阅读说明：本技术 一种防护服面料的制备方法 (Preparation method of protective clothing fabric ) 是由 楼力峰 杨奋理 陶武彪 于 2020-05-08 设计创作，主要内容包括：本发明公开了一种防护服面料的制备方法,它依次包括塑炼、混炼、混炼胶破碎、胶浆制备、涂布以及硫化工序,其中混炼过程中氟橡胶、丁腈橡胶、丁基橡胶以及氯磺化聚乙烯橡胶按照各自相应的配方进行混炼,待胶浆制备完成后再进行多次反复的涂布操作,经硫化后,最后完成成品面料的制备。虽然本发明制备的防护服面料的厚度只有0.45—0.5mm,但是经过第三方检测,它具有足够可靠的防护能力,能够适应各种复杂的化学污染环境,因此具有良好的市场应用前景。(The invention discloses a preparation method of protective clothing fabric, which sequentially comprises the working procedures of plastication, mixing, rubber compound crushing, rubber cement preparation, coating and vulcanization, wherein fluororubber, nitrile rubber, butyl rubber and chlorosulfonated polyethylene rubber are mixed according to respective corresponding formulas in the mixing process, repeated coating operation is carried out for many times after the rubber cement preparation is finished, and the preparation of finished fabric is finally finished after vulcanization. Although the thickness of the protective clothing fabric prepared by the invention is only 0.45-0.5 mm, the protective clothing fabric has sufficient and reliable protective capability through third-party detection, can adapt to various complex chemical pollution environments, and therefore has good market application prospect.)

1. A preparation method of protective clothing fabric is characterized by comprising the following steps:

a. plasticating fluororubber, nitrile rubber, butyl rubber and chlorosulfonated polyethylene rubber;

b. and (2) kneading, namely kneading the plasticated rubbers respectively, wherein:

adding magnesium oxide, white carbon black, benzyl tribasic phosphorus chloride, bisphenol AF and coumarone into the plasticated fluororubber for mixing to prepare fluororubber mixed rubber, wherein the fluororubber mixed rubber comprises the following components in parts by weight: 100 parts of fluororubber, 3-5 parts of magnesium oxide, 40-50 parts of white carbon black, 0.5-1 part of benzyl tribasic phosphorus chloride, 10-15 parts of bisphenol AF and 3-8 parts of coumarone;

adding zinc oxide, stearic acid, argil, tetramethyl thiuram disulfide, N-cyclohexyl-2-benzothiazole sulfonamide and sulfur into the plasticated nitrile rubber, mixing and preparing nitrile rubber compound, wherein the weight parts of the nitrile rubber compound are respectively as follows: 100 parts of nitrile rubber, 4-6 parts of zinc oxide, 0.5-2 parts of stearic acid, 48-55 parts of pottery clay, 0.3-1 part of tetramethyl thiuram disulfide, 0.8-2 parts of N-cyclohexyl-2-benzothiazole sulfonamide and 1-2 parts of sulfur;

adding zinc oxide, stearic acid, argil, tetramethylthiuram disulfide, 2' -dithiodibenzothiazyl, sulfur and chlorinated paraffin into the plasticated butyl rubber, mixing and preparing a butyl rubber compound, wherein the weight parts of the butyl rubber compound are as follows: 100 parts of butyl rubber, 4-6 parts of zinc oxide, 0.8-2 parts of stearic acid, 18-25 parts of pottery clay, 0.8-1.5 parts of tetramethyl thiuram disulfide, 1-2 parts of 2, 2' -dithiodibenzothiazole, 1-3 parts of sulfur and 30-35 parts of chlorinated paraffin;

adding magnesium oxide, stearic acid, mica powder, white carbon black, dipentamethylenethiuram tetrasulfide, sulfur and zinc borate into the plasticated chlorosulfonated polyethylene rubber for mixing to prepare chlorosulfonated polyethylene rubber compound, wherein the weight parts of the chlorosulfonated polyethylene rubber compound are respectively as follows: 100 parts of chlorosulfonated polyethylene rubber, 4-6 parts of magnesium oxide, 0.8-2 parts of stearic acid, 18-22 parts of mica powder, 0.8-2 parts of white carbon black, 1-2 parts of dipentaerythritol tetrasulfide, 1-3 parts of sulfur and 28-35 parts of zinc borate;

c. crushing the rubber compound, and respectively cutting the compounded fluororubber rubber compound, butyronitrile rubber compound, butyl rubber compound and chlorosulfonated polyethylene rubber compound into particles with the particle size of less than or equal to 5 cm;

d. and (3) preparing mucilage, namely respectively dissolving the crushed particles in an organic solvent, wherein:

dissolving the fluororubber mixed rubber in acetone according to the weight part ratio of 1.2:1 to prepare fluororubber mixed rubber slurry;

dissolving the butyronitrile rubber compound in acetone according to the weight part ratio of 1.5:1 to prepare butyronitrile rubber compound slurry;

dissolving the butyl rubber compound in solvent gasoline according to the weight portion ratio of 0.9:1 to prepare butyl rubber compound slurry;

dissolving chlorosulfonated polyethylene rubber compound in toluene according to the weight ratio of 1:1 to prepare chlorosulfonated polyethylene rubber compound slurry;

e. coating, namely coating at least one layer of each mucilage on the base cloth, and respectively heating and drying each layer of the mucilage to obtain a composite layer blank;

f. and (3) vulcanizing, namely putting the composite layer blank in an environment with the temperature of 150-180 ℃ and the vulcanization pressure of 40-60kg/cm2 for vulcanization reaction for 5-8min to obtain the finished fabric.

2. The method for preparing the fabric for the protective clothing according to claim 1, which is characterized in that: in the step (b), the step (c),

the parts by weight of the fluororubber and the compounding agent are respectively as follows: 100 parts of fluororubber, 3 parts of magnesium oxide, 45 parts of white carbon black, 0.8 part of benzyl tribasic phosphorus chloride, 12 parts of bisphenol AF and 5 parts of coumarone;

the nitrile rubber and the compounding agent respectively comprise the following components in parts by weight: 100 parts of nitrile rubber, 5 parts of zinc oxide, 1 part of stearic acid, 50 parts of pottery clay, 0.5 part of tetramethyl thiuram disulfide, 1 part of N-cyclohexyl-2-benzothiazole sulfonamide and 1.5 parts of sulfur;

the butyl rubber and the compounding agent respectively comprise the following components in parts by weight: 100 parts of butyl rubber, 5 parts of zinc oxide, 1 part of stearic acid, 20 parts of pottery clay, 1 part of tetramethyl thiuram disulfide, 1.5 parts of 2, 2' -dithiodibenzothiazole, 1.5 parts of sulfur and 30 parts of chlorinated paraffin;

the chlorosulfonated polyethylene rubber and the compounding agent respectively comprise the following components in parts by weight: 100 parts of chlorosulfonated polyethylene rubber, 5 parts of magnesium oxide, 1 part of stearic acid, 20 parts of mica powder, 1 part of white carbon black, 1.5 parts of dipentaerythritol tetrasulfide, 1.5 parts of sulfur and 30 parts of zinc borate.

3. The method for preparing the fabric for the protective clothing according to claim 2, characterized in that: and e, coating at least one layer of each adhesive cement on the front surface of the base cloth.

4. The method for preparing the fabric for the protective clothing according to claim 2, characterized in that: and e, respectively coating at least one layer of the adhesive cement on the front surface and the back surface of the base cloth.

5. The method for preparing the fabric for the protective clothing according to claim 4, characterized in that: the front surface of the base cloth is coated with a layer of fluororubber mixing rubber cement, two layers of butyronitrile mixing rubber cement, two layers of butyl mixing rubber cement and two layers of chlorosulfonated polyethylene mixing rubber cement from inside to outside in sequence; coating a layer of fluororubber mixing rubber cement, two layers of butyronitrile mixing rubber cement, two layers of butyl mixing rubber cement and two layers of chlorosulfonated polyethylene mixing rubber cement on the back surface of the base cloth from inside to outside in sequence; and the coating thickness of each mucilage is 0.01-0.02 mm.

6. The method for preparing the fabric for the protective clothing according to claim 5, which is characterized in that: before coating, a bridging agent is added into the fluororubber mixing rubber cement in a weight ratio of 5: 1.

7. The method for preparing a fabric for protective clothing according to any one of claims 1 to 6, characterized in that: before step f, spraying rubber release agent on the front and back surfaces of the composite layer blank prepared in step e.

8. The method for preparing the fabric for the protective clothing according to claim 1, which is characterized in that: in step f, the vulcanization temperature is 170 ℃, the vulcanization pressure is 50kg/cm2, and the time lasts for 5-8 min.

9. The method for preparing the fabric for the protective clothing according to claim 1, which is characterized in that: the base cloth is polyester fiber.

Technical Field

The invention relates to the field of fire fighting, in particular to a preparation method of protective clothing fabric with reliable protective capability in a multi-chemical polluted environment.

Background

With the increasing development of economic activities in China, the chemical industry is used as an important economic support in China, the production, transportation, storage and use of hazardous chemicals are more and more frequent, and the demand of the fields of social production and labor protection on chemical protective clothing is huge. In addition to the demand for chemical protective clothing in the production link, the demand for chemical protective clothing in military, fire fighting, public security and other national forces for maintaining the safety and stability of social order has also increased explosively in recent years.

Military and civil integration is an important policy advocated by the current army equipment procurement. 3000 sets of high-end airtight chemical protective clothing are tendered to the society by a certain department of the military in the early 2017, the purchase price of each set is 4 ten thousand yuan, the total purchase amount is 1.2 million yuan, but the tendered three military industry enterprise products cannot meet the requirements of bidding technical documents, so that the tendered tender is caused, and the reason of the tender is related to the quality of the chemical protective clothing fabric.

For decades, domestic fire-fighting enterprises can only produce low-end chemical protective clothing of PVC class, and only deal with the protection of acid-base chemicals. Before the standard of national fire-fighting protective clothing is forcibly implemented, the products enter fire-fighting rescue teams through various channels of mixed fish and dragon beads, and great potential safety hazards are brought to dangerous chemical rescue work. In recent years, national reference is made to international general standards, a series of standards such as GB 245639-. After the accident of 'serious explosion of Tianjin hazardous chemicals' in 2015, the fire department of the Ministry of public Security decides to forcibly implement '3C' of public security fire-fighting equipment, and supervises the Shanghai fire-fighting research institute of the Ministry of public Security to check the production and sale of all chemical protective clothing, and all products must meet the requirements specified by GA770-2008 firefighter chemical protective clothing. In the future, products which do not have detection reports of the detection center of Shanghai fire research institute are not allowed to be distributed in the market. In the early 2017, Shanghai fire research institute detection center of the Ministry of public Security officials formally begins to receive product submission of enterprises. As the production technology of the protective clothing fabric is not available, no domestic enterprise checks the protective clothing by oneself so far.

The market disorder becomes normal after all, foreign chemical protection related enterprises begin to arrange early, and the initial material processing is changed into the direct investment production of protective clothing fabric in China. The Kandi Tek group in Germany is beginning to invest in Suzhou, Jiangsu to produce chemical-proof adhesive tapes to supply several brand of fire-fighting protective clothing abroad.

The technical approaches of the chemical protective clothing fabric currently produced in China mainly include a PVC calendering and compounding technology of common civil enterprises and a butyl rubber calendering and compounding and vulcanizing technology of military enterprises. Because the PVC material has poor chemical stability, poor corrosion resistance and extremely low chemical permeation resistance, the PVC material cannot meet the requirement of hazardous chemical protection and can only be used as low-end acid-base chemical protective clothing. The PVC protective clothing fabric has low technical content, and enterprises engaged in the production of the products are all located in Jiangzhe and Zhejiang areas. In addition, the PVC adhesive tape is hardened at low temperature, and the prepared chemical protective clothing can hardly be used in winter in the north.

The military protective clothing for military in China is prepared by calendering and compounding butyl rubber on base cloth, and then performing pot-type vulcanization and batch production. The calendering method for producing a thin adhesive tape has very high requirements for the precision of equipment and the experience of production technicians, otherwise the thickness of the product is easily uneven. Even if this factor is eliminated, calendered tapes present a number of technically insurmountable drawbacks: the hand feeling is stiff; the protection time is short; the adhesive strength between the adhesive layer and the base cloth is low, and the like. The adhesive tape that adopts the pot-type to vulcanize need spill a large amount of talcum powders at the adhesive tape surface cloth for preventing that the adhesive tape from adhering to each other in vulcanization process, and the talcum powder adhesion is on the adhesive tape surface layer, seriously influences the appearance quality of adhesive tape, and causes the talcum powder to fly upward when using, seriously influences the respiratory tract health of personnel of dress.

In addition, according to the permeation principle of dangerous chemicals, a chemical permeation channel is easily generated in a single-layer calendered adhesive tape product due to the molecular aggregation of sizing materials, the protection time is short, in addition, the protection object is single, the high temperature is difficult to resist, the low-temperature environment is difficult to adapt to, once the environmental temperature reaches 100 ℃, the protection performance is greatly reduced, or the surface of the protective clothing is melted or damaged, and the protective clothing is difficult to resist to a high-temperature fire field. At low temperatures, protective clothing becomes stiff and is prone to yielding damage.

Disclosure of Invention

The invention provides a preparation method of protective clothing fabric, and aims to solve the problems of low protective reliability and poor adaptability of the protective clothing fabric in the prior art.

In order to achieve the purpose, the technical scheme provided by the invention is as follows:

a preparation method of protective clothing fabric comprises the following steps:

a. plasticating fluororubber, nitrile rubber, butyl rubber and chlorosulfonated polyethylene rubber;

b. and (2) kneading, namely kneading the plasticated rubbers respectively, wherein:

adding magnesium oxide, white carbon black, benzyl tribasic phosphorus chloride, bisphenol AF and coumarone into the plasticated fluororubber for mixing to prepare fluororubber mixed rubber, wherein the fluororubber mixed rubber comprises the following components in parts by weight: 100 parts of fluororubber, 3-5 parts of magnesium oxide, 40-50 parts of white carbon black, 0.5-1 part of benzyl tribasic phosphorus chloride, 10-15 parts of bisphenol AF and 3-8 parts of coumarone;

adding zinc oxide, stearic acid, argil, tetramethyl thiuram disulfide, N-cyclohexyl-2-benzothiazole sulfonamide and sulfur into the plasticated nitrile rubber, mixing and preparing nitrile rubber compound, wherein the weight parts of the nitrile rubber compound are respectively as follows: 100 parts of nitrile rubber, 4-6 parts of zinc oxide, 0.5-2 parts of stearic acid, 48-55 parts of pottery clay, 0.3-1 part of tetramethyl thiuram disulfide, 0.8-2 parts of N-cyclohexyl-2-benzothiazole sulfonamide and 1-2 parts of sulfur;

adding zinc oxide, stearic acid, argil, tetramethylthiuram disulfide, 2' -dithiodibenzothiazyl, sulfur and chlorinated paraffin into the plasticated butyl rubber, mixing and preparing a butyl rubber compound, wherein the weight parts of the butyl rubber compound are as follows: 100 parts of butyl rubber, 4-6 parts of zinc oxide, 0.8-2 parts of stearic acid, 18-25 parts of pottery clay, 0.8-1.5 parts of tetramethyl thiuram disulfide, 1-2 parts of 2, 2' -dithiodibenzothiazole, 1-3 parts of sulfur and 30-35 parts of chlorinated paraffin;

adding magnesium oxide, stearic acid, mica powder, white carbon black, dipentamethylenethiuram tetrasulfide, sulfur and zinc borate into the plasticated chlorosulfonated polyethylene rubber for mixing to prepare chlorosulfonated polyethylene rubber compound, wherein the weight parts of the chlorosulfonated polyethylene rubber compound are respectively as follows: 100 parts of chlorosulfonated polyethylene rubber, 4-6 parts of magnesium oxide, 0.8-2 parts of stearic acid, 18-22 parts of mica powder, 0.8-2 parts of white carbon black, 1-2 parts of dipentaerythritol tetrasulfide, 1-3 parts of sulfur and 28-35 parts of zinc borate;

c. crushing the rubber compound, and respectively cutting the compounded fluororubber rubber compound, butyronitrile rubber compound, butyl rubber compound and chlorosulfonated polyethylene rubber compound into particles with the particle size of less than or equal to 5 cm;

d. and (3) preparing mucilage, namely respectively dissolving the crushed particles in an organic solvent, wherein:

dissolving the fluororubber mixed rubber in acetone according to the weight part ratio of 1.2:1 to prepare fluororubber mixed rubber slurry;

dissolving the butyronitrile rubber compound in acetone according to the weight part ratio of 1.5:1 to prepare butyronitrile rubber compound slurry;

dissolving the butyl rubber compound in solvent gasoline according to the weight portion ratio of 0.9:1 to prepare butyl rubber compound slurry;

dissolving chlorosulfonated polyethylene rubber compound in toluene according to the weight ratio of 1:1 to prepare chlorosulfonated polyethylene rubber compound slurry;

e. coating, namely coating at least one layer of each mucilage on the base cloth, and respectively heating and drying each layer of the mucilage to obtain a composite layer blank;

f. and (3) vulcanizing, namely putting the composite layer blank in an environment with the temperature of 150-180 ℃ and the vulcanization pressure of 40-60kg/cm2 for vulcanization reaction for 5-8min to obtain the finished fabric.

In a preferred embodiment, in step b:

the parts by weight of the fluororubber and the compounding agent are respectively as follows: 100 parts of fluororubber, 3 parts of magnesium oxide, 45 parts of white carbon black, 0.8 part of benzyl tribasic phosphorus chloride, 12 parts of bisphenol AF and 5 parts of coumarone;

the nitrile rubber and the compounding agent respectively comprise the following components in parts by weight: 100 parts of nitrile rubber, 5 parts of zinc oxide, 1 part of stearic acid, 50 parts of pottery clay, 0.5 part of tetramethyl thiuram disulfide, 1 part of N-cyclohexyl-2-benzothiazole sulfonamide and 1.5 parts of sulfur;

the butyl rubber and the compounding agent respectively comprise the following components in parts by weight: 100 parts of butyl rubber, 5 parts of zinc oxide, 1 part of stearic acid, 20 parts of pottery clay, 1 part of tetramethyl thiuram disulfide, 1.5 parts of 2, 2' -dithiodibenzothiazole, 1.5 parts of sulfur and 30 parts of chlorinated paraffin;

the chlorosulfonated polyethylene rubber and the compounding agent respectively comprise the following components in parts by weight: 100 parts of chlorosulfonated polyethylene rubber, 5 parts of magnesium oxide, 1 part of stearic acid, 20 parts of mica powder, 1 part of white carbon black, 1.5 parts of dipentaerythritol tetrasulfide, 1.5 parts of sulfur and 30 parts of zinc borate.

In a preferred embodiment, in step e, the front surface of the base fabric is coated with at least one layer of each of the above-mentioned mucilages.

In a preferred embodiment, in step e, at least one layer of each of the above-mentioned mucilages is coated on the front surface and the back surface of the base fabric respectively.

In a recommended embodiment, the front surface of the base fabric is coated with a layer of fluororubber paste, two layers of nitrile-butadiene paste, two layers of butyl paste and two layers of chlorosulfonated polyethylene paste in this order from inside to outside; coating a layer of fluororubber mixing rubber cement, two layers of butyronitrile mixing rubber cement, two layers of butyl mixing rubber cement and two layers of chlorosulfonated polyethylene mixing rubber cement on the back surface of the base cloth from inside to outside in sequence; and the coating thickness of each mucilage is 0.01-0.02 mm.

In a preferred embodiment, the crosslinking agent is added to the fluororubber paste in a ratio of 5:1 parts by weight before coating.

In a preferred embodiment, before step f, the front and back sides of the composite layer blank prepared in step e are sprayed with a rubber release agent.

In a preferred embodiment, in step f, the vulcanization temperature is 170 ℃ and the vulcanization pressure is 50kg/cm2 for 5-8 min.

In a preferred embodiment, the base fabric is a polyester fiber.

Compared with the prior art, the technical scheme provided by the invention has the following beneficial effects:

1. the protective clothing is prepared by mixing fluororubber, nitrile rubber, butyl rubber and chlorosulfonated polyethylene rubber serving as main raw materials according to a corresponding formula, and preparing corresponding mucilage to coat the front and back surfaces of the base cloth layer by layer, so that the protective clothing is flame-retardant, resistant to high/low temperature, capable of preventing various chemical infiltrations, suitable for various complex chemical pollution environments and good in market application prospect.

2. The protective clothing fabric prepared by the invention has a reliable protective effect, the thickness of each adhesive layer coated on the base fabric is very small, and the thickness of the finished product fabric can be controlled to be about 0.45-0.5 mm which is far lower than the domestic standard of 0.8 mm. In addition, the weight per unit area of the protective clothing fabric is only about 620g/m2 through actual measurement, so that the clothing fabric does not have heavy wearing feeling.

3. According to the invention, the bridging agent is added before the coating of the fluororubber mixed paste, so that the adhesive force between the rubber and the base cloth is greatly enhanced, and the problem of degumming of the base cloth is avoided.

4. The product adopts a double-sided multilayer coating method, and has the following two main advantages:

structurally, double-sided coating is safer than single-sided coating. In the process of rescue work, scratch is inevitable to meet, if the front surface is scratched, the back surface can provide protection, and the safety is higher.

In terms of process, the multilayer coating process can also avoid structural defects or raw material impurity defects generated in a certain coating process, zero waste product production of 100% is achieved, and production cost is reduced.

Detailed Description

For further understanding of the present invention, the present invention will be described in detail with reference to examples, which are provided for illustration of the present invention but are not intended to limit the scope of the present invention.

First, this embodiment is a preferred embodiment of the present invention.

A preparation method of protective clothing fabric is characterized by comprising the following steps:

1. plasticating, namely plasticating the fluororubber, the nitrile rubber, the butyl rubber and the chlorosulfonated polyethylene rubber respectively, so that the raw rubber is changed into a plastic substance from an elastomer, and meanwhile, the uniform plasticity of the raw rubber can be prepared for subsequent mulling. The plastication temperature is generally 40-70 ℃ and the time is 10-20 min.

2. Mixing, namely mixing the fluororubber, the nitrile rubber, the butyl rubber and the chlorosulfonated polyethylene rubber according to the formula requirement. The purpose is to supplement various auxiliary agents into the raw rubber, so that the physical and chemical properties of the rubber compound meet the design requirements, the rubber compound meets the production process conditions of the rubber compound, and the rubber compound is convenient to produce. For example, the strengthening agent improves the strength, the plasticizer improves the flow and conforms to the hardness, the special auxiliary agent improves the resistivity and the flame retardant rate, and other auxiliary agents provide a good production process and the like.

The specific formula is as follows:

fluororubber formula (parts by mass)

Fluororubber	100	Magnesium oxide	3
				White carbon black	45	Benzyl tri-basic phosphorus chloride	0.8
Parts of bisphenol AF	12	Coumarone	5

Nitrile rubber formula (parts by mass)

Nitrile rubber	100	TMTD	0.5
				Zinc oxide	5	CZ	1
Stearic acid	1	Sulfur	1.5
				Argil	50

Butyl rubber formula (parts by mass)

Butyl rubber	100	TMTD	1
				Zinc oxide	5	DM	1.5
Stearic acid	1	Sulfur	1.5
				Argil	20	Chlorinated paraffin	30

Chlorosulfonated polyethylene (sea Polon) rubber formula (parts by mass)

Remarking: TMTD Tetramethylthiuram disulfide

CZ N-cyclohexyl-2-benzothiazolesulfenamide

DM 2, 2' -dithiodibenzothiazyl

DPTT dipentamethylenethiuram tetrasulfide

3. And crushing the rubber compound, and respectively cutting the compounded fluororubber rubber compound, butyronitrile rubber compound, butyl rubber compound and chlorosulfonated polyethylene rubber compound into particles with the particle diameter less than 5 centimeters. The main purpose is to facilitate the dissolution and the stirring and accelerate the dissolution speed.

4. And (3) preparing mucilage, namely respectively dissolving the crushed particles in respective organic solvents, wherein:

dissolving the fluororubber mixed rubber in acetone according to the weight part ratio of 1.2:1 to prepare acetone mixed rubber slurry;

dissolving the butyronitrile rubber compound in acetone according to the weight part ratio of 1.5:1 to prepare butyronitrile rubber compound slurry;

dissolving the butyl rubber compound in solvent gasoline according to the weight portion ratio of 0.9:1 to prepare butyl rubber compound slurry;

dissolving chlorosulfonated polyethylene rubber compound in toluene according to the weight ratio of 1:1 to prepare chlorosulfonated polyethylene rubber compound slurry;

5. and (4) filtering undissolved particles and impurities in the various mucilages obtained in the step (4) respectively, wherein the main purpose of filtering is to ensure that the obtained mucilages are uniform and ensure that the mucilage meets the requirements of coating (coating).

6. Adding a bridging agent into the fluororubber mixing mucilage in a weight ratio of 5:1, and uniformly stirring. Matching with the coumarone added in the mixing process. The combination of the two materials can ensure that the peeling strength of the interface between the base cloth and the rubber is as high as 2.3KN/m, the index of GA770-2008 firefighter chemical protective clothing is 0.78KN/m, and the test result is three times of the index value. If the bridging agent is completely sprayed, the higher peeling strength can be obtained, but the cost is very high because the bridging agent is expensive.

7. Coating, namely coating a layer of fluororubber mixed paste, two layers of butyronitrile mixed paste, two layers of butyl mixed paste and two layers of chlorosulfonated polyethylene mixed paste on a base fabric (polyester fibers with the thickness of 0.22mm are adopted in the embodiment) from inside to outside in sequence on the front surface; the back of the base cloth is coated with a layer of fluororubber mixing rubber cement, two layers of butyronitrile mixing rubber cement, two layers of butyl mixing rubber cement and two layers of chlorosulfonated polyethylene mixing rubber cement from inside to outside in sequence.

Specifically;

firstly, the front side of the base fabric is coated with the fluororubber mixing mucilage once, and the oven is heated and dried in a continuous step mode. The solvent in the mucilage is ensured to be volatilized as much as possible.

And secondly, coating the nitrile butadiene mixed rubber cement twice. The oven adopts continuous step-type heating and heating drying. The solvent in the mucilage is ensured to be volatilized as much as possible.

And thirdly, coating the mixture twice by using butyl mixing mucilage, and heating and drying the mixture. The adhesive tape is cooled by the cooling roller after coming out of the drying channel, so that the phenomenon of roller sticking of the adhesive tape is avoided.

And fourthly, coating the surface layer twice by adopting chlorosulfonated polyethylene rubber.

And fifthly, after the front surface of the base cloth is coated, the back surface of the base cloth is sequentially coated from the inner layer to the outer layer by adopting the same coating process.

In the embodiment, the thickness of each single coating of the adhesive cement layers is 0.02mm, the coating process is carried out in a coating device, and each coating is carried out in a continuous oven for heating and drying, wherein the heating temperature is 100 ℃, and the duration is 12 min. Thus, a composite layer blank is produced. It should be noted that, in the coating process of the coating device, the thickness of each coating is generally between 0.01-0.02 mm, and the thickness of each coating is not more than 0.02mm, otherwise, the flowing and thickness unevenness of the adhesive slurry are easily caused.

8. And (3) spraying a rubber release agent, and spraying the rubber release agent on the front side and the back side of the prepared composite layer blank. Preventing the adhesion between rubber and rubber.

9. And vulcanizing, namely vulcanizing the composite layer blank by adopting a drum vulcanizer, wherein the rubber surface is directly contacted with the stainless steel belt and the vulcanizing roller, and the vulcanized rubber fabric has soft and sanitary hand feeling on the surface, thereby thoroughly getting rid of the dirty, messy and poor images of the rubber fabric products produced by the pot vulcanization of the talcum powder. The specific process is as follows:

cleaning the vulcanizing roller and the steel belt of the vulcanizing machine.

Secondly, setting vulcanization parameters, wherein the vulcanization time is 5-8min, the vulcanization temperature is 170 ℃, and the vulcanization pressure is 50kg/cm 2. Waiting for the equipment to reach the vulcanization condition of the product.

And thirdly, the composite layer blank is flatly sent into a vulcanizing machine. The composite layer blank is contacted with the vulcanizing roller and the steel belt, and a fluorine release agent is adopted, so that the phenomena of rubber sticking to the roller and the steel belt are avoided.

Fourthly, obtaining the antichemical adhesive tape with clean appearance, uniform texture and good compactness after the vulcanization is finished.

Combining the steps, the protective clothing fabric can be produced, the protective clothing fabric is provided with 14 rubber layers on the front and back sides except the base cloth, the thickness of the rubber layers is only 0.5mm, and the rubber layers are arranged in unit areaThe weight of the powder is 630g/m². Physical and chemical tests on this product gave the following three tables:

table 1 shows the comparison between the test results and the standard values of the physical protection indexes of the finished fabric of the example:

table 2 shows the comparison of the measured results of the chemical permeability of the finished fabrics of the examples with the standard values

Chemical reagent	Test temperature	Mean penetration time (index)	Measured value
				Dimethyl sulfate	32℃±1℃	≥60min	≥120min
Ammonia gas	32℃±1℃	≥60min	≥120min
				Chlorine gas	32℃±1℃	≥60min	≥120min
Phosgene	32℃±1℃	≥60min	≥120min
				Hydrogen chloride	32℃±1℃	≥60min	≥120min
Hydrocyanic acid	32℃±1℃	≥60min	≥120min

Table 3 shows the comparison of the flame retardant property and the standard value of the finished fabric of the examples

	Measured value	Standard index
			Flaming combustion time(s)	≤5	≤10
Flameless combustion time(s)	≤5	≤10
			Damaged length (cm)	≤10	≤10

As can be seen from the table I, the fabric for the protective clothing prepared by the embodiment has excellent physical properties, and simultaneously has excellent heat resistance and cold resistance.

As can be seen from the table II, the protective clothing fabric permeates 6 main common toxic industrial chemicals, the protection time is not less than 60 minutes, and the chemical protection capability is good. In addition, as can be seen from the third table, the flame retardant property of the fabric of the protective clothing is also excellent.

In addition, the adhesive strength of the base cloth and the rubber reaches 2.3KN/m, so that the bonding force of the base cloth and the rubber is very large, and the problem of degumming of the base cloth and the rubber is basically avoided.

Example two

The second embodiment is basically the same as the first embodiment, and the main difference is that in the second embodiment, the mixture ratio of the added compounding agents is slightly changed during the mixing process of the four rubbers. The method comprises the following specific steps:

fluororubber formula (parts by mass)

Fluororubber	100	Magnesium oxide	3
				White carbon black	45	Benzyl tri-basic phosphorus chloride	0.8
Parts of bisphenol AF	12	Coumarone	4

Nitrile rubber formula (parts by mass)

Nitrile rubber	100	TMTD	0.3
				Zinc oxide	4	CZ	0.8
Stearic acid	0.5	Sulfur	1
				Argil	48

Butyl rubber formula (parts by mass)

Butyl rubber	100	TMTD	0.8
				Zinc oxide	4	DM	1
Stearic acid	0.8	Sulfur	1
				Argil	18	Chlorinated paraffin	32

Chlorosulfonated polyethylene (sea Polon) rubber formula (parts by mass)

Rubber of Syngnathus	100	White carbon black	0.8
				Magnesium oxide	4	DPTT	1
Stearic acid	0.8	Sulfur	1
				Mica powder	18	Zinc borate	28

The following three meters were obtained by physical and chemical tests of the second protective garment fabric of this example

Table 4 shows the comparison between the detection results of the physical protection indexes of the two-product fabric of the example and the standard values:

table 5 shows the comparison of the measured results of the chemical permeability of the fabrics of the two products of the examples with the standard values

Chemical reagent	Test temperature	Mean penetration time (index)	Measured value
				Dimethyl sulfate	32℃±1℃	≥60min	≥70
Ammonia gas	32℃±1℃	≥60min	≥70
				Chlorine gas	32℃±1℃	≥60min	≥70
Phosgene	32℃±1℃	≥60min	≥70
				Hydrogen chloride	32℃±1℃	≥60min	≥70
Hydrocyanic acid	32℃±1℃	≥60min	≥70

Table 6 shows the comparison between the flame retardant property and the standard value of the fabric of the two-product of the example

	Measured value	Standard index
			Flaming combustion time(s)	≤8	≤10
Flameless combustion time(s)	≤8	≤10
			Damaged length (cm)	≤10	≤10

The fabric of the protective clothing prepared in the second embodiment is basically the same as the fabric of the protective clothing prepared in the first embodiment, although the individual performance parameters are slightly increased or decreased, the individual performance parameters basically meet the industrial standards, but the comprehensive performance of the fabric is slightly inferior to that of the fabric of the protective clothing prepared in the first embodiment.

EXAMPLE III

The third embodiment is basically the same as the first embodiment, and the main difference is that in the third embodiment, the mixture ratio of the added compounding agents is slightly changed during the mixing process of the four rubbers. The method comprises the following specific steps:

fluororubber formula (parts by mass)

Fluororubber	100	Magnesium oxide	3
				White carbon black	32	Benzyl tri-basic phosphorus chloride	0.8
Parts of bisphenol AF	10	Coumarone	4

Nitrile rubber formula (parts by mass)

Butyl rubber formula (parts by mass)

Butyl rubber	100	TMTD	1.5
				Zinc oxide	6	DM	2
Stearic acid	2	Sulfur	3
				Argil	25	Chlorinated paraffin	35

Chlorosulfonated polyethylene (sea Polon) rubber formula (parts by mass)

Rubber of Syngnathus	100	White carbon black	2
				Magnesium oxide	6	DPTT	2
Stearic acid	2	Sulfur	3
				Mica powder	22	Zinc borate	35

The following three meters are obtained through physical and chemical tests of the three-proofing protective garment fabric of the embodiment

Table 7 shows the comparison between the test results and the standard values of the physical protection indexes of the fabrics of the three examples:

table 8 shows the comparison of the measured results of the chemical permeability of the fabrics of the three examples with the standard values

Table 9 shows the comparison between the flame retardant property and the standard value of the fabrics of the three products of examples

	Measured value	Standard index
			Flaming combustion time(s)	≤6	≤10
Flameless combustion time(s)	≤6	≤10
			Damaged length (cm)	≤10	≤10

The fabric of the protective clothing manufactured in the third embodiment is basically the same as the fabric of the protective clothing in the first embodiment, and although the individual performance parameters are slightly increased or decreased, the fabric of the protective clothing basically meets the industrial standard, the comprehensive performance of the fabric of the protective clothing is slightly inferior to that of the fabric of the protective clothing in the first embodiment.

Comparative example 1

Other steps and parameters are kept unchanged, step 6 in the first embodiment is removed, the peel strength of the base fabric and the rubber interface is as high as 0.8KN/m, which is slightly higher than 0.78KN/m which is an index of GA770-2008 firefighter chemical protective clothing, and the problem of degumming easily occurs during use.

Comparative example No. two

Other steps and parameters are kept unchanged, the coumarone in the formula of the fluororubber mixing is removed in the first embodiment, the peeling strength of the interface between the base cloth and the rubber is improved completely through the bridging agent, and the peeling strength is 1.5KN/m through actual tests, although the peeling strength is higher than the index of GA770-2008 firefighter chemical protective clothing, namely 0.78KN/m, but is smaller than the peeling strength achieved after the coumarone is added in the first embodiment, and in addition, the bridging agent is completely adopted, so the cost is higher.

Comparative example No. three

Other steps and parameters are kept unchanged, the proportion of the fluorine mixing rubber paste and the bridging agent in the step 6 of the embodiment is changed to 4:1, namely, the proportion of the fluorine mixing rubber paste is increased, and the peel strength is only 1.8KN/m and is obviously less than 1.8KN/m which is achieved when the proportion of the fluorine mixing rubber paste is 5:1 in the embodiment I.

Comparative example No. four

Other steps and parameters are kept unchanged, the proportion of the fluorine mixing rubber paste and the bridging agent in the step 6 of the embodiment is changed into 5:2, namely, the proportion of the bridging agent is increased, the peeling strength is only 2.2KN/m, and although the proportion of the bridging agent is increased, the peeling strength is not increased but is reduced to a certain extent.

The present invention has been described in detail with reference to the embodiments, but the description is only for the preferred embodiments of the present invention and should not be construed as limiting the scope of the present invention. All equivalent changes and modifications made within the scope of the present invention shall fall within the scope of the present invention.