Game machine and representation method of game machine
阅读说明:本技术 游戏机和游戏机的表示方法 (Game machine and representation method of game machine ) 是由 中岛大辅 太田祐辅 野原敦 于 2018-12-25 设计创作,主要内容包括:游戏机(10)具备游戏板(12)和配置在游戏板(12)前方的玻璃单元(15)。玻璃单元(15)含有通过激发光而发出波长为380~780nm的可见光的发光材料。(A game machine (10) is provided with a game board (12) and a glass unit (15) arranged in front of the game board (12). The glass unit (15) contains a light-emitting material that emits visible light having a wavelength of 380 to 780nm by excitation light.)
1. A game machine comprising a game board and a glass unit disposed in front of the game board,
the glass unit contains a light-emitting material which emits visible light with a wavelength of 380-780 nm by means of excitation light.
2. The gaming machine as set forth in claim 1,
the glass unit is further provided with a light source for irradiating the glass unit with excitation light.
3. The gaming machine as set forth in claim 2,
the light source irradiates the excitation light from the outer peripheral surface side of the glass unit or from the game board side.
4. The gaming machine according to claim 2 or 3,
the light source is an LED light source or an LD light source capable of irradiating light of an excitation wavelength, or constitutes a projection system.
5. The gaming machine according to any one of claims 1 to 4,
the glass unit has a multilayer structure in which at least 1 transparent plate and a resin film are laminated,
the resin film includes a resin and a light-emitting material that radiates the visible light by incidence of excitation light.
6. The gaming machine according to any one of claims 1 to 5,
the glass unit comprises 2 transparent plates and an intermediate film arranged between the 2 transparent plates, and has a laminated glass structure with the 2 transparent plates bonded via the intermediate film,
the intermediate film has 1 or more resin films, and at least one of the resin films is a light-emitting layer containing a resin and a light-emitting material that radiates the visible light by incidence of excitation light.
7. The gaming machine according to any one of claims 1 to 6,
the light emitting state of the glass unit is changed when any one game action selected from the group consisting of winning, hitting, standing, missing, occurrence of a probability fluctuation, a mode change due to a change in the probability fluctuation, ending of the probability fluctuation, and ending of a hit period is performed.
8. A display method of a game machine including a game board and a glass unit arranged in front of the game board,
the glass unit contains a light-emitting material which emits visible light with a wavelength of 380-780 nm by means of excitation light,
the visible light is emitted by irradiating excitation light to the glass unit.
Technical Field
The present invention relates to a game machine such as a pachinko machine or a slot machine, and a presentation method performed in the game machine.
Background
A game machine such as a pachinko machine or a slot machine is variously shown in order to enhance entertainment. For example, it is known to provide a liquid crystal display on a game board, in which various video images are displayed. In addition, it is also known to apply various decorations to a game board, mount a light source such as an LED on the decoration, and make the decoration emit light.
In recent years, various kinds of displays have been required for game machines, and it has been studied to use a protective glass unit attached to the front surface of a game board, in addition to the game board. For example, patent document 1 discloses that printing or a concave-convex shape is applied to a main surface of a glass unit facing a game board, light from a light-emitting device provided on one surface of the glass unit is reflected on the main surface, and a pattern corresponding to the printing or the concave-convex shape is displayed.
Patent document 1 also discloses a glass unit including a pair of transparent substrates and an electro-optical functional layer sandwiched between the transparent substrates. The electro-optical functional layer transmits light when a voltage is applied, and can scatter light when no voltage is applied. Therefore, by adjusting whether or not a voltage is applied, characters and a screen can be displayed on the glass unit.
Prior art documents
Patent document 1: japanese patent laid-open publication No. 2017-86196
Disclosure of Invention
However, the game board disclosed in patent document 1 can display only specific characters and pictures, and it is difficult to adjust the gradation of an image, and various representations cannot be made. Further, since it is necessary to provide an electro-optical functional layer on the glass unit or to perform printing, the structure of the glass unit becomes complicated, and the visibility of the glass unit may be deteriorated.
Accordingly, an object of the present invention is to provide a game board that can be variously displayed with a simple configuration by using a glass unit in front of the game board.
The present inventors have found that the above problems can be solved by incorporating a predetermined light-emitting material in a glass unit, and have completed the following invention. The gist of the present invention is as follows.
[1] A game machine comprising a game board and a glass unit disposed in front of the game board,
the glass unit contains a light-emitting material which emits visible light with a wavelength of 380-780 nm by means of excitation light.
[2] The game machine according to the above [1], further comprising a light source that irradiates the glass unit with excitation light.
[3] The gaming machine according to [2], wherein the light source irradiates the excitation light from an outer peripheral surface side of the glass unit or from the game board side.
[4] The game machine according to the above [2] or [3], wherein the light source is an LED light source capable of emitting light of an excitation wavelength, an LD light source, or another light source medium emitting light of the wavelength, and is configured as a projection system.
[5] The game machine according to any one of the above [1] to [4], wherein the glass unit has a multilayer structure in which at least 1 transparent plate and a resin film are laminated,
the resin film contains a resin and a luminescent material that radiates the above-described corresponding visible light by incidence of excitation light.
[6] The game machine according to any one of the above [1] to [5], wherein the glass unit has a laminated glass structure in which 2 transparent plates and an interlayer film provided between the 2 transparent plates are bonded to each other via the interlayer film,
the intermediate film has 1 or more resin films, and at least one of the resin films is a light-emitting layer containing a resin and a light-emitting material that radiates the visible light by incidence of excitation light.
[7] According to the game machine described in any one of the above [1] to [6], when any one of game actions selected from, for example, winning, hitting, standing, missing, occurrence of a probability variation, a mode change due to a change in the probability variation, an end of the probability variation, and an end of a hit period is performed, the light emission state is changed by the glass unit.
[8] A display method of a game machine including a game board and a glass unit disposed in front of the game board,
the glass unit contains a light-emitting material which emits visible light with a wavelength of 380-780 nm by means of excitation light,
the visible light is emitted by irradiating excitation light to the glass unit.
The invention provides a game board which can be variously displayed by a simple structure by using a glass unit in front of the game board.
Drawings
Fig. 1 is a perspective view showing the entire structure of a game machine.
Fig. 2 is a plan view of the front cover for showing the arrangement position of the light source in embodiment 1.
Fig. 3 is a perspective view of a glass unit for showing the arrangement position of a light source in embodiment 1.
Fig. 4 is a schematic diagram showing a specific example of the display performed in the glass unit.
Fig. 5 is a perspective view of a glass unit for showing the arrangement position of a light guide in embodiment 2.
Fig. 6 is a schematic cross-sectional view of a game machine for showing the arrangement position of a light source in embodiment 3.
Fig. 7 is a schematic diagram showing a specific example of the display performed in the glass unit.
Fig. 8 is a schematic diagram showing an example of the light source unit used in
Fig. 9 is a schematic diagram showing a specific example of the display performed in the glass unit.
Fig. 10 is a schematic diagram showing a specific example of the display performed in the glass unit.
Fig. 11 is a schematic diagram showing a specific example of the display performed in the glass unit.
Fig. 12 is a schematic diagram showing a specific example of the display performed in the glass unit.
Fig. 13 is a flowchart showing an example of a light emission control program for the glass unit.
Detailed Description
[ Structure and representation of Game machine ]
Hereinafter, the structure of a game machine and a display on a glass unit according to the present invention will be described in detail with reference to the drawings in embodiments 1 to 4.
(embodiment 1)
Fig. 1 is a perspective view for explaining an example of a game machine.
The
The
The front surface of the game board 12 has a game area 12A for playing a game, and the game area 12A can be seen from the outside through the
The
As shown in fig. 2, in the present embodiment, a
The maximum wavelength of the light emitted from the
By setting the maximum wavelength of the light emitted from the
The light-emitting material may emit visible light as described above, and preferably emits visible light having a maximum emission wavelength of 440nm or more, and can display blue, green, and red. Further, for example, if the visible light having a wavelength of 570nm or more is used, the visible light is yellow or red, and is suitable as a color for heightening the player's mood, indicating a hit or a hit.
The
The
Fig. 3 is a schematic perspective view showing the
However, the
Further, as shown in fig. 3, each
The optical axis of the
In the case where the
The excitation light emitted from the
Note that the term "not to emit light at the center" does not mean that light is not emitted at all strictly, and includes light emission only to the extent that it is not visually detectable.
In the present embodiment, for example, by emitting light from a part of the
Here, if the irradiation intensity of the
Therefore, for example, it may be indicated that clouds or aurora exist on the outer periphery of the
As described above, according to embodiment 1, various representations can be made using the outer peripheral portion of the
In embodiment 1, the
(embodiment 2)
Next, embodiment 2 of the present invention will be described with respect to the differences from embodiment 1. In the present embodiment, as shown in fig. 5, a
Here, the
Light emitted from
The
According to the technical configuration of embodiment 2 described above, the outer peripheral portion of the
(embodiment 3)
Next, embodiment 3 of the present invention will be explained. In embodiments 1 and 2, the excitation light from the
In the present embodiment, as shown in fig. 6, the
In the present embodiment, only 1
In addition, in the present embodiment, the
In the present embodiment, as in embodiment 1, various representations can be made by irradiating excitation light from the
Specifically, as shown in fig. 7(a),
In the present embodiment, the central portion of the glass unit may be caused to emit light as shown in fig. 7, or only the outer peripheral portion of the glass unit may be caused to emit light as shown in fig. 4. When the outer peripheral portion of the glass unit is caused to emit light, the
Further, by moving the
As described above, in the present embodiment, as in the above embodiments, various representations can be made using a glass unit.
(embodiment 4)
Next,
The MEMS mirror 31 can oscillate around the 2-axis, for example, and irradiates the
As in the present embodiment, if the projection system is used, various representations can be easily performed as shown in fig. 9. Specifically, a reel that can change the pattern is displayed on the
Further, as shown in fig. 9(E), a moving image showing a complicated motion of blood splash or bullet marks may be displayed, or as shown in fig. 9(F), various representations may be performed by emitting light in a certain area.
As shown in fig. 10, a
The
As described above, in
The light source unit in the present embodiment may be a unit other than the light source unit having the MEMS mirror 31, as long as it constitutes a projection system capable of displaying various images. As such a light source unit, a unit other than the light source unit having the MEMS mirror 31 may be used to irradiate scanning light. Since the light source unit for emitting scanning light is generally small, the glass unit can be made to emit light without increasing the size of the game machine, as in the case of the light source unit having the MEMS mirror.
Further, the light source unit may be a light source unit capable of irradiating the glass unit with the excitation light as a light beam. The light beams irradiate all light emitting portions of the glass unit at the same timing, and scanning deviation or the like does not occur as in the case of using scanning light.
Examples of the unit other than the light source unit having the MEMS mirror include a light source unit using a DMD (Digital micro mirror Device) system using DLP (Digital light Processing), an LCOS (Liquid crystal on silicon) system, and the like.
In the above description, the glass unit is explained on the premise that it emits monochromatic light by irradiation of specific excitation light, but the glass unit may emit light of a plurality of colors. In this case, the glass unit contains a plurality of luminescent materials whose maximum excitation wavelength and maximum luminescence wavelength are different from each other. The light source may be a light source that emits light corresponding to the excitation wavelength of each light-emitting material, and the wavelength of the excitation light to be irradiated may be changed according to the color of the emitted light. For example, a plurality of light sources that emit excitation lights different from each other may be prepared. Alternatively, a light source to which an optical filter capable of changing the transmission wavelength is attached may be used.
[ light emission control of glass Unit ]
Next, a specific example of the light emission control of the glass unit will be described in detail.
The light emission of the
More specifically, when a game action desired by the player occurs, such as a prize winning, a hit, standing, or a probability variation, the
When a game action unintended by the player is ended, such as a miss, a probability variation, or a hit period, the light emitting action may be ended, the light emitting intensity may be reduced, or the
For example, when standing upright is detected, the light emitting area or the light emitting intensity may be set to be larger than the light emitting area or the light emitting intensity when winning is detected. Similarly, when a hit is detected, the light emitting area or light emitting intensity may be set to be larger than the light emitting area or light emitting intensity when standing upright or winning a prize is detected.
Since the player's feeling is likely to be heightened by increasing the light emitting area or the light emitting intensity, the player can be given a feeling of expectation with respect to hitting and standing, and the entertainment can be further improved.
As described above, when the
For example, in a normal state, the
On the other hand, when a game action desired by the player occurs, such as a prize winning, a hit, standing, or a probability change, the
In addition, the winning in the pinball machine means that a pinball enters a winning slot provided in a game surface of a game board, and the pinball falls out or a lottery for a hit is obtained by winning. In this specification, the winning in the slot machine means that coins are inserted and a button or the like is appropriately pressed to start the rotation of the reel.
Hit in a pachinko machine means that various rights are obtained by winning or drawing, for example, by occurrence of a hit, opening of a predetermined winning gate such as a winning zone, etc. In the slot machine, the coin is dropped by matching the pattern of the reels.
The standing position indicates a drawing hit expected to be obtained, and for example, indicates a state in which the pattern of the reel can be hit by matching 1 more.
In addition, the miss indicates, for example, a lottery miss obtained by winning a prize in a pachinko machine. In a slot machine, the reels do not match despite the winning of a prize.
The probability variation indicates a state in which the probability of occurrence of a lottery hit is high, and occurs, for example, when a specific hit (a jackpot) is obtained among hits. On the other hand, the probability variation ends, for example, when a specific hit (a small or medium bet) is obtained among the hits, or when the number of balls to be hit after the occurrence of the probability variation exceeds a specific number. The pattern change is a change in an operation such as presentation performed in the game machine in accordance with a change in the probability fluctuation (for example, a change in the start and end of the probability fluctuation or a change in the hit probability).
The hit period means a period in which a hit occurs in the pachinko machine and a predetermined prize-winning slot such as a winning zone is opened.
Next, an example of a light emission control program of the glass unit of the present invention will be described with reference to fig. 13. Although an example of a control program for the game machine according to
As shown in fig. 13, the program first determines whether or not the prize slot is awarded a marble prize in S11, and if it is determined that the prize is awarded, the program proceeds to S12, and if the prize is not awarded, the program stands by in S11. At S12, light emission is performed to indicate winning. As light emission, for example, the light-emitting
Next, in S13, the result of the lottery drawing resulting from the winning is read, and whether or not the result of the lottery drawing stands upright is detected. Here, if it is detected that the vehicle is not standing, a miss is indicated in S20. The non-emission state of the
On the other hand, if it is detected in S13 that the lottery result is upright, a lighting operation indicating upright is started in S14. As the operation of emitting light to show standing, any operation may be performed, and here, the operation of emitting light from the
In addition, in the case of standing upright, since the display device normally displays the
Next, in S15, it is detected whether the lottery result hits. If there is a hit, the representation corresponding to the hit is made in S16. The indication may be arbitrary, and for example, as shown in fig. 12, a light-emitting
On the other hand, in S15, if a miss is detected, the process proceeds to S20, and in S20, the above-described miss may be indicated.
The above light emission control program is only an example, and any other light emission control may be performed. For example, the light emission state may be changed according to the type of hit or stand. More specifically, the light emission state may be changed depending on whether the hit is a medium or medium lottery. In addition, the light emission state may be changed depending on whether the normal standing position or the standing position with a higher occurrence probability of the jackpot than the other standing positions. In addition, the light emission state at the time of occurrence of the standing or hitting can be changed depending on whether or not the probability is changed.
Further, the light emission state of the glass unit may be changed when the probability variation occurs or ends, and the occurrence or end of the probability variation may be indicated by the light emission of the glass unit.
[ glass Unit ]
Next, the structure of the glass unit used in the present invention will be described in detail.
The glass unit used in the present invention may be composed of 1 layer of a single body, or may have a multilayer structure having 2 or more layers. In addition, the glass unit is preferably at least one layer which is a transparent plate. The transparent plate is made of any one of inorganic glass and organic glass. Organic glass is also known as so-called plexiglas. In the glass unit having a multilayer structure, the number of transparent plates may be 1 or 2 or more. In the glass unit, the transparent plate may be a light-emitting layer containing a light-emitting material and emitting light by incident excitation light, but a layer other than the transparent plate may be a light-emitting layer containing a light-emitting material.
In addition, the glass cell preferably has a multilayer structure in which at least 1 transparent plate and a resin film are laminated, and in the multilayer structure, the resin film more preferably contains a resin and a light-emitting material to serve as a light-emitting layer.
The light-emitting layer is not limited to the resin film or the transparent plate, and may be a light-emitting material film formed by vacuum deposition, sputtering, or the like of a light-emitting material. The luminescent material film may be formed on at least one surface of the transparent plate, for example.
(luminescent Material)
The light-emitting material is a material that radiates visible light by incidence of excitation light, and more specifically, a material that absorbs excitation light emitted from the light source and emits visible light having a longer wavelength than the excitation light. The light-emitting material may emit so-called phosphorescence by irradiation with excitation light.
Specifically, the light-emitting material includes, for example, a lanthanide complex having a ligand containing a halogen atom, because of its ability to exhibit high light-emitting properties. Among the lanthanide complexes, the lanthanide complexes having a ligand containing a halogen atom emit light at high emission intensity by irradiation with light. Examples of the lanthanide complexes having a halogen atom-containing ligand include lanthanide complexes having a halogen atom-containing monodentate ligand, lanthanide complexes having a halogen atom-containing bidentate ligand, lanthanide complexes having a halogen atom-containing tridentate ligand, lanthanide complexes having a halogen atom-containing tetradentate ligand, lanthanide complexes having a halogen atom-containing pentadentate ligand, lanthanide complexes having a halogen atom-containing hexadentate ligand, and the like.
Wherein the lanthanide complex having a bidentate ligand containing a halogen atom or the lanthanide complex having a tridentate ligand containing a halogen atom can emit visible light at high luminous intensity by irradiating light having a wavelength of 300 to 410 nm. Further, the lanthanide complex having a bidentate ligand containing a halogen atom or the lanthanide complex having a tridentate ligand containing a halogen atom is excellent in heat resistance, and can prevent deterioration of the light-emitting material.
In this specification, lanthanoid includes lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium or lutetium. In order to obtain higher luminous intensity, the lanthanoid is preferably neodymium, europium or terbium, more preferably europium or terbium, and further preferably europium.
Examples of the bidentate ligand containing a halogen atom include a ligand having a structure represented by the following general formula (1), a ligand having a structure represented by the following general formula (2), and the like.
In the above general formula (1), R1And R3Represents an organic group, R1And R3At least one of which is an organic group containing a halogen atom, R2Represents a linear organic group having 1 or more carbon atoms. R is as defined above1And R3The hydrocarbon group is preferably a hydrocarbon group, more preferably a hydrocarbon group having 1 to 10 carbon atoms, still more preferably a hydrocarbon group having 1 to 5 carbon atoms, and particularly preferably a hydrocarbon group having 1 to 3 carbon atoms. A part of the hydrogen atoms of the hydrocarbon group may be substituted with atoms and functional groups other than hydrogen atoms. Examples of the hydrocarbon group having 1 to 3 carbon atoms include a methyl group, an ethyl group, a propyl group, or a methyl group in which a hydrogen atom is unsubstituted, or a methyl group in which a part of a hydrogen atom is substituted with a halogen atomAlkyl, ethyl, propyl, and the like. Examples of the halogen atom of the methyl group, ethyl group and propyl group in which a part of the hydrogen atoms is substituted with a halogen atom include a fluorine atom, a chlorine atom, a bromine atom and an iodine atom. The hydrocarbon group having 1 to 3 carbon atoms is preferably a methyl group, an ethyl group, or a propyl group, in which a part of hydrogen atoms is substituted with a halogen atom, and more preferably a trifluoromethyl group, in order to emit light with high emission intensity.
R is as defined above2Preferably an alkylene group having 1 or more carbon atoms, more preferably an alkylene group having 1 to 5 carbon atoms, and most preferably a methylene group having 1 carbon atom. The alkylene group having 1 or more carbon atoms may have a part of the hydrogen atoms substituted with atoms other than hydrogen atoms and functional groups.
The above-mentioned lanthanide complexes having a halogen atom-containing ligand may have at least one halogen atom-containing ligand, and may have a ligand containing no halogen atom. Examples of the ligand not containing a halogen atom include the same ligands as those represented by the above general formula (1) except that they do not contain a halogen atom, and ligands having structures represented by the following general formulae (2) to (8). In the ligands having the structures represented by the following general formulae (2) to (8), some or all of the hydrogen atoms may be replaced by-COOR, -SO3、-NO2-OH, alkyl, -NH2And the like.
Further, in the above formula (2), 2N may be located at any position of the bipyridine skeleton. For example, 2N atoms are present at the 2,2 ', 3', 4 ', 2, 3', 2,4 ', 3, 4' positions of the bipyridyl skeleton. Among them, 2N are preferably present at the 2 and 2' positions.
In the above formula (3), 2N may be located at any position of the bipyridyl skeleton. Among them, 2N are preferably present at the 1-and 10-positions.
In the above formula (4), 2N may be located at any position of the bipyridyl skeleton. Among them, 2N are preferably present at the 1-and 10-positions.
In formula (5), 3N may be located at any position of the terpyridine skeleton.
H2N-R4-NH2(6)
In the above formula (6), R at the center4Represents a linear organic group having 1 or more carbon atoms.
In the above formula (7), 2R5Represents a linear organic group having 1 or more carbon atoms.
In the formula (8), n represents an integer of 1 or 2.
Examples of the lanthanide complexes having a bidentate ligand containing a halogen atom include europium tris (trifluoroacetylacetone) phenanthroline (Eu (TFA)3phen), tris (trifluoroacetylacetone) diphenylphenanthroline europium (Eu (TFA)3dpphen), tris (hexafluoroacetylacetonato) diphenylphenanthrolium, tris (hexafluoroacetylacetonato) bis (triphenylphosphine) europium, tris (trifluoroacetylacetone) 2,2 ' -bipyridyl europium, tris (hexafluoroacetylacetonato) 2,2 ' -bipyridyl europium, tris (5,5,6,6,7,7, 7-heptafluoro-2, 4-pentanedionate) 2,2 ' -bipyridyl europium ([ Eu (FPD)3]bpy), tris (trifluoroacetylacetone) 3,4,7, 8-tetramethyl-1, 10-phenanthroline europium ([ Eu (TFA)3]tmphen), tris (5,5,6,6,7,7, 7-heptafluoro-2, 4-pentanedionate) phenanthroline europium ([ Eu (FPD)3]phen), terpyridine trifluoroacetylacetoneEuropium, terpyridyl hexafluoroacetylacetone europium and the like.
Examples of the above-mentioned lanthanide complexes having a bidentate ligand containing a halogen atom include tris (trifluoroacetylacetone) phenanthrolinium (Tb (TFA))3phen), tris (trifluoroacetylacetone) diphenylphenanthrolinium (Tb (TFA)3dpphen), tris (hexafluoroacetylacetonato) diphenylphenanthrolinium, tris (hexafluoroacetylacetonato) bis (triphenylphosphine) onium, tris (trifluoroacetylacetone) 2,2 ' -bipyridinium, tris (hexafluoroacetylacetonato) 2,2 ' -bipyridinium, tris (5,5,6,6,7,7, 7-heptafluoro-2, 4-pentanedionate) 2,2 ' -bipyridinium ([ Tb (FPD)3]bpy), tris (trifluoroacetylacetone) 3,4,7, 8-tetramethyl-1, 10-phenanthrolinium ([ Tb (TFA)3]tmphen), tris (5,5,6,6,7,7, 7-heptafluoro-2, 4-pentanedionate) phenanthrolinium ([ Tb (FPD)3]phen), terpyridyl trifluoroacetylacetonium, terpyridyl hexafluoroacetylacetonatoium, and the like.
As the halogen atom of the above-mentioned lanthanide complex having a ligand containing a halogen atom, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom can be used. Among them, fluorine atoms are preferable for stabilizing the structure of the ligand.
Among the above-mentioned lanthanide complexes having a bidentate ligand containing a halogen atom or lanthanide complexes having a tridentate ligand containing a halogen atom, a lanthanide complex having a bidentate ligand containing a halogen atom acetylacetone skeleton is preferable particularly in view of excellent initial luminescence.
Examples of the above-mentioned lanthanide complexes having a bidentate ligand having a halogen atom-containing acetylacetone skeleton include Eu (TFA)3phen、Eu(TFA)3dpphen、Eu(HFA)3phen、[Eu(FPD)3]bpy、[Eu(TFA)3]tmphen、[Eu(FPD)3]phen, and the like. The structures of these lanthanide complexes with bidentate ligands having a halogen atom-containing acetylacetone backbone are shown.
The lanthanide ligand having a bidentate ligand having a halogen atom-containing acetylacetone skeleton as described aboveExamples of the compound include Tb (TFA)3phen、Tb(TFA)3dpphen、Tb(HFA)3phen、[Tb(FPD)3]bpy、[Tb(TFA)3]tmphen、[Tb(FPD)3]phen, and the like.
The above-mentioned lanthanide complex having a halogen atom-containing ligand is preferably in the form of particles. By being granular, the above-mentioned lanthanide complex having a halogen atom-containing ligand can be more easily finely dispersed in the light-emitting layer.
When the lanthanide complex having a halogen atom-containing ligand is in the form of particles, the average particle diameter of the lanthanide complex preferably has a lower limit of 0.01. mu.m, a preferred upper limit of 10 μm, a more preferred lower limit of 0.03. mu.m, and a more preferred upper limit of 1 μm.
As the light-emitting material, a light-emitting material having a terephthalate structure can also be used. The luminescent material having a terephthalate structure emits light when irradiated with light.
Examples of the light-emitting material having a terephthalate structure include a compound having a structure represented by the following general formula (9) and a compound having a structure represented by the following general formula (10).
These may be used alone or in combination of two or more.
In the above general formula (9), R6Represents an organic group, x is 1, 2, 3 or 4.
In order to further improve the visible light transmittance of the glass unit, x is preferably 1 or 2, more preferably has a hydroxyl group at the 2-position or 5-position of the benzene ring, and further preferably has hydroxyl groups at the 2-position and 5-position of the benzene ring.
R is as defined above6The organic group (b) is preferably a hydrocarbon group, more preferably a hydrocarbon group having 1 to 10 carbon atoms, still more preferably a hydrocarbon group having 1 to 5 carbon atoms, and particularly preferably a hydrocarbon group having 1 to 3 carbon atoms. When the hydrocarbon group has 10 or less carbon atoms, the light-emitting material having a terephthalate structure can be easily dispersed in the light-emitting layerIn (1). The hydrocarbon group is preferably an alkyl group.
Examples of the compound having a structure represented by the above general formula (9) include diethyl-2, 5-dihydroxyterephthalate, dimethyl-2, 5-dihydroxyterephthalate, and the like. Among them, the compound having the structure represented by the above general formula (9) is preferably diethyl-2, 5-dihydroxyterephthalate ("diethyl 2, 5-dihydroxyterephthalate" manufactured by Aldrich Co.).
In the above general formula (10), R7Represents an organic group, R8And R9Represents a hydrogen atom or an organic group, and y is 1, 2, 3 or 4.
R is as defined above7The organic group (b) is preferably a hydrocarbon group, more preferably a hydrocarbon group having 1 to 10 carbon atoms, still more preferably a hydrocarbon group having 1 to 5 carbon atoms, and particularly preferably a hydrocarbon group having 1 to 3 carbon atoms. If the number of carbon atoms of the hydrocarbon group is not more than the upper limit, the light-emitting material having a terephthalate structure can be easily dispersed in the light-emitting layer. The hydrocarbon group is preferably an alkyl group.
In the above general formula (10), NR8R9Is an amino group. R8And R9Preferably a hydrogen atom. Among the hydrogen atoms of the benzene ring of the compound having the structure represented by the above general formula (10), one hydrogen atom may be the above amino group, two hydrogen atoms may be the above amino group, three hydrogen atoms may be the above amino group, or four hydrogen atoms may be the above amino group.
The compound having a structure represented by the above general formula (10) is preferably diethyl-2, 5-diaminoterephthalate (for example, manufactured by Aldrich).
(resin film)
As described above, the glass cell is preferably provided with a resin film serving as a light-emitting layer. The glass unit preferably has a laminated glass structure in which an interlayer film is provided between 2 transparent plates, and the 2 transparent plates are bonded via the interlayer film.
In the laminated glass structure, the interlayer film is preferably formed of 1 resin film, which is a light-emitting layer. In addition, 2 or more resin films may be provided on the intermediate film, and at least 1 resin film among the plurality of resin films may serve as the light-emitting layer.
The resin film to be a light-emitting layer does not necessarily need to constitute an interlayer, and may be provided on the surface of any transparent plate opposite to the surface on the interlayer side, for example, in a laminated glass structure. In the case where the transparent plate provided in the glass unit is 1 sheet, it may be provided on either surface of the single-layer transparent plate.
In the case where a resin film as a light-emitting layer is provided on either one of the surface of the single-layer transparent plate or the surface opposite to the above-mentioned laminated glass structure, a sheet-like member having a light-emitting layer (resin film) may be bonded to the surface of the single-layer glass or the laminated glass structure with an adhesive, a bonding agent, or the like. In this way, the sheet-like member is bonded to the conventional glass unit by so-called post bonding, whereby the light-emitting layer can be provided on the glass unit.
The resin film to be a light-emitting layer contains a resin and a light-emitting material, and is usually a film in which a light-emitting material is dispersed in a resin. The light-emitting material is preferably dispersed throughout the entire light-emitting layer. Therefore, the glass unit emits visible light regardless of the position of the glass unit to which the excitation light is applied.
As the resin used in the resin film, a thermoplastic resin is preferable. By using a thermoplastic resin, the resin film easily functions as an adhesive layer, and when an interlayer film is formed, the resin film is easily adhered to a transparent plate or the like as described above.
When the resin film contains the light-emitting material, the content of the light-emitting material is preferably 0.001 parts by mass, more preferably 0.05 parts by mass or more, and still more preferably 0.1 parts by mass or more, per 100 parts by mass of the resin. By setting the content of the light-emitting material to be equal to or more than these lower limit values, the glass unit can sufficiently emit light. The content of the light-emitting material is preferably 10 parts by mass or less, more preferably 3 parts by mass or less, and still more preferably 1.5 parts by mass or less. By setting these upper limit values or less, the transparency of the glass unit can be easily ensured.
The thickness of the resin film is not particularly limited, and is, for example, 0.1 to 2mm, preferably 0.2 to 1 mm. If the thickness of the resin film is set to this range, sufficient light emission luminance is ensured without impairing the transparency of the glass cell.
The thickness of the interlayer film is not particularly limited, and is, for example, 0.1 to 3mm, preferably 0.2 to 2 mm.
As described above, as the resin used in the resin film, a thermoplastic resin is preferable. The thermoplastic resin used in the resin film is not particularly limited, and examples thereof include polyvinyl acetal resins, ethylene-vinyl acetate copolymer resins, ionomer resins, polyurethane resins, thermoplastic elastomers, and the like. By using these resins, the adhesion of the resin film to the transparent plate can be easily ensured, and the resin film is particularly suitable for the case where the intermediate film is formed of a resin film.
In the resin film, 1 kind of thermoplastic resin may be used alone, or 2 or more kinds may be used in combination. Among these, polyvinyl acetal resins are particularly preferable because they exhibit excellent adhesion to inorganic glass when the resin film contains a plasticizer.
In the case where the resin film contains a thermoplastic resin, the resin film may further contain a plasticizer. When the resin film contains a plasticizer, the resin film becomes soft, and as a result, the glass cell becomes soft. In addition, when the transparent plate, particularly the transparent plate is made of inorganic glass, adhesiveness with the transparent plate can be improved. In the case of using a polyvinyl acetal resin as the thermoplastic resin, it is particularly effective to contain a plasticizer in the layer.
Examples of the plasticizer include organic ester plasticizers such as monobasic organic acid esters and polybasic organic acid esters, and phosphoric acid plasticizers such as organic phosphoric acid plasticizers and organic phosphorous acid plasticizers. Among them, organic ester plasticizers are preferable, and triethylene glycol di-2-ethylhexanoate (3GO) is particularly preferable.
The content of the plasticizer is not particularly limited, and the lower limit is preferably 30 parts by mass and the upper limit is preferably 70 parts by mass with respect to 100 parts by mass of the thermoplastic resin. When the content of the plasticizer is 30 parts by mass or more, the glass unit is appropriately softened, and the workability and the like are improved. Further, if the content of the plasticizer is 70 parts by mass or less, the plasticizer can be prevented from separating from the resin film. A more preferable lower limit of the content of the plasticizer is 35 parts by mass, and a more preferable upper limit is 63 parts by mass.
When the resin film of the present invention contains a thermoplastic resin, the resin film is mainly composed of a thermoplastic resin or a thermoplastic resin and a plasticizer, and the total amount of the thermoplastic resin and the plasticizer is usually 70% by mass or more, preferably 80% by mass or more, and more preferably 90% by mass or more, based on the total amount of the resin film.
The resin film which does not serve as the light-emitting layer is the same as described above except that it does not contain a light-emitting material. The resin film may contain additives such as an antioxidant, an adhesion regulator, an ultraviolet absorber, an infrared absorber, and an antistatic agent, if necessary.
In the case of using a thermoplastic resin, for example, the resin film may be formed by kneading materials constituting the intermediate film, such as a thermoplastic resin, a light-emitting material, and a plasticizer, and then subjecting the obtained composition to extrusion molding, press molding, or the like.
(transparent plate)
The transparent plate is not particularly limited as long as it can be used for a glass unit, and inorganic glass or organic glass can be used. The inorganic glass is not particularly limited, and examples thereof include transparent glass, float glass, polished glass, template glass, mesh glass, wire glass, and green glass.
The organic glass is generally glass called plexiglass, and is not particularly limited, and includes transparent organic glass made of a resin such as polycarbonate, acrylic resin, acrylic copolymer resin, or polyester.
In the case where the glass unit has 2 or more transparent plates, the plurality of transparent plates may be made of the same kind of material as each other or may be made of different materials. For example, in the case of having 2 transparent plates, one may be inorganic glass and the other may be organic glass. In the case of having a plurality of transparent plates, it is preferable that the plurality of transparent plates be all of inorganic glass or all of organic glass.
The thickness of each transparent plate is not particularly limited, but is, for example, about 0.1 to 15mm, preferably 0.5 to 5 mm. In the case where the glass unit has a plurality of transparent plates, the thicknesses of the respective transparent plates may be the same as or different from each other.
As described above, in the glass unit, the transparent plate may become a light emitting layer that emits visible light. In the case where the transparent plate becomes a light emitting layer, the transparent plate itself contains a light emitting material. In this case, the light-emitting material may be dispersed in an inorganic material constituting the inorganic glass or an organic material (resin) constituting the organic glass of the transparent plate. Here, the light emitting material may be dispersed throughout the entire transparent plate. When the transparent plate itself contains a light-emitting material, the content of the light-emitting material is preferably 0.001 parts by mass or more, more preferably 0.05 parts by mass or more, and still more preferably 0.1 parts by mass or more per 100 parts by mass of the inorganic material constituting the inorganic glass or 100 parts by mass of the resin constituting the organic glass. By setting the content of the light-emitting material to be equal to or more than these lower limit values, the glass unit can sufficiently emit light. The content of the light-emitting material is preferably 10 parts by mass or less, more preferably 3 parts by mass or less, and still more preferably 1.5 parts by mass or less. By setting the content of the inorganic material to be equal to or less than these upper limit values, it is possible to prevent the transparency of the glass unit from being impaired by the light-emitting material.
In the case where the transparent plate contains a light-emitting material to serve as a light-emitting layer, the glass unit may have a laminated glass structure as described above, or the transparent plate may be formed of a single layer. In the case of the laminated glass structure, at least 1 transparent plate may be used as the light emitting layer.
The glass unit transmits visible light so that the game board can be visually recognized from the outside. The visible light transmittance of the glass unit is preferably 50% or more, more preferably 70% or more. By increasing the visible light transmittance, the player can easily observe the game board surface. The upper limit of the visible light transmittance is not particularly limited, and the higher the visible light transmittance, the better the visible light transmittance, but practically, the upper limit is preferably 99% or less, and more preferably 95% or less. Further, the visible light transmittance can be measured, for example, based on JISR3106 (1998).
In addition, as described above, the glass unit emits visible light by incidence of excitation light from the light source. The visible light is light with a wavelength of 380-780 nm. The glass unit may emit light of blue, green, red, yellow, or the like, or may emit white light or the like by mixing light of 2 or more colors. In the case of mixing 2 or more colors of light, for example, 2 or more light-emitting layers may be provided, and the colors may be mixed by irradiating different light to each layer, but 2 or more light-emitting materials may be contained in 1 light-emitting layer.
In addition, as described above, the light emitting layer may contain 2 or more light emitting materials whose maximum light emission wavelength and maximum excitation wavelength are different from each other. With this configuration, the glass unit is irradiated with excitation light corresponding to the excitation wavelength of each light-emitting material, whereby light emission of 2 colors or more can be performed. In this case, it is preferable that 2 or more light-emitting layers be provided, and the maximum light-emitting wavelength and the maximum excitation wavelength of the light-emitting material contained in each light-emitting layer are different from those of the light-emitting materials contained in the other light-emitting layers. For the light emission of 2 colors or more, for example, a europium complex and a terbium complex having a ligand containing a halogen atom can be used as the light emitting material.
Description of the reference numerals
10 Game machine
11 casing
12 Game board
13 front cover
14 frame body
15 glass unit
15A, 15B transparent plate
15C intermediate film
15E light emitting region
15X peripheral surface
16 light source
17 display device screen
20 light guide
30 light source unit
31 MEMS mirror
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