阅读说明：本技术 一种环保型洗涤材料的配方及工艺 (Formula and process of environment-friendly washing material ) 是由 金德利 于 2021-08-16 设计创作，主要内容包括：本发明公开了一种环保型洗涤材料的配方,其原料按照质量份数包括表面活性剂65-75份、洗涤助剂3-8份、硅酸钠和硫酸钠的组合物2-5份、抗污垢再沉积剂5-8份、漂白剂0.5-1.0份、荧光增白剂0.3-0.5份、酶制剂1.0-1.5份、功能助剂2-3份、稳泡剂3-5份、抑泡剂2-4份、助溶剂8-15份以及溶剂35-45份；稳泡剂为月桂基二甲基氧化胺和豆蔻基二甲基氧化胺,抑泡剂为聚醚和硅油。本发明在同粘度下的稀释倍数破5,且能稳定发挥；保证洗涤能力的情况下具备高液态化的性能表现；搭配本发明的配方采用全喷雾混合成型,混合程度高溶解彻底,有利于打破悬浮,成型更好。(The invention discloses a formula of an environment-friendly washing material, which comprises the following raw materials, by mass, 65-75 parts of a surfactant, 3-8 parts of a washing assistant, 2-5 parts of a composition of sodium silicate and sodium sulfate, 5-8 parts of an anti-fouling redeposition agent, 0.5-1.0 part of a bleaching agent, 0.3-0.5 part of a fluorescent whitening agent, 1.0-1.5 parts of an enzyme preparation, 2-3 parts of a functional assistant, 3-5 parts of a foam stabilizer, 2-4 parts of a foam inhibitor, 8-15 parts of a cosolvent and 35-45 parts of a solvent; the foam stabilizer is lauryl dimethyl amine oxide and myristyl dimethyl amine oxide, and the foam inhibitor is polyether and silicone oil. The invention has the advantages that the dilution multiple is reduced by 5 under the same viscosity, and the stable performance can be realized; the performance of high liquidization is realized under the condition of ensuring the washing capacity; the formula of the invention is matched to adopt full-spray mixing forming, the mixing degree is high, the dissolution is thorough, the suspension breaking is facilitated, and the forming is better.)

1. The formula of the environment-friendly washing material is characterized in that the raw materials comprise, by mass, 65-75 parts of a surfactant, 3-8 parts of a washing assistant, 2-5 parts of a composition of sodium silicate and sodium sulfate, 5-8 parts of an anti-fouling redeposition agent, 0.5-1.0 part of a bleaching agent, 1.0-1.5 parts of an enzyme preparation, 2-3 parts of a functional assistant, 3-5 parts of a foam stabilizer, 2-4 parts of a foam inhibitor, 8-15 parts of a cosolvent and 35-45 parts of a solvent; the foam stabilizer is lauryl dimethyl amine oxide and myristyl dimethyl amine oxide, and the foam inhibitor is polyether and silicone oil.

2. The formulation of claim 1, wherein the surfactant is a combination of anionic surfactant and nonionic surfactant, and comprises sodium alkyl sulfonate, alkanolamide and polyether, and the ratio of sodium alkyl sulfonate, alkanolamide and polyether is 6:3: 1.

3. The formulation of claim 1, wherein the detergent builder is a phosphate compound; the phosphate compounds include potassium pyrophosphate, sodium hexametaphosphate, nitrilotriacetic acid, sodium polyacrylate and zeolite, wherein the nitrilotriacetic acid, the sodium polyacrylate and the zeolite are mixed substitutes of sodium tripolyphosphate, and the mixing ratio is 3:1: 2; the mixture ratio of potassium pyrophosphate, sodium hexametaphosphate, nitrilotriacetic acid, sodium polyacrylate and zeolite is 4:5: 6.

4. The formulation of claim 1, wherein the ratio of sodium silicate to sodium sulfate is 5:2, the pH of the formulation is maintained at 6.5-7.5, the functional additives comprise pH regulator, and the pH regulator is sodium carbonate according to the pH of the molded product.

5. The formulation of claim 1, wherein the soil redeposition resistant agent is sodium carboxymethyl cellulose; the bleaching agent is one of sodium perborate and sodium hypochlorite, and the sodium hypochlorite is used in textile industry and is added with a fluorescent whitening agent in a matching way, wherein the addition amount of the fluorescent whitening agent is 0.3-0.5 part.

6. The formulation of claim 1, wherein the enzyme preparation comprises protease, lipase, cellulase, amylase, cellulase and protease in the textile industry, and lipase and amylase in the food-related cleaning industry.

7. The formulation of claim 1, wherein the antistatic agent is one of dimethyl ammonium distearate and dimethyl octyl ammonium bromide stearate, and the softening agent is one of higher alcohol polyoxyethylene ether and amine oxide.

8. The formulation of claim 1, wherein the solvent is one of ethylene glycol, glycol ether, and tetrachloroethylene; the cosolvent is sodium toluene sulfonate.

9. The process for preparing the novel environment-friendly washing material is characterized by comprising the following steps of:

s1 material distinguishing; dividing raw materials of a washing material into a high-temperature resistant type and a non-high-temperature resistant type, wherein a surfactant and an enzyme preparation are divided into non-high-temperature resistant type materials, and firstly mixing the raw materials required by the surfactant and the enzyme preparation for later use;

s2 full spray forming; firstly, mixing a composition of sodium silicate and sodium sulfate, a bleaching agent, a fluorescent whitening agent, a functional assistant, a foam stabilizer and a cosolvent used in raw materials at 70-85 ℃, mixing and stirring to prepare a first batch of ingredients, cooling the slurry to 40 ℃, spraying the slurry in a spray form by using high tower hot air spray, spraying surfactant powder on the other side of the high tower, drying and mixing the two parts of materials in the high tower to obtain a mixed ingredient, and uniformly stirring and guiding out the mixed ingredient;

an S3 formulation; adding a solvent into the mixed ingredients obtained in the step S2 for multiple times, and uniformly stirring to obtain slurry, wherein the stirring condition is (60 +/-3) DEG C, and the concentration of the slurry is 60%; adding a washing assistant, an anti-fouling redeposition agent and a foam inhibitor into the obtained slurry, stirring and mixing uniformly to ensure that the cheongsam condition of the obtained mixed slurry is controlled below 3%;

adjusting the pH value of the S4 preparation; and (4) heating the mixed pulp obtained in the step (S3) to 40 ℃, adding sodium carbonate according to the pH value of the mixed pulp, adjusting the pH value of the mixed pulp to 6.5-7.5, adding an enzyme preparation into the mixed pulp, and uniformly stirring to finish the preparation.

10. The process of claim 9, wherein in the step of S2 full spray forming, the hot air blower is used to spray the material, the temperature in the tower is maintained at 130-150 ℃, and the temperature at the hot air nozzle of the first material is 300-320 ℃; the temperature at the hot air nozzle of the surfactant was 170-.

Technical Field

The invention relates to the field of cleaning products, in particular to a formula and a process of an environment-friendly washing material.

Background

Cleaning compositions, i.e., materials that alter the surface activity of water and enhance the soil removal performance of soils on the surface of an object being cleaned, include synthetic detergents and soaps, sometimes collectively referred to as detergents. The concept of stain removal is very broad, and stain removal in daily life mainly refers to stain removal of clothes, which is the most important function of washing products. Washing of household utensils, tableware, fruits and vegetables is also referred to as decontamination, but is conventionally referred to as cleaning, and the washing products used are referred to as detergents.

The detergent raw materials used at present are basically the following: surfactants, detergency builders, solvents and cosolvents, anti-soil redeposition agents, bleaching and optical brighteners, antistatic and softening agents, enzyme preparations, stabilisers and suds suppressors. The combination of the raw materials can obtain the synthetic detergent, and the main problems of the synthetic detergent at present are low active matter content, high content of non-effective components, low proportion of concentrated and liquid products and the like.

In the formula and the process disclosed at present, the invention relates to the invention for improving the ratio of the concentrated liquid state to the concentrated liquid state, for example, the invention discloses CN201710877936.6 'a low-viscosity super-concentrated fruit-vegetable tableware detergent composition and a preparation method thereof', the components of a surfactant are optimized in the formula of the invention, the low viscosity and the high fluidity are achieved, and the obtained detergent has better liquefaction degree; for example, "a concentrated dish washing detergent" disclosed in publication No. CN201611070045.1, is constructed to be a stable highly concentrated detergent and to raise its viscosity after dilution. The two inventions are the same in concept and application field, betaine is adopted in the component of the surfactant, the betaine has low irritation and belongs to an amphoteric surfactant, so that the cleaning in the catering field is more suitable, but actually, the surfactant needs to be compounded by adding other active agents (mostly nonionic surfactants) or defoaming agents and defoaming components to ensure low foaming and high concentration so as to ensure liquidity and high concentration, the cleaning power is poor, and the single dosage is still larger. According to the data provided by the two inventions, the data which can be achieved by the two inventions are 3 times of detergency and 4 times of concentration stability, the first invention does not refer to specific data on the concentration stability, and the two inventions lack certain measurement on the viscosity (fluidity/liquidization), and the formula of the two inventions is obviously insufficient.

Disclosure of Invention

The invention aims to solve the defects of high concentration stability and poor liquidity of a detergent in the prior art, and provides a formula of an environment-friendly washing material and a process for preparing the novel environment-friendly washing material.

In order to achieve the purpose, the invention adopts the following technical scheme:

the formula of the environment-friendly washing material comprises the following raw materials, by mass, 65-75 parts of a surfactant, 3-8 parts of a washing assistant, 2-5 parts of a composition of sodium silicate and sodium sulfate, 5-8 parts of an anti-fouling redeposition agent, 0.5-1.0 part of a bleaching agent, 0.3-0.5 part of a fluorescent whitening agent, 1.0-1.5 parts of an enzyme preparation, 2-3 parts of a functional assistant, 3-5 parts of a foam stabilizer, 2-4 parts of a foam inhibitor, 8-15 parts of a cosolvent and 35-45 parts of a solvent; the foam stabilizer is lauryl dimethyl amine oxide and myristyl dimethyl amine oxide, and the foam inhibitor is polyether and silicone oil.

Preferably, the surfactant is a compound of an anionic surfactant and a nonionic surfactant, and comprises sodium alkyl sulfonate, alkanolamide and polyether, and the ratio of the sodium alkyl sulfonate to the alkanolamide to the polyether is 6:3: 1.

Preferably, the washing assistant is phosphate compound; the phosphate compounds include potassium pyrophosphate, sodium hexametaphosphate, nitrilotriacetic acid, sodium polyacrylate and zeolite, wherein the nitrilotriacetic acid, the sodium polyacrylate and the zeolite are mixed substitutes of sodium tripolyphosphate, and the mixing ratio is 3:1: 2; the mixture ratio of potassium pyrophosphate, sodium hexametaphosphate, nitrilotriacetic acid, sodium polyacrylate and zeolite is 4:5: 6.

Preferably, the ratio of the sodium silicate to the sodium sulfate is 5:2, the pH value of the formula is maintained to be 6.5-7.5, the functional auxiliary agent comprises a pH value regulator, and the pH value regulator is sodium carbonate according to different pH values of formed products.

Preferably, the anti-soil redeposition agent is sodium carboxymethyl cellulose; the bleaching agent is one of sodium perborate and sodium hypochlorite, and the sodium hypochlorite is used in textile industry and is added with a fluorescent whitening agent in a matching way, wherein the addition amount of the fluorescent whitening agent is 0.3-0.5 part.

Preferably, the enzyme preparation comprises protease, lipase, cellulase, amylase, cellulase and protease are used in the textile industry, and lipase and amylase are used in food related cleaning.

Preferably, the antistatic agent is one of dimethyl ammonium distearate and dimethyl octyl ammonium bromide stearate, and the softening agent is one of higher alcohol polyoxyethylene ether and amine oxide.

Preferably, the solvent is one of ethylene glycol, glycol ether and tetrachloroethylene; the cosolvent is sodium toluene sulfonate.

The process of producing environment friendly detergent material includes the following steps: s1 material distinguishing; dividing raw materials of a washing material into a high-temperature resistant type and a non-high-temperature resistant type, wherein a surfactant and an enzyme preparation are divided into non-high-temperature resistant type materials, and firstly mixing the raw materials required by the surfactant and the enzyme preparation for later use; s2 full spray forming; firstly, mixing a composition of sodium silicate and sodium sulfate, a bleaching agent, a fluorescent whitening agent, a functional assistant, a foam stabilizer and a cosolvent used in raw materials at 70-85 ℃, mixing and stirring to prepare a first batch of ingredients, cooling the slurry to 40 ℃, spraying the slurry in a spray form by using high tower hot air spray, spraying surfactant powder on the other side of the high tower, drying and mixing the two parts of materials in the high tower to obtain a mixed ingredient, and uniformly stirring and guiding out the mixed ingredient; an S3 formulation; adding a solvent into the mixed ingredients obtained in the step S2 for multiple times, and uniformly stirring to obtain slurry, wherein the stirring condition is (60 +/-3) DEG C, and the concentration of the slurry is 60%; adding a washing assistant, an anti-fouling redeposition agent and a foam inhibitor into the obtained slurry, stirring and mixing uniformly to ensure that the cheongsam condition of the obtained mixed slurry is controlled below 3%; adjusting the pH value of the S4 preparation; and (4) heating the mixed pulp obtained in the step (S3) to 40 ℃, adding sodium carbonate according to the pH value of the mixed pulp, adjusting the pH value of the mixed pulp to 6.5-7.5, adding an enzyme preparation into the mixed pulp, and uniformly stirring to finish the preparation.

Preferably, in the step of S2 full spray forming, a hot air blower is adopted to spray the materials, the temperature in the tower is kept at 130-150 ℃, and the temperature at the hot air nozzle of the first batch of materials is kept at 300-320 ℃; the temperature at the hot air nozzle of the surfactant was 170-.

Compared with the prior art, the invention has the beneficial effects that:

(1) the sodium alkylsulfonate, alkanolamide and polyether are used as surfactants, lauryl dimethyl amine oxide and myristyl dimethyl amine oxide are used as foam stabilizers, and polyether and silicone oil are used as foam inhibitors, so that active ingredients of the detergent can be improved, a stable environment can be provided, the dilution multiple can be conveniently improved, the dilution multiple under the same viscosity can be reduced by 5, and the stable performance can be realized;

(2) the combination of sodium silicate and sodium sulfate and the combination of potassium pyrophosphate and sodium hexametaphosphate are adopted, so that the fluidity of the detergent is improved as much as possible under the condition of ensuring the washing capacity, and the detergent has high liquidization performance under the condition of high concentration;

(3) the formula of the invention is matched to adopt full-spray mixing forming, the mixing degree is high, the dissolution is thorough, the suspension breaking is facilitated, and the forming is better.

Drawings

FIG. 1 is a table of formulations of the scrubbing material of the present invention;

fig. 2 is a test chart of a product one, a product two, and a product three.

Detailed Description

The technical solution of the present invention will be clearly and completely described below with reference to specific embodiments.

FIG. 1 is a table of formulations of the detergent materials of the present invention, as follows:

firstly, the overall formula of the invention is as follows: the formula of the environment-friendly washing material comprises, by mass, 65-75 parts of a surfactant, 3-8 parts of a washing assistant, 2-5 parts of a composition of sodium silicate and sodium sulfate, 5-8 parts of an anti-fouling redeposition agent, 0.5-1.0 part of a bleaching agent, 0.3-0.5 part of a fluorescent whitening agent, 1.0-1.5 parts of an enzyme preparation, 2-3 parts of a functional assistant, 3-5 parts of a foam stabilizer, 2-4 parts of a foam inhibitor, 8-15 parts of a cosolvent and 35-45 parts of a solvent.

The formula (I) needs to firstly and specifically explain two types of components, namely a surfactant, a foam stabilizer and a foam inhibitor, which can greatly influence the washing effect, and the combined application of the foam stabilizer, the foam inhibitor and the surfactant component is one of means for improving the washing effect as far as possible under the condition of ensuring that the viscosity is not changed

The surfactant is amphiphilic molecules with both oleophilic and hydrophilic parts in chemical structure, can be adsorbed on a two-phase interface, is in monomolecular arrangement to reduce the surface tension of a solution, and is called as surface activity, and a substance with the surface activity is called as a surfactant; briefly, such compositions are used in detergents to break the surface protective layer of the laundry, allowing the detergent composition to function to displace the stains to be washed. In the prior art, the defect that the active matters are few exists, and the problem of insufficient washing caused by that the washed matters can not fully contact with stains occurs naturally; in view of the problem, the great application of betaine in the prior art is to solve the problem, which is an excellent amphoteric surfactant, but firstly, betaine cannot be well applied to industrial washing, and secondly, although the application range of betaine is wide, the cleaning power is low and the foam stabilizing effect can be achieved, so that the foam inhibitor is required to have proper strength, the preparation difficulty is high, and the obtained material has no advantage in viscosity maintenance.

In response to this problem, the present invention defines the surfactant and the foam stabilizer and foam inhibitor: the surfactant is a compound of an anionic surfactant and a nonionic surfactant, and comprises sodium alkyl sulfonate, alkanolamide and polyether, wherein the ratio of the sodium alkyl sulfonate to the alkanolamide to the polyether is 6:3: 1; the foam stabilizer is lauryl dimethyl amine oxide and myristyl dimethyl amine oxide, and the foam inhibitor is polyether and silicone oil.

The sodium alkyl sulfonate is an anionic surfactant, the alkanolamide and the polyether are nonionic surfactants, the two substances are compounded to form a compound surfactant with strong applicability, the polyether has a good defoaming effect, and the compound surfactant and the sodium alkyl sulfonate can form a good defoaming effect; on the basis, the mixture of lauryl dimethyl amine oxide and myristyl dimethyl amine oxide has an oxide structure which can well act with polyether, and the defoaming and foam inhibiting effects are stably realized. The sodium alkyl sulfonate and the alkanolamide are not only strong active agent combinations, wherein the alkanolamide is also a foam stabilizer, and the alkanolamide (the foam stabilizer) and the polyether (the foam inhibitor) are simultaneously mixed in the nonionic surfactant to form an environment with little foam, stability and high activity, so that the washing materials can be well exerted, the washing force is high, and the difficulty degree of adjusting the viscosity is greatly reduced.

In addition to the above, the actions of the ingredients in the above formulation are further illustrated and defined.

The washing assistant is phosphate compound; the phosphate compounds include potassium pyrophosphate, sodium hexametaphosphate, nitrilotriacetic acid, sodium polyacrylate and zeolite, wherein the nitrilotriacetic acid, the sodium polyacrylate and the zeolite are mixed substitutes of sodium tripolyphosphate, and the mixing ratio is 3:1: 2; the mixture ratio of potassium pyrophosphate, sodium hexametaphosphate, nitrilotriacetic acid, sodium polyacrylate and zeolite is 4:5: 6.

Sodium hexametaphosphate, molecular formula (NaPO)₃)₆(ii) a The pH value of the aqueous solution of sodium hexametaphosphate is close to 7, the aqueous solution has little irritation to the skin, the aqueous solution also has the effect of preventing corrosion when the concentration is higher, and the aqueous solution has good complexing ability to calcium and magnesium ions in neutral and alkalescent solutions, and the components are mainly applied to industrial environment to play the role of protecting equipment and products.

Potassium pyrophosphate, molecular formula: k₄P₂O₇(ii) a Has complexing ability to metal ions such as calcium, magnesium and the like and also has certain washing assisting effect, and the component and sodium hexametaphosphate can form advantage complementation on hygroscopicity.

Phosphate compounds are commonly used as sodium tripolyphosphate, but the components are eliminated year by year, so organic chelates (nitrilotriacetic acid which seals metal ions in chelating agent molecules through chelation to soften water), polyelectrolyte (sodium polyacrylate which can be adsorbed on the surface of a washed object and the surface of dirt, increases electrostatic repulsion between the washed object and the dirt, is beneficial to removing the dirt, can increase the dispersing capacity of the dirt, and prevents the dirt from redepositing) and a molecular sieve (zeolite which softens hard water and adsorbs eluted dirt) are adopted to replace the sodium tripolyphosphate. The three components are combined to simultaneously play roles in softening water and adsorbing dirt, can well replace sodium tripolyphosphate in strength, and is environment-friendly.

The ratio of the sodium silicate to the sodium sulfate is 5:2, the pH value of the formula is maintained at 6.5-7.5, the functional auxiliary agent comprises a pH value regulator, and the pH value regulator is sodium carbonate according to different pH values of molded products. Since industrial detergents are not substantially strongly acidic detergents which are highly irritating in order to protect products and equipment, it is necessary to adjust the pH in consideration of the fact that sodium carbonate is used to adjust the pH and the enzyme preparation is allowed to survive after the addition.

(III) necessity of sodium silicate and sodium sulfate; sodium silicate is commonly called water glass or sodium silicate and has a molecular formula of Na₂O·nSiO₂·xH₂O; the granular solid or viscous aqueous solution has a buffering effect on the pH value of the solution, and the colloidal solution generated by hydrolysis has a dispersing effect on solid dirt particles and an emulsifying effect on oil stains; the sodium sulfate is white crystal or powder, so that the surface adsorption amount of the anionic surfactant can be increased (the activity performance of the anionic surfactant is improved) and micelle is formed in the solution, so that the surface tension of the washing solution is reduced, the effects of wetting, decontamination and the like are facilitated, the viscosity of the feed liquid can be reduced, the liquefaction degree of a finished product is improved by matching with the sodium silicate, and the washing capacity can be improved.

The following components are more common, and the following components are used in consideration of no conflict with the components of the former part of the present invention.

The anti-soil redeposition agent is sodium carboxymethyl cellulose (CMC); the bleaching agent is one of sodium perborate and sodium hypochlorite, and the sodium hypochlorite is used in textile industry and is added with a fluorescent whitening agent in a matching way, wherein the addition amount of the fluorescent whitening agent is 0.3-0.5 part. It is worth mentioning that PVP is superior to CMC in terms of its combination with surfactants, but is of limited optimization and is cost-prohibitive, and therefore CMC is still more suitable, but PVP is also under consideration in the present formulation.

The enzyme preparation comprises protease, lipase, cellulase and amylase, wherein the cellulase and protease are used in textile industry, and the lipase and amylase are used in food-related cleaning.

The antistatic agent is one of distearic acid dimethyl ammonium chloride and stearic acid dimethyl octyl ammonium bromide, and the softening agent is one of higher alcohol polyoxyethylene ether and amine oxide.

The solvent is one of glycol, glycol ether and tetrachloroethylene; the cosolvent is sodium toluene sulfonate.

The process of producing environment friendly detergent material includes the following steps: s1 material distinguishing; dividing raw materials of a washing material into a high-temperature resistant type and a non-high-temperature resistant type, wherein a surfactant and an enzyme preparation are divided into non-high-temperature resistant type materials, and firstly mixing the raw materials required by the surfactant and the enzyme preparation for later use; s2 full spray forming; firstly, mixing a composition of sodium silicate and sodium sulfate, a bleaching agent, a fluorescent whitening agent, a functional assistant, a foam stabilizer and a cosolvent used in raw materials at 70-85 ℃, mixing and stirring to prepare a first batch of ingredients, cooling the slurry to 40 ℃, spraying the slurry in a spray form by using high tower hot air spray, spraying surfactant powder on the other side of the high tower, drying and mixing the two parts of materials in the high tower to obtain a mixed ingredient, and uniformly stirring and guiding out the mixed ingredient; an S3 formulation; adding a solvent into the mixed ingredients obtained in the step S2 for multiple times, and uniformly stirring to obtain slurry, wherein the stirring condition is (60 +/-3) DEG C, and the concentration of the slurry is 60%; adding a washing assistant, an anti-fouling redeposition agent and a foam inhibitor into the obtained slurry, stirring and mixing uniformly to ensure that the cheongsam condition of the obtained mixed slurry is controlled below 3%; adjusting the pH value of the S4 preparation; and (4) heating the mixed pulp obtained in the step (S3) to 40 ℃, adding sodium carbonate according to the pH value of the mixed pulp, adjusting the pH value of the mixed pulp to 6.5-7.5, adding an enzyme preparation into the mixed pulp, and uniformly stirring to finish the preparation.

In the step of S2 full spray forming, a hot air blower is adopted to spray out the materials, the temperature in the tower is kept at 130-150 ℃, and the temperature at the hot air nozzle of the first batch of materials is 300-320 ℃; the temperature at the hot air nozzle of the surfactant was 170-.

In the aspect of the process, full spray forming is mainly adopted, so that the mixing degree and the drying degree of raw materials can be improved, and the dissolving speed and the dissolving proportion of the raw materials entering a solvent are improved; it should be noted that, in terms of PH adjustment, adjustment must be performed first and then enzyme is added, so that the process tolerance rate is higher.

The above ratios are all good ratios obtained by experiments, and are not explained here.

The above formulation concept is illustrated by the following examples.

Example one

The formula of the environment-friendly washing material comprises the following raw materials, by mass, 65 parts of a surfactant, 3 parts of a washing assistant, 2 parts of a composition of sodium silicate and sodium sulfate, 5 parts of an anti-fouling redeposition agent, 0.5 part of a bleaching agent, 0.3 part of a fluorescent whitening agent, 1 part of an enzyme preparation, 2 parts of a functional assistant, 3 parts of a foam stabilizer, 2 parts of a foam inhibitor, 8 parts of a cosolvent and 35 parts of a solvent; the foam stabilizer is lauryl dimethyl amine oxide and myristyl dimethyl amine oxide, and the foam inhibitor is polyether and silicone oil.

In this embodiment, the surfactant is a complex of an anionic surfactant and a nonionic surfactant, and includes sodium alkyl sulfonate, alkanolamide and polyether, and the ratio of the sodium alkyl sulfonate, the alkanolamide and the polyether is 6:3: 1.

In this embodiment, the washing aid is a phosphate-based compound; the phosphate compounds include potassium pyrophosphate, sodium hexametaphosphate, nitrilotriacetic acid, sodium polyacrylate and zeolite, wherein the nitrilotriacetic acid, the sodium polyacrylate and the zeolite are mixed substitutes of sodium tripolyphosphate, and the mixing ratio is 3:1: 2; the mixture ratio of potassium pyrophosphate, sodium hexametaphosphate, nitrilotriacetic acid, sodium polyacrylate and zeolite is 4:5: 6.

In this example, the ratio of sodium silicate to sodium sulfate is 5:2, the PH of the formulation is maintained at 6.5-7.5, and the functional additives include PH modifiers, which are sodium carbonate according to the PH of the molded product.

In this example, the anti-soil redeposition agent is sodium carboxymethyl cellulose; the bleaching agent is sodium perborate.

In this example, the enzyme preparation comprises protease, lipase, cellulase, amylase, cellulase and protease are used in the textile industry and lipase and amylase are used in food related cleaning.

In this example, the antistatic agent is dimethyl ammonium distearate and the softening agent is amine oxide.

In this example, the solvent is ethylene glycol; the cosolvent is sodium toluene sulfonate.

According to the process steps of the invention described above, a finished product one is obtained.

Example two

The formula of the environment-friendly washing material comprises the following raw materials, by mass, 75 parts of a surfactant, 8 parts of a washing assistant, 5 parts of a composition of sodium silicate and sodium sulfate, 8 parts of an anti-fouling redeposition agent, 1.0 part of a bleaching agent, 0.5 part of a fluorescent whitening agent, 1.5 parts of an enzyme preparation, 3 parts of a functional assistant, 5 parts of a foam stabilizer, 4 parts of a foam inhibitor, 15 parts of a cosolvent and 45 parts of a solvent; the foam stabilizer is lauryl dimethyl amine oxide and myristyl dimethyl amine oxide, and the foam inhibitor is polyether and silicone oil.

In this embodiment, the surfactant is a complex of an anionic surfactant and a nonionic surfactant, and includes sodium alkyl sulfonate, alkanolamide and polyether, and the ratio of the sodium alkyl sulfonate, the alkanolamide and the polyether is 6:3: 1.

In this embodiment, the washing aid is a phosphate-based compound; the phosphate compounds include potassium pyrophosphate, sodium hexametaphosphate, nitrilotriacetic acid, sodium polyacrylate and zeolite, wherein the nitrilotriacetic acid, the sodium polyacrylate and the zeolite are mixed substitutes of sodium tripolyphosphate, and the mixing ratio is 3:1: 2; the mixture ratio of potassium pyrophosphate, sodium hexametaphosphate, nitrilotriacetic acid, sodium polyacrylate and zeolite is 4:5: 6.

In this example, the ratio of sodium silicate to sodium sulfate is 5:2, the PH of the formulation is maintained at 6.5-7.5, and the functional additives include PH modifiers, which are sodium carbonate according to the PH of the molded product.

In this example, the anti-soil redeposition agent is sodium carboxymethyl cellulose; the bleaching agent is sodium perborate.

In this example, the enzyme preparation comprises protease, lipase, cellulase, amylase, cellulase and protease are used in the textile industry and lipase and amylase are used in food related cleaning.

In this example, the antistatic agent is dimethyl octyl ammonium bromide stearate and the softening agent is amine oxide.

In this example, the solvent is tetrachloroethylene; the cosolvent is sodium toluene sulfonate.

According to the process steps of the invention, the finished product II is obtained.

EXAMPLE III

The formula of the environment-friendly washing material comprises the following raw materials, by mass, 70 parts of a surfactant, 5 parts of a washing assistant, 4 parts of a composition of sodium silicate and sodium sulfate, 6 parts of an anti-fouling redeposition agent, 0.8 part of a bleaching agent, 0.4 part of a fluorescent whitening agent, 1.2 parts of an enzyme preparation, 2.5 parts of a functional assistant, 4 parts of a foam stabilizer, 3 parts of a foam inhibitor, 12 parts of a cosolvent and 40 parts of a solvent; the foam stabilizer is lauryl dimethyl amine oxide and myristyl dimethyl amine oxide, and the foam inhibitor is polyether and silicone oil.

In this embodiment, the surfactant is a complex of an anionic surfactant and a nonionic surfactant, and includes sodium alkyl sulfonate, alkanolamide and polyether, and the ratio of the sodium alkyl sulfonate, the alkanolamide and the polyether is 6:3: 1.

In this embodiment, the washing aid is a phosphate-based compound; the phosphate compounds include potassium pyrophosphate, sodium hexametaphosphate, nitrilotriacetic acid, sodium polyacrylate and zeolite, wherein the nitrilotriacetic acid, the sodium polyacrylate and the zeolite are mixed substitutes of sodium tripolyphosphate, and the mixing ratio is 3:1: 2; the mixture ratio of potassium pyrophosphate, sodium hexametaphosphate, nitrilotriacetic acid, sodium polyacrylate and zeolite is 4:5: 6.

In this example, the ratio of sodium silicate to sodium sulfate is 5:2, the PH of the formulation is maintained at 6.5-7.5, and the functional additives include PH modifiers, which are sodium carbonate according to the PH of the molded product.

In this example, the anti-soil redeposition agent is sodium carboxymethyl cellulose; the bleaching agent is sodium perborate.

In this example, the enzyme preparation comprises protease, lipase, cellulase, amylase, cellulase and protease are used in the textile industry and lipase and amylase are used in food related cleaning.

In this embodiment, the antistatic agent is dimethyl ammonium distearate, and the softening agent is higher alcohol polyoxyethylene ether.

In this embodiment, the solvent is a glycol ether; the cosolvent is sodium toluene sulfonate.

According to the process steps of the invention, finished product three is obtained.

With respect to the technical effect of the present invention, in addition to the foregoing explanation, the three products were first subjected to a cleaning test involving a cleaning power and a dilution factor at an equivalent viscosity, which is determined by a flowability balance.

Refer to fig. 2. The cleaning ability is measured according to the standard that the quantity of the metal articles and the textiles which can be cleaned thoroughly under the same dosage in the industrial cleaning process is measured according to the standard that insoluble substances do not remain on the surfaces of the cleaned objects, new stains are not generated, new covering layers harmful to subsequent processes are not formed, and the quality of products is not influenced, and the parameters are obtained by reference to GB 38508-2020.

It can be seen that the dilution factor is kept at 5.5 times basically, 4 can be stably exerted on industrial cleaning, and the data is better, so that the formula idea of the invention is correct and even advanced.

Exemplary embodiments of the proposed solution of the present disclosure have been described in detail above with reference to preferred embodiments, however, it will be understood by those skilled in the art that many variations and modifications may be made to the specific embodiments described above, and that many combinations of the various technical features and structures presented in the present disclosure may be made without departing from the concept of the present disclosure, without departing from the scope of the present disclosure, which is defined by the appended claims.