阅读说明：本技术 显示面板及其制备方法、显示装置 (Display panel, preparation method thereof and display device ) 是由 王菲菲 占红明 邵喜斌 于 2020-05-13 设计创作，主要内容包括：本发明实施例提供了一种显示面板及其制备方法、显示装置。显示面板包括相对设置的阵列基板和对向基板,以及设置在所述阵列基板和对向基板之间的液晶层,所述阵列基板或对向基板上设置有彩膜层和补偿层,所述彩膜层包括周期性排布的n个彩膜单元,所述补偿层包括周期性排布的n个补偿单元,第i彩膜单元用于过滤出第i颜色光线,第i补偿单元与第i彩膜单元的位置相对应,所述第i补偿单元用于使经过所述第i补偿单元的第i颜色光线的相位延迟与经过所述液晶层的第i颜色光线的相位延迟之和为第i颜色光线波长的整数倍。本发明实施例不仅有效改善了暗态漏光和发紫问题,而且有效改善了色偏问题。(The embodiment of the invention provides a display panel, a preparation method thereof and a display device. The display panel comprises an array substrate, an opposite substrate and a liquid crystal layer, wherein the array substrate and the opposite substrate are arranged oppositely, the liquid crystal layer is arranged between the array substrate and the opposite substrate, a color film layer and a compensation layer are arranged on the array substrate or the opposite substrate, the color film layer comprises n color film units which are periodically arranged, the compensation layer comprises n compensation units which are periodically arranged, the ith color film unit is used for filtering out ith color light, the ith compensation unit corresponds to the ith color film unit in position, and the ith compensation unit is used for enabling the sum of the phase delay of the ith color light passing through the ith compensation unit and the phase delay of the ith color light passing through the liquid crystal layer to be integral multiple of the wavelength of the ith color light. The embodiment of the invention not only effectively improves the problems of dark state light leakage and purple emission, but also effectively improves the problem of color cast.)

1. A display panel is characterized by comprising an array substrate, an opposite substrate and a liquid crystal layer, wherein the array substrate and the opposite substrate are oppositely arranged, the liquid crystal layer is arranged between the array substrate and the opposite substrate, a color film layer and a compensation layer are arranged on the array substrate or the opposite substrate, the color film layer comprises n color film units which are periodically arranged, the compensation layer comprises n compensation units which are periodically arranged, and the optical axis directions of the n compensation units are parallel to the initial optical axis direction of liquid crystal molecules in the liquid crystal layer; the ith color film unit is used for filtering an ith color light ray, the ith compensation unit corresponds to the ith color film unit in position, and the ith compensation unit is used for enabling the sum of the phase delay of the ith color light ray passing through the ith compensation unit and the phase delay of the ith color light ray passing through the liquid crystal layer to be integral multiple of the wavelength of the ith color light ray; n is a positive integer greater than 2, i is 1, 2, … …, n.

2. The display panel of claim 1, wherein the color film layer is disposed on a side of the array substrate facing the opposite substrate or on a side of the opposite substrate facing the array substrate.

3. The display panel according to claim 1, wherein the compensation layer is disposed on a side of the array substrate facing the opposite substrate or on a side of the opposite substrate facing the array substrate.

4. The display panel of claim 1, wherein the color film layer is disposed on a side of the opposite substrate facing the array substrate, and the compensation layer is disposed on a side of the opposite substrate facing the array substrate, or wherein the compensation layer is disposed on a side of the opposite substrate facing the array substrate, and the color film layer is disposed on a side of the compensation layer facing the array substrate.

5. The display panel of claim 1, wherein the compensation layer comprises a positive double-curvature uniaxial plate.

6. The display panel according to claim 5, wherein the material of the positive double-bending uniaxial plate comprises: 20 to 45 weight percent of liquid crystal, 5 to 35 weight percent of liquid crystalline polymerized monomer, 0.05 to 19.5 weight percent of polymerized monomer and 0.05 to 0.5 weight percent of initiator; or comprises the following steps: 20 to 39.5 weight percent of liquid crystal, 5 to 20 weight percent of liquid crystalline polymerized monomer, 5 to 20 weight percent of ultraviolet polymerized monomer, 5 to 20 weight percent of thermal polymerized monomer and 0.05 to 0.5 weight percent of initiator.

7. The display panel according to any one of claims 1 to 6, wherein the n color film units include a red color film unit for filtering out red light, a green color film unit for filtering out green light, and a blue color film unit for filtering out blue light, the n compensation units include a first compensation unit corresponding to a position of the red color film unit, a second compensation unit corresponding to a position of the green color film unit, and a third compensation unit corresponding to a position of the blue color film unit, a phase retardation value of the red light passing through the first compensation unit is greater than a phase retardation value of the green light passing through the second compensation unit, and a phase retardation value of the green light passing through the second compensation unit is greater than a phase retardation value of the blue light passing through the third compensation unit.

8. The display panel according to claim 7, wherein the first, second and third compensation units have the same thickness in a direction perpendicular to the display panel, the refractive index difference of the first compensation unit is larger than that of the second compensation unit, and the refractive index difference of the second compensation unit is larger than that of the third compensation unit.

9. The display panel according to claim 7, wherein the refractive index differences of the first compensation unit, the second compensation unit and the third compensation unit are the same, and in a direction perpendicular to the display panel, the thickness of the first compensation unit is greater than that of the second compensation unit, and the thickness of the second compensation unit is greater than that of the third compensation unit.

10. A display device comprising the display panel according to any one of claims 1 to 9.

11. A method for manufacturing a display panel, comprising:

respectively preparing an array substrate and an opposite substrate, wherein a color film layer and a compensation layer are formed on the array substrate or the opposite substrate;

forming a liquid crystal layer between the array substrate and the opposite substrate;

the color film layer comprises n color film units which are periodically arranged, the compensation layer comprises n compensation units which are periodically arranged, and the optical axis directions of the n compensation units are parallel to the initial optical axis direction of liquid crystal molecules in the liquid crystal layer; the ith color film unit is used for filtering an ith color light ray, the ith color film unit corresponds to the ith compensation unit in position, and the ith compensation unit is used for enabling the sum of the phase delay of the ith color light ray passing through the ith compensation unit and the phase delay of the ith color light ray passing through the liquid crystal layer to be integral multiple of the wavelength of the ith color light ray; n is a positive integer greater than 2, i is 1, 2, … …, n.

12. The method according to claim 11, wherein the color film layer and the compensation layer are formed on an opposite substrate, and the preparing of the opposite substrate comprises:

and sequentially preparing a color film layer and a compensation layer on the opposite substrate, or sequentially preparing the compensation layer and the color film layer on the opposite substrate.

13. The production method according to claim 12, wherein producing the compensation layer comprises:

forming a polymer liquid crystal composite film, forming a liquid crystal polymer layer through heating or ultraviolet irradiation treatment, and carrying out exposure and development treatment on the liquid crystal polymer layer by adopting a mask plate to form a first compensation unit;

coating a polymer liquid crystal composite film containing an ultraviolet polymerization monomer and a thermal polymerization monomer, and performing ultraviolet irradiation on the polymer liquid crystal composite film by using a mask to form a second compensation unit;

and arranging the opposite substrate on a heating base station or in an oven, and heating the polymer liquid crystal composite film to form a third compensation unit.

14. The manufacturing method according to claim 11, wherein the n color film units include a red color film unit, a green color film unit, and a blue color film unit, the n compensation units include a first compensation unit corresponding to a position of the red color film unit, a second compensation unit corresponding to a position of the green color film unit, and a third compensation unit corresponding to a position of the blue color film unit, a phase delay of a red light beam passing through the first compensation unit is greater than a phase delay of a green light beam passing through the second compensation unit, and a phase delay value of the green light beam passing through the second compensation unit is greater than a phase delay of the blue light beam passing through the third compensation unit.

15. The manufacturing method according to claim 11, wherein the first compensation unit, the second compensation unit, and the third compensation unit have the same thickness in a direction perpendicular to the display panel, the refractive index difference of the first compensation unit is larger than the refractive index difference of the second compensation unit, and the refractive index difference of the second compensation unit is larger than the refractive index difference of the third compensation unit; or the refractive index differences of the first compensation unit, the second compensation unit and the third compensation unit are the same, and in the direction perpendicular to the display panel, the thickness of the first compensation unit is larger than that of the second compensation unit, and the thickness of the second compensation unit is larger than that of the third compensation unit.

Technical Field

The invention relates to the technical field of display, in particular to a display panel, a preparation method thereof and a display device.

Background

Liquid Crystal Displays (LCD) have features of small size, low power consumption, no radiation, etc., and have been rapidly developed in recent years. The LCD main body structure comprises a Thin Film Transistor (TFT) substrate and a Color Filter (CF) substrate of a CELL (CELL), Liquid Crystal (LC) molecules are filled between the array substrate and the Color Filter substrate, and an electric field for driving the Liquid Crystal to deflect is formed by controlling a common electrode and a pixel electrode, so that gray scale display is realized. According to the display mode, the LCD can be classified into: a Twisted Nematic (TN) display mode, a Vertical Alignment (VA) display mode, an In Plane Switching (IPS) display mode, and an Advanced Super Dimension Switching (ADS) display mode, and the like. The ADS and the IPS belong to a horizontal electric field type display device, and have the advantages of wide viewing angle, high aperture ratio, high penetration rate, high resolution, high response speed, low power consumption, low chromatic aberration and the like.

At present, the horizontal electric field type display device has the problems of dark state light leakage, purple, color cast and the like, thereby not only influencing the product quality, but also influencing the application of the ADS display mode to curved surface products.

Disclosure of Invention

The following is a summary of the subject matter described in detail herein. This summary is not intended to limit the scope of the claims.

The technical problem to be solved by the embodiments of the present invention is to provide a display panel, a manufacturing method thereof, and a display device, so as to solve the problems of dark state light leakage, purple emission, color cast and the like existing in the existing structure.

In order to solve the technical problem, an embodiment of the present invention provides a display panel, including an array substrate and an opposite substrate which are oppositely disposed, and a liquid crystal layer disposed between the array substrate and the opposite substrate, where the array substrate or the opposite substrate is provided with a color film layer and a compensation layer, the color film layer includes n color film units which are periodically arranged, the compensation layer includes n compensation units which are periodically arranged, and an optical axis direction of the n compensation units is parallel to an initial optical axis direction of liquid crystal molecules in the liquid crystal layer; the ith color film unit is used for filtering an ith color light ray, the ith compensation unit corresponds to the ith color film unit in position, and the ith compensation unit is used for enabling the sum of the phase delay of the ith color light ray passing through the ith compensation unit and the phase delay of the ith color light ray passing through the liquid crystal layer to be integral multiple of the wavelength of the ith color light ray; n is a positive integer greater than 2. i is 1, 2, … …, n.

Optionally, the color film layer is disposed on a side of the array substrate facing the opposite substrate, or on a side of the opposite substrate facing the array substrate.

Optionally, the compensation layer is disposed on a side of the array substrate facing the opposite substrate, or on a side of the opposite substrate facing the array substrate.

Optionally, the color film layer is disposed on one side of the opposite substrate facing the array substrate, and the compensation layer is disposed on one side of the opposite substrate facing the array substrate, or the compensation layer is disposed on one side of the opposite substrate facing the array substrate, and the color film layer is disposed on one side of the compensation layer facing the array substrate.

Optionally, the compensation layer comprises a positive double-flex uniaxial plate.

Optionally, the material of the positive double-bending single-shaft plate comprises: 20 to 45 weight percent of liquid crystal, 5 to 35 weight percent of liquid crystalline polymerized monomer, 0.05 to 19.5 weight percent of polymerized monomer and 0.05 to 0.5 weight percent of initiator; or comprises the following steps: 20 to 39.5 weight percent of liquid crystal, 5 to 20 weight percent of liquid crystalline polymerized monomer, 5 to 20 weight percent of ultraviolet polymerized monomer, 5 to 20 weight percent of thermal polymerized monomer and 0.05 to 0.5 weight percent of initiator.

Optionally, the n color film units include a red color film unit for filtering out red light, a green color film unit for filtering out green light, and a blue color film unit for filtering out blue light, the n compensation units include a first compensation unit corresponding to a position of the red color film unit, a second compensation unit corresponding to a position of the green color film unit, and a third compensation unit corresponding to a position of the blue color film unit, a phase delay value of the red light passing through the first compensation unit is greater than a phase delay value of the green light passing through the second compensation unit, and a phase delay value of the green light passing through the second compensation unit is greater than a phase delay value of the blue light passing through the third compensation unit.

Optionally, in a direction perpendicular to the display panel, the thicknesses of the first compensation unit, the second compensation unit and the third compensation unit are the same, the refractive index difference of the first compensation unit is larger than that of the second compensation unit, and the refractive index difference of the second compensation unit is larger than that of the third compensation unit.

Optionally, the refractive index differences of the first compensation unit, the second compensation unit and the third compensation unit are the same, and in a direction perpendicular to the display panel, the thickness of the first compensation unit is greater than that of the second compensation unit, and the thickness of the second compensation unit is greater than that of the third compensation unit.

The embodiment of the invention also provides a display device which comprises the display panel.

In order to solve the above technical problem, an embodiment of the present invention further provides a method for manufacturing a display panel, including:

respectively preparing an array substrate and an opposite substrate, wherein a color film layer and a compensation layer are formed on the array substrate or the opposite substrate;

forming a liquid crystal layer between the array substrate and the opposite substrate;

the color film layer comprises n color film units which are periodically arranged, the compensation layer comprises n compensation units which are periodically arranged, and the optical axis directions of the n compensation units are parallel to the initial optical axis direction of liquid crystal molecules in the liquid crystal layer; the ith color film unit is used for filtering an ith color light ray, the ith color film unit corresponds to the ith compensation unit in position, and the ith compensation unit is used for enabling the sum of the phase delay of the ith color light ray passing through the ith compensation unit and the phase delay of the ith color light ray passing through the liquid crystal layer to be integral multiple of the wavelength of the ith color light ray; n is a positive integer greater than 2. i is 1, 2, … …, n.

Optionally, the color film layer and the compensation layer are formed on an opposite substrate, and preparing the opposite substrate includes:

and sequentially preparing a color film layer and a compensation layer on the opposite substrate, or sequentially preparing the compensation layer and the color film layer on the opposite substrate.

Optionally, preparing a compensation layer comprises:

forming a polymer liquid crystal composite film, forming a liquid crystal polymer layer through heating or ultraviolet irradiation treatment, and carrying out exposure and development treatment on the liquid crystal polymer layer by adopting a mask plate to form a first compensation unit;

coating a polymer liquid crystal composite film containing an ultraviolet polymerization monomer and a thermal polymerization monomer, and performing ultraviolet irradiation on the polymer liquid crystal composite film by using a mask to form a second compensation unit;

and arranging the opposite substrate on a heating base station or in an oven, and heating the polymer liquid crystal composite film to form a third compensation unit.

Optionally, the n color film units include a red color film unit, a green color film unit and a blue color film unit, the n compensation units include a first compensation unit corresponding to a position of the red color film unit, a second compensation unit corresponding to a position of the green color film unit and a third compensation unit corresponding to a position of the blue color film unit, a phase delay of the red light passing through the first compensation unit is greater than a phase delay of the green light passing through the second compensation unit, and a phase delay value of the green light passing through the second compensation unit is greater than a phase delay of the blue light passing through the third compensation unit.

Optionally, in a direction perpendicular to the display panel, the thicknesses of the first compensation unit, the second compensation unit and the third compensation unit are the same, the refractive index difference of the first compensation unit is larger than that of the second compensation unit, and the refractive index difference of the second compensation unit is larger than that of the third compensation unit; or the refractive index differences of the first compensation unit, the second compensation unit and the third compensation unit are the same, and in the direction perpendicular to the display panel, the thickness of the first compensation unit is larger than that of the second compensation unit, and the thickness of the second compensation unit is larger than that of the third compensation unit.

The embodiment of the invention provides a display panel, a preparation method thereof and a display device, wherein a plurality of compensation units are arranged and respectively perform phase compensation on a plurality of color lights, when the polarization state of the transmitted light changes due to non-uniform external force on the display panel, the phase delay of the plurality of color lights passing through the plurality of compensation units can be matched with the phase delay of a liquid crystal layer, so that the phase delay of the plurality of color polarized lights passing through the liquid crystal layer is compensated, each color light can be recovered to the original polarization state, and each color light cannot be emitted from the horizontally oriented display panel in the dark state, so that the problems of dark state light leakage and purple emission are effectively improved, and the problem of color cast is effectively improved.

Other aspects will be apparent upon reading and understanding the attached drawings and detailed description.

Drawings

The accompanying drawings are included to provide a further understanding of the disclosed embodiments and are incorporated in and constitute a part of this specification, illustrate embodiments of the disclosure and together with the example serve to explain the principles of the disclosure and not to limit the disclosure. The shapes and sizes of the various elements in the drawings are not to be considered as true proportions, but are merely intended to illustrate the present disclosure.

FIG. 1 is a diagram illustrating a structure of a display panel according to an embodiment of the present invention;

FIG. 2 is a schematic diagram illustrating a black matrix pattern formed according to an embodiment of the present invention;

FIG. 3 is a schematic diagram illustrating a color film pattern formed according to an embodiment of the present invention;

FIG. 4 is a schematic diagram illustrating a first compensation unit according to an embodiment of the present invention;

FIG. 5 is a schematic diagram illustrating a second compensation unit according to an embodiment of the present invention;

FIG. 6 is a schematic diagram illustrating a third compensation unit according to an embodiment of the present invention;

FIG. 7 is a schematic view of an embodiment of the present invention after coating a polymer liquid crystal composite film;

FIG. 8 is a schematic diagram illustrating a second compensation unit according to an embodiment of the present invention;

FIG. 9 is a schematic diagram of a third compensation unit according to an embodiment of the present invention;

FIG. 10 is a diagram of another structure of a display panel according to an embodiment of the present invention;

FIG. 11 is a diagram illustrating another structure of a display panel according to an embodiment of the present invention;

FIG. 12 is a diagram of another structure of a display panel according to an embodiment of the present invention.

Description of reference numerals:

10-an array substrate; 11-an array structure layer; 20-opposite substrate;

21-opposite structural layer; 30-color film layer; 31-first color film unit;

32-second color film unit; 33-third color film unit; 40-a compensation layer;

41 — a first compensation unit; 42-a second compensation unit; 43 — a third compensation unit;

100-an array substrate; 200-an opposite substrate; 300-liquid crystal layer.

Detailed Description

To make the objects, technical solutions and advantages of the present disclosure more apparent, embodiments of the present disclosure will be described in detail below with reference to the accompanying drawings. Embodiments may be embodied in many different forms. Those skilled in the art can readily appreciate the fact that the forms and details may be varied into a variety of forms without departing from the spirit and scope of the present disclosure. Therefore, the present disclosure should not be construed as being limited to the contents described in the following embodiments. The embodiments and features of the embodiments in the present disclosure may be arbitrarily combined with each other without conflict.

In the drawings, the size of each component, the thickness of layers, or regions may be exaggerated for clarity. Therefore, the embodiments of the present disclosure are not necessarily limited to the dimensions, and the shapes and sizes of the respective components in the drawings do not reflect a true scale. Further, the drawings schematically show ideal examples, and the embodiments of the present disclosure are not limited to the shapes or numerical values shown in the drawings.

The ordinal numbers such as "first", "second", "third", and the like in the present specification are provided for avoiding confusion among the constituent elements, and are not limited in number.

In this specification, for convenience, words such as "middle", "upper", "lower", "front", "rear", "vertical", "horizontal", "top", "bottom", "inner", "outer", etc., indicating orientations or positional relationships are used to explain positional relationships of constituent elements with reference to the drawings, only for convenience of description and simplification of description, and do not indicate or imply that the referred device or element must have a specific orientation, be constructed in a specific orientation, and be operated, and thus, should not be construed as limiting the present disclosure. The positional relationship of the components is changed as appropriate in accordance with the direction in which each component is described. Therefore, the words described in the specification are not limited to the words described in the specification, and may be replaced as appropriate.

In this specification, the terms "mounted," "connected," and "connected" are to be construed broadly unless otherwise specifically indicated and limited. For example, it may be a fixed connection, or a removable connection, or an integral connection; can be a mechanical connection, or an electrical connection; either directly or indirectly through intervening components, or both may be interconnected. The specific meaning of the above terms in the present disclosure can be understood in specific instances by those of ordinary skill in the art.

In this specification, a transistor refers to an element including at least three terminals, i.e., a gate electrode, a drain electrode, and a source electrode. The transistor has a channel region between a drain electrode (drain electrode terminal, drain region, or drain electrode) and a source electrode (source electrode terminal, source region, or source electrode), and current can flow through the drain electrode, the channel region, and the source electrode. In this specification, the channel region refers to a region through which current mainly flows.

In this specification, the first electrode may be a drain electrode and the second electrode may be a source electrode, or the first electrode may be a source electrode and the second electrode may be a drain electrode. In the case of using transistors of opposite polarities, or in the case of changing the direction of current flow during circuit operation, the functions of the "source electrode" and the "drain electrode" may be interchanged. Therefore, in this specification, "source electrode" and "drain electrode" may be exchanged with each other.

In this specification, "electrically connected" includes a case where constituent elements are connected together by an element having some kind of electrical action. The "element having a certain electric function" is not particularly limited as long as it can transmit and receive an electric signal between connected components. Examples of the "element having some kind of electric function" include not only an electrode and a wiring but also a switching element such as a transistor, a resistor, an inductor, a capacitor, other elements having various functions, and the like.

In the present specification, "parallel" means a state in which an angle formed by two straight lines is-10 ° or more and 10 ° or less, and therefore, includes a state in which the angle is-5 ° or more and 5 ° or less. The term "perpendicular" refers to a state in which the angle formed by two straight lines is 80 ° or more and 100 ° or less, and therefore includes a state in which the angle is 85 ° or more and 95 ° or less.

In the present specification, "film" and "layer" may be interchanged with each other. For example, the "conductive layer" may be sometimes replaced with a "conductive film". Similarly, the "insulating film" may be replaced with an "insulating layer".

At present, when a horizontal electric field type display panel is bent or pressed to bear force, the display panel has the problems of serious dark state light leakage, purple emission, color cast and the like. Taking the LCD of the ADS display mode as an example, the display panel includes an array substrate, an opposite substrate, and a liquid crystal layer located between the array substrate and the opposite substrate, and liquid crystal molecules in the liquid crystal layer have an initial optical axis in a horizontal direction. In order to ensure normal display, a first polarizing film and a second polarizing film, the light transmission axes of which are perpendicular to each other, are respectively arranged on the outer sides of the array substrate and the opposite substrate. Because the liquid crystal can not emit light, the display panel is also provided with a backlight source, and light rays emitted by the backlight source are emitted through the first polaroid, the array substrate, the liquid crystal layer, the opposite substrate and the second polaroid in sequence. Under the condition of no voltage, the liquid crystal has no twisting effect on light, the polarization direction of the light passing through the first polaroid and the liquid crystal is vertical to the light transmission axis direction of the second polaroid, the light cannot transmit, so that a dark picture is displayed, and the display panel is in a dark state. Under the condition of voltage application, the liquid crystal molecules rotate to distort light rays, the polarization direction of the light rays is changed, the light rays can be emitted through the second polaroid, bright pictures are displayed, and the display panel is in a bright state. Since the array substrate and the substrate of the opposite substrate are generally formed of glass, the glass has a birefringence effect on light. When the display panel is bent or pressed to bear force, the glass is changed from an isotropic medium to an optical anisotropic medium, and according to different stress conditions, the glass can generate non-uniform stress birefringence, so that the polarization state of light penetrating through the glass is changed. Generally, the polarization states generated by the substrate substrates of the array substrate and the substrate substrates of the opposite substrate are equal in phase and opposite in direction, and in the absence of a liquid crystal layer, the polarization states generated by the two substrate substrates can be cancelled out, but due to the existence of the liquid crystal layer, the liquid crystal amplifies the phase difference, so that the polarization states generated by the two substrate substrates cannot be cancelled out, and the problems of light leakage, purple emission and color cast in a dark state (L0) occur.

The embodiment of the invention provides a display panel, aiming at solving the problems of dark state light leakage, purple and color cast of the existing structure. The display panel comprises an array substrate, an opposite substrate, a liquid crystal layer, a color film layer and a compensation layer, wherein the array substrate and the opposite substrate are oppositely arranged, the liquid crystal layer, the color film layer and the compensation layer are arranged between the array substrate and the opposite substrate, the color film layer comprises n color film units which are periodically arranged, the compensation layer comprises n compensation units which are periodically arranged, and the optical axis directions of the n compensation units are parallel to the initial optical axis direction of liquid crystal molecules in the liquid crystal layer; the ith color film unit is used for filtering an ith color light ray, the ith compensation unit corresponds to the ith color film unit in position, and the ith compensation unit is used for enabling the sum of the phase delay of the ith color light ray passing through the ith compensation unit and the phase delay of the ith color light ray passing through the liquid crystal layer to be integral multiple of the wavelength of the ith color light ray; n is a positive integer greater than 2. i is 1, 2, … …, n.

In an exemplary embodiment, the color film layer may be disposed on a side of the array substrate facing the opposite substrate, or on a side of the opposite substrate facing the array substrate.

In an exemplary embodiment, the compensation layer may be disposed on a side of the array substrate facing the opposite substrate, or disposed on a side of the opposite substrate facing the array substrate.

In an exemplary embodiment, the color film layer may be disposed on a surface of the opposite substrate on a side facing the array substrate, and the compensation layer is disposed on a surface of the color film layer on a side facing the array substrate, or the compensation layer may be disposed on a surface of the opposite substrate on a side facing the array substrate, and the color film layer is disposed on a surface of the compensation layer on a side facing the array substrate.

In an exemplary embodiment, the n color film units may include a red color film unit filtering out red (R) light, a green color film unit filtering out green (G) light, and a blue color film unit filtering out blue (B) light. The n compensation units comprise a first compensation unit corresponding to the position of the red color film unit, a second compensation unit corresponding to the position of the green color film unit and a third compensation unit corresponding to the position of the blue color film unit. The phase delay value of the red light passing through the first compensation unit is larger than that of the green light passing through the second compensation unit, and the phase delay value of the green light passing through the second compensation unit is larger than that of the blue light passing through the third compensation unit. In some possible implementation manners, the n color film units may include a red color film unit, a green color film unit, a blue color film unit, and a white (W) color film unit.

In an exemplary embodiment, the compensation layer comprises a positive double-folded uniaxial plate (+ a plate).

In an exemplary embodiment, the display panel is a horizontal electric field type display panel, and may be an ADS display mode or an IPS display mode.

In the embodiment of the present invention, the sum of the phase retardation of the ith compensation unit and the phase retardation of the liquid crystal layer may not strictly be an integer multiple of the ith color light, and may have a certain tolerance range, for example, the tolerance range is within ± 20%, which is within the protection scope of the present invention. The optical axis direction of the i-th compensation unit and the initial optical axis direction of the liquid crystal molecules in the liquid crystal layer may be parallel to each other within a certain tolerance range, for example, the tolerance range is ± 11 °, and the invention is within the protection scope. Wherein i is 1, 2 or 3.

The display panel according to the embodiment of the present invention can be implemented in various ways, and the technical solution according to the embodiment of the present invention is described in detail below by using specific embodiments.

Fig. 1 is a schematic view of a structure of a display panel according to an embodiment of the invention, which illustrates a structure in which a color film layer and a compensation layer are disposed on one side of an opposite substrate. As shown in fig. 1, the display panel includes an array substrate 100 and an opposite substrate 200 disposed opposite to each other, and a liquid crystal layer 300 disposed between the array substrate 100 and the opposite substrate 200. The array substrate 100 includes an array substrate 10 and an array structure layer 11 disposed on a surface of the array substrate 10 facing the opposite substrate 200. The opposite substrate 200 includes an opposite substrate 20, a color film layer 30 disposed on a surface of the opposite substrate 20 facing the array substrate 100, and a compensation layer 40 disposed on a surface of the color film layer 30 facing the array substrate 100, wherein the color film layer 30 is used for filtering out light of a corresponding color, and the compensation layer 40 is used for performing phase compensation on the light of the corresponding color. The display panel further comprises an array polarizer, an opposite polarizer and a backlight source (not shown), wherein the array polarizer is arranged on the surface of the side of the array substrate 100 far away from the opposite substrate 200, the opposite polarizer is arranged on the surface of the side of the opposite substrate 200 far away from the array substrate 100, the light transmission axis of the array polarizer is perpendicular to the light transmission axis of the opposite polarizer, the backlight source is arranged on the side of the array polarizer far away from the array substrate 100, light rays emitted by the backlight source sequentially pass through the array polarizer, the array substrate 10, the array structural layer 11, the liquid crystal layer 300, the compensation layer 40, the color film layer 30, the opposite substrate 20 and the opposite polarizer, and the initial optical axis direction of liquid crystal molecules of the liquid crystal layer 300 is a horizontal direction.

In an exemplary embodiment, the color film layer 30 includes a first color film unit 31, a second color film unit 32, and a third color film unit 33, which are periodically arranged. The first color film unit 31 is configured to filter light passing through the first color film unit 201 to filter out first color light. The second color film unit 32 is configured to filter the light passing through the second color film unit 32 to filter out a second color light. The third color film unit 33 is configured to filter the light passing through the third color film unit 33 to filter out a third color light.

In an exemplary embodiment, the compensation layer 40 includes first, second, and third compensation units 41, 42, and 43 that are periodically arranged. The first compensation unit 41 corresponds to the first color film unit 31 in position, and is configured to perform phase compensation on the first color light passing through the first compensation unit 41, so that the sum of the phase retardation of the first color light passing through the first compensation unit 41 and the phase retardation of the first color light passing through the liquid crystal layer 300 is an integral multiple of the wavelength of the first color light. The second compensation unit 42 corresponds to the second color film unit 32 in position, and is configured to perform phase compensation on the second color light passing through the second compensation unit 42, so that the sum of the phase retardation of the second color light passing through the second compensation unit 42 and the phase retardation of the second color light passing through the liquid crystal layer 300 is an integer multiple of the wavelength of the second color light. The third compensation unit 43 corresponds to the third color film unit 33, and is configured to perform phase compensation on the third color light passing through the third compensation unit 43, so that the sum of the phase retardation of the third color light passing through the third compensation unit 43 and the phase retardation of the third color light passing through the liquid crystal layer 300 is an integer multiple of the wavelength of the third color light.

Light rays propagate more slowly in substances with a higher refractive index and more rapidly in substances with a lower refractive index. Since the liquid crystal has optical birefringence and refractive indexes of the liquid crystal include a normal (ordinary) refractive index n0 and an extraordinary (extraordinary) refractive index ne, when light passes through the liquid crystal layer with refractive index differences in XY directions, the traveling distances of the light in XY directions are different, and the difference is Phase Retardation (Phase Retardation), also called Phase difference. Where X is an X-axis direction within the liquid crystal layer plane, and Y is a Y-axis direction perpendicular to the X-axis within the liquid crystal layer plane. The in-plane phase retardation R of the liquid crystal layer 300 according to the phase retardation calculation formula_LC(ne-n0) × d2, d2 is the thickness of the liquid crystal layer 300 in the direction perpendicular to the display panel, n0 is the ordinary refractive index of the liquid crystal, and ne is the extraordinary refractive index of the liquid crystal.

In an exemplary embodiment, the compensation layer 40 may be a positive doubly-twisted uniaxial (+ a) plate, also called a + a compensation film layer, satisfying nx > ny ═ nz, where nx is the refractive index in the X-axis direction within the + a plate surface, ny is the refractive index in the Y-axis direction perpendicular to the X-axis within the + a plate surface, and nz is the refractive index in the thickness direction of the + a plate. The in-plane phase retardation R of the compensation layer 40 according to the phase retardation calculation formula_+AD1, d1 is the thickness of the compensation layer 40 perpendicular to the display panel direction. Thus, the sum of the phase retardation of the incident light passing through the + a plate and the phase retardation of the incident light passing through the liquid crystal layer as an integral multiple of the wavelength of the incident light can be expressed as: r_+A+R_LCM λ, m 0, ± 1, ± 2 … …, λ being the wavelength of the incident light. By adjusting the material properties (nx or ny) or the thickness parameter (d1) of the + a plate so as to satisfy (nx-ny) d1 (m) λ - (ne-n0) d2, the + a plate can compensate for the in-plane phase retardation of light passing through the liquid crystal layer when the optical axis direction of the + a plate is parallel to the initial optical axis direction of liquid crystal molecules in the liquid crystal layer. In some possible implementations, the + a plate may use a liquid crystal composite film to reduce the manufacturing cost.

In an exemplary embodiment, the first color film unit 31 is a red color film unit for filtering out red light, the second color film unit 32 is a green color film unit for filtering out green light, and the third color film unit 33 is a blue color film unit for filtering out blue light.

In an exemplary embodiment, the first compensation unit 41 corresponds to a position of the red color film unit, and the in-plane phase retardation R of the first compensation unit 41_+AR＝(nx_R-ny_R)*d1_R，d1_RThe thickness of the first compensation unit 41 is perpendicular to the display panel direction. Thus, by adjusting the material property (nx) of the first compensation unit 41_ROr ny_R) Or thickness parameter (d1)_R) So that R is_+AR+R_LC＝m*λ_RM is 0, ± 1, ± 2 … …, i.e. satisfies (nx)_R-ny_R)*d1_R+(ne-n0)*d2＝m*λ_R，λ_RThe wavelength of the red light, when the optical axis direction of the first compensation unit 41 is parallel to the initial optical axis direction of the liquid crystal molecules in the liquid crystal layer, the in-plane phase retardation of the red light generated by the liquid crystal layer 300 can be compensated.

In an exemplary embodiment, the second compensation unit 42 corresponds to a position of the green color film unit, and the in-plane phase delay G of the second compensation unit 42_+AG＝(nx_G-ny_G)*d1_G，d1_GThe thickness of the second compensation unit 42 is perpendicular to the display panel direction. Thus, by adjusting the material property (nx) of the second compensation unit 42_GOr ny_G) Or thickness parameter (d1)_G) So that G is_+AG+G_LC＝m*λ_GM is 0, ± 1, ± 2 … …, i.e. satisfies (nx)_G-ny_G)*d1_G+(ne-n0)*d2＝m*λ_G，λ_GThe wavelength of the green light, when the optical axis direction of the second compensation unit 42 is parallel to the initial optical axis direction of the liquid crystal molecules in the liquid crystal layer, the in-plane phase retardation of the green light generated by the liquid crystal layer 300 can be compensated.

In an exemplary embodiment, the third compensation unit 43 corresponds to a position of the blue color film unit, and the in-plane phase retardation B of the third compensation unit 43_+AB＝(nx_B-ny_B)*d1_B，d1_BThe thickness of the third compensation unit 43 is perpendicular to the display panel direction. Thus, by adjusting the material property (nx) of the third compensation unit 43_BOr ny_B) Or thickness parameter (d1)_B) So that B is_+AB+B_LC＝m*λ_BM is 0, ± 1, ± 2 … …, i.e. satisfies (nx)_B-ny_B)*d1_B+(ne-n0)*d2＝m*λ_B，λ_BThe wavelength of the blue light, when the optical axis direction of the third compensation unit 43 is parallel to the initial optical axis direction of the liquid crystal molecules in the liquid crystal layer, the in-plane phase retardation of the blue light generated by the liquid crystal layer 300 can be compensated.

In an exemplary embodiment, the integer multiple may be 1, that is, the sum of the phase retardation of the first compensation unit 41 and the phase retardation of the liquid crystal layer is the wavelength of red light, the sum of the phase retardation of the second compensation unit 42 and the phase retardation of the liquid crystal layer is the wavelength of green light, and the sum of the phase retardation of the third compensation unit 43 and the phase retardation of the liquid crystal layer is the wavelength of blue light, so that the thicknesses of the first compensation unit 41, the second compensation unit 42, and the third compensation unit 43 may be reduced as much as possible, which is beneficial to thinning the display panel.

In an exemplary embodiment, the wavelength of the red light may be set to 605nm to 700nm, the wavelength of the green light may be set to 505nm to 600nm, the wavelength of the blue light may be set to 400nm to 500nm, and the phase delays of the first, second, and third compensation units 41, 42, and 43 may be set to 50nm to 400 nm. Since the material properties and thickness of the liquid crystal layer are constant, the phase retardation of the + a plate is different for different wavelengths of incident light. Since the wavelength of the red light is greater than that of the green light, and the wavelength of the green light is greater than that of the blue light, the phase delay R of the red light passing through the first compensation unit 41_+ARGreater than the phase delay R of the green light passing through the second compensation unit 42_+AGThe green light passes through the phase delay R of the second compensation unit 42_+AGIs greater than the phase delay R of the blue light passing through the third compensation unit 43_+AB。

In the exemplary embodimentIn an embodiment, three compensation units may be provided with the same thickness, i.e. d1_R＝d1_G＝d1_BBut the refractive index difference (nx) of the first compensation unit 41_R-ny_R) Greater than the refractive index difference (nx) of the second compensation unit 42_G-ny_G) Refractive index difference (nx) of the second compensation unit 42_G-ny_G) Greater than the refractive index difference (nx) of the third compensation unit 43_B-ny_B) To realize the phase delay R of the red light passing through the first compensation unit 41_+ARGreater than the phase delay R of the green light passing through the second compensation unit 42_+AGThe green light passes through the phase delay R of the second compensation unit 42_+AGIs greater than the phase delay R of the blue light passing through the third compensation unit 43_+AB。

In an exemplary embodiment, three compensation units may be arranged with the same refractive index difference, i.e., nx_R-ny_R＝nx_G-ny_G＝nx_B-ny_BBut the thickness d1 of the first compensation element 41_RGreater than the thickness d1 of the second compensation element 42_GThickness d1 of second compensation element 42_GGreater than the thickness d1 of the third compensation unit 43_BTo realize the phase delay R of the red light passing through the first compensation unit 41_+ARGreater than the phase delay R of the green light passing through the second compensation unit 42_+AGThe green light passes through the phase delay R of the second compensation unit 42_+AGIs greater than the phase delay R of the blue light passing through the third compensation unit 43_+AB。

In some possible implementations, the thicknesses and refractive index differences of the three compensation units may be different, and the phase delay R of the red light passing through the first compensation unit 41 is realized by adjusting the refractive index differences and the thicknesses_+ARGreater than the phase delay R of the green light passing through the second compensation unit 42_+AGThe green light passes through the phase delay R of the second compensation unit 42_+AGIs greater than the phase delay R of the blue light passing through the third compensation unit 43_+AB。

The structure of the display panel is explained below by way of an example of a manufacturing process of the display panel. The "patterning process" referred to in this disclosure includes depositing a film layer, coating a photoresist, mask exposing, developing, etching, and stripping a photoresist. The deposition may employ any one or more of sputtering, evaporation and chemical vapor deposition, the coating may employ any one or more of spray coating and spin coating, and the etching may employ any one or more of dry etching and wet etching. "thin film" refers to a layer of a material deposited or coated onto a substrate. The "thin film" may also be referred to as a "layer" if it does not require a patterning process throughout the fabrication process. If the "thin film" requires a patterning process during the entire fabrication process, it is referred to as a "thin film" before the patterning process and a "layer" after the patterning process. The "layer" after the patterning process includes at least one "pattern". The "a and B are disposed in the same layer" in the present disclosure means that a and B are simultaneously formed by the same patterning process.

The manufacturing process of the display panel of the embodiment mainly includes two parts, the first part includes substrate manufacturing, and the second part includes alignment pressing (box aligning). The substrate preparation comprises array substrate preparation and opposite substrate preparation, and the two methods have no sequence requirement and can be carried out simultaneously. The following describes the two parts of the process.

First, preparation of array substrate in first part

The array substrate of the embodiment comprises an array substrate and a driving structure layer arranged on the array substrate, wherein a main structure of the driving structure layer comprises a thin film transistor, a pixel electrode and a common electrode. The process of forming the driving structure layer in this embodiment may adopt a mature process of manufacturing the LCD. In an exemplary embodiment, the process of forming the driving structure layer may include: (1) and forming a grid line, a grid electrode and a common electrode pattern on the array substrate. (2) A gate insulating layer covering the gate line, the gate electrode, and the common electrode, and an active layer disposed on the gate insulating layer are formed. (3) And forming a data line, a source electrode and a drain electrode, wherein a conductive channel is formed between the source electrode and the drain electrode. (4) And forming a passivation layer covering the data line, the source electrode and the drain electrode, and forming a through hole exposing the drain electrode on the passivation layer. (5) And forming a pixel electrode on the passivation layer, wherein the pixel electrode is connected with the drain electrode through a through hole on the passivation layer. The liquid crystal display device comprises a common electrode, a pixel electrode, a plate electrode and a slit electrode, wherein the common electrode is used for providing a common voltage, the pixel electrode is used for providing a pixel voltage for display, one of the common electrode and the pixel electrode is the plate electrode, the other one of the common electrode and the pixel electrode is the slit electrode, and a multi-dimensional electric field generated between the slit electrode and the plate electrode drives liquid crystal to deflect. In some possible implementations, the method of manufacturing the array substrate may further include forming an alignment film and performing an alignment process on the alignment film.

Second, preparation of the opposing substrate in the first part

(1) Preparing a black matrix pattern, including: a black matrix film is coated on the opposite substrate 20, the black matrix film is exposed by using a mask, and a pattern of black matrices 23 arranged at intervals is formed on the opposite substrate 20 after development, as shown in fig. 2.

(2) Preparing a color film layer pattern, comprising: a color film layer 30 pattern is formed on the opposite substrate 20 on which the black matrix 23 pattern is formed, the color film layer 30 pattern includes a red color film unit 31, a green color film unit 32, and a blue color film unit 33, and the red color film unit 31, the green color film unit 32, and the blue color film unit 33 are respectively disposed between the black matrices 23 and are periodically arranged according to a set rule, as shown in fig. 3. In an exemplary embodiment, the color film layer 30 pattern is formed using a well-established manufacturing process. In some possible implementations, after the color film layer 30 is formed, a planarization layer (OC) may also be formed.

(3) And preparing a compensation layer pattern. In this embodiment, the compensation layer can be formed by using a plurality of manufacturing methods, and three manufacturing methods will be described as an example.

The first method for preparing the compensation layer comprises the following steps:

(311) the counter substrate 20 having the above-described structure is coated with a polymer liquid crystal composite film, and the polymer liquid crystal composite film is subjected to a heating treatment or an ultraviolet irradiation treatment to polymerize liquid crystal molecules in the polymer liquid crystal composite film, thereby forming a first liquid crystal polymer layer. Then, the first liquid crystal polymer layer is subjected to exposure and development processes using a mask, and first compensation units 41 disposed at intervals are formed on the counter substrate 20, as shown in fig. 4. In this embodiment, the first compensation unit 41 corresponds to a position of the red color filter unit, that is, an orthographic projection of the first compensation unit 41 on the opposite substrate 20 includes an orthographic projection of the red color filter unit on the opposite substrate 20. By adjusting the thickness of the polymer liquid crystal composite film, the phase retardation of the red light passing through the first compensation unit 41 can be adjusted, so that the sum of the phase retardation of the red light passing through the first compensation unit 41 and the phase retardation of the red light passing through the liquid crystal layer in the display panel is an integral multiple of the wavelength of the red light.

(312) Coating a polymer liquid crystal composite film, forming a second liquid crystal polymer layer through a heating or ultraviolet light irradiation process, and performing an exposure and development process on the second liquid crystal polymer layer using a mask to form second compensation units 42 disposed at intervals on the opposite substrate 20, as shown in fig. 5. In this embodiment, the second compensation unit 42 corresponds to a position of the green color filter unit, that is, an orthographic projection of the second compensation unit 42 on the opposite substrate 20 includes an orthographic projection of the green color filter unit on the opposite substrate 20. By adjusting the thickness of the polymer liquid crystal composite film, the phase retardation of the green light passing through the second compensation unit 42 can be adjusted, so that the sum of the phase retardation of the green light passing through the second compensation unit 42 and the phase retardation of the green light passing through the liquid crystal layer in the display panel is an integral multiple of the wavelength of the green light. In an exemplary embodiment, the first liquid crystal polymer layer and the second liquid crystal polymer layer are made of the same material, and since the wavelength of red light is greater than that of green light, the thickness of the first compensation unit 41 is greater than that of the second compensation unit 42, and the thickness of the first compensation unit 41 may be 0.5 μm to 3.0 μm.

(313) Coating a polymer liquid crystal composite film, forming a third liquid crystal polymer layer through heating or ultraviolet irradiation treatment, and performing exposure and development treatment on the third liquid crystal polymer layer by using a mask to form third compensation units 43 arranged at intervals on the counter substrate 20, as shown in fig. 6. In this embodiment, the third compensation unit 43 corresponds to a position of the blue color filter unit, that is, an orthographic projection of the third compensation unit 43 on the opposite substrate 20 includes an orthographic projection of the blue color filter unit on the opposite substrate 20. By adjusting the thickness of the polymer liquid crystal composite film, the phase retardation of the blue light passing through the third compensation unit 43 can be adjusted, so that the sum of the phase retardation of the blue light passing through the third compensation unit 43 and the phase retardation of the blue light passing through the liquid crystal layer in the display panel is an integral multiple of the wavelength of the blue light. In an exemplary embodiment, the second liquid crystal polymer layer is the same material as the third liquid crystal polymer layer, and since the wavelength of green light is greater than that of blue light, the thickness of the second compensation unit 42 is greater than that of the third compensation unit 43.

In some possible implementations, after the polymer liquid crystal composite film is formed and before the heating treatment or the ultraviolet irradiation treatment is performed, the polymer liquid crystal composite film may be irradiated with ultraviolet light in a linear polarization state, so that the optical axis direction of liquid crystal molecules in the polymer liquid crystal composite film is parallel to a set direction, where the set direction is an initial optical axis direction of liquid crystal molecules in a liquid crystal layer of the display panel. Note that, after the liquid crystal is polymerized, the optical axis direction of the liquid crystal molecules does not change, unlike the case of a liquid crystal layer in a display panel. In some possible implementations, before the compensation layer is prepared, a step of forming an alignment film and performing an alignment treatment on the alignment film may be further included. In some possible implementation manners, an alignment film may be formed first, and alignment processing may be performed on the alignment film, then the first compensation unit 41, the second compensation unit 42, and the third compensation unit 43 are sequentially formed, and in the process of sequentially forming each compensation unit, after the corresponding polymer liquid crystal composite film is formed, polarization state ultraviolet irradiation processing may be performed.

In some possible implementations, the wavelength of the linearly polarized ultraviolet light may be 300nm to 370 nm. The heat treatment may include pre-baking and post-baking, and the pre-baking process may include: keeping the temperature at 50-130 ℃ for 0.5-10 min, wherein the post-baking process can comprise the following steps: keeping the temperature at 150-240 ℃ for 10-40 min. The ultraviolet light irradiation treatment may include first ultraviolet light irradiation and second ultraviolet light irradiation, and the first ultraviolet light irradiation process may include: the adopted wavelength is 365nm, and the light intensity is 0.5mw/cm²～600mw/cm²The ultraviolet light irradiation is carried out for 0.5min to 60min, and the secondary ultraviolet light irradiation process can be carried outComprises the following steps: the adopted wavelength is 254nm, and the light intensity is 0.5mw/cm²～600mw/cm²The ultraviolet light is irradiated for 0.5min to 60 min. In some possible implementations, the polymer liquid crystal composite film may be processed using various combinations of baking and ultraviolet irradiation. For example, the pre-baking process and the post-baking process are sequentially performed, or the first ultraviolet light irradiation and the second ultraviolet light irradiation process are sequentially performed. For another example, a pre-baking process, a first ultraviolet irradiation process, and a post-baking process are sequentially performed. For another example, the pre-baking process, the first ultraviolet irradiation, the second ultraviolet irradiation, and the like are sequentially performed, and the baking parameters (temperature, time) and the ultraviolet parameters (wavelength, light intensity, time) may be adjusted according to the combination condition, which is not specifically limited herein.

In some possible implementations, the material of the polymer liquid crystal composite film may include liquid crystal, liquid crystalline polymerized monomer, and initiator. In some possible implementations, in the material of the polymer liquid crystal composite film, the weight percentage of the liquid crystal may be 20% to 45%, the weight percentage of the liquid crystal polymerized monomer may be 5% to 35%, the weight percentage of the polymerized monomer may be 0.05% to 19.5%, and the weight percentage of the initiator may be 0.05% to 0.5%.

In an exemplary embodiment, the liquid crystal may be a small molecule nematic liquid crystal, including, but not limited to, any one or more of MAT-1370, MAT-1284, LCCC-17-435, and LCCC-17-1243. The polymerization monomer may be a thermal polymerization monomer or an ultraviolet polymerization monomer, including, but not limited to, any one or more of polyethylene glycol diglycidyl ether, bisphenol F epoxy resin, trimethylolpropane triglycidyl ether, and pentaerythritol glycidyl ether. The initiator may be a thermal initiator or a photoinitiator, including but not limited to IRG 651 any one or more of benzoin and derivatives, benzils, and benzophenones. The additive can adopt one or more of boron fluoride dipyrrole fluorescent dye, ethidium bromide and rhodamine.

In exemplary embodiments, the liquid crystalline polymerized monomer may employ any one or more of the compounds having the following chemical formula:

in some possible implementations, the polyethylene glycol diglycidyl ether can employ a compound having the following formula:

bisphenol F epoxy resins may employ compounds having the following chemical formula:

trimethylolpropane triglycidyl ether a compound having the following formula may be used:

the pentaerythritol glycidyl ether can be a compound having the following chemical formula:

thus, the preparation of the counter substrate is completed. In the first method for preparing the compensation layer in this embodiment, three compensation units are sequentially prepared, the three compensation units are made of the same material and have different thicknesses, and the three compensation units have different thicknesses by adjusting the coating thickness, so that the preparation process is mature.

The second method for preparing the compensation layer comprises the following steps:

(321) the first compensation unit 41 is formed using a first preparation method. The method comprises the following steps: a polymer liquid crystal composite film is coated on the opposite substrate 20, a liquid crystal polymer layer is formed through heating or ultraviolet irradiation treatment, and the liquid crystal polymer layer is exposed and developed by using a mask, so that a first compensation unit 41 is formed on the red color film unit, as shown in fig. 4. In some possible implementations, the polymerization degree of the liquid crystal molecules can be adjusted by adjusting parameters such as the heating temperature and the heating time of the heating process, the wavelength of the ultraviolet light, the intensity of the ultraviolet light, and the irradiation time of the ultraviolet light irradiation process, and further adjusting the refractive index nx in the X-axis direction and the refractive index ny in the Y-axis direction of the first compensation unit 41, and adjusting the phase retardation of the red light passing through the first compensation unit 41, so that the sum of the phase retardation of the red light passing through the first compensation unit 41 and the phase retardation of the red light passing through the liquid crystal layer in the display panel is an integral multiple of the wavelength of the red light.

(322) On the opposite substrate 20 formed with the above structure, a polymer liquid crystal composite film containing an ultraviolet light polymerization monomer and a thermal polymerization monomer is coated, and the polymer liquid crystal composite film is located on the color film layer 30 between the adjacent first compensation units 41, as shown in fig. 7. In an exemplary embodiment, the material of the polymer liquid crystal composite film may include liquid crystal, liquid crystalline polymerized monomer, thermal polymerized monomer, ultraviolet polymerized monomer, and initiator. In some possible implementations, in the material of the polymer liquid crystal composite film, the weight percentage of the liquid crystal may be 20% to 39.5%, the weight percentage of the liquid crystal polymerized monomer may be 5% to 20%, the weight percentage of the ultraviolet polymerized monomer may be 5% to 20%, the weight percentage of the thermal polymerized monomer may be 5% to 20%, and the weight percentage of the initiator may be 0.05% to 0.5%.

(323) The polymer liquid crystal composite film in the region corresponding to the green color film unit is subjected to ultraviolet irradiation by using the mask, that is, only the region corresponding to the green color film unit is irradiated by shielding the region through the mask, so that the ultraviolet photopolymerization monomer in the irradiated polymer liquid crystal composite film is polymerized in the diffusion process to form the second compensation unit 42, as shown in fig. 8. On-line displayIn an exemplary embodiment, the ultraviolet light irradiation process may include: the adopted wavelength is 365nm, and the light intensity is 0.5mw/cm²～600mw/cm²The ultraviolet light is irradiated for 0.5min to 60 min. In some possible implementations, by adjusting the wavelength of the ultraviolet light, the intensity of the ultraviolet light irradiation, and the irradiation time, the concentration gradient of the ultraviolet light polymerization monomer can be adjusted, so as to adjust the refractive index nx in the X-axis direction and the refractive index ny in the Y-axis direction of the second compensation unit 42, and adjust the phase retardation of the green light passing through the second compensation unit 42, so that the sum of the phase retardation of the green light passing through the second compensation unit 42 and the phase retardation of the green light passing through the liquid crystal layer in the display panel is an integral multiple of the wavelength of the green light.

(324) The mask is removed, and the opposite substrate 20 with the above structure is disposed on a heating base or in an oven for thermal polymerization, so that the thermal polymerization monomer in the polymer liquid crystal composite film in the region corresponding to the blue color filter unit is polymerized to form the third compensation unit 43, as shown in fig. 9. In an exemplary embodiment, the thermal polymerization process may include: keeping the temperature at 80-250 ℃ for 10-60 min. In some possible implementations, by adjusting the heating temperature and the heating time, the polymerization degree of the thermally polymerized monomer can be adjusted, and further, the refractive index nx in the X-axis direction and the refractive index ny in the Y-axis direction of the third compensation unit 43 are adjusted, and the phase retardation of the blue light passing through the third compensation unit 43 is adjusted, so that the sum of the phase retardation of the blue light passing through the third compensation unit 43 and the phase retardation of the blue light passing through the liquid crystal layer in the display panel is an integral multiple of the wavelength of the blue light.

In some possible implementations, the first compensation unit, the second compensation unit, and the third compensation unit have the same thickness, and the thickness is 0.5 μm to 3.0 μm. The first compensation unit is prepared by the first preparation method, so that the refractive index parameter of the first compensation unit can be adjusted conveniently. Because the second compensation unit and the third compensation unit adopt different polymerization modes, the material components in the two compensation units are different, and the refractive index parameters of the two compensation units are different, so that the refractive index difference of the first compensation unit 41 is larger than that of the second compensation unit 42, and the refractive index difference of the second compensation unit 42 is larger than that of the third compensation unit 43. Since the three compensation units have the same thickness, the three compensation layers with the same thickness can be reused as the flat layers, so that the complexity of the process for preparing the opposite substrate is reduced, and the production cost of the product is saved.

In some possible implementations, after the polymer liquid crystal composite film is coated and before the polymer liquid crystal composite film is irradiated with the ultraviolet light, an alignment treatment step may be further included, in which the polymer liquid crystal composite film is irradiated with the ultraviolet light in a linear polarization state, so that the optical axis direction of the liquid crystal molecules in the polymer liquid crystal composite film is parallel to the set direction. In some possible implementations, before the compensation layer is prepared, a step of forming an alignment film and performing an alignment treatment on the alignment film may be further included.

Thus, the preparation of the counter substrate is completed. In the second method for preparing the compensation layer, a compensation unit is prepared by a conventional process, and then the other two compensation units are prepared by the polymer liquid crystal composite film containing the ultraviolet light polymerization monomer and the thermal polymerization monomer.

The third method for preparing the compensation layer comprises the following steps:

the preparation method is an extension of the first method for preparing the compensation layer, and the main preparation process is basically the same as that of the first method for preparing the compensation layer, except that the three prepared compensation units are made of different materials and have the same thickness. In an exemplary embodiment, a third method of preparing a compensation layer includes:

(331) coating a first polymer liquid crystal composite film, forming a first liquid crystal polymer layer through heating treatment or ultraviolet irradiation treatment, and performing exposure and development treatment on the first liquid crystal polymer layer by using a mask to form a first compensation unit 41.

(332) Coating a second polymer liquid crystal composite film, forming a second liquid crystal polymer layer through heating treatment or ultraviolet irradiation treatment, and performing exposure and development treatment on the second liquid crystal polymer layer by using a mask to form a second compensation unit 42. The first liquid crystal polymer layer is different from the second liquid crystal polymer layer in material, and the thickness of the second compensation unit 42 is the same as that of the first compensation unit 41.

(333) And coating a third polymer liquid crystal composite film, forming a third liquid crystal polymer layer through heating treatment or ultraviolet irradiation treatment, and performing exposure and development treatment on the third liquid crystal polymer layer by using a mask to form a third compensation unit 43. The third liquid crystal polymer layer is different from the second liquid crystal polymer layer in material, and the thickness of the third compensation unit 43 is the same as that of the second compensation unit 42.

Thus, the preparation of the counter substrate is completed. The third method for preparing the compensation layer is to sequentially prepare three compensation units, wherein the three compensation units have the same thickness but different materials, and the three compensation units have different refractive index parameters by adjusting the materials. In some possible implementations, the third method for preparing the compensation layer may be to make the three compensation units different in material and thickness.

In some possible implementations, the method of manufacturing the opposite substrate may further include forming a planarization layer (OC), an alignment film, and performing an alignment treatment on the alignment film.

Third and second parts

The box aligning process comprises the following steps: coating a sealing body on a non-display area of the array substrate, dripping liquid crystal on a display area of the array substrate, relatively approaching the opposite substrate and the array substrate to align and press the opposite substrate and the array substrate under a vacuum condition, and curing the frame sealing glue through ultraviolet curing and/or thermosetting to finish a box aligning process to form the display panel. In some possible implementations, the sealant may be coated on the array substrate or the opposite substrate. The liquid crystal may be dispensed on the array substrate or the opposite substrate, and the invention is not limited thereto.

It should be noted that the foregoing process for manufacturing the display panel is only an exemplary process, and in practice, the array substrate and the opposite substrate may be manufactured in other manners. For example, the adjustment of the phase retardation value of the compensation unit can be achieved by simultaneously adjusting the thickness parameter and the refractive index parameter of the compensation unit by combining the adjustment of the thickness parameter of the compensation unit in the first method for preparing the compensation layer and the adjustment of the refractive index parameter of the compensation unit in the second method for preparing the compensation layer, or one or two compensation units can adopt the thickness parameter and the other two or one compensation unit can adopt the refractive index parameter. For another example, in the second method for preparing the compensation layer, two compensation units can be simultaneously prepared by using the polymer liquid crystal composite film, and then another compensation unit can be prepared by using a conventional process. For another example, in the second method for preparing a compensation layer, a compensation unit prepared separately may be a polymer liquid crystal composite film containing an ultraviolet light polymerization monomer, or a polymer liquid crystal composite film containing a thermal polymerization monomer, and the present invention is not particularly limited thereto.

Can see out through this embodiment display panel's structure and preparation process, this embodiment is through setting up three compensating unit, three compensating unit carries out phase compensation to three colour light respectively, when display panel receives inhomogeneous external force to cause to see through the light polarization state and change, three colour light can match with the phase delay of liquid crystal layer through the phase delay of three compensating unit, and then compensate the phase delay of three colour polarized light through the liquid crystal layer, make every colour light all can resume original polarization state, every colour light all can not follow the display panel of horizontal orientation and jet out when the dark state, dark state light leakage and purple problem have not only been effectively improved, and the colour cast problem has effectively been improved.

In the related art, although a compensation film layer is provided between the array substrate and the opposite substrate, a standard wavelength, for example, 550nm, is usually set in the visible light wavelength range, so that the sum of the phase retardation of the incident white light passing through the compensation film layer and the phase retardation of the white light passing through the liquid crystal layer is equal to an integral multiple of 550 nm. The research of the inventor of the application finds that the problems of dark state purple and color cast cannot be solved although the related scheme improves the dark state light leakage to a certain extent. In fact, the existing solutions only reduce the light leakage in a certain wavelength range (e.g. 550nm), and thus reduce the overall light leakage, but because light leakage still exists in other wavelength ranges, the existing solutions improve the dark state light leakage and aggravate the dark state purple and color cast problems. In contrast, in the embodiment, the three compensation units are arranged to perform phase compensation on the three color lights respectively, so that the light leakage amount is reduced in a larger wavelength range, the dark state light leakage problem is improved to the maximum extent, the light leakage amount reduced by each color is equivalent, and the color cast compensation of the three colors is realized, so that the dark state purple and color cast problems are effectively improved, the non-dispersion is realized, and the L0 picture quality is improved. Meanwhile, the scheme of the embodiment breaks the bottleneck that the curved surface of the ADS display mode is limited, and increases the feasibility of applying the ADS display mode to a curved surface product. Further, the process flow for preparing the display panel is basically the same as the existing preparation process flow, can be realized by utilizing mature preparation equipment, has small process improvement, high compatibility, simple process realization, easy implementation and good application prospect.

Fig. 10 is a schematic view of another structure of the display panel according to the embodiment of the invention, which illustrates a structure in which the color film layer and the compensation layer are disposed on one side of the opposite substrate. The present embodiment is an extension of the foregoing embodiment, the main structure of the display panel is substantially the same as that of the foregoing embodiment, the display panel includes an array substrate 100 and an opposite substrate 200 which are oppositely disposed, and a liquid crystal layer 300 disposed between the array substrate 100 and the opposite substrate 200, the array substrate 100 includes an array substrate 10 and an array structure layer 11 disposed on a surface of the array substrate 10 facing the opposite substrate 200, and the opposite substrate 200 includes an opposite substrate 20, a color film layer 30 and a compensation layer 40. As shown in fig. 10, unlike the previous embodiments, the compensation layer 40 of the present embodiment is disposed on the surface of the opposite substrate 20 facing the array substrate 100, and the color film layer 30 is disposed on the surface of the compensation layer 40 facing the array substrate 100.

Fig. 11 is a schematic view of another structure of the display panel according to the embodiment of the invention, which illustrates a structure in which the color film layer and the compensation layer are disposed on one side of the array substrate. The present embodiment is an extension of the foregoing embodiment, and the main structure of the display panel is substantially the same as that of the foregoing embodiment, and the display panel includes an array substrate 100 and an opposite substrate 200 which are oppositely disposed, and a liquid crystal layer 300 disposed between the array substrate 100 and the opposite substrate 200. As shown in fig. 11, unlike the previous embodiments, the color film layer 30 and the compensation layer 40 of the present embodiment are disposed on the surface of the array substrate 100 facing the opposite substrate 20. Specifically, the opposite substrate 200 includes an opposite substrate 20 and an opposite structure layer 21 disposed on a surface of the opposite substrate 20 on a side facing the array substrate 100. The array substrate 100 includes an array substrate 10, an array structure layer 11 disposed on a surface of the array substrate 10 facing the opposite substrate 200, a compensation layer 40 disposed on a surface of the array structure layer 11 facing the opposite substrate 200, and a color film layer 30 disposed on a surface of the compensation layer 40 facing the opposite substrate 200. In some possible implementations, the color film layer 30 may be disposed on the array structure layer 11, and the compensation layer 40 is disposed on the color film layer 30.

Fig. 12 is a schematic view of another structure of the display panel according to the embodiment of the invention, which illustrates a structure in which the color film layer is disposed on one side of the opposite substrate and the compensation layer is disposed on one side of the array substrate. The present embodiment is an extension of the foregoing embodiment, and the main structure of the display panel is substantially the same as that of the foregoing embodiment, and the display panel includes an array substrate 100 and an opposite substrate 200 which are oppositely disposed, and a liquid crystal layer 300 disposed between the array substrate 100 and the opposite substrate 200. As shown in fig. 12, unlike the previous embodiments, the color film layer 30 of the present embodiment is disposed on the surface of the opposite substrate 200 facing the array substrate 100, and the compensation layer 40 is disposed on the surface of the array substrate 100 facing the opposite substrate 200. Specifically, the opposite substrate 200 includes an opposite substrate 20, an opposite structure layer 21 disposed on a surface of the opposite substrate 20 facing the array substrate 100, and a color film layer 30 disposed on a surface of the opposite structure layer 21 facing the array substrate 100. The array substrate 100 includes an array substrate 10, an array structure layer 11 disposed on a surface of the array substrate 10 facing the opposite substrate 200, and a compensation layer 40 disposed on a surface of the array structure layer 11 facing the opposite substrate 200. In some possible implementations, the compensation layer 40 may be disposed on a surface of the opposite structure layer 21 facing the array substrate 100, and the color film layer 30 is disposed on a surface of the array structure layer 11 facing the opposite substrate 200.

The structures shown in fig. 10 to 12 also achieve the technical effects of the foregoing embodiments, and not only effectively improve the dark state light leakage and purple emission, but also effectively improve the color shift.

Based on the technical concept of the foregoing embodiment, the embodiment of the invention also provides a preparation method of the display panel. The preparation method of the display panel comprises the following steps:

s1, preparing an array substrate and an opposite substrate respectively, wherein a color film layer and a compensation layer are formed on the array substrate or the opposite substrate;

s2, forming a liquid crystal layer between the array substrate and the opposite substrate;

the color film layer comprises n color film units which are periodically arranged, the compensation layer comprises n compensation units which are periodically arranged, and the optical axis directions of the n compensation units are parallel to the initial optical axis direction of liquid crystal molecules in the liquid crystal layer; the ith color film unit is used for filtering an ith color light ray, the ith color film unit corresponds to the ith compensation unit in position, and the ith compensation unit is used for enabling the sum of the phase delay of the ith color light ray passing through the ith compensation unit and the phase delay of the ith color light ray passing through the liquid crystal layer to be integral multiple of the wavelength of the ith color light ray; n is a positive integer greater than 2. i is 1, 2, … …, n.

In an exemplary embodiment, the forming the color film layer and the compensation layer on the opposite substrate, the preparing the opposite substrate in step S1 includes:

and sequentially preparing a color film layer and a compensation layer on the opposite substrate, or sequentially preparing the compensation layer and the color film layer on the opposite substrate.

In an exemplary embodiment, preparing the compensation layer includes:

forming a polymer liquid crystal composite film, forming a liquid crystal polymer layer through heating or ultraviolet irradiation treatment, and carrying out exposure and development treatment on the liquid crystal polymer layer by adopting a mask plate to form a first compensation unit;

coating a polymer liquid crystal composite film containing an ultraviolet polymerization monomer and a thermal polymerization monomer, and performing ultraviolet irradiation on the polymer liquid crystal composite film by using a mask to form a second compensation unit;

and arranging the opposite substrate on a heating base station or in an oven, and heating the polymer liquid crystal composite film to form a third compensation unit.

In an exemplary embodiment, the n color film units include a red color film unit, a green color film unit and a blue color film unit, the n compensation units include a first compensation unit corresponding to a position of the red color film unit, a second compensation unit corresponding to a position of the green color film unit and a third compensation unit corresponding to a position of the blue color film unit, a phase delay of a red light ray passing through the first compensation unit is greater than a phase delay of a green light ray passing through the second compensation unit, and a phase delay of a green light ray passing through the second compensation unit is greater than a phase delay of a blue light ray passing through the third compensation unit.

In an exemplary embodiment, the first, second and third compensation units have the same thickness in a direction perpendicular to the display panel, the first compensation unit has a refractive index difference greater than that of the second compensation unit, and the second compensation unit has a refractive index difference greater than that of the third compensation unit.

In an exemplary embodiment, the thickness of the compensation layer is 0.5 μm to 3.0 μm.

In an exemplary embodiment, the refractive index differences of the first, second and third compensation units are the same, and in a direction perpendicular to the display panel, the thickness of the first compensation unit is greater than the thickness of the second compensation unit, and the thickness of the second compensation unit is greater than the thickness of the third compensation unit.

The specific process of manufacturing the display panel has been described in detail in the previous embodiments, and is not described herein again.

The embodiment of the invention provides a preparation method of a display panel, which is characterized in that a plurality of compensation units are arranged and respectively perform phase compensation on a plurality of color lights, when the polarization state of the transmitted light changes due to non-uniform external force on the display panel, the phase delay of the plurality of color lights passing through the plurality of compensation units can be matched with the phase delay of a liquid crystal layer, so that the phase delay of the plurality of color polarized lights passing through the liquid crystal layer is compensated, each color light can be recovered to the original polarization state, and each color light cannot be emitted from the horizontally oriented display panel in a dark state, so that the problems of dark state light leakage and purple emission are effectively improved, and the problem of color cast is effectively improved. The preparation method of the display panel can be realized by utilizing mature preparation equipment, has small process improvement, high compatibility, simple process realization, easy implementation and good application prospect.

The embodiment of the invention also provides a display device which comprises the horizontal electric field type display panel. The display device can be any product or component with a display function, such as a mobile phone, a tablet computer, a television, a display, a notebook computer, a digital photo frame, a navigator and the like.

Although the embodiments disclosed in the present disclosure are described above, the descriptions are only for the convenience of understanding the present disclosure, and are not intended to limit the present disclosure. It will be understood by those skilled in the art of the present disclosure that various changes in form and details may be made therein without departing from the spirit and scope of the disclosure, and that the scope of the present disclosure is to be limited only by the terms of the appended claims.