Threaded joint for pipe and method for manufacturing threaded joint for pipe
阅读说明:本技术 管用螺纹接头及管用螺纹接头的制造方法 (Threaded joint for pipe and method for manufacturing threaded joint for pipe ) 是由 后藤邦夫 于 2018-04-24 设计创作,主要内容包括:本发明提供一种具有高的过扭矩性能的管用螺纹接头及其制造方法。本实施方式的管用螺纹接头(1)具备公扣部(5)和母扣部(8)。公扣部(5)和母扣部(8)具备具有螺纹部(4)、(7)以及无螺纹金属接触部的接触表面(6)、(9)。管用螺纹接头(1)在公扣部(5)和母扣部(8)中的至少一者的接触表面(6)、(9)上具备固体润滑覆膜层(21),所述固体润滑覆膜层(21)含有树脂、固体润滑粉末以及Cr<Sub>2</Sub>O<Sub>3</Sub>。(The invention provides a threaded joint for pipes having high over-torque performance and a method of manufacturing the same. A threaded joint (1) for pipes according to the present embodiment is provided with a male buckle section (5) and a female buckle section (8). The male (5) and female (8) button portions have contact surfaces (6), (9) with threaded portions (4), (7) and unthreaded metal contact portions. A threaded joint (1) for pipes is provided with a solid lubricating coating layer (21) on the contact surfaces (6, 9) of at least one of a pin (5) and a box (8), the solid lubricating coating layer (21) containing a resin, a solid lubricating powder, and Cr 2 O 3 。)
1. A threaded joint for pipes, which is provided with a pin portion and a box portion,
the pin portion and the box portion having contact surfaces with a threaded portion and an unthreaded metal contact portion,
the threaded joint for pipes is provided with a solid lubricating coating layer on the contact surface of at least one of the pin portion and the box portion,
the solid lubricating coating layer contains:
resin, a,
Solid lubricating powder, and
Cr2O3。
2. a threaded joint for pipes as set forth in claim 1,
the solid lubricating coating layer contains 1.0 to 20.0 mass% of the Cr2O3。
3. A threaded joint for pipes as set forth in claim 2,
the solid lubricating coating layer contains:
1.0 to 20.0 mass% of the Cr2O3、
50.0 to 90.0 mass% of the resin, and
5.0 to 30.0 mass% of the solid lubricating powder.
4. A threaded joint for pipes as set forth in any of claims 1-3 wherein,
the resin is 1 or more than 2 selected from the group consisting of epoxy resin, phenolic resin, furan resin, polyamideimide resin, polyamide resin, polyimide resin, and polyether ether ketone resin.
5. A threaded joint for pipes as set forth in claim 4 wherein,
the resin is 1 or more than 2 selected from the group consisting of epoxy resin, phenolic resin, polyamide-imide resin and polyamide resin.
6. A threaded joint for pipes as set forth in any of claims 1-5 wherein,
the solid lubricant powder is 1 or more than 2 selected from the group consisting of graphite, zinc oxide, boron nitride, talc, molybdenum disulfide, tungsten disulfide, graphite fluoride, tin sulfide, bismuth sulfide, organic molybdenum, thiosulfate compound, polytetrafluoroethylene, and melamine cyanurate.
7. A threaded joint for pipes as set forth in claim 6 wherein,
the solid lubricant powder is 1 or more selected from the group consisting of graphite and polytetrafluoroethylene.
8. A method of manufacturing a threaded joint for pipes as set forth in any one of claims 1 to 7, wherein the method comprises:
coating the contact surface of at least one of the male and female snap parts with the resin, the solid lubricant powder, and the Cr2O3The step (2) of preparing the composition of (4); and the number of the first and second groups,
and a step of curing the composition applied to the contact surface to form the solid lubricating coating layer.
9. A method of manufacturing a threaded joint for pipes as set forth in claim 8,
the method further comprises, before the step of applying the composition, the steps of:
and a step of forming a Zn alloy plating layer on the contact surface of at least one of the male snap part and the female snap part by electroplating.
10. A method of manufacturing a threaded joint for pipes as set forth in claim 9,
the method further comprises, before the step of forming the Zn alloy plating layer, the steps of:
and forming a surface roughness on the contact surface of at least one of the male and female snap portions.
Technical Field
The present invention relates to a threaded joint for pipes and a method for manufacturing a threaded joint for pipes, and more particularly, to a threaded joint for oil well pipes and a method for manufacturing a threaded joint for oil well pipes.
Background
Oil well pipes are used for the production of oil and gas fields. An oil country tubular good is formed by connecting a plurality of steel pipes according to the depth of a well. The steel pipes are connected by tightly screwing pipe threaded joints formed at the ends of the steel pipes to each other. The oil country tubular goods are pulled up and loosened by inspection or the like, and are tightened again after inspection and reused.
A threaded joint for pipes is provided with a male buckle portion and a female buckle portion. The male portion includes a male thread portion and a non-threaded metal contact portion formed on an outer peripheral surface of a distal end portion of the steel pipe. The box portion includes a female screw portion and an unthreaded metal contact portion formed on an inner peripheral surface of a distal end portion of the steel pipe. The screw portions of the pin portion and the box portion and the unthreaded metal contact portion are repeatedly subjected to strong friction during tightening and loosening of the threads of the steel pipe. If these portions do not have sufficient durability against friction, galling (sintering that cannot be repaired) occurs when the screw is repeatedly tightened and loosened. Therefore, a threaded joint for pipes is required to have sufficient durability against friction, i.e., excellent seizure resistance.
Conventionally, in order to improve seizure resistance, heavy metal-containing compound grease called paint has been used. The seizure resistance of a threaded joint for pipes can be improved by applying the compound grease to the surface of the threaded joint for pipes. However, heavy metals such as Pb, Zn, and Cu contained in the compound grease may affect the environment. Therefore, it is desired to develop a threaded joint for pipes that does not use compound grease.
International publication No. WO2014/042144 (patent document 1) proposes a threaded joint for pipes that is excellent in seizure resistance even without compound grease.
The composition for forming a solid lubricating coating layer described in
Disclosure of Invention
Problems to be solved by the invention
However, the threaded and unthreaded metal contact portions of the pin portion and the box portion include a metal seal portion and a shoulder portion. When screwing the threaded joint for pipes, the shoulder portions of the pin portion and the box portion contact each other. The torque generated at this time is referred to as shoulder torque. In screwing up a threaded joint for pipes, the screwing up is further performed until the fastening is completed after the shoulder torque is reached. This improves the airtightness of the threaded joint for pipes. When the screw is further tightened, plastic deformation of the metal constituting at least one of the pin portion and the box portion starts. The torque generated at this time is referred to as yield torque.
The torque at the time of completion of fastening (hereinafter referred to as fastening torque) is set so that a sufficient seal surface pressure can be obtained regardless of the magnitude of the thread interference amount. If the difference between the shoulder torque and the yield torque (hereinafter referred to as shoulder friction torque Δ T') is sufficient, the range of tightening torque becomes wide. As a result, the fastening torque can be easily adjusted. Therefore, a threaded joint for pipes is required to have high shoulder friction torque Δ T', i.e., an overtorque performance, in addition to the seizure resistance described above.
In
The present invention aims to provide a threaded joint for pipes having high over-torque performance and a method for manufacturing the same.
Means for solving the problems
The threaded joint for pipes of the present embodiment is a threaded joint for pipes provided with a pin portion and a box portion. The pin portion and the box portion have contact surfaces with a threaded portion and an unthreaded metal contact portion. A threaded joint for pipes is provided with a solid lubricating coating layer on the contact surface of at least one of a pin portion and a box portion. The solid lubricating coating layer contains resin, solid lubricating powder and Cr2O3。
The method for manufacturing a threaded joint for pipes according to the present embodiment includes: and a step of forming the solid lubricating coating layer on the contact surface of at least one of the male and female snap parts.
ADVANTAGEOUS EFFECTS OF INVENTION
The threaded joint for pipes of the present embodiment has a solid lubricantAnd a slip film layer. The solid lubricating coating layer contains Cr2O3. Therefore, the threaded joint for pipes of the present embodiment has high over-torque performance.
Drawings
Fig. 1 is a diagram showing a relationship between the number of revolutions and the torque of a threaded joint for pipes.
FIG. 2 is a view showing Cr in a solid lubricating coating layer2O3Graph of content versus over-torque performance.
FIG. 3 is a view showing Cr in a solid lubricating coating layer2O3Graph of the relationship between the content and the sintering resistance.
Fig. 4 is a diagram showing a structure of a threaded joint for pipes according to the present embodiment.
Fig. 5 is a sectional view of a threaded joint for pipes.
Fig. 6 is a sectional view of a contact surface of a threaded joint for pipes according to the present embodiment.
Fig. 7 is a diagram for explaining the shoulder friction torque Δ T' in the embodiment.
Detailed Description
Hereinafter, the present embodiment will be described in detail with reference to the drawings. The same or corresponding portions in the drawings are denoted by the same reference numerals, and description thereof will not be repeated.
The present inventors have variously studied the relationship between the torque overload performance and the seizure resistance of a threaded joint for pipes. As a result, the following findings were obtained.
[ over-torque performance ]
When the steel pipes are threaded tightly with each other, the optimum torque for ending the threading is determined in advance. Fig. 1 is a diagram showing a relationship between the number of rotations of a steel pipe and torque at the time of tightening a thread in a threaded joint for pipes having a shoulder portion. Referring to fig. 1, when screwing a threaded joint for pipes, torque initially rises in proportion to the number of revolutions. The rate of increase in torque at this time is low. If the screwing is further performed, the shoulder portions come into contact with each other. The torque at this time is referred to as shoulder torque. When the thread tightening is further performed after the shoulder torque is reached, the torque rises again in proportion to the number of revolutions. The torque rise rate at this time is high. When the torque reaches a predetermined value (tightening torque), tightening of the thread is completed. If the torque at the time of tightening the threads reaches the tightening torque, the metal seal portions interfere with each other with an appropriate surface pressure. In this case, the gas tightness of the threaded joint for pipes is improved.
If the tightening is further performed after the tightening torque is reached, the torque becomes excessively high. If the torque becomes too high, plastic deformation occurs in a part of the male and female snap portions. The torque at this time is referred to as yield torque. If the shoulder friction torque Δ T', which is the difference between the shoulder torque and the yield torque, is large, the range of the tightening torque is sufficient. As a result, the fastening torque can be easily adjusted. Therefore, the shoulder friction torque Δ T' is preferably large. In the present specification, the high over-torque performance means that the shoulder friction torque Δ T' is high.
In order to increase the shoulder friction torque Δ T', it is effective to reduce the shoulder torque or increase the yield torque. It is considered that when the solid lubricating coating layer contains hard particles, the yield torque increases at high surface pressure. If the yield torque increases, the shoulder friction torque Δ T' increases.
However, the present inventors have conducted investigations and found that a high shoulder friction torque Δ T' cannot be obtained even when hard particles are simply contained in the solid lubricating coating layer. Such as CaF2Although hard particles are used, CaF is used as shown in examples described later2A high shoulder friction torque Δ T' cannot be obtained.
Accordingly, the present inventors have further made various studies and found that by containing Cr in the solid lubricating coating layer2O3The high shoulder friction torque Δ T' can be obtained.
FIG. 2 is a view showing Cr in a solid lubricating coating layer2O3Graph of content versus over-torque performance. FIG. 2 is obtained by the examples described later. The horizontal axis in FIG. 2 represents Cr in the solid lubricating coating layer2O3The content of (a). The vertical axis of fig. 2 represents the over-torque performance. The over-torque performance is obtained as follows: in test No. 1 in the examples described later, the shoulder friction torque when the solid lubricating coating layer was replaced with the API standard coatingThe value of Δ T' is determined as a relative value with reference to (100). The white circle marks (∘) in fig. 2 indicate the over-torque performance of the example formed with the solid lubricating coating layer. The white triangular mark (Δ) in fig. 2 indicates the over-torque performance when API (american petroleum institute) standard paint is used in place of the solid lubricating coating layer.
As can be seen from FIG. 2, if the solid lubricating coating layer contains Cr2O3The over-torque performance exceeds 100. That is, if Cr is contained2O3High over-torque performance can be obtained.
[ sintering resistance ]
The present inventors have further found that Cr in the solid lubricating coating layer is adjusted2O3When the content (b) is (d), the over-torque performance is improved and the seizure resistance is also improved.
FIG. 3 is a view showing Cr in a solid lubricating coating layer2O3Graph of the relationship between the content and the sintering resistance. FIG. 3 is obtained by the following examples. The horizontal axis in FIG. 3 represents Cr in the solid lubricating coating layer2O3The content of (a). The vertical axis of fig. 3 indicates the number of times (times) the fastening can be performed without sintering.
According to FIG. 3, if Cr2O3When the content is 1.0 to 20.0 mass%, the number of times of fastening without sintering exceeds 10 times. I.e., if Cr2O3When the content is 1.0 to 20.0 mass%, high sintering resistance can be obtained.
The threaded joint for pipes according to the present embodiment completed based on the above-described findings has the following features. A threaded joint for pipes is provided with a male buckle portion and a female buckle portion. The pin portion and the box portion have contact surfaces with a threaded portion and an unthreaded metal contact portion. A threaded joint for pipes is provided with a solid lubricating coating layer on the contact surface of at least one of a pin portion and a box portion. The solid lubricating coating layer contains resin, solid lubricating powder and Cr2O3。
The threaded joint for pipes of the present embodiment contains Cr in the solid lubricating coating layer2O3. Therefore, high over-torque performance is achieved.
In the aboveIn the solid lubricating coating layer, Cr2O3The content of (B) is preferably 1.0 to 20.0 mass%.
If Cr is contained in the solid lubricating coating layer2O3When the content of (b) is 1.0 to 20.0 mass%, the sintering resistance of the solid lubricating coating layer is improved.
The solid lubricating coating layer may contain 1.0 to 20.0 mass% of Cr2O350.0 to 90.0 mass% of a resin, and 5.0 to 30.0 mass% of a solid lubricant powder.
Preferably, the resin is 1 or 2 or more selected from the group consisting of an epoxy resin, a phenol resin, a furan resin, a polyamideimide resin, a polyamide resin, a polyimide resin, and a polyether ether ketone resin.
In this case, the over-torque performance and the seizure resistance of the solid lubricating coating layer are further improved.
The resin may be 1 or 2 or more selected from the group consisting of epoxy resin, phenol resin, polyamideimide resin, and polyamide resin.
Preferably, the solid lubricant powder is 1 or 2 or more selected from the group consisting of graphite, zinc oxide, boron nitride, talc, molybdenum disulfide, tungsten disulfide, graphite fluoride, tin sulfide, bismuth sulfide, organic molybdenum, thiosulfate compound, polytetrafluoroethylene, and melamine cyanurate.
Preferably, the solid lubricant powder is 1 or more selected from the group consisting of graphite and polytetrafluoroethylene.
In this case, the over-torque performance and the seizure resistance of the solid lubricating coating layer are further improved.
The method of manufacturing a threaded joint for pipes according to the present embodiment includes a coating step and a curing step. In the coating step, a coating composition containing a resin, a solid lubricant powder and Cr is applied to the contact surface of at least one of the male and female portions2O3The composition of (1). In the curing step, the composition applied to the contact surface is cured to form a solid lubricating coating layer.
The above-described manufacturing method may further include a Zn alloy plating layer formation step before the coating step. In the Zn alloy plating layer forming step, a Zn alloy plating layer is formed by electroplating on the contact surface of at least one of the pin portion and the box portion.
The above-described manufacturing method may further include a surface roughness forming step before the Zn alloy plating layer forming step. In the surface roughness forming step, surface roughness is formed on a contact surface of at least one of the pin portion and the box portion.
The threaded joint for pipes and the method of manufacturing the threaded joint for pipes according to the present embodiment will be described in detail below.
[ threaded joints for pipes ]
A threaded joint for pipes is provided with a male buckle portion and a female buckle portion. Fig. 4 is a diagram showing a structure of a threaded joint for pipes according to the present embodiment. The threaded joint for
A typical threaded joint for
The pin portion and the box portion have contact surfaces with a threaded portion and an unthreaded metal contact portion. Fig. 5 is a sectional view of the threaded joint for
[ solid lubricating coating layer 21]
The threaded joint for
The solid
The components are described in detail below.
[ resin ]
The resin has the function of acting as a binder. The resin may be a known resin.
The resin is, for example, 1 or 2 selected from the group consisting of a thermosetting resin and a thermoplastic resin. The thermosetting resin is, for example, 1 or 2 or more selected from the group consisting of epoxy resin, phenol resin, furan resin, and polyimide resin. The thermoplastic resin is, for example, 1 or 2 or more selected from the group consisting of a polyamideimide resin, a polyamide resin, and a polyether ether ketone resin.
Preferably, the resin is 1 or 2 or more selected from the group consisting of epoxy resin, phenol resin, furan resin, polyamideimide resin, polyamide resin, polyimide resin, and polyether ether ketone resin. These resins have appropriate hardness. Therefore, the wear resistance, the seizure resistance, and the over-torque performance of the solid
More preferably, the resin is 1 or 2 or more selected from the group consisting of epoxy resin, phenol resin, furan resin, polyamideimide resin and polyamide resin.
Particularly preferably, the resin is 1 or 2 or more selected from the group consisting of epoxy resin, polyamideimide resin and polyamide resin.
Epoxy resins are thermosetting resins. When the epoxy resin is subjected to a thermosetting treatment, the epoxy groups remaining in the polymer crosslink and network. Thereby, the epoxy resin is cured.
The polyamideimide resin is a thermoplastic resin.
The polyamide resin is a thermoplastic resin. The polyamide resin is a polymer in which a plurality of monomers are bonded through amide bonds.
The content of the resin in the solid
[ solid lubricating powder ]
In order to further improve the lubricity of the solid
The lubricants are roughly classified into, for example, the following 5 types. The solid lubricating powder contains at least 1 selected from the group consisting of the following (1) to (4).
(1) Lubricants that exhibit lubricity by having a specific crystal structure that slides easily, such as a hexagonal layered crystal structure (e.g., graphite, zinc oxide, boron nitride, and talc);
(2) lubricants that exhibit lubricity by having a reactive element in addition to by a crystal structure (e.g., molybdenum disulfide, tungsten disulfide, graphite fluoride, tin sulfide, bismuth sulfide, and organic molybdenum);
(3) lubricants that exhibit lubricity through chemical reactivity (e.g., thiosulfate compounds);
(4) lubricants that exhibit lubricity by plastic or viscoplastic behavior under frictional stress (e.g., Polytetrafluoroethylene (PTFE) and Melamine Cyanurate (MCA)); and the number of the first and second groups,
(5) a lubricant (e.g., perfluoropolyether (PFPE)) which is liquid or greasy and exhibits lubricity by being present at the boundary between contact surfaces to prevent direct contact between the surfaces.
Any of the solid lubricating powders (1) to (4) above can be used. The solid lubricating powder may be used alone in any of the above-mentioned items (1) to (4). For example, (1) the solid lubricating powder may be used alone. The solid lubricating powder may be used in combination of a plurality of the above-mentioned components (1) to (4). For example, the compound (4) may be used in combination with the compound (1). That is, the solid lubricating powder is preferably 1 or 2 or more selected from the group consisting of graphite, zinc oxide, boron nitride, talc, molybdenum disulfide, tungsten disulfide, graphite fluoride, tin sulfide, bismuth sulfide, organic molybdenum, thiosulfate compound, Polytetrafluoroethylene (PTFE), and Melamine Cyanurate (MCA).
Preferably, the solid lubricating powder contains 1 or more selected from the group consisting of (1) and (4) above. As the solid lubricating powder (1), graphite is preferable from the viewpoint of the adhesion and rust prevention of the solid
It is further preferred that the solid lubricant powder is Polytetrafluoroethylene (PTFE).
The content of the solid lubricant powder in the solid
[Cr2O3]
Cr2O3Also known as chromium (III) oxide. Cr (chromium) component2O3Is an inorganic compound. Cr (chromium) component2O3Has an equation of 151.99. Cr (chromium) component2O3Is obtained by pyrolysis of ammonium dichromate (ammonium dichromate). Cr (chromium) component2O3The crystals were purified by sublimation to form dark green metallic luster crystals. Cr (chromium) component2O3Is extremely stable and harder than quartz. Cr (chromium) component2O3Has no toxicity and danger.
As described above, if the solid
Cr in solid lubricating coating layer 212O3The content is preferably 1.0 to 20.0 mass%. If Cr2O3When the content is 1.0 mass% or more, sufficient over-torque performance can be obtained, and the seizure resistance is also improved. If Cr2O3When the content is 20.0 mass% or less, the strength of the solid
Cr2O3For example dark green particles. Cr (chromium) component2O3Preferably, the particle diameter of (2) is 45 μm or less. From the viewpoint of uniform dispersibility, it is more preferably 10 μm or less. The particle size is an arithmetic average of effective particle size distribution obtained by particle size distribution measurement by a laser diffraction/scattering method (SALD series manufactured by Shimadzu corporation). Cr (chromium) component2O3The lower limit of the preferred particle diameter of (2) is, for example, 1 μm.
Cr2O3For example, chromium (III) oxide available from Wako pure chemical industries, Ltd.
[ other ingredients ]
The solid
[ Rust-preventive additive ]
The solid
The content of the rust-preventive additive in the solid
[ Corrosion inhibitor ]
The solid
[ thickness of solid lubricating coating layer ]
The thickness of the solid
The thickness of the solid
The solid
[ base material of threaded joint for pipe ]
The composition of the base material of the threaded joint for
[ production method ]
A method of manufacturing the threaded joint for
The method of manufacturing the threaded joint for
[ Process for Forming solid lubricating coating layer ]
The solid lubricating coating layer includes a coating step and a curing step. In the coating step, a solid lubricating coating layer-forming composition (also simply referred to as a composition) is coated on the contact surface of at least one of the
First, a composition for forming a solid lubricating coating layer is produced. The composition for forming a solid lubricating coating layer contains a resin and a solid lubricating powderPowder and Cr2O3. The solvent-free composition can be prepared by, for example, heating a resin to a molten state and adding a solid lubricant powder and Cr2O3And kneading the mixture to produce the rubber composition. A powder mixture in which all the components are mixed in powder form may be used as the composition.
The solvent-based composition can be prepared by, for example, mixing a resin, a solid lubricant powder and Cr2O3Dissolved or dispersed in a solvent and mixed. Examples of the solvent include water, various alcohols, and organic solvents. The proportion of the solvent is not particularly limited. The ratio of the solvent may be adjusted to an appropriate viscosity according to the coating method. The proportion of the solvent is, for example, 30 to 50% by mass when the total amount of all components except the solvent is 100% by mass.
[ coating Process ]
In the coating step, the composition is coated on the contact surfaces 6, 9 by a known method.
In the case of solvent-free compositions, the compositions can be applied by the hot-melt method. In the hot melt method, the composition is heated to melt the resin, and a low-viscosity fluid state is formed. The composition in a fluid state is sprayed from a spray gun having a heat retention function. The composition is heated and melted in a tank equipped with an appropriate stirring device, supplied to a spray head of a spray gun (kept at a predetermined temperature) via a metering pump by a compressor, and sprayed. The holding temperature in the tank and the spray head is adjusted according to the melting point of the resin in the composition. The coating method may use brush coating, dipping, and the like instead of spraying. The heating temperature of the composition is preferably 10 to 50 ℃ higher than the melting point of the resin. In coating the composition, it is preferable that the contact surfaces 6, 9 of at least one of the
In the case of a solvent-based composition, the composition in a solution state is applied to the contact surface by spraying or the like. In this case, the viscosity is adjusted to enable the composition to be sprayed under normal temperature and pressure environments.
[ curing step ]
In the curing step, the composition applied to the contact surface is cured to form the solid
In the case of a solvent-free composition, the composition applied to the contact surfaces 6, 9 is cooled, whereby the composition in a molten state is solidified to form the solid
In the case of a solvent-based composition, the solid
The solidification step may be performed by rapid cooling using a nitrogen or carbon dioxide gas cooling system. In the rapid cooling, the steel pipe is indirectly cooled from the opposite surfaces of the contact surfaces 6 and 9 (the outer surface of the
The solid
The method of manufacturing the threaded joint for
[ Zn alloy plating layer formation step ]
In the Zn alloy plating layer forming step, a Zn alloy plating layer is formed by electroplating on the contact surface of at least one of the
Alternatively, in the Zn alloy plating layer forming step, the Zn alloy plating layer is formed by electroplating on the contact surface of at least one of the
When the Zn alloy plating layer forming step is performed, the seizure resistance and corrosion resistance of the threaded joint for
The plating treatment can be performed by a known method. For example, a plating bath containing ions of the metal element contained in the Zn alloy plating layer is prepared. Then, at least one of the contact surfaces 6, 9 of the male and
More specifically, for example, in the case of forming a Cu — Sn — Zn alloy plating layer, the plating bath contains copper ions, tin ions, and zinc ions. The composition of the plating bath is preferably Cu: 1-50 g/L, Sn: 1-50 g/L, and Zn: 1 to 50 g/L. The conditions of the plating are, for example, plating bath pH: 1-10, plating bath temperature: 60 ℃, current density: 1 to 100A/dm2And processing time: 0.1-30 minutes.
In the case of forming a Zn — Ni alloy plating layer, the plating bath contains zinc ions and nickel ions. The composition of the plating bath is preferably Zn: 1-100 g/L and Ni: 1 to 50 g/L. The conditions of the plating are, for example, plating bath pH: 1-10, plating bath temperature: 60 ℃, current density: 1 to 100A/dm2And processing time: 0.1-30 minutes.
The hardness of the Zn alloy plating layer is preferably 300 or more in terms of micro vickers hardness. If the hardness of the Zn alloy plating layer is 300 or more, the corrosion resistance of the threaded joint for
The hardness of the Zn alloy plating layer can be measured as follows. In the Zn alloy plating layer of the obtained threaded joint for
In the case of the multilayer plating treatment, the plating layer of the lowermost layer is preferably set to a film thickness of less than 1 μm. The thickness of the plating layer (total thickness in the case of multilayer plating) is preferably 5 to 15 μm.
The thickness of the Zn alloy plating layer was measured as follows. On the contact surface on which the Zn alloy plating layer was formed, a probe of a vortex phase type film thickness measuring instrument according to iso (international Organization for standardization)21968(2005) was brought into contact with the contact surface. The phase difference between the high-frequency magnetic field on the probe input side and the eddy current on the Zn-Ni alloy plating layer excited thereby was measured. The phase difference is converted into the thickness of the Zn alloy plating layer.
The method of manufacturing the threaded joint for
[ procedure for Forming surface roughness ]
In the surface roughness forming step, surface roughness is formed on the contact surface of at least one of the
The maximum height Rz of the profile and the arithmetic mean deviation Ra of the profile mentioned in the present specification are measured based on JIS B0601 (2013). The measurement was performed using a scanning probe microscope SPI3800N manufactured by SII Nano Technology. For the measurement conditions, the number of data acquisitions was 1024 × 1024 in a2 μm × 2 μm region of the sample as a unit of the number of data acquisitions. The reference length was set to 2.5 mm. The larger the maximum height Rz of the profile is, the larger the contact area with the solid
The surface roughness of the contact surfaces 6, 9 of the threaded joint for
[ Sand blast treatment ]
The blasting treatment is a treatment of mixing a blasting material (abrasive) with compressed air and projecting it to the contact surfaces 6, 9. The blasting material is, for example, a spherical blasting material and an angular abrasive material. By the sand blasting, the surface roughness of the contact surfaces 6, 9 can be increased. The blasting treatment may be performed by a known method. For example, air is compressed by a compressor, and the compressed air is mixed with the blasting material. The material of the blasting material is, for example, stainless steel, aluminum, ceramic, alumina, or the like. Conditions such as the projection speed of the blast treatment can be appropriately set.
[ acid pickling treatment ]
The pickling process is a process of roughening the contact surfaces 6 and 9 by immersing them in a strong acid solution such as sulfuric acid, hydrochloric acid, nitric acid, or hydrofluoric acid. Thereby, the surface roughness of the contact surfaces 6, 9 can be increased.
[ chemical conversion treatment ]
The chemical conversion treatment is a treatment for forming a porous chemical conversion coating having a large surface roughness. The chemical conversion treatment is, for example, a phosphate chemical conversion treatment, an oxalate chemical conversion treatment, and a borate chemical conversion treatment. From the viewpoint of the adhesiveness of the solid
The phosphate chemical conversion treatment can be carried out by a known method. As the treatment liquid, an acidic phosphate chemical conversion treatment liquid for a general zinc-plated material can be used. For example, there is mentioned a zinc phosphate-based chemical conversion treatment containing 1 to 150g/L of phosphate ions, 3 to 70g/L of zinc ions, 1 to 100g/L of nitrate ions, and 0 to 30g/L of nickel ions. A manganese phosphate-based chemical conversion treatment liquid commonly used for the threaded joint 1 for pipes may be used. The liquid temperature is, for example, from room temperature to 100 ℃. The processing time may be set as appropriate according to the desired film thickness, and may be, for example, 15 minutes. In order to promote the formation of the chemical conversion coating, surface conditioning may be performed before the phosphate chemical conversion treatment. The surface conditioning is a treatment of immersing the titanium colloid-containing aqueous solution for surface conditioning. It is preferable to perform water washing or hot water washing after the phosphate chemical conversion treatment, and then to perform drying.
The chemical conversion coating is porous. Therefore, when the solid
In the surface roughness forming step, only 1 treatment may be performed, or a plurality of treatments may be combined. In the case of performing 1 treatment, it is preferable to perform a treatment selected from the group consisting of sand blast treatment, acid pickling treatment, and phosphate chemical conversion treatment. In the surface roughness forming step, 2 or more kinds of treatment may be performed. In this case, for example, the phosphate chemical conversion treatment may be performed after the blasting treatment. After the surface roughness forming step is performed, the solid
[ 3-valent chromate treatment ]
In the case of performing the Zn alloy plating treatment, the 3-valent chromate treatment may be performed after the Zn alloy plating layer formation step and before the solid lubricating coating layer formation step. The 3-valent chromate treatment is a treatment for forming a chromate film of 3-valent chromium. The coating film formed by the 3-valent chromate treatment suppresses white rust on the surface of the Zn alloy plating layer. Thereby, the product appearance is improved (the white rust of the Zn alloy plating layer is not rust of the base material of the threaded joint for
The 3-valent chromate treatment can be carried out by a known method. For example, the
The thickness of the 3-valent chromate coating can be measured by the same method as that for the solid
In the method of manufacturing the threaded joint for
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