阅读说明：本技术 一种环保快速改性醇洗净剂 (Environment-friendly quick-modification alcohol detergent ) 是由 何国锐 于 2021-09-13 设计创作，主要内容包括：本发明公开了一种环保快速改性醇洗净剂,本发明涉及清洗剂技术领域,其技术方案是：包括原料和辅料,所述原料(按重量计)包括：水40g～50g、改性甲醇20g～24g、乙醇8g～10g、二氯甲烷4g～6g、三氯乙烷2g～6g、三氯乙烯2g～8g、丙酮6g～8g、氢氧化钠4g～6g、烷基苯磺酸钠2g～4g、三乙醇胺2g～4g,所述辅料(按重量计)包括：非离子表面活性剂8g～10g、增稠剂4g～12g、稳定剂8g～10g、耐热剂14g～16g、二甲苯磺酸钠4g～6g、焦磷酸钾2g～6g,一种环保快速改性醇洗净剂有益效果是：通过二氯甲烷、三氯乙烷、三氯乙烯、丙酮、氢氧化钠、烷基苯磺酸钠、三乙醇胺、二甲苯磺酸钠、焦磷酸钾,具有提高洗净剂的洗涤效果。(The invention discloses an environment-friendly quick-modification alcohol cleaning agent, which relates to the technical field of cleaning agents and adopts the technical scheme that: the compound feed comprises raw materials and auxiliary materials, wherein the raw materials (by weight) comprise: 40 g-50 g of water, 20 g-24 g of modified methanol, 8 g-10 g of ethanol, 4 g-6 g of dichloromethane, 2 g-6 g of trichloroethane, 2 g-8 g of trichloroethylene, 6 g-8 g of acetone, 4 g-6 g of sodium hydroxide, 2 g-4 g of sodium alkyl benzene sulfonate and 2 g-4 g of triethanolamine, wherein the auxiliary materials (by weight) comprise: 8-10 g of nonionic surfactant, 4-12 g of thickener, 8-10 g of stabilizer, 14-16 g of heat-resistant agent, 4-6 g of sodium xylene sulfonate and 2-6 g of potassium pyrophosphate, and the environment-friendly rapidly-modified alcohol detergent has the beneficial effects that: the washing effect of the cleaning agent is improved by dichloromethane, trichloroethane, trichloroethylene, acetone, sodium hydroxide, sodium alkyl benzene sulfonate, triethanolamine, sodium xylene sulfonate and potassium pyrophosphate.)

1. An environment-friendly fast-modified alcohol cleaning agent comprises raw materials and auxiliary materials, and is characterized in that: the raw materials (by weight) comprise: 40 g-50 g of water, 20 g-24 g of modified methanol, 8 g-10 g of ethanol, 4 g-6 g of dichloromethane, 2 g-6 g of trichloroethane, 2 g-8 g of trichloroethylene, 6 g-8 g of acetone, 4 g-6 g of sodium hydroxide, 2 g-4 g of sodium alkyl benzene sulfonate and 2 g-4 g of triethanolamine, wherein the auxiliary materials (by weight) comprise: 8-10 g of nonionic surfactant, 4-12 g of thickening agent, 8-10 g of stabilizer, 14-16 g of heat-resistant agent, 4-6 g of sodium xylene sulfonate and 2-6 g of potassium pyrophosphate.

2. The environmentally friendly rapidly modifying alcohol detergent composition as claimed in claim 1, wherein: the nonionic surfactant is one or more of fatty alcohol-polyoxyethylene ether, polyoxyethylene sorbitan fatty acid ester and polyglycerol fatty acid ester.

3. The environmentally friendly rapidly modifying alcohol detergent composition as claimed in claim 1, wherein: the thickener is one or more of organic bentonite, diatomite and attapulgite clay.

4. The environmentally friendly rapidly modifying alcohol detergent composition as claimed in claim 1, wherein: the stabilizer is one or a mixture of more of calcium stearate, zinc stearate and nontoxic phosphite ester.

5. The environmentally friendly rapidly modifying alcohol detergent composition as claimed in claim 1, wherein: the heat-resistant agent is one or a mixture of more of organic silicon, perfluoropolyether, diatomite and silicon rubber.

6. The environmentally friendly rapidly modifying alcohol detergent composition as claimed in claim 1, wherein: the preparation method comprises the following specific steps:

s1, adding water, modified methanol and ethanol into a reaction kettle, stirring, and then adding dichloromethane into the reaction kettle, and stirring to obtain a mixture A;

s2, adding trichloroethane and trichloroethylene into the reaction kettle, stirring, and then adding acetone into the reaction kettle, stirring to obtain a mixture B;

s3, adding sodium hydroxide and sodium alkyl benzene sulfonate into a reaction kettle for stirring, and after stirring, adding triethanolamine into the reaction kettle for stirring to obtain a mixture C;

s4, adding sodium xylene sulfonate and potassium pyrophosphate into a reaction kettle, and stirring to obtain a mixture D;

s5, placing the mixture A, the mixture B, the mixture C and the mixture D into a reaction kettle, and stirring to obtain a mixture E;

s6, putting the mixture E and the heat-resistant agent into a reaction kettle, and stirring to obtain a mixture F;

s7, putting the mixture F, the nonionic surfactant, the thickening agent and the stabilizing agent into a reaction kettle, and stirring to obtain a mixture G;

s8, the mixture G is allowed to stand and is allowed to cool naturally, thereby obtaining a detergent.

7. The environmentally friendly rapidly modifying alcohol detergent composition as claimed in claim 6, wherein: in the step S1, the stirring temperature without adding dichloromethane is 45-50 ℃, the stirring time is 60-66 min, the stirring temperature after adding dichloromethane is 50-60 ℃, and the stirring time is 70-80 min.

8. The environmentally friendly rapidly modifying alcohol detergent composition as claimed in claim 6, wherein: in the step S2, the stirring temperature without adding acetone is 60-70 ℃, the stirring time is 55-60 min, the stirring temperature with adding acetone is 60-65 ℃, and the stirring time is 70-80 min.

9. The environmentally friendly rapidly modifying alcohol detergent composition as claimed in claim 6, wherein: in the step S3, the stirring temperature without adding triethanolamine is 70-80 ℃, the stirring time is 62-66 min, the stirring temperature after adding triethanolamine is 75-80 ℃, and the stirring time is 50-70 min.

10. The environmentally friendly rapidly modifying alcohol detergent composition as claimed in claim 6, wherein: in the step S4, the stirring time and temperature are 110-120 ℃, and the stirring time is 45-55 min;

in the step S5, the stirring time and temperature is 420-440 ℃, and the stirring time is 50-55 min;

in the step S6, the stirring time and temperature are 440-460 ℃, and the stirring time is 40-50 min;

in the step S7, the stirring time and temperature are 450-470 ℃, and the stirring time is 60-70 min.

Technical Field

The invention relates to the technical field of cleaning agents, and particularly relates to an environment-friendly quickly-modified alcohol cleaning agent.

Background

The cleaning agent is a large category and various types, including inorganic cleaning and organic cleaning, and the difference between the organic cleaning agent and the inorganic cleaning agent is that the organic cleaning agent is a cleaning agent made of a carbon-containing compound, and the inorganic cleaning agent is a cleaning agent made of a carbon-free compound, so that the organic cleaning agent and the inorganic cleaning agent belong to inorganic matters, the classification methods of the cleaning agents are various and different from each country, and the cleaning agents are generally classified into three types, namely water-based cleaning agent, semi-water-based cleaning agent and non-water-based cleaning agent, and the industrial cleaning agents are chemical or biological agents used in industry for removing dirt and are collectively called industrial cleaning agents.

The prior art has the following defects: the existing industrial cleaning agent is not environment-friendly and has poor cleaning effect.

Therefore, the invention is necessary to develop an environment-friendly quick-modifying alcohol detergent.

Disclosure of Invention

Therefore, the invention provides an environment-friendly quick modified alcohol cleaning agent, which is prepared by selecting water, modified methanol, ethanol, dichloromethane, trichloroethane, trichloroethylene, acetone, sodium hydroxide, sodium alkyl benzene sulfonate and triethanolamine as raw materials, selecting a nonionic surfactant, a thickening agent, a stabilizer, a heat-resistant agent, sodium xylene sulfonate and potassium pyrophosphate as auxiliary materials and then proportioning according to a certain proportion, so as to solve the problems that the existing industrial cleaning agent is not environment-friendly and has poor cleaning effect.

In order to achieve the above purpose, the invention provides the following technical scheme: an environment-friendly fast-modified alcohol cleaning agent comprises raw materials and auxiliary materials, wherein the raw materials (by weight) comprise: 40 g-50 g of water, 20 g-24 g of modified methanol, 8 g-10 g of ethanol, 4 g-6 g of dichloromethane, 2 g-6 g of trichloroethane, 2 g-8 g of trichloroethylene, 6 g-8 g of acetone, 4 g-6 g of sodium hydroxide, 2 g-4 g of sodium alkyl benzene sulfonate and 2 g-4 g of triethanolamine, wherein the auxiliary materials (by weight) comprise: 8-10 g of nonionic surfactant, 4-12 g of thickening agent, 8-10 g of stabilizer, 14-16 g of heat-resistant agent, 4-6 g of sodium xylene sulfonate and 2-6 g of potassium pyrophosphate.

Preferably, the nonionic surfactant is one or a mixture of fatty alcohol-polyoxyethylene ether, polyoxyethylene sorbitan fatty acid ester and polyglycerol fatty acid ester.

Preferably, the thickener is one or a mixture of more of organic bentonite, diatomite and attapulgite clay.

Preferably, the stabilizer is one or a mixture of more of calcium stearate, zinc stearate and nontoxic phosphite ester.

Preferably, the heat-resistant agent is one or a mixture of more of organosilicon, perfluoropolyether, diatomite and silicone rubber.

Preferably, the preparation method comprises the following specific steps:

s1, adding water, modified methanol and ethanol into a reaction kettle, stirring, and then adding dichloromethane into the reaction kettle, and stirring to obtain a mixture A;

s2, adding trichloroethane and trichloroethylene into the reaction kettle, stirring, and then adding acetone into the reaction kettle, stirring to obtain a mixture B;

s3, adding sodium hydroxide and sodium alkyl benzene sulfonate into a reaction kettle for stirring, and after stirring, adding triethanolamine into the reaction kettle for stirring to obtain a mixture C;

s4, adding sodium xylene sulfonate and potassium pyrophosphate into a reaction kettle, and stirring to obtain a mixture D;

s5, placing the mixture A, the mixture B, the mixture C and the mixture D into a reaction kettle, and stirring to obtain a mixture E;

s6, putting the mixture E and the heat-resistant agent into a reaction kettle, and stirring to obtain a mixture F;

s7, putting the mixture F, the nonionic surfactant, the thickening agent and the stabilizing agent into a reaction kettle, and stirring to obtain a mixture G;

s8, the mixture G is allowed to stand and is allowed to cool naturally, thereby obtaining a detergent.

Preferably, in the step S1, the stirring temperature without adding dichloromethane is 45-50 ℃, the stirring time is 60-66 min, the stirring temperature after adding dichloromethane is 50-60 ℃, and the stirring time is 70-80 min.

Preferably, in the step S2, the stirring temperature without adding acetone is 60-70 ℃, the stirring time is 55-60 min, the stirring temperature with adding acetone is 60-65 ℃, and the stirring time is 70-80 min.

Preferably, in the step S3, the stirring temperature without adding triethanolamine is 70-80 ℃, the stirring time is 62-66 min, the stirring temperature after adding triethanolamine is 75-80 ℃, and the stirring time is 50-70 min.

Preferably, in the step S4, the stirring time and temperature are 110-120 ℃, and the stirring time is 45-55 min;

in the step S5, the stirring time and temperature is 420-440 ℃, and the stirring time is 50-55 min;

in the step S6, the stirring time and temperature are 440-460 ℃, and the stirring time is 40-50 min;

in the step S7, the stirring time and temperature are 450-470 ℃, and the stirring time is 60-70 min.

The invention has the beneficial effects that:

1. the modified methanol has the effect of improving the environmental protection of the cleaning agent;

2. the washing effect of the cleaning agent is improved by dichloromethane, trichloroethane, trichloroethylene, acetone, sodium hydroxide, sodium alkyl benzene sulfonate, triethanolamine, sodium xylene sulfonate and potassium pyrophosphate;

3. the heat-resistant agent has the effect of improving the low-temperature resistance of the detergent, thereby improving the application range of the detergent.

Detailed Description

The following description of the preferred embodiments of the present invention is provided for the purpose of illustration and description, and is in no way intended to limit the invention.

Example 1:

the invention provides an environment-friendly fast-modified alcohol cleaning agent, which comprises raw materials and auxiliary materials, wherein the raw materials (by weight) comprise: 40g of water, 20g of modified methanol, 8g of ethanol, 4g of dichloromethane, 2g of trichloroethane, 2g of trichloroethylene, 6g of acetone, 4g of sodium hydroxide, 2g of sodium alkyl benzene sulfonate and 2g of triethanolamine, wherein the auxiliary materials (by weight) comprise: 8g of nonionic surfactant, 4g of thickening agent, 8g of stabilizing agent, 14g of heat-resistant agent, 4g of sodium xylene sulfonate and 2g of potassium pyrophosphate.

Further, the nonionic surfactant is one or a mixture of fatty alcohol-polyoxyethylene ether, polyoxyethylene sorbitan fatty acid ester and polyglycerol fatty acid ester.

Further, the thickener is one or a mixture of more of organic bentonite, diatomite and attapulgite clay.

Further, the stabilizer is one or a mixture of more of calcium stearate, zinc stearate and nontoxic phosphite ester.

Further, the heat-resistant agent is one or a mixture of more of organic silicon, perfluoropolyether, diatomite and silicon rubber.

Further, the preparation method comprises the following specific steps:

s1, adding water, modified methanol and ethanol into a reaction kettle, stirring, adding dichloromethane into the reaction kettle, and stirring to obtain a mixture A, wherein the stirring temperature of the mixture A without dichloromethane is 45 ℃, the stirring time is 60min, the stirring temperature of the mixture A after dichloromethane is added is 50 ℃, and the stirring time is 70 min;

s2, adding trichloroethane and trichloroethylene into a reaction kettle, stirring, then adding acetone into the reaction kettle, and stirring to obtain a mixture B, wherein the stirring temperature without adding acetone is 60 ℃, the stirring time is 55min, and the stirring temperature with adding acetone is 60 ℃, and the stirring time is 70 min;

s3, adding sodium hydroxide and sodium alkyl benzene sulfonate into a reaction kettle, stirring, adding triethanolamine into the reaction kettle, and stirring to obtain a mixture C, wherein the stirring temperature of the mixture C without triethanolamine is 70 ℃, the stirring time is 62min, the stirring temperature of the mixture C after triethanolamine is added is 75 ℃, and the stirring time is 50 min;

s4, placing sodium xylene sulfonate and potassium pyrophosphate into a reaction kettle to be stirred, so as to obtain a mixture D, wherein the stirring time is 110 ℃, and the stirring time is 45 min;

s5, placing the mixture A, the mixture B, the mixture C and the mixture D into a reaction kettle, and stirring to obtain a mixture E, wherein the stirring time is 420 ℃ and 50 min;

s6, putting the mixture E and the heat-resistant agent into a reaction kettle, and stirring to obtain a mixture F, wherein the stirring time is 440 ℃, and the stirring time is 40 min;

s7, placing the mixture F, the nonionic surfactant, the thickening agent and the stabilizing agent into a reaction kettle, and stirring to obtain a mixture G, wherein the stirring time is 450 ℃ and 60 min;

s8, the mixture G is allowed to stand and is allowed to cool naturally, thereby obtaining a detergent.

Example 2:

the invention provides an environment-friendly fast-modified alcohol cleaning agent, which comprises raw materials and auxiliary materials, wherein the raw materials (by weight) comprise: 45g of water, 22g of modified methanol, 9g of ethanol, 5g of dichloromethane, 4g of trichloroethane, 5g of trichloroethylene, 7g of acetone, 5g of sodium hydroxide, 3g of sodium alkyl benzene sulfonate and 3g of triethanolamine, wherein the auxiliary materials (by weight) comprise: 9g of nonionic surfactant, 8g of thickening agent, 9g of stabilizing agent, 15g of heat-resistant agent, 5g of sodium xylene sulfonate and 4g of potassium pyrophosphate.

Further, the nonionic surfactant is one or a mixture of fatty alcohol-polyoxyethylene ether, polyoxyethylene sorbitan fatty acid ester and polyglycerol fatty acid ester.

Further, the thickener is one or a mixture of more of organic bentonite, diatomite and attapulgite clay.

Further, the stabilizer is one or a mixture of more of calcium stearate, zinc stearate and nontoxic phosphite ester.

Further, the heat-resistant agent is one or a mixture of more of organic silicon, perfluoropolyether, diatomite and silicon rubber.

Further, the preparation method comprises the following specific steps:

s1, adding water, modified methanol and ethanol into a reaction kettle, stirring, adding dichloromethane into the reaction kettle, and stirring to obtain a mixture A, wherein the stirring temperature of the mixture A without dichloromethane is 47.5 ℃, the stirring time is 63min, the stirring temperature of the mixture A after dichloromethane is added is 55 ℃, and the stirring time is 75 min;

s2, adding trichloroethane and trichloroethylene into a reaction kettle, stirring, adding acetone into the reaction kettle, and stirring to obtain a mixture B, wherein the stirring temperature without adding acetone is 65 ℃, the stirring time is 57.5min, the stirring temperature with adding acetone is 62.5 ℃, and the stirring time is 75 min;

s3, adding sodium hydroxide and sodium alkyl benzene sulfonate into a reaction kettle, stirring, adding triethanolamine into the reaction kettle, and stirring to obtain a mixture C, wherein the stirring temperature of the mixture C without triethanolamine is 75 ℃, the stirring time is 64min, the stirring temperature of the mixture C after triethanolamine is added is 77.5 ℃, and the stirring time is 60 min;

s4, placing sodium xylene sulfonate and potassium pyrophosphate into a reaction kettle to be stirred, so as to obtain a mixture D, wherein the stirring time is 115 ℃, and the stirring time is 50 min;

s5, placing the mixture A, the mixture B, the mixture C and the mixture D into a reaction kettle, and stirring to obtain a mixture E, wherein the stirring time is 430 ℃ and 52.5 min;

s6, putting the mixture E and the heat-resistant agent into a reaction kettle, and stirring to obtain a mixture F, wherein the stirring time is 450 ℃ and 45 min;

s7, placing the mixture F, the nonionic surfactant, the thickening agent and the stabilizing agent into a reaction kettle, and stirring to obtain a mixture G, wherein the stirring time is 460 ℃ and 65 min;

s8, the mixture G is allowed to stand and is allowed to cool naturally, thereby obtaining a detergent.

Example 3:

the invention provides an environment-friendly fast-modified alcohol cleaning agent, which comprises raw materials and auxiliary materials, wherein the raw materials (by weight) comprise: 50g of water, 24g of modified methanol, 10g of ethanol, 6g of dichloromethane, 6g of trichloroethane, 8g of trichloroethylene, 8g of acetone, 6g of sodium hydroxide, 4g of sodium alkyl benzene sulfonate and 4g of triethanolamine, wherein the auxiliary materials (by weight) comprise: 10g of nonionic surfactant, 12g of thickening agent, 10g of stabilizing agent, 16g of heat-resistant agent, 6g of sodium xylene sulfonate and 6g of potassium pyrophosphate.

Further, the nonionic surfactant is one or a mixture of fatty alcohol-polyoxyethylene ether, polyoxyethylene sorbitan fatty acid ester and polyglycerol fatty acid ester.

Further, the thickener is one or a mixture of more of organic bentonite, diatomite and attapulgite clay.

Further, the stabilizer is one or a mixture of more of calcium stearate, zinc stearate and nontoxic phosphite ester.

Further, the heat-resistant agent is one or a mixture of more of organic silicon, perfluoropolyether, diatomite and silicon rubber.

Further, the preparation method comprises the following specific steps:

s1, adding water, modified methanol and ethanol into a reaction kettle, stirring, adding dichloromethane into the reaction kettle, and stirring to obtain a mixture A, wherein the stirring temperature of the mixture A without dichloromethane is 50 ℃, the stirring time is 66min, the stirring temperature of the mixture A after dichloromethane is added is 60 ℃, and the stirring time is 80 min;

s2, adding trichloroethane and trichloroethylene into a reaction kettle, stirring, adding acetone into the reaction kettle, and stirring to obtain a mixture B, wherein the stirring temperature without adding acetone is 70 ℃, the stirring time is 60min, the stirring temperature with adding acetone is 65 ℃, and the stirring time is 80 min;

s3, adding sodium hydroxide and sodium alkyl benzene sulfonate into a reaction kettle, stirring, adding triethanolamine into the reaction kettle, and stirring to obtain a mixture C, wherein the stirring temperature of the mixture C without triethanolamine is 80 ℃, the stirring time is 66min, the stirring temperature of the mixture C after triethanolamine is added is 80 ℃, and the stirring time is 70 min;

s4, placing sodium xylene sulfonate and potassium pyrophosphate into a reaction kettle to be stirred, so as to obtain a mixture D, wherein the stirring time is 120 ℃, and the stirring time is 55 min;

s5, placing the mixture A, the mixture B, the mixture C and the mixture D into a reaction kettle, and stirring to obtain a mixture E, wherein the stirring time is 440 ℃, and the stirring time is 55 min;

s6, putting the mixture E and the heat-resistant agent into a reaction kettle, and stirring to obtain a mixture F, wherein the stirring time is 460 ℃ and the stirring time is 50 min;

s7, placing the mixture F, the nonionic surfactant, the thickening agent and the stabilizing agent into a reaction kettle, and stirring to obtain a mixture G, wherein the stirring time is 470 ℃ and 70 min;

s8, the mixture G is allowed to stand and is allowed to cool naturally, thereby obtaining a detergent.

The following data were obtained by comparing the detergents prepared in examples 1 to 3 above:

as can be seen from the above table, the cleaning agents prepared in examples 1 to 3 have better performances in terms of cleaning effect, heat resistance and environmental protection, but the cleaning agents have different effects in terms of cleaning effect, heat resistance and environmental protection due to different ratios of water, modified methanol, ethanol, dichloromethane, trichloroethane, trichloroethylene, acetone, sodium hydroxide, sodium alkylbenzenesulfonate, triethanolamine, nonionic surfactant, thickener, stabilizer, heat resistance, sodium xylene sulfonate and potassium pyrophosphate.

The above description is only a preferred embodiment of the present invention, and any person skilled in the art may modify the present invention or modify it into an equivalent technical solution by using the technical solution described above. Therefore, any simple modifications or equivalent substitutions made in accordance with the technical solution of the present invention are within the scope of the claims of the present invention.