阅读说明：本技术 一种速溶型祛味剂、其制备方法及其应用 (Instant deodorant, preparation method and application thereof ) 是由 杜维威 邵添恒 于 2021-07-13 设计创作，主要内容包括：本发明涉及祛味剂技术领域,具体涉及一种速溶型祛味剂、其制备方法及其应用。其制备方法为：将重量份为衣康酸锌、乙二胺四乙酸钠、无水硫酸钠、硬脂酸钙、碳酸氢钠、十二烷基硫酸钠、C14-16烯烃磺酸钠,份卡松防腐剂均匀混合后烘干,冷却后加入薰衣草粉末香精和份一水柠檬酸混合均匀后进行压片处理。本发明的产品该组合物可用于室内异味的清洁,其具有方便运输、保存时间长的优点。(The invention relates to the technical field of smell removing agents, and particularly relates to an instant smell removing agent, and a preparation method and application thereof. The preparation method comprises the following steps: uniformly mixing zinc itaconate, sodium ethylene diamine tetracetate, anhydrous sodium sulfate, calcium stearate, sodium bicarbonate, sodium dodecyl sulfate, C14-16 olefin sodium sulfonate and the kathon preservative in parts by weight, drying, cooling, adding lavender powder essence and citric acid monohydrate in parts by weight, uniformly mixing, and tabletting. The product of the invention can be used for cleaning indoor peculiar smell, and has the advantages of convenient transportation and long storage time.)

1. The instant deodorant is characterized by being prepared from the following raw materials in parts by weight: 10-20 parts of disintegrating agent, 1-3 parts of zinc itaconate and 30-50 parts of anhydrous sodium sulfate.

2. The instant deodorant according to claim 1, wherein the flavor-enhancing agent comprises: the disintegrating agent comprises 5-10 parts of citric acid monohydrate and 5-10 parts of sodium bicarbonate.

3. The instant deodorant according to claim 1, wherein the flavor-enhancing agent comprises: the paint also comprises 1-5 parts of sodium dodecyl sulfate and 1-5 parts of C14-16 olefin sodium sulfonate.

4. The instant deodorant according to claim 1, wherein the flavor-enhancing agent comprises: and also comprises 1-3 parts of sodium ethylene diamine tetracetate.

5. The instant deodorant according to claim 1, wherein the flavor-enhancing agent comprises: and one or more of 0.1-1 part of lavender powder essence, 0.1-1 part of orange powder essence or 0.1-1 part of lemon powder essence.

6. The instant deodorant according to claim 1, wherein the flavor-enhancing agent comprises: and 0.01-0.07 part of kasong preservative.

7. The instant deodorant according to claim 1, wherein the flavor-enhancing agent comprises: and also comprises 1-3 parts of calcium stearate.

8. The method for preparing an instant deodorant according to any one of claims 1 to 7, characterized in that: uniformly mixing 1-3 parts by weight of zinc itaconate, 1-3 parts by weight of sodium ethylene diamine tetracetate, 30-50 parts by weight of anhydrous sodium sulfate, 1-3 parts by weight of calcium stearate, 5-10 parts by weight of sodium bicarbonate, 1-5 parts by weight of sodium dodecyl sulfate, 1-5 parts by weight of C14-16 olefin sodium sulfonate and 0.01-0.07 part by weight of Kathon preservative, adding one or more of 0.1-1 part by weight of lavender powder essence, 0.1-1 part by weight of orange powder essence or 0.1-1 part by weight of lemon powder essence and 5-10 parts by weight of citric acid monohydrate, and tabletting.

9. The method for preparing an instant deodorant according to claim 7, wherein the method comprises the following steps: uniformly mixing 1-3 parts by weight of zinc itaconate, 1-3 parts by weight of sodium ethylene diamine tetracetate, 30-50 parts by weight of anhydrous sodium sulfate, 1-3 parts by weight of calcium stearate, 5-10 parts by weight of sodium bicarbonate, 1-5 parts by weight of sodium dodecyl sulfate, 1-5 parts by weight of C14-16 olefin sodium sulfonate and 0.01-0.07 part by weight of Kathon preservative, drying at 90-120 ℃, cooling, adding one or more of 0.1-1 part by weight of lavender powder essence, 0.1-1 part by weight of orange powder essence or 0.1-1 part by weight of lemon powder essence and 5-10 parts by weight of citric acid monohydrate, uniformly mixing, and tabletting.

10. The use of the instant deodorant according to any one of claims 1 to 7, wherein the use of the instant deodorant comprises: and (3) putting the odor removing agent into water with the mass part of 50-70 times, and after the odor removing agent is fully dissolved, carrying out spray treatment towards an object to be cleaned or air.

Technical Field

The invention relates to the field of odor removing agents, in particular to an instant odor removing agent and a preparation method thereof.

Background

Formaldehyde peculiar smell brought by home decoration has negative effects of stimulation, sensitization, mutation and the like, and the health of people is greatly harmed; the household quality is greatly influenced by the mildew smell in the environment, the kitchen peculiar smell (oil smoke, acid odor and the like), the toilet peculiar smell and the like, and the carried bacterial spores, rancid oil, methyl mercaptan, methylamine, NH3 and the like cause diseases, carcinogenesis and other hazards to people. Various household articles, personal articles such as shoes and socks, articles such as clothes and cloth in a vehicle and the like can accumulate a great amount of bacteria, fungi, viruses and dust mite pollution along with the prolonging of the service life.

At present, chinese patent application No. cn201310249838.x discloses a bactericidal deodorant comprising: 0.25-5 wt% of organosilicon quaternary ammonium salt; 0.1-2% by weight of an organosilicon coupling agent; 0.2-2% by weight of a stabilizer; the balance of deionized water; the sterilization deodorant provided by the invention has the effects of resisting bacteria, preventing mildew, removing odor and preventing odor, has a lasting antibacterial effect and a wide antibacterial range, is safe and reliable for any product, and does not pollute the environment. The organosilicon quaternary ammonium salt has the functions of sterilization and bacteriostasis, and the performance of the organosilicon quaternary ammonium salt, which is nontoxic, mild, soft and smooth to human bodies, is used for preparing the sterilization deodorant of the invention into a spray type medicament form, is used for the sterilization treatment of various trauma infections and skin infections, can quickly sterilize and relieve itching of various skin infections, and can kill bacteria and inhibit the activity of the bacteria.

Aiming at the related technical scheme, the inventor thinks that the sterilizing and deodorizing agent is liquid packaged by a bottle, the storage time is short, the transportation is inconvenient, and the processing and production cost is high.

Disclosure of Invention

The invention provides an instant deodorant, a preparation method and application thereof, and aims to reduce the production cost of the sterilization deodorant and facilitate transportation of the sterilization deodorant.

In a first aspect, the instant deodorant, the preparation method and the application thereof provided by the invention adopt the following technical scheme:

an instant deodorant is prepared from the following raw materials in parts by weight: 10-20 parts of disintegrating agent, 1-3 parts of zinc itaconate and 30-50 parts of anhydrous sodium sulfate.

By adopting the technical scheme, after the zinc itaconate is dissolved in water, amines, aldehydes, sulfur-containing compounds and lower fatty acid in the air are decomposed into carbon dioxide, water, sulfate ions and nitrate ions by the zinc ions and the itaconic acid, so that the odor in the air is eliminated. The disintegrant plays roles of foaming and propelling, so that the zinc itaconate is rapidly mixed in water, the anhydrous sodium sulfate has excellent hygroscopicity, and the condition that the zinc itaconate is denatured and ineffective due to the interference of moisture in the air in the preservation process of the odor removing agent is reduced. The stability of the zinc itaconate is higher than that of the itaconic acid, and the zinc itaconate is more resistant to alkaline substances than the itaconic acid, so that the zinc itaconate is not easy to deteriorate due to the fact that anhydrous sodium sulfate absorbs water and is alkaline. The odor removing agent after compression molding is dissolved in water and then sprayed into the air, so that the odor in the air is removed, the odor removing agent is convenient to transport, a large storage space is not needed, meanwhile, the odor removing agent after compression molding is not easy to deteriorate, and the storage time of the odor removing agent is longer compared with that of a liquid odor removing agent.

Preferably, the disintegrating agent comprises 5-10 parts of citric acid monohydrate and 5-10 parts of sodium bicarbonate.

By adopting the technical scheme, the anhydrous sodium sulfate has better hygroscopicity, so that the citric acid monohydrate and the sodium bicarbonate are kept dry, and the storage time of the citric acid monohydrate and the sodium bicarbonate is prolonged. After citric acid monohydrate and sodium bicarbonate enter water, a large number of bubbles are generated, so that zinc itaconate is rapidly dispersed in water, and the rapid dissolution of the zinc itaconate in the water is promoted.

Preferably, the instant deodorant also comprises 1-5 parts of sodium dodecyl sulfate and 1-5 parts of C14-16 olefin sodium sulfonate.

By adopting the technical scheme, the sodium dodecyl sulfate and the C14-16 olefin sodium sulfonate promote the zinc itaconate to be quickly dissolved in water, and meanwhile, solutes in the water are kept in a suspended state for a long time, so that the long-time use of the deodorant is facilitated.

Preferably, the instant deodorant also comprises 1-3 parts of sodium ethylene diamine tetracetate.

By adopting the technical scheme, the sodium ethylene diamine tetracetate and calcium and magnesium ions in water have chelation reaction, so that the reaction of the calcium and magnesium ions with sodium dodecyl sulfate and C14-16 olefin sodium sulfonate is reduced.

Preferably, the instant deodorant also comprises one or more of 0.1-1 part of lavender powder essence, 0.1-1 part of orange powder essence or 0.1-1 part of lemon powder essence.

By adopting the technical scheme, the lavender powder essence is sprayed into the air, so that the air quality is improved, and the lavender powder essence is sprayed onto an object, so that the smell of the object is more comfortable and better smells.

Preferably, the instant deodorant also comprises 0.01-0.07 part of a kasong preservative.

By adopting the technical scheme, the kasong preservative enables the storage time of the deodorant to be longer, and can kill bacteria in the air or on the surface of an object.

Preferably, the instant deodorant also comprises 1-3 parts of calcium stearate.

By adopting the technical scheme, the sodium stearate has the function of demoulding, so that the deodorant is conveniently compressed and formed.

In a second aspect, the invention provides a preparation method of an instant deodorant, which adopts the following technical scheme:

a preparation method of an instant deodorant comprises the steps of uniformly mixing 1-3 parts by weight of zinc itaconate, 1-3 parts by weight of sodium ethylene diamine tetracetate, 30-50 parts by weight of anhydrous sodium sulfate, 1-3 parts by weight of calcium stearate, 5-10 parts by weight of sodium bicarbonate, 1-5 parts by weight of sodium dodecyl sulfate, 1-5 parts by weight of C14-16 olefin sodium sulfonate and 0.01-0.07 part by weight of a kasong preservative, adding one or more of 0.1-1 part of lavender powder essence, 0.1-1 part of orange powder essence or 0.1-1 part of lemon powder essence and 5-10 parts by weight of citric acid monohydrate, and uniformly mixing and then carrying out tabletting treatment.

By adopting the technical scheme, the smell removing agent after compression molding is convenient to transport, the smell removing agent is thrown into water, citric acid monohydrate and sodium bicarbonate generate a large amount of bubbles after entering the water, so that zinc itaconate is rapidly dispersed in the water, the rapid dissolution of the zinc itaconate in the water is promoted, after the zinc itaconate is dissolved in the water, amines, aldehydes, sulfur-containing compounds and lower fatty acid in the air are decomposed into carbon dioxide, water, sulfate ions and nitrate ions by the itaconic acid and the zinc ions, and the odor in the air is eliminated.

Preferably, 1-3 parts by weight of zinc itaconate, 1-3 parts by weight of sodium ethylene diamine tetracetate, 30-50 parts by weight of anhydrous sodium sulfate, 1-3 parts by weight of calcium stearate, 5-10 parts by weight of sodium bicarbonate, 1-5 parts by weight of sodium dodecyl sulfate, 1-5 parts by weight of C14-16 olefin sodium sulfonate and 0.01-0.07 part by weight of Kathon preservative are uniformly mixed, then dried at 90-120 ℃, cooled, added with one or more of 0.1-1 part by weight of lavender powder essence, 0.1-1 part by weight of orange powder essence or 0.1-1 part by weight of lemon powder essence and 5-10 parts by weight of citric acid monohydrate, and then tabletted.

By adopting the technical scheme, the mixing and tabletting treatment is carried out in a dry environment, so that the contact of zinc itaconate, citric acid monohydrate and sodium bicarbonate in the smell removing agent with moisture in the air is reduced, and the storage time of the smell removing agent is prolonged.

In a third aspect, the invention provides an application of an instant deodorant, which adopts the following technical scheme:

an application of an instant smell remover is that the smell remover is placed in water with the mass part of 50-70 times that of the smell remover, and after the smell remover is fully dissolved, the smell remover is sprayed towards an object to be cleaned or air.

By adopting the technical scheme, the zinc ions decompose amines, aldehydes, sulfur-containing compounds and lower fatty acid in the air into carbon dioxide, water, sulfate ions and nitrate ions, thereby eliminating the odor in the air.

In conclusion, the invention has the following beneficial effects:

1. according to the invention, zinc itaconate and sodium sulfate are adopted, and after the zinc itaconate is dissolved in water, amines, aldehydes, sulfur-containing compounds and lower fatty acid in the air are decomposed into carbon dioxide, water, sulfate ions and nitrate ions by zinc ions, so that the odor in the air is eliminated. The disintegrant plays a propelling role in the foaming process, so that the zinc itaconate is quickly mixed in water, the lauryl sodium sulfate and the C14-16 olefin sodium sulfonate promote the quick dissolution of the zinc itaconate, and the sodium ethylene diamine tetracetate and calcium and magnesium ions in the water generate a chelation reaction, so that the reaction of the calcium and magnesium ions and a surfactant is reduced, the anhydrous sodium sulfate has excellent hygroscopicity, and the condition that the zinc itaconate is denatured and ineffective due to the interference of moisture in the air in the preservation process of the odor removing agent is reduced. The stability of the zinc itaconate is higher than that of the itaconic acid, and the zinc itaconate is more resistant to alkaline substances than the itaconic acid, so that the zinc itaconate is not easy to deteriorate due to the fact that anhydrous sodium sulfate absorbs water and is alkaline. The sodium stearate has the function of demoulding, so that the smell removing agent is conveniently compressed and formed, and the smell removing agent after compression forming is dissolved in water and then sprayed into the air, so that the peculiar smell in the air is removed, the smell removing agent is conveniently transported, and a large storage space is not needed.

2. Citric acid monohydrate and sodium bicarbonate are preferably adopted in the invention, and a large number of bubbles are generated after the citric acid monohydrate and the sodium bicarbonate enter water, so that zinc itaconate is rapidly dispersed in the water, and the rapid dissolution of the zinc itaconate in the water is promoted.

3. According to the invention, sodium dodecyl sulfate and C14-16 olefin sodium sulfonate, which are preferably adopted, promote the zinc itaconate to be rapidly dissolved in water, and simultaneously enable solutes in the water to be kept in a suspended state for a long time, so that the long-time use of the deodorant is facilitated.

4. According to the method, the odor removing agent is tableted, the odor removing agent after compression molding is convenient to transport, the odor removing agent is thrown into water, citric acid monohydrate and sodium bicarbonate generate a large number of bubbles after entering the water, so that zinc itaconate is rapidly dispersed in the water, the zinc itaconate is promoted to be rapidly dissolved in the water, and after the zinc itaconate is dissolved in the water, amines, aldehydes, sulfur-containing compounds and lower fatty acid in the air are decomposed into carbon dioxide, water, sulfate ions and nitrate ions by the zinc ions, so that the odor in the air is eliminated.

Detailed Description

Raw materials

Examples

Example 1

1 g of zinc itaconate, 30 g of anhydrous sodium sulfate and 5 g of sodium bicarbonate are uniformly mixed, added with 5 g of citric acid monohydrate and uniformly mixed, and then tabletted and placed for one month.

And (3) putting the prepared smell removing agent into water with the mass part being 70 times and 3.15 kilograms, and carrying out spraying treatment towards an object to be cleaned or air after the smell removing agent is fully dissolved.

Example 2

1 g of zinc itaconate, 30 g of anhydrous sodium sulfate, 1 g of calcium stearate, 5 g of sodium bicarbonate, 1 g of sodium dodecyl sulfate and 1 g of C14-16 olefin sodium sulfonate are uniformly mixed, added with 5 g of citric acid monohydrate and uniformly mixed, then tabletting treatment is carried out, and the mixture is placed for one month.

And (3) placing the prepared smell removing agent into water with the mass part being 50 times and 2.25 kilograms, and carrying out spraying treatment towards an object to be cleaned or air after the smell removing agent is fully dissolved.

Example 3

1 g of zinc itaconate, 1 g of sodium ethylene diamine tetracetate, 30 g of anhydrous sodium sulfate, 1 g of calcium stearate, 5 g of sodium bicarbonate, 1 g of sodium dodecyl sulfate and 1 g of C14-16 olefin sodium sulfonate are uniformly mixed, added with 5 g of citric acid monohydrate, uniformly mixed and tableted, and placed for one month.

And (3) placing the prepared smell removing agent into water with the mass part being 50 times and 2.25 kilograms, and carrying out spraying treatment towards an object to be cleaned or air after the smell removing agent is fully dissolved.

Example 4

Uniformly mixing 1 g of zinc itaconate, 1 g of sodium ethylene diamine tetracetate, 30 g of anhydrous sodium sulfate, 1 g of calcium stearate, 5 g of sodium bicarbonate, 1 g of lauryl sodium sulfate, 1 g of C14-16 olefin sodium sulfonate and 0.01 g of a kalon preservative, drying at 90 ℃, cooling, adding 0.1 g of lavender powder essence and 5 g of citric acid monohydrate, uniformly mixing, tabletting, and standing for one month.

The prepared smell removing agent is placed in water with the mass part being 60 times that of 2.7 kilograms, and is sprayed towards an object to be cleaned or air after being fully dissolved.

Example 5

Uniformly mixing 1 g of zinc itaconate, 1 g of sodium ethylene diamine tetracetate, 30 g of anhydrous sodium sulfate, 1 g of calcium stearate, 5 g of sodium bicarbonate, 1 g of sodium dodecyl sulfate, 1 g of C14-16 olefin sodium sulfonate and 0.01 g of a kathon preservative, drying at 90 ℃, cooling, adding 0.1 g of lemon powder essence and 5 g of citric acid monohydrate, uniformly mixing, tabletting, and standing for one month.

The prepared smell removing agent is placed in water with the mass part being 60 times that of 2.7 kilograms, and is sprayed towards an object to be cleaned or air after being fully dissolved.

Example 6

Uniformly mixing 2 g of zinc itaconate, 2 g of sodium ethylene diamine tetracetate, 35 g of anhydrous sodium sulfate, 2 g of calcium stearate, 7 g of sodium bicarbonate, 3 g of sodium dodecyl sulfate, 3 g of C14-16 olefin sulfonate and 0.05 g of a cason preservative, drying at 110 ℃, cooling, adding 0.5 g of orange powder essence and 7 g of citric acid monohydrate, uniformly mixing, tabletting, and standing for one month.

The prepared smell removing agent is placed in water with the mass part being 60 times that of 2.7 kilograms, and is sprayed towards an object to be cleaned or air after being fully dissolved.

Example 7

Uniformly mixing 3 g of zinc itaconate, 3 g of sodium ethylene diamine tetracetate, 50 g of anhydrous sodium sulfate, 3 g of calcium stearate, 10 g of sodium bicarbonate, 5 g of lauryl sodium sulfate, 5 g of C14-16 olefin sodium sulfonate and 0.07 g of a Kathon preservative, drying at 120 ℃, cooling, adding 1 g of lavender powder essence and 10 g of citric acid monohydrate, uniformly mixing, tabletting, and standing for one month.

And (3) placing the prepared smell removing agent into water with the mass part being 60 times and 3.15 kilograms, and carrying out spraying treatment towards an object to be cleaned or air after the smell removing agent is fully dissolved.

Performance test

Detection method/test method

Oriented volume of 1m³Spraying 10ml of liquid mixed with deodorant into the closed space, wherein the ammonia concentration in the closed space before spraying is 2.0mg/m³After the spraying is finished, the spraying is waited for 5 minutes for detection, and specific detection data are shown in table 1:

TABLE 1

	Concentration before deodorization (mg/m)3)	Concentration after deodorization (mg/m)3)	Removal Rate (%)
				Example 1	2.0	0.25	87.5
Example 2	2.0	0.24	88.0
				Example 3	2.0	0.16	92.0
Example 4	2.0	0.15	93.5
				Example 5	2.0	0.11	94.5
Example 6	2.0	0.11	94.5
				Example 7	2.0	0.10	95.0

Oriented volume of 1m³Spraying 10ml of liquid mixed with deodorant in the sealed space, wherein the concentration of total volatile organic compounds in the sealed space before spraying is 4.0mg/m³And waiting for 5 minutes for detection after spraying is finished. Specific detection data are shown in table 2:

TABLE 2

	Concentration before deodorization (mg/m)3)	Concentration after deodorization (mg/m)3)	Removal Rate (%)
				Example 1	4.0	0.80	80.0
Example 2	4.0	0.60	85.0
				Example 3	4.0	0.56	86.0
Example 4	4.0	0.50	87.5
				Example 5	4.0	0.40	90.0
Example 6	4.0	0.34	91.5
				Example 7	4.0	0.33	91.8

It can be seen from the combination of examples 1, 6, 7, 1 and 2 that after zinc itaconate is dissolved in water, the zinc ions decompose ammonia and volatile organic compounds in the air into nitrate ions, carbon dioxide and water, thereby eliminating the odor in the air. Citric acid monohydrate and sodium bicarbonate, wherein a large number of bubbles are generated after the citric acid monohydrate and the sodium bicarbonate enter water, so that zinc itaconate is rapidly dispersed in the water, and the rapid dissolution of the zinc itaconate in the water is promoted. The sodium dodecyl sulfate and 1-5 parts of C14-16 sodium olefin sulfonate promote the rapid dissolution of zinc itaconate, and sodium ethylene diamine tetracetate and calcium and magnesium ions in water are subjected to a chelation reaction, so that the reaction of the calcium and magnesium ions and a surfactant is reduced, and the anhydrous sodium sulfate has excellent hygroscopicity, so that the condition that the zinc itaconate is denatured and ineffective due to the interference of moisture in the air in the preservation process of the odor removing agent is reduced. The stability of the zinc itaconate is higher than that of the itaconic acid, and the zinc itaconate is more resistant to alkaline substances than the itaconic acid, so that the zinc itaconate is not easy to deteriorate due to the fact that anhydrous sodium sulfate absorbs water and is alkaline. The sodium stearate has the function of demoulding, so that the smell removing agent is conveniently compressed and formed, and the smell removing agent after compression forming is dissolved in water and then sprayed into the air, so that the peculiar smell in the air is removed, the smell removing agent is conveniently transported, and a large storage space is not needed.

As can be seen from the combination of examples 1 and 5 and tables 1 and 2, the cason preservative allows the deodorant to be stored for a longer period of time, while killing bacteria in the air or on the surface of an object.

The present embodiment is only for explaining the present invention, and it is not limited to the present invention, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present invention.