Liquid crystal panel and method for manufacturing same
阅读说明:本技术 液晶面板及其制造方法 (Liquid crystal panel and method for manufacturing same ) 是由 金癸成 李应淇 金暎坤 李铉洙 金唯彬 金建佑 金泳台 于 2018-07-16 设计创作,主要内容包括:本发明涉及液晶面板及其制造方法,根据本发明的一个方面,提供了液晶面板,其包括具有第一表面和与第一表面相反的第二表面的液晶单元、设置在第一表面上的第一偏光板和设置在第二表面上的第二偏光板,其中第一偏光板和第二偏光板各自包括起偏振器层和结合至起偏振器层的低透湿性基材层,并且通过调节第一偏光板和第二偏光板的收缩力来控制第一偏光板与第二偏光板之间的挠曲平衡。(According to one aspect of the present invention, there is provided a liquid crystal panel including a liquid crystal cell having a first surface and a second surface opposite to the first surface, a first polarizing plate disposed on the first surface, and a second polarizing plate disposed on the second surface, wherein the first polarizing plate and the second polarizing plate each include a polarizer layer and a low moisture-permeable base material layer bonded to the polarizer layer, and a deflection balance between the first polarizing plate and the second polarizing plate is controlled by adjusting a contraction force of the first polarizing plate and the second polarizing plate.)
1. A liquid crystal panel includes a liquid crystal cell having a first surface and a second surface opposite to the first surface; a first polarizing plate disposed on the first surface; and a second polarizing plate disposed on the second surface, wherein the first polarizing plate and the second polarizing plate each include a polarizer layer and a low moisture permeability base material layer bonded to the polarizer layer, and the liquid crystal panel satisfies the following equation 1:
[ equation 1]
|αMD-αTD|≤1
In the case of the equation 1, the,MDis a value determined by equation 2, andTDfor the value determined by equation 3:
[ equation 2]
αMD(sum of absorption axial bending moments acting on each layer of the first polarizing plate)/(sum of transmission axial bending moments acting on each layer of the second polarizing plate)
[ equation 3]
αTD(sum of transmission axial bending moments acting on each layer of the first polarizing plate)/(sum of absorption axial bending moments acting on each layer of the second polarizing plate)
In equations 2 and 3, the absorbed axial bending moment acting on each layer is determined by the product of the distance from the center of the liquid crystal panel to the center of the relevant layer and the absorbed axial contraction force acting on the relevant layer, and
the transmissive axial bending moment acting on each layer is determined by the product of the distance from the center of the liquid crystal panel to the center of the relevant layer and the transmissive axial shrinkage force acting on the relevant layer.
2. The liquid crystal panel according to claim 1,
α thereinMDAnd αTDEach 0.8 to 1.2.
3. The liquid crystal panel according to claim 2,
α thereinMDAnd αTDEach 0.85 to 1.15.
4. The liquid crystal panel according to claim 1,
α thereinMDAnd αTDEach is 1.
5. The liquid crystal panel according to claim 1,
α thereinMDAnd αTDHave the same value.
6. The liquid crystal panel according to claim 1,
the following equation 4 is satisfied:
[ equation 4]
(αMD-1)(αTD-1)≤0。
7. The liquid crystal panel according to claim 1,
wherein the contraction force is determined based on a contraction rate.
8. The liquid crystal panel according to claim 1,
wherein the polarizer layer has an absorption axial contraction force of 5N to 9N when held at 80 ℃ for 2 hours.
9. The liquid crystal panel according to claim 1,
wherein when the low moisture-permeable base material layer is held at 80 ℃ for 2 hours, the low moisture-permeable base material layer has a transmission axial contractive force of 3N to 10N.
10. The liquid crystal panel according to claim 1,
wherein the polarizer layer and the low moisture permeability base material layer are bonded to each other via a UV adhesive layer.
11. The liquid crystal panel according to claim 1,
wherein the number of layers constituting the first polarizing plate and the second polarizing plate, respectively, is the same.
12. The liquid crystal panel according to claim 1,
wherein the number of layers constituting the first polarizing plate and the second polarizing plate, respectively, is different.
13. A method for manufacturing a liquid crystal panel by attaching a first polarizing plate and a second polarizing plate to both surfaces of a liquid crystal cell, respectively,
wherein the first polarizing plate and the second polarizing plate each comprise a polarizer layer and a low moisture permeability base material layer bonded to the polarizer layer, an
The method includes the step of producing the first polarizing plate and the second polarizing plate to satisfy the following equation 1:
[ equation 1]
|αMD-αTD|≤1
In equation 1, αMDIs the value determined by equation 2, and αTDFor the value determined by equation 3:
[ equation 2]
αMD(sum of absorption axial bending moments acting on each layer of the first polarizing plate)/(sum of transmission axial bending moments acting on each layer of the second polarizing plate)
[ equation 3]
αTD(sum of transmission axial bending moments acting on each layer of the first polarizing plate)/(sum of absorption axial bending moments acting on each layer of the second polarizing plate)
In equations 2 and 3, the absorbed axial bending moment acting on each layer is determined by the product of the distance from the center of the liquid crystal panel to the center of the relevant layer and the absorbed axial contraction force acting on the relevant layer, and
the transmissive axial bending moment acting on each layer is determined by the product of the distance from the center of the liquid crystal panel to the center of the relevant layer and the transmissive axial shrinkage force acting on the relevant layer.
14. The method for manufacturing a liquid crystal panel according to claim 13,
α thereinMDAnd αTDEach 0.8 to 1.2.
15. The method for manufacturing a liquid crystal panel according to claim 14,
α thereinMDAnd αTDEach 0.85 to 1.15.
16. The method for manufacturing a liquid crystal panel according to claim 13,
α thereinMDAnd αTDEach is 1.
17. The method for manufacturing a liquid crystal panel according to claim 13,
the following equation 4 is satisfied:
[ equation 4]
(αMD-1)(αTD-1)≤0。
18. The method for manufacturing a liquid crystal panel according to claim 13,
wherein the polarizer layer has an absorption axial contraction force of 5N to 9N when held at 80 ℃ for 2 hours.
19. The method for manufacturing a liquid crystal panel according to claim 13,
wherein when the low moisture-permeable base material layer is held at 80 ℃ for 2 hours, the low moisture-permeable base material layer has a transmission axial contractive force of 3N to 10N.
Technical Field
The invention relates to a liquid crystal panel and a manufacturing method thereof.
This application claims rights based on priority from korean patent application No. 10-2017-.
Background
A liquid crystal display device is a display that visualizes polarized light due to a conversion effect of liquid crystal, and is used in various categories from small-sized displays such as computers, notebook computers, electronic watches, and portable terminals to large-sized TVs.
A large number of polarizing plates, which have been mass-produced at present and are actually used for display devices, are polarizing plates obtained by bonding protective films, which are optically transparent and also have mechanical strength, to both sides or one side of a polarizing film (polarizer) formed by dyeing a polyvinyl alcohol-based film with iodine or a dichroic material such as a dichroic dye and crosslinking the film with a boron compound, followed by stretching and orientation.
However, the stretched polyvinyl alcohol-based film has a problem that shrinkage deformation easily occurs under durable conditions such as high temperature and high humidity. If the polarizer is deformed, the stress affects the protective film and the liquid crystal cell to cause warpage, and thus the following problems occur: such as a change in physical characteristics of a polarizing plate including the same and a light leakage phenomenon in a liquid crystal display device.
Disclosure of Invention
Technical problem
The problem to be solved by the invention is to provide a liquid crystal panel and a manufacturing method thereof, wherein the deflection balance of an upper polarizer and a lower polarizer can be adjusted by adjusting the contraction force of the polarizers.
Technical scheme
In order to solve the above problems, there is provided a liquid crystal panel including a liquid crystal cell having a first surface and a second surface opposite to the first surface; a first polarizing plate disposed on the first surface; and a second polarizing plate disposed on the second surface, wherein the first polarizing plate and the second polarizing plate each include a polarizer layer and a low moisture permeability base material layer bonded to the polarizer layer, and the liquid crystal panel satisfies the following equation 1.
[ equation 1]
|αMD-αTD|≤1
In equation 1, MD is a value determined by
[ equation 2]
αMD(sum of absorption axial bending moment) acting on each layer of the first polarizing plate)/(sum of transmission axial bending moment (transmission axial bending moment) acting on each layer of the second polarizing plate)
[ equation 3]
αTD(sum of transmitted axial bending moments acting on the respective layers of the first polarizing plate)/(sum of absorbed axial bending moments acting on the respective layers of the second polarizing plate)
In
the transmissive axial bending moment acting on each layer is determined by the product of the distance from the center of the liquid crystal panel to the center of the relevant layer and the transmissive axial contraction force acting on the relevant layer.
Advantageous effects
As described above, the liquid crystal panel and the method of manufacturing the same relating to at least one embodiment of the present invention have the following effects.
The deflection balance of the upper/lower polarizing plates can be adjusted by adjusting the contraction force of the polarizing plates.
In addition, cracks of the polarizing plate can be prevented, and a light leakage phenomenon of the liquid crystal display device can be prevented.
Drawings
Fig. 1 is a schematic sectional view showing a liquid crystal panel.
Fig. 2 shows the result of the evaluation of the bending of the polarizing plate.
Fig. 3 is a conceptual diagram for explaining
Detailed Description
Hereinafter, a liquid crystal panel and a method of manufacturing the same according to one embodiment of the present invention will be described in detail with reference to the accompanying drawings.
In addition, the same or similar reference numerals are given to the same or corresponding parts regardless of the reference numerals, redundant description thereof will be omitted, and the size and shape of each constituent element shown may be enlarged or reduced for convenience of description.
Fig. 1 is a schematic sectional view showing a
Further, fig. 2 shows the result of the bending evaluation of the polarizing plate, and fig. 3 is a conceptual diagram for explaining
Referring to fig. 1, a
In addition, the first and second polarizing
In this document, the MD direction indicates the absorption axis direction, and the TD direction indicates the transmission axis direction.
In addition, the first and second polarizing
Further, the
Further, the low moisture permeability
Further, the low moisture permeability
On the other hand, the shrinkage force can be measured by a DMA measurement instrument from TA Corporation. For example, the measurement instrument has no temperature acceleration conditions, starts at 25 ℃, reaches 75 ℃ after 3 minutes, and stabilizes at 80 ℃ after 7 minutes. The measurement time was 2 hours (120 minutes), and 120 minutes after stabilization at 80 ℃. In the measurement method, the sample was clamped to a jig, pulled and fixed to maintain the strain at 0.1% under a preload of 0.01N, and then the shrinkage force applied while maintaining the strain at 0.1% at a high temperature was measured. The sample was made to have a width of about 5.3mm and a length of about 15mm, both ends of the sample in the longitudinal direction were fixed to the grips of the measuring instrument, and then the contraction force was measured. Here, the sample length of 15mm is a length excluding a portion fixed to the jig.
Referring to fig. 2 and tables 1 and 2, the substrates a to C constitute a low moisture-permeable substrate layer, which is a low moisture-permeable substrate differing in only TD heat shrinkage characteristics and having the same other characteristics. At this time, the shrinkage force was data measured at 80 ℃ for 2 hours using a DMA measuring instrument from TA Corporation.
The polarizer layer and the low moisture permeability base material layer used in categories 1 to 5 of table 2 and fig. 2 are as follows. In categories 1 to 5, the polarizer layers are all the same, and the low moisture permeability base material layers have a difference only in the TD-direction shrinkage force.
For the polarizing plates (upper polarizing plate and lower polarizing plate), a PET film (MD shrink force: 0N to 1N, TD shrink force: 4N to 12N (categories 1 to 5), thickness: 80 μm) as a low moisture-permeable base material layer was attached to one side of a PVA polarizing film (MD shrink force: 8N, thickness: 17 μm) as a polarizer layer using an epoxy compound-based uv-curable adhesive (thickness: 2 μm to 3 μm). At the time of attachment, the TD direction of the PET film and the MD direction (absorption axis direction) of the PVA polarizing film are attached so as to be substantially perpendicular to each other. Subsequently, a hard coat layer was formed to a thickness of about 5 to 7 μm on the surface of the PVA polarizing film to which the PET film was not attached, using a material containing an epoxy compound and an oxetane compound. Thereafter, an acrylic pressure-sensitive adhesive layer having a thickness of about 25 μm was formed in the lower portion of the hard coat layer to produce a polarizing plate.
The upper polarizing plate was attached to the upper surface of a general 32-inch LCD (liquid crystal display) panel (liquid crystal cell, thickness: about 400 μm) by a pressure-sensitive adhesive layer, and the lower polarizing plate was attached to the lower surface by a pressure-sensitive adhesive layer.
Subsequently, the LCD panel was introduced into a chamber at a temperature of 60 ℃ for 72 hours, taken out, and the panel change amounts at an elapsed time of 2 hours and an elapsed time of 24 hours were measured and summarized in the following table 3, the result of which is depicted in fig. 1 (flatness after 24 hours). In the following table 3, the term flatness is a difference between a portion of the liquid crystal panel most bent toward the upper polarizing plate (e.g., a first polarizing plate) and a portion most bent toward the lower polarizing plate (e.g., a second polarizing plate), and the flatness may be determined by using a known three-dimensional measuring machine (Dukin co., Ltd.).
[ Table 1]
[ Table 2]
Drying conditions
α
X
β
Tg+20℃
γ
Tg+30℃
In [ table 2], α of the drying conditions indicates a case where drying is not performed, β indicates a case where drying is performed at a temperature of Tg +20 ℃, and γ indicates a case where drying is performed at a temperature of Tg +30 ℃.
In summary, the shape of the flatness varies depending on the base material having different TD heat shrinkage characteristics of the low moisture-permeable base material layer, wherein it can be confirmed that the flatness is improved when the TD heat shrinkage characteristics are further controlled by changing the drying temperature conditions.
Further, the polarizer layers 210, 220 may have a thickness of less than 25 μm, a degree of polarization of 99% or more, and a transmittance of 40% or more, and may be formed of PVA. Further, the MD direction shrinkage force of the polarizer layers 210, 220 may be 5N to 9N. Further, the MD direction shrink force of the polarizer layers 210, 220 may be greater than 5N and less than 9N. The polarizer layers 210, 220 are provided by stretching them in the MD direction, and when the MD shrinkage force has a value greater than the above range, there is a high possibility that heat-resistant cracks are generated.
On the other hand, the thickness of the UV
In this document, the MD direction (absorption axis direction) represents the machine direction, the TD direction (transmission axis direction) represents the transverse direction, and the MD direction and the TD direction are orthogonal to each other.
Further, in a state where the first
In addition, the number of layers respectively constituting the first
Alternatively, the number of layers constituting the first
Referring to fig. 3, the
[ equation 1]
|αMD-αTD|≤1
In equation 1, αMDα for the value determined by
[ equation 2]
αMD(sum of absorption axial bending moment acting on each layer of the first polarizing plate)/(sum of transmission axial bending moment acting on each layer of the second polarizing plate)
[ equation 3]
αTD(sum of transmitted axial bending moments acting on the respective layers of the first polarizing plate)/(sum of absorbed axial bending moments acting on the respective layers of the second polarizing plate)
In
Further, the transmissive axial bending moment acting on each layer is determined by the product of the distance (unit: μm) from the center of the liquid crystal panel to the center of the relevant layer and the transmissive axial contraction force (unit: N) acting on the relevant layer.
In this document, the center of the liquid crystal panel means the center of the total thickness of the
Further, α defined by
That is, for each of the orthogonal directions (MD, TD), the ratio of the bending moment acting on the first
Furthermore, α is preferableMDAnd αTDEach 0.85 to 1.15, and preferably, αMDAnd αTDEach is 1.
Therefore, in the above equation 1, preferably, | αMD–αTDThe value of | may be 0.4 or less, more preferably, | αMD–αTDThe value of | may be 0.3 or less.
In addition, αMDAnd αTDMay have the same value.
[ Table 3]
Table 3 is based on room temperature data after a duration of 72 hours at 60 ℃ and shows that when the bending moment of the polarizer layer is constant, it is adjusted so that α is controlled by controlling the TD-direction bending moment of the low moisture-permeable base material layers (base materials 1 to 4)MDAnd αTDResults of close to 1, respectively (see
In addition, the liquid crystal panel may satisfy the
[ equation 4]
(αMD-1)(αTD-1)≤0
By satisfying the
Further, the MD-direction bending moment acting on each layer can be determined by the product of the distance (z1 to z4, unit: μm) from the center of the liquid crystal panel to the center of each layer and the MD-direction shrinkage force (unit: N) acting on the relevant layer, and the TD-direction bending moment acting on each layer can be determined by the product of the distance (z1 to z4, unit: μm) from the center of the liquid crystal panel to the center of each layer and the TD-direction shrinkage force (unit: N) acting on the relevant layer.
For example, referring to FIG. 3, αMDAnd αTDCan be determined by the following
[ equation 5]
αMD(MD shrinkage force z1 of the polarizer layer in the first polarizing plate + MD shrinkage force z2 of the low moisture-permeable base material layer in the first polarizing plate)/(TD shrinkage force z3 of the polarizer layer in the second polarizing plate + TD shrinkage force z4 of the low moisture-permeable base material layer in the second polarizing plate)
[ equation 6]
αTD(TD shrinkage force of the polarizer layer in the first polarizing plate z1+ TD shrinkage force of the low moisture-permeable base material layer in the first polarizing plate z 2)/(MD shrinkage force of the polarizer layer in the second polarizing plate z3+ MD shrinkage force of the low moisture-permeable base material layer in the second polarizing plate z4)
z1 may be the distance from the center of the
As examples of
Further, the contraction force may be determined based on the contraction rate. That is, the shrinkage force-based equation may be replaced with a shrinkage rate-based equation.
In summary, in the
Further, the method for manufacturing the
As described above, the first and second
Further, the method includes the step of producing the first polarizing plate and the second polarizing plate to satisfy the following equation 1.
[ equation 1]
|αMD-αTD|≤1
In equation 1, MD is a value determined by
[ equation 2]
αMDFirst polarization (acting on the first polarization)The sum of the absorbed axial bending moments at the layers of the sheet)/(the sum of the transmitted axial bending moments acting at the layers of the second polarizing plate)
[ equation 3]
αTD(sum of transmitted axial bending moments acting on the respective layers of the first polarizing plate)/(sum of absorbed axial bending moments acting on the respective layers of the second polarizing plate)
In
the transmissive axial bending moment acting on each layer is determined by the product of the distance from the center of the liquid crystal panel to the center of the relevant layer and the transmissive axial contraction force acting on the relevant layer.
Further, the method may include the step of producing the first polarizing plate and the second polarizing plate such that MD and TD defined by the following
Furthermore, α is preferableMDAnd αTDEach 0.85 to 1.15, and preferably, αMDAnd αTDEach is 1.
Further, it is preferable that the step of producing the first polarizing plate and the second polarizing plate satisfies the
[ equation 4]
(αMD-1)(αTD-1)≤0
Further, in the steps of producing the first polarizing plate and the second polarizing plate, the MD direction (absorption axis direction) shrinkage force of the polarizer layer may be adjusted to satisfy
Further, in the steps of producing the first polarizing plate and the second polarizing plate, the TD-direction (transmission axis direction) shrinkage force of the low moisture-permeable substrate layer may be adjusted to satisfy
The preferred embodiments of the present invention as described above have been disclosed for illustrative purposes, and those skilled in the art, having the ordinary knowledge of the present invention, may make various modifications, adaptations and additions within the spirit and scope of the invention, and such modifications, adaptations and additions should be considered to fall within the scope of the appended claims.
INDUSTRIAL APPLICABILITY
According to the liquid crystal panel and the method of manufacturing the same related to at least one embodiment of the present invention, by adjusting the shrinkage force of the polarizing plate, the deflection balance of the upper/lower polarizing plates can be adjusted, cracks of the polarizing plate can be prevented, and a light leakage phenomenon of the liquid crystal display device can be prevented.
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