阅读说明：本技术 一种抗静电高吸水树脂及其制备方法和应用 (Antistatic super absorbent resin and preparation method and application thereof ) 是由 荣敏杰 李振 许永升 于庆华 荣帅帅 于 2020-07-28 设计创作，主要内容包括：本发明涉及一种抗静电高吸水树脂及其制备方法和应用。所述方法包括：将丙烯酸与水混合,得到丙烯酸溶液,然后用氢氧化钠将所述丙烯酸溶液中和,得到含有丙烯酸和丙烯酸钠的混合液；往所述混合液中加入交联剂后通氮除氧,然后加入引发剂引发聚合,得到聚合物水凝胶；将所述聚合物水凝胶依次进行破碎、烘干、粉碎和筛分的步骤,得到高吸水树脂颗粒；往所述高吸水树脂颗粒的表面喷洒表面处理液后保温处理,制得抗静电高吸水树脂；所述交联剂中含有抗静电剂和/或所述表面处理液中含有抗静电剂。本发明在制备高吸水树脂的聚合阶段和/或表面处理阶段加入抗静电剂,有效地解决了因高吸水树脂静电产生的粘辊现象,大大提升了卫生用品质量的稳定性。(The invention relates to an antistatic super absorbent resin and a preparation method and application thereof. The method comprises the following steps: mixing acrylic acid with water to obtain an acrylic acid solution, and then neutralizing the acrylic acid solution with sodium hydroxide to obtain a mixed solution containing acrylic acid and sodium acrylate; adding a cross-linking agent into the mixed solution, introducing nitrogen to remove oxygen, and then adding an initiator to initiate polymerization to obtain polymer hydrogel; sequentially crushing, drying, crushing and screening the polymer hydrogel to obtain super absorbent resin particles; spraying surface treatment liquid on the surfaces of the super absorbent resin particles, and then carrying out heat preservation treatment to obtain the antistatic super absorbent resin; the crosslinking agent contains an antistatic agent and/or the surface treatment liquid contains an antistatic agent. The antistatic agent is added in the polymerization stage and/or the surface treatment stage of the preparation of the super absorbent resin, so that the roller sticking phenomenon caused by static electricity of the super absorbent resin is effectively avoided, and the quality stability of the sanitary product is greatly improved.)

1. A preparation method of antistatic super absorbent resin is characterized by comprising the following steps:

(1) mixing acrylic acid with water to obtain an acrylic acid solution, and then neutralizing the acrylic acid solution with sodium hydroxide to obtain a mixed solution containing acrylic acid and sodium acrylate;

(2) adding a cross-linking agent into the mixed solution, introducing nitrogen to remove oxygen, and then adding an initiator to initiate polymerization to obtain polymer hydrogel;

(3) sequentially crushing, drying, crushing and screening the polymer hydrogel to obtain super absorbent resin particles;

(4) spraying surface treatment liquid on the surfaces of the super absorbent resin particles, and then carrying out heat preservation treatment to obtain the antistatic super absorbent resin;

the crosslinking agent contains an antistatic agent and/or the surface treatment liquid contains an antistatic agent.

2. The method of claim 1, wherein:

the dosage of the antistatic agent accounts for 0.001-0.01% of the weight percentage of the super absorbent resin particles; and/or

The weight ratio of the usage amount of the surface treatment liquid to the usage amount of the super absorbent resin particles is (0.3-5): 100.

3. the method of claim 1, wherein:

the dosage of the cross-linking agent is 0.1-1% of the mass of the acrylic acid; and/or

The amount of the initiator is 0.01-0.5% of the mass of the acrylic acid.

4. The method of claim 1, wherein:

in the step (1), neutralizing the acrylic acid solution with sodium hydroxide until the neutralization degree is 50-90%, preferably 60-80%; and/or

The sum of the concentration of acrylic acid and sodium acrylate in the mixed solution is 30-50%.

5. The method of claim 1, wherein:

the particle size of the super absorbent resin particles is 300-700 mu m.

6. The production method according to any one of claims 1 to 5, characterized in that:

the temperature of the drying and/or the heat preservation treatment is 100-200 ℃, and preferably 100-120 ℃.

7. The production method according to any one of claims 1 to 5, characterized in that:

the cross-linking agent is one or more of polyethylene glycol, N-methylene bisacrylamide, polyethylene glycol diacrylate and trimethylolpropane triacrylate;

the initiator is a redox initiator, an oxidant in the redox initiator is one or more of hydrogen peroxide and persulfate, and a reducing agent in the redox initiator is one or more of sulfite, bisulfite and ascorbic acid;

the antistatic agent is one or more of sodium p-nonylphenoxy propyl sulfonate, alkyl bi-alpha-hydroxyethyl amine phosphate, monoglycerides of stearic acid, alkyl dicarboxymethyl ammonium ethyl lactone and dodecyl dimethyl quaternary ethyl inner salt; and/or

The surface treatment liquid is one or more of polyalcohol, polyamine compound and epoxy compound.

8. The method of claim 7, wherein:

the polyalcohol is one or more of ethylene glycol, butanediol, glycerol and triethylene glycol;

the polyamine compound is one or more of ethylenediamine, diethylenediamine and triethylenediamine; and/or

The epoxy compound is one or more of butanediol diglycidyl ether, polyglycerol polyglycidyl ether and sorbitol polyglycidyl ether.

9. The antistatic super absorbent resin prepared by the preparation method according to any one of claims 1 to 8.

10. Use of the antistatic super absorbent resin prepared by the preparation method according to any one of claims 1 to 8 in sanitary articles.

Technical Field

The invention belongs to the technical field of polymeric functional polymer chemical additives, and particularly relates to an antistatic super absorbent resin, and a preparation method and application thereof.

Background

The super absorbent resin contains strong hydrophilic groups, has a three-dimensional network structure after moderate crosslinking, can quickly absorb water with the mass of dozens of times or even thousands of times of the self mass through hydration to form gel, and is widely applied to the field of sanitary products such as baby paper diapers, sanitary napkins and the like because the material has high water absorption speed, large water absorption capacity, strong water retention capacity and no toxicity and odor.

At present, the research on the super absorbent resin mainly focuses on the improvement of the self absorption performance of the super absorbent resin product, and in the practical application of the super absorbent resin, for example, in the production and blanking process of the hygienic product, the roller sticking phenomenon can be generated due to the static electricity of the super absorbent resin, so that the problem that the quality stability of the produced hygienic product is affected due to uneven blanking of the super absorbent resin is not concerned. In the prior art, no relevant report that the roll sticking phenomenon is avoided in the production process of the sanitary products by eliminating the electrostatic hidden trouble of the super absorbent resin is found, so that the quality stability of the sanitary products such as paper diapers, sanitary towels and the like is ensured.

In view of the above problems, it is very necessary to provide an antistatic super absorbent resin, a preparation method and applications thereof.

Disclosure of Invention

In order to solve the technical problems in the prior art, the invention provides an antistatic super absorbent resin and a preparation method and application thereof. The antistatic agent is added in the polymerization stage and/or the surface treatment stage of the preparation of the super absorbent resin, so that the roller sticking phenomenon caused by static electricity of the super absorbent resin is effectively avoided, and the quality stability of the sanitary product is greatly improved.

In order to achieve the above object, the present invention provides, in a first aspect, a method for preparing an antistatic super absorbent resin, the method comprising the steps of:

(1) mixing acrylic acid with water to obtain an acrylic acid solution, and then neutralizing the acrylic acid solution with sodium hydroxide to obtain a mixed solution containing acrylic acid and sodium acrylate;

(2) adding a cross-linking agent into the mixed solution, introducing nitrogen to remove oxygen, and then adding an initiator to initiate polymerization to obtain polymer hydrogel;

(3) sequentially crushing, drying, crushing and screening the polymer hydrogel to obtain super absorbent resin particles;

(4) spraying surface treatment liquid on the surfaces of the super absorbent resin particles, and then carrying out heat preservation treatment to obtain the antistatic super absorbent resin;

the crosslinking agent contains an antistatic agent and/or the surface treatment liquid contains an antistatic agent.

Preferably, the antistatic agent accounts for 0.001-0.01 wt% of the super absorbent resin particles; and/or the weight ratio of the usage amount of the surface treatment liquid to the usage amount of the super absorbent resin particles is (0.3-5): 100.

preferably, the amount of the cross-linking agent is 0.1-1% of the mass of the acrylic acid; and/or the dosage of the initiator is 0.01-0.5% of the mass of the acrylic acid.

Preferably, in the step (1), the acrylic acid solution is neutralized by sodium hydroxide to a neutralization degree of 50 to 90%, preferably 60 to 80%; and/or the sum of the concentration of the acrylic acid and the concentration of the sodium acrylate in the mixed solution is 30-50%.

Preferably, the particle size of the super absorbent resin particles is 300-700 μm.

Preferably, the temperature of the drying and/or the heat preservation treatment is 100-200 ℃, and preferably 100-120 ℃.

Preferably, the cross-linking agent is one or more of polyethylene glycol, N-methylene bisacrylamide, polyethylene glycol diacrylate and trimethylolpropane triacrylate; the initiator is a redox initiator, an oxidant in the redox initiator is one or more of hydrogen peroxide and persulfate, and a reducing agent in the redox initiator is one or more of sulfite, bisulfite and ascorbic acid; the antistatic agent is one or more of sodium p-nonylphenoxy propyl sulfonate, alkyl bi-alpha-hydroxyethyl amine phosphate, monoglycerides of stearic acid, alkyl dicarboxymethyl ammonium ethyl lactone and dodecyl dimethyl quaternary ethyl inner salt; and/or the surface treatment liquid is one or more of polyalcohol, polyamine compound and epoxy compound.

Preferably, the polyalcohol is one or more of ethylene glycol, butanediol, glycerol and triethylene glycol; the polyamine compound is one or more of ethylenediamine, diethylenediamine and triethylenediamine; and/or the epoxy compound is one or more of butanediol diglycidyl ether, polyglycerol polyglycidyl ether and sorbitol polyglycidyl ether.

The present invention provides, in a second aspect, an antistatic super absorbent resin obtained by the production method according to the first aspect of the present invention.

In a third aspect, the invention provides the use of the antistatic super absorbent resin prepared by the preparation method in the first aspect of the invention in sanitary articles.

Compared with the prior art, the invention at least has the following beneficial effects:

(1) the invention starts from the practical application of the super absorbent resin, aims at the phenomenon that the finished product quality fluctuates due to uneven blanking caused by the fact that the super absorbent resin is easy to stick a roller in the blanking process of the production of sanitary products manufacturers, and introduces the antistatic agent in the polymerization stage and/or the surface treatment stage by combining all links of the production process of the super absorbent resin, thereby eliminating the electrostatic hidden trouble of the super absorbent resin and ensuring the quality stability of the sanitary products such as paper diapers, sanitary towels and the like.

(2) In the process of preparing the antistatic super absorbent resin, a large number of creative experiments show that the proper amount of the antistatic agent is obtained, namely the amount of the antistatic agent is required to be controlled to be 0.001-0.01 percent of the weight of the super absorbent resin particles, the addition of the antistatic agent with the proper amount has no influence on indexes such as the absorption performance of the super absorbent resin, but the antistatic agent has a good antistatic effect in the application process, does not have the phenomenon of roller sticking, and greatly improves the quality stability of sanitary products such as paper diapers and sanitary towels.

(3) In some preferred embodiments of the invention, the antistatic agent is added during the polymerization stage, because some antistatic agents are in powder form, which easily drifts or escapes when added during the surface treatment stage; and add antistatic agent in the polymerization stage and compare the surface treatment stage and add antistatic agent, can avoid producing the dust in the production process, can effectually prevent that powdered antistatic agent from wafting or overflowing, add antistatic agent in the polymerization stage, antistatic agent can be wrapped up in wherein by high-molecular polymer, after crushing, stoving, crushing and screening step, antistatic agent can be contained in super absorbent resin granule for super absorbent resin's antistatic effect is better.

Drawings

FIG. 1 is a graph showing the effects of the antistatic super absorbent resin prepared in example 1 and the super absorbent resin prepared in comparative example 1 in the blanking process in the production of sanitary articles. In the figure, (a) shows the use effect diagram of the antistatic super absorbent resin prepared in example 1; (b) the figure shows the effect of the super absorbent resin prepared in comparative example 1.

FIG. 2 is a graph showing the effects of the antistatic super absorbent resin prepared in example 2 and the super absorbent resin prepared in comparative example 2 in blanking process in the production of sanitary articles. In the figure, (a) shows the use effect diagram of the antistatic super absorbent resin prepared in example 2; (b) the figure shows the effect of the super absorbent resin prepared in comparative example 2.

FIG. 3 is a graph showing the effects of the antistatic super absorbent resin prepared in example 3 and the super absorbent resin prepared in comparative example 3 in blanking process in the production of sanitary articles. In the figure, (a) shows the use effect diagram of the antistatic super absorbent resin prepared in example 3; (b) the figure shows the effect of the super absorbent resin prepared in comparative example 3.

FIG. 4 is a graph showing the effects of the antistatic super absorbent resin prepared in example 4 and the super absorbent resin prepared in comparative example 4 in blanking process in the production of sanitary articles. In the figure, (a) shows the use effect diagram of the antistatic super absorbent resin prepared in example 4; (b) the effect of the super absorbent resin prepared in comparative example 4 is shown.

FIG. 5 is a graph showing the effects of the antistatic super absorbent resin prepared in example 5 and the super absorbent resins prepared in comparative examples 5 and 6 in the blanking process in the production of sanitary articles. In the figure, (a) shows the use effect diagram of the antistatic super absorbent resin prepared in example 5; (b) a graph showing the effect of the super absorbent resin prepared in comparative example 5; (c) the figure shows the effect of the super absorbent resin prepared in comparative example 6.

Detailed Description

In order to make the objects, technical solutions and advantages of the present invention more apparent, the technical solutions of the present invention will be clearly and completely described below with reference to the embodiments of the present invention. It is to be understood that the embodiments described are only a few embodiments of the present invention, and not all embodiments. All other embodiments, which can be obtained by a person skilled in the art without any inventive step based on the embodiments of the present invention, are within the scope of the present invention.

The present invention provides, in a first aspect, a method for preparing an antistatic super absorbent resin, the method comprising the steps of:

(1) mixing acrylic acid with water (such as deionized water) to obtain an acrylic acid solution, and then neutralizing the acrylic acid solution with sodium hydroxide to obtain a mixed solution containing acrylic acid and sodium acrylate; in the present invention, the acrylic acid solution may be neutralized with, for example, a sodium hydroxide solution having a concentration of 50 wt%; in the invention, for example, acrylic acid and deionized water are added into 2000mL of four-mouth flask equipped with a stirrer, a reflux condenser tube, a thermometer and a dropping funnel, liquid alkali is dropped through the dropping funnel, the temperature of the flask is reduced by cold water in the dropping process, the temperature is controlled not to exceed 50 ℃, so that the acrylic acid solution is neutralized by sodium hydroxide solution, and mixed solution containing acrylic acid and sodium acrylate is obtained;

(2) adding a cross-linking agent into the mixed solution, introducing nitrogen to remove oxygen, and then adding an initiator to initiate polymerization to obtain polymer hydrogel; in the invention, for example, adding a cross-linking agent into the mixed solution, then introducing nitrogen to remove oxygen, then adding an initiator, then continuing introducing nitrogen to remove oxygen and enabling the initiator to initiate polymerization to obtain a polymer hydrogel, specifically, for example, transferring the mixed solution into a beaker, adding a cross-linking agent such as N, N-methylene bisacrylamide, trimethylolpropane triacrylate and the like into the mixed solution, blowing nitrogen to remove oxygen, adding an initiator such as hydrogen peroxide, sodium bisulfite and the like after uniformly mixing, continuing blowing nitrogen to remove oxygen, wherein the oxygen content is not higher than 1ppm, and initiating polymerization at 45-50 ℃ to obtain the polymer hydrogel;

(3) sequentially crushing, drying, crushing and screening the polymer hydrogel to obtain super absorbent resin particles; in the invention, the crushing is the crushing of hydrogel blocks, and the crushing is the crushing of dried gel particles; in the invention, preferably, the polymer hydrogel is crushed and dried at 100-200 ℃, more preferably 100-120 ℃, and the moisture content of the dried gel (gel particles) is less than or equal to 5 percent; in the present invention, the polymer hydrogel is abbreviated as hydrogel;

(4) spraying surface treatment liquid on the surfaces of the super absorbent resin particles, and then carrying out heat preservation treatment to obtain the antistatic super absorbent resin; the cross-linking agent contains an antistatic agent and/or the surface treatment liquid contains an antistatic agent; in the invention, for example, the super absorbent resin sprayed with the surface treatment liquid is kept at 100-200 ℃, preferably 100-120 ℃ for 1h to obtain the antistatic super absorbent resin; in the invention, the surface treatment process of the super absorbent resin particles is carried out after the surface treatment liquid is sprayed on the surfaces of the super absorbent resin particles and the heat preservation treatment is carried out.

In the invention, when the cross-linking agent contains an antistatic agent, namely the antistatic agent is added in the polymerization stage of the preparation of the super absorbent resin, namely in the step (2), the cross-linking agent containing the antistatic agent is added into the mixed solution, then nitrogen is introduced to remove oxygen, and then an initiator is added to initiate polymerization to obtain the polymer hydrogel; of course, in the step (2), the antistatic agent and the crosslinking agent may be directly added to the mixed solution, then nitrogen is introduced to remove oxygen, and then the initiator is added to initiate polymerization to obtain the polymer hydrogel, without first mixing the antistatic agent with the crosslinking agent; in the invention, when the surface treatment liquid contains the antistatic agent, namely the antistatic agent is added in the surface treatment stage of the preparation of the super absorbent resin, namely in the step (4), the surface treatment liquid containing the antistatic agent is sprayed on the surfaces of the super absorbent resin particles and then the heat preservation treatment is carried out, thus obtaining the antistatic super absorbent resin.

In the present invention, the amount of each raw material may be, for example: 300-500 parts of acrylic acid, 100-700 parts of deionized water, 200-400 parts of 50 wt% sodium hydroxide solution, 0.3-5 parts of cross-linking agent, 0.03-2.5 parts of initiator, 3-20 parts of surface treatment liquid and 0.001-0.6 part of antistatic agent, preferably 0.001-0.1 part.

The invention starts from the practical application of the super absorbent resin, aims at the phenomenon that the finished product quality fluctuates due to uneven blanking caused by the fact that the super absorbent resin is easy to stick a roller in the blanking process of the production of sanitary products manufacturers, and introduces the antistatic agent in the polymerization stage and/or the surface treatment stage by combining all links of the production process of the super absorbent resin, thereby eliminating the electrostatic hidden trouble of the super absorbent resin and ensuring the quality stability of the sanitary products such as paper diapers, sanitary towels and the like; the present invention is more preferable to add the antistatic agent in the polymerization stage because some antistatic agents are in powder form, and the powder form of antistatic agent is easily drifted or escaped when the antistatic agent is added in the surface treatment stage; and add antistatic agent in the polymerization stage and compare the surface treatment stage and add antistatic agent, can avoid producing the dust in the production process, can effectually prevent that powdered antistatic agent from wafting or overflowing, add antistatic agent in the polymerization stage, antistatic agent can be wrapped up in wherein by high-molecular polymer, after crushing, stoving, crushing and screening step, antistatic agent can be contained in super absorbent resin granule for super absorbent resin's antistatic effect is better.

According to some preferred embodiments, the antistatic agent is used in an amount of 0.001 to 0.01% by weight (e.g., 0.001%, 0.002%, 0.003%, 0.004%, 0.005%, 0.006%, 0.007%, 0.008%, 0.009%, or 0.01%) of the super absorbent resin particles; if the amount of the antistatic agent is too small, the antistatic effect of the super absorbent resin is poor, and if the amount of the antistatic agent is too large, even if the amount is slightly large, the absorption performance of the super absorbent resin is obviously reduced, and the antistatic agent with proper amount is difficult to obtain; in the process of preparing the antistatic super absorbent resin, a large number of creative experiments show that the proper amount of the antistatic agent is obtained, namely the amount of the antistatic agent is required to be controlled to be 0.001-0.01 percent of the weight of the super absorbent resin particles, the addition of the antistatic agent with the proper amount has no influence on indexes such as the absorption performance of the super absorbent resin, but the antistatic agent has a good antistatic effect in the application process, does not have a roller sticking phenomenon, and greatly improves the quality stability of sanitary products such as paper diapers and sanitary napkins.

According to some preferred embodiments, the weight ratio of the surface treatment liquid to the super absorbent resin particles is (0.3 to 5): 100 (e.g., 0.3:100, 0.5:100, 0.8:100, 1:100, 1.5:100, 2:100, 2.5:100, 3:100, 3.5:100, 4:100, 4.5:100, or 5: 100).

According to some preferred embodiments, the cross-linking agent is used in an amount of 0.1 to 1% (e.g., 0.1%, 0.2%, 0.3%, 0.4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, or 1%) by mass of the acrylic acid; and/or the initiator is used in an amount of 0.01 to 0.5% (e.g., 0.01%, 0.05%, 0.08%, 0.1%, 0.2%, 0.3%, 0.4%, or 0.5%) by mass of the acrylic acid.

According to some preferred embodiments, in step (1), the acrylic acid solution is neutralized with sodium hydroxide to a degree of neutralization of 50 to 90% (e.g., 50%, 55%, 60%, 65%, 70%, 75%, 80%, 85%, or 90%), preferably 60 to 80% (e.g., 60%, 65%, 70%, 75%, or 80%); and/or the sum of the concentrations of acrylic acid and sodium acrylate in the mixed solution is 30-50% (for example, 30%, 35%, 40%, 45% or 50%).

According to some preferred embodiments, the particle size of the super absorbent resin particles is 300 to 700 μm.

According to some preferred embodiments, the temperature of the drying and/or the heat preservation treatment is 100 to 200 ℃, preferably 100 to 120 ℃.

According to some preferred embodiments, the cross-linking agent is one or more of polyethylene glycol, N-methylene bisacrylamide (N, N-methylene bisacrylamide), polyethylene glycol diacrylate (polyethylene glycol diacrylate), trimethylolpropane triacrylate; the initiator is a redox initiator, an oxidant in the redox initiator is one or more of hydrogen peroxide and persulfate, and a reducing agent in the redox initiator is one or more of sulfite, bisulfite and ascorbic acid; the antistatic agent is one or more of sodium p-nonylphenoxy propyl sulfonate, alkyl bi-alpha-hydroxyethyl amine phosphate, monoglycerides of stearic acid, alkyl dicarboxymethyl ammonium ethyl lactone and dodecyl dimethyl quaternary ethyl inner salt; and/or the surface treatment liquid is one or more of polyalcohol, polyamine compound and epoxy compound.

According to some preferred embodiments, the polyhydric alcohol is one or more of ethylene glycol, butylene glycol (e.g., 1, 3-butylene glycol, 1, 4-butylene glycol), glycerol, triethylene glycol; the polyamine compound is one or more of ethylenediamine, diethylenediamine and triethylenediamine; and/or the epoxy compound is one or more of butanediol diglycidyl ether, polyglycerol polyglycidyl ether and sorbitol polyglycidyl ether. In the present invention, for example, the surface treatment liquid may be prepared into a 50 wt% to 60 wt% aqueous solution, and then the antistatic agent may be added to the aqueous solution and stirred uniformly to obtain the surface treatment liquid containing the antistatic agent, which is sprayed.

According to some preferred embodiments, the antistatic super absorbent resin is synthesized by the following steps: neutralizing acrylic acid with alkali, adding a cross-linking agent and an initiator to carry out polymerization reaction to obtain hydrogel, and then crushing and drying the hydrogel; crushing and screening the dried gel; spraying surface treatment liquid containing an antistatic agent on the surfaces of the screened resin particles for surface treatment to obtain the super absorbent resin (antistatic super absorbent resin) with antistatic property, wherein the specific preparation method comprises the following steps:

mixing acrylic acid with water, and then adding sodium hydroxide to neutralize, wherein the neutralization degree is 50-90%, preferably 60-80%, and the concentration of the mixture of acrylic acid and sodium acrylate in water is 30-50%, so as to obtain a mixed solution containing acrylic acid and sodium acrylate;

adding a cross-linking agent into the mixed solution, blowing nitrogen, adding an initiator after uniform mixing, and continuously blowing nitrogen to initiate polymerization to obtain polymer hydrogel, wherein the dosage of the cross-linking agent is 0.1-1% of the mass of the acrylic acid in the step I, and the dosage of the initiator is 0.01-0.5% of the mass of the acrylic acid in the step I;

crushing and drying the polymer hydrogel obtained in the step II, wherein the drying temperature is 100-200 ℃, and the preferred temperature is 100-120 ℃;

fourthly, crushing and screening the dried polymer gel in the third step, and selecting super absorbent resin particles with the particle size of 300-700 mu m;

fifthly, spraying surface treatment liquid containing antistatic agent on the super absorbent resin particles screened in the step IV; the dosage of the antistatic agent is 0.001-0.01 part by weight of the antistatic agent per 100 parts by weight of the super absorbent resin particles; the amount of the surface treatment liquid is 0.3-5 parts by weight per 100 parts by weight of the super absorbent resin particles;

sixthly, preserving the temperature of the super absorbent resin particles sprayed with the surface treatment liquid in the fifth step for 1 hour at 100-200 ℃, preferably 100-120 ℃, and obtaining the antistatic super absorbent resin.

The present invention provides, in a second aspect, an antistatic super absorbent resin obtained by the production method according to the first aspect of the present invention.

In a third aspect, the invention provides the use of the antistatic super absorbent resin prepared by the preparation method in the first aspect of the invention in sanitary articles. The antistatic super absorbent resin prepared by the invention has good antistatic effect in the application process, and does not have roller sticking phenomenon, and the excellent performance can greatly improve the quality stability of sanitary products such as paper diapers, sanitary towels and the like; moreover, the antistatic super absorbent resin is adopted to produce sanitary articles, so that the roller sticking phenomenon does not exist, and the production and blanking device is convenient to clean and easy to maintain.

The present invention will be further described with reference to the following examples. These examples are merely illustrative of preferred embodiments of the present invention and the scope of the present invention should not be construed as being limited to these examples.