutes to obtain the high-strength anti-erosion ladle self-flowing castable.

And adding 5.0wt% of water into the obtained high-strength anti-erosion ladle self-flowing castable, stirring for 5 minutes, measuring the flowing property of the high-strength anti-erosion ladle self-flowing castable, wherein the flowing value is 83%, carrying out vibration casting molding, preparing a standard strip-shaped sample of 160mm multiplied by 40mm, naturally curing for 24 hours, demoulding, and drying the sample in an oven at the temperature of 110 +/-5 ℃ for 24 hours to obtain a finished product detection sample block of the ladle self-flowing castable.

Through tests, the prepared detection sample block of the ladle self-flowing castable is detected at normal temperature, and the physical and chemical indexes of the finished detection sample block are as follows: the bulk density is 3.19g/cm³The normal-temperature compressive strength is 102.9MPa, the normal-temperature rupture strength is 12.8MPa, and the scouring resistance and the erosion resistance are good.

Through tests, the prepared finished product detection sample block of the ladle permanent layer castable is sintered at the temperature of 1550 ℃, the temperature is kept for 3 hours, and the physicochemical indexes of the cooled finished product detection sample block are as follows: the bulk density is 3.15g/cm³The normal-temperature compressive strength is 170.5MPa, the normal-temperature rupture strength is 26.6MPa, and the scouring resistance and the erosion resistance are both good.

Example 8

The high-strength anti-erosion ladle self-flowing castable provided by the embodiment is prepared from the following raw materials in parts by mass:

5 parts of chrome corundum aggregate with the particle size of 3-5mm, 40 parts of water-washing corundum aggregate with the particle size of 1-3mm, 30 parts of water-washing corundum aggregate with the particle size of 0-1mm, 2 parts of white corundum fine powder with the particle size of 0.074-0.083mm, 3 parts of white corundum fine powder with the particle size of 0.044-0.074mm, 15 parts of 98-fused magnesia fine powder with the particle size of 0.074-0.083mm, 10 parts of low-sodium alpha alumina micro powder with the particle size of 1.5-2 mu m, 15 parts of low-sodium alpha alumina micro powder with the particle size of 3-5 mu m, 1 part of pure calcium aluminate cement, 0.1 part of zirconium composite silicon micro powder, 5 parts of retarding type water reducing agent superfine alumina (the manufacturer is Lekott (Chongqing chemical product Co., model: KF 51S), and 0.01 part of high molecular weight polyethylene organic fiber.

The method for preparing the high-strength erosion-resistant ladle self-flowing castable comprises the following steps: and mixing the prepared raw materials according to the selected mass parts, and then carrying out dry mixing for 3 minutes to obtain the high-strength anti-erosion ladle self-flowing castable.

And (3) adding 5.0wt% of water into the obtained high-strength anti-erosion ladle self-flowing castable, stirring for 5 minutes, measuring the flowing property of the castable, wherein the flowing value is 40%, carrying out vibration casting molding to prepare a standard strip-shaped sample of 160mm multiplied by 40mm, naturally curing for 24 hours, demoulding, and drying the sample in an oven at the temperature of 110 +/-5 ℃ for 24 hours to obtain a finished product detection sample block of the ladle self-flowing castable.

Through tests, the prepared detection sample block of the ladle self-flowing castable is detected at normal temperature, and the physical and chemical indexes of the finished detection sample block are as follows: the bulk density is 3.12g/cm³The normal-temperature compressive strength is 60.3MPa, the normal-temperature rupture strength is 7.8MPa, and the scouring resistance and the erosion resistance are both common.

Through tests, the prepared finished product detection sample block of the ladle permanent layer castable is sintered at the temperature of 1550 ℃, the temperature is kept for 3 hours, and the physicochemical indexes of the cooled finished product detection sample block are as follows: the bulk density is 3.07g/cm³The normal-temperature compressive strength is 100.7MPa, the normal-temperature rupture strength is 14.5MPa, and the scouring resistance and the erosion resistance are both common.

Example 9

The high-strength anti-erosion ladle self-flowing castable provided by the embodiment is prepared from the following raw materials in parts by mass:

40 parts of chrome corundum aggregate with the particle size of 3-5mm, 10 parts of water-washing corundum aggregate with the particle size of 1-3mm, 10 parts of water-washing corundum aggregate with the particle size of 0-1mm, 20 parts of white corundum fine powder with the particle size of 0.074-0.083mm, 20 parts of white corundum fine powder with the particle size of 0.044-0.074mm, 1 part of 98-fused magnesia fine powder with the particle size of 0.074-0.083mm, 1 part of low-sodium alpha alumina micro powder with the particle size of 1.5-2 mu m, 10 parts of pure calcium aluminate cement, 5 parts of zirconium composite silicon micro powder, 0.1 part of retarding water reducer ultrafine alumina (the manufacturer is Lekote (Chongqing) chemical product company Limited, the model is KF 51S), and 0.5 parts of high molecular weight polyethylene organic fiber.

The method for preparing the high-strength erosion-resistant ladle self-flowing castable comprises the following steps: and mixing the prepared raw materials according to the selected mass parts, and then carrying out dry mixing for 3 minutes to obtain the high-strength anti-erosion ladle self-flowing castable.

And adding 5.0wt% of water into the obtained high-strength anti-erosion ladle self-flowing castable, stirring for 5 minutes, measuring the flowing property of the high-strength anti-erosion ladle self-flowing castable, wherein the flowing value is 38%, carrying out vibration casting molding, preparing a standard strip-shaped sample of 160mm multiplied by 40mm, naturally curing for 24 hours, demoulding, and drying the sample in an oven at the temperature of 110 +/-5 ℃ for 24 hours to obtain a finished product detection sample block of the ladle self-flowing castable.

Through tests, the prepared detection sample block of the ladle self-flowing castable is detected at normal temperature, and the physical and chemical indexes of the finished detection sample block are as follows: the bulk density is 3.11g/cm³The normal-temperature compressive strength is 65.9MPa, the normal-temperature rupture strength is 6.2MPa, and the scouring resistance and the erosion resistance are both common.

Through tests, the prepared finished product detection sample block of the ladle permanent layer castable is sintered at the temperature of 1550 ℃, the temperature is kept for 3 hours, and the physicochemical indexes of the cooled finished product detection sample block are as follows: the bulk density is 3.08g/cm³The normal-temperature compressive strength is 104.6MPa, the normal-temperature rupture strength is 15.8MPa, and the scouring resistance and the erosion resistance are both common.

It should be understood that the above examples are only for clarity of illustration and are not intended to limit the embodiments. Other variations and modifications will be apparent to persons skilled in the art in light of the above description. And are neither required nor exhaustive of all embodiments. And obvious variations or modifications therefrom are within the scope of the invention.