阅读说明：本技术 一种箱包布涂覆用tpe组合物及其制备方法 (TPE composition for luggage cloth coating and preparation method thereof ) 是由 董青 王志峰 许荣清 董练 于 2021-07-22 设计创作，主要内容包括：本申请涉及箱包生产的领域,更具体地说,它涉及一种箱包布涂覆用TPE组合物及其制备方法。箱包布涂覆用TPE组合物包括TPE：105份-127份、稳定剂：0.4份-3.2份、苯丙氨酸：1.3份-5.7份、软化剂：2份-7份、二环己基甲烷二异氰酸酯：4.6份-12.8份；其制备方法为：首先将原料混合后,温度控制在80℃-100℃,搅拌均匀得到第一混合物,然后对第一混合物进行挤出造粒,温度控制在195℃-225℃,出料得到箱包布涂覆用TPE组合物。本申请具有增强TPE涂层整体的力学性能,同时一定程度上延长涂履有TPE的箱包使用寿命的效果。(The application relates to the field of luggage production, in particular to a TPE composition for luggage cloth coating and a preparation method thereof. The TPE composition for coating the luggage cloth includes TPE: 105-127 parts of stabilizer: 0.4-3.2 parts, phenylalanine: 1.3-5.7 parts of a softening agent: 2-7 parts of dicyclohexylmethane diisocyanate: 4.6 to 12.8 portions; the preparation method comprises the following steps: firstly, mixing the raw materials, controlling the temperature to be 80-100 ℃, uniformly stirring to obtain a first mixture, then extruding and granulating the first mixture, controlling the temperature to be 195-225 ℃, and discharging to obtain the TPE composition for coating the luggage cloth. This application has the holistic mechanical properties of reinforcing TPE coating, and the extension simultaneously to a certain extent is scribbled the case and bag life's that has TPE effect.)

1. The TPE composition for luggage cloth coating is characterized by being prepared from the following raw materials in parts by weight:

TPE: 105-127 parts;

a stabilizer: 0.4 to 3.2 portions;

phenylalanine: 1.3-5.7 parts;

softening agent: 2-7 parts;

dicyclohexylmethane diisocyanate: 4.6 to 12.8 portions.

2. The TPE composition for luggage cloth coating of claim 1, wherein: the TPE composition for coating the luggage cloth is prepared from the following raw materials in parts by weight:

TPE: 115 to 122 portions;

a stabilizer: 1.6 to 2.2 portions;

phenylalanine: 2.8 to 4.7 portions;

softening agent: 4-7 parts;

dicyclohexylmethane diisocyanate: 7.8 to 11.2 portions.

3. A TPE composition for luggage cloth coating according to any of claims 1-2, characterized in that: the TPE composition for coating the luggage cloth further comprises 14-25 parts by weight of polyamide resin.

4. A TPE composition for luggage cloth coating according to any of claims 1-2, characterized in that: the TPE composition for coating the luggage cloth further comprises 8-15 parts of p-phenylenediamine by weight.

5. A TPE composition for luggage cloth coating according to any of claims 1-2, characterized in that: the stabilizer is one of tribasic lead sulfate, dibasic lead phosphite and dibasic lead stearate.

6. A TPE composition for luggage cloth coating according to any of claims 1-2, characterized in that: the softening agent is one of white oil, naphthenic oil and aromatic oil.

7. The TPE composition for luggage cloth coating of claim 3, wherein: the viscosity of the polyamide resin is 150-250 cp.

8. A method for preparing the TPE composition for luggage cloth coating of any one of claims 1-2 and 5-7, comprising the following steps:

the method comprises the following steps: mixing the raw materials, controlling the temperature at 80-100 ℃, and uniformly stirring to obtain a first mixture;

step two: and extruding and granulating the first mixture, controlling the temperature to be 195-225 ℃, and discharging to obtain the TPE composition for coating the luggage cloth.

9. The method for preparing the TPE composition for luggage cloth coating according to claim 8, wherein in the first step, 14-25 parts by weight of polyamide resin and 8-15 parts by weight of p-phenylenediamine are added together.

Technical Field

The application relates to the field of high polymer materials, in particular to a TPE composition for luggage cloth coating and a preparation method thereof.

Background

The cloth coating is a special process treatment, so that a layer of uniform covering rubber material is formed on the surface of the cloth, and the cloth has the characteristics of water resistance, wind resistance and the like.

At present, in the coating process of luggage cloth, the adopted polymer materials mainly comprise polyethylene, polyvinyl chloride, polyvinyl acetate, polyurethane and the like, however, the hand feeling of the polyethylene coating is poor, the weather resistance and the low-temperature performance of the polyvinyl chloride coating are poor, the hand feeling of the polyvinyl acetate coating is hard, the price of the polyurethane coating is high, and the polyurethane coating is poor in yellowing resistance, acid resistance and alkali resistance, so that the polymer materials are not ideal cloth coating materials at the present stage.

Thermoplastic elastomer TPE, also called artificial rubber or synthetic rubber, is used in the cloth coating production of bags and suitcases because of the characteristics of TPE material such as excellent colorability, soft touch, good weather resistance, excellent processing property, no need of vulcanization and the like. However, after the existing luggage coated with the TPE material is used for a long time, the TPE coating is easy to crack and fall off, and the defect that the service life of the luggage is influenced exists.

Disclosure of Invention

In order to effectively enhance the mechanical property of a TPE coating and better prolong the service life of a case coated with the TPE, the application provides a TPE composition for coating case cloth and a preparation method thereof.

In a first aspect, the present application provides a TPE composition for luggage cloth coating, which adopts the following technical scheme:

the TPE composition for coating the luggage cloth is prepared from the following raw materials in parts by weight:

TPE: 105-127 parts;

a stabilizer: 0.4 to 3.2 portions;

phenylalanine: 1.3-5.7 parts;

softening agent: 2-7 parts;

dicyclohexylmethane diisocyanate: 4.6 to 12.8 portions.

By adopting the technical scheme, the tensile strength of the TPE composition for coating the luggage cloth before and after aging treatment can be effectively improved through the synergistic cooperation between the phenylalanine and the dicyclohexylmethane diisocyanate and the TPE, so that the aging resistance and the tearing resistance of the TPE composition for coating the luggage cloth are greatly improved, the protective effect on the luggage is strengthened to a certain degree, and the purpose of effectively prolonging the service life of the luggage coated with the TPE composition is achieved.

The performance enhancement phenomenon may be caused by that, a TPE is firstly plasticized and formed into an elastomer at a high temperature, and then, after a period of stirring, dicyclohexylmethane diisocyanate in a raw material system reacts with phenylalanine at first to modify part of isocyanate groups in the dicyclohexylmethane diisocyanate, and then the modified isocyanate groups are combined with rubber segments in the TPE elastomer, while the unmodified isocyanate groups are bonded with the resin segments in the TPE elastomer, so that the connection strength between the resin segments and the rubber segments in the TPE elastomer is effectively improved by the entirety of the dicyclohexylmethane diisocyanate, the overall mechanical properties of the TPE composition for coating the luggage cloth can be better enhanced, the aging resistance and the tear resistance of the luggage coated with the TPE composition can be improved, the service life of the luggage can be prolonged to a certain extent, has great economic value.

Preferably, the TPE composition for coating the luggage cloth is prepared from the following raw materials in parts by weight:

TPE: 115 to 122 portions;

a stabilizer: 1.6 to 2.2 portions;

phenylalanine: 2.8 to 4.7 portions;

softening agent: 4-7 parts;

dicyclohexylmethane diisocyanate: 7.8 to 11.2 portions.

By adopting the technical scheme, when the addition amount of each raw material component is further controlled, the tensile strength of the TPE composition for coating the luggage cloth can be better improved, so that the purpose of effectively prolonging the service life of the luggage can be achieved by improving the aging resistance and the tearing resistance of the luggage.

Preferably, the TPE composition for coating the luggage cloth further comprises 14-25 parts by weight of polyamide resin.

By adopting the technical scheme, when the polyamide resin with a certain weight part is selected and added into a raw material system, the adhesive force between the dicyclohexylmethane diisocyanate and the TPE elastomer can be further increased through the polyamide resin, so that the service life of a luggage coated with the TPE composition can be further prolonged through better improving the overall mechanical property of the TPE composition for luggage cloth coating.

Preferably, the TPE composition for coating the luggage cloth further comprises 8-15 parts by weight of p-phenylenediamine.

By adopting the technical scheme, when the inventor adds p-phenylenediamine into the raw material system and controls the addition of the p-phenylenediamine, the synergistic effect among TPE, phenylalanine and dicyclohexylmethane diisocyanate can be better improved, so that the tensile strength of the TPE composition for coating luggage cloth before and after aging treatment is effectively improved, and the aging resistance and the tear resistance of the TPE composition for coating luggage cloth can be further improved.

Preferably, the stabilizer is one of tribasic lead sulfate, dibasic lead phosphite and dibasic lead stearate.

By adopting the technical scheme, when one of tribasic lead sulfate, dibasic lead phosphite and dibasic lead stearate is selected as a stabilizer to be added, the synergistic effect among TPE, phenylalanine and dicyclohexylmethane diisocyanate can be more favorably exerted, so that the condition that the surface of a case coated with the TPE composition is cracked can be more effectively reduced, and the service life of the case is further prolonged.

Preferably, the softening agent is one of white oil, naphthenic oil and aromatic oil.

By adopting the technical scheme, when the inventor adds one of white oil, naphthenic oil and aromatic oil to the raw material system, the tearing resistance and the aging resistance of the TPE composition for coating the luggage cloth can be further improved, so that the purpose of prolonging the service life of the luggage better is achieved.

Preferably, the viscosity of the polyamide resin is 150-250 cp.

By adopting the technical scheme, after the polyamide resin with the viscosity of 150-250cp is selected and added by the inventor, the interaction force between the dicyclohexylmethane diisocyanate and the TPE elastomer can be effectively improved, so that the integral tear resistance and the aging resistance of the TPE composition for coating the luggage cloth can be further enhanced.

In a second aspect, the present application provides a preparation method of a TPE composition for luggage cloth coating, which adopts the following technical scheme:

a preparation method of a TPE composition for luggage cloth coating comprises the following steps:

the method comprises the following steps: mixing the raw materials, controlling the temperature at 80-100 ℃, and uniformly stirring to obtain a first mixture;

step two: and extruding and granulating the first mixture, controlling the temperature to be 195-225 ℃, and discharging to obtain the TPE composition for coating the luggage cloth.

The TPE composition for coating the luggage cloth is manufactured by adopting the steps, so that the synergistic effect among the TPE, the phenylalanine and the dicyclohexylmethane diisocyanate can be fully exerted, and the protective effect of the TPE composition on the luggage can be better promoted.

Preferably, in the first step, 14 to 25 parts by weight of polyamide resin and 8 to 15 parts by weight of p-phenylenediamine are added together.

By adopting the technical scheme, the polyamide resin and the p-phenylenediamine are added along with the dicyclohexylmethane diisocyanate, so that the beneficial effects of the polyamide resin and the p-phenylenediamine in a raw material system can be better exerted, and the TPE composition for coating the luggage cloth, which meets the mechanical property requirement, can be more favorably manufactured.

In summary, the present application has the following beneficial effects:

1. the tensile strength of the TPE composition for coating the luggage cloth before and after aging can be effectively improved through the synergistic cooperation among the TPE, the phenylalanine and the dicyclohexylmethane diisocyanate, so that the aging resistance and the tearing resistance of the TPE composition for coating the luggage cloth are greatly improved, and the purpose of effectively prolonging the service life of the luggage coated with the TPE composition is achieved;

2. when the inventor selects a certain weight part of polyamide resin to be added into a raw material system, the adhesive force between dicyclohexylmethane diisocyanate and a TPE elastomer can be further increased through the polyamide resin, so that the service life of a case coated with the TPE can be further prolonged through better improving the overall mechanical property of the TPE composition for coating the case cloth;

3. when the inventor adds p-phenylenediamine into the raw material system and controls the addition of the p-phenylenediamine, the mechanical property of the TPE composition for coating the luggage cloth can be effectively improved, so that the aging resistance and the tear resistance of the TPE composition for coating the luggage cloth can be further enhanced.

Detailed Description

The present application is described in further detail below.

Source of raw materials

TPE: the trademark is EM460, injection grade, and is purchased from Xiangjie plastification science and technology Limited company in Dongguan city;

dicyclohexylmethane diisocyanate: the density is 1.066g/cm³The product number is rd1060000000029 and is purchased from Hubei Chengfeng chemical Co., Ltd;

phenylalanine: the density is 1.201g/cm³The sparkling point is 139.8 ℃, and is purchased from Shaanxi Chengming Biotechnology GmbH.

Polyamide resin: the model number is KPL-88787, and is purchased from Kapler Biotech, Inc. in Shandong;

p-phenylenediamine: flash point of 155 ℃, boiling point of 267 ℃, industrial grade, purchased from Shandong Xin Chemicals, Inc.;

lead sulfate tribasic: melting point of 820 deg.C, refractive index of 2.1, and is available from Shijiazhu Taiwang chemical Co., Ltd;

dibasic lead phosphite: refractive index of 2.25, technical grade, available from Hubei Xin run chemical Co., Ltd;

dibasic lead stearate: a refractive index of 1.6 and a density of 2.15g/cm³Purchased from Wuhanji Industrial chemical industries, Ltd;

white oil: model number 5, industrial grade, purchased from denna brilliant-Hao chemical Co., Ltd;

naphthenic oil: commercial, Inc., Jinchuan, Jinan Hui;

aromatic oil: the index flash point (open) is more than 210 ℃, the aromatic hydrocarbon content is 84 percent, and the index flash point (open) is purchased from Hubei Xingsheng Hengshi scientific and technological Limited company;

potassium stearate: the product number is SSWXCS, food grade, and is purchased from Jiangsu Banaba Biotech limited;

coumarone resin: the glass transition temperature was 56 ℃ and the model was LA-F564, available from Shandong Leon New Material science and technology Co.

Examples

Example 1

A TPE composition for luggage cloth coating is prepared by the following steps:

the method comprises the following steps: adding 105kg of TPE, 5.7kg of phenylalanine, 4.6kg of dicyclohexylmethane diisocyanate, 3.2kg of potassium stearate and 2kg of coumarone resin into a high-speed mixer, controlling the temperature at 80 ℃, and uniformly mixing to obtain a first mixture;

step two: and adding the first mixture into a double-screw extruder for extrusion granulation, controlling the rotating speed of screws at 300r/min and the temperature at 225 ℃, cooling for 20s, and discharging to obtain the TPE composition for luggage cloth coating.

Example 2

A TPE composition for luggage cloth coating is prepared by the following steps:

the method comprises the following steps: adding 127kg of TPE, 1.3kg of phenylalanine, 12.8kg of dicyclohexylmethane diisocyanate, 0.4kg of potassium stearate and 7kg of coumarone resin into a high-speed mixer, controlling the temperature at 100 ℃, uniformly mixing, cooling for 20s, and discharging to obtain a first mixture;

step two: and adding the first mixture into a double-screw extruder for extrusion granulation, wherein the rotating speed of a screw is 300r/min, the temperature is controlled at 195 ℃, and discharging after cooling for 20s to obtain the TPE composition for luggage cloth coating.

Example 3

A TPE composition for luggage cloth coating is prepared by the following steps:

the method comprises the following steps: adding 111kg of TPE, 2kg of phenylalanine, 5.9kg of dicyclohexylmethane diisocyanate, 2.8kg of potassium stearate and 3.2kg of coumarone resin into a high-speed mixer, controlling the temperature at 95 ℃, and uniformly mixing to obtain a first mixture;

step two: and adding the first mixture into a double-screw extruder for extrusion granulation, controlling the rotating speed of screws at 300r/min and the temperature at 200 ℃, cooling for 20s, and discharging to obtain the TPE composition for coating the luggage cloth.

Example 4

A TPE composition for luggage cloth coating is prepared by the following steps:

the method comprises the following steps: adding 115kg of TPE, 2.8kg of phenylalanine, 11.2kg of dicyclohexylmethane diisocyanate, 2.2kg of potassium stearate and 7kg of coumarone resin into a high-speed mixer, controlling the temperature at 95 ℃, and uniformly mixing to obtain a first mixture;

step two: and adding the first mixture into a double-screw extruder for extrusion granulation, controlling the rotating speed of screws at 300r/min and the temperature at 200 ℃, cooling for 20s, and discharging to obtain the TPE composition for coating the luggage cloth.

Example 5

A TPE composition for luggage cloth coating is prepared by the following steps:

the method comprises the following steps: adding 122kg of TPE, 4.7kg of phenylalanine, 7.8kg of dicyclohexylmethane diisocyanate, 1.6kg of potassium stearate and 4kg of coumarone resin into a high-speed mixer, controlling the temperature at 95 ℃, and uniformly mixing to obtain a first mixture;

step two: and adding the first mixture into a double-screw extruder for extrusion granulation, controlling the rotating speed of screws at 300r/min and the temperature at 200 ℃, cooling for 20s, and discharging to obtain the TPE composition for coating the luggage cloth.

Example 6

A TPE composition for luggage cloth coating is different from that of example 5 in that the raw material further comprises a polyamide resin with a viscosity of 90-110cp, and in the first step, 25kg of the polyamide resin is added together.

Example 7

A TPE composition for luggage cloth coating is different from that of example 5 in that the raw material further comprises a polyamide resin with a viscosity of 90-110cp, and in the first step, 14kg of the polyamide resin is added together.

Example 8

A TPE composition for luggage cloth coating is different from that of example 5 in that the raw material further comprises a polyamide resin with a viscosity of 90-110cp, and in the first step, a polyamide resin with a mass of 22kg is added together.

Example 9

A TPE composition for coating luggage cloth, which is different from example 8 in that the raw material further comprises p-phenylenediamine, and in the first step, 8kg of p-phenylenediamine is added.

Example 10

A TPE composition for coating luggage cloth, which is different from example 8 in that the raw material further comprises p-phenylenediamine, and in the first step, p-phenylenediamine is added in an amount of 15 kg.

Example 11

A TPE composition for coating luggage cloth, which is different from example 8 in that the raw material further comprises p-phenylenediamine, and p-phenylenediamine is added together in a mass of 12kg in the first step.

Example 12

A TPE composition for bag cloth coating, differing from example 11 in that potassium stearate was replaced with an equal amount of tribasic lead sulfate.

Example 13

A TPE composition for bag cloth coating, differing from example 11 in that potassium stearate was replaced with an equal amount of dibasic lead phosphite.

Example 14

A TPE composition for bag coating, differing from example 11 in that potassium stearate was replaced with an equal amount of dibasic lead stearate.

Example 15

A TPE composition for luggage coating, differing from example 14 in that coumarone resin was replaced with an equal amount of naphthenic oil.

Example 16

A TPE composition for luggage coating, differing from example 14 in that coumarone resin was replaced with an equal amount of white oil.

Example 17

A TPE composition for luggage cloth coating was different from that of example 14 in that coumarone resin was replaced with an equal amount of aromatic oil.

Example 18

A TPE composition for luggage cloth coating, which is different from example 17 in that the viscosity of the polyamide resin was 120-160 cp.

Example 19

A TPE composition for luggage cloth coating, which is different from example 17 in that the viscosity of the polyamide resin was 150-250 cp.

Comparative example

Comparative example 1

A TPE composition for luggage coating, differing from example 3 in that phenylalanine was replaced with an equal amount of TPE.

Comparative example 2

A TPE composition for luggage cloth coating was distinguished from example 3 in that dicyclohexylmethane diisocyanate was replaced with the same amount of TPE.

Comparative example 3

A TPE composition for luggage cloth coating, which differs from example 3 in that phenylalanine and dicyclohexylmethane diisocyanate are replaced by equal amounts of TPE.

Performance test

The tensile strength (MPa) of the TPE compositions for luggage cloth coating prepared in examples 1-19 and comparative examples 1-3 was tested according to ISO/DIS37-1990 determination of vulcanization and thermoplastic rubber-tensile stress strain Properties; then, the TPE compositions for bag and bag cloth coating prepared in examples 1-19 and comparative examples 1-3 are placed in an anti-yellowing aging test box to be treated for 24h, the temperature of the anti-yellowing aging test box is controlled to be 70 ℃, the humidity is controlled to be 90%, and the oxygen concentration is 65%, finally, the tensile strength (MPa) of the TPE compositions for bag and bag cloth coating prepared in examples 1-19 and comparative examples 1-3 after being treated by the anti-yellowing aging test box is detected according to ISODIS37-1990 'determination of vulcanization and thermoplastic rubber-tensile stress strain performance', and the tensile strength change rate (%) of the rubber products before and after treatment is calculated, wherein the tensile strength change rate is calculated according to the following formula. Wherein, the greater the tensile strength before treatment, the stronger the tear resistance of the TPE composition for coating the luggage cloth; the smaller the change rate of tensile strength, the stronger the aging resistance of the TPE composition for the bag cloth coating.

TABLE 1-summary of test data for examples 1-19 and comparative examples 1-3

According to comparison of test data of example 3 and comparative examples 1 to 3 in table 1, after the inventor adds the TPE, phenylalanine and dicyclohexylmethane diisocyanate to the raw material system, the inventor can effectively increase the tensile strength of the TPE composition for coating the luggage cloth before and after treatment by exerting the synergistic effect between the phenylalanine, dicyclohexylmethane diisocyanate and the TPE, and is also beneficial to reducing the tensile strength change rate of the TPE composition for coating the luggage cloth before and after aging treatment, so that the aging resistance and the tear resistance of the luggage coated with the TPE composition can be visually embodied to be improved to a greater extent, and the purpose of effectively prolonging the service life of the luggage is achieved.

From the comparison of the test data of examples 3 to 5 in table 1, the inventors have found that when the amount of each raw material added is further controlled, the tensile strength of the TPE composition for use in coating luggage cloth before and after the treatment can be improved more effectively, and the rate of change in tensile strength of the TPE composition for use in coating luggage cloth after aging can be further reduced.

According to the comparison of the test data of the examples 5 to 8 in table 1, after the polyamide resin is added into the raw material system, the synergistic effect among the TPE, phenylalanine and dicyclohexylmethane diisocyanate is better exerted, and it can be seen that the tensile strength of the TPE composition for coating luggage cloth is obviously increased before and after the treatment, and the rate of change of the tensile strength of the TPE composition for coating luggage cloth is reduced to a certain extent, so that the purpose of improving the tear resistance and the aging resistance of the TPE composition for coating luggage cloth is achieved.

According to the comparison of the test data of the examples 8 to 11 in table 1, after the inventor adds p-phenylenediamine to the raw material system, the synergistic effect of the TPE, phenylalanine and dicyclohexylmethane diisocyanate can be better improved, so that the tear resistance and the aging resistance of the TPE composition for coating the luggage cloth can be better improved, and the purpose of further prolonging the service life of the luggage coated with the TPE composition can be achieved.

From the comparison of the test data of examples 12 to 14 in table 1, it is found that when three of tribasic lead sulfate, dibasic lead phosphite and dibasic lead stearate are added as different stabilizers to the raw material system, the tensile strength of the TPE composition for bag and bag fabric coating before and after aging treatment can be more effectively improved, and the rate of change of the tensile strength of the TPE composition for bag and bag fabric coating before and after aging treatment can be further reduced, so that the purpose of more effectively prolonging the service life of the bag and bag can be achieved by further improving the mechanical properties of the whole TPE composition for bag and bag fabric coating.

From comparison of the test data of examples 15 to 17 in table 1, it is clear that when three kinds of naphthenic oil, white oil and aromatic oil are added as different stabilizers to a raw material system, the inventors can further improve the tensile strength of the TPE composition for luggage cloth coating before and after aging treatment, and can also better reduce the change rate of the tensile strength of the TPE composition for luggage cloth coating, thereby achieving the purpose of improving the tear resistance and the aging resistance of the TPE composition for luggage cloth coating to a certain extent.

According to the comparison of the test data of the examples 17 to 19 in table 1, when the viscosity of the polyamide resin is controlled to be 150-250cp, the inventor can exert the function of the polyamide resin in the raw material system to a greater extent so as to better exert the synergistic effect of the TPE, the phenylalanine and the dicyclohexylmethane diisocyanate, thereby further enhancing the tear resistance and the aging resistance of the TPE composition for coating the luggage cloth, more effectively prolonging the service life of the luggage coated with the TPE composition, and having great economic value.

The present embodiment is only for explaining the present application, and it is not limited to the present application, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present application.