阅读说明：本技术 一种新型无污染净水剂配方及其制备方法 (A kind of Novel pollution-free water purification agent prescription and preparation method thereof ) 是由 王忠厚 杨宗兰 经文静 李奎江 于 2018-05-26 设计创作，主要内容包括：本发明公开了一种新型无污染净水剂配方及其制备方法,采用水溶性硅、中草药提取物、硅酸镁、活性炭、硫酸盐、氯酸钠、碳酸氢铵、二氧化氯、聚合氯化铝、甲壳素、聚合磷酸铝铁等原料,经过一系列工艺步骤,制得净水剂。本发明施用到水中可以产生震荡波,从而将水中的杂质有效溶解,同时增加溶解氧的浓度,提供充足氧气,有利于鱼虾的生长发育；没有有毒物质,既能有效杀菌,又不会对人体产生毒害作用,安全性高；施用本发明净水剂后,可以有效抑制水体中藻类的过度繁殖,改善养殖水体的富营养化状态,对修复养殖系统水环境具有显著效果,可为对虾的高产、高效养殖营造良好的水域生态环境,促进鱼虾生长提高鱼虾品质。(The invention discloses a kind of Novel pollution-free water purification agent prescriptions and preparation method thereof, using raw materials such as water-soluble silicon, Chinese herbal medicine extract, magnesium silicate, active carbon, sulfate, sodium chlorate, ammonium hydrogen carbonate, chlorine dioxide, aluminium polychloride, chitin, polymer phosphate ferro-aluminums, by series of process step, water purification agent is made.The present invention, which is administered in water, can produce Sasser, so that the impurity in water effectively be dissolved, while increasing the concentration of dissolved oxygen, provides sufficient oxygen, is conducive to the growth and development of fishes and shrimps；There is no noxious material, can effectively sterilize and toxic action is generated to human body, it is highly-safe；After applying water purification agent of the present invention, the excessive multiplication of Measures of Algae in Water Body can effectively be inhibited, improve the eutrophic state of breeding water body, there is remarkable result to cultivating system water environment is repaired, good water area ecological environment can be built for the highly efficient and productive cultivation of prawn, fishes and shrimps growth is promoted to improve fishes and shrimps quality.)

1. a kind of Novel pollution-free water purification agent prescription, it is characterised in that: including following component and its parts by weight: water-soluble silicon 50-60 parts, 40-50 parts of Chinese herbal medicine extract, 7-9 parts of magnesium silicate, 9-12 parts of active carbon, 15-18 parts of sulfate, sodium chlorate 5-7 Part, 2-7 parts of ammonium hydrogen carbonate, 1-5 parts of chlorine dioxide, 5-8 parts of aluminium polychloride, 3-6 parts of chitin, polymer phosphate ferro-aluminum 10-14 Part.

2. Novel pollution-free water purification agent prescription as described in claim 1, it is characterised in that: the water purification agent prescription preferred embodiment Are as follows: 55 parts of water-soluble silicon, 45 parts of Chinese herbal medicine extract, 8 parts of magnesium silicate, 9 parts of active carbon, 16 parts of sulfate, 6 parts of sodium chlorate, carbon 4 parts of sour hydrogen ammonium, 3 parts of chlorine dioxide, 6 parts of aluminium polychloride, 4 parts of chitin, 11 parts of polymer phosphate ferro-aluminum.

3. Novel pollution-free water purification agent prescription as claimed in claim 1 or 2, it is characterised in that: the sulfate be aluminum sulfate, One of ferric sulfate, calcium sulfate, sodium sulphate are a variety of.

4. Novel pollution-free water purification agent prescription as claimed in claim 3, it is characterised in that: the water-soluble silicon is by high-grade Silica by 1650 DEG C of -2000 DEG C of high-temperature physics extraction methods persistently burn the gasification obtained as above arrived in moxibustion 8 hours silicon member Plain ingredient.

5. the Novel pollution-free water purification agent prescription as described in claims 1 or 2 or 4, it is characterised in that: the Chinese herbal medicine extract Pressed by geranium wilfordii, great Ye, frutus cnidii, pumpkin seeds, the root of Beijing euphorbia, Celastrus angulatus, kuh-seng, Chinese torreyanut, radix bupleuri, granatum, Chinese ash, morning glory, Phoenix-tail fern, cortex acanthopanacis, Radix Glycyrrhizae composition, the production method of Chinese herbal medicine extract are as follows: said herbal medicine plus water are rinsed, are cut into broken Piece is crushed to 40~80 mesh, removes the impurity in medicinal material, adds water to cook 8-12h；At a temperature of 80 DEG C~95 DEG C, concentration 2 is small When to get Chinese herbal medicine extract.

6. a kind of preparation method of Novel pollution-free water purification agent prescription, characterized by the following steps:

(1) sulfate, water-soluble silicon, ammonium hydrogen carbonate, chitin are mixed in deionized water solution, stirs 6-9h at room temperature； Then ultrasonic disperse is carried out using electromagnetic acoustic device, the power of the ultrasonic disperse is 900-1000W, and jitter time 2h is obtained To mixed solution；

(2) above-mentioned mixed solution is mixed with the Chinese herbal medicine extract of corresponding number and sodium chlorate, is then heated at 70-85 DEG C 4-5h is stirred, then pressure 0.6-0.9MPa is gradually warmed up, continue to stir 6-7h, mixed liquor is made to cool；

(3) when the mixed liquor in step (2) cools to 28 DEG C, place it in enamel reaction still, then thereto plus Enter magnesium silicate, active carbon, chlorine dioxide, start stirring, aluminium polychloride and polymer phosphate ferro-aluminum, stirring are added while stirring 30-40 minutes, discharging obtained water purification agent after standing 6-8h.

7. the preparation method of Novel pollution-free water purification agent prescription as claimed in claim 6, it is characterised in that: the step (2) It is carried out under vacuum nitrogen gas atmosphere.

8. the preparation method of Novel pollution-free water purification agent prescription as described in claim 1, it is characterised in that: flat according to every 1000 500 grams -750 grams of water purification agent dosage is added in square meter Shui Shen 1-1.5 meters of aquaculture pond, and full pond uses, and interval uses one in 10-15 days It is secondary.

Technical field

The present invention relates to water treatment fields more particularly to a kind of Novel pollution-free water purification agent prescription and preparation method thereof.

Background technique

It is greatly developing aquatic products high-density breeding, industrial aquaculture and in fish transport, storage process, can often generate water The problem of middle oxygen-supplying amount wretched insufficiency and water quality degenerate, to cause fish dead due to suffocating and be poisoned.

The rapid corruption that residual bait is had meanwhile in culture fishery, in pond increases the ammonia nitrogen in water body, water quality Variation is frequent, such as heavy metal ion, disinfectant, insecticide residues, it is easy to allow aquatic livestock to cause stress reaction, to lead It is lethal to die.And these drugs gather residual in aquatic livestock body, and it can be to the further prevention and treatment of aquatic animal disease and the mankind Food safety and health bring new hidden danger.The aqueous solution of existing water purification agent is in strong basicity, and improper use will will cause fish Class is dead, while its auxiliary agent, using harmful substances such as manganese dioxide, potassium permanganate, they can remain in fish body, to eater Cause secondary pollution.

Although all there is noxious material residual, dissolution currently, there is some cleansers for being used for water process when aquaculture The problems such as oxygen concentration is low, and sterilization is not thorough.Therefore it provides it is a kind of efficiently quickly, effectively prevent secondary pollution, bactericidal effect it is good, The water quality cleansing agent for aquaculture pond that dissolved oxygen concentration realizes high yielding culture is improved, is that field scientific research technical staff is anxious One of important problem to be solved.

Summary of the invention

The present invention provides a kind of Novel pollution-free water purification agent prescription and preparation method thereof, solve existing net in background technique Aqua causes in fishes and shrimps body noxious material accumulation, forms that secondary pollution, oxygen in water concentration is low, sterilization there are noxious material It is not thorough, a series of problems such as breeding efficiency is low.

Specific technical solution is as follows:

A kind of Novel pollution-free water purification agent prescription, including following component and its parts by weight: 50-60 parts of water-soluble silicon, in 40-50 parts of herb extracts, 7-9 parts of magnesium silicate, 9-12 parts of active carbon, 15-18 parts of sulfate, 5-7 parts of sodium chlorate, ammonium hydrogen carbonate 2-7 parts, 1-5 parts of chlorine dioxide, 5-8 parts of aluminium polychloride, 3-6 parts of chitin, 10-14 parts of polymer phosphate ferro-aluminum.

Preferably, the water purification agent prescription preferred embodiment are as follows: 55 parts of water-soluble silicon, 45 parts of Chinese herbal medicine extract, magnesium silicate 8 Part, 9 parts of active carbon, 16 parts of sulfate, 6 parts of sodium chlorate, 4 parts of ammonium hydrogen carbonate, 3 parts of chlorine dioxide, 6 parts of aluminium polychloride, crust 4 parts, 11 parts of polymer phosphate ferro-aluminum of element.

Preferably, the sulfate is one of aluminum sulfate, ferric sulfate, calcium sulfate, sodium sulphate or a variety of.

Preferably, the water-soluble silicon is to extract high-grade silica by 1650 DEG C of -2000 DEG C of high-temperature physics Method persistently burns the element silicon ingredient of the gasification obtained as above arrived in moxibustion 8 hours.

Preferably, the Chinese herbal medicine extract pressed by geranium wilfordii, great Ye, frutus cnidii, pumpkin seeds, the root of Beijing euphorbia, Celastrus angulatus, hardship Ginseng, Chinese torreyanut, radix bupleuri, granatum, Chinese ash, morning glory, phoenix-tail fern, cortex acanthopanacis, Radix Glycyrrhizae composition, the production method of Chinese herbal medicine extract Are as follows: said herbal medicine plus water are rinsed, cut into pieces, 40~80 mesh are crushed to, the impurity in medicinal material is removed, adds water to cook 8- 12h；At a temperature of 80 DEG C~95 DEG C, 2 hours are concentrated to get Chinese herbal medicine extract.

A kind of preparation method of Novel pollution-free water purification agent prescription, includes the following steps:

(1) sulfate, water-soluble silicon, ammonium hydrogen carbonate, chitin are mixed in deionized water solution, stirs 6- at room temperature 9h；Then ultrasonic disperse is carried out using electromagnetic acoustic device, the power of the ultrasonic disperse is 900-1000W, jitter time 2h, Obtain mixed solution；

(2) above-mentioned mixed solution is mixed with the Chinese herbal medicine extract of corresponding number and sodium chlorate, then at 70-85 DEG C Heating stirring 4-5h, pressure 0.6-0.9MPa, is then gradually warmed up, and continues to stir 6-7h, mixed liquor is made to cool；

(3) it when the mixed liquor in step (2) cools to 28 DEG C, places it in enamel reaction still, then to it Middle addition magnesium silicate, active carbon, chlorine dioxide, start stirring, and aluminium polychloride and polymer phosphate ferro-aluminum are added while stirring, Stirring 30-40 minutes, discharging obtains water purification agent after standing 6-8h.

Preferably, the step (2) carries out under vacuum nitrogen gas atmosphere.

Preferably, it is used according to the water purification agent that every 1-1.5 meters of 1000 square metres of depth of water of aquaculture pond is added 500 grams -750 grams Amount, full pond use, and are spaced 10-15 days using primary.

The utility model has the advantages that

1. by 1650 DEG C of -2000 DEG C of high-temperature physics extraction methods, persistently to burn moxibustion 8 small by high-grade silica by the present invention When the gasification obtained as above arrived element silicon ingredient made from water-soluble silicon, water-soluble silicon, which is dissolved into water, can produce Sasser, from And effectively dissolve the impurity in water, while increasing the concentration of dissolved oxygen, sufficient oxygen is provided, the growth hair of fishes and shrimps is conducive to It educates.

2. raw material is carried out ultrasonic disperse using electromagnetic acoustic device by the present invention, dispersion degree and the atom oscillation of raw material are improved Frequency can be uniformly distributed in water when being contacted with water, and rate of playing effectiveness is fast, can improve water quality rapidly, be protected Water holding body is stablized.

3. the present invention is mixed using Chinese herbal medicine extract and water-soluble silicon with other raw materials, can without noxious material Effectively sterilization, is safe from harm to fishes and shrimps, effectively prevent secondary pollution, while toxic action will not be generated to human body, highly-safe.

4. can effectively inhibit the excessive multiplication of Measures of Algae in Water Body after applying water purification agent of the present invention, improve breeding water body Eutrophic state has remarkable result to cultivating system water environment is repaired, and can build for the highly efficient and productive cultivation of prawn good Water area ecological environment, promote fishes and shrimps growth improve fishes and shrimps quality.

Specific embodiment