阅读说明：本技术 一种防开裂耐腐蚀砂浆及其制备方法 (Anti-cracking corrosion-resistant mortar and preparation method thereof ) 是由 周旦 万志强 王亚 于 2021-08-16 设计创作，主要内容包括：本发明公开了一种防开裂耐腐蚀砂浆及其制备方法,具体涉及建筑施工砂浆技术领域,包括：水泥、乳胶粉、玄武岩纤维、水、石英砂和复合增强剂。本发明可有效提高防开裂耐腐蚀砂浆的耐磨性能、耐腐蚀性能、耐高寒性能,可有效防止砂浆产品在高寒高原环境下的防开裂和防腐蚀性能；可制成纳米银颗粒、石墨烯和氧化石墨烯的复合材料；可对纳米二氧化钛进行改性处理,然后将改性后的纳米二氧化钛与氧化石墨烯进行复合；聚酰亚胺纤维为复合增强剂中的支撑网络,中空玻璃微珠可作为支撑框架,可有效加强复合增强剂的稳定性和安全性,进而保证砂浆的耐磨性能、耐腐蚀性能、耐高寒性能。(The invention discloses anti-cracking and corrosion-resistant mortar and a preparation method thereof, and particularly relates to the technical field of building construction mortar, which comprises the following steps: cement, latex powder, basalt fiber, water, quartz sand and a composite reinforcing agent. The anti-cracking and anti-corrosion mortar can effectively improve the wear resistance, the corrosion resistance and the high-cold resistance of the anti-cracking and anti-corrosion mortar, and can effectively prevent the anti-cracking and anti-corrosion performance of the mortar product in a high-cold plateau environment; the composite material of nano silver particles, graphene and graphene oxide can be prepared; the nano titanium dioxide can be modified, and then the modified nano titanium dioxide is compounded with the graphene oxide; the polyimide fibers are a supporting network in the composite reinforcing agent, and the hollow glass beads can be used as a supporting frame, so that the stability and the safety of the composite reinforcing agent can be effectively enhanced, and further the wear resistance, the corrosion resistance and the high and cold resistance of the mortar are ensured.)

1. The anti-cracking and anti-corrosion mortar is characterized in that: comprises the following components in percentage by weight: 24.60-25.80% of cement, 16.60-17.80% of water, 3.10-3.50% of latex powder, 6.40-8.20% of basalt fiber, 4.40-5.20% of composite reinforcing agent and the balance of quartz sand.

2. The anti-cracking and anti-corrosion mortar of claim 1, wherein: the composite reinforcing agent comprises the following components in percentage by weight: 8.40-9.20% of silver nitrate, 9.40-10.20% of glucose, 7.40-8.20% of graphene oxide, 10.80-11.40% of polyimide fibers, 18.80-19.40% of hollow glass microspheres, 7.80-8.40% of nano titanium dioxide, 0.30-0.50% of silane coupling agent KH570, and the balance of epoxy resin.

3. The anti-cracking and anti-corrosion mortar of claim 2, wherein: comprises the following components in percentage by weight: 24.60% of cement, 16.60% of water, 3.10% of latex powder, 6.40% of basalt fiber, 4.40% of composite reinforcing agent and 44.90% of quartz sand; the composite reinforcing agent comprises the following components in percentage by weight: 8.40% of silver nitrate, 9.40% of glucose, 7.40% of graphene oxide, 10.80% of polyimide fibers, 18.80% of hollow glass microspheres, 7.80% of nano titanium dioxide, 0.30% of silane coupling agent KH570 and 37.10% of epoxy resin.

4. The anti-cracking and anti-corrosion mortar of claim 2, wherein: comprises the following components in percentage by weight: 25.80% of cement, 17.80% of water, 3.50% of latex powder, 8.20% of basalt fiber, 5.20% of composite reinforcing agent and 39.50% of quartz sand; the composite reinforcing agent comprises the following components in percentage by weight: 9.20% of silver nitrate, 10.20% of glucose, 8.20% of graphene oxide, 11.40% of polyimide fibers, 19.40% of hollow glass microspheres, 8.40% of nano titanium dioxide, 0.50% of silane coupling agent KH570 and 32.70% of epoxy resin.

5. The anti-cracking and anti-corrosion mortar of claim 2, wherein: comprises the following components in percentage by weight: 25.20% of cement, 17.20% of water, 3.30% of latex powder, 7.30% of basalt fiber, 4.80% of composite reinforcing agent and 42.20% of quartz sand; the composite reinforcing agent comprises the following components in percentage by weight: 8.80% of silver nitrate, 9.80% of glucose, 7.80% of graphene oxide, 11.10% of polyimide fibers, 19.10% of hollow glass microspheres, 8.10% of nano titanium dioxide, 0.40% of silane coupling agent KH570 and 34.90% of epoxy resin.

6. The preparation method of the anti-cracking and corrosion-resistant mortar is characterized by comprising the following steps: the preparation method comprises the following specific steps:

the method comprises the following steps: weighing the above cement, latex powder, basalt fiber, water, quartz sand and silver nitrate, glucose, graphene oxide, polyimide fiber, hollow glass microsphere, nano titanium dioxide, silane coupling agent KH570 and epoxy resin in the composite reinforcing agent in parts by weight;

step two: adding the silver nitrate, the glucose, the graphene oxide, the polyimide fibers, the hollow glass beads, the nano titanium dioxide and the silane coupling agent KH570 into deionized water, and performing ultrasonic treatment for 30-40 minutes to obtain a mixture A;

step three: adding the mixture A prepared in the step two into microwave equipment with a solvent collector, carrying out microwave irradiation stripping treatment for 2-3 minutes, and introducing inert gas to obtain a mixture B;

step four: blending and stirring the mixture B in the third step and the epoxy resin in the first step to obtain a mixture C, and adding the mixture C into an electrostatic spinning device for electrostatic spinning treatment to obtain a composite reinforcing agent;

step five: and C, blending and stirring the cement and the water in the step I, adding the latex powder in the step I and the composite reinforcing agent prepared in the step four, continuously stirring, finally adding the basalt fiber and the quartz sand in the step I, and continuously stirring to obtain the anti-cracking and anti-corrosion mortar.

7. The preparation method of the anti-cracking and anti-corrosion mortar according to claim 6, wherein the preparation method comprises the following steps: in the second step, the weight ratio of the total weight of silver nitrate, glucose, graphene oxide, polyimide fibers, hollow glass microspheres, nano titanium dioxide and silane coupling agent KH570 to deionized water is as follows: 1: 5-10, the ultrasonic frequency is 23-27 KHz, and the ultrasonic power is 900-1300W; in the third step, the microwave frequency is 1350-1550 MHz, and the microwave output power density is 110-130 mW/cm³The inert gas is one of nitrogen, argon and helium; in the fourth step, in the electrostatic spinning treatment process, 16-18 KV high voltage is applied, and the distance between a capillary nozzle of the injector and the receiving device is 9-11 cm.

8. Preparation method of anti-cracking and anti-corrosion mortar according to claim 7The method is characterized in that: in the second step, the weight ratio of the total weight of silver nitrate, glucose, graphene oxide, polyimide fibers, hollow glass microspheres, nano titanium dioxide and silane coupling agent KH570 to deionized water is as follows: 1: 5, the ultrasonic frequency is 23KHz, and the ultrasonic power is 900W; in the third step, the microwave frequency is 1350MHz, and the microwave output power density is 110mW/cm³The inert gas is one of nitrogen, argon and helium; in the fourth step, 16KV high voltage is applied in the electrostatic spinning process, and the distance between the capillary nozzle of the injector and the receiving device is 9 cm.

9. The preparation method of the anti-cracking and anti-corrosion mortar according to claim 7, wherein the preparation method comprises the following steps: in the second step, the weight ratio of the total weight of silver nitrate, glucose, graphene oxide, polyimide fibers, hollow glass microspheres, nano titanium dioxide and silane coupling agent KH570 to deionized water is as follows: 1: 10, the ultrasonic frequency is 27KHz, and the ultrasonic power is 1300W; in the third step, the microwave frequency is 1550MHz, and the microwave output power density is 130mW/cm³The inert gas is one of nitrogen, argon and helium; in the fourth step, in the electrostatic spinning process, 18KV high voltage is applied, and the distance between the capillary nozzle of the injector and the receiving device is 11 cm.

10. The preparation method of the anti-cracking and anti-corrosion mortar according to claim 7, wherein the preparation method comprises the following steps: in the second step, the weight ratio of the total weight of silver nitrate, glucose, graphene oxide, polyimide fibers, hollow glass microspheres, nano titanium dioxide and silane coupling agent KH570 to deionized water is as follows: 1: 7, the ultrasonic frequency is 25KHz, and the ultrasonic power is 1100W; in the third step, the microwave frequency is 1450MHz, and the microwave output power density is 120mW/cm³The inert gas is one of nitrogen, argon and helium; in the fourth step, in the electrostatic spinning treatment process, 17KV high voltage is applied, and the distance between the capillary nozzle of the injector and the receiving device is 10 cm.

Technical Field

The invention relates to the technical field of building construction mortar, in particular to anti-cracking and anti-corrosion mortar and a preparation method thereof.

Background

Mortar is a bonding substance used for building bricks in building construction, and is synthesized by adding water into sand and cementing materials (cement, lime paste, clay and the like) in a certain proportion, and is also called mortar. The mortar used in common use is: cement mortar, mixed mortar (or cement lime mortar), lime mortar and clay mortar. The main difference between the building mortar and the concrete is that the building mortar does not contain coarse aggregate, and the building mortar is prepared by a cementing material, fine aggregate and water according to a certain proportion. The reasonable use of the mortar plays an important role in saving cementing materials, facilitating construction and improving engineering quality. The method is divided into the following steps according to different purposes: masonry mortar, finishing mortar (including decorative mortar and waterproof mortar), bonding mortar and the like.

The existing mortar is easy to crack and generate corrosion damage after being used for a long time in the outdoor environment of alpine plateau.

Disclosure of Invention

In order to overcome the above defects of the prior art, embodiments of the present invention provide a crack-resistant and corrosion-resistant mortar and a preparation method thereof.

The anti-cracking and anti-corrosion mortar comprises the following components in percentage by weight: 24.60-25.80% of cement, 16.60-17.80% of water, 3.10-3.50% of latex powder, 6.40-8.20% of basalt fiber, 4.40-5.20% of composite reinforcing agent and the balance of quartz sand.

Further, the composite reinforcing agent comprises the following components in percentage by weight: 8.40-9.20% of silver nitrate, 9.40-10.20% of glucose, 7.40-8.20% of graphene oxide, 10.80-11.40% of polyimide fibers, 18.80-19.40% of hollow glass microspheres, 7.80-8.40% of nano titanium dioxide, 0.30-0.50% of silane coupling agent KH570, and the balance of epoxy resin.

Further, the paint comprises the following components in percentage by weight: 24.60% of cement, 16.60% of water, 3.10% of latex powder, 6.40% of basalt fiber, 4.40% of composite reinforcing agent and 44.90% of quartz sand; the composite reinforcing agent comprises the following components in percentage by weight: 8.40% of silver nitrate, 9.40% of glucose, 7.40% of graphene oxide, 10.80% of polyimide fibers, 18.80% of hollow glass microspheres, 7.80% of nano titanium dioxide, 0.30% of silane coupling agent KH570 and 37.10% of epoxy resin.

Further, the paint comprises the following components in percentage by weight: 25.80% of cement, 17.80% of water, 3.50% of latex powder, 8.20% of basalt fiber, 5.20% of composite reinforcing agent and 39.50% of quartz sand; the composite reinforcing agent comprises the following components in percentage by weight: 9.20% of silver nitrate, 10.20% of glucose, 8.20% of graphene oxide, 11.40% of polyimide fibers, 19.40% of hollow glass microspheres, 8.40% of nano titanium dioxide, 0.50% of silane coupling agent KH570 and 32.70% of epoxy resin.

Further, the paint comprises the following components in percentage by weight: 25.20% of cement, 17.20% of water, 3.30% of latex powder, 7.30% of basalt fiber, 4.80% of composite reinforcing agent and 42.20% of quartz sand; the composite reinforcing agent comprises the following components in percentage by weight: 8.80% of silver nitrate, 9.80% of glucose, 7.80% of graphene oxide, 11.10% of polyimide fibers, 19.10% of hollow glass microspheres, 8.10% of nano titanium dioxide, 0.40% of silane coupling agent KH570 and 34.90% of epoxy resin.

A preparation method of anti-cracking corrosion-resistant mortar comprises the following specific preparation steps:

the method comprises the following steps: weighing the above cement, latex powder, basalt fiber, water, quartz sand and silver nitrate, glucose, graphene oxide, polyimide fiber, hollow glass microsphere, nano titanium dioxide, silane coupling agent KH570 and epoxy resin in the composite reinforcing agent in parts by weight;

step two: adding the silver nitrate, the glucose, the graphene oxide, the polyimide fibers, the hollow glass beads, the nano titanium dioxide and the silane coupling agent KH570 into deionized water, and performing ultrasonic treatment for 30-40 minutes to obtain a mixture A;

step three: adding the mixture A prepared in the step two into microwave equipment with a solvent collector, carrying out microwave irradiation stripping treatment for 2-3 minutes, and introducing inert gas to obtain a mixture B;

step four: blending and stirring the mixture B in the third step and the epoxy resin in the first step to obtain a mixture C, and adding the mixture C into an electrostatic spinning device for electrostatic spinning treatment to obtain a composite reinforcing agent;

step five: and C, blending and stirring the cement and the water in the step I, adding the latex powder in the step I and the composite reinforcing agent prepared in the step four, continuously stirring, finally adding the basalt fiber and the quartz sand in the step I, and continuously stirring to obtain the anti-cracking and anti-corrosion mortar.

Further, in the second step, the weight ratio of the total weight of the silver nitrate, the glucose, the graphene oxide, the polyimide fiber, the hollow glass microsphere, the nano titanium dioxide and the silane coupling agent KH570 to the deionized water is as follows: 1: 5-10, the ultrasonic frequency is 23-27 KHz, and the ultrasonic power is 900-1300W; in the third step, the microwave frequency is 1350-1550 MHz, and the microwave output power density is 110-130 mW/cm³The inert gas is one of nitrogen, argon and helium; in the fourth step, in the electrostatic spinning treatment process, 16-18 KV high voltage is applied, and the distance between a capillary nozzle of the injector and the receiving device is 9-11 cm.

Further, in the second step, the weight ratio of the total weight of the silver nitrate, the glucose, the graphene oxide, the polyimide fiber, the hollow glass microsphere, the nano titanium dioxide and the silane coupling agent KH570 to the deionized water is as follows: 1: 5, the ultrasonic frequency is 23KHz, and the ultrasonic power is 900W; in the third step, the microwave frequency is 1350MHz, and the microwave output power density is 110mW/cm³The inert gas is one of nitrogen, argon and helium; in the fourth step, 16KV high voltage is applied in the electrostatic spinning process, and the distance between the capillary nozzle of the injector and the receiving device is 9 cm.

Further, in the second step, the weight ratio of the total weight of the silver nitrate, the glucose, the graphene oxide, the polyimide fiber, the hollow glass microsphere, the nano titanium dioxide and the silane coupling agent KH570 to the deionized water is as follows: 1: 10, the ultrasonic frequency is 27KHz, and the ultrasonic power is 1300W; in the third step, the microwave frequency is 1550MHz, and the microwave output power density is 130mW/cm³The inert gas is one of nitrogen, argon and helium; in step four, the electrostatic spinningIn the treatment process, 18KV high voltage is applied, and the distance between the capillary nozzle of the injector and the receiving device is 11 cm.

Further, in the second step, the weight ratio of the total weight of the silver nitrate, the glucose, the graphene oxide, the polyimide fiber, the hollow glass microsphere, the nano titanium dioxide and the silane coupling agent KH570 to the deionized water is as follows: 1: 7, the ultrasonic frequency is 25KHz, and the ultrasonic power is 1100W; in the third step, the microwave frequency is 1450MHz, and the microwave output power density is 120mW/cm³The inert gas is one of nitrogen, argon and helium; in the fourth step, in the electrostatic spinning treatment process, 17KV high voltage is applied, and the distance between the capillary nozzle of the injector and the receiving device is 10 cm.

The invention has the technical effects and advantages that:

1. the anti-cracking and anti-corrosion mortar processed by the raw material formula can effectively improve the wear resistance, corrosion resistance and high-cold resistance of the anti-cracking and anti-corrosion mortar, and can effectively prevent the anti-cracking and anti-corrosion performance of the mortar product in the high-cold plateau environment; mixing silver nitrate, glucose and graphene oxide in the composite reinforcing agent in deionized water, and performing ultrasonic treatment to prepare a composite material of nano silver particles, graphene and graphene oxide; the nano titanium dioxide can be modified, and then the modified nano titanium dioxide is compounded with the graphene oxide; the polyimide fiber is a supporting network in the composite reinforcing agent, the hollow glass beads can be used as a supporting frame, and the modified nano titanium dioxide, nano silver particles, graphene and graphene oxide are compounded to the outside and the inside of the aperture of the hollow glass beads, so that the stability and the safety of the composite reinforcing agent can be effectively enhanced, and the wear resistance, the corrosion resistance and the high and cold resistance of the mortar are further ensured;

2. in the process of preparing the anti-cracking corrosion-resistant mortar, in the second step, blending 27KHz ultrasonic treatment is carried out, so that the nano titanium dioxide can be effectively modified, silver nitrate and graphene oxide are reduced into a composite material of nano silver particles, graphene and graphene oxide by glucose, and the modified nano titanium dioxide, nano silver particles, graphene and graphene oxide are blended with polyimide fibers and hollow glass beads for composite treatment; in the third step, the mixture A is subjected to microwave irradiation stripping treatment, and the modified nano titanium dioxide and nano silver particles are inserted into the graphene and the graphene oxide, so that the temperature resistance, the corrosion resistance, the wear resistance and the antibacterial performance of the composite reinforcing agent can be further enhanced; in the fourth step, after the mixture B and the epoxy resin are subjected to blending treatment, electrostatic spinning is performed, so that the composite treatment effect of the nano silver particles, the graphene oxide, the polyimide fibers, the hollow glass beads, the modified nano titanium dioxide and the epoxy resin can be effectively realized, and the wear resistance, the corrosion resistance and the high and cold resistance of the mortar can be effectively ensured.

Detailed Description

The following will clearly and completely describe the technical solutions in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

Example 1:

the invention provides anti-cracking and corrosion-resistant mortar, which comprises the following components: 24.60kg of cement, 16.60kg of water, 3.10kg of latex powder, 6.40kg of basalt fiber, 4.40kg of composite reinforcing agent and 44.90kg of quartz sand; the composite reinforcing agent comprises the following components in percentage by weight: 0.3696kg of silver nitrate, 0.4136kg of glucose, 0.3256kg of graphene oxide, 0.4752kg of polyimide fibers, 0.8272kg of hollow glass microspheres, 0.3432kg of nano titanium dioxide, 0.0132kg of silane coupling agent KH570 and 1.6324kg of epoxy resin;

the invention also provides a preparation method of the anti-cracking and corrosion-resistant mortar, which comprises the following specific preparation steps:

the method comprises the following steps: weighing the above cement, latex powder, basalt fiber, water, quartz sand and silver nitrate, glucose, graphene oxide, polyimide fiber, hollow glass microsphere, nano titanium dioxide, silane coupling agent KH570 and epoxy resin in the composite reinforcing agent in parts by weight;

step two: adding the silver nitrate, the glucose, the graphene oxide, the polyimide fibers, the hollow glass beads, the nano titanium dioxide and the silane coupling agent KH570 in the step one into deionized water, and performing ultrasonic treatment for 30 minutes to obtain a mixture A;

step three: adding the mixture A prepared in the step two into microwave equipment with a solvent collector, carrying out microwave irradiation stripping treatment for 2 minutes, and introducing inert gas to obtain a mixture B;

step four: blending and stirring the mixture B in the third step and the epoxy resin in the first step to obtain a mixture C, and adding the mixture C into an electrostatic spinning device for electrostatic spinning treatment to obtain a composite reinforcing agent;

step five: and C, blending and stirring the cement and the water in the step I, adding the latex powder in the step I and the composite reinforcing agent prepared in the step four, continuously stirring, finally adding the basalt fiber and the quartz sand in the step I, and continuously stirring to obtain the anti-cracking and anti-corrosion mortar.

In the second step, the weight ratio of the total weight of silver nitrate, glucose, graphene oxide, polyimide fibers, hollow glass microspheres, nano titanium dioxide and silane coupling agent KH570 to deionized water is as follows: 1: 5, the ultrasonic frequency is 23KHz, and the ultrasonic power is 900W; in the third step, the microwave frequency is 1350MHz, and the microwave output power density is 110mW/cm³The inert gas is one of nitrogen, argon and helium; in the fourth step, 16KV high voltage is applied in the electrostatic spinning process, and the distance between the capillary nozzle of the injector and the receiving device is 9 cm.

Example 2:

different from the embodiment 1, the method comprises the following steps: 25.80kg of cement, 17.80kg of water, 3.50kg of latex powder, 8.20kg of basalt fiber, 5.20kg of composite reinforcing agent and 39.50kg of quartz sand; the composite reinforcing agent comprises the following components in percentage by weight: 0.4784kg of silver nitrate, 0.5304kg of glucose, 0.4264kg of graphene oxide, 0.5928kg of polyimide fibers, 1.0088kg of hollow glass microspheres, 0.4368kg of nano titanium dioxide, 0.026kg of silane coupling agent KH570 and 1.7004kg of epoxy resin.

Example 3:

unlike the examples 1 to 2, the present invention comprises: 25.20kg of cement, 17.20kg of water, 3.30kg of latex powder, 7.30kg of basalt fiber, 4.80kg of composite reinforcing agent and 42.20kg of quartz sand; the composite reinforcing agent comprises the following components in percentage by weight: 0.4224kg of silver nitrate, 0.4704kg of glucose, 0.3744kg of graphene oxide, 0.5328kg of polyimide fibers, 0.9168kg of hollow glass microspheres, 0.3888kg of nano titanium dioxide, 0.0192kg of silane coupling agent KH570 and 1.6752kg of epoxy resin.

The anti-cracking and corrosion-resistant mortar prepared in the above examples 1-3, the anti-cracking and corrosion-resistant mortar of the first control group, the anti-cracking and corrosion-resistant mortar of the second control group, the anti-cracking and corrosion-resistant mortar of the fourth control group, the anti-cracking and corrosion-resistant mortar of the fifth control group and the anti-cracking and corrosion-resistant mortar of the sixth control group are respectively taken, the anti-cracking and corrosion-resistant mortar of the first control group has no silver nitrate compared with the examples, the anti-cracking and corrosion-resistant mortar of the second control group has no glucose compared with the examples, the anti-cracking and corrosion-resistant mortar of the third control group has no graphene oxide compared with the examples, the anti-cracking and corrosion-resistant mortar of the fourth control group has no polyimide fiber compared with the examples, the anti-cracking and corrosion-resistant mortar of the fifth control group has no hollow glass bead compared with the examples, and the anti-cracking and corrosion-resistant mortar of the sixth control group has no nano titanium dioxide compared with the examples, testing the anti-cracking corrosion-resistant mortar processed in the three embodiments and the anti-cracking corrosion-resistant mortar of six control groups respectively in nine groups, preparing 30 groups of anti-cracking corrosion-resistant mortar in each control group and embodiment, coating the anti-cracking corrosion-resistant mortar on a wallboard with the coating thickness of 3cm, and testing after drying; the test results are shown in table one:

table one:

as can be seen from Table I, when the cracking-resistant and corrosion-resistant mortar comprises the following raw materials in proportion: 25.20kg of cement, 17.20kg of water, 3.30kg of latex powder, 7.30kg of basalt fiber, 4.80kg of composite reinforcing agent and 42.20kg of quartz sand; the composite reinforcing agent comprises the following components in percentage by weight: 0.4224kg of silver nitrate, 0.4704kg of glucose, 0.3744kg of graphene oxide, 0.5328kg of polyimide fiber, 0.9168kg of hollow glass microsphere, 0.3888kg of nano titanium dioxide, 0.0192kg of silane coupling agent KH570 and 1.6752kg of epoxy resin, so that the wear resistance, corrosion resistance and high-cold resistance of the anti-cracking and corrosion-resistant mortar can be effectively improved, and the anti-cracking and corrosion-resistant performance of the mortar product in a high-cold plateau environment can be effectively prevented; example 3 is a preferred embodiment of the present invention, silver nitrate, glucose and graphene oxide in the composite reinforcing agent are mixed in deionized water and subjected to ultrasonic treatment, and the glucose can effectively perform a reduction reaction on the silver nitrate and the graphene oxide to prepare a composite material of nano silver particles, graphene and graphene oxide, so that the temperature resistance, corrosion resistance, wear resistance and antibacterial performance of the composite reinforcing agent can be effectively enhanced; the silane coupling agent KH570 is compounded with the nano titanium dioxide, so that the nano titanium dioxide can be effectively modified, and then the modified nano titanium dioxide is compounded with the graphene oxide, so that the low-temperature resistance of the composite reinforcing agent can be further enhanced, and the low-temperature resistance of the mortar is further improved; the polyimide fiber is a supporting network in the composite reinforcing agent, so that the high and low temperature resistance, the ultraviolet resistance and the flame retardant property of the composite reinforcing agent can be effectively enhanced, the hollow glass beads can be used as a supporting frame, the modified nano titanium dioxide, nano silver particles, graphene and graphene oxide are compounded to the outside and the inside of the aperture of the hollow glass beads, the stability and the safety of the composite reinforcing agent can be effectively enhanced, and the wear resistance, the corrosion resistance and the high and cold resistance of the mortar are further ensured.

Example 4:

the invention provides anti-cracking and anti-corrosion mortar, which comprises 25.20kg of cement, 17.20kg of water, 3.30kg of emulsion powder, 7.30kg of basalt fiber, 4.80kg of composite reinforcing agent and 42.20kg of quartz sand; the composite reinforcing agent comprises the following components in percentage by weight: 0.4224kg of silver nitrate, 0.4704kg of glucose, 0.3744kg of graphene oxide, 0.5328kg of polyimide fibers, 0.9168kg of hollow glass microspheres, 0.3888kg of nano titanium dioxide, 0.0192kg of silane coupling agent KH570 and 1.6752kg of epoxy resin;

the invention also provides a preparation method of the anti-cracking and corrosion-resistant mortar, which comprises the following specific processing steps:

the method comprises the following steps: weighing the above cement, latex powder, basalt fiber, water, quartz sand and silver nitrate, glucose, graphene oxide, polyimide fiber, hollow glass microsphere, nano titanium dioxide, silane coupling agent KH570 and epoxy resin in the composite reinforcing agent in parts by weight;

step two: adding the silver nitrate, the glucose, the graphene oxide, the polyimide fibers, the hollow glass beads, the nano titanium dioxide and the silane coupling agent KH570 in the step one into deionized water, and performing ultrasonic treatment for 35 minutes to obtain a mixture A;

step three: adding the mixture A prepared in the step two into microwave equipment with a solvent collector, carrying out microwave irradiation stripping treatment for 2.5 minutes, and introducing inert gas to obtain a mixture B;

step four: blending and stirring the mixture B in the third step and the epoxy resin in the first step to obtain a mixture C, and adding the mixture C into an electrostatic spinning device for electrostatic spinning treatment to obtain a composite reinforcing agent;

step five: and C, blending and stirring the cement and the water in the step I, adding the latex powder in the step I and the composite reinforcing agent prepared in the step four, continuously stirring, finally adding the basalt fiber and the quartz sand in the step I, and continuously stirring to obtain the anti-cracking and anti-corrosion mortar.

In the second step, the weight ratio of the total weight of silver nitrate, glucose, graphene oxide, polyimide fibers, hollow glass microspheres, nano titanium dioxide and silane coupling agent KH570 to deionized water is as follows: 1: 5, the ultrasonic frequency is 23KHz, and the ultrasonic power is 900W; in the third step, the microwave frequency is 1350MHz, and the microwave output power density isIs 110mW/cm³The inert gas is one of nitrogen, argon and helium; in the fourth step, 16KV high voltage is applied in the electrostatic spinning process, and the distance between the capillary nozzle of the injector and the receiving device is 9 cm.

Example 5:

different from the example 4, in the second step, the weight ratio of the total weight of the silver nitrate, the glucose, the graphene oxide, the polyimide fiber, the hollow glass microspheres, the nano titanium dioxide and the silane coupling agent KH570 to the deionized water is as follows: 1: 10, the ultrasonic frequency is 27KHz, and the ultrasonic power is 1300W; in the third step, the microwave frequency is 1550MHz, and the microwave output power density is 130mW/cm³The inert gas is one of nitrogen, argon and helium; in the fourth step, in the electrostatic spinning process, 18KV high voltage is applied, and the distance between the capillary nozzle of the injector and the receiving device is 11 cm.

Example 6:

different from the examples 4 to 5, in the second step, the weight ratio of the total weight of the silver nitrate, the glucose, the graphene oxide, the polyimide fiber, the hollow glass microspheres, the nano titanium dioxide and the silane coupling agent KH570 to the deionized water is as follows: 1: 7, the ultrasonic frequency is 25KHz, and the ultrasonic power is 1100W; in the third step, the microwave frequency is 1450MHz, and the microwave output power density is 120mW/cm³The inert gas is one of nitrogen, argon and helium; in the fourth step, in the electrostatic spinning treatment process, 17KV high voltage is applied, and the distance between the capillary nozzle of the injector and the receiving device is 10 cm.

The anti-cracking and anti-corrosion mortar prepared in the above examples 4 to 6, the anti-cracking and anti-corrosion mortar of the seventh control group, the anti-cracking and anti-corrosion mortar of the eighth control group and the anti-cracking and anti-corrosion mortar of the ninth control group were respectively taken, compared with the embodiment, the anti-cracking and anti-corrosion mortar of the seventh control group has no operation in the second step, compared with the embodiment, the anti-cracking and anti-corrosion mortar of the eighth control group has no operation in the third step, compared with the embodiment, the cracking-resistant corrosion-resistant mortar of the control group nine does not have the operation in the fourth step, the cracking-resistant corrosion-resistant mortar processed in the three embodiments and the cracking-resistant corrosion-resistant mortar of the three control groups are respectively tested in six groups, each control group and the embodiment are used for preparing 30 groups of cracking-resistant corrosion-resistant mortar, the cracking-resistant corrosion-resistant mortar is coated on the wallboard, the coating thickness is 3cm, the test is carried out after the cracking-resistant corrosion-resistant mortar is dried, and the test results are shown in the table two:

table two:

as can be seen from table two, example 6 is a preferred embodiment of the present invention; in the second step, blending 27KHz ultrasonic treatment is carried out on silver nitrate, glucose, graphene oxide, polyimide fibers, hollow glass beads, nano titanium dioxide and a silane coupling agent KH570 and deionized water, so that the nano titanium dioxide can be effectively modified, the silver nitrate and the graphene oxide are reduced into a composite material of nano silver particles, graphene and graphene oxide by the glucose, and the modified nano titanium dioxide, the nano silver particles, the graphene and the graphene oxide are blended and compounded with the polyimide fibers and the hollow glass beads; in the third step, the mixture A is subjected to microwave irradiation stripping treatment, so that graphene and graphene oxide can be effectively stripped and layered, and the modified nano titanium dioxide and nano silver particles are inserted into the graphene and graphene oxide, so that the temperature resistance, corrosion resistance, wear resistance and antibacterial property of the composite reinforcing agent can be further enhanced; in the fourth step, after the mixture B and the epoxy resin are subjected to blending treatment, electrostatic spinning is performed, so that the composite treatment effect of the nano silver particles, the graphene oxide, the polyimide fibers, the hollow glass beads, the modified nano titanium dioxide and the epoxy resin can be effectively realized, the stability of the composite reinforcing agent is better, and the wear resistance, the corrosion resistance and the high and cold resistance of the mortar can be effectively ensured.

It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.

Finally, it should be noted that: although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that changes may be made in the embodiments and/or equivalents thereof without departing from the spirit and scope of the invention. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.