阅读说明：本技术 一种石墨工件表层保护层全自动涂覆装置 (Full-automatic coating device for surface protective layer of graphite workpiece ) 是由 欧明桥 于 2020-11-17 设计创作，主要内容包括：本发明涉及抗氧化石墨材料涂层方法技术领域,具体为一种石墨工件表层保护层全自动涂覆装置,其包括反应釜、石墨化罐、搅拌机构、涂层平台、排气机构、驱动机构及拨动清扫机构,通过石墨化罐中的单质硅粉末与氧化铝粉末通过反应形成氧化硅气体,并利用排气机构中的搅拌桨叶将氧化硅气体输送至涂层平台对平台上的石墨工件进行涂层,形成碳化硅涂层,配合平台的下降,利用拨动清扫机构,使的石墨工件在整个反应过程中,绕轴向进行旋转,达到均匀涂层,并且拨动清扫机构还会在涂层过程中,不断对石墨工件表层进行清扫,达到涂层表面的清洁与附着强度,解决了现有石墨工件涂层不均匀的技术问题。(The invention relates to the technical field of an anti-oxidation graphite material coating method, in particular to a full-automatic coating device for a surface protection layer of a graphite workpiece, which comprises a reaction kettle, a graphitizing tank, a stirring mechanism, a coating platform, an exhaust mechanism, a driving mechanism and a stirring and cleaning mechanism, the simple substance silicon powder in the graphitizing tank reacts with the alumina powder to form silica gas, silicon oxide gas is conveyed to the coating platform by a stirring blade in the exhaust mechanism to coat the graphite workpiece on the platform to form a silicon carbide coating, and the graphite workpiece rotates around the axial direction in the whole reaction process by stirring the cleaning mechanism in cooperation with the descending of the platform to achieve uniform coating, and stir and clean the mechanism still can constantly clean graphite workpiece surface layer in the coating process, reach the cleanness and the adhesion strength on coating surface, solved current inhomogeneous technical problem of graphite workpiece coating.)

1. The utility model provides a full-automatic coating device of graphite work piece top layer protective layer which characterized in that includes:

the device comprises a reaction kettle (1), wherein a lifting hatch cover (11) is arranged at the top of the reaction kettle (1), a hatch door (12) which is opened in a rotating mode and a gas transmission pipeline (13) used for introducing Ar gas into the reaction kettle (1) are arranged in the middle of the reaction kettle (1), and a heater used for heating is arranged in the reaction kettle (1);

the reaction tank (2), the reaction tank (2) is arranged at the lower part of the reaction kettle (1), and Si and Al which are used for containing the mixture ratio are arranged in the reaction tank₂O₃A cavity (21) for the powder mixture;

the stirring mechanism (3) is arranged at the bottom of the reaction tank (2) and is used for stirring the substances in the accommodating cavity (21);

the coating platform (4) is arranged right above the reaction tank (2), the coating platform (4) is used for placing a graphite workpiece (10) to be coated, the coating platform (4) gradually descends along the vertical direction to be close to the reaction tank (2) in the coating process of the graphite workpiece (10), and a plurality of rolling balls (40) are embedded in the contact part of the coating platform (4) and the graphite workpiece (10);

the exhaust mechanism (5) is installed at the top of the reaction tank (2), and comprises a sealing cover (51) for covering and sealing the reaction tank (2) and a gas transmission assembly (52) for communicating the coating platform (4) with the accommodating cavity (21), wherein the gas transmission assembly (52) is used for transmitting SiO gas in the accommodating cavity (21) to the graphite workpiece (10);

the driving mechanism (6) is arranged on the reaction kettle (1), synchronously drives the stirring mechanism (3), the coating platform (4) and the exhaust mechanism (5) to work, and comprises a driving component (61) and a linkage component (62), the driving component (61) is in transmission connection with the stirring mechanism (3), and the driving component (61) is in transmission connection with the coating platform (4) and the exhaust mechanism (5) through the linkage component (62); and

the stirring cleaning mechanism (7) is installed on the coating platform (4), the stirring cleaning mechanism (7) is used for stirring the graphite workpiece (10) to rotate on the coating platform (4), and the stirring cleaning mechanism (7) is used for cleaning the surface of the graphite workpiece (10) in the coating process of the graphite workpiece (10).

2. The full-automatic coating device for the protective layer on the surface of the graphite workpiece according to claim 1, wherein the stirring mechanism (3) comprises a stirring blade (31) and a rotating disk (32), the stirring blade (31) is rotatably mounted in the reaction tank (2), a rotating shaft (311) on the stirring blade penetrates through the bottom of the reaction tank (2) and is arranged outside the reaction tank (2), a cross groove (312) is formed in the bottom of the rotating shaft (311), the rotating disk (32) is rotatably mounted in the reaction tank (1) by being driven by the driving component (61) and is located below the reaction tank (2), a butt joint shaft (321) coaxially arranged with the rotating shaft (311) is arranged on the rotating shaft, and a quincunx head (322) correspondingly clamped with the cross groove (312) is arranged on the top of the butt joint shaft (321).

3. The device for automatically coating the surface protection layer on the graphite workpiece according to claim 1, wherein the lifting assembly (41) comprises:

the outer gear ring (411) is rotatably mounted on the hatch cover (11) and is driven to rotate by the driving assembly (61) through the linkage assembly (62), internal teeth (413) on the outer gear ring (411) are arranged in a tooth-missing manner, and the internal teeth (413) are divided into a plurality of tooth parts (4131) which are arranged at equal intervals along the circumferential direction of the outer gear ring (411);

a plurality of rotating gears (412), a plurality of rotating gears (412) are arranged in the outer gear ring (411) at equal intervals along the circumferential circumference of the outer gear ring (411), and are meshed with internal teeth (413) on the outer gear ring (411);

the screw rods (414) are arranged in one-to-one correspondence with the rotary gears (412), the tops of the screw rods (414) are rotatably mounted on the hatch cover (11), and the bottoms of the screw rods (414) are rotatably mounted on the sealing cover (51); and

the lead screw nut (415) is sleeved on the corresponding lead screw (414) and is arranged on the coating platform (4), and the lead screw (414) rotates to drive the coating platform (4) to move through the lead screw nut (415).

4. The full-automatic coating device for the protective layer on the surface layer of the graphite workpiece as claimed in claim 3, wherein a material rest (42) for supporting the graphite workpiece (10) is arranged at the central line position of the coating platform (4), a hollow hole (421) is formed in the material rest (42), a plurality of air holes (43) are uniformly distributed at the position, facing the material rest (42), of the coating platform (4), and the balls (40) are embedded on the top end face of the material rest (42).

5. The device for automatically coating the surface protection layer on the graphite workpiece according to claim 1, wherein the gas transmission assembly (52) comprises an exhaust pipe (521) and an exhaust hood (522), the exhaust pipe (521) is arranged between the coating platform (4) and the sealing cover (51) and comprises a steel pipe part (5211) and a hose part (5212), and the exhaust hood (522) is arranged in a funnel shape, covers the graphite workpiece (10) and is connected with the hose part (5212).

6. The device for fully automatically coating the surface protective layer on the graphite workpiece according to claim 5, wherein an exhaust valve (53) is arranged at the connecting position of the steel pipe part (5211) and the hose part (5212), the exhaust valve (53) is rotatably sleeved on the steel pipe part (5211) and is internally provided with a valve sealing plate (531), and the steel pipe part (5211) is provided with a valve compensation sealing plate (532) matched with the valve sealing plate (531).

7. The device for automatically coating the surface protective layer of the graphite workpiece as claimed in claim 3, wherein the driving assembly (61) comprises:

the motor (611), the motor (611) is installed at the bottom of the reaction kettle (1);

a main shaft (612), wherein the main shaft (612) is vertically arranged in the reaction kettle (1) and is driven by the motor (611) to rotate; and

a drive sprocket set (613), the drive sprocket set (613) being mounted between the spindle (612) and the rotary disk (32), which drives the rotary disk (32) to rotate with the spindle (612).

8. The device for automatically coating the surface protection layer of the graphite workpiece according to claim 7, wherein the linkage assembly (62) comprises:

a lift ring (621), the lift ring (621) being disposed along a circumferential direction of the rotating disk (32), and including a convex lift portion (6211) and a concave settling portion (6212);

the transmission shaft (622) is vertically and rotatably arranged on the hatch cover (11), can be adjusted in a lifting manner along the axial direction, and is arranged on the lifting ring (621) in a sliding and abutting manner at the bottom of the transmission shaft (622);

a driving gear (623), wherein the driving gear (623) is installed at the top of the main shaft (612);

the transmission gear (624) is mounted at the top of the transmission shaft (622), and when the transmission shaft (622) collides with the lifting part (6211), the transmission gear (624) is meshed with the driving gear (623) and the external teeth (4112) on the external gear ring (411) respectively; and

the transmission chain wheel (625) is rotatably arranged in the middle of the transmission shaft (622) and is arranged statically relative to the transmission shaft (622) in the vertical direction, and when the transmission shaft (622) is lifted, a key (6221) on the transmission chain wheel is inserted and matched with a key groove (6251) on the transmission chain wheel (625);

the rotating chain wheel (626) is sleeved on the exhaust valve (53), and the rotating chain wheel (626) is connected with the transmission chain wheel (625) through a transmission chain (627).

9. The full-automatic coating device for the surface protection layer of the graphite workpiece according to claim 4, wherein the poking and cleaning mechanism (7) comprises:

the rotary sleeves (71), the rotary sleeves (71) are rotatably sleeved on the corresponding screw rods (414), two groups of rotary sleeves (71) are arranged, and the rotary sleeves (71) are in friction contact with the graphite workpiece (10) to drive the graphite workpiece (10) to rotate;

the rotary driving groups (72) are arranged in one-to-one correspondence with the rotary sleeves (71), and the rotary driving groups (72) drive the rotary sleeves (71) to rotate along with the lifting of the coating platform (4);

the bottom cleaning brush (73), the bottom cleaning brush (73) is arranged on the top end face of the material rack (42), and the bottom cleaning brush (73) is used for cleaning the bottom end face of the graphite workpiece (10);

the side wall cleaning brush (74), the side wall cleaning brush (74) is installed on one side of the graphite workpiece (10), and the side wall cleaning brush (74) cleans the side wall of the graphite workpiece (10);

the top cleaning brush (75) is arranged at the top of the graphite workpiece (10), and the top cleaning brush (75) cleans the top end face of the graphite workpiece (10); and

the clamping roller (76), clamping roller (76) and two sets of rotatory sleeve (71) become the triangle and arrange the setting, this clamping roller (76) rely on the compression elastic force of spring part (78) that sets up on bottom sliding seat (77), will graphite work piece (10) extrusion contradict in on the rotatory sleeve (71), clamping roller (76) with sliding seat (77) relative rotation sets up, just sliding seat (77) along installing in slide rail (79) slip setting on coating platform (4).

10. The apparatus for coating a surface protection layer on a graphite workpiece according to claim 9, wherein the rotary driving unit (72) comprises:

a driven bevel gear (721), the driven bevel gear (721) being mounted on the top of the rotating sleeve (71);

the driving bevel gear (722) is rotatably arranged on one side of the driven bevel gear (721) through a mounting vertical plate (723), and the driving bevel gear (722) is meshed with the driven bevel gear (721);

the starting gear (724) is coaxially arranged with the driving bevel gear (722) and is arranged on the mounting vertical plate (723), and the starting gear (724) drives the driving bevel gear (722) to rotate; and

a starting rack (725), wherein the starting rack (725) is vertically arranged above the reaction tank (2), and the starting rack (725) penetrates through the coating platform (4) and is meshed with the starting gear (724).

Technical Field

The invention relates to the technical field of anti-oxidation graphite material coating methods, in particular to a full-automatic coating device for a surface protection layer of a graphite workpiece.

Background

The graphite material is a basic material with various excellent characteristics, and particularly, the graphite material can still ensure the sufficient product performance under the high temperature condition of more than 1200 ℃, which cannot be realized by common metal materials. However, the graphite material has a biggest defect that the graphite material cannot realize the above functions due to oxidation in an oxygen-containing environment, and therefore, the graphite material is subjected to surface modification based on a coating technology, so that the graphite material can normally exert excellent characteristics in the oxygen-containing environment.

The mainstream graphite surface modification technology at present is CVD (chemical vapor deposition) coating method, and a compact independent coating structure can be generated on the graphite surface by the method, so that the graphite material is isolated from the external oxygen-containing environment, and the graphite material is protected.

The problems and the defects of the existing coating technology are mainly that the coating of the graphite material is prepared by the CVD technology, the technological process is complex, the cost of raw materials is high, the graphite coating structure with higher uniformity can be obtained, but the comprehensive cost is higher, the cost performance is insufficient in the application environment of the middle-end and low-end antioxidant graphite materials, and the coating is difficult to be widely applied.

In chinese patent with patent application No. CN201210374319.1, a method for preparing a silicon carbide coating on a graphite surface is disclosed, which comprises: placing a graphite crucible filled with solid silicon materials in a high-temperature graphitization furnace, placing a graphite matrix on a graphite support in the graphite crucible, and utilizing direct reaction of silicon vapor and carbon on the surface of the graphite matrix to generate a silicon carbide coating; and secondly, placing the graphite substrate with the silicon carbide coating on the surface in a chemical vapor deposition furnace, and cracking the surface of the silicon carbide coating on the surface of the graphite substrate to generate a CVD (chemical vapor deposition) silicon carbide coating.

Although the technical scheme disclosed in the above patent solves the problem that silicon vapor is used to form an anti-oxidation silicon carbide coating on the surface of a graphite workpiece, the technical scheme uses a silicon simple substance which can be prepared only by processing silicate or silicon dioxide, the comprehensive cost is high, in the reaction process of the silicon vapor and the graphite workpiece, the silicon vapor does not circulate, the silicon vapor is difficult to uniformly wrap the graphite workpiece, and the prepared coating is uneven in thickness.

Disclosure of Invention

Aiming at the problems, the invention provides a full-automatic coating device for a graphite workpiece surface protective layer, which is characterized in that simple substance silicon powder in a graphitization tank reacts with alumina powder to form silica gas, the silica gas is conveyed to a coating platform by a stirring blade in an exhaust mechanism to coat a graphite workpiece on the platform to form a silicon carbide coating, and the stirring cleaning mechanism is stirred to rotate the graphite workpiece around the axial direction in the whole reaction process to achieve uniform coating in cooperation with the descending of the platform, and the stirring cleaning mechanism can also continuously clean the surface of the graphite workpiece in the coating process to achieve the cleaning and adhesion strength of the coating surface, so that the technical problem of uneven coating of the existing graphite workpiece is solved.

In order to achieve the purpose, the invention provides the following technical scheme:

the utility model provides a full-automatic coating device of graphite work piece top layer protective layer, includes:

the reactor comprises a reaction kettle, wherein the top of the reaction kettle is provided with a lifting hatch cover, the middle of the reaction kettle is provided with a rotationally opened hatch door and a gas transmission pipeline for introducing Ar gas into the reaction kettle, and the reaction kettle is internally provided with a heater for heating;

the reaction tank is arranged at the lower part of the reaction kettle, and Si and Al which are used for containing the mixture ratio are arranged in the reaction tank₂O₃A cavity for the powder mixture of (a);

the stirring mechanism is arranged at the bottom of the reaction tank and is used for stirring the substances in the containing cavity;

the coating platform is arranged right above the reaction tank and used for placing a graphite workpiece to be coated, the coating platform gradually descends along the vertical direction to be close to the reaction tank in the coating process of the graphite workpiece, and a plurality of rolling balls are embedded in the contact part of the coating platform and the graphite workpiece;

the exhaust mechanism is arranged at the top of the reaction tank and comprises a sealing cover for covering and sealing the reaction tank and a gas transmission assembly for communicating the coating platform with the containing cavity, and the gas transmission assembly transmits SiO gas in the containing cavity to the graphite workpiece;

the driving mechanism is arranged on the reaction kettle, synchronously drives the stirring mechanism, the coating platform and the exhaust mechanism to work, and comprises a driving component and a linkage component, wherein the driving component is in transmission connection with the stirring mechanism, and is respectively in transmission connection with the coating platform and the exhaust mechanism through the linkage component; and

the stirring and cleaning mechanism is arranged on the coating platform and used for stirring the graphite workpiece to rotate on the coating platform, and the stirring and cleaning mechanism is used for cleaning the surface of the graphite workpiece in the coating process of the graphite workpiece.

As an improvement, the stirring mechanism comprises a stirring blade and a rotating disk, the stirring blade is rotatably installed in the reaction tank, a rotating shaft on the stirring blade penetrates through the bottom of the reaction tank and is arranged outside the reaction tank, a cross groove is formed in the bottom of the rotating shaft, the rotating disk is driven by the driving assembly to be rotatably installed in the reaction tank and is located below the reaction tank, a butt joint shaft coaxially arranged with the rotating shaft is arranged on the rotating disk, and a plum blossom head correspondingly clamped with the cross groove is arranged at the top of the butt joint shaft.

As an improvement, the lift assembly comprises:

the outer gear ring is rotatably mounted on the cabin cover and is driven to rotate by the driving assembly through the linkage assembly, internal teeth on the outer gear ring are arranged in a tooth-missing manner, and the internal teeth are divided into a plurality of tooth parts which are arranged at equal intervals along the circumferential direction of the outer gear ring;

the rotary gears are arranged in the outer gear ring at equal intervals along the circumferential circumference of the outer gear ring and are meshed with the inner teeth on the outer gear ring;

the screw rods are arranged in one-to-one correspondence with the rotary gears, the tops of the screw rods are rotatably installed on the cabin cover, and the bottoms of the screw rods are rotatably installed on the sealing cover; and

the lead screw nut is sleeved on the corresponding lead screw and is arranged on the coating platform, and the lead screw rotates to drive the coating platform to move through the lead screw nut.

As an improvement, a material rack for supporting a graphite workpiece is arranged at the position of the center line of the coating platform, hollow holes are formed in the material rack, a plurality of air holes are uniformly distributed in the position, facing the material rack, of the coating platform, and the ball bearings are embedded in the top end face of the material rack.

As an improvement, the gas transmission assembly comprises an exhaust pipe and an exhaust hood, the exhaust pipe is arranged between the coating platform and the sealing cover and comprises a steel pipe part and a hose part, and the exhaust hood is arranged in a funnel shape and covers the graphite workpiece and is connected with the hose part.

As an improvement, an exhaust valve is arranged at the connecting position of the steel pipe part and the hose part, the exhaust valve is rotatably sleeved on the steel pipe part, a valve sealing plate is arranged in the exhaust valve, and a valve compensation sealing plate matched with the valve sealing plate is arranged on the steel pipe part.

As an improvement, the drive assembly comprises:

the motor is arranged at the bottom of the reaction kettle;

the main shaft is vertically arranged in the reaction kettle and is driven to rotate by the motor; and

the driving chain wheel set is installed between the main shaft and the rotating disc and drives the rotating disc to rotate along with the main shaft.

As an improvement, the linkage assembly comprises:

the lifting ring is arranged along the circumferential direction of the rotating disc and comprises a convex lifting part and a concave settling part;

the transmission shaft is vertically and rotatably arranged on the cabin cover, can be adjusted in a lifting manner along the axial direction, and is arranged on the lifting ring in a sliding and abutting mode at the bottom of the transmission shaft;

the driving gear is mounted at the top of the main shaft;

the transmission gear is arranged at the top of the transmission shaft, and when the transmission shaft is abutted against the lifting part, the transmission gear is respectively meshed with the driving gear and the external teeth on the external gear ring; and

the transmission chain wheel is rotatably arranged in the middle of the transmission shaft and is arranged in a static manner in the vertical direction relative to the transmission shaft, and when the transmission shaft is lifted, keys on the transmission chain wheel are in inserting fit with key grooves on the transmission chain wheel;

and the rotating chain wheel is sleeved on the exhaust valve and is connected with the transmission chain wheel through a transmission chain.

As an improvement, the toggle sweeping mechanism comprises:

the rotary sleeves are rotatably sleeved on the corresponding screw rods and are provided with two groups, and the rotary sleeves are in friction contact with the graphite workpiece to drive the graphite workpiece to rotate;

the rotary driving groups are arranged in one-to-one correspondence with the rotary sleeves, and drive the rotary sleeves to rotate along with the lifting of the coating platform;

the bottom cleaning brush is arranged on the top end face of the material rack and used for cleaning the bottom end face of the graphite workpiece;

the side wall cleaning brush is arranged on one side of the graphite workpiece and is used for cleaning the side wall of the graphite workpiece;

the top cleaning brush is arranged at the top of the graphite workpiece and cleans the top end surface of the graphite workpiece; and

the clamping roller and the two groups of rotating sleeves are arranged in a triangular mode, the clamping roller presses the graphite workpiece to abut against the rotating sleeves by means of the compression elastic force of spring pieces arranged on the sliding seat at the bottom, the clamping roller and the sliding seat are arranged in a relative rotating mode, and the sliding seat is arranged on the coating platform in a sliding mode along a sliding rail.

As a refinement, the rotary drive group comprises:

the driven bevel gear is mounted at the top of the rotating sleeve;

the driving bevel gear is rotatably arranged on one side of the driven bevel gear through a vertical mounting plate, and the driving bevel gear is meshed with the driven bevel gear;

the starting gear and the driving bevel gear are coaxially arranged and are arranged on the mounting vertical plate, and the starting gear drives the driving bevel gear to rotate; and

and the starting rack is vertically arranged above the reaction tank, penetrates through the coating platform and is meshed with the starting gear.

The invention has the beneficial effects that:

(1) according to the invention, silicon oxide gas is formed by reacting elemental silicon powder in a graphitization tank with aluminum oxide powder, the silicon oxide gas is conveyed to a coating platform by a stirring blade in an exhaust mechanism to coat a graphite workpiece on the platform to form a silicon carbide coating, and the stirring cleaning mechanism is used to rotate the graphite workpiece around the axial direction in the whole reaction process in cooperation with the descending of the platform to achieve uniform coating, and continuously clean the surface layer of the graphite workpiece in the coating process by stirring the cleaning mechanism to achieve the cleaning and adhesion strength of the coating surface, so that the technical problem of uneven coating of the existing graphite workpiece is solved;

(2) in the coating process, the silicon oxide gas is used for reacting with the graphite workpiece to generate a silicon carbide coating and carbon monoxide gas, and the carbon monoxide gas can be recycled to the next graphite workpiece to be coated and processed for carrying out reduction pretreatment on the graphite workpiece to be coated and processed, so that residual oxides in pores of the graphite workpiece are removed, and the stability in the coating process is ensured;

(3) according to the invention, the stirring blades are used for promoting the reaction speed of the simple substance silicon powder and the silicon dioxide powder in the reaction process and the air blowing and exhausting process respectively, and the silicon oxide gas generated by the reaction can be rapidly exhausted in the air blowing and exhausting process, so that the interference of the air pressure of Ar gas is avoided, and the purpose of uniformly coating the graphite workpiece is achieved;

(4) in the process of descending the platform, the coating platform bearing the graphite workpiece moves downwards after reacting with the silicon oxide gas for a certain time, so that the carbon monoxide gas generated by the reaction can not wrap the graphite workpiece, the subsequent silicon oxide gas can smoothly contact with the surface of the graphite workpiece, and the interference and influence of the carbon monoxide gas on the coating are avoided;

(5) according to the invention, the starting gear arranged on the coating platform is matched with the starting rack by descending the coating platform, the rotating sleeve is driven to rotate by the bevel gear set formed by matching the driven bevel gear and the driving bevel gear, and the graphite workpiece is driven to rotate by the rotation of the rotating sleeve, so that the graphite workpiece is uniformly coated by rotating;

(6) according to the invention, through the matching of the bottom cleaning brush, the side wall cleaning brush and the top cleaning brush, the graphite workpiece is continuously cleaned in the coating process, so that the surface of the graphite workpiece can be always kept clean, and the attachments on the surface of the graphite workpiece can be quickly removed through cleaning, so that the surface cleaning and the coating uniformity of the graphite workpiece are ensured, and the firmness of the coating on the surface of the graphite workpiece can be effectively ensured through cleaning.

In conclusion, the method has the advantages of uniform coating, full reaction, low comprehensive cost and the like, and is particularly suitable for the technical field of the coating method of the antioxidant graphite material.

Drawings

FIG. 1 is a schematic perspective view of the present invention;

FIG. 2 is a schematic view of the internal structure of a reaction vessel according to the present invention;

FIG. 3 is a schematic view of the internal structure of a reaction kettle according to the present invention;

FIG. 4 is a schematic cross-sectional view of the present invention;

FIG. 5 is a schematic diagram of the side view of the inside of the reaction vessel according to the present invention;

FIG. 6 is a schematic perspective view of a graphitization pot according to the present invention;

FIG. 7 is a schematic perspective view of a stirring blade according to the present invention;

FIG. 8 is a perspective view of a rotary plate according to the present invention;

FIG. 9 is an enlarged view of the structure at A in FIG. 8;

FIG. 10 is a schematic view of the transmission shaft and the transmission gear of the present invention;

FIG. 11 is a perspective view of the outer ring gear of the present invention;

FIG. 12 is a schematic cross-sectional view of an exhaust pipe according to the present invention;

FIG. 13 is a perspective view of the exhaust valve of the present invention;

FIG. 14 is a perspective view of a coating platform according to the present invention;

FIG. 15 is a perspective view of the toggle sweeping mechanism of the present invention;

FIG. 16 is a schematic cross-sectional view of an elastic telescopic positioning rod according to the present invention.

Detailed Description

The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

In the description of the present invention, it is to be understood that the terms "center", "longitudinal", "lateral", "length", "width", "thickness", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer", "clockwise", "counterclockwise", and the like, indicate orientations and positional relationships based on those shown in the drawings, and are used only for convenience of description and simplicity of description, and do not indicate or imply that the equipment or element being referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus, should not be considered as limiting the present invention.

Furthermore, the terms "first", "second" and "first" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defined as "first" or "second" may explicitly or implicitly include one or more of that feature. In the description of the present invention, "a plurality" means two or more unless specifically defined otherwise.

The first embodiment is as follows:

as shown in fig. 1 to 9, a preparation apparatus for a SiC coating for enhancing oxidation resistance of a graphite material includes:

the reactor comprises a reaction kettle 1, wherein a lifting hatch 11 is arranged at the top of the reaction kettle 1, a hatch 12 which is opened in a rotating manner and a gas transmission pipeline 13 for introducing Ar gas into the reaction kettle 1 are arranged in the middle of the reaction kettle 1, and a heater for heating is arranged in the reaction kettle 1;

a reaction tank 2, wherein the reaction tank 2 is arranged at the lower part of the reaction kettle 1, and Si and Al which are used for containing the mixture ratio are arranged in the reaction tank 2₂O₃A cavity 21 for the powder mixture of (a);

the stirring mechanism 3 is arranged at the bottom of the reaction tank 2, and is used for stirring the substances in the accommodating cavity 21;

the coating platform 4 is arranged right above the reaction tank 2, the coating platform 4 is used for placing a graphite workpiece 10 to be coated, the coating platform 4 gradually descends along the vertical direction to be close to the reaction tank 2 in the coating process of the graphite workpiece 10, and a plurality of rolling balls 40 are embedded in the contact part of the coating platform 4 and the graphite workpiece 10;

the exhaust mechanism 5 is installed at the top of the reaction tank 2, and comprises a sealing cover 51 for covering and sealing the reaction tank 2 and a gas transmission assembly 52 for communicating the coating platform 4 with the cavity 21, wherein the gas transmission assembly 52 transmits the SiO gas in the cavity 21 to the graphite workpiece 10;

the driving mechanism 6 is mounted on the reaction kettle 1, synchronously drives the stirring mechanism 3, the coating platform 4 and the exhaust mechanism 5 to work, and comprises a driving component 61 and a linkage component 62, wherein the driving component 61 is in transmission connection with the stirring mechanism 3, and the driving component 61 is in transmission connection with the coating platform 4 and the exhaust mechanism 5 through the linkage component 62 respectively; and

the stirring cleaning mechanism 7 is arranged on the coating platform 4, the stirring cleaning mechanism 7 is used for stirring the graphite workpiece 10 to rotate on the coating platform 4, and the stirring cleaning mechanism 7 is used for cleaning the surface of the graphite workpiece 10 in the coating process of the graphite workpiece 10.

The stirring mechanism 3 includes a stirring blade 31 and a rotating disk 32, the stirring blade 31 is rotatably installed in the graphitizing tank 2, the rotating shaft 311 thereon penetrates through the bottom of the graphitizing tank 2 and is disposed outside the graphitizing tank 2, the bottom of the rotating shaft 311 is provided with a cross groove 312, the rotating disk 32 is driven by the driving component 61 to be rotatably installed in the reaction kettle 1 and is located below the graphitizing tank 2, a butt joint shaft 321 coaxially disposed with the rotating shaft 311 is disposed thereon, and a quincunx head 322 correspondingly engaged with the cross groove 312 is disposed at the top of the butt joint shaft 321.

In the beginning, the stirring blade 31 is used for the reaction between Si and Al₂O₃The powder mixture of (1) is stirred to accelerate the mixing of Si and Al₂O₃The reaction rate of the powder mixture of (1) and ensuring Si and Al₂O₃And the invention realizes the quick transmission connection of the stirring paddle 31 and the rotating disk 32 through the quick butt joint of the rotating shaft 311 and the butt joint shaft 321.

It is to be emphasized that Si and Al₂O₃Reaction to form SiO₂Gas, then at high temperature, to make SiO₂Reacting with Si to generate SiO gas, wherein the reaction conditions are 2230 ℃, and Si: melting point 1414 ℃ and boiling point 2900 ℃; al (Al)₂O₃: melting point 2303 deg.C, boiling point 3250 deg.C; SiO 2₂: melting point 1650 deg.C, boiling point 2230 deg.C; al: melting point is 660 ℃; boiling point 2327 ℃, SiO: melting point 1702 ℃ and boiling point 1880 ℃, so that at a high temperature of 2230 ℃, only Al is present in the reaction system₂O₃Solid, Si liquid and Al liquid, and SiO₂And SiO are both gases.

Further, the graphitization tank 2 is supported by a bracket 20 provided in the reaction vessel 1, and is mounted on the bracket 20 after the graphitization tank 2 enters the reaction vessel 1 through the port 12.

It is further explained that the hatch 11, the coating platform 4 and the sealing cover 51 are connected into a whole, when the hatch 11 is driven to lift by the hydraulic system 111 externally arranged outside the reaction kettle 1, the coating platform 4 and the sealing cover 51 are also lifted synchronously, and the lifting assembly 41 for driving the coating platform 4 to lift is also arranged on the hatch 11.

As shown in fig. 2 to 6, as a preferred embodiment, the lifting assembly 41 includes:

an outer gear ring 411, wherein the outer gear ring 411 is rotatably mounted on the hatch 11 and is driven to rotate by the driving assembly 61 through the linkage assembly 62;

a plurality of rotary gears 412, which are arranged inside the outer ring gear 411 at equal intervals along the circumferential circumference of the outer ring gear 411 and are meshed with the internal teeth 413 on the outer ring gear 411;

the screw rods 414 are arranged in one-to-one correspondence with the rotary gears 412, the tops of the screw rods 414 are rotatably mounted on the hatch cover 11, and the bottoms of the screw rods 414 are rotatably mounted on the cover 51; and

the lead screw nut 415 is sleeved on the corresponding lead screw 414 and is installed on the coating platform 4, and the lead screw 414 rotates to drive the coating platform 4 to move through the lead screw nut 415.

Further, the internal teeth 413 on the outer ring gear 411 are arranged in a missing tooth manner, and the internal teeth 413 are divided into a plurality of tooth portions 4131 which are arranged at equal intervals along the circumferential direction of the outer ring gear 411.

Si and Al in the graphitization tank 2₂O₃After the powder mixture completely reacts to generate SiO gas, in the process of coating the graphite workpiece 10 by the SiO gas, in order to avoid the influence of waste gas CO generated by the reaction on the coating of the graphite workpiece 10, the driving mechanism 6 drives the outer gear ring 411 to rotate, the lead screw 414 matched with the outer gear ring 41 through the rotating gear 412 rotates, the coating platform 4 moves downwards by virtue of the lead screw nut 415 and is gradually close to the graphitization tank 2, and the coating platform 4 moves by virtue of the movement of the coating platform 4, so that the graphite workpiece 10 is coated by the SiO gasThe gas flow is formed, and the influence of waste gas is avoided.

Further, in order to better coat the graphite workpiece 10, after the coating platform 4 descends for a certain distance, the coating platform 4 stops for a certain time, so that the graphite workpiece 10 performs a coating reaction, and in the second step, the graphite workpiece 10 continues to move downwards after reacting for a certain time, and the reaction is repeated, so that the coating reaction effect of the graphite workpiece 10 is ensured, and the interference of waste gas CO is avoided.

As shown in fig. 14, as a preferred embodiment, a material rest 42 for supporting the graphite workpiece 10 is disposed at a central line position of the coating platform 4, a hollow hole 421 is disposed on the material rest 42, and a plurality of air holes 43 are uniformly distributed at a position of the coating platform 4 facing the material rest 42.

It should be noted that the coating platform 4 is provided with the hollow holes 421, and the hollow holes 421 enable the local position of the lower end face of the graphite workpiece 10 to be coated first, and in the subsequent process, the support points are used for lifting, so that the problem that the bottom end face of the graphite workpiece 10 cannot be coated comprehensively can be effectively solved.

As shown in fig. 12 and 13, in a preferred embodiment, the gas delivery assembly 52 includes a gas exhaust pipe 521 and a gas exhaust hood 522, the gas exhaust pipe 521 is disposed between the coating platform 4 and the cap 51 and includes a steel pipe portion 5211 and a hose portion 5212, and the gas exhaust hood 522 is disposed in a funnel shape, covers the graphite workpiece 10, and is connected to the hose portion 5212.

Further, an exhaust valve 53 is disposed at a connection position of the steel pipe portion 5211 and the hose portion 5212, the exhaust valve 53 is rotatably sleeved on the steel pipe portion 5211, a valve closing plate 531 is disposed in the exhaust valve 53, and a valve compensation closing plate 532 matched with the valve closing plate 531 is disposed on the steel pipe portion 5211.

The lid 51 closes the top opening of the graphitization tank 2, so that Si and Al in the graphitization tank 2 are mixed₂O₃The chamber 21 in the graphitization pot 2 is a closed space when the powder mixture is reacted, and after the reaction is completed, the silicon oxide gas needs to be discharged, and at this time, the silicon oxide gas needs to be dischargedThe air pipe 521 is opened, and the valve closing plate 531 rotates in a staggered manner relative to the valve compensation closing plate 532 by means of rotation of the exhaust valve 53, so that the exhaust pipe 521 is opened.

It is further explained that the rotation of the exhaust valve 53 is realized by the cooperation of the driving assembly 61 and the linkage assembly 62, when the reaction is performed in the interior of the graphitization tank 2 to generate the silicon oxide gas, the driving assembly 61 and the linkage assembly 62 are not matched, the exhaust pipe 521 cannot be opened, and the Si and Al in the interior of the graphitization tank 2 are ensured₂O₃The reaction environment of the powder mixture of (1) is stable.

As shown in fig. 7, as a preferred embodiment, the driving assembly 61 includes:

the motor 611, the said motor 611 is mounted to the bottom of the said reaction vessel 1;

a main shaft 612, wherein the main shaft 612 is vertically installed in the reaction kettle 1 and is driven by the motor 611 to rotate; and

a set of drive sprockets 613, the set of drive sprockets 613 being mounted between the main shaft 612 and the rotating disk 32, which drive the rotating disk 32 to rotate with the main shaft 612.

As further shown in fig. 5 and 7, the linkage assembly 62 includes:

a lifting ring 621, which is provided along the circumferential direction of the rotating disk 32, and includes a convex lifting portion 6211 and a concave settling portion 6212;

the transmission shaft 622 is vertically and rotatably mounted on the hatch 11, can be adjusted in an up-and-down manner along the axial direction, and is slidably arranged on the lifting ring 621 in an abutting manner at the bottom of the transmission shaft 622;

a driving gear 623, wherein the driving gear 623 is mounted at the top of the main shaft 612;

a transmission gear 624, wherein the transmission gear 624 is installed on the top of the transmission shaft 622, and when the transmission shaft 622 collides with the lifting part 6211, the transmission gear 624 is meshed with the driving gear 623 and the external teeth 4112 on the external gear ring 411 respectively; and

the transmission chain wheel 625 is rotatably mounted in the middle of the transmission shaft 622 and is arranged statically in the vertical direction relative to the transmission shaft 622, and when the transmission shaft 622 is lifted, a key 6221 on the transmission chain wheel 625 is inserted and matched with a key groove 6251 on the transmission chain wheel 625;

the rotating chain wheel 626 is sleeved on the exhaust valve 53, and is connected with the transmission chain wheel 625 through a transmission chain 627.

It should be noted that the motor 611 drives the main shaft 612 to rotate, the main shaft drives the rotating disc 32 to rotate through the driving chain wheel set 613, the rotating disc 32 drives the stirring blade 31 to rotate, and it is noted that the lifting ring 621 mounted on the rotating disc 32 rotates synchronously with the rotating disc 32, at the stage when the graphitization tank 2 is sealed to react to generate the silicon oxide gas, the settling portion 6212 on the lifting ring 621 collides with the bottom of the transmission shaft 622, the transmission gear 624 is separated from the driving gear 623, at this time, the driving assembly 61 and the linkage assembly 62 are in a separated state, and after the reaction in the graphitization tank 2 is completed, the lifting portion 6211 on the lifting ring 621 collides with the bottom of the transmission shaft 622, the transmission gear 624 is meshed with the driving gear 623, and the transmission gear 624 is meshed with the external teeth 4112 on the external teeth ring 411, and the external teeth 411 are driven to rotate, the lowering of the coating platform 4 is also achieved.

It is further noted that, synchronously, after the transmission shaft 622 is lifted, the key 6221 on the transmission shaft 622 is inserted and matched with the key groove 6251 on the transmission chain wheel 625, so that the transmission chain wheel 625 rotates, the exhaust valve 53 rotates through the matching of the rotating chain wheel 626 and the transmission chain 627, and the silicon oxide gas in the graphitization tank 2 is continuously discharged through the stirring of the stirring blade 31.

It should be emphasized that, by the arrangement of the lifting ring 621 and the linkage assembly 62, the tight connection from the reaction stage to the exhaust stage of the silicon oxide gas in the graphitization tank 2 is realized, and at the same time, the lowering of the coating platform is performed synchronously with the exhaust of the silicon oxide gas.

As shown in fig. 14 to 16, as a preferred embodiment, the toggle sweeping mechanism 7 includes:

the rotating sleeves 71 are rotatably sleeved on the corresponding screw rods 414, two groups of the rotating sleeves 71 are arranged, and the rotating sleeves 71 are in friction contact with the graphite workpiece 10 to drive the graphite workpiece 10 to rotate;

the rotary driving groups 72 are arranged corresponding to the rotary sleeves 71 one by one, and the rotary driving groups 72 drive the rotary sleeves 71 to rotate along with the lifting of the coating platform 4;

the bottom cleaning brush 73 is arranged on the top end face of the material rack 42, and the bottom cleaning brush 73 is used for cleaning the bottom end face of the graphite workpiece 10;

a side wall cleaning brush 74, wherein the side wall cleaning brush 74 is installed at one side of the graphite workpiece 10, and the side wall cleaning brush 74 cleans the side wall of the graphite workpiece 10;

a top cleaning brush 75, wherein the top cleaning brush 75 is arranged on the top of the graphite workpiece 10, and the top cleaning brush 75 cleans the top end surface of the graphite workpiece 10; and

the clamping rollers 76 and the two sets of the rotating sleeves 71 are arranged in a triangular mode, the clamping rollers 76 press the graphite workpiece 10 to abut against the rotating sleeves 71 by means of the compression elastic force of the spring pieces 78 arranged on the bottom sliding seats 77, the clamping rollers 76 and the sliding seats 77 are arranged in a relatively rotating mode, and the sliding seats 77 are arranged in a sliding mode along sliding rails 79 arranged on the coating platform 4.

Further, the rotary drive group 72 includes:

a driven bevel gear 721, the driven bevel gear 721 being installed on the top of the rotating sleeve 71;

a drive bevel gear 722, the drive bevel gear 722 being rotatably mounted on one side of the driven bevel gear 721 via a mounting vertical plate 723, the drive bevel gear 722 being engaged with the driven bevel gear 721;

a starting gear 724, the starting gear 724 and the drive bevel gear 722 are coaxially arranged and are mounted on the mounting vertical plate 723, and the starting gear 724 drives the drive bevel gear 722 to rotate; and

a starting rack 725, wherein the starting rack 725 is vertically installed above the reaction tank 2, and the starting rack 725 is penetrated through the coating platform 4 and is engaged with the starting gear 724.

It should be noted that, the coating platform 4 descends to drive the starting gear 724 to cooperate with the starting rack 725, so that the driving bevel gear 722 rotates to drive the driven bevel gear 721 to rotate, so that the rotating sleeve 71 rotates, when the early rotating sleeve rotates, the graphite workpiece 10 rotates on the coating platform 4 through the balls 40, so that the bottom side of the graphite workpiece 10 is rotated and switched in real time, the bottom side of the graphite workpiece 10 obtains a complete and uniform coating, meanwhile, the graphite workpiece 10 rotates, in the coating process, the graphite workpiece 10 is in contact with the Si0 gas more uniformly, and the surface of the graphite workpiece 10 is also coated more uniformly.

Further, in the process of coating the graphite workpiece 10, the graphite workpiece is continuously cleaned in the coating process by matching the bottom cleaning brush, the side wall cleaning brush and the top cleaning brush, so that the surface of the graphite workpiece can be always kept clean, attachments on the surface of the graphite workpiece can be quickly removed by cleaning, the surface cleaning and the coating uniformity of the graphite workpiece are ensured, and the firmness of the coating on the surface of the graphite workpiece can be effectively ensured by cleaning.

In addition, the clamping roller 76 can be subjected to tightness adjustment, after the graphite workpiece 10 is mounted on the graphite workpiece 10, the clamping roller 76 is compressed by the spring piece 78 to tightly push the graphite workpiece 10 in an included angle of the rotating sleeve 71, so that the graphite workpiece 10 can rotate along with the rotation of the rotating sleeve 71, when the graphite workpiece 10 is removed from the coating platform 4, the spring piece 78 is compressed by the backward removal of the clamping roller 76, so that the graphite workpiece 10 can be smoothly removed from the coating platform 4, and the clamping roller 76 can be positioned and fixed by the matching of the hand-holding rods 771 arranged on two sides of the sliding seat 77 and the elastic telescopic positioning rod 772, wherein the elastic positioning rod 772 is composed of a positioning seat 7721, a telescopic head 7722 and a telescopic elastic element 7723, the telescopic head 7722 is slidably arranged in the positioning seat 7721, and the telescopic element 7723 is arranged between the positioning seat 7721 and the telescopic head 7722 in a butting manner.

The working process is as follows:

the method comprises the following steps:

firstly, weighing powder, namely calculating and weighing Si and Al according to the coating area of the graphite workpiece 10₂O₃The powder is fully mixed, and the mixed powder is placed in the cavity 21 in the graphitizing tank 2;

step two, loading a graphitizing tank, opening a hatch door 12 on a reaction kettle 1, transferring the graphitizing tank 2 added with powder into the reaction kettle 1, enabling a rotating shaft 311 of a stirring blade 31 on a stirring mechanism 3 at the bottom of the graphitizing tank 2 to be in inserted butt joint with a butt joint shaft 321 on a rotating disc 32 arranged at the bottom of the reaction kettle 1, and closing the hatch door 12;

sealing, namely after placing the graphite workpiece 10 to be coated on the coating platform 4, descending the hatch 11 at the top of the reaction kettle 1 to drive the graphite workpiece 10 to enter the reaction kettle 1, sealing the reaction kettle 1, synchronously descending the seal cover 51 connected with the hatch 11, and sealing the top of the graphitization tank 2;

step four, reacting, namely heating the reaction kettle 1 by a heater on the inner wall of the reaction kettle 1, synchronously introducing Ar gas into the reaction kettle 1 through a gas transmission pipeline 13 on the reaction kettle 1, and introducing Si and Al in the graphitization tank 2₂O₃The powder reacts under the stirring of the stirring paddle 31 driven by the driving component 61 to generate Si0 gas;

step five, blowing air and exhausting air, wherein a lifting part 6211 on a lifting ring 621 synchronously rotating along with the stirring blade 31 is abutted against a transmission shaft 622 in a linkage assembly 62, so that the linkage assembly 62 is in transmission connection with a driving assembly 61 and is used for connecting the graphitization tank 2 with an exhaust valve 53 in an exhaust mechanism 5 of the coating platform 4 to be started, and under the rotation of the stirring blade 31, Si0 gas in the graphitization tank 2 is conveyed to the graphite workpiece 10 through an exhaust pipe 521 in the exhaust mechanism 5;

sixthly, coating, namely reacting Si0 gas discharged to the graphite workpiece 10 with the surface layer of the graphite workpiece 10 to form a SiC coating to wrap the graphite workpiece 10 and simultaneously form CO waste gas;

step seven, the platform descends, and in synchronization with the step four, the driving assembly 61 drives the lifting assembly 41 for driving the coating platform 4 to ascend and descend through the linkage assembly 62, and the coating platform 4 gradually approaches the graphitizing tank 2 to drive the graphite workpiece 10 to be separated from the package of the CO waste gas;

step eight, rotating the workpiece, wherein in a synchronous manner with the step seven, in the process of descending the coating platform 4, the starting gear 724 synchronously descending along with the coating platform 4 is matched with the starting rack 725, so that the starting gear 724 rotates, the rotating sleeve 71 rotates in a manner of matching with the transmission of the driving bevel gear 722 and the driven bevel gear 721, the graphite workpiece 10 is driven to rotate automatically through the rotation of the rotating sleeve 71, and the surface layer of the graphite improved workpiece 10 is cleaned in a manner of matching with the arrangement of the bottom cleaning brush 73, the side wall cleaning brush 74 and the top cleaning brush 75;

and step nine, resetting and outputting, wherein after the graphite workpiece 10 finishes coating, the driving assembly 61 rotates reversely, the coating platform 4 is lifted and reset through the linkage assembly 62, and after the reaction kettle 1 is cooled to the natural temperature, the graphite workpiece 10 is output.

The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents and improvements made within the spirit and principle of the present invention are intended to be included within the scope of the present invention.