阅读说明：本技术 用于清洁表面的组合物 (Composition for cleaning surfaces ) 是由 丹尼尔·赫尔佐格 于 2018-04-27 设计创作，主要内容包括：本发明涉及用于清洁表面和/或用于检测溶液中或表面上的有机物质的组合物,所述组合物包含a)至少一种高锰酸、高铁酸和/或铬酸的盐,b)至少一种有机膦酸盐,和c)至少一种过硫酸盐,其中所述至少一种有机膦酸盐具有通式(I)<Image he="255" wi="388" file="DDA0002244399750000011.GIF" imgContent="drawing" imgFormat="GIF" orientation="portrait" inline="no"></Image>其中R<Sup>1</Sup>是有机基团,X<Sup>1</Sup>是OH或OM<Sub>1</Sub>和X<Sup>2</Sup>是OH或OM<Sub>2</Sub>,其中M<Sub>1</Sub>和M<Sub>2</Sub>代表碱金属离子或铵离子,其中有机基团R<Sup>1</Sup>是单取代或多取代或未取代的C<Sub>1</Sub>-C<Sub>12</Sub>烷基基团部分、C<Sub>3</Sub>-C<Sub>10</Sub>环烷基基团部分或C<Sub>6</Sub>-C<Sub>14</Sub>芳基基团部分,其中所述有机部分可以与1至3个另外的通式(I)的膦酸盐基团连接。(The invention relates to a composition for cleaning surfaces and/or for detecting organic substances in solution or on surfaces, comprising a) at least one salt of permanganic acid, ferric acid and/or chromic acid, b) at least one organic phosphonate, and c) at least one persulfate, wherein the at least one organic phosphonate has the general formula (I) Wherein R is 1 Is an organic radical, X 1 Is OH or OM 1 And X 2 Is OH or OM 2 Which isMiddle M 1 And M 2 Represents an alkali metal ion or an ammonium ion, wherein the organic radical R 1 Is one or more substituted or unsubstituted C 1 ‑C 12 Alkyl radical moiety, C 3 ‑C 10 Cycloalkyl radical moiety or C 6 ‑C 14 An aryl group moiety, wherein the organic moiety may be attached to 1 to 3 additional phosphonate groups of formula (I).)

1. A composition for cleaning a surface and/or for detecting organic matter in or on a solution comprising

a) At least one salt of permanganic acid, ferric acid and/or chromic acid,

b) at least one organic phosphonate, and

c) at least one persulfate salt,

wherein the at least one organic phosphonate has the general formula (I)

Wherein R is¹Is an organic moiety, X¹Is OH or OM₁And X²Is OH or OM₂Wherein M is₁And M₂Represents an alkali metal ion or an ammonium ion wherein the organic moiety R¹Is one or more substituted or unsubstituted C₁-C₁₂Alkyl moiety, C₃-C₁₀Cycloalkyl moiety or C₆-C₁₄(ii) an aryl moiety, wherein the organic moiety can be attached to 1 to 3 additional phosphonate groups of formula (I).

2. The composition of claim 1, wherein said C is₁-C₁₂Alkyl moiety, C₃-C₁₀Cycloalkyl moiety or C₆-C₁₄Aryl moiety by C₁-C₆Alkyl moieties and/or OH moieties.

3. The composition according to claim 1 or 2, wherein the at least one organic phosphonate is selected from the group consisting of 1-hydroxyethane- (1, 1-diphosphonic acid), 2-phosphonobutane-1, 2, 4-tricarboxylic acid and salts thereof, preferably an alkali metal salt.

4. The composition according to any one of claims 1 to 3, wherein the at least one salt of permanganate, ferrate and/or chromic acid is an alkali metal salt, preferably selected from the group consisting of potassium permanganate, potassium ferrate and potassium dichromate.

5. The composition according to any one of claims 1 to 4, wherein the at least one persulfate is a salt of peroxydisulfuric acid or peroxymonosulfuric acid.

6. The composition according to any one of claims 1 to 5, wherein the at least one persulfate is a peroxodisulfate salt selected from the group consisting of sodium peroxodisulfate, potassium peroxodisulfate and ammonium peroxodisulfate and/or a peroxomonosulfate salt selected from the group consisting of potassium peroxomonosulfate.

7. The composition according to any one of claims 1 to 6, wherein the composition comprises at least one calcium salt, preferably selected from the group consisting of calcium nitrate.

8. The composition according to any one of claims 1 to 7, wherein the composition comprises the at least one salt of permanganic acid, ferric acid and/or chromic acid in a weight ratio to the at least one organic phosphonate of from 1:50 to 1:500, preferably from 1:75 to 1:300, even more preferably from 1:100 to 1: 200.

9. The composition of any one of claims 1 to 8, wherein the composition is an aqueous composition.

10. The composition according to any one of claims 1 to 9, wherein the composition comprises more than 50 wt.%, preferably more than 70 wt.%, even more preferably more than 90 wt.% of water.

11. The composition according to claim 9 or 10, wherein the aqueous composition comprises from 0.1 to 2 wt. -%, preferably from 0.2 to 1.5 wt. -%, even more preferably from 0.3 to 1 wt. -%, even more preferably from 0.4 to 0.8 wt. -%, even more preferably from 0.4 to 0.6 wt. -%, even more preferably 0.5 wt. -% of at least one further oxidizing agent.

12. The composition according to any one of claims 9 to 11, wherein the aqueous composition comprises from 0.01 to 1 wt. -%, preferably from 0.02 to 0.9 wt. -%, even more preferably from 0.05 to 0.8 wt. -%, even more preferably from 0.075 to 0.7 wt. -%, even more preferably from 0.1 to 0.6 wt. -%, even more preferably from 0.2 to 0.6 wt. -%, even more preferably from 0.3 to 0.6 wt. -% of at least one organophosphonate.

13. The composition according to any one of claims 9 to 12, wherein the aqueous composition comprises from 0.1 to 3 wt.%, preferably from 0.2 to 2 wt.%, more preferably from 0.3 to 1 wt.% of at least one calcium salt.

14. The composition of any one of claims 1 to 8, wherein the composition is substantially free of water.

15. The composition according to any one of claims 1 to 8 or 14, wherein the composition comprises less than 20 wt.%, preferably less than 10 wt.%, even more preferably less than 5 wt.%, even more preferably less than 1 wt.% of water.

16. The composition of any one of claims 1 to 15, wherein the composition comprises at least one alkali hydroxide.

17. The composition of claim 16, wherein the at least one alkali hydroxide is NaOH, KOH, or LiOH.

18. The composition according to claim 16 or 17, wherein the aqueous composition comprises from 0.1 to 5 wt. -%, preferably from 0.2 to 3 wt. -%, even more preferably from 0.3 to 1.5 wt. -%, even more preferably from 0.4 to 1 wt. -%, even more preferably from 0.4 to 0.8 wt. -%, even more preferably 0.5 wt. -% of at least one alkaline hydroxide.

19. A kit for cleaning a surface and/or for detecting organic matter in or on a solution comprising

a1) A container comprising the composition of any one of claims 1 to 15, and

b1) a container containing at least one alkali hydroxide, or

a2) A container comprising the at least one alkali metal salt of permanganate, ferrate and/or chromic acid as defined in claim 4,

b2) a container comprising the at least one organic phosphonate as defined in any one of claims 1 to 3 and optionally the at least one persulfate as defined in any one of claims 5 or 6, and

c2) a container comprising at least one alkali hydroxide.

20. The kit of claim 19, wherein the at least one alkali hydroxide is NaOH, KOH, or LiOH.

21. A method for cleaning a surface and/or detecting organic matter in or on a solution, comprising the steps of:

contacting the composition according to any one of claims 1 to 18 or a composition obtainable by mixing the components of container a1 and container b1 or container a2, container b2 and container b3 with a surface to be cleaned or a surface or a solution on or in which an organic substance to be detected is present.

22. Use of the organic phosphonate as defined in any of claims 1 to 3 for stabilizing a salt of permanganic acid, ferric acid and/or chromic acid in a composition, preferably an aqueous composition.

Example (b):