Method for manufacturing imprint mold
阅读说明:本技术 压印模具制造方法 (Method for manufacturing imprint mold ) 是由 黄胜铭 林圣凱 陈志强 张晖谷 鍾佳欣 王潍淇 王铭瑞 吕仁贵 罗再昇 沈煌凱 于 2017-12-12 设计创作,主要内容包括:本发明提供一种压印模具制造方法。压印模具制造方法,包含:设置模具图案层于基材上;于模具图案层上设置第一硬掩膜层,第一硬掩膜层具有一个或多个第一镂空区域;在模具图案层形成第一模具图案,第一模具图案的范围与第一镂空区域于模具图案层的垂直投影范围完全重迭;去除第一硬掩膜层;于模具图案层上设置第二硬掩膜层,第二硬掩膜层具有一个或多个第二镂空区域,第二镂空区域于模具图案层的垂直投影范围与第一模具图案相邻接;在模具图案层形成第二模具图案,第二模具图案的范围与第二镂空区域于模具图案层的垂直投影范围完全重迭;去除第二硬掩膜层。(The invention provides a manufacturing method of an imprinting mold. An imprint mold manufacturing method, comprising: arranging a mold pattern layer on a base material; arranging a first hard mask layer on the mold pattern layer, wherein the first hard mask layer is provided with one or more first hollow areas; forming a first mold pattern on the mold pattern layer, wherein the range of the first mold pattern is completely overlapped with the vertical projection range of the first hollow area on the mold pattern layer; removing the first hard mask layer; arranging a second hard mask layer on the mold pattern layer, wherein the second hard mask layer is provided with one or more second hollow-out areas, and the vertical projection range of the second hollow-out areas on the mold pattern layer is adjacent to the first mold pattern; forming a second mold pattern on the mold pattern layer, wherein the range of the second mold pattern is completely overlapped with the vertical projection range of the second hollow area on the mold pattern layer; and removing the second hard mask layer.)
1. A method of fabricating an imprint mold, comprising:
step S1000: arranging a mold pattern layer on a base material;
step S2000: arranging a first hard mask layer on the mold pattern layer, wherein the first hard mask layer is provided with one or more first hollow areas;
step S3000: forming a first mold pattern on the mold pattern layer, wherein the range of the first mold pattern is completely overlapped with the vertical projection range of the first hollow area on the mold pattern layer;
step S4000: removing the first hard mask layer;
step S5000: arranging a second hard mask layer on the mold pattern layer, wherein the second hard mask layer is provided with one or more second hollow-out areas, and the vertical projection range of the second hollow-out area on the mold pattern layer is adjacent to the first mold pattern;
step S6000: forming a second mold pattern on the mold pattern layer, wherein the range of the second mold pattern is completely overlapped with the vertical projection range of the second hollow area on the mold pattern layer;
step S7000: and removing the second hard mask layer.
2. The method of claim 1, wherein the step S3000 comprises:
arranging a first imprinting photoresist layer on the first hard mask layer and the first hollow area;
imprinting a first imprinting area of the first imprinting photoresist layer to form a first imprinting pattern, wherein the vertical projection range of the first imprinting area on the first hard mask layer completely covers the range of the first hollow area;
the first imprint resist layer and the mold pattern layer are etched to form the first mold pattern on the mold pattern layer.
3. The method of claim 1, wherein the step S6000 comprises:
arranging a second imprinting photoresist layer on the second hard mask layer and the second hollow area;
imprinting a second imprinting area of the second imprinting photoresist layer to form a second imprinting pattern, wherein the vertical projection range of the second imprinting area on the second hard mask layer completely covers the range of the second hollow area;
the second imprint resist layer and the mold pattern layer are etched to form the second mold pattern in the mold pattern layer.
4. The method of claim 3, wherein the first and second imprinting areas are imprinted using the same master mold in the steps S3000 and S6000, respectively.
5. The method of claim 2, wherein the first imprint region of the first imprint photoresist layer is imprinted using contact exposure to form a residual photoresist layer and the first imprint pattern on the residual photoresist layer, wherein:
the first hard mask layer has a hard mask layer thickness HHM;
The residual photoresist layer has a residual photoresist layer thickness HRL;
HHM<HRL。
6. The imprint mold manufacturing method according to claim 2,
forming a residual photoresist layer and the first imprint pattern on the residual photoresist layer after imprinting the first imprint region of the first imprint photoresist layer, wherein:
the residual photoresist layer has a residual photoresist layer thickness HRL;
The first imprint pattern has a first height H1;
Etching the first imprint photoresist layer and the mold pattern layer until the residual photoresist layer is removed:
the first imprint pattern has a second height H2;
The first imprint resist layer has a top etch ratio E1;
The first imprint photoresist layer has a bottom etch rate E2;
Wherein HRL≦[(H1–(H2-H3))x(E2/E1)]。
7. The method of claim 2, wherein the first imprint region of the first imprint photoresist layer is imprinted to form a residual photoresist layer and the first imprint pattern on the residual photoresist layer, the first imprint pattern having a first height H1In which H is1Not more than three times the smaller of the line width of the first imprint pattern and the pitch width of the first imprint pattern.
8. The imprint mold manufacturing method according to claim 2,
forming a residual photoresist layer and the first imprint pattern on the residual photoresist layer after imprinting the first imprint region of the first imprint photoresist layer, wherein:
the mold pattern layer has a fourth height H4;
Etching the first imprint photoresist layer and the mold pattern layer until the residual photoresist layer is removed, wherein:
the first imprint pattern has a second height H2;
The top etch rate of the imprint photoresist layer is E1;
Etching the first imprint photoresist layer and the mold pattern layer to expose a portion of the substrate, wherein:
the first imprint pattern has a third height H3;
The etching rate of the mold pattern layer is E3;
Wherein (H)2-H3)=(E1x(H4/E3))。
9. The method of claim 1, wherein the step S3000 comprises:
arranging a first pattern photoresist layer on the first hard mask layer;
using a polydimethylsiloxane photomask to contact and expose a first imprinting area of the first pattern photoresist layer so as to form a first exposure pattern, wherein the vertical projection range of the first imprinting area on the first hard mask layer completely covers the range of the first hollow area;
the first patterned photoresist layer and the mold pattern layer are etched to form the first mold pattern on the mold pattern layer.
10. The method of claim 1, wherein the step S3000 comprises:
arranging a first pattern photoresist layer on the first hard mask layer;
exposing a first imprinting area of the first pattern photoresist layer through a photomask by using a UV interference principle to form a first exposure pattern, wherein the vertical projection range of the first imprinting area on the first hard mask layer completely covers the range of the first hollow area;
the first patterned photoresist layer and the mold pattern layer are etched to form the first mold pattern on the mold pattern layer.
11. The method of claim 1, wherein the step S3000 comprises:
arranging a first pattern photoresist layer on the first hard mask layer;
scanning and exposing a first imprinting area of the first pattern photoresist layer through a photomask by using a high-resolution electron beam to form a first exposure pattern, wherein the vertical projection range of the first imprinting area on the first hard mask layer completely covers the range of the first hollow area;
the first patterned photoresist layer and the mold pattern layer are etched to form the first mold pattern on the mold pattern layer.
Technical Field
The invention relates to a manufacturing method of an imprinting (imprint) mold.
Background
In the fabrication technology of a mold having a nanostructure pattern required by the nanoimprint lithography technology, an Electron Beam lithography (Electron Beam lithography) technology is commonly used in combination with an organic photoresist, so as to form the nanostructure pattern on a planar mold. However, the equipment cost for fabricating the nanostructure pattern using the electron beam lithography is high, the lithography fabrication technique is time-consuming and limited to less than 12 inches of wafer, and it is not favorable for fabricating a large-area mold with the nanostructure pattern.
Another method for preparing a large-area mold with a nano-structure pattern is to splice a plurality of small molds to form a large-area mold through a splicing process. One way is to prepare a plurality of small replica molds from a small master mold by photo-polymerization or the like, and to position the replica molds side by side as tiles or tiles to create a large area mold. However, when the small molds are closely arranged, the small molds are prone to have overlapping and breaking phenomena, so that when the small molds are subsequently used as imprinting molds, nanoimprint invalid regions are formed, the nanoimprint quality is affected, and even the problem of subsequent nanostructure etching is caused.
The second mode is to achieve the goal of enlarging the area by a repeated construction (Step and Repeat) mode, but the actual structure at the splicing part is not easy to form a completely continuous ideal splicing interface, and how to achieve the precision requirement of splicing is one of the problems.
In conclusion, the cost for manufacturing a large-area mold with a nanostructure pattern is difficult to reduce, and the improvement space is provided.
Disclosure of Invention
The invention mainly aims to provide a manufacturing method of an imprinting mold, which can reduce the manufacturing cost.
The imprint mold of the present invention has a plurality of mold patterns that are about the same or different, and there is no difference in height between the mold patterns.
The surface of the imprinting mold of the present invention comprises a first region, a second region, and an overlapping region. A first mold pattern is arranged in the first area, and the first mold pattern has a first line width and a first depth. The second region is provided with a second mold pattern, and the second mold pattern has a second line width and a second depth. The overlapping area is located between the first area and the second area, a third mold pattern is arranged in the overlapping area, and the third mold pattern has a third line width and a third depth. The top surfaces of the first mold pattern and the second mold pattern are located at the same level, the third line width is less than or equal to the first line width or the second line width, and the third depth is less than or equal to the first depth or the second depth.
The surface of the imprinting mold of the present invention comprises a first region, a second region, and an overlapping region. A first mold pattern is arranged in the first area, and the first mold pattern has a first line width and a first depth. The second region is provided with a second mold pattern, and the second mold pattern has a second line width and a second depth. The overlapped area is positioned between the first area and the second area, is concave and has a third depth. The top surfaces of the first mold pattern and the second mold pattern are located at the same level, and the third depth is less than or equal to the first depth or the second depth.
The surface of the imprinting mold of the present invention includes a first region and a second region. A first mold pattern is arranged in the first area, and the first mold pattern has a first line width and a first depth. The second area is internally provided with a second mold pattern, the second mold pattern has a second line width and a second depth, and a space is formed between the first area and the second area. The top surfaces of the first mold pattern and the second mold pattern are positioned on the same level, and the distance is not equal to the first line width and the second line width.
The imprint mold manufacturing method of the present invention includes: (step S1000) arranging a mold pattern layer on the substrate; (step S2000) providing a first hard mask layer on the mold pattern layer, wherein the first hard mask layer has one or more first hollow areas; (step S3000) forming a first mold pattern on the mold pattern layer, wherein a range of the first mold pattern completely overlaps with a vertical projection range of the first hollow area on the mold pattern layer; (step S4000) removing the first hard mask layer; (step S5000) disposing a second hard mask layer on the mold pattern layer, wherein the second hard mask layer has one or more second hollow areas, and the vertical projection range of the second hollow areas on the mold pattern layer is adjacent to the first mold pattern; (step S6000) forming a second mold pattern on the mold pattern layer, wherein a range of the second mold pattern completely overlaps with a vertical projection range of the second hollow area on the mold pattern layer; (step S7000) the second hard mask layer is removed.
Drawings
FIGS. 1A to 5B are schematic views of an embodiment of an imprint mold according to the present invention;
FIG. 6 is a schematic flowchart of an embodiment of a method for manufacturing an imprint mold according to the present invention;
FIGS. 7A to 7K are schematic views showing an example of manufacturing an imprint mold using the imprint mold manufacturing method of the present invention;
FIGS. 8A-8C are schematic diagrams of an embodiment of the present invention in which a first imprint photoresist layer and a mold pattern layer are etched to form a first mold pattern on the mold pattern layer;
FIG. 9 is a schematic view of an embodiment of contact exposure using a PDMS mask according to the present invention;
FIG. 10 is a schematic view of an embodiment of the present invention using UV interference principle to expose through a mask;
FIG. 11 is a schematic diagram of an embodiment of the present invention using high resolution electron beams to scan expose through a mask.
Wherein, the reference numbers:
100. 404 first region
200. 505 second region
300 overlap region
311 third pattern unit
312 projection
400 base material
500 mold pattern layer
610 first hard mask layer
611 first hollow out region
620 second hard mask layer
621 second hollow-out region
701 first imprint region
702 second imprint region
710 first imprint photoresist layer
711 first imprint pattern
712 residual photoresist layer
720 second imprint photoresist layer
721 second imprint pattern
810 polydimethylsiloxane photomask
811 polydimethylsiloxane body
812 patterned metal layer
813 ultraviolet light
821 high resolution electron beam
822 template mask
900 impression mould
910. 940 first mold pattern
911. 941 top surface of first mold pattern
920. 950 second mold pattern
921. 951 Top surface of second mold Pattern
930 third mold pattern
931 top surface of the third mold pattern
D1 and D4 first depth
D2 and D5 second depth
Third depth D3
H1 first height
H2 second height
H3 third height
H4 fourth height
HHM hard mask layer thickness
HRL residual photoresist layer thickness
S1000 step
S2000 step
S3000 step
S4000 step
S5000 step
S6000 step
S7000 step
W1, W4 first line width
W2, W5 second line width
W3 third linewidth
W312 projected linewidth
W311 third pattern unit line width
W6 distance
Detailed Description
In the drawings, the thickness of layers, films, panels, regions, etc. have been exaggerated for clarity. Like reference numerals refer to like elements throughout the specification. It will be understood that when an element such as a layer, film, region, or substrate is referred to as being "on" or "connected to" another element, it can be directly on or connected to the other element or intervening elements may also be present. In contrast, when an element is referred to as being "directly on" or "directly connected to" another element, there are no intervening elements present. As used herein, "connected" may refer to physically and/or electrically connected.
As used herein, "about", "approximately" or "substantially" includes the stated value and the average value within an acceptable range of deviation of the specified value as determined by one of ordinary skill in the art, taking into account the measurement in question and the specified amount of error associated with the measurement (i.e., the limitations of the measurement system). For example, "about" may mean within one or more standard deviations of the stated value, or within ± 30%, ± 20%, ± 10%, ± 5%.
Unless defined otherwise, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. It will be further understood that terms, such as those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the relevant art and the present invention and will not be interpreted in an idealized or overly formal sense unless expressly so defined herein.
As shown in fig. 1A to 5B, the imprint mold of the present invention has a plurality of mold patterns that are about the same or different, and there is substantially no height step difference between the mold patterns. More specifically, the surface of the imprint mold of the present invention includes a plurality of regions, each region having a mold pattern disposed therein, and the mold patterns are substantially free of height differences therebetween, i.e., the top surfaces thereof are substantially flush.
As shown in fig. 1A and 1B, the surface of the
In the embodiment shown in FIG. 1B, the third linewidth W3First linewidth W ≦1And a second line width W2Wherein the first line width W1And a second line width W2May be substantially the same or different. However, in various embodiments, the third line width W3May be less than or equal to the first line width W1And a second line width W2One of them.
In the embodiment shown in FIG. 1B, the third depth D3First depth D ≦1And a second depth D2Wherein the first depth D1And a second depth D2May be substantially the same or different. However, in a different embodiment, the third depth D3May be only equal to or less than the first depth D1And a second depth D2One of them.
As shown in fig. 2A and 2B, the
In the implementation shown in fig. 2A and 2B, there is no height difference between the
In the embodiment shown in fig. 1A to 3B, the
In the imprint mold of the present invention, the first depth D1And a second depth D2Optionally, about equal or unequal, first linewidth W1And a second line width W2About equal or unequal may be selected. Specifically, in the embodiments shown in FIGS. 1B, 2B, and 3B, the first depth D1And a second depth D2Not equal, whereas in the embodiment shown in FIG. 4B, the first depth D1And a second depth D2About equal. In the embodiments shown in FIGS. 1B, 2B, 3B, and 4B, the first line width W1And a second line width W2Not equal.
As shown in fig. 5A and 5B, the surface of the
A first depth D4And a second depth D5About equal or unequal may be selected. First line width W4And a second line width W5About equal or unequal may be selected. Specifically, in the embodiment shown in FIG. 5B, the first depth D4And a second depth D5Unequal, first linewidth W4And a second line width W5About equal. The line width and the depth refer to the cross-sectional width and the height of the pattern structure, respectively.
Further, the
As shown in the flowchart of fig. 6, the imprint mold manufacturing method of the present invention includes the following steps, as in the display apparatus of the foregoing embodiment.
Step S1000, a mold pattern layer is disposed on the substrate. For example: in one embodiment, as shown in FIG. 7A, a
Step S2000 is to dispose a first hard mask layer on the mold pattern layer, wherein the first hard mask layer has one or more first hollow areas. For example: in one embodiment, as shown in fig. 7B, a first
Step S3000, a first mold pattern is formed on the mold pattern layer, wherein a range of the first mold pattern completely overlaps with a vertical projection range of the first hollow area on the mold pattern layer. For example: in one embodiment, step S3000 includes: as shown in fig. 7C, a first
In one embodiment, Nano-imprinting (Nano-imprint lithography) is used to imprint the first imprint regions 701 of the first imprint resist
In one embodiment using contact exposure, the first imprint region 701 of the first
In a different embodiment, the first imprint region 701 of the first
In a different embodiment, after the first imprint region 701 of the first
In a different embodiment, the first imprint region 701 of the first
Step S4000, the first hard mask layer is removed. For example: in one embodiment, the first
Step S5000, a second hard mask layer is disposed on the mold pattern layer, wherein the second hard mask layer has one or more second hollow areas, and the vertical projection range of the second hollow area on the mold pattern layer is adjacent to the first mold pattern. For example: in one embodiment, as shown in fig. 7G, a second hard mask layer 620 is disposed on the
Step S6000, forming a second mold pattern on the mold pattern layer, wherein a range of the second mold pattern completely overlaps with a vertical projection range of the second hollow area on the mold pattern layer. For example: in one embodiment, step S6000 includes: as shown in fig. 7H, a second imprint photoresist layer 720 is disposed on the second hard mask layer 620 and the second hollow-out region 621; then, as shown in fig. 7I, the second imprinting area 702 of the second imprinting photoresist layer 720 is imprinted to form a second imprinting pattern 721, wherein the vertical projection range of the second imprinting area 702 on the second hard mask layer 620 completely covers the range of the second hollow area 621; thereafter, the second imprint photoresist layer 720 and the
In step S7000, the second hard mask layer is removed. More specifically, in one embodiment, the second hard mask layer 620 shown in fig. 7J is removed by using an etching solution (e.g., an acid solution) for soaking or dry etching, etc., so as to form the
In the embodiments shown in fig. 7A to 7K, the first stamping region 701 (fig. 7D) and the second stamping region (fig. 7I) are stamped by using the same mother mold in steps S3000 and S6000, so as to form the
Various patterning methods may be used in steps S3000 and S6000.
In one embodiment, step S3000 includes: as shown in fig. 7C, a first
In one embodiment, step S3000 includes: as shown in fig. 7C, a first
In one embodiment, step S3000 includes: as shown in fig. 7C, a first
The present invention is capable of other embodiments, and various changes and modifications may be made by one skilled in the art without departing from the spirit and scope of the invention as defined in the appended claims.