White diamond glittering diamond glaze ceramic tile and preparation method thereof
阅读说明：本技术 一种白钻闪光金刚釉瓷砖及其制备方法 (White diamond glittering diamond glaze ceramic tile and preparation method thereof ) 是由 邓荣 林伟 刘畅 吴则昌 陈贤伟 欧阳文 于 2021-08-20 设计创作，主要内容包括：本发明公开了一种白钻闪光金刚釉瓷砖及其制备方法,包括由下至上依次复合的砖坯、底釉层、图案层、面釉白钻闪光层,所述面釉白钻闪光层采用面釉和白钻干粒混合而成,其比例为20：1,白钻干粒以重量份数计包括钾钠长石40～45份、堇青石20～30份、冰晶石7～12份、晶体粉5～8份。本发明制备的白钻干粒具有良好的光泽度,使得陶瓷砖表面可呈现出亮晶晶的闪光效果,有效提升金刚瓷砖的装饰效果。(The invention discloses a white diamond sparkling diamond glaze ceramic tile and a preparation method thereof, wherein the white diamond sparkling ceramic tile comprises a green brick, a ground glaze layer, a pattern layer and a surface glaze white diamond sparkling layer which are sequentially compounded from bottom to top, wherein the surface glaze white diamond sparkling layer is formed by mixing surface glaze and white diamond dry particles, and the proportion of the surface glaze white diamond sparkling layer is 20: the dry white diamond particles comprise, by weight, 40-45 parts of potash feldspar, 20-30 parts of cordierite, 7-12 parts of cryolite and 5-8 parts of crystal powder. The dry white diamond grains prepared by the method have good glossiness, so that the surface of the ceramic tile can show a glittering effect of brilliant crystals, and the decorative effect of the diamond ceramic tile is effectively improved.)
1. The utility model provides a white brill flash of light buddha's warrior attendant glaze ceramic tile which characterized in that: comprises a green brick, a ground glaze layer, a pattern layer and a surface glaze white diamond flashing layer which are sequentially compounded from bottom to top;
the surface glaze white diamond flashing layer is formed by mixing surface glaze and dry white diamond particles in a ratio of 20: 1, the chemical mass composition of the dry white diamond particles is as follows: SiO 22：45～55％，Al2O3：16～25％，K2O：1～2％，Na2O：6～12％，CaO：3～8.6％，MgO：1～2％，ZnO：0～1％；
The dry white diamond particles comprise, by weight, potash-sodalite: 40-45 parts of wollastonite: 5-6 parts of cordierite: 20-30 parts of quartz: 8-12 parts of alumina: 8-17 parts of cryolite: 7-12 parts of crystal powder: 5-8 parts.
2. The white diamond sparkling diamond glazed tile according to claim 1, wherein: the green brick comprises potassium albite and sodalite in parts by weight: 30-46 parts of kaolin: 25-28 parts of talc sand: 2-8 parts of mixed mud: 12-15 parts of sodium aluminum sand: 4-8 parts.
3. The white diamond sparkling diamond glazed tile according to claim 1, wherein: the ground coat comprises the following components in parts by weight: 20-25 parts of zirconium silicate: 15-25 parts of potash-sodalite: 25-35 parts of kaolin: 50-75 parts of silicon dioxide: 25-55 parts of talc sand: 20-25 parts.
4. The white diamond sparkling diamond glazed tile according to claim 1, wherein: the overglaze comprises zinc oxide in parts by weight: 15-30 parts of potash-sodalite, 15-20 parts of kaolin: 70-95 parts, 10-15 parts of calcined kaolin, 30-45 parts of dolomite, 5-8 parts of wollastonite and a micropore forming agent: 1-3 parts.
5. The method for preparing the white diamond sparkling diamond glazed tile according to claims 1 to 4, which comprises the following steps:
1) pressing the blank into a green brick, removing free water in the green brick through a drying process, and controlling the water content in the green brick to be less than 0.3 percent of the total mass;
2) spraying the ground coat on the green brick to form a ground coat layer;
3) printing a texture pattern on the surface of the ground coat layer by an ink-jet printer to obtain a pattern layer;
4) applying surface glaze and dry white diamond particles on the surface of the pattern layer to obtain a surface glaze white diamond flash layer;
5) and firing the green brick at 1300-1350 ℃ for 60-75 min to obtain the diamond glaze ceramic tile with white diamond glittering.
6. The method for preparing a white diamond sparkling diamond glazed tile according to claim 5, wherein the method comprises the following steps: the preparation process of the dry white diamond particles comprises the following steps: calcining the raw materials at a high temperature of 1460 ℃ or higher, performing melt quenching on the raw materials to form a frit, and mixing the frit and water according to a ratio of 1: 3, placing the mixture in a ball milling device for grinding until the particle size is less than 0.2mm, drying, and controlling the moisture content in the raw materials to be less than 0.1 percent of the total mass so as to obtain the dry white diamond particles.
7. The method for preparing a white diamond sparkling diamond glazed tile according to claim 5, wherein the method comprises the following steps: the glossiness of the dry white diamond grains is 100-120 GS.
Technical Field
The invention relates to the field of diamond-glazed ceramic tiles, in particular to a white diamond glittering diamond-glazed ceramic tile and a preparation method thereof.
Background
The ceramic tile is a plate-shaped or block-shaped ceramic product produced by clay, potash feldspar, albite and other inorganic non-metallic raw materials through the processes of material mixing, ball milling, powder making, molding, sintering and the like, and is widely applied to decorating and protecting walls and floors of buildings and structures.
In the manufacture of ceramic tiles, various products have different expression forms of glossiness, such as matt, matte, satin, highlight, bright and other different gloss effects. The general product expresses the glossiness effect of the product through the whole glossiness that glaze itself burns, and conventional glazed tile product is mostly dumb smooth face and bright plain noodles, and polished tile, the full glaze product can reach high glossiness after polishing, and it is not with the glossiness effect that glaze itself reflects, and the glossiness of whole brick face tends to unanimous, does not have too big change, and the glossiness of visualing does not have obvious contrast.
CN104529553A discloses a glazed tile made of ceramic waste and having a surface like broken diamond sand twinkling starlight and a preparation method thereof, wherein the scheme mainly adopts that crystallized melt particles are maintained in a slightly concave-convex shape after being calcined at high temperature, and fine crystals like pyroxene and sphene can be re-precipitated after being cooled, and the crystals are fine and large in quantity and can emit twinkling starlight like broken diamond sand under the irradiation of light. However, the crystal obtained by the method has small fineness and low glossiness, so that the glittering effect is greatly reduced, the glossiness is difficult to generate in a low-brightness environment, and the decorative effect is poor.
Accordingly, the prior art is deficient and needs improvement.
Disclosure of Invention
The technical problem to be solved by the invention is as follows: provides a white diamond glittering diamond glaze ceramic tile with high gloss of dry ceramic tiles and uniform surface distribution of dry ceramic tiles and a preparation method thereof.
In order to achieve the purpose, the technical scheme of the invention is as follows:
a white diamond sparkling diamond glaze ceramic tile comprises a green brick, a ground glaze layer, a pattern layer and a surface glaze white diamond sparkling layer which are sequentially compounded from bottom to top;
the surface glaze white diamond flashing layer is formed by mixing surface glaze and dry white diamond particles in a ratio of 20: 1, the chemical mass composition of the dry white diamond particles is as follows: SiO 22：45～55％，Al2O3：16～25％，K2O：1～2％，Na2O：6～12％，CaO：3～8.6％，MgO：1～2％，ZnO：0～1％；
The dry white diamond particles comprise, by weight, potash-sodalite: 40-45 parts of wollastonite: 5-6 parts of cordierite: 20-30 parts of quartz: 8-12 parts of alumina: 8-17 parts of cryolite: 7-12 parts of crystal powder: 5-8 parts.
Preferably, the green brick comprises potassium albite: 30-46 parts of kaolin: 25-28 parts of talc sand: 2-8 parts of mixed mud: 12-15 parts of sodium aluminum sand: 4-8 parts.
Preferably, the ground coat layer comprises zinc oxide: 20-25 parts of zirconium silicate: 15-25 parts of potash-sodalite: 25-35 parts of kaolin: 50-75 parts of silicon dioxide: 25-55 parts of talc sand: 20-25 parts.
Preferably, the overglaze comprises zinc oxide in parts by weight: 15-30 parts of potash-sodalite: 15-20 parts of kaolin: 70-95 parts of calcined kaolin: 10-15 parts of dolomite: 30-45 parts of wollastonite: 5-8 parts of a micropore forming agent: 1-3 parts.
The invention also provides a preparation method of the white diamond glittering diamond glaze ceramic tile, which comprises the following specific technical scheme:
a preparation method of a white diamond glittering diamond glaze ceramic tile comprises the following steps:
1) pressing the blank into a green brick, removing free water in the green brick through a drying process, and controlling the water content in the green brick to be less than 0.3 percent of the total mass;
2) spraying the ground coat on the green brick to form a ground coat layer;
3) printing a texture pattern on the surface of the ground coat layer by an ink-jet printer to obtain a pattern layer;
4) applying surface glaze and dry white diamond particles on the surface of the pattern layer to obtain a surface glaze white diamond flash layer;
5) and firing the green brick at 1300-1350 ℃ for 60-75 min to obtain the diamond glaze ceramic tile with white diamond glittering.
Preferably, the preparation process of the dry white diamond particles comprises the following steps: calcining the raw materials at a high temperature of 1460 ℃ or higher, performing melt quenching on the raw materials to form a frit, and mixing the frit and water according to a ratio of 1: 3, placing the mixture in a ball milling device for grinding until the particle size is less than 0.2mm, drying, and controlling the moisture content in the raw materials to be less than 0.1 percent of the total mass so as to obtain the dry white diamond particles.
Compared with the prior art, the invention has the following advantages:
the dry white diamond grains prepared by the method are mainly prepared from potash feldspar, cryolite, crystal powder, cordierite, quartz and other materials according to a certain proportion, the cryolite and the cordierite have good glossiness, the crystal powder can improve the integral wear resistance and hardness in a molten state, the quartz can reduce the transparency of the cryolite and the cordierite and improve the integral brightness, under natural light irradiation, the dry white diamond grains on the surface of the ceramic tile can show the glittering effect of bright crystal grains, and the decoration effect and the application value of the diamond ceramic tile are effectively improved.
Detailed Description
The present invention will be described in detail with reference to the following specific examples.
Example 1
The embodiment provides a white diamond glittering diamond-glazed ceramic tile which comprises a green brick, a ground glaze layer, a pattern layer and a surface glaze white diamond glittering layer which are sequentially compounded from bottom to top;
the surface glaze white diamond flashing layer is formed by mixing surface glaze and dry white diamond particles in a ratio of 20: 1, the chemical mass composition of the dry white diamond particles is as follows: SiO 22：45％，Al2O3：16％，K2O：1％，Na2O：6％，CaO：3％，MgO：1％，ZnO：1％；
The dry white diamond particles comprise, by weight, potash-sodalite: 40 parts of wollastonite: 5 parts of cordierite: 20 parts of quartz: 8 parts of alumina: 8 parts of cryolite: 7 parts of crystal powder: 5 parts of a mixture;
specifically, the green brick comprises potassium albite and sodalite in parts by weight: 30 parts of kaolin: 25 parts of talc sand: 2 parts of mixed mud: 12 parts and sodium-aluminum sand: 4 parts.
Specifically, the ground coat comprises zinc oxide in parts by weight: 20 parts of zirconium silicate: 15 parts of potassium-sodalite: 25 parts of kaolin: 50 parts of silicon dioxide: 25 parts of talc sand: and 20 parts.
Specifically, the overglaze comprises zinc oxide in parts by weight: 15 parts of potassium-sodalite: 15 parts of kaolin: 70 parts of calcined kaolin: 10 parts of dolomite: 30 parts of wollastonite: 5 parts of micropore forming agent: 1 part.
The preparation method of the white diamond glittering diamond glaze ceramic tile comprises the following steps:
1) pressing the blank into a green brick, removing free water in the green brick through a drying process, and controlling the water content in the green brick to be less than 0.3 percent of the total mass;
2) spraying the ground coat on the green brick to form a ground coat layer;
3) printing a texture pattern on the surface of the ground coat layer by an ink-jet printer to obtain a pattern layer;
4) applying surface glaze and dry white diamond particles on the surface of the pattern layer to obtain a surface glaze white diamond flash layer;
5) and firing the green brick at the temperature of 1300 ℃ for 75min to obtain the diamond glaze ceramic tile with white diamond glittering.
Specifically, the preparation process of the dry white diamond particles comprises the following steps: calcining the raw materials at a high temperature of 1460 ℃ or higher, performing melt quenching on the raw materials to form a frit, and mixing the frit and water according to a ratio of 1: 3, placing the mixture in a ball milling device for grinding until the particle size is less than 0.2mm, drying, and controlling the moisture content in the raw materials to be less than 0.1 percent of the total mass so as to obtain the dry white diamond particles.
Example 2
The embodiment provides a white diamond glittering diamond-glazed ceramic tile which comprises a green brick, a ground glaze layer, a pattern layer and a surface glaze white diamond glittering layer which are sequentially compounded from bottom to top;
the surface glaze white diamond flashing layer is formed by mixing surface glaze and dry white diamond particles in a ratio of 20: 1, the chemical mass composition of the dry white diamond particles is as follows: SiO 22：55％，Al2O3：25％，K2O：2％，Na2O：12％，CaO：8.6％，MgO：2％，ZnO：1％；
The dry white diamond particles comprise, by weight, potash-sodalite: 45 parts of wollastonite: 6 parts of cordierite: 30 parts of quartz: 12 parts of alumina: 17 parts of cryolite: 12 parts of crystal powder: 8 parts of a mixture;
the composite glue comprises ethylene glycol solvent in parts by weight: 70 parts of vegetable oil: 15 parts of water: 45 parts of carboxymethyl cellulose: 5 parts of polyvinyl butyral: 4 parts.
Specifically, the green brick comprises potassium albite and sodalite in parts by weight: 46 parts of kaolin: 28 parts of talc sand: 8 parts of mixed mud: 15 parts of sodium-aluminum sand: 8 parts.
Specifically, the ground coat comprises zinc oxide in parts by weight: 25 parts of zirconium silicate: 25 parts of potassium-sodalite: 35 parts of kaolin: 75 parts of silicon dioxide: 55 parts and talc sand: and 25 parts.
Specifically, the overglaze comprises zinc oxide in parts by weight: 30 parts of potassium-sodalite: 20 parts of kaolin: 95 parts of calcined kaolin: 15 parts of dolomite: 45 parts of wollastonite: 8 parts and micropore forming agent: and 3 parts.
The preparation method of the white diamond glittering diamond glaze ceramic tile comprises the following steps:
1) pressing the blank into a green brick, removing free water in the green brick through a drying process, and controlling the water content in the green brick to be less than 0.3 percent of the total mass;
2) spraying the ground coat on the green brick to form a ground coat layer;
3) printing a texture pattern on the surface of the ground coat layer by an ink-jet printer to obtain a pattern layer;
4) applying surface glaze and dry white diamond particles on the surface of the pattern layer to obtain a surface glaze white diamond flash layer;
5) and firing the green brick at 1350 ℃ for 60min to obtain the diamond-glazed ceramic tile with white diamond glittering.
Specifically, the preparation process of the dry white diamond particles comprises the following steps: calcining the raw materials at a high temperature of 1460 ℃ or higher, performing melt quenching on the raw materials to form a frit, and mixing the frit and water according to a ratio of 1: 3, placing the mixture in a ball milling device for grinding until the particle size is less than 0.2mm, drying, and controlling the moisture content in the raw materials to be less than 0.1 percent of the total mass so as to obtain the dry white diamond particles.
Example 3
The embodiment provides a white diamond glittering diamond-glazed ceramic tile which comprises a green brick, a ground glaze layer, a pattern layer and a surface glaze white diamond glittering layer which are sequentially compounded from bottom to top;
the surface glaze white diamond flashing layer is formed by mixing surface glaze and dry white diamond particles in a ratio of 20: 1, the chemical mass composition of the dry white diamond particles is as follows: SiO 22：50％，Al2O3：20％，K2O：1％，Na2O：8.5％，CaO：5.6％，MgO：2％，ZnO：1％；
The dry white diamond particles comprise, by weight, potash-sodalite: 43 parts of wollastonite: 5 parts of cordierite: 25 parts of quartz: 10 parts of alumina: 14 parts of cryolite: 9 parts of crystal powder: 6 parts of (1);
the composite glue comprises ethylene glycol solvent in parts by weight: 60 parts of vegetable oil: 12 parts of water: 40 parts of carboxymethyl cellulose: 4 parts of polyvinyl butyral: and 3 parts.
Specifically, the green brick comprises potassium albite and sodalite in parts by weight: 40 parts of kaolin: 26 parts of talc sand: 5 parts of mixed mud: 14 parts of sodium-aluminum sand: 6 parts.
Specifically, the ground coat layer comprises zinc oxide in parts by weight: 23 parts of zirconium silicate: 20 parts of potassium-sodalite: 30 parts of kaolin: 63 parts of silicon dioxide: 40 parts of talc sand: 23 parts.
Specifically, the overglaze comprises zinc oxide in parts by weight: 20 parts, 16 parts of potash-soda feldspar and kaolin: 82 parts, 13 parts of calcined kaolin, 38 parts of dolomite, 6 parts of wollastonite and a micropore forming agent: and 2 parts.
The preparation method of the white diamond glittering diamond glaze ceramic tile comprises the following steps:
1) pressing the blank into a green brick, removing free water in the green brick through a drying process, and controlling the water content in the green brick to be less than 0.3 percent of the total mass;
2) spraying the ground coat on the green brick to form a ground coat layer;
3) printing a texture pattern on the surface of the ground coat layer by an ink-jet printer to obtain a pattern layer;
4) applying surface glaze and dry white diamond particles on the surface of the pattern layer to obtain a surface glaze white diamond flash layer;
5) and firing the green brick at 1350 ℃ for 60min to obtain the diamond-glazed ceramic tile with white diamond glittering.
Specifically, the preparation process of the dry white diamond particles comprises the following steps: calcining the raw materials at a high temperature of 1460 ℃ or higher, performing melt quenching on the raw materials to form a frit, and mixing the frit and water according to a ratio of 1: 3, placing the mixture in a ball milling device for grinding until the particle size is less than 0.2mm, drying, and controlling the moisture content in the raw materials to be less than 0.1 percent of the total mass so as to obtain the dry white diamond particles.
Comparative example 1
The white diamond glittering diamond-glazed ceramic tile in comparative example 1 is different from example 1 in that the white diamond dry particles lack cryolite, cordierite and crystal powder, and the white diamond dry particles comprise, by weight, potash feldspar: 40 parts of wollastonite: 5 parts of quartz: 10 parts of alumina: 8 parts.
Comparative example 2
The difference between the white diamond glittering diamond glazed tile of the present comparative example 2 and the tile of example 1 is that the calcination temperature in the process for preparing the dry white diamond particles is 1350 ℃.
The white diamond sparkling diamond glazed tiles prepared in examples 1 to 3 and comparative examples 1 to 2 were subjected to the performance test, and the results are shown in the following table 1:
table 1 results of performance testing
As can be seen from the above table 1, the cryolite, cordierite and crystal powder can effectively improve the glossiness of the dry white diamond grains, so that the diamond glazed ceramic tile can show a shining diamond effect under light irradiation, thereby improving the decorative effect of the ceramic tile; meanwhile, the overall wear resistance level of the dry white diamond particles can be influenced at different calcination temperatures.
Compared with the prior art, the invention has the following advantages:
the dry white diamond grains prepared by the method are mainly prepared from potash feldspar, cryolite, crystal powder, cordierite, quartz and other materials according to a certain proportion, the cryolite and the cordierite have good glossiness, the crystal powder can improve the integral wear resistance and hardness in a molten state, the quartz can reduce the transparency of the cryolite and the cordierite and improve the integral brightness, under natural light irradiation, the dry white diamond grains on the surface of the ceramic tile can show the glittering effect of bright crystal grains, and the decoration effect and the application value of the diamond ceramic tile are effectively improved.
The present invention is not limited to the above preferred embodiments, and any modifications, equivalent substitutions and improvements made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
- 上一篇：一种医用注射器针头装配设备
- 下一篇：一种高强度石油压裂硅酸镁铝支撑剂及其制备方法