阅读说明：本技术 一种有色粒状固体洁厕剂及其制备方法和专用盛放容器 (Colored granular solid toilet cleaner, preparation method thereof and special container ) 是由 张清华 梁勇 刘雪玲 于 2019-11-04 设计创作，主要内容包括：本发明涉及一种有色粒状固体洁厕剂。是由以下质量份数比的组分制成：40～50硫酸钠、5～15异构脂肪醇聚氧乙烯醚、5～10过碳酸钠、3～5羟丙基纤维素、3～7食用淀粉、5～8硬脂酸钠、5～10去离子水、1～3蓖麻油酸锌、1～3N-烷基丙胺基甘氨酸、0.5～1乙二胺四乙酸二钠、0.01～0.1食品级亮蓝色素与0.1～0.3松木香型香精。本发明的制备方法：(一).称量配料：各组分按配比称量,分别置于各自专用容器内,待用；(二).搅拌混料：将混料调为有一定流动性的膏状产品；(三).将上述混料膏状产品经成粒机成型为有色粒状固体颗粒。本发明的溶解速率小,作用时间长久,释放速度恒定均匀,用专用容器效果更佳。(The invention relates to a colored granular solid toilet cleaner. The feed additive is prepared from the following components in parts by mass: 40-50 parts of sodium sulfate, 5-15 parts of isomeric fatty alcohol-polyoxyethylene ether, 5-10 parts of sodium percarbonate, 3-5 parts of hydroxypropyl cellulose, 3-7 parts of edible starch, 5-8 parts of sodium stearate, 5-10 parts of deionized water, 1-3 parts of zinc ricinoleate, 1-3 parts of N-alkyl propylamino glycine, 0.5-1 part of disodium ethylenediamine tetraacetic acid, 0.01-0.1 part of food-grade brilliant blue pigment and 0.1-0.3 part of pine fragrance essence. The preparation method comprises the following steps: weighing and proportioning: weighing the components according to the proportion, and respectively placing the components in respective special containers for later use; (II) stirring and mixing: mixing the mixed materials into a paste product with certain fluidity; and thirdly, forming the mixed paste product into colored granular solid particles by a granulator. The invention has the advantages of small dissolution rate, long acting time, constant and uniform release speed and better effect by using a special container.)

1. A colored granular solid toilet cleaner is a granular solid prepared from the following components in percentage by mass: 40-50 parts of sodium sulfate, 5-15 parts of isomeric fatty alcohol-polyoxyethylene ether, 5-10 parts of sodium percarbonate, 3-5 parts of hydroxypropyl cellulose, 3-7 parts of edible starch, 5-8 parts of sodium stearate, 5-10 parts of deionized water, 1-3 parts of zinc ricinoleate, 1-3 parts of N-alkyl propylamino glycine, 0.5-1 part of disodium ethylene diamine tetraacetate, 0.01-0.1 part of blue pigment and 0.1-0.3 part of essence.

2. A method of preparing a colored granular solid toilet cleaner according to claim 1, characterized in that: the method comprises the following manufacturing steps:

weighing and proportioning: weighing the components according to the proportion, and respectively placing the components in respective special containers for later use;

(II) stirring and mixing: uniformly mixing sodium sulfate, sodium percarbonate, hydroxypropyl cellulose, edible starch, sodium stearate and disodium ethylene diamine tetraacetate to obtain a powder raw material; then mixing and stirring the isomeric fatty alcohol-polyoxyethylene ether, the zinc ricinoleate, the N-alkyl propylamine glycine, a proper amount of coloring agent and the essence to obtain a paste raw material; adding the pasty raw material into the powder raw material, continuously stirring, uniformly mixing, and finally adding deionized water to mix the materials into a pasty product with certain fluidity;

thirdly, forming the mixed paste product into colored granular solid particles through a granulator, and then airing the colored granular solid particles to obtain irregular blue particles; the diameter range of the particles is required to be controlled to be 3-15 mm, products of at least four particles with different diameters are arranged according to the increasing of the diameters from small to large, and the particles with different diameters are distributed in an increasing trend from small to large according to the mass fraction ratio of the products.

3. A method of preparing a coloured granular solid toilet cleaner according to claim 2, characterised in that: in the step (III), the diameters of the colored granular solid particles are set to be 3 mm-6 mm, 6 mm-9 mm, 9 mm-12 mm and 12 mm-15 mm, and the four different particles are distributed in an increasing trend from small to large in the ratio of the mass fraction of the product.

4. The container for holding a colored granular solid toilet cleaner as claimed in claim 1, which comprises a container body and a container cover, wherein: a first release hole with the diameter of 2 mm-10 mm is arranged at the top end of the container cover, a second release hole with the diameter of 2 mm-10 mm is arranged at the position of 1/2-3/4 of the side edge of the container body, and a sealing label is stuck on the round hole before use;

one 20-50 g of weight material is placed in every 50-75 ml of container space in the container so as to stabilize the container in the flushing process.

Technical Field

The invention relates to a colored granular solid toilet cleaner, a preparation method thereof and a special container.

Background

At present, the inner wall of a toilet bowl used in places such as homes, hotels and the like is very easy to deposit scales such as water scales, urine scales and the like, and the toilet bowl needs to be washed frequently, which causes inconvenience for use and is even more inconvenient for families busy in work. In order to clean the toilet, a solid toilet cleaning agent is usually put into a water tank of the toilet, and the solid toilet cleaning agent can be dissolved in water in the water tank of the toilet, so that the toilet can be cleaned when water is flushed every time, dirt formation and bacterial breeding can be well prevented, and the cleanness and brightness of the toilet can be kept.

However, the current solid toilet cleaner has a fast dissolving speed in water, can be generally used for about 15 days or even shorter time, and the release speed of active ingredients in the solid toilet cleaner is not uniform, so that the using effect of the solid toilet cleaner is obviously reduced along with the time, the using effect is reduced, and the effect of a toilet bowl cannot be improved for a long time.

Disclosure of Invention

The invention aims to provide a colored granular solid toilet cleaner, a preparation method and a special tool thereof, and the colored granular solid toilet cleaner well solves the problems that the solid toilet cleaner in the prior art is high in dissolving speed in water, the release speed of active ingredients in the solid toilet cleaner is not uniform, the toilet cleaning effect is influenced, and the effect of a toilet basin cannot be improved for a long time; the toilet cleaner has the functions of scale inhibition, cleaning, bacteriostasis and odor removal, has small dissolution rate in water and long action time, and can maintain the toilet cleaning function for a long time and improve water scales and stains on the inner wall of a toilet basin by matching with a special tool, and the release speed of active ingredients in the solid toilet cleaner is constant and uniform.

In order to achieve the purpose, the invention adopts the following technical scheme:

the invention relates to a colored granular solid toilet cleaner which is prepared from the following components in parts by mass: 40-50 parts of sodium sulfate, 5-15 parts of isomeric fatty alcohol-polyoxyethylene ether, 5-10 parts of sodium percarbonate, 3-5 parts of hydroxypropyl cellulose, 3-7 parts of edible starch, 5-8 parts of sodium stearate, 5-10 parts of deionized water, 1-3 parts of zinc ricinoleate, 1-3 parts of N-alkyl propylamino glycine, 0.5-1 part of disodium ethylenediamine tetraacetic acid, 0.01-0.1 part of food-grade brilliant blue pigment and 0.1-0.3 part of pine fragrance essence.

The preparation method of the colored granular solid toilet cleaner comprises the following steps:

weighing and proportioning: weighing the components according to the proportion, and respectively placing the components in respective special containers for later use;

(II) stirring and mixing: uniformly mixing sodium sulfate, sodium percarbonate, hydroxypropyl cellulose, edible starch, sodium stearate and disodium ethylene diamine tetraacetate to obtain a powder raw material; then mixing and stirring the isomeric fatty alcohol-polyoxyethylene ether, the zinc ricinoleate, the N-alkyl propylamine glycine, a proper amount of coloring agent and the essence to obtain a paste raw material; adding the pasty raw material into the powder raw material, continuously stirring, uniformly mixing, and finally adding deionized water to mix the materials into a pasty product with certain fluidity;

thirdly, forming the mixed paste product into colored granular solid particles through a granulator, and then airing the colored granular solid particles to obtain irregular blue particles; the diameter range of the particles is required to be controlled to be 3-15 mm, products of at least four particles with different diameters are arranged according to the increasing of the diameters from small to large, and the particles with different diameters are distributed in an increasing trend from small to large according to the mass fraction ratio of the products.

Further, in the optimized preparation method of the colored granular solid toilet cleaner, in the step (three), the diameters of the colored granular solid particles are set to be 3-6 mm, 6-9 mm, 9-12 mm and 12-15 mm, and the colored granular solid particles are distributed in an increasing trend from small to large in the product mass fraction ratio.

The invention relates to a special container for a colored particle solid toilet cleaner, which comprises a container body and a container cover, and is characterized in that: the top end of the container cover is provided with a first release hole with the diameter of 2 mm-10 mm, a second release hole with the diameter of 2 mm-10 mm is arranged at the position of the side 1/2-3/4 of the container body, the height of the container is 10 cm-20 cm, and sealing labels are stuck on the two release holes before use.

In the container, 20-50 g of weight material is placed in every 50-75 ml of container space so as to stabilize the container in the flushing process.

When in use, the colored particle solid toilet cleaner is filled into the container and then vertically immersed into a water tank of a toilet type closestool for normal use.

The invention has the beneficial effects that:

the cellulose and the starch play a role in stable slow release, and can control the active ingredients in the solid toilet cleaner to release at a constant speed for a long time; the isomeric fatty alcohol polyoxyethylene ether mainly plays a role in wetting, decontaminating and emulsifying; the sodium stearate can be used for increasing the hardness of the solid toilet cleaner, plays a role in shaping, is beneficial to product forming and has a certain cleaning effect; the sodium percarbonate, the zinc ricinoleate and the N-alkyl propylamine glycine have the functions of cleaning, deodorizing and inhibiting the breeding of bacteria, and the disodium ethylene diamine tetraacetate can soften water quality, prevent calcium ions and magnesium ions in water from depositing to form dirt, and improve the toilet cleaning effect; the colored granular solid toilet cleaner has the advantages of good scale inhibition and toilet cleaning effects, low dissolution rate in water, long service life, constant and uniform release speed of effective components in the solid toilet cleaner and capability of keeping the toilet cleaning effect for a long time through mutual cooperation of the components.

The special containing container is specially designed for matching the characteristics of the colored granular solid toilet cleaner particles and the diameter setting of the particles, and the like, and can further effectively control the release speed and time of the solid toilet cleaner in the water tank, so that the colored granular solid toilet cleaner can be optimally and uniformly released and can reach the theoretical time close to the longest release. The container can be stably arranged in a water tank of a toilet bowl, cannot be inclined due to flushing, cannot cause residues of the solid toilet cleaner to be left in the water tank, and is obviously superior to the use mode of the block toilet cleaner sold in the market.

The special containing container can be stored in water for a long time, is acid and alkali resistant, is not easy to corrode, can be repeatedly used, and reduces the use cost of users.

The following is a comparison of the effectiveness of the colored granular solid toilet cleaner of the present invention and a conventional bulk toilet cleaner (see Table 1)

Table 1: the comparison of the use effect of the invention and the use effect of the commercial massive blue bubble toilet cleaner is shown in the table

To summarize: through the practical tests, compared with the commercially available block toilet cleaning block, the block toilet cleaning block has the obvious advantages in the aspects of release time, lasting release time, whether residues are left in a toilet water tank or not and the like, and can be used for determining that the block toilet cleaning block can effectively overcome the defects of the commercially available block toilet cleaning block and improving the utilization rate and the use time of the toilet cleaning agent product.

Drawings

Fig. 1 is a schematic structural diagram of an embodiment of a special holding container for a colored granular solid toilet cleaner according to the invention.

Detailed Description

The invention is further described in the following by means of specific embodiments in conjunction with the accompanying drawings. It should be understood that the detailed description and specific examples, while indicating the present invention, are given by way of illustration and explanation only, not limitation. It is to be understood that the described embodiments are merely a few embodiments of the invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

In the present invention, unless otherwise specified, the proportions are in weight units, all equipment and materials are commercially available or commonly used in the industry, and the methods in the following examples are conventional in the art unless otherwise specified.