Decarbonization waste gas recovery system alkali device of synthetic ammonia
阅读说明:本技术 一种合成氨的脱碳废气回收制碱装置 (Decarbonization waste gas recovery system alkali device of synthetic ammonia ) 是由 孙彩军 徐松 郑健 于 2019-09-30 设计创作,主要内容包括:本发明提供一种合成氨的脱碳废气回收制碱装置,其特征在于:它包括用管线连通的鼓泡吸收塔(1)、二氧化碳储罐(2)、风机(3)、稀液槽(4)、离心机(5)、分离液槽(6)、烘干机(7)、输送泵(8)、吸收泵(9)、制碱槽(10)。本发明结构简单、使用方便,通过将脱碳净化后的二氧化碳在次输入到鼓泡吸收塔内直接吸收制碱,变废为宝,减少工业废气的排放,以及排放带来的环境气味问题得到解决。(The invention provides an alkali making device by recovering decarbonized waste gas of synthetic ammonia, which is characterized in that: the device comprises a bubbling absorption tower (1), a carbon dioxide storage tank (2), a fan (3), a dilute liquid tank (4), a centrifuge (5), a separation liquid tank (6), a dryer (7), a delivery pump (8), an absorption pump (9) and an alkali preparation tank (10) which are communicated by pipelines. The invention has simple structure and convenient use, and the carbon dioxide after decarburization and purification is input into the bubbling absorption tower for the second time to directly absorb the soda, thereby changing waste into valuable, reducing the emission of industrial waste gas and solving the problem of environmental odor caused by emission.)
1. A decarbonization waste gas recovery alkali making device for synthetic ammonia comprises a bubbling absorption tower (1), wherein one side of the bubbling absorption tower (1) is communicated with a decarbonization waste gas input pipe (11), the decarbonization waste gas input pipe (11) is also provided with a waste gas inlet valve (11 a) correspondingly matched with the decarbonization waste gas input pipe, one side of the bubbling absorption tower (1) is provided with an alkali making tank (10), a spray pipe (10 a) is communicated between the alkali making tank (10) and the bubbling absorption tower (1), the spray pipe (10 a) is also provided with an absorption pump (9) correspondingly matched with the spray pipe, one end of the spray pipe (10 a) is inserted into the bubbling absorption tower (1), and the end part of the spray pipe is connected with a liquid distributor (10 c);
a dilute liquid tank (4) is arranged on one side of the lower part of the bubbling absorption tower (1), an outflow pipe (4 a) is communicated between the lower part of the bubbling absorption tower (1) and the dilute liquid tank (4), and an outflow control valve (4 b) which is correspondingly matched with the outflow pipe (4 a) is arranged on the outflow pipe;
a centrifugal machine (5) is further arranged on one side of the bottom of the tower body of the bubbling absorption tower (1), a pipeline (5 a) is communicated between the bottom of the liquid accumulation part (1 a) and the centrifugal machine (5), a solid outlet of the centrifugal machine (5) is communicated with a dryer (7), and a liquid outlet of the centrifugal machine (5) is communicated with a separation liquid tank (6);
a second liquid return pipe (8 a) is communicated between the separation liquid tank (6) and the other side of the lower part of the bubbling absorption tower (1), and a delivery pump (8) is arranged on the second liquid return pipe (8 a).
2. The apparatus for producing soda by recycling decarbonized exhaust gas from ammonia synthesis according to claim 1, wherein: the device is characterized in that a carbon dioxide storage tank (2) is arranged on the other side of the bubbling absorption tower (1), a pressure gauge (a pressure transmitter) (2 b) and a liquid level meter which is displayed in the figure are correspondingly matched and arranged on the carbon dioxide storage tank (2), the upper part of the carbon dioxide storage tank (2) is communicated with the upper part of the bubbling absorption tower (1) through a carbon return tube (a pipeline) (2 a), a carbon inlet tube (12) is communicated between one side of the bottom of the carbon dioxide storage tank (2) and the decarburization waste gas input tube (11), and a fan (3) which is correspondingly matched is arranged on the carbon inlet tube (12).
3. The apparatus for producing soda by recycling decarbonized exhaust gas from ammonia synthesis according to claim 2, wherein: a second carbon return tube (7 a) is also communicated between the gas outlet of the dryer (7) and the carbon return tube (2 a).
4. The apparatus for producing soda by recycling decarbonized exhaust gas from ammonia synthesis according to claim 2, wherein: a liquid return pipe (6 a) is connected between the other side of the bottom of the carbon dioxide storage tank (2) and the separation liquid tank (6), and a liquid return control valve (6 b) which is correspondingly matched with the liquid return pipe (6 a) is arranged on the liquid return pipe.
5. The apparatus for producing soda by recycling decarbonized exhaust gas from ammonia synthesis according to claim 1, wherein: a concentrated product groove (13) is arranged on one side of the dilute liquid groove (4), a pipeline (13 a) is communicated between the dilute liquid groove (4) and the concentrated product groove (13), and a low-temperature steam input pipe (14) is also arranged on one side of the concentrated product groove (13).
6. The apparatus for producing soda by recycling decarbonized exhaust gas from ammonia synthesis according to claim 1, wherein: a branch pipe (8 b) communicated with the dilute liquid tank (4) is also arranged on the second liquid return pipe (8 a), and a branch pipe control valve (8 c) is arranged on the branch pipe (8 b).
7. The apparatus for producing soda by recycling decarbonized exhaust gas from ammonia synthesis according to claim 1, wherein: a second branch pipe (8 d) communicated with the spray pipe (10 a) is further arranged on the second liquid return pipe (8 a), and a third liquid return control valve (8 f) correspondingly matched with the second branch pipe (8 d) is further arranged on the second branch pipe.
The technical field is as follows:
the invention relates to the field of recovery of decarbonization waste gas of synthetic ammonia, in particular to a decarbonization waste gas recovery alkali-making device of synthetic ammonia.
Background art:
with the needs of various technical progress and environmental improvement requirements of ammonia synthesis enterprises, in recent years, the chemical industry is famous for high pollution, the environmental problem becomes one of bottlenecks restricting the development of the chemical industry, and the search for a proper mode and a method is an irreparable task.
The decarbonization process adopted by the current ammonia synthesis enterprise generally comprises a pressure swing adsorption decarbonization process and a carbon-propane liquid decarbonization process, the pressure swing adsorption decarbonization process is a decarbonization process which is adopted in a large area at present, but the existing process has effective gas loss, the ton ammonia cost which influences the ammonia synthesis to different degrees influences the economic benefit of the enterprise, the carbon-propane decarbonization process does not have the effective gas loss, the absorption cycle discharges high-concentration CO2 gas which is generally directly discharged into the atmosphere, the emission of greenhouse gas is invisibly increased, and the high-concentration CO2 gas is accompanied with special odor, so that the process is not environment-friendly and is not beneficial to a low-carbon economic mode advocated by the current enterprise economy.
The invention content is as follows:
the invention aims to overcome the defects in the prior art and provides the device for recovering the decarbonized waste gas of the synthetic ammonia to prepare the alkali.
The application provides the following technical scheme:
a decarbonization waste gas recovery alkali making device for synthetic ammonia comprises a bubbling absorption tower, wherein one side of the bubbling absorption tower is communicated with a decarbonization waste gas input pipe, the decarbonization waste gas input pipe is also provided with a waste gas inlet valve correspondingly matched with the decarbonization waste gas input pipe, one side of the bubbling absorption tower is provided with an alkali making tank, a spray pipe is communicated between the alkali making tank and the bubbling absorption tower, the spray pipe is also provided with an absorption pump correspondingly matched with the spray pipe, one end of the spray pipe is inserted into the bubbling absorption tower, and the end part of the spray pipe is connected with a liquid distributor; a dilute liquid tank is arranged on one side of the lower part of the bubbling absorption tower body, an outflow pipe is communicated between the lower part of the bubbling absorption tower body and the dilute liquid tank, and an outflow control valve which is correspondingly matched with the outflow pipe is arranged on the outflow pipe;
a centrifugal machine is further arranged on one side of the bottom of the bubbling absorption tower body, a pipeline is communicated between the bottom of the liquid accumulating part and the centrifugal machine, a solid outlet of the centrifugal machine is communicated with a dryer, and a liquid outlet of the centrifugal machine is communicated with a separation liquid tank;
a second liquid return pipe is communicated between the separation liquid tank and the other side of the lower part of the bubbling absorption tower, and a delivery pump is arranged on the second liquid return pipe.
On the basis of the technical scheme, the following further technical scheme can be provided:
the other side of the bubbling absorption tower is provided with a carbon dioxide storage tank, the carbon dioxide storage tank is also provided with a pressure gauge and a liquid level meter which are correspondingly matched with the pressure gauge and are displayed in the figure, the upper part of the carbon dioxide storage tank is communicated with the upper part of the bubbling absorption tower through a carbon return tube, a carbon inlet tube is also communicated between one side of the bottom of the carbon dioxide storage tank and the decarbonization waste gas input tube, and a fan which is correspondingly matched with the carbon inlet tube is also arranged on the carbon inlet tube.
And a second carbon return tube is communicated between the gas outlet of the dryer and the carbon return tube.
A liquid return pipe is connected between the other side of the bottom of the carbon dioxide storage tank and the separation liquid tank, and a liquid return control valve which is correspondingly matched with the liquid return pipe is arranged on the liquid return pipe.
And a thick liquid groove is arranged on one side of the thin liquid groove, a pipeline is communicated between the thin liquid groove and the thick liquid groove, and a low-temperature steam input pipe is also arranged on one side of the thick liquid groove.
And a branch pipe communicated with the dilute liquid tank is also arranged on the second liquid return pipe, and a branch pipe control valve is arranged on the branch pipe.
And a second branch pipe communicated with the spray pipe is further arranged on the second liquid return pipe, and a third liquid return control valve correspondingly matched with the second branch pipe is further arranged on the second branch pipe.
The invention has the advantages that:
the invention has simple structure and convenient use, and the carbon dioxide after decarburization and purification is input into the bubbling absorption tower for the second time to directly absorb the soda, thereby changing waste into valuable, reducing the emission of industrial waste gas and solving the problem of environmental odor caused by emission.
Description of the drawings:
FIG. 1 is a process flow diagram of the present invention.
The specific implementation mode is as follows:
as shown in figure 1, the decarbonization waste gas recovery alkali making device for synthetic ammonia comprises a bubbling absorption tower 1, wherein one side of the lower part of the bubbling absorption tower 1 is communicated with a decarbonization waste
An alkali making
The
A carbon
A
When the pressure in the carbon
The carbon dioxide gas that has accelerated simultaneously also can accelerate the carbon dioxide waste gas in the decarbonization waste
The lower part of the tower body of the bubbling absorption tower 1 is provided with a conical liquid accumulation part 1a, one side of the liquid accumulation part 1a is provided with a dilute
Still be equipped with
The worker opens the liquid
The solid outlet of the
A liquid return pipe 6a is connected between the other side of the bottom of the carbon
A second liquid return pipe 8a is communicated between the
The second liquid return pipe 8a is also provided with a
A
The concentration (PH value) of the sodium carbonate solution in the
When the concentration of the sodium carbonate solution discharged from the
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