Fabry-Perot cavity filter and method for dynamic color regulation
阅读说明:本技术 用于动态色彩调控的法布里-珀罗腔滤波器及方法 (Fabry-Perot cavity filter and method for dynamic color regulation ) 是由 蒋向东 李明成 许文瑞 王继岷 李伟 于 2020-07-23 设计创作,主要内容包括:本发明提供一种用于动态色彩调控的法布里-珀罗腔滤波器及制备方法和调谐方法,从上至下依次包括第一层金属薄膜层、第二层非导电电介质层、第三层透明导电氧化物层、第四层金属层、第五层衬底层;所述第二层非导电电介质层作为阻挡层阻挡介电常数趋于0的材料发生电化学金属化后的金属离子迁移;所述第三层透明导电氧化物层为介电常数趋于0的材料,在电场作用下能实现折射率的改变,从而调节法布里-珀罗腔腔体的折射率;本发明基于ECM效应实现ENZ材料的有效折射率的改变,从而改变FP腔的共振波长,能有效解决上述问题,并且能够在撤去电压的同时,完成对共振条件的记忆。(The invention provides a Fabry-Perot cavity filter for dynamic color regulation and control, a preparation method and a tuning method, which sequentially comprise a first metal film layer, a second non-conductive dielectric layer, a third transparent conductive oxide layer, a fourth metal layer and a fifth substrate layer from top to bottom; the second non-conductive dielectric layer is used as a barrier layer to block metal ion migration of a material with a dielectric constant of being close to 0 after electrochemical metallization; the third transparent conductive oxide layer is made of a material with a dielectric constant of 0, and the refractive index can be changed under the action of an electric field, so that the refractive index of the Fabry-Perot cavity body is adjusted; the invention realizes the change of the effective refractive index of the ENZ material based on the ECM effect, thereby changing the resonance wavelength of the FP cavity, effectively solving the problems and completing the memory of the resonance condition while removing the voltage.)
1. A Fabry-Perot cavity filter for dynamic color tuning, comprising: the multilayer composite film sequentially comprises a first metal film layer (11), a second non-conductive dielectric layer (12), a third transparent conductive oxide layer (13), a fourth metal layer (14) and a fifth substrate layer (15) from top to bottom;
the first metal film layer (11) is used for introducing incident light into the Fabry-Perot cavity and is used as an upper metal layer in a metal-insulator-metal structure of the Fabry-Perot cavity;
the second non-conductive dielectric layer (12) is an intermediate dielectric layer in a metal-insulator-metal structure of a Fabry-Perot cavity and is used as a barrier layer for blocking metal ion migration after electrochemical metallization of a material with a dielectric constant of about 0;
the third transparent conductive oxide layer (13) is made of a material with a dielectric constant of 0, and the refractive index can be changed under the action of an electric field, so that the refractive index of the Fabry-Perot cavity is adjusted;
the fourth metal layer (14) is used as a lower metal layer in a Fabry-Perot cavity metal-insulator-metal structure;
the bottom is a fifth layer substrate layer (15), on which the structure is prepared;
meanwhile, a memristor unit is formed by a first metal thin film layer (11), a second non-conductive dielectric layer (12), a third transparent conductive oxide layer (13) and a fourth metal layer (14), wherein the first metal thin film layer (11) is used as a first electrode, the fourth metal layer is used as a second electrode (14), the first metal thin film layer (11) and the second non-conductive dielectric layer (12) form a mutually-perpendicular crossed array structure, the second non-conductive dielectric layer (12) and the third transparent conductive oxide layer (13) form a mutually-perpendicular crossed array structure, the first electrode is electrically connected with the second electrode, voltage is applied to the memristor unit to complete regulation and control of the refractive index, the voltage is removed, and the refractive index completes memory.
2. The fabry-perot cavity filter for dynamic color manipulation of claim 1, wherein: the first metal film layer (11) is made of Au, the thickness of the Au film ensures that incident light can penetrate through the Au film to enter the FP cavity, and the thickness of the Au film is 15-30 nm.
3. The fabry-perot cavity filter for dynamic color manipulation of claim 1, wherein: the second non-conductive dielectric layer (12) is a titanium dioxide layer, TiO2TiO as non-conductive dielectric to form an electric field in the memristive cell2The layer thickness is 50-100 nm.
4. The fabry-perot cavity filter for dynamic color manipulation of claim 1, wherein: the third transparent conductive oxide layer (13) is a silicon dioxide silver-doped film layer, SiO2The preset volume fraction of Ag is 90%, the silicon dioxide silver-doped thin film layer exists in the area of the real part of dielectric constant area 0, and the thickness of the silicon dioxide silver-doped thin film layer is 75-150 nm.
5. The fabry-perot cavity filter for dynamic color manipulation of claim 1, wherein: the fourth metal layer (14) is an Au layer, and the thickness of the Au layer is 200-300 nm.
6. The fabry-perot cavity filter for dynamic color manipulation of claim 1, wherein: the fifth layer substrate layer (15) is a Si substrate layer, and the thickness of the fifth layer substrate layer is 15 mm.
7. The method of any of claims 1 to 6 for preparing a Fabry-Perot cavity filter for dynamic color tuning, comprising the steps of:
(1) depositing an Au film on the fifth substrate layer (15) by using a direct-current magnetron sputtering mode;
(2) depositing a silicon dioxide silver-doped transparent conductive film on the fourth metal layer (14) by using a radio frequency magnetron co-sputtering mode, and patterning the layer of material by using a mask;
(3) depositing TiO on the third transparent conductive oxide layer (13) by using a direct current magnetron sputtering mode2Patterning the layer of material by using a mask;
(4) and depositing an Ag film on the second non-conductive dielectric layer (12) by using a direct current magnetron sputtering method, and patterning the material of the layer by using a mask to form an electrode.
8. The method of tuning the resonance wavelength and the resonance intensity of a fabry-perot cavity filter for dynamic color tuning of any of claims 1 to 6, characterized by the steps of:
filter pair x when no voltage is applied1The wavelength has strong absorption and presents a color, a positive voltage is applied to a fourth metal layer (14) through a voltage device, Ag atoms in a third transparent conductive oxide layer (13) can be electrochemically metalized, Ag is pre-embedded in the third transparent conductive oxide layer, adjacent Ag clusters are equivalent to two electrodes, the Ag atoms can form Ag nanowires between the Ag clusters through oxidation-reduction reaction, the effective refractive index of the third transparent conductive oxide layer is changed, the Ag nanowires near the interface of a second non-conductive dielectric layer and the third transparent conductive oxide layer can be blocked at the interface to form an Ag layer, and the refractive index of the third transparent conductive oxide layer is changed along with the formation of the Ag nanowires at the moment, so that the Ag nanowire layer can be used for x2The wavelength has strong absorption and shows b color; as the positive voltage is further applied to the fourth metal layer, Ag nano-wires in the third transparent conductive oxide layer are further formed, the refractive index is continuously changed, and the x is subjected to the positive voltage3The wavelength has strong absorption and shows c color;
the first metal film layer (11) is applied with positive voltage through a voltage device, Ag atoms continue to generate electrochemical metallization effect, Ag nano wires of the third transparent conductive oxide layer start to be gradually broken, the refractive index changes, and x is subjected to2The wavelength has strong absorption and shows b color, as a positive voltage is further applied to the first metal film layer (11), Ag wires formed in the third transparent conductive oxide layer are completely broken, the refractive index returns to the initial value, and the color of the third transparent conductive oxide layer is x1The wavelength has strong absorption and exhibits a color.
Technical Field
The invention belongs to the technical field of display, and particularly relates to a Fabry-Perot cavity filter for dynamic color regulation and control, and a preparation method and a tuning method thereof.
Background
In the field of display technology, plasma structures can be used to generate different colors, but once the structures are determined, the generated colors are fixed. The plasma structure has the characteristics of thin structure, stability, high resolution and the like in the display technology. How to dynamically adjust the color of the plasma is a hotspot of current research, most of the ideas of dynamic adjustment are to change the structure of the plasma so as to adjust the intensity or wavelength of the plasma, and the current main regulation and control mode is mainly based on: direct electrochemical control, reversible electrochemical deposition, polarization control, a pullable embedded structure, a phase change material, and electromechanical control of the distance between two metals of a fabry-perot (FP) cavity. The invention mainly realizes the dynamic adjustment of colors based on the FP cavity.
FP cavities are typically a special optical structure formed by two high reflectivity metal layers and an intermediate layer cavity. Incident light beams can generate a multi-beam interference effect in the cavity, light waves meeting the phase matching condition can generate resonance, and the resonance wavelength is related to the cavity length and the cavity refractive index.
However, most FP cavities choose to adjust the resonant wavelength by adjusting the cavity length in two main ways: the first is to prepare FP cavities of different cavity lengths, but this does not allow for a truly dynamic adjustment, and the second is to electrostatically adjust the distance between the two metal plates, but such devices are expensive to manufacture and complex to manufacture, and the mechanical device lifetime decreases with time.
The FP cavity that changes the resonance wavelength by changing the cavity refractive index is reported, and the reason for this is because the refractive index of the material that can be used as the FP cavity is not easily changed. The material with the dielectric constant tending to 0 (Epsilon-near-zero) ENZ material refers to the material with the real part of the dielectric constant tending to 0 in a specific wavelength interval. Based on the change Δ n of the refractive index of the material being Δ/2(2 √), a large change in the refractive index can be obtained with a theoretically limited change in the dielectric constant when the value approaches 0. The metal ions in the ENZ material under bias, due to the electrochemical metallization (ECM) occurring, also enable dynamic adjustment and memory of the refractive index. Therefore, based on the technology, the FP cavity based on the ENZ material is designed, and the function of dynamically regulating and controlling the color can be realized by changing the resonance wavelength.
Disclosure of Invention
Aiming at the problem that the length of the Fabry-Perot (FP) cavity is adjusted to adjust the resonance wavelength and the resonance intensity, the invention provides the FP cavity which uses a material (ENZ material) with a dielectric constant of being close to 0 as a cavity material, the resonance wavelength and the resonance intensity are adjusted by dynamically adjusting the refractive index of the ENZ material by applying voltage so as to achieve the purpose of adjusting color, and the memory of the color is completed after the voltage is removed.
In order to achieve the purpose, the technical scheme of the invention is as follows:
a Fabry-Perot cavity filter for dynamic color regulation comprises a first
the first metal
the second non-conductive dielectric layer is used as an intermediate
the third transparent
the
the bottom is a fifth
meanwhile, a first metal
Preferably, the first metal
Preferably, the second non-conductive
Preferably, the third transparent
Preferably, the
Preferably, the fifth
In order to achieve the above object, the present invention further provides a method for preparing a fabry-perot cavity filter for dynamic color control, comprising the following steps:
(1) depositing an Au film on the
(2) depositing a silicon dioxide silver-doped transparent conductive film on the
(3) depositing TiO2 on the third transparent
(4) depositing an Ag film on the second non-conductive
In order to achieve the above object, the present invention further provides a method for tuning the resonance wavelength and the resonance intensity of the fabry-perot cavity filter for dynamic color control, comprising the following steps:
filter pair x when no voltage is applied1The wavelength has strong absorption and presents a color, a positive voltage is applied to the
applying positive voltage to the first
The invention has the beneficial effects that: most reports about the dynamic adjustment of the FP cavity currently adjust the resonance mode of the FP cavity by electromechanically controlling the thickness of the cavity between two metal plates, but this kind of FP cavity has mechanical loss, and the change of the cavity length inevitably causes the design problem of the device structure. The invention realizes the change of the effective refractive index of the ENZ material based on the ECM effect, thereby changing the resonance wavelength of the FP cavity, effectively solving the problems and completing the memory of the resonance condition while removing the voltage.
Drawings
FIG. 1 is a schematic perspective view of the present invention;
FIG. 2 is a top view of the structure provided by the present invention;
FIG. 3 is a schematic structural diagram of a voltage modulation unit according to the present invention;
FIG. 4 is a schematic diagram of a voltage modulation process according to the present invention;
FIG. 5 is a diagram of simulation results of the present invention.
1 is a Fabry-Perot cavity; 2 is an Ag accumulation layer, and 11 is a first metal film layer; 12 is a second non-conductive dielectric layer; 13 is a third transparent conductive oxide layer; 14 is a fourth metal layer; 15 is a fifth substrate layer;
Detailed Description
The embodiments of the present invention are described below with reference to specific embodiments, and other advantages and effects of the present invention will be easily understood by those skilled in the art from the disclosure of the present specification. The invention is capable of other and different embodiments and of being practiced or of being carried out in various ways, and its several details are capable of modification in various respects, all without departing from the spirit and scope of the present invention.
A Fabry-Perot cavity filter for dynamic color regulation comprises a first
the first metal
the second non-conductive dielectric layer is used as an intermediate
the third transparent
the
the bottom is a fifth
meanwhile, a first metal
The first
The second non-conductive
The third transparent
The
The fifth
The embodiment also provides a method for preparing the fabry-perot cavity filter for dynamic color control, which comprises the following steps:
(1) depositing an Au film on the
(2) depositing a silicon dioxide silver-doped transparent conductive film on the
(3) depositing TiO2 on the third transparent
(4) depositing an Ag film on the second
The embodiment further provides a method for tuning the resonance wavelength and the resonance intensity of the fabry-perot cavity filter for dynamic color control, which includes the following steps:
filter pair x when no voltage is applied1The wavelength has strong absorption and presents a color, a positive voltage is applied to the
applying positive voltage to the first
Specifically, in this embodiment, as shown in fig. 1 and fig. 2, each device may be regarded as a plurality of FP cavity control units through the structural design of the cross array (cross array) perpendicular to each other, and different control units can achieve different adjustment effects, so as to achieve control over the entire adjustment effect, and meanwhile, the cross array (cross array) structure can ensure that the ohmic contact is sufficiently small.
As shown in fig. 3, the FP cavity control unit includes a first metal
As shown in fig. 4, the voltage modulated effective refractive index occurs primarily between the second
Fig. 5 shows the simulation result of FDTD (time domain effective difference method) according to the present invention, where the incident light is vertical.
When no positive voltage is applied to the FP cavity control unit, the Ag nanowire is not formed in the third transparent
When the FP cavity control unit initially applies a positive voltage, Ag nanowires of the third transparent
When the FP cavity control unit further applied a positive voltage, Ag nanowires of the third transparent
When the FP cavity control unit further applies a positive voltage, the Ag nanowire of the third transparent
When the FP chamber control unit applies negative voltage, the Ag nano-wires of the third transparent
The foregoing embodiments are merely illustrative of the principles and utilities of the present invention and are not intended to limit the invention. Any person skilled in the art can modify or change the above-mentioned embodiments without departing from the spirit and scope of the present invention. Accordingly, it is intended that all equivalent modifications or changes which can be made by those skilled in the art without departing from the spirit and technical spirit of the present invention be covered by the claims of the present invention.
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