Method for manufacturing liquid crystal film and method for manufacturing optical laminate

文档序号：1648969 发布日期：2019-12-24 浏览：9次中文

阅读说明：本技术 液晶膜的制造方法及光学层叠体的制造方法 (Method for manufacturing liquid crystal film and method for manufacturing optical laminate ) 是由越野哲史于 2019-06-12 设计创作，主要内容包括：本发明提供液晶膜的制造方法及光学层叠体的制造方法。一种液晶膜的制造方法,该制造方法具有：准备依次包含第1基材层、第1液晶层、以及粘接层的带有粘接层的第1层叠部的工序；准备包含第2基材层及第2液晶层的第2层叠部的工序；对所述带有粘接层的第1层叠部的所述粘接层侧的表面、以及所述第2层叠部的所述第2液晶层侧的表面中的至少一方进行表面活化处理的工序；将所述带有粘接层的第1层叠部的宽度方向剖面中的包含所述粘接层的端部的第1端部的至少一方除去的工序；以及将除去所述第1端部后的所述带有粘接层的第1层叠部的所述粘接层、与所述第2层叠部的所述第2液晶层贴合而得到液晶层层叠体的工序。(The invention provides a method for manufacturing a liquid crystal film and a method for manufacturing an optical laminate. A method for manufacturing a liquid crystal film, comprising: preparing a1 st laminated part with an adhesive layer, which sequentially comprises a1 st base material layer, a1 st liquid crystal layer, and an adhesive layer; preparing a 2 nd laminated part including a 2 nd base material layer and a 2 nd liquid crystal layer; a step of performing surface activation treatment on at least one of the surface of the 1 st laminated part with an adhesive layer on the adhesive layer side and the surface of the 2 nd laminated part on the 2 nd liquid crystal layer side; removing at least one of the 1 st end portions including the end portions of the adhesive layer in the cross section in the width direction of the 1 st laminated portion with the adhesive layer; and a step of bonding the adhesive layer of the 1 st laminated part with the adhesive layer after the 1 st end part is removed and the 2 nd liquid crystal layer of the 2 nd laminated part to obtain a liquid crystal layer laminate.)

1. A method for manufacturing a liquid crystal film, comprising:

preparing a1 st laminated part with an adhesive layer, which sequentially comprises a1 st base material layer, a1 st liquid crystal layer and the adhesive layer;

preparing a 2 nd laminated part including a 2 nd base material layer and a 2 nd liquid crystal layer;

a step of performing surface activation treatment on at least one of the surface of the 1 st laminated part with an adhesive layer on the adhesive layer side and the surface of the 2 nd laminated part on the 2 nd liquid crystal layer side;

removing at least one of the 1 st end portions including the end portions of the adhesive layer in the cross section in the width direction of the 1 st laminated portion with the adhesive layer; and

a step of bonding the adhesive layer of the 1 st laminated part with the adhesive layer after the 1 st end part is removed and the 2 nd liquid crystal layer of the 2 nd laminated part to obtain a liquid crystal layer laminate,

in the 1 st laminated part with the adhesive layer, at least one end part of the cross section in the width direction of the laminated part is more inward in the width direction than the end part of the 1 st liquid crystal layer,

the step of removing is performed before or after the step of performing the surface activation treatment,

removing the 1 st end portion so that a position of an end portion of the adhesive layer on a side from which the 1 st end portion is removed is identical to a position of an end portion of the 1 st liquid crystal layer in a widthwise cross section of the 1 st laminated portion with the adhesive layer from which the 1 st end portion is removed.

2. The method of manufacturing a liquid crystal film according to claim 1,

the step of removing is performed before the step of performing the surface activation treatment.

3. The method for manufacturing a liquid crystal film according to claim 1 or 2,

in the 1 st laminated part with the adhesive layer, in a cross section in the width direction, positions of both ends in the width direction of the adhesive layer are located more inward in the width direction than positions of both ends in the width direction of the 1 st liquid crystal layer,

the 1 st end portion is a width-direction both ends of the 1 st laminated portion with the adhesive layer.

4. A method for manufacturing a liquid crystal film, comprising:

preparing a1 st laminated part with an adhesive layer, which sequentially comprises a1 st base material layer, a1 st liquid crystal layer and the adhesive layer;

preparing a 2 nd laminated part including a 2 nd base material layer and a 2 nd liquid crystal layer;

a step of bonding the adhesive layer of the 1 st laminated part with the adhesive layer to the 2 nd liquid crystal layer of the 2 nd laminated part to obtain a liquid crystal layer laminate,

in the 1 st laminated part with the adhesive layer, at least one end part of the cross section in the width direction, the position of the end part in the width direction of the adhesive layer is more inward in the width direction than the position of the end part of the 1 st liquid crystal layer,

in the liquid crystal layer laminate, at least one end portion of the cross section in the width direction, a position of an end portion of the adhesive layer is the same as a position of an end portion of the 2 nd liquid crystal layer, or is positioned outside in the width direction with respect to the position of the end portion of the 2 nd liquid crystal layer.

5. The method of manufacturing a liquid crystal film according to claim 4,

in the liquid crystal layer laminate, in a cross section in the width direction thereof, positions of both ends in the width direction of the adhesive layer are the same as positions of both ends in the width direction of the 2 nd liquid crystal layer, or are positioned outside in the width direction with respect to the positions of both ends in the width direction of the 2 nd liquid crystal layer.

6. The method of manufacturing a liquid crystal film according to claim 4 or 5,

in the liquid crystal layer laminate, at least one end portion of the cross section in the width direction, a position of the end portion of the 2 nd liquid crystal layer is the same as a position of an end portion of the 2 nd base material layer.

7. The method for producing a liquid crystal film according to any one of claims 4 to 6,

in the liquid crystal layer laminate, in a cross section in the width direction, positions of both ends in the width direction of the 2 nd liquid crystal layer are the same as positions of both ends in the width direction of the 2 nd base material layer.

8. The method for producing a liquid crystal film according to any one of claims 1 to 7, further comprising a step of peeling off a1 st peeling layer including one of the 1 st base material layer and the 2 nd base material layer of the liquid crystal layer laminate.

9. A method for manufacturing a liquid crystal film, comprising:

a step of preparing a1 st laminated part with an adhesive layer, which comprises a1 st base material layer, a1 st liquid crystal layer, and an adhesive layer in this order, and in which, at least one end portion of a cross section in the width direction of the 1 st laminated part with the adhesive layer, the position of the end portion of the adhesive layer is located further inward in the width direction than the position of the end portion of the 1 st liquid crystal layer;

preparing a 2 nd laminated part including a 2 nd base material layer and a 2 nd liquid crystal layer;

a step of obtaining a liquid crystal layer laminate by bonding the adhesive layer of the 1 st laminate section with the adhesive layer and the 2 nd liquid crystal layer of the 2 nd laminate section, wherein the liquid crystal layer laminate is obtained such that the position of the end of the adhesive layer is located further inward in the width direction than the position of the end of the 2 nd liquid crystal layer at the at least one end of the cross section in the width direction of the liquid crystal layer laminate; and

a step of removing a 2 nd end portion including an end portion of the adhesive layer on a side where the one end portion is located in the liquid crystal layer laminate,

and performing the removal step of removing the 2 nd end portion so that a position of an end portion of the adhesive layer on a side from which the 2 nd end portion is removed is identical to a position of at least 1 end portion of the 1 st liquid crystal layer and the 2 nd liquid crystal layer in a cross section in a width direction of the liquid crystal layer stack after the 2 nd end portion is removed.

10. The method of manufacturing a liquid crystal film according to claim 9,

the removing step is performed to remove the 2 nd end portion so that a position of an end portion of the adhesive layer on a side from which the 2 nd end portion is removed is the same as a position of an end portion of the 1 st liquid crystal layer and the same as a position of an end portion of the 2 nd liquid crystal layer in a cross section in a width direction of the liquid crystal layer stack after the 2 nd end portion is removed.

11. The method of manufacturing a liquid crystal film according to claim 9 or 10,

in the liquid crystal layer laminate, in a cross section in the width direction thereof, positions of both ends of the adhesive layer are located more inward in the width direction than positions of both ends of the 2 nd liquid crystal layer,

the 2 nd end portions are both ends in the width direction of the liquid crystal layer laminate.

12. The method of manufacturing a liquid crystal film according to any one of claims 9 to 11, further comprising a step of peeling off a1 st peeling layer including one of the 1 st base material layer and the 2 nd base material layer in the liquid crystal layer laminate after the 2 nd end portion is removed.

13. A method for manufacturing a liquid crystal film, comprising:

preparing a 2 nd laminated part including a 2 nd base material layer and a 2 nd liquid crystal layer;

a step of obtaining a1 st liquid crystal layer laminate by bonding the adhesive layer of the 1 st laminate part with the adhesive layer to the 2 nd liquid crystal layer of the 2 nd laminate part, wherein the 1 st liquid crystal layer laminate is obtained such that the position of the end of the adhesive layer is located further inward in the width direction than the position of the end of the 2 nd liquid crystal layer at the at least one end of the 1 st liquid crystal layer laminate in the width direction cross section;

a step of obtaining a 2 nd liquid crystal layer laminate by peeling a1 st peeling layer including one of the 1 st base material layer and the 2 nd base material layer of the 1 st liquid crystal layer laminate; and

a step of removing a 3 rd end portion including an end portion of the adhesive layer on a side where the at least one end portion of the 2 nd liquid crystal layer stack is located,

the removing step is performed to remove the 3 rd end portion so that the position of the end portion of the adhesive layer is the same as the position of at least one end portion of the 1 st liquid crystal layer and the 2 nd liquid crystal layer in the 3 rd end portion-removed side of the 2 nd liquid crystal layer laminate in the width direction cross section of the 2 nd liquid crystal layer laminate after the 3 rd end portion is removed.

14. The method of manufacturing a liquid crystal film according to claim 13,

the removing step is performed to remove the 3 rd end portion so that the position of the end portion of the adhesive layer is the same as the position of the end portion of the 1 st liquid crystal layer and the position of the end portion of the 2 nd liquid crystal layer is the same as the position of the end portion of the 3 rd liquid crystal layer in the width direction cross section of the 2 nd liquid crystal layer stack from which the 3 rd end portion is removed.

15. The method of manufacturing a liquid crystal film according to claim 13 or 14,

in the 1 st laminated part with the adhesive layer, in a cross section in the width direction, positions of both ends of the adhesive layer are located more inward in the width direction than positions of both ends of the 1 st liquid crystal layer,

in the 1 st liquid crystal layer laminate, in a cross section in the width direction thereof, positions of both ends of the adhesive layer are located more inward in the width direction than positions of both ends of the 2 nd liquid crystal layer,

the 3 rd end portions are both ends in the width direction of the 2 nd liquid crystal layer laminate.

16. The method for producing a liquid crystal film according to any one of claims 1 to 15,

the step of preparing the 1 st laminated part with the adhesive layer includes:

a step of preparing the 1 st laminated part including the 1 st base material layer and the 1 st liquid crystal layer, and a step of laminating an adhesive layer on the side of the 1 st liquid crystal layer opposite to the 1 st base material layer to obtain the 1 st laminated part with the adhesive layer.

17. The method for producing a liquid crystal film according to any one of claims 1 to 16,

the step of performing the surface activation treatment performs the surface activation treatment on the surface on the adhesive layer side of the 1 st laminated part with the adhesive layer and the surface on the 2 nd liquid crystal layer side of the 2 nd laminated part.

18. The method for producing a liquid crystal film according to any one of claims 1 to 17,

the surface activation treatment is corona treatment.

19. The method for producing a liquid crystal film according to any one of claims 1 to 18,

the 1 st liquid crystal layer is a phase difference layer.

20. The method for producing a liquid crystal film according to any one of claims 1 to 19,

the 2 nd liquid crystal layer is a phase difference layer.

21. The method for producing a liquid crystal film according to any one of claims 1 to 20,

the 1 st laminated part with the adhesive layer includes a1 st alignment layer between the 1 st base material layer and the 1 st liquid crystal layer.

22. The method for producing a liquid crystal film according to any one of claims 1 to 21,

the 2 nd laminated part includes a 2 nd alignment layer between the 2 nd base material layer and the 2 nd liquid crystal layer.

23. A method for manufacturing an optical laminate, comprising:

a step of preparing a liquid crystal film produced by the method for producing a liquid crystal film according to any one of claims 8 and 12 to 15,

A step of preparing an optical film,

And a step of laminating the optical film on the layer exposed by peeling the 1 st peeling layer with the optical film adhesive layer interposed therebetween.

24. The method for manufacturing an optical laminate according to claim 23, further comprising a step of peeling off a 2 nd peeling layer including one of the 1 st base material layer and the 2 nd base material layer which is not included in the 1 st peeling layer.

25. The method for manufacturing an optical stack according to claim 24,

an adhesive layer for an optical layered body is laminated on the layer exposed by peeling the 2 nd peeling layer.

Technical Field

The present invention relates to a method for manufacturing a liquid crystal film and a method for manufacturing an optical laminate.

Background

Organic EL display devices using Organic Light Emitting Diodes (OLEDs) are used in various fields such as smart phones, televisions, and digital cameras because they can achieve not only light weight and thin profile, but also high image quality such as wide viewing angle, fast response speed, and high contrast, as compared with liquid crystal display devices. In an organic EL display device, it is known that in order to suppress a reduction in visibility due to reflection of external light, antireflection performance is improved by using a circularly polarizing plate or the like.

JP 2015-25947 a1 describes a circularly polarizing plate obtained by laminating a linearly polarizing plate and a 1/4 wavelength plate as an optical film applied to an image display panel of an organic EL display device or a liquid crystal display device, and describes that a 1/2 wavelength retardation layer and a 1/4 wavelength retardation layer are laminated to form a 1/4 wavelength plate.

Disclosure of Invention

Problems to be solved by the invention

An object of the present invention is to provide a method for producing a liquid crystal film suitable for producing an optical laminate, and a method for producing an optical laminate.

Means for solving the problems

The present invention provides a method for manufacturing a liquid crystal film and a method for manufacturing an optical laminate, which are described below.

[ 1 ] A method for manufacturing a liquid crystal film, comprising:

preparing a1 st laminated part with an adhesive layer, which sequentially comprises a1 st base material layer, a1 st liquid crystal layer, and an adhesive layer;

preparing a 2 nd laminated part including a 2 nd base material layer and a 2 nd liquid crystal layer;

removing at least one of the 1 st end portions including the end portions of the adhesive layer in the cross section in the width direction of the 1 st laminated portion with the adhesive layer; and

the step of removing is performed before or after the step of performing the surface activation treatment,

the 1 st end portion is removed such that a position of an end portion of the adhesive layer on a side from which the 1 st end portion is removed is the same as a position of an end portion of the 1 st liquid crystal layer in a widthwise cross section of the 1 st laminated portion with the adhesive layer from which the 1 st end portion is removed.

The method for producing a liquid crystal film according to [ 1 ], wherein the step of removing is performed before the step of performing the surface activation treatment.

[ 3 ] the method for producing a liquid crystal film according to the above [ 1 ] or [ 2 ], wherein in the 1 st laminated part with the adhesive layer, positions of both ends in the width direction of the adhesive layer are located more inward in the width direction than positions of both ends in the width direction of the 1 st liquid crystal layer in a cross section in the width direction,

the 1 st end portion is a width-direction both ends of the 1 st laminated portion with the adhesive layer.

[ 4 ] A method for manufacturing a liquid crystal film, comprising:

preparing a1 st laminated part with an adhesive layer, which sequentially comprises a1 st base material layer, a1 st liquid crystal layer, and an adhesive layer;

preparing a 2 nd laminated part including a 2 nd base material layer and a 2 nd liquid crystal layer;

a step of bonding the adhesive layer of the 1 st laminated part with the adhesive layer to the 2 nd liquid crystal layer of the 2 nd laminated part to obtain a liquid crystal layer laminate,

in the liquid crystal layer laminate, at least one end portion of the cross section in the width direction, a position of an end portion of the adhesive layer is the same as or outside in the width direction with respect to a position of an end portion of the 2 nd liquid crystal layer.

[ 5 ] the method for producing a liquid crystal film according to [ 4 ], wherein in the 1 st laminated layer with an adhesive layer, positions of both ends in the width direction of the adhesive layer are located more inward in the width direction than positions of both ends in the width direction of the 1 st liquid crystal layer in a cross section in the width direction,

in the liquid crystal layer laminate, in a cross section in the width direction thereof, positions of both ends in the width direction of the adhesive layer are the same as or outside in the width direction of the 2 nd liquid crystal layer.

[ 6 ] the method for manufacturing a liquid crystal film according to any one of [ 4 ] and [ 5 ], wherein the liquid crystal layer laminate has at least one end portion in the cross-sectional plane in the width direction, the end portion of the 2 nd liquid crystal layer being positioned at the same position as the end portion of the 2 nd base material layer.

[ 7 ] the method according to any one of [ 4 ] to [ 6 ], wherein positions of both ends in a width direction of the 2 nd liquid crystal layer in the liquid crystal layer laminate are the same as positions of both ends in the width direction of the 2 nd base layer in a cross section in the width direction.

The method for producing a liquid crystal film according to any one of [ 1 ] to [ 7 ], further comprising a step of peeling off a1 st peeling layer including one of the 1 st base material layer and the 2 nd base material layer of the liquid crystal layer laminate.

[ 9 ] A method for manufacturing a liquid crystal film, comprising:

a step of preparing a1 st laminated part with an adhesive layer, which includes a1 st base material layer, a1 st liquid crystal layer, and an adhesive layer in this order, and in which, at least one end portion of a cross section in the width direction of the 1 st laminated part with the adhesive layer, the position of the end portion of the adhesive layer is located further inward in the width direction than the position of the end portion of the 1 st liquid crystal layer;

preparing a 2 nd laminated part including a 2 nd base material layer and a 2 nd liquid crystal layer;

a step of removing a 2 nd end portion including an end portion of the adhesive layer on a side where the one end portion is located in the liquid crystal layer laminate,

the removing step is performed to remove the 2 nd end portion so that a position of an end portion of the adhesive layer on a side from which the 2 nd end portion is removed is identical to a position of at least 1 end portion of the 1 st liquid crystal layer and the 2 nd liquid crystal layer in a cross section in a width direction of the liquid crystal layer stack after the 2 nd end portion is removed.

[ 10 ] the method for manufacturing a liquid crystal film according to [ 9 ], wherein the removing step removes the 2 nd end so that a position of an end of the adhesive layer on a side from which the 2 nd end is removed is the same as a position of an end of the 1 st liquid crystal layer and the same as a position of an end of the 2 nd liquid crystal layer in a cross-sectional view of the liquid crystal layer stack in a width direction after the 2 nd end is removed.

[ 11 ] the method for producing a liquid crystal film according to any one of [ 9 ] and [ 10 ], wherein in the 1 st laminated part with the adhesive layer, positions of both ends in the width direction of the adhesive layer are located more inward in the width direction than positions of both ends in the width direction of the 1 st liquid crystal layer in a cross section in the width direction,

the 2 nd end portions are both ends in the width direction of the liquid crystal layer laminate.

The method for producing a liquid crystal film according to any one of [ 9 ] to [ 11 ], further comprising a step of peeling off a1 st peeling layer including one of the 1 st base material layer and the 2 nd base material layer in the liquid crystal layer laminate after the 2 nd end portion is removed.

[ 13 ] A method for manufacturing a liquid crystal film, comprising:

a step of preparing a1 st laminated part with an adhesive layer, which includes a1 st base material layer, a1 st liquid crystal layer, and an adhesive layer in this order, and a step of preparing the 1 st laminated part with an adhesive layer, in which at least one end portion of a cross section in a width direction of the 1 st laminated part with an adhesive layer is positioned further inward in the width direction than a position of an end portion of the 1 st liquid crystal layer;

preparing a 2 nd laminated part including a 2 nd base material layer and a 2 nd liquid crystal layer;

a step of obtaining a1 st liquid crystal layer laminate by bonding the adhesive layer of the 1 st laminate part with the adhesive layer and the 2 nd liquid crystal layer of the 2 nd laminate part, wherein the 1 st liquid crystal layer laminate is obtained such that the position of the end of the adhesive layer is located further inward in the width direction than the position of the end of the 2 nd liquid crystal layer at the at least one end of the 1 st liquid crystal layer laminate in the width direction cross section;

a step of removing a 3 rd end portion including an end portion of the adhesive layer on a side where the at least one end portion of the 2 nd liquid crystal layer stack is located,

The method for manufacturing a liquid crystal film according to [ 13 ], wherein the removing step removes the 3 rd end portion so that a position of an end portion of the adhesive layer is the same as a position of an end portion of the 1 st liquid crystal layer and the same as a position of an end portion of the 2 nd liquid crystal layer in a width-directional cross section of the 2 nd liquid crystal layer laminate from which the 3 rd end portion is removed.

[ 15 ] the method for producing a liquid crystal film according to any one of [ 13 ] and [ 14 ], wherein in the 1 st laminated part with the adhesive layer, positions of both ends in the width direction of the adhesive layer are located more inward in the width direction than positions of both ends in the width direction of the 1 st liquid crystal layer in a cross section in the width direction,

in the 1 st liquid crystal layer laminate, in a cross section in the width direction thereof, positions of both ends in the width direction of the adhesive layer are located more inward in the width direction than positions of both ends in the width direction of the 2 nd liquid crystal layer,

the 3 rd end portions are both ends in the width direction of the 2 nd liquid crystal layer laminate.

The method according to any one of [ 1 ] to [ 15 ], wherein the step of preparing the 1 st stacked part with the adhesive layer comprises:

preparing a1 st laminated part including the 1 st base material layer and the 1 st liquid crystal layer; and

and a step of laminating an adhesive layer on the 1 st liquid crystal layer on the side opposite to the 1 st base material layer to obtain the 1 st laminated part with the adhesive layer.

The method for producing a liquid crystal film according to any one of [ 1 ] to [ 16 ], wherein the step of performing the surface activation treatment performs surface activation treatment on a surface on the adhesive layer side of the 1 st laminated part with an adhesive layer and a surface on the 2 nd liquid crystal layer side of the 2 nd laminated part.

The method for producing a liquid crystal film according to any one of [ 1 ] to [ 17 ], wherein the surface activation treatment is a corona treatment.

The method according to any one of [ 1 ] to [ 18 ], wherein the 1 st liquid crystal layer is a retardation layer.

The method according to any one of [ 1 ] to [ 19 ], wherein the 2 nd liquid crystal layer is a retardation layer.

The method for producing a liquid crystal film according to any one of [ 1 ] to [ 20 ], wherein the 1 st laminated part with an adhesive layer includes a1 st alignment layer between the 1 st base material layer and the 1 st liquid crystal layer.

The method for producing a liquid crystal film according to any one of [ 1 ] to [ 21 ], wherein the 2 nd stacked part includes a 2 nd alignment layer between the 2 nd base material layer and the 2 nd liquid crystal layer.

[ 23 ] A method for producing an optical laminate, comprising:

a step of preparing a liquid crystal film produced by the method for producing a liquid crystal film according to any one of [ 8 ] and [ 12 ] to [ 15 ],

Step of preparing optical film, and

and a step of laminating the optical film on the layer exposed by peeling the 1 st peeling layer with the optical film adhesive layer interposed therebetween.

The method for producing an optical laminate according to [ 23 ], further comprising a step of peeling a 2 nd peeling layer including a layer not included in the 1 st peeling layer out of the 1 st base material layer and the 2 nd base material layer.

[ 25 ] the method for producing an optical laminate according to [ 24 ], wherein an adhesive layer for an optical laminate is laminated on the layer exposed by peeling the 2 nd peeling layer.

Effects of the invention

According to the present invention, a method for producing a liquid crystal film suitable for producing an optical laminate and a method for producing an optical laminate can be provided.

Drawings

Fig. 1(a) to (e) are schematic cross-sectional views schematically showing an example of a process for producing a retardation film as a liquid crystal film of the present invention.

Fig. 2(a) to (c) are schematic cross-sectional views schematically showing an example of the process for producing the optical laminate of the present invention.

Fig. 3(a) to (d) are schematic cross-sectional views schematically showing another example of a process for producing a retardation film as a liquid crystal film of the present invention.

Fig. 4(a) to (c) are schematic cross-sectional views schematically showing another example of the process for producing the optical laminate of the present invention.

Fig. 5(a) to (e) are schematic cross-sectional views schematically showing another example of a process for producing a retardation film as a liquid crystal film of the present invention.

Fig. 6(a) to (e) are schematic cross-sectional views schematically showing another example of the process for producing a retardation film as a liquid crystal film of the present invention.

Fig. 7(a) to (d) are schematic cross-sectional views schematically showing an example of a process for producing an optical laminate which is a premise of the present invention.

Description of the symbols

10a to 10d, 10p No. 1 laminate part with adhesive layer, 10a₁1 st laminated part with adhesive layer, 11a to 11d, 11a after 1 st end part is removed₁、11c₁、11d₂11p No. 1 base material layer, 12a to 12d, 12a₁、12c₁、12b₁、12d₂、12p、12p₁Phase difference layer 1 (liquid crystal layer 1), 12' p transfer portions 13a to 13d, 13a₁、13c₁、13d₂13p adhesive layer, 14a 1 st end portion,20a to 20d, 20p 2 nd laminate parts, 21a to 21d, 21c₁21p 2 nd base material layer, 22a to 22d, 22a₁、22c₁、22d₁、22d₂22p No. 2 retardation layer (No. 2 liquid crystal layer), 30d No. 2 retardation layer laminate (No. 2 liquid crystal layer laminate), 30d₂A 2 nd retardation layer laminate after the 3 rd end portion was removed (a 2 nd liquid crystal layer laminate after the 3 rd end portion was removed), 34d a 3 rd end portion, 40a to 40c, 40p retardation layer laminates (liquid crystal layer laminates), 40d a1 st retardation layer laminate (a 1 st liquid crystal layer laminate), 40c₁The retardation layer laminate after the 2 nd end was removed (the liquid crystal layer laminate after the 2 nd end was removed), 44c the 2 nd end, 50a to 50d, 50p retardation films (liquid crystal films), 60a to 60d, 60p optical films, a part of 60 'p optical film, 62a to 62d, 62p optical film adhesive layer, 62' p optical film adhesive layer, 70a to 70d, 70p optical laminate, W width direction.

Detailed Description

Before describing preferred embodiments of the method for manufacturing a liquid crystal film and the method for manufacturing an optical laminate according to the present invention, the premise of the embodiments of the present invention will be described. Fig. 7(a) to (d) are schematic cross-sectional views schematically showing steps of manufacturing an optical laminate 70p, which will be a premise of the embodiment described later. In the figure, W represents the width direction. In the following description, a case where the 1 st liquid crystal layer and the 2 nd liquid crystal layer are respectively the 1 st retardation layer and the 2 nd retardation layer, and the liquid crystal film is a retardation film is exemplified.

In the method for producing an optical laminate, as shown in fig. 7(a), a retardation layer laminate 40p may be used in which a1 st laminate 10p including a1 st base material layer 11p and a1 st retardation layer 12p and a 2 nd laminate 20p including a 2 nd base material layer 21p and a 2 nd retardation layer 22p are laminated with an adhesive layer 13p interposed therebetween. When the 2 nd base material layer 21p is peeled from the retardation layer laminate 40p as shown in fig. 7(b), a part of the 2 nd retardation layer 22p is transferred to the peeled 2 nd base material layer 21p, and the 2 nd retardation layer 22p is formed on the adhesive layer 13p₁The retardation film 50 p. This is because the retardation layer laminate 40p shown in fig. 7(a) has a width of the 2 nd retardation layer 22pAt both ends in the direction, there are non-fixed regions (portions indicated by the diagonal lines in fig. 7 (a)) not fixed to the adhesive layer 13p, and the 2 nd retardation layer 22p is separated into the 2 nd retardation layer 22p as a region fixed to the adhesive layer 13p by peeling the 2 nd base material layer 21p₁And transferred to the non-fixed region of the 2 nd base material layer 21 p.

Next, in the 2 nd retardation layer 22p of the retardation film 50p shown in FIG. 7(b)₁As shown in fig. 7 c, after the optical film 60p is laminated with the optical film adhesive layer 62p interposed therebetween, the 1 st base material layer 11p included in the retardation film 50p is peeled off, and an optical laminate 70p can be obtained (fig. 7 d).

However, in the retardation layer laminate 40p shown in fig. 7(a), there is a region where the 1 st retardation layer 12p and the 2 nd retardation layer 22p do not face each other with the adhesive layer 13p interposed therebetween at the end in the width direction. In such a region, the 1 st retardation layer 12p and the 2 nd retardation layer 22p are likely to be in direct contact, and depending on the strength of contact between the 1 st retardation layer 12p and the 2 nd retardation layer 22p and the state of the surfaces of the 1 st retardation layer 12p and the 2 nd retardation layer 22p, as shown in fig. 7(a), a part 12 'p (hereinafter, sometimes referred to as a "transfer part 12' p") of the 1 st retardation layer 12p may be transferred to the 2 nd retardation layer 22 p. When the transfer portion 12' p of the 1 st retardation layer 12p is transferred to the 2 nd retardation layer 22p, a part of the 1 st retardation layer 12p is peeled off, and a peeled-off portion p is formed in the 1 st retardation layer 12 p. Depending on the state of the surfaces of the 1 st retardation layer 12p and the 2 nd retardation layer 22p, and the contact state between the 1 st retardation layer 12p and the 2 nd retardation layer 22p, there may be a case where the detached part p of the 1 st retardation layer 12p and the transition part 12' p to the 2 nd retardation layer 22p occur continuously in the longitudinal direction.

Since such a peeling portion p is also present in the retardation film 50p as shown in fig. 7 b, when the optical film 60p is laminated on the retardation film 50p via the optical film adhesive layer 62p (fig. 7 c), the 1 st base material layer 11p and the optical film 60p may be bonded to each other via the optical film adhesive layer 62p in the region of the peeling portion p. When the 1 st base material layer 11p is peeled off with such an adhesive portion formed, as shown in fig. 7(d), a part 60 'p of the optical film 60p and a part 62' p of the optical film adhesive layer 62p are fixed to the 1 st base material layer 11p, and therefore the optical laminate 70p obtained may be a laminate in which the optical film 60p and the optical film adhesive layer 62p are broken at the end portions thereof. The optical laminate 70p having the broken end portion as shown in fig. 7(d) is not preferable because the appearance is poor and the traveling property tends to be unstable when the optical laminate 70p is transported.

In addition, in the retardation layer laminate 40p shown in fig. 7(a), the transfer portion 12' p may be detached during conveyance of the 2 nd base material layer 21p peeled from the retardation layer laminate 40 p. The detached transfer portion 12' p adheres to the retardation film 50p and the conveyance path, and causes contamination of the product and the conveyance path during production, and may cause poor appearance of the resulting optical laminate. In the retardation layer laminate 40p shown in fig. 7(a), a part of the 2 nd retardation layer 22p may be shifted to the 1 st retardation layer 12 p. In these cases, a part of the 2 nd retardation layer 22p transferred to the 1 st retardation layer 12p may fall off and adhere to the retardation film and the conveyance path during conveyance of the retardation film, which may cause contamination of the product and the conveyance path during production, and may cause poor appearance of the obtained optical laminate.

Therefore, in the following embodiments, a method for manufacturing a liquid crystal film and a method for manufacturing an optical laminate are described, which can appropriately manufacture an optical laminate by suppressing appearance defects of the optical laminate and instability of traveling performance during transportation by making it difficult to cause breakage of an end portion, contamination of a product during manufacturing, a transportation path, or the like.

Hereinafter, preferred embodiments of the method for manufacturing a liquid crystal film and the method for manufacturing an optical laminate according to the present invention will be described with reference to the drawings. In the following description, a case where the 1 st liquid crystal layer and the 2 nd liquid crystal layer are the 1 st retardation layer and the 2 nd retardation layer, respectively, and the liquid crystal film is a retardation film will be described as an example.

[ embodiment 1 ]

(method for producing retardation film)

Fig. 1(a) to (e) are schematic cross-sectional views schematically showing an example of a method for producing a retardation film 50a (liquid crystal film) according to the present embodiment. In the figure, W represents the width direction.

The method for producing the retardation film 50a of the present embodiment includes, for example:

a step of preparing a1 st laminated part 10a with an adhesive layer, which includes a1 st base material layer 11a, a1 st retardation layer 12a (1 st liquid crystal layer), and an adhesive layer 13a in this order (fig. 1 a);

a step of preparing a 2 nd laminated part 20a including a 2 nd base material layer 21a and a 2 nd retardation layer 22a (2 nd liquid crystal layer) (fig. 1 (b));

a step of removing both widthwise ends (1 st end 14a) of the 1 st laminated part 10a with the adhesive layer (fig. 1(a) and (c));

the 1 st laminated part 10a with an adhesive layer after the 1 st end part 14a is removed₁Adhesive layer 13a of₁A step of performing surface activation treatment on the surface on the side and the surface on the 2 nd retardation layer 22a side of the 2 nd stacked part 20 a; and

the 1 st laminated part 10a with the adhesive layer after surface activation treatment₁Adhesive layer 13a of₁And a step of obtaining a retardation layer laminate 40a (liquid crystal layer laminate) by laminating the retardation layer 2 22a of the 2 nd laminate part 20a (fig. 1 (d)).

In the 1 st laminated part 10a with an adhesive layer shown in FIG. 1(a), in its cross section in the width direction, the positions of both ends in the width direction of the adhesive layer 13a are located further inward in the width direction than the positions of both ends in the width direction of the 1 st retardation layer 12a,

the step of removing the 1 st end portion 14a shown in FIG. 1(a) is performed before the step of performing the surface activation treatment, and the 1 st end portion 14a is removed in such a manner that the 1 st laminated portion 10a with the adhesive layer after the 1 st end portion 14a is removed₁In the cross section in the width direction of (2), the adhesive layer 13a₁And the 1 st retardation layer 12a at both ends in the width direction₁The positions of both ends in the width direction of (1) are the same (fig. 1 (c)). The method for producing the retardation film 50a may further include a step of peeling the 2 nd base material layer 21a (1 st peeling layer) as shown in fig. 1 (e).

The following description is specifically made based on the drawings. In the manufacturing method shown in fig. 1, first, a1 st laminated part 10a with an adhesive layer including a1 st base material layer 11a, a1 st retardation layer 12a, and an adhesive layer 13a in this order as shown in fig. 1(a), and a 2 nd laminated part 20a including a 2 nd base material layer 21a and a 2 nd retardation layer 22a as shown in fig. 1(b) are prepared. The 1 st and 2 nd laminated portions 10a and 20a with adhesive layers are long film-like materials, and the steps described later are performed while the 1 st and 2 nd laminated portions 10a and 20a with adhesive layers are continuously conveyed. The width direction W is a direction orthogonal to the longitudinal direction of the film.

Then, the 1 st laminated part 10a with an adhesive layer shown in fig. 1(a) is cut at both ends in the width direction by a broken line Xa, and the 1 st end part 14a on the outer side in the width direction with respect to the broken line Xa is removed. As a result, as shown in FIG. 1(c), the substrate layer 11a having the 1 st base material layer 11a was obtained₁1 st retardation layer 12a₁And an adhesive layer 13a₁1 st laminated part 10a with adhesive layer after removing 1 st end part 14a₁(hereinafter, it may be referred to as "the 1 st laminated part with adhesive layer 10a₁". ). Next, the 1 st laminated part 10a with an adhesive layer₁Adhesive layer 13a of₁The surface of the first laminated part 10a with an adhesive layer is subjected to surface activation treatment on the surface of the second laminated part 20a on the 2 nd retardation layer 22a side₁Adhesive layer 13a of₁The resulting laminate was bonded to the 2 nd retardation layer 22a of the 2 nd laminate section 20a to obtain a retardation layer laminate 40a shown in fig. 1 (d). Thereafter, the 2 nd base material layer 21a (1 st release layer) was peeled from the retardation layer laminate 40a, thereby obtaining a retardation film 50a shown in fig. 1 (e).

In the 1 st laminated part 10a with an adhesive layer, as shown in fig. 1(a), in a cross section in the width direction, positions of both ends in the width direction of the adhesive layer 13a are located inward with respect to positions of both ends in the width direction of the 1 st retardation layer 12 a. The positions of both ends in the width direction of the adhesive layer 13a are not particularly limited, but may be in a region of 0.2cm or more, a region of 0.5cm or more, a region of 1.0cm or more, and a region of generally 20cm or less, and preferably a region of 15cm or less, inward in the width direction with respect to the position of the end in the width direction of the 1 st retardation layer 12 a. In the 1 st laminated part 10a with an adhesive layer shown in fig. 1(a), the positions of both ends in the width direction of the 1 st base material layer 11a are located outside the positions of both ends in the width direction of the 1 st retardation layer 12a, but may be the same as the positions of both ends in the width direction of the 1 st retardation layer 12 a.

In the 2 nd laminated part 20a, as shown in fig. 1(b), in the cross section in the width direction, both ends in the width direction of the 2 nd base material layer 21a may be positioned outside both ends in the width direction of the 2 nd retardation layer 22a, or may be positioned at the same positions as both ends in the width direction of the 2 nd retardation layer 22 a.

The position of the broken line Xa in FIG. 1(a) is determined by removing the 1 st end 14a of the 1 st laminated part 10a with an adhesive layer at both widthwise ends of the 1 st laminated part 10a with an adhesive layer₁(FIG. 1(c)) an adhesive layer 13a in a cross section in the width direction₁And the 1 st phase difference layer 12a₁In the same manner as the positions of the two ends of (a).

In the 1 st laminated part 10a with an adhesive layer shown in fig. 1(a), the position of the broken line Xa is usually determined so that the 1 st end 14a includes the ends of the 1 st base material layer 11a and the 1 st retardation layer 12a, and preferably determined so that the 1 st base material layer 11a, the 1 st retardation layer 12a, and the adhesive layer 13a are included. The layers contained in the 1 st end portion 14a removed from both width-direction end portions of the 1 st laminated portion 10a with an adhesive layer may be the same as or different from each other.

The position of the broken line Xa defining the region of the 1 st end portion 14a is a region of usually 0.5cm or more, may be a region of 1.0cm or more, may be a region of 1.5cm or more, and is a region of usually 20cm or less, preferably a region of 15cm or less, and more preferably a region of 10cm or less, on the inner side in the width direction with respect to the end portion of the 1 st laminated portion 10a with an adhesive layer located on the outermost side in the width direction. The distance from the end of the 1 st laminated part 10a with an adhesive layer located on the outermost side in the width direction to the position of the broken line Xa may be the same at both ends of the 1 st laminated part 10a with an adhesive layer in the width direction, or may be different from each other.

As the 1 st laminated part 10a with adhesive layer₁Adhesive layer 13a of₁The surface activation treatment performed on the side surface and the surface on the 2 nd retardation layer 22a side of the 2 nd stacked part 20a include a treatment for hydrophilizing the surface. Specific examples thereof include discharge treatments such as corona treatment, plasma treatment, and glow discharge; flame treatment; carrying out ozone treatment; carrying out UV ozone treatment; and ionizing active ray treatment such as ultraviolet ray treatment and electron beam treatment, among them, corona treatment and plasma treatment are preferable, and corona treatment is more preferable.

The degree of the surface activation treatment is not particularly limited, but it is preferable that the 1 st laminated part 10a with an adhesive layer is formed₁Adhesive layer 13a of₁The surface of (2) and the surface of the 2 nd retardation layer 22a of the 2 nd stacked part 20a are treated so that the water contact angle is less than 100 °, more preferably less than 90 °, and still more preferably less than 80 °. When the surface activation treatment is corona treatment, the treatment amount may be, for example, 30 to 3000J/m²。

In the retardation layer laminate 40a, the adhesive layer 13a is provided in a cross section in the width direction thereof₁And the 1 st retardation layer 12a at both ends in the width direction₁The positions of both ends in the width direction of (2) are the same. The positions of both ends in the width direction of the 2 nd retardation layer 22a and the 2 nd base material layer 21a in the retardation layer laminate 40a are not particularly limited. In order to effectively utilize the 1 st retardation layer 12a₁Preferably, in the retardation layer laminate 40a, the positions of both ends in the width direction of the 2 nd retardation layer 22a and the adhesive layer 13a₁The widthwise ends of (b) are located at the same position or outside of the position. In order to prevent the adhesive layer-attached first laminated part 10a from being involved in transportation of the retardation layer laminated body 40a₁Adhesive layer 13a of₁Exposing or forming the adhesive layer 13a₁The adhesive or the adhesive bleeding in (2) is preferably applied to both ends of the retardation layer laminate 40a in the width direction, at least one of the 2 nd retardation layer 22a and the 2 nd base material layer 21a, and the adhesive layer 13a₁Of the end portionThe position is the same, or located outside with respect to this position.

The retardation film 50a can be obtained by peeling the 2 nd base material layer 21a (1 st peeling layer) from the retardation layer laminate 40 a. The retardation film 50a shown in FIG. 1(e) has a1 st base material layer 11a₁1 st retardation layer 12a₁And an adhesive layer 13a₁And 2 nd retardation layer 22a₁. In the retardation film 50a, the 2 nd retardation layer 22a is formed in a cross section in the width direction thereof₁And the adhesive layer 13a and the positions of both ends in the width direction of₁The positions of both ends in the width direction of (2) are the same.

When the 2 nd base material layer 21a is peeled from the retardation layer laminate 40a shown in fig. 1(d), a part of the 2 nd retardation layer 22a is easily transferred to the peeled 2 nd base material layer 21a as shown in fig. 1 (e). This is because, in the retardation layer laminate 40a shown in fig. 1(d), in the cross section in the width direction thereof, the positions of both ends in the width direction of the 2 nd retardation layer 22a are located with respect to the adhesive layer 13a₁Is located outside the width direction both ends of the retardation layer 22a, and has a layer not fixed to the adhesive layer 13a₁The unfixed area (the portion indicated by the diagonal lines in fig. 1(d) with the lower left and the higher right). Therefore, when the 2 nd base material layer 21a is peeled from the retardation layer laminate 40a, the 2 nd retardation layer 22a shown in fig. 1(d) is separated and fixed to the adhesive layer 13a₁(ii) region (2 nd retardation layer 22a shown in FIG. 1 (e))₁) And unfixed regions (portions indicated by oblique lines in fig. 1(d) and (e) with lower left and higher right) transferred to the 2 nd base material layer 21a, the 2 nd retardation layer 22a can be obtained in the cross section in the width direction as shown in fig. 1(e)₁And the 1 st laminated part 10a with an adhesive layer₁Adhesive layer 13a of₁The retardation film 50a having the same position at both ends in the width direction.

When the surface activation treatment is performed in the process of producing the retardation film 50a, particularly when the 1 st retardation layer 12p and the 2 nd retardation layer 22p are in direct contact as in the case of the retardation layer laminate 40p described with reference to fig. 7(a) to (d), a phenomenon tends to occur in which a part 12' p of the 1 st retardation layer 12p is transferred to the 2 nd retardation layer 22p or a part of the 2 nd retardation layer 22p is transferred to the 1 st retardation layer 12 p.

In contrast, in the retardation film 50a obtained by the production method of the present embodiment, the 1 st retardation layer 12a₁Phase difference layer 22a with No. 2₁Sandwiching an adhesive layer 13a₁Facing each other, without the 1 st retardation layer 12a₁Phase difference layer 22a with No. 2₁Without sandwiching the adhesive layer 13a₁The facing areas. Therefore, in the retardation film 50a, the 1 st retardation layer 12a is not present₁Phase difference layer 22a with No. 2₁In the case of direct contact, and thus the 1 st retardation layer 12a₁To the 2 nd phase difference layer 22a₁Transfer, or 2 nd retardation layer 22a₁To the 1 st phase difference layer 12a₁The transfer can be prevented. This makes it possible to suppress the occurrence of breakage at the end of the optical laminate 70a when the optical laminate 70a described later is manufactured using the retardation film 50a, and to suppress contamination of the product and the conveyance path during the manufacturing.

(method for producing optical layered body)

Fig. 2(a) to (c) are schematic cross-sectional views schematically showing an example of the method for producing the optical laminate 70a according to the present embodiment. In the figure, W represents the width direction.

The method for manufacturing the optical laminate 70a of the present embodiment includes:

a step of preparing a retardation film 50a (FIG. 2(a))

A step of preparing an optical film 60a (FIG. 2(a)), and

an optical film 60a is laminated on the 2 nd retardation layer 22a exposed by peeling the 2 nd base material layer 21a (1 st peeling layer) via an optical film adhesive layer 62a₁Step (2) (FIG. 2 (b)).

The method for producing the optical laminate 70a of the present embodiment may further comprise peeling the 1 st base material layer 11a₁(step (2 nd release layer) (FIG. 2(c)), the first base material layer 11a may be peeled off₁And the 1 st retardation layer 12a is exposed₁And an adhesive layer for an optical layered body is laminated on the upper layer.

The following description is specifically made based on the drawings. In the method of manufacturing the optical laminate 70a shown in fig. 2(c), first, as shown in fig. 2(a), a retardation film 50a and an optical film 60a are prepared. The retardation film 50a and the optical film 60a are long film-like materials, and the steps described below are performed while continuously conveying the retardation film 50a and the optical film 60 a.

Then, as shown in fig. 2(b), the optical film 60a is laminated on the 2 nd retardation layer 22a of the retardation film 50a via the adhesive layer 62a for optical film₁. In this case, the optical film 60a may be provided with the optical film adhesive layer 62a, and the optical film adhesive layer 62a and the 2 nd retardation layer 22a of the retardation film 50a may be further provided₁The retardation film 50a may be bonded to the 2 nd retardation layer 22a₁An optical film adhesive layer 62a is provided thereon, and the optical film adhesive layer 62a is bonded to the optical film 60 a.

After the optical film 60a and the retardation film 50a are laminated with the optical film adhesive layer 62a interposed therebetween, the 1 st base material layer 11a included in the retardation film 50a is peeled off₁(peeling layer 2), thereby obtaining an optical laminate 70a shown in fig. 2 (c). As shown in fig. 2(c), the optical laminate 70a includes the 1 st retardation layer 12a laminated in this order₁And an adhesive layer 13a₁2 nd retardation layer 22a₁An optical film adhesive layer 62a, and an optical film 60 a. The optical laminate 70a may be formed by peeling the 1 st base material layer 11a₁And the 1 st retardation layer 12a is exposed₁An adhesive layer for an optical layered body, not shown, is formed thereon. The adhesive layer for an optical layered body can be used when it is bonded to a display panel such as an organic EL display device or a liquid crystal display device.

The optical film 60a may have both ends in the width direction positioned on the width direction cross section of the optical laminate 70a so as to be in contact with the 2 nd retardation layer 22a₁And an adhesive layer 13a₁And 1 st retardation layer 12a₁The positions of both ends in the width direction of any one of them are the same, and may be different from any one of them. For example, the optical film 60a may have a length in the width direction larger than that of the 2 nd retardation layer 22a as shown in FIG. 2(c)₁And an adhesive layer 13a₁And 1 st retardation layer 12a₁May be longer or shorter than either of these layers.

Positions at both ends in the width direction of the adhesive layer 62a for optical filmIt is preferable that the optical layered body 70a is located at the same position as both ends of the optical film 60a in the width direction in the cross section in the width direction, or located further inward than the position. In addition, the positions of both ends in the width direction of the adhesive layer 62a for optical film are preferably the same as the 2 nd retardation layer 22a₁And an adhesive layer 13a₁And 1 st retardation layer 12a₁The positions of both ends in the width direction of any one of the above-mentioned members are the same or are located further inward in the width direction than the positions. This prevents the optical film adhesive layer 62a from sticking to the transport path and contaminating the transport path by protruding outward in the width direction of the optical laminate 70a when the optical laminate 70a is transported.

As described above, in the retardation film 50a shown in FIG. 1(e), the 1 st retardation layer 12a is not present₁Phase difference layer 22a with No. 2₁In the case of direct contact, and thus the 1 st retardation layer 12a₁To the 2 nd phase difference layer 22a₁Transfer, or 2 nd retardation layer 22a₁To the 1 st phase difference layer 12a₁The transfer can be prevented. Therefore, unlike the retardation layer laminate 40p described with reference to fig. 7(a) to (d), the optical laminate 70a shown in fig. 2(c) can be produced without generating the detached portion p in the 1 st retardation layer 12p and without breaking the end portion like the optical laminate 70p and without contaminating the product and the conveyance path during production.

The method for producing the retardation film and the method for producing the optical laminate according to the present embodiment may be modified as shown below. The above-described embodiments and the modifications described below may be combined as desired.

(modification 1 of embodiment 1)

In the manufacturing method of the present embodiment, the 1 st end portion 14a in the width direction of the 1 st laminated part 10a with an adhesive layer can be removed. In this case, the end of the optical layered body is prevented from being broken on the side from which the 1 st end 14a is removed, and contamination of the product and the conveyance path during production can be prevented.

(modification 2 of embodiment 1)

In the manufacturing method of the present embodiment, only one of the surfaces may be tabulatedAnd (5) performing surface activation treatment. For the 1 st laminated part 10a with an adhesive layer₁Adhesive layer 13a of₁The 2 nd retardation layer 22a is easily bonded to the 2 nd laminate part 20a, and is preferably bonded to the 1 st laminate part 10a with an adhesive layer₁Adhesive layer 13a of₁The surface of the second laminated part 20a and the surface of the 2 nd retardation layer 22a are both subjected to surface activation treatment.

In the manufacturing method of the present embodiment, the surface of the 1 st laminated part 10a with an adhesive layer before the 1 st end part 14a is removed on the adhesive layer 13a side may be subjected to surface activation treatment. In this case, the surface activation treatment may be performed only on one of the surface of the 1 st laminated part 10a with the adhesive layer before the 1 st end part 14a is removed on the adhesive layer 13a side and the surface of the 2 nd laminated part 20a on the 2 nd retardation layer 22a side. In order to effectively exhibit the effect, it is preferable to remove the 1 st end portion 14a and then apply the adhesive layer-attached 1 st laminated portion 10a₁And carrying out surface activation treatment.

(modification 3 of embodiment 1)

In the manufacturing method of the present embodiment, only one end portion in the width direction of the adhesive layer may be positioned further inward in the width direction than the end portion of the 1 st retardation layer. In this case, in the step of removing the 1 st end portion, the 1 st end portion on the one end portion side of the adhesive layer of the 1 st laminated portion with the adhesive layer may be removed.

(modification 4 of embodiment 1)

In the production method of the present embodiment, the 1 st release layer may be the 1 st base material layer 11a₁And the 2 nd release layer is a 2 nd base material layer 21 a. In this case, the 1 st base material layer 11a may be peeled off₁And the 1 st retardation layer 12a is exposed₁An optical film is laminated on the 2 nd retardation layer 22a exposed by peeling off the 2 nd base material layer 21a via an adhesive layer for optical film₁An adhesive layer for optical layered body is formed thereon. Alternatively, the 1 st base material layer 11a may be peeled₁And the 1 st retardation layer 12a is exposed₁An adhesive layer for an optical layered body is laminated on the substrate, and then a 2 nd retardation layer 22a is exposed by peeling off a 2 nd base material layer 21a₁Upper clip is separated from lightAn optical film is laminated with an adhesive layer for an optical film.

[ 2 nd embodiment ]

(method for producing retardation film)

Fig. 3(a) to (d) are schematic cross-sectional views schematically showing an example of a method for producing the retardation film 50b (liquid crystal film) according to the present embodiment. In the figure, W represents the width direction. The method for producing the retardation film 50b of the present embodiment includes:

a step of preparing a1 st laminated part 10b with an adhesive layer, which includes a1 st base material layer 11b, a1 st retardation layer 12b (1 st liquid crystal layer), and an adhesive layer 13b in this order (fig. 3 (a));

a step of preparing a 2 nd laminated part 20b including a 2 nd base material layer 21b and a 2 nd retardation layer 22b (a 2 nd liquid crystal layer) (fig. 3 (b));

a step of performing surface activation treatment on the surface of the 1 st laminated part 10b with an adhesive layer on the adhesive layer 13b side and the surface of the 2 nd laminated part 20b on the 2 nd retardation layer 22b side; and

and a step of obtaining a retardation layer laminate 40b (liquid crystal layer laminate) by bonding the adhesive layer 13b of the 1 st laminate section 10b with the adhesive layer to the 2 nd retardation layer 22b of the 2 nd laminate section 20b (fig. 3 (c)).

In the 1 st laminated part 10b with an adhesive layer shown in FIG. 3(a), in its cross section in the width direction, the positions of both ends in the width direction of the adhesive layer 13b are located further inward in the width direction than the positions of both ends in the width direction of the 1 st retardation layer 12b,

in the retardation layer laminate 40b shown in fig. 3(c), in the cross section in the width direction thereof, the positions of both ends in the width direction of the adhesive layer 13b are the same as the positions of both ends in the width direction of the 2 nd retardation layer 22 b. The method for producing the retardation film 50b may further include a step of peeling the 2 nd base material layer 21b (1 st peeled layer) (fig. 3 d).

The following description is specifically made based on the drawings. In the manufacturing method shown in fig. 3, first, a1 st laminated part 10b with an adhesive layer including a1 st base material layer 11b, a1 st retardation layer 12b, and an adhesive layer 13b in this order as shown in fig. 3(a), and a 2 nd laminated part 20b including a 2 nd base material layer 21b and a 2 nd retardation layer 22b as shown in fig. 3(b) are prepared. The 1 st laminated portion 10b and the 2 nd laminated portion 20b with adhesive layers are long film-like materials, and the steps described later are performed while the 1 st laminated portion 10b and the 2 nd laminated portion 20b with adhesive layers are continuously conveyed. The width direction W is a direction orthogonal to the longitudinal direction of the film.

The 1 st base material layer 11b, the 1 st retardation layer 12b, and the adhesive layer 13b of the 1 st laminated part 10b with an adhesive layer are the same as the 1 st base material layer 11a, the 1 st retardation layer 12a, and the adhesive layer 13a of the 1 st laminated part 10a with an adhesive layer shown in fig. 1(a), and therefore, the description thereof is omitted.

In the 2 nd laminated part 20b shown in fig. 3(b), in its cross section in the width direction, the positions of both ends in the width direction of the 2 nd base material layer 21b are the same as the positions of both ends in the width direction of the 2 nd retardation layer 22 b.

Then, after the surface activation treatment is performed on the surface of the 1 st laminated part 10b with an adhesive layer on the adhesive layer 13b side and the surface of the 2 nd laminated part 20b on the 2 nd retardation layer 22b side, the adhesive layer 13b of the 1 st laminated part 10b with an adhesive layer is bonded to the 2 nd retardation layer 22b of the 2 nd laminated part 20b, and a retardation layer laminated body 40b shown in fig. 3(c) is obtained. Thereafter, the 2 nd base material layer 21b (1 st release layer) was peeled from the retardation layer laminate 40b, thereby obtaining a retardation film 50b shown in fig. 3 (d).

The surface activation treatment of the surface of the 1 st laminated part 10b with an adhesive layer on the adhesive layer 13b side and the surface of the 2 nd laminated part 20b on the 2 nd retardation layer 22b side can be performed as described in the above embodiments. In the surface activation treatment of the present embodiment, the surface of the 1 st retardation layer 12b of the 1 st stacked part 10b with an adhesive layer on the adhesive layer 13b side, the surface of the adhesive layer 13b (the surface on the opposite side of the 1 st retardation layer 12 b), and the surface of the 2 nd retardation layer 22b (the surface on the opposite side of the 2 nd base material layer 21 b) are preferably treated so that the water contact angles thereof are less than 100 °, more preferably less than 90 °, and still more preferably less than 80 °.

In the cross section in the width direction of the retardation layer laminate 40b, as shown in fig. 3(c), the positions of both ends in the width direction of the adhesive layer 13b are preferably the same as the positions of both ends in the width direction of the 2 nd laminate section 20b (the 2 nd base material layer 21b and the 2 nd retardation layer 22 b). The retardation film 50b shown in fig. 3(d) can be obtained by peeling the 2 nd base material layer 21b from the obtained retardation layer laminate 40 b.

In contrast, in the retardation film 50b obtained by the production method of the present embodiment, the 1 st retardation layer 12b and the 2 nd retardation layer 22b face each other with the adhesive layer 13b interposed therebetween, and there is no region where the 1 st retardation layer 12b and the 2 nd retardation layer 22b do not face each other with the adhesive layer 13b interposed therebetween. Therefore, in the retardation film 50b, since the 1 st retardation layer 12b and the 2 nd retardation layer 22b are not in direct contact, a part of the 1 st retardation layer 12b is transferred to the 2 nd retardation layer 22b, or a part of the 2 nd retardation layer 22b is prevented from being transferred to the 1 st retardation layer 12 b. This makes it possible to suppress the occurrence of breakage at the end of the optical laminate 70b when the optical laminate 70b described later is manufactured using the retardation film 50b, and to suppress contamination of products and conveyance paths during the manufacturing process.

(method for producing optical layered body)

Fig. 4(a) to (c) are schematic cross-sectional views schematically showing an example of the method for producing the optical laminate 70b according to the present embodiment. In the figure, W represents the width direction. The manufacturing method shown in fig. 4(c) includes:

a step of preparing a retardation film 50b (FIG. 4(a))

A step of preparing an optical film 60b (FIG. 4(a)), and

a step of laminating the optical film 60b on the 2 nd retardation layer 22b exposed by peeling the 2 nd base material layer 21b (1 st peeling layer) with the optical film adhesive layer 62b interposed therebetween (fig. 4 (b)).

Optical system of the present embodimentThe method of manufacturing the laminate 70b may further include a step of peeling the 1 st base material layer 11b (the 2 nd peeling layer) (fig. 4(c)), or may be performed on the 1 st retardation layer 12b exposed by peeling the 1 st base material layer 11b₁And an adhesive layer for an optical layered body is laminated on the upper layer.

The following description is specifically made based on the drawings. In the manufacturing method shown in fig. 4, first, as shown in fig. 4(a), a retardation film 50b and an optical film 60b are prepared. The retardation film 50b and the optical film 60b are long film-like materials, and the steps described below are performed while continuously conveying the retardation film 50b and the optical film 60 b.

Then, as shown in fig. 4(b), the optical film 60b is laminated on the 2 nd retardation layer 22b of the retardation film 50b via the optical film adhesive layer 62 b. In this case, the optical film adhesive layer 62b may be provided on the optical film 60b, and the optical film adhesive layer 62b may be bonded to the 2 nd retardation layer 22b of the retardation film 50b, or the optical film adhesive layer 62b may be provided on the 2 nd retardation layer 22b of the retardation film 50b, and the optical film adhesive layer 62b may be bonded to the optical film 60 b.

After the optical film 60b and the retardation film 50b are laminated with the optical film adhesive layer 62b interposed therebetween, the 1 st base material layer 11b (the 2 nd release layer) included in the retardation film 50b is peeled off, whereby an optical laminate 70b shown in fig. 4(c) can be obtained. As shown in fig. 4(c), the optical laminate 70b includes the 1 st retardation layer 12b laminated in this order₁An adhesive layer 13b, a 2 nd retardation layer 22b, an adhesive layer 62b for optical film, and an optical film 60 b. In the optical laminate 70b, the 1 st retardation layer 12b is provided in a cross section in the width direction thereof₁The positions of both ends in the width direction of (b) are the same as those of both ends in the width direction of the adhesive layer 13 b.

When the 1 st base material layer 11b is peeled, a part of the 1 st retardation layer 12b is easily transferred to the peeled 1 st base material layer 11b as shown in fig. 4 (c). This is because, in the laminate shown in fig. 4(b), in the cross section in the width direction thereof, the positions of both ends in the width direction of the 1 st retardation layer 12b are located outside the positions of both ends in the width direction of the adhesive layer 13b, and the 1 st retardation layer 12b has unfixed regions (a diagonal line chart in which the height is lower on the left and higher on the right in fig. 4(b)) which are not fixed to the adhesive layer 13Shown in the section). Therefore, when the 1 st base material layer 11b is peeled from the laminate shown in fig. 4(b), the 1 st retardation layer 12b shown in fig. 4(b) is separated into a region fixed to the adhesive layer 13b (the 1 st retardation layer 12b shown in fig. 4(c))₁) And a non-fixed region (a part indicated by a diagonal line in fig. 4(b) and (c) with a lower left and a higher right) transferred to the 1 st base material layer 11b, the 1 st retardation layer 12b can be obtained in a cross section in the width direction as shown in fig. 4(c)₁And the optical layered body 70b having the same positions at both ends in the width direction as those of the adhesive layer 13.

The optical laminate 70b may be disposed on the 1 st retardation layer 12b exposed by peeling the 1 st base material layer 11b₁An adhesive layer for optical layered body, not shown, is formed thereon. The adhesive layer for an optical layered body can be used when it is bonded to a display panel such as an organic EL display device or a liquid crystal display device.

The optical film 60b may have, in a cross section in the width direction of the optical laminate 70b, positions at both ends in the width direction thereof, the 2 nd retardation layer 22b, the adhesive layer 13b, and the 1 st retardation layer 12b₁The positions of both ends in the width direction of any one of them are the same, and may be different from any one of them. For example, the optical film 60b may have a length in the width direction larger than the 2 nd retardation layer 22b, the adhesive layer 13b, and the 1 st retardation layer 12b as shown in FIG. 4(c)₁May be longer or shorter than either of these layers.

The positions of both ends in the width direction of the optical film adhesive layer 62b are preferably the same as or inward in the width direction of both ends in the width direction of the optical film 60b in the cross section in the width direction of the optical laminate 70 b. The positions of both ends in the width direction of the adhesive layer 62b for optical film are preferably the same as those of the 2 nd retardation layer 22b, the adhesive layer 13b, and the 1 st retardation layer 12b₁The positions of both ends in the width direction of any one of the above-mentioned members are the same or are located further inward in the width direction than the positions. This prevents the optical film adhesive layer 62b from sticking to the transport path and contaminating the transport path by protruding outward in the width direction of the optical laminate 70b when the optical laminate 70b is transported.

Shown in FIG. 3(d)In the retardation film 50b, the 1 st retardation layer 12b is not present₁Directly contacting the 2 nd retardation layer 22b, and thus the 1 st retardation layer 12b₁Is transferred to the 2 nd retardation layer 22b, or a part of the 2 nd retardation layer 22b is transferred to the 1 st retardation layer 12b₁The transfer can be prevented. Therefore, unlike the retardation layer laminate 40p described with reference to fig. 7(a) to (d), the optical laminate 70b shown in fig. 4(c) can be produced without generating the detached portion p in the 1 st retardation layer 12p and without breaking the end portion like the optical laminate 70p and without contaminating the product and the conveyance path during production.

(modification 1 of embodiment 2)

In the manufacturing method of the present embodiment, the positions of both ends in the width direction of the adhesive layer 13b may be located outside the positions of both ends in the width direction of the 2 nd laminated part (the 2 nd base material layer and the 2 nd retardation layer).

(modification 2 of embodiment 2)

In the manufacturing method of the present embodiment, an object having the same structure as the 2 nd laminated part 20a shown in fig. 1(b) described in the previous embodiment can be used.

In this case, the retardation layer laminate may be obtained such that the positions of both ends in the width direction of the adhesive layer are the same as the positions of both ends in the width direction of the 2 nd retardation layer in the cross section in the width direction of the retardation layer laminate, or the retardation layer laminate may be obtained such that the positions of both ends in the width direction of the adhesive layer are located outward with respect to the positions of both ends in the width direction of the 2 nd retardation layer.

In the retardation layer laminate obtained using the 2 nd laminate section in which the positions of both ends in the width direction of the 2 nd base material layer are located outside the positions of both ends in the width direction of the 2 nd retardation layer, when the positions of both ends in the width direction of the adhesive layer are located outside the positions of both ends in the width direction of the 2 nd retardation layer, the 2 nd base material layer and the adhesive layer may be bonded to each other. When the 2 nd base material layer is bonded to the adhesive layer, it tends to be difficult to peel the 2 nd base material layer or to obtain a retardation film. In this case, the 2 nd base material layer can be easily peeled by removing both ends of the retardation layer laminate so that the positions of both ends in the width direction of the adhesive layer are the same as those of both ends in the width direction of the 2 nd base material layer in the cross section in the width direction of the retardation layer laminate. Alternatively, both widthwise ends may be removed from the 2 nd laminated part 20b shown in fig. 1(b) to obtain the 2 nd laminated part 20b shown in fig. 3(b), and the retardation layer laminated body 40b and the retardation film 50b may be obtained by the steps described based on fig. 3(c) and (d) using the 2 nd laminated part 20 b.

(modification 3 of embodiment 2)

In the manufacturing method of the present embodiment, only one of the surfaces may be subjected to the surface activation treatment. In order to facilitate the adhesion of the adhesive layer 13b of the 1 st laminated part 10b with an adhesive layer to the 2 nd retardation layer 22b of the 2 nd laminated part 20b, both the surface of the 1 st laminated part 10b with an adhesive layer on the adhesive layer 13b side and the surface of the 2 nd retardation layer 22b of the 2 nd laminated part 20b are preferably subjected to surface activation treatment.

(modification 4 of embodiment 2)

In this case, the retardation layer laminate may have the aforementioned one end of the adhesive layer at the same position as the end of the 2 nd retardation layer or at a position outside the position in the width direction in the cross section in the width direction.

(modification 5 of embodiment 2)

In the production method of the present embodiment, the 1 st release layer may be a1 st base material layer 11b, and the 2 nd release layer may be a 2 nd base material layer 21 b. In this case, the optical film may be laminated on the 1 st retardation layer exposed by peeling the 1 st base material layer 11b, with the adhesive layer for an optical film interposed therebetween. In the retardation layer laminate 40b shown in fig. 3(c), the positions of both ends in the width direction of the 1 st retardation layer 12b are located outside the positions of both ends in the width direction of the adhesive layer 13b, and the 1 st retardation layer 12b has an unfixed region not fixed to the adhesive layer 13b and a region fixed to the adhesive layer 13 b. Therefore, when the 1 st base material layer 11b is peeled, the 1 st retardation layer 12b is easily separated into a non-fixed region of the 1 st retardation layer 12b and a region fixed to the adhesive layer 13 b. Therefore, when the 1 st release layer is the 1 st base material layer 11b, the optical film may be laminated on the region of the 1 st retardation layer 12b fixed to the adhesive layer 13b with the adhesive layer for the optical film interposed therebetween. When the 1 st release layer includes a1 st base material layer, the adhesive layer for an optical laminate may be formed on the 2 nd retardation layer 22b exposed by peeling the 2 nd base material layer 21 b.

Alternatively, an optical film may be laminated on the 1 st retardation layer exposed by peeling the 1 st base material layer 11b, and then an optical film may be laminated on the 2 nd retardation layer exposed by peeling the 2 nd base material layer 21b with the adhesive layer for an optical film interposed therebetween.

[ embodiment 3 ]

(method for producing retardation film)

Fig. 5(a) to (e) are schematic cross-sectional views schematically showing an example of a method for producing the retardation film 50c (liquid crystal film) according to the present embodiment. In the figure, W represents the width direction. The method for producing the retardation film 50c of the present embodiment includes, for example:

a step of preparing a1 st laminated part 10c with an adhesive layer, which includes a1 st base material layer 11c, a1 st retardation layer 12c (1 st liquid crystal layer), and an adhesive layer 13c in this order (fig. 5 (a));

a step of preparing a 2 nd laminated part 20c including a 2 nd base material layer 21c and a 2 nd retardation layer 22c (a 2 nd liquid crystal layer) (fig. 5 (b));

a step of performing surface activation treatment on the surface of the 1 st laminated part 10c with an adhesive layer on the adhesive layer 13c side and the surface of the 2 nd laminated part 20c on the 2 nd retardation layer 22c side;

a step of obtaining a retardation layer laminate 40c (liquid crystal layer laminate) by bonding the adhesive layer 13c of the 1 st laminate section 10c with the adhesive layer to the 2 nd retardation layer 22c of the 2 nd laminate section 20c (fig. 5 (c)); and

and a step of removing both widthwise ends (2 nd end 44c) of the retardation layer laminate 40c (fig. 5 d).

In the 1 st laminated part 10c with an adhesive layer shown in FIG. 5(a), in its cross section in the width direction, the positions of both ends in the width direction of the adhesive layer 13c are located further inward in the width direction than the positions of both ends in the width direction of the 1 st retardation layer 12c,

in the retardation layer laminate 40c shown in FIG. 5(c), in the cross section in the width direction thereof, the positions of both ends in the width direction of the adhesive layer 13c are located more inward in the width direction than the positions of the ends in the width direction of the 2 nd retardation layer 22c,

in the step of removing the 2 nd end portion 44c shown in fig. 5(c), the 2 nd end portion 44c is removed in such a manner that the retardation layer laminate 40c after the 2 nd end portion 44c is removed₁(the liquid crystal layer laminate after removal of the 2 nd end portion) in the cross section in the width direction, the adhesive layer 13c₁And the 1 st retardation layer 12c at both ends in the width direction₁Are the same in position at both ends in the width direction of the retardation film, and are different from the 2 nd retardation layer 22c₁The positions of both ends in the width direction of (b) are the same (fig. 5 (d)). The method for producing the retardation film 50c may further comprise peeling off the 2 nd base material layer 21c₁(first release layer) (FIG. 5 (e)).

The following description is specifically made based on the drawings. In the manufacturing method shown in fig. 5, first, a1 st laminated part 10c with an adhesive layer including a1 st base material layer 11c, a1 st retardation layer 12c, and an adhesive layer 13c in this order as shown in fig. 5(a), and a 2 nd laminated part 20c including a 2 nd base material layer 21c and a 2 nd retardation layer 22c as shown in fig. 5(b) are prepared. The 1 st laminated portion 10c and the 2 nd laminated portion 20c with adhesive layers are long film-like materials, and the steps described later are performed while the 1 st laminated portion 10c and the 2 nd laminated portion 20c with adhesive layers are continuously conveyed. The width direction W is a direction orthogonal to the longitudinal direction of the film.

The 1 st base material layer 11c, the 1 st retardation layer 12c, and the adhesive layer 13c of the 1 st laminated part with adhesive layer 10c are the same as the 1 st base material layer 11a, the 1 st retardation layer 12a, and the adhesive layer 13a of the 1 st laminated part with adhesive layer 10a shown in fig. 1(a) described in the previous embodiment, and therefore, the description thereof is omitted. The 2 nd base material layer 21c and the 2 nd retardation layer 22c of the 2 nd stacked part 20c are the same as the 2 nd base material layer 21a and the 2 nd retardation layer 22a of the 2 nd stacked part 20a shown in fig. 1(b) described in the previous embodiment, and therefore, the description thereof is omitted.

Then, after the surface activation treatment is performed on the surface of the 1 st laminated part 10c with an adhesive layer on the adhesive layer 13c side and the surface of the 2 nd laminated part 20c on the 2 nd retardation layer 22c side, the adhesive layer 13c of the 1 st laminated part 10c with an adhesive layer is bonded to the 2 nd retardation layer 22c of the 2 nd laminated part 20c, and a retardation layer laminated body 40c shown in fig. 5(c) is obtained. In the resulting retardation layer laminate 40c, as shown in fig. 5(c), in the cross section in the width direction, the positions of both ends in the width direction of the adhesive layer 13c are located inward of the positions of the ends in the width direction of the 2 nd retardation layer 22 c.

The surface activation treatment of the surface of the 1 st stacked part 10c with an adhesive layer on the adhesive layer 13c side and the surface of the 2 nd stacked part 20c on the 2 nd retardation layer 22c side may be performed as described in the above embodiment, and the magnitude of the water contact angle of each surface after the surface activation treatment is also described in the above embodiment.

Next, both ends in the width direction of the retardation layer laminated body 40c shown in fig. 5(c) are cut by a broken line Xc, and the 2 nd end portion 44c on the outer side in the width direction with respect to the broken line Xc is removed. As a result, as shown in FIG. 5(d), the substrate layer 11c having the 1 st base material layer 11c in this order is obtained₁And the 1 st retardation layer 12c₁And an adhesive layer 13c₁And 2 nd retardation layer 22c₁And 2 nd base material layer 21c₁The retardation layer laminate 40c from which the 2 nd end 44c is removed₁(hereinafter, it may be referred to as "retardation layer laminate 40c₁". ). Thereafter, the retardation layer laminate 40c₁Peeling off the 2 nd base material layer 21c₁(1 st release layer) to obtain a retardation film 50c shown in FIG. 5 (e).

The position of the broken line Xc in fig. 5(c) is determined in such a manner that the retardation layer laminate 40c after the removal of the 2 nd end portion 44c₁In the cross section in the width direction of (2), the adhesive layer 13c₁And the 1 st retardation layer 12c at both ends in the width direction₁Are the same in position at both ends in the width direction of the retardation film, and are different from the 2 nd retardation layer 22c₁In the same manner as the positions of both ends in the width direction. In the retardation layer laminate 40c shown in fig. 5(c), the position of the broken line Xc is usually determined so that the 2 nd end 44c includes the ends of the 1 st base material layer 11c, the 1 st retardation layer 12c, the 2 nd retardation layer 22c, and the 2 nd base material layer 21c, and is preferably determined so that the 1 st base material layer 11c, the 1 st retardation layer 12c, the adhesive layer 13c, the 2 nd retardation layer 22c, and the 2 nd base material layer 21c are included. The layers included in the 2 nd end portions 44c removed from both ends in the width direction of the retardation layer laminated body 40c may be the same as each other or different from each other.

A retardation layer laminate 40c obtained by removing the 2 nd end 44c₁In the cross section in the width direction, as shown in FIG. 5(d), the adhesive layer 13c₁And the 1 st base material layer 11c and the positions of both ends in the width direction of₁And the 1 st retardation layer 12c₁And 2 nd retardation layer 22c₁And the 2 nd base material layer 21c₁The positions of both ends in the width direction of (2) are the same.

The position of the broken line Xc defining the region of the 2 nd end 44c is a region of usually 0.5cm or more, may be a region of 1.0cm or more, may be a region of 1.5cm or more, and is usually a region of 20cm or less, preferably a region of 15cm or less, and more preferably a region of 10cm or less, on the inner side in the width direction with respect to the end located on the outermost side in the width direction of the retardation layer laminated body 40 c. The distance from the end of the retardation layer laminated body 40c located on the outermost side in the width direction to the position of the broken line Xc may be the same at both ends of the retardation layer laminated body 40c in the width direction, or may be different from each other.

The retardation film 50c can be formed by laminating the retardation layer 40c₁Peeling off the 2 nd base material layer 21c₁(the 1 st release layer). As shown in FIG. 5(e), the retardation film 50c has a1 st base material layer 11c₁1 st phasePotential difference layer 12c₁And an adhesive layer 13c₁And 2 nd retardation layer 22c₁. In the retardation film 50c, the adhesive layer 13c is formed on the cross section in the width direction₁And the 1 st base material layer 11c and the positions of both ends in the width direction of₁And the 1 st retardation layer 12c₁And 2 nd retardation layer 22c₁The positions of both ends in the width direction of (2) are the same.

In the retardation layer laminate 40c shown in fig. 5(c), in the cross section in the width direction thereof, the positions of both ends in the width direction of the adhesive layer 13c are located inward of the positions of both ends in the width direction of the 1 st retardation layer 12c and the positions of both ends in the width direction of the 2 nd retardation layer 22 c. Therefore, similarly to the retardation layer laminate 40p shown in fig. 7(a), when the 1 st retardation layer 12c and the 2 nd retardation layer 22c are in direct contact with each other, a phenomenon tends to occur in which a part of the 1 st retardation layer 12c is transferred to the 2 nd retardation layer 22c or a part of the 2 nd retardation layer 22c is transferred to the 1 st retardation layer 12 c.

Therefore, in the present embodiment, both ends (2 nd end 44c) in the width direction of the retardation layer laminated body 40c are removed (fig. 5(d)), and the retardation layer laminated body 40c after the 2 nd end 44c is removed₁In the cross section in the width direction of (2), the adhesive layer 13c₁And the 1 st retardation layer 12c at both ends in the width direction₁Are the same in position at both ends in the width direction of the retardation film, and are different from the 2 nd retardation layer 22c₁The positions of both ends in the width direction of (2) are the same. Therefore, even if a phenomenon occurs in which a portion of the 1 st retardation layer 12c migrates to the 2 nd retardation layer 22c or a portion of the 2 nd retardation layer 22c migrates to the 1 st retardation layer 12c at both ends in the width direction of the retardation layer laminate 40c shown in fig. 5(c), a portion in which such a phenomenon occurs can be removed as the 2 nd end portion 44 c. Thereby, the 2 nd end 44c of the retardation layer laminate 40c can be removed₁Since the retardation film 50c is produced, when an optical laminate is produced using the retardation film 50c, the occurrence of breakage at the end of the optical laminate can be suppressed, and contamination of the product and the conveyance path during production can be suppressed.

(method for producing optical layered body)

The method for manufacturing an optical laminate of the present embodiment includes:

a step of preparing a retardation film 50c,

Step of preparing optical film, and

laminating the optical film on the 2 nd base material layer 21c by peeling through the adhesive layer for optical film₁(1 st release layer) exposed 2 nd retardation layer 22c₁The process (2).

The method for producing the optical laminate of the present embodiment may further comprise peeling the 1 st base material layer 11c₁(2 nd peeling layer) for peeling the 1 st base material layer 11c₁And the 1 st retardation layer 12c is exposed₁And an adhesive layer for an optical layered body is laminated on the upper layer.

The method for producing the optical laminate of the present embodiment is the same as the production method described with reference to fig. 2(a) to (c) except for using the retardation film 50c, and therefore, detailed description thereof is omitted.

In the retardation film 50c shown in fig. 5(e), in the retardation layer laminate 40c, a portion where the 1 st retardation layer 12c and the 2 nd retardation layer 22c are in direct contact and a peeled portion p or a transferred portion from the peeled portion may occur is removed as the 2 nd end portion 44 c. Therefore, it is possible to suppress the occurrence of end breakage and the contamination of the product and the conveyance path during the production, as in the optical laminate 70p described with reference to fig. 7(a) to (d), and to appropriately produce an optical laminate.

(modification 1 of embodiment 3)

In the manufacturing method of the present embodiment, one 2 nd end 44c in the width direction of the retardation layer laminated body 40c may be removed. In this case, the end of the optical layered body can be prevented from being broken on the side from which the 2 nd end 44c is removed, and contamination of the product and the conveyance path during the production can be prevented.

(modification 2 of embodiment 3)

The present embodimentIn the manufacturing method of (3), the 2 nd end portion 44c may be removed by removing the adhesive layer 13c₁And the 1 st retardation layer 12c at both ends in the width direction₁So as to be at the same position as both ends in the width direction of (2) or with the phase difference layer 22c₁In the same manner as the positions of both ends in the width direction. This operation can also suppress the occurrence of breakage at the end of the optical layered body and prevent contamination of the product and the conveyance path during production.

(modification 3 of embodiment 3)

In the manufacturing method of the present embodiment, only one of the surfaces may be subjected to the surface activation treatment. In order to facilitate the adhesion of the adhesive layer 13c of the 1 st laminated part 10c with an adhesive layer to the 2 nd retardation layer 22c of the 2 nd laminated part 20c, both the surface of the 1 st laminated part 10c with an adhesive layer on the adhesive layer 13c side and the surface of the 2 nd retardation layer 22c of the 2 nd laminated part 20c are preferably subjected to surface activation treatment.

(modification 4 of embodiment 3)

In this case, in the retardation layer laminate, the 2 nd end portion on the one end portion side of the adhesive layer of the 1 st laminate portion with the adhesive layer may be removed.

(modification 5 of embodiment 3)

In the production method of the present embodiment, the 1 st release layer may be a1 st base material layer 11c₁The 2 nd stripping layer is a 2 nd base material layer 21c₁. In this case, the 1 st base material layer 11c may be peeled off₁And the 1 st retardation layer 12c is exposed₁Laminating an optical film on the base layer via an adhesive layer for optical film, and peeling off the 2 nd base layer 21c₁And the exposed 2 nd retardation layer 22c₁An adhesive layer for optical layered body is formed thereon. Alternatively, the 1 st base material layer 11c may be peeled off₁And the 1 st retardation layer 12c is exposed₁On which an adhesive layer for optical laminate is laminated first, and then the 2 nd base material layer 21c is peeled off and exposed2 nd retardation layer 22c₁An optical film is laminated on the substrate with an adhesive layer for an optical film interposed therebetween.

[ 4 th embodiment ]

(method for producing retardation film)

Fig. 6(a) to (e) are schematic cross-sectional views schematically showing an example of the method for producing the retardation film 50d according to the present embodiment. In the figure, W represents the width direction. The method for producing the retardation film 50d (liquid crystal film) of the present embodiment includes, for example:

a step of preparing a1 st laminated part 10d with an adhesive layer, which includes a1 st base material layer 11d, a1 st retardation layer 12d (1 st liquid crystal layer), and an adhesive layer 13d in this order (fig. 6 (a));

a step of preparing a 2 nd laminated part 20d including a 2 nd base material layer 21d and a 2 nd retardation layer 22d (a 2 nd liquid crystal layer) (fig. 6 (b));

a step of performing surface activation treatment on the surface of the 1 st laminated part 10d with an adhesive layer on the adhesive layer 13d side and the surface of the 2 nd laminated part 20d on the 2 nd retardation layer 22d side;

a step of obtaining a1 st retardation layer laminate 40d (1 st liquid crystal layer laminate) by bonding the adhesive layer 13d of the 1 st laminate section 10d with the adhesive layer to the 2 nd retardation layer 22d of the 2 nd laminate section 20d (fig. 6 (c));

a step of obtaining a 2 nd retardation layer laminate 30d (2 nd liquid crystal layer laminate) by peeling the 2 nd base material layer 21d (1 st peeling layer) of the 1 st retardation layer laminate 40d (fig. 6 (d)); and

and a step of removing both widthwise ends (3 rd end portions 34d) of the 2 nd retardation layer laminated body 30 d.

In the 1 st laminated part 10d with an adhesive layer shown in FIG. 6(a), in its cross section in the width direction, the positions of both ends in the width direction of the adhesive layer 13d are located further inward in the width direction than the positions of both ends in the width direction of the 1 st retardation layer 12d,

in the 1 st retardation layer laminate 40d shown in FIG. 6(c), in the cross section in the width direction thereof, the positions of both ends in the width direction of the adhesive layer 13d are located further inward in the width direction than the positions of both ends in the width direction of the 2 nd retardation layer 22d,

division shown in FIG. 6(d)The step of removing the 3 rd end portion 34d removes the 3 rd end portion 34d in such a manner that the 2 nd retardation layer laminated body 30d after the 3 rd end portion 34d is removed₂(the 2 nd liquid crystal layer laminate after removing the 3 rd end portion) in the cross section in the width direction, the adhesive layer 13d was formed₂And the 1 st phase difference layer 12d at both ends in the width direction₂Are the same in position at both ends in the width direction of the retardation film, and are different from the 2 nd retardation layer 22d₂The positions of both ends in the width direction of (b) are the same (fig. 6 (e)).

The following description is specifically made based on the drawings. In the manufacturing method shown in fig. 6, first, a1 st laminated part 10d with an adhesive layer including a1 st base material layer 11d, a1 st retardation layer 12d, and an adhesive layer 13d in this order as shown in fig. 6(a), and a 2 nd laminated part 20d including a 2 nd base material layer 21d and a 2 nd retardation layer 22d as shown in fig. 6(b) are prepared. The 1 st laminated portion 10d and the 2 nd laminated portion 20d with adhesive layers are long film-like materials, and the steps described later are performed while the 1 st laminated portion 10d and the 2 nd laminated portion 20d with adhesive layers are continuously conveyed. The width direction W is a direction orthogonal to the longitudinal direction of the film.

The 1 st base material layer 11d, the 1 st retardation layer 12d, and the adhesive layer 13d of the 1 st laminated part with adhesive layer 10d are the same as the 1 st base material layer 11a, the 1 st retardation layer 12a, and the adhesive layer 13a of the 1 st laminated part with adhesive layer 10a shown in fig. 1(a), and therefore, the description thereof is omitted.

The 2 nd base material layer 21d and the 2 nd retardation layer 22d included in the 2 nd stacked part 20d are the same as the 2 nd base material layer 21a and the 2 nd retardation layer 22a included in the 2 nd stacked part 20a shown in fig. 1(b), and therefore, the description thereof is omitted.

Then, after the surface activation treatment is performed on the surface of the 1 st laminated part 10d with an adhesive layer on the adhesive layer 13d side and the surface of the 2 nd laminated part 20d on the 2 nd retardation layer 22d side, the adhesive layer 13d of the 1 st laminated part 10d with an adhesive layer is bonded to the 2 nd retardation layer 22d of the 2 nd laminated part 20d, and a1 st retardation layer laminated body 40d shown in fig. 6(c) is obtained. In the 1 st retardation layer laminated body 40d, as shown in fig. 6(c), in the cross section in the width direction, the positions of both ends in the width direction of the adhesive layer 13c are located more inward than the positions of the ends in the width direction of the 2 nd retardation layer 22 c.

The surface activation treatment of the surface of the 1 st stacked part 10d with an adhesive layer on the adhesive layer 13d side and the surface of the 2 nd stacked part 20d on the 2 nd retardation layer 22d side can be performed as described in the foregoing embodiment, and the magnitude of the water contact angle of each surface after the surface activation treatment is also described in the foregoing embodiment, and therefore, the description thereof is omitted.

Next, the 2 nd base material layer 21d (1 st release layer) is peeled from the 1 st retardation layer laminate 40d shown in fig. 6(c), and a 2 nd retardation layer laminate 30d is obtained (fig. 6 (d)). When the 2 nd base material layer 21d is peeled from the 1 st retardation layer laminate 40d, a part of the 2 nd retardation layer 22d is transferred to the peeled 2 nd base material layer 21d as shown in fig. 6 (d). This is because, in the 1 st retardation layer laminated body 40d shown in fig. 6(c), in the cross section in the width direction thereof, the positions of both ends in the width direction of the 2 nd retardation layer 22d are located outside the positions of both ends in the width direction of the adhesive layer 13d, and the 2 nd retardation layer 22d has an unfixed area (a portion indicated by a diagonal line lower in the left and higher in the right in fig. 6(c)) which is not fixed to the adhesive layer 13 d. Therefore, when the 2 nd base material layer 21d is peeled from the 1 st retardation layer laminate 40d, the 2 nd retardation layer 22d shown in fig. 6(c) is separated into a region fixed to the adhesive layer 13d (the 2 nd retardation layer 22d shown in fig. 6(d))₁) And a non-fixed region (a part indicated by a diagonal line in fig. 6(c) and (d) with a lower left and a higher right) transferred to the 2 nd base material layer 21d, the 2 nd retardation layer 22d can be obtained in a cross section in the width direction as shown in fig. 6(d)₁And 2 nd retardation layer laminated bodies 30d having the same positions at both ends in the width direction as those of the adhesive layers 13 d.

Then, both ends in the width direction of the 2 nd retardation layer laminated body 30d shown in fig. 6(d) are cut by a broken line Xd, and the 3 rd end portion 34d on the outer side in the width direction with respect to the broken line Xd is removed. As a result, as shown in FIG. 6(e), the substrate layer 11d having the 1 st base material layer 11d in this order is obtained₂1 st retardation layer 12d₂And an adhesive layer 13d₂And the 2 nd retardation layer 22d₂After removing the 3 rd end 34d, the 2 nd phase differenceLaminate 30d₂(hereinafter, it may be referred to as "retardation layer laminate 30d₂". ) The retardation film 50d can be produced.

The position of the broken line Xd in fig. 6(d) is determined in such a manner that the 2 nd retardation layer stack 30d after the 3 rd end portion 34d is removed₂In the cross section in the width direction of (2), the adhesive layer 13d₂And the 1 st phase difference layer 12d at both ends in the width direction₂Are the same in position at both ends in the width direction of the retardation film, and are different from the 2 nd retardation layer 22d₂In the same manner as the positions of both ends in the width direction. In the 2 nd retardation layer laminate 30d shown in fig. 6(d), the position of the broken line Xd is usually determined so that the 3 rd end 34d includes the ends of the 1 st base material layer 11d, the 1 st retardation layer 12d, and the 2 nd retardation layer 22d, and is preferably determined so that the end of the 1 st base material layer 11d, the 1 st retardation layer 12d, the adhesive layer 13d, and the 2 nd retardation layer 22d is included. The layers included in the 3 rd end portions 34d removed from both ends in the width direction of the 2 nd retardation layer laminated body 30d may be the same as each other or different from each other.

A 2 nd retardation layer laminate 30d obtained by removing the 3 rd end 34d₂In the cross section in the width direction, as shown in FIG. 6(e), the adhesive layer 13d₂And the 1 st base material layer 11d and the positions of both ends in the width direction of₂1 st retardation layer 12d₂And 2 nd retardation layer 22d₂The positions of both ends in the width direction of (2) are the same.

The position of the broken line Xd defining the region of the 3 rd end 34d is a region of generally 0.5cm or more, may be a region of 1.0cm or more, may be a region of 1.5cm or more, and is generally a region of 20cm or less, preferably a region of 15cm or less, and more preferably a region of 10cm or less, inward in the width direction with respect to the end of the 2 nd retardation layer laminated body 30d located at the outermost side in the width direction. The distance from the end of the 2 nd retardation layer laminated body 30d located on the outermost side in the width direction to the position of the broken line Xd may be the same at both ends of the 2 nd retardation layer laminated body 30d in the width direction, or may be different from each other.

In the 1 st retardation layer laminate 40d shown in fig. 6(c), in the cross section in the width direction thereof, the positions of both ends in the width direction of the adhesive layer 13d are located inward of the positions of both ends in the width direction of the 1 st retardation layer 12d and the positions of both ends in the width direction of the 2 nd retardation layer 22 d. Therefore, similarly to the retardation layer laminate 40p shown in fig. 7(a), when the 1 st retardation layer 12d and the 2 nd retardation layer 22d are in direct contact with each other, a phenomenon tends to occur in which a part of the 1 st retardation layer 12d is transferred to the 2 nd retardation layer 22d or a part of the 2 nd retardation layer 22d is transferred to the 1 st retardation layer 12 d.

Therefore, in the present embodiment, both widthwise ends (3 rd end portions 34d) of the 2 nd retardation layer laminate 30d (fig. 6(d)) obtained by peeling the 2 nd base material layer 21d from the 1 st retardation layer laminate 40d are removed. The 2 nd retardation layer laminate 30d after removing the 3 rd end 34d₂In a cross section in the width direction thereof, an adhesive layer 13d₂And the 1 st phase difference layer 12d at both ends in the width direction₂Are the same in position at both ends in the width direction of the retardation film, and are different from the 2 nd retardation layer 22d₂The positions of both ends in the width direction of (2) are the same. Thus, even when a phenomenon occurs in which a part of the 1 st retardation layer 12d migrates to the 2 nd retardation layer 22d or a part of the 2 nd retardation layer 22d migrates to the 1 st retardation layer 12d at both ends in the width direction of the 1 st retardation layer laminated body 40d, the 2 nd retardation layer laminated body 30d can be obtained by removing the part in which such a phenomenon occurs as the 3 rd end portion 34d₂. When an optical laminate is produced using the retardation film 50d, the occurrence of breakage at the end of the optical laminate can be suppressed, and contamination of the product and the conveyance path during production can be suppressed.

(method for producing optical layered body)

The method for manufacturing an optical laminate of the present embodiment includes:

a step of preparing a retardation film 50d,

Step of preparing optical film, and

an optical film is laminated on the 2 nd retardation layer 22d exposed by peeling the 2 nd base material layer 21d (1 st peeling layer) and having the 3 rd end 34d removed, with the optical film interposed therebetween₂The process (2).

Light of the present embodimentThe method for producing the chemical laminate may further comprise peeling the 1 st base material layer 11d₂(2 nd release layer) for peeling the 1 st base material layer 11d₂And the 1 st retardation layer 12d is exposed₂And an adhesive layer for an optical layered body is laminated on the upper layer.

The method for producing the optical laminate of the present embodiment is the same as the production method described with reference to fig. 2(a) to (c) except for using the retardation film 50d, and therefore, detailed description thereof is omitted.

In the retardation film 50d shown in fig. 6(e), in the 1 st retardation layer laminate 40d, a portion where the 1 st retardation layer 12d and the 2 nd retardation layer 22d are in direct contact with each other and a peeled-off portion p or a transferred portion from the peeled-off portion may occur is removed as the 3 rd end portion 34 d. Therefore, it is possible to suppress the occurrence of end breakage and the contamination of the product and the conveyance path during the production, as in the optical laminate 70p described with reference to fig. 7(a) to (d), and to appropriately produce an optical laminate.

(modification 1 of embodiment 4)

In the manufacturing method of the present embodiment, one 3 rd end portion 34d in the width direction of the 2 nd retardation layer laminated body 30d may be removed. In this case, the 3 rd end 34d is removed, so that the end of the optical layered body is prevented from being broken, and the product and the conveyance path during the production can be prevented from being contaminated.

(modification 2 of embodiment 4)

In the manufacturing method of the present embodiment, the 3 rd end portion 34d may be removed by removing the adhesive layer 13d₂And the 1 st phase difference layer 12d at both ends in the width direction₂Are the same in position at both ends in the width direction of (2) or are the same in position as the phase difference layer 22d₂In the same manner as the positions of both ends in the width direction. This operation can also suppress the occurrence of breakage at the end of the optical layered body and prevent contamination of the product and the conveyance path during production.

(modification 3 of embodiment 4)

In the manufacturing method of the present embodiment, only one of the surfaces may be subjected to the surface activation treatment. In order to facilitate the adhesion of the adhesive layer 13d of the 1 st laminated part 10d with an adhesive layer to the 2 nd retardation layer 22d of the 2 nd laminated part 20d, both the surface of the 1 st laminated part 10d with an adhesive layer on the adhesive layer 13d side and the surface of the 2 nd retardation layer 22d of the 2 nd laminated part 20d are preferably subjected to surface activation treatment.

(modification 4 of embodiment 4)

In the production method of the present embodiment, the 1 st release layer may be a1 st base material layer, and the 2 nd release layer may be a 2 nd base material layer. In this case, both widthwise ends (3 rd end portions) of the 2 nd retardation layer laminate obtained by peeling the 1 st base material layer are removed, and in the 2 nd retardation layer laminate after the 3 rd end portions are removed, the positions of both widthwise ends of the adhesive layer are made the same as the positions of both widthwise ends of the 1 st retardation layer and the positions of both widthwise ends of the 2 nd retardation layer. Thereafter, an optical film may be laminated on the 1 st retardation layer of the 2 nd retardation layer laminate after the 3 rd end portion is removed, with an adhesive layer for an optical film interposed therebetween.

Alternatively, an optical film may be laminated on the 1 st retardation layer exposed by peeling the 1 st base material layer 11d, and then an optical film may be laminated on the 2 nd retardation layer exposed by peeling the 2 nd base material layer 21d with the adhesive layer for an optical film interposed therebetween.

While the embodiments and the modifications of the present invention have been described above, the present invention is not limited to these embodiments and modifications, and for example, the configurations and steps of the embodiments and the modifications may be combined and implemented. Hereinafter, the respective matters common to all the embodiments and the modifications thereof will be described in detail.

(No. 1 substrate layer and No. 2 substrate layer)

The 1 st base material layer and the 2 nd base material layer function as support layers for supporting a1 st alignment layer and a 2 nd alignment layer, which will be described later, and a1 st liquid crystal layer and a 2 nd liquid crystal layer, which are formed on these base material layers.

The 1 st base material layer and the 2 nd base material layer are preferably films formed of a resin material.

As the resin material, for example, a resin material excellent in transparency, mechanical strength, thermal stability, stretchability, and the like is used. Specific examples thereof include polyolefin resins such as polyethylene and polypropylene; cyclic polyolefin resins such as norbornene polymers; polyester resins such as polyethylene terephthalate and polyethylene naphthalate; (meth) acrylic resins such as (meth) acrylic acid and polymethyl (meth) acrylate; cellulose ester resins such as triacetyl cellulose, diacetyl cellulose, and cellulose acetate propionate; vinyl alcohol resins such as polyvinyl alcohol and polyvinyl acetate; a polycarbonate-based resin; a polystyrene-based resin; a polyarylate-based resin; a polysulfone-based resin; a polyether sulfone-based resin; a polyamide resin; a polyimide-based resin; a polyether ketone resin; polyphenylene sulfide-based resin; polyphenylene ether resins, and mixtures and copolymers thereof. Among these resins, any of cyclic polyolefin resins, polyester resins, cellulose ester resins, and (meth) acrylic resins, or mixtures thereof are preferably used. The "(meth) acrylic acid" means "at least 1 kind of acrylic acid and methacrylic acid".

The 1 st base material layer and the 2 nd base material layer may be single layers of 1 kind of resin or a mixture of 2 or more kinds of resins, or may have a multilayer structure of 2 or more layers. In the case of having a multilayer structure, the resins forming the respective layers may be the same as or different from each other.

An arbitrary additive may be added to the resin material forming the film formed of the resin material. Examples of the additives include ultraviolet absorbers, antioxidants, lubricants, plasticizers, mold release agents, coloring inhibitors, flame retardants, nucleating agents, antistatic agents, pigments, and colorants.

The thickness of the 1 st base material layer and the 2 nd base material layer is not particularly limited, but is preferably 1 to 500 μm, more preferably 1 to 300 μm, and further preferably 5 to 200 μm in view of strength, handling properties, and the like.

In the case where the 1 st laminated part with an adhesive layer has a1 st alignment layer described later, or the 2 nd laminated part has a 2 nd alignment layer described later, in order to improve the adhesion between the 1 st base material layer and the 1 st alignment layer and the adhesion between the 2 nd base material layer and the 2 nd alignment layer, corona treatment, plasma treatment, flame treatment, or the like may be performed on at least the surface of the 1 st base material layer on the side where the 1 st alignment layer is formed and at least the surface of the 2 nd base material layer on the side where the 2 nd alignment layer is formed, and a primer layer or the like may be formed. The adhesion can be adjusted by adjusting the components of the composition for forming the alignment layer used to form the 1 st alignment layer and the 2 nd alignment layer and the components of the composition for forming the liquid crystal layer used to form the 1 st liquid crystal layer and the 2 nd liquid crystal layer.

(1 st alignment layer and 2 nd alignment layer)

The 1 st laminated part with an adhesive layer may include a1 st alignment layer between the 1 st base material layer and the 1 st liquid crystal layer. In addition, the 2 nd laminated part may include a 2 nd alignment layer between the 2 nd base material layer and the 2 nd liquid crystal layer.

The 1 st alignment layer and the 2 nd alignment layer have alignment regulating forces for aligning liquid crystal compounds contained in the 1 st liquid crystal layer and the 2 nd liquid crystal layer formed on the alignment layers in a desired direction. Examples of the 1 st alignment layer and the 2 nd alignment layer include an alignment polymer layer formed of an alignment polymer, a photo-alignment polymer layer formed of a photo-alignment polymer, and a groove alignment layer having a concave-convex pattern or a plurality of grooves (grooves) on a surface thereof, and the 1 st alignment layer and the 2 nd alignment layer may be the same kind of layer or different kinds of layers. The thickness of the 1 st alignment layer and the 2 nd alignment layer is usually 10 to 500nm, preferably 10 to 200 nm.

The alignment polymer layer can be formed by applying a composition in which an alignment polymer is dissolved in a solvent to a base material layer (1 st base material layer or 2 nd base material layer), removing the solvent, and performing a rubbing treatment as necessary. In this case, the orientation regulating force of the oriented polymer layer formed of the oriented polymer can be arbitrarily adjusted by utilizing the surface state and the friction condition of the oriented polymer.

The photo-alignment polymer layer may be formed by applying a composition including a polymer or monomer having a photoreactive group and a solvent to a substrate layer (a 1 st substrate layer or a 2 nd substrate layer) and irradiating polarized light. In this case, the photo-alignment polymer layer can be arbitrarily adjusted in alignment regulating force by using the polarized light irradiation condition of the photo-alignment polymer.

The groove alignment layer can be formed, for example, by a method of forming a concave-convex pattern by exposing and developing a surface of a photosensitive polyimide film through an exposure mask having a slit with a pattern shape; a method of forming an uncured layer of an active energy ray-curable resin on a plate-like master having grooves on the surface thereof, transferring the layer to a base material layer (1 st base material layer or 2 nd base material layer), and curing the layer; a method in which an uncured layer of an active energy ray-curable resin is formed on a base material layer (1 st base material layer or 2 nd base material layer), and a roll-shaped master having irregularities is pressed against the layer or the like to form irregularities and cure the irregularities.

The 1 st and 2 nd release layers described above may include a1 st alignment layer and a 2 nd alignment layer. That is, in the case where the 1 st release layer includes the 2 nd base material layer, the 1 st release layer may include the 2 nd alignment layer. Similarly, when the 2 nd release layer includes the 1 st base material layer, the 2 nd release layer may include the 1 st alignment layer. The same applies to the case where the 1 st release layer includes the 1 st base material layer and the case where the 2 nd release layer includes the 2 nd base material layer. In addition, in the case where the 1 st release layer does not include the 1 st alignment layer or the 2 nd alignment layer, the 1 st alignment layer or the 2 nd alignment layer may be left on the 1 st liquid crystal layer or the 2 nd liquid crystal layer, respectively, after the 1 st release layer is released. Similarly, in the case where the 2 nd release layer does not include the 1 st alignment layer or the 2 nd alignment layer, the 1 st alignment layer or the 2 nd alignment layer may be left on the 1 st liquid crystal layer or the 2 nd liquid crystal layer, respectively, after the 2 nd release layer is released. The layers included in the 1 st release layer and the 2 nd release layer can be set by adjusting the relationship between the adhesion forces between the layers, and can be adjusted by, for example, the above-described corona treatment, plasma treatment, flame treatment, primer layer, composition for forming an alignment layer, composition for forming a liquid crystal layer, or the like performed on the 1 st base layer and the 2 nd base layer.

When the 1 st alignment layer remains on the 1 st liquid crystal layer, the adhesive layer for an optical layered body may be provided on the 1 st alignment layer. In the case where the 2 nd alignment layer remains on the 2 nd liquid crystal layer, the adhesive layer for an optical film may be provided on the 2 nd alignment layer.

(No. 1 liquid crystal layer and No. 2 liquid crystal layer)

The 1 st liquid crystal layer and the 2 nd liquid crystal layer may be formed using a known liquid crystal compound. The type of the liquid crystal compound is not particularly limited, and a rod-like liquid crystal compound, a discotic liquid crystal compound, and a mixture thereof can be used. The liquid crystal compound may be a polymeric liquid crystal compound, a polymerizable liquid crystal compound, or a mixture thereof. For example, when a polymerizable liquid crystal compound is used, the 1 st liquid crystal layer and the 2 nd liquid crystal layer can be formed as liquid crystal cured layers by applying a composition containing a polymerizable liquid crystal compound onto an alignment layer (the 1 st alignment layer or the 2 nd alignment layer) to form a coating film and curing the coating film. Alternatively, a liquid crystal layer (1 st liquid crystal layer or 2 nd liquid crystal layer) may be formed by applying a liquid crystal compound on a base material layer (1 st base material layer or 2 nd base material layer) to form a coating film and stretching the coating film together with the base material layer.

The 1 st liquid crystal layer and the 2 nd liquid crystal layer may be, for example, a1 st retardation layer and a 2 nd retardation layer, respectively. The 1 st retardation layer and the 2 nd retardation layer are not particularly limited as long as they provide a predetermined retardation to light, and examples thereof include layers functioning as an 1/2 wavelength plate, a 1/4 wavelength plate, a positive C plate, a 1/4 wavelength plate having reverse wavelength dispersibility, and the like.

When the optical film in the optical laminate of the present embodiment is a polarizing film, the optical laminate of the present embodiment can be used as a composite polarizing plate. When the composite polarizing plate constitutes a circular polarizing plate, the types of liquid crystal layers forming the 1 st liquid crystal layer and the 2 nd liquid crystal layer (the 1 st retardation layer and the 2 nd retardation layer) are preferably selected so that the layer structure of the composite polarizing plate is a structure in which a polarizing layer (linear polarizing layer), an 1/2 wavelength plate, and a 1/4 wavelength plate are sequentially stacked, or a structure in which a polarizing layer (linear polarizing layer), a 1/4 wavelength plate having reverse wavelength dispersibility, and a positive C plate are sequentially stacked.

(liquid Crystal film)

The liquid crystal film includes a1 st liquid crystal layer and a 2 nd liquid crystal layer, and may be a retardation film when the 1 st liquid crystal layer and the 2 nd liquid crystal layer are a1 st retardation layer and a 2 nd retardation layer, respectively, for example.

(optical film)

Examples of the optical film include a polarizing film, a reflective film, a semi-transmissive reflective film, a brightness enhancement film, an optical compensation film, and a film with an antiglare function. Further, a film having the same structure as the retardation film (liquid crystal film) described above may be used. The optical film may have a 1-layer structure, or may have a multilayer structure of 2 or more layers.

(adhesive layer)

The adhesive layer may be formed using an adhesive, a pressure-sensitive adhesive, or a combination thereof, and usually has 1 layer, or may have 2 or more layers. When the adhesive layer includes 2 or more layers, the layers may be formed of the same material or different materials.

The adhesive may be a combination of 1 or 2 or more of an aqueous adhesive, an active energy ray-curable adhesive, a pressure-sensitive adhesive, and the like. Examples of the aqueous adhesive include a polyvinyl alcohol resin aqueous solution and an aqueous two-part type urethane emulsion adhesive. The active energy ray-curable adhesive is an adhesive that is cured by irradiation with an active energy ray such as ultraviolet ray, and examples thereof include an adhesive containing a polymerizable compound and a photopolymerization initiator, an adhesive containing a photoreactive resin, and an adhesive containing a binder resin and a photoreactive crosslinking agent. Examples of the polymerizable compound include photopolymerizable monomers such as a photocurable epoxy monomer, a photocurable acrylic monomer, and a photocurable urethane monomer, and oligomers derived from these monomers. Examples of the photopolymerization initiator include photopolymerization initiators containing active species that generate neutral radicals, anionic radicals, cationic radicals, and the like by irradiation with active energy rays such as ultraviolet rays.

Examples of the binder include a composition containing a base polymer such as a (meth) acrylic resin, a styrene resin, or a silicone resin, and a crosslinking agent such as an isocyanate compound, an epoxy compound, or an aziridine compound.

The adhesive layer is preferably formed using an active energy ray-curable adhesive, and particularly preferably formed using an adhesive containing an ultraviolet-curable epoxy monomer and a photo cation polymerization initiator.

(adhesive layer for optical film)

The adhesive layer for an optical film can be formed using an adhesive, a pressure-sensitive adhesive, or a combination thereof. The optical film adhesive layer is usually 1 layer, but may be formed of 2 or more layers. When the adhesive layer for an optical film includes 2 or more layers, each layer may be formed of the same material or different materials.

Examples of the adhesive and the pressure-sensitive adhesive for forming the adhesive layer for an optical film include the same adhesives and pressure-sensitive adhesives as those used for the adhesive layer. As the adhesive layer for an optical film, an adhesive is preferably used.

(adhesive layer for optical layered body)

The adhesive layer for an optical layered body can be formed using an adhesive, a pressure-sensitive adhesive, or a combination thereof. The optical laminate adhesive layer is usually 1 layer, but may be formed of 2 or more layers. When the adhesive layer for an optical layered body includes 2 or more layers, the layers may be formed of the same material or different materials.

Examples of the adhesive and the pressure-sensitive adhesive for forming the adhesive layer for an optical layered body include the same adhesives and pressure-sensitive adhesives used for the adhesive layer. As the adhesive layer for an optical film, an adhesive is preferably used.

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