阅读说明：本技术 酒糟保健敷泥及其制备方法 (Health-care vinasse applying mud and preparation method thereof ) 是由 段兆法 谈志新 于 2019-10-17 设计创作，主要内容包括：本发明公开了一种酒糟保健敷泥及其制备方法,该酒糟保健敷泥由如下重量份原料制成：酒糟20-25份、甘油硬脂酸酯12-15份、改性火山泥25-30份、改性海藻泥25-30份、川乌15-18份、麻黄15-18份、松节15-18份、白芍15-18份、去离子水40-50份、碳酸氢钠5.5-8份；本发明在制备过程中加入川乌、麻黄、松节、白芍的提取液,使酒糟保健敷泥具有祛风燥湿舒筋通络活血止痛、缓解支气管平滑肌痉挛的作用,同时制备了改性火山泥和改性海藻泥加入酒糟保健敷泥中,使得敷泥在使用时除了自身含有的水分外,还可以吸收空气中的水分,并提升了酒糟保健敷泥表面光滑性,使得酒糟保健敷泥易清洗,进一步减小了酒糟保健敷泥对皮肤的伤害,有很好的应用市场。(The invention discloses vinasse health-care compress mud and a preparation method thereof, wherein the vinasse health-care compress mud is prepared from the following raw materials in parts by weight: 20-25 parts of vinasse, 12-15 parts of glycerol stearate, 25-30 parts of modified volcanic mud, 25-30 parts of modified seaweed mud, 15-18 parts of monkshood, 15-18 parts of ephedra, 15-18 parts of pine nodular branch, 15-18 parts of white paeony root, 40-50 parts of deionized water and 5.5-8 parts of sodium bicarbonate; the invention adds the extract of radix aconiti, ephedra, loose knot and white paeony root in the preparation process, so that the vinasse health care compress mud has the functions of dispelling wind, eliminating dampness, relaxing muscles and tendons, activating blood circulation, relieving pain and relieving bronchial smooth muscle spasm, and simultaneously prepares the modified volcanic mud and the modified seaweed mud which are added into the vinasse health care compress mud, so that the compress mud can absorb moisture in the air besides the moisture contained in the compress mud when in use, and the surface smoothness of the vinasse health care compress mud is improved, so that the vinasse health care compress mud is easy to clean, the damage of the vinasse health care compress mud to the skin is further reduced, and the invention has good application market.)

1. The health-care vinasse applying mud is characterized in that: the feed is prepared from the following raw materials in parts by weight: 20 parts of vinasse, 12 parts of glycerol stearate, 25 parts of modified volcanic mud, 25 parts of modified seaweed mud, 15 parts of radix aconiti, 15 parts of ephedra, 15 parts of pine nodular branch, 15 parts of radix paeoniae alba, 40 parts of deionized water and 5.5-8 parts of sodium bicarbonate;

the preparation method of the vinasse health-care compress mud comprises the following steps:

step S1: cleaning radix Aconiti, herba Ephedrae, lignum Pini nodi, and radix Paeoniae alba, respectively adding into a traditional Chinese medicine blender, pulverizing for 45min until the blocks are completely pulverized into powder, adding the powder and deionized water into a stirring kettle, stirring at 90 deg.C for 2 hr, and filtering to obtain traditional Chinese medicine solution;

step S2: adding the vinasse into a stirring kettle, adding deionized water, pulping at the temperature of 50 ℃ and the rotating speed of 1500r/min, adding the pulped vinasse into a filter, and sieving with a 30-mesh sieve to obtain vinasse pulp;

step S3: adding the traditional Chinese medicine solution prepared in the step S1, the vinasse slurry prepared in the step S2, glyceryl stearate, the modified volcanic mud, the modified seaweed mud and sodium bicarbonate into a reaction kettle, stirring for 3 hours at the temperature of 50-60 ℃ and the rotating speed of 500r/min, standing for 30 minutes, and cooling to room temperature to prepare the vinasse health-care compress mud.

2. The health vinasse dressing mud of claim 1, wherein: the deionized water dosage ratio of the step S1 and the step S2 is 1: 1.

3. The health vinasse dressing mud of claim 1, wherein: the modified volcanic mud is prepared from the following raw materials in parts by weight: 20-25 parts of volcanic mud, 10-12 parts of glycerol, 10-13 parts of sodium glutamate, 10-15 parts of liquid bromine, 7-10 parts of red phosphorus, 10-13 parts of ethanol, 8.5-10 parts of concentrated sulfuric acid, 10-15 parts of sodium hydroxide solution, 8-10 parts of copper oxide, 10-15 parts of dilute hydrochloric acid, 7-9 parts of deionized water and 3.5-5 parts of activated carbon;

the preparation method of the modified volcanic mud comprises the following steps:

(1) adding sodium glutamate, liquid bromine and red phosphorus into a reaction kettle, reacting for 30-45min at the temperature of 45-50 ℃ and the rotating speed of 1000r/min, adding ethanol and concentrated sulfuric acid, and reacting for 15-30min at the temperature of 60-70 ℃ to obtain a sodium glutamate derivative 1;

(2) adding a sodium hydroxide solution and copper oxide into the reaction kettle in the step (1), reacting for 30-45min at the temperature of 80-90 ℃ to obtain a sodium glutamate derivative 2, adding dilute hydrochloric acid, and reacting for 30-45min at the temperature of 80-90 ℃ to obtain a sodium glutamate derivative 3;

(3) adding deionized water into the reaction kettle in the step (2), stirring for 5-10min at the rotation speed of 1500r/min, filtering to obtain a first mixed solution, adding the first mixed solution into a distillation kettle, distilling for 2h at the temperature of 180 ℃ to obtain a light yellow melt, adding deionized water again, stirring for 5-10min at the rotation speed of 1500r/min until the melt is dissolved, adding activated carbon, heating for 5min at the temperature of 85-90 ℃, filtering while hot, filtering out redundant activated carbon to obtain a second mixed solution, adding the second mixed solution into the distillation kettle, distilling at the temperature of 100 ℃, and then drying in vacuum to obtain a sodium glutamate derivative 4;

(4) adding the volcanic mud, the glycerol and the sodium glutamate derivative 4 prepared in the step (3) into a stirring kettle, and stirring for 1-2 hours at the temperature of 50-60 ℃ and the rotating speed of 1500r/min to prepare the modified volcanic mud.

4. The health vinasse compress mud of claim 3, wherein: the mass fraction of the concentrated sulfuric acid is 98%, the concentration of the sodium hydroxide solution is 0.1mol/L, the mass fraction of the dilute hydrochloric acid is 15%, and the two-time dosage ratio of the deionized water in the step (3) is 1: 1.

5. The health vinasse dressing mud of claim 1, wherein: the modified seaweed mud is prepared from the following raw materials in parts by weight: 20-25 parts of seaweed mud, 10-13 parts of 8-phenyloctanoic acid, 20-25 parts of ethanol, 8.5-10 parts of concentrated sulfuric acid, 10-15 parts of liquid bromine, 8.5-12 parts of ferric chloride, 10-13 parts of copper powder, 20-25 parts of dilute hydrochloric acid and 10-12 parts of glycerol;

the preparation method of the modified seaweed mud comprises the following steps:

(1) adding 8-phenyloctanoic acid, ethanol and concentrated sulfuric acid into a reaction kettle, and reacting at 60-70 ℃ for 15-30min to obtain 8-phenyloctanoic acid derivative 5;

(2) adding the 8-phenyloctanoic acid derivative 5 prepared in the step (1), liquid bromine and ferric chloride into a reaction kettle, and reacting for 30-45min at the temperature of 80-90 ℃ to obtain an 8-phenyloctanoic acid derivative 6;

(3) adding the 8-phenyloctanoic acid derivative 6 prepared in the step (2) and copper powder into a reaction kettle, and reacting for 1-2h at the temperature of 130-140 ℃ to obtain an 8-phenyloctanoic acid derivative 7;

(4) reacting the 8-phenyloctanoic acid derivative 7 prepared in the step (3) with dilute hydrochloric acid in a reaction kettle at the temperature of 80-90 ℃ for 30-45min to obtain an 8-phenyloctanoic acid derivative 8;

(5) and (3) adding the 8-phenyloctanoic acid derivative 8 obtained in the step (4), the seaweed mud and glycerol into a stirring kettle, and stirring for 1-2 hours at the temperature of 50-60 ℃ and the rotating speed of 1500r/min to obtain the modified seaweed mud.

6. The distiller's grain health care compress mud of claim 5, wherein: the mass fraction of the concentrated sulfuric acid is 98%, the concentration of the sodium hydroxide solution is 0.1mol/L, and the mass fraction of the dilute hydrochloric acid is 15%.

7. A method for preparing the vinasse health care mud for applying according to claim 1, which is characterized by comprising the following steps of: the method comprises the following steps:

step S1: cleaning radix Aconiti, herba Ephedrae, lignum Pini nodi, and radix Paeoniae alba, respectively adding into a traditional Chinese medicine blender, pulverizing for 45min until the blocks are completely pulverized into powder, adding the powder and deionized water into a stirring kettle, stirring at 90 deg.C for 2 hr, and filtering to obtain traditional Chinese medicine solution;

step S2: adding the vinasse into a stirring kettle, adding deionized water, pulping at the temperature of 50 ℃ and the rotating speed of 1500r/min, adding the pulped vinasse into a filter, and sieving with a 30-mesh sieve to obtain vinasse pulp;

step S3: adding the traditional Chinese medicine solution prepared in the step S1, the vinasse slurry prepared in the step S2, glyceryl stearate, the modified volcanic mud, the modified seaweed mud and sodium bicarbonate into a reaction kettle, stirring for 3 hours at the temperature of 50-60 ℃ and the rotating speed of 500r/min, standing for 30 minutes, and cooling to room temperature to prepare the vinasse health-care compress mud.

Technical Field

The invention belongs to the field of preparation of paste, and particularly relates to vinasse health-care paste and a preparation method thereof.

Background

The vinasse is residue left after wine brewing of rice, wheat, sorghum and the like, is generally used as a feed for pigs and cattle by farmers, is acidic after fermentation of the raw materials of the vinasse, contains more water, is not beneficial to being used as the feed for a long time, is easy to corrode and cause environmental pollution if most of the vinasse is stacked for a long time, and is also a problem worthy of attention of people;

rheumatism is a disease mainly attacking joints, bones, muscles, blood vessels and related soft tissues or connective tissues, the treatment difficulty of the rheumatism is high, the rheumatism cannot be cured radically, and the rheumatism is relieved by frequently using the dressing mud in traditional Chinese medicine;

chinese invention patent CN102670347A discloses a method for producing attapulgite, lees and folium artemisiae argyi hot compress mud, the invention adds folium artemisiae argyi mixed liquid into fresh lees to be stirred and mixed into lees and folium artemisiae argyi mixture, high-viscosity attapulgite powder soil is slowly added into lees and folium artemisiae argyi mixture to be stirred into attapulgite, alcohol folium artemisiae argyi hot compress mud, the invention has good health care function in preparing the compress mud, but the moisture retention of the compress mud is general, the compress mud becomes dry after a period of use, so that the skin at the position of the compress mud is dry and even causes skin injury, and meanwhile, when the compress mud is cleaned, the compress mud is not easy to clean, so that part of the mud is adhered to the surface of the skin.

Disclosure of Invention

The invention aims to provide vinasse health-care compress mud and a preparation method thereof, which are improved aiming at the defects of common vinasse health-care compress mud in the market, the invention adds the extracting solutions of radix aconiti, ephedra, loose knot and radix paeoniae alba in the preparation process, can well play the roles of dispelling wind, eliminating dampness, relaxing muscles and tendons, activating blood circulation, relieving pain and relieving bronchial smooth muscle spasm when the vinasse health-care compress mud is used, and simultaneously prepares modified volcanic mud and modified seaweed mud, the modified volcanic mud is added with vinasse health care compress mud, so that the alcohol health care compress mud can absorb moisture in air in the use process and prevent skin from drying, the modified seaweed mud enables the surface smoothness of the seaweed mud to be enhanced, the easy cleaning performance of the vinasse health-care applying mud is improved, the modified volcanic mud and the modified seaweed mud are jointly used, the damage of the vinasse health-care applying mud to skin is further reduced, and the modified seaweed mud has a good application market.

The technical problems to be solved by the invention are as follows:

1. the traditional vinasse health-care mud is dried after being applied to the skin for a period of time, so that the skin is very dry after the vinasse health-care mud is used, and the skin is seriously damaged even;

2. after using lees health care to apply mud, need wash, traditional lees health care applies mud can glue and glue on the skin surface because of using for a long time, needs carefully to wash when wasing, and the part is applied mud simultaneously and is easily remained on the skin surface, further influences the skin.

The purpose of the invention can be realized by the following technical scheme:

a vinasse health-care compress mud and a preparation method thereof are prepared from the following raw materials in parts by weight: 20-25 parts of vinasse, 12-15 parts of glycerol stearate, 25-30 parts of modified volcanic mud, 25-30 parts of modified seaweed mud, 15-18 parts of monkshood, 15-18 parts of ephedra, 15-18 parts of pine nodular branch, 15-18 parts of white paeony root, 40-50 parts of deionized water and 5.5-8 parts of sodium bicarbonate;

the preparation method of the vinasse health-care compress mud comprises the following steps:

step S1: cleaning radix Aconiti, herba Ephedrae, lignum Pini nodi, and radix Paeoniae alba, respectively adding into a traditional Chinese medicine blender, pulverizing for 30-45min until the blocks are completely pulverized into powder, adding the powder and deionized water into a stirring kettle, stirring at 80-90 deg.C for 1-2 hr, and filtering to obtain traditional Chinese medicine solution;

step S2: adding distiller's grains into a stirring kettle, adding deionized water, pulping at 40-50 deg.C and 1500r/min, adding the pulped distiller's grains into a filter, and sieving with 30 mesh sieve to obtain distiller's grain slurry;

step S3: adding the traditional Chinese medicine solution prepared in the step S1, the vinasse slurry prepared in the step S2, glyceryl stearate, the modified volcanic mud, the modified seaweed mud and sodium bicarbonate into a reaction kettle, stirring for 2-3h at the temperature of 50-60 ℃ and the rotating speed of 500r/min, standing for 20-30min, and cooling to room temperature.

Further, the deionized water is used in the ratio of 1:1 in the steps S1 and S2.

Further, the modified volcanic mud is prepared from the following raw materials in parts by weight: 20-25 parts of volcanic mud, 10-12 parts of glycerol, 10-13 parts of sodium glutamate, 10-15 parts of liquid bromine, 7-10 parts of red phosphorus, 10-13 parts of ethanol, 8.5-10 parts of concentrated sulfuric acid, 10-15 parts of sodium hydroxide solution, 8-10 parts of copper oxide, 10-15 parts of dilute hydrochloric acid, 7-9 parts of deionized water and 3.5-5 parts of activated carbon;

the preparation method of the modified volcanic mud comprises the following steps:

(1) adding sodium glutamate, liquid bromine and red phosphorus into a reaction kettle, reacting for 30-45min at the temperature of 45-50 ℃ and the rotating speed of 1000r/min, adding ethanol and concentrated sulfuric acid, and reacting for 15-30min at the temperature of 60-70 ℃ to obtain a sodium glutamate derivative 1;

(2) adding a sodium hydroxide solution and copper oxide into the reaction kettle in the step (1), reacting for 30-45min at the temperature of 80-90 ℃ to obtain a sodium glutamate derivative 2, adding dilute hydrochloric acid, and reacting for 30-45min at the temperature of 80-90 ℃ to obtain a sodium glutamate derivative 3;

(3) adding deionized water into the reaction kettle in the step (2), stirring for 5-10min at the rotation speed of 1500r/min, filtering to obtain a first mixed solution, adding the first mixed solution into a distillation kettle, distilling for 2h at the temperature of 180 ℃ to obtain a light yellow melt, adding deionized water again, stirring for 5-10min at the rotation speed of 1500r/min until the melt is dissolved, adding activated carbon, heating for 5min at the temperature of 85-90 ℃, filtering while hot, filtering out redundant activated carbon to obtain a second mixed solution, adding the second mixed solution into the distillation kettle, distilling at the temperature of 100 ℃, and then drying in vacuum to obtain a sodium glutamate derivative 4;

(4) adding the volcanic mud, the glycerol and the sodium glutamate derivative 4 prepared in the step (3) into a stirring kettle, and stirring for 1-2 hours at the temperature of 50-60 ℃ and the rotating speed of 1500r/min to prepare the modified volcanic mud.

Further, the mass fraction of the concentrated sulfuric acid is 98%, the concentration of the sodium hydroxide solution is 0.1mol/L, the mass fraction of the dilute hydrochloric acid is 15%, and the two-time dosage ratio of the deionized water in the step (3) is 1: 1.

Further, the modified seaweed mud is prepared from the following raw materials in parts by weight: 20-25 parts of seaweed mud, 10-15 parts of 8-phenyloctanoic acid, 20-25 parts of ethanol, 8.5-10 parts of concentrated sulfuric acid, 10-15 parts of liquid bromine, 8.5-12 parts of ferric chloride, 8-0 part of copper powder, 10-15 parts of dilute hydrochloric acid, 10-15 parts of sodium hydroxide and 10-12 parts of glycerol;

the preparation method of the modified seaweed mud comprises the following steps:

(1) adding 8-phenyloctanoic acid, ethanol and concentrated sulfuric acid into a reaction kettle, and reacting at 60-70 ℃ for 15-30min to obtain 8-phenyloctanoic acid derivative 5;

(2) adding the 8-phenyloctanoic acid derivative 5 prepared in the step (1), liquid bromine and ferric chloride into a reaction kettle, and reacting at the temperature of 80-90 ℃ for 30-45min to obtain an 8-phenyloctanoic acid derivative 6;

(3) adding the 8-phenyloctanoic acid derivative 6 prepared in the step (2) and copper powder into a reaction kettle, and reacting for 1-2h at the temperature of 130-140 ℃ to obtain an 8-phenyloctanoic acid derivative 7;

(4) reacting the 8-phenyloctanoic acid derivative 7 prepared in the step (3) with a dilute hydrochloric acid reaction kettle at the temperature of 80-90 ℃ for 30-45min, adding a sodium hydroxide solution, and stirring to obtain an 8-phenyloctanoic acid derivative 8;

(5) and (3) adding the 8-phenyloctanoic acid derivative 8 obtained in the step (4), the seaweed mud and glycerol into a stirring kettle, and stirring for 1-2 hours at the temperature of 50-60 ℃ and the rotating speed of 1500r/min to obtain the modified seaweed mud.

Further, the mass fraction of the concentrated sulfuric acid is 98%, the concentration of the sodium hydroxide solution is 0.1mol/L, and the mass fraction of the dilute hydrochloric acid is 15%.

The invention has the beneficial effects that:

1. in the process of preparing the vinasse health-care compress mud, the common monkshood mother root, the ephedra herb, the loose knot and the white paeony root are firstly crushed and then heated and stirred, so that beneficial substances contained in the common monkshood mother root, the ephedra herb, the loose knot and the white paeony root are extracted, the residues are filtered out, the mixed solution is added into the vinasse health-care compress mud, and the effects of dispelling wind, eliminating dampness, relaxing muscles and tendons, activating blood circulation to stop pain and relieving spasm of bronchial smooth muscle can be well achieved by using the vin;

2. the invention prepares a modified volcanic mud in the process of preparing vinasse health care compress mud, uses sodium glutamate as raw material, replaces hydrogen on methyl in the sodium glutamate with bromine through liquid bromine, protects carboxyl in the sodium glutamate through ethanol, further replaces the bromine with hydroxyl, and then deprotects the protected carboxyl to obtain a substance similar to sodium pyrrolidone carboxylate, the substance has good hygroscopicity as the sodium pyrrolidone carboxylate, and simultaneously a monomer substance contains two hydroxyl groups, the hydroxyl groups belong to hydrophilic groups, can form hydrogen bonds with water molecules, have larger hydroxyl polarity and are easy to combine with water with large dielectric constant, and the modified volcanic mud is added into the vinasse health care compress mud to ensure that the alcohol health care compress mud can absorb moisture in the air in the using process, prevent skin drying and further protect skin;

3. the invention discloses a modified seaweed mud prepared in the process of preparing vinasse health care compress mud, which is prepared by taking 8-phenyloctanoic acid as a raw material, protecting carboxyl of the 8-phenyloctanoic acid, substituting hydrogen on a benzene ring pair into bromine under the action of a catalyst through bromine liquid, adding copper powder to perform Ullmann reaction under a high temperature condition, amplifying original molecules, deprotecting, reducing carboxylic acid, further reacting with sodium hydroxide to form an analogue with sodium aliphatate, wherein one molecule contains two long alkyl chains, the alkyl chains are soft and can be freely twisted and are similar to soap, and the substance is added into the seaweed mud to prepare the modified seaweed mud, so that the surface smoothness of the seaweed mud is enhanced, and the easiness in cleaning of the vinasse health care compress mud is further improved.

Detailed Description

The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.