阅读说明：本技术 用于吸收制品的吸收层 (Absorbent layer for absorbent article ) 是由 G.A.维恩斯 于 2020-03-27 设计创作，主要内容包括：本发明描述了一种具有整合的粗梳非织造物的流体管理层。该流体管理层具有：约115克/平方米(gsm)和约250gsm之间的基重；多根吸收纤维；多根加强纤维；和多根弹性纤维。这些吸收纤维占该流体管理层的约20重量％至约60重量％。这些加强纤维具有4至10的分特,并且这些弹性纤维具有3至12的分特。(A fluid management layer with an integrated carded nonwoven is described. The fluid management layer has: a basis weight between about 115 grams per square meter (gsm) and about 250 gsm; a plurality of absorbent fibers; a plurality of reinforcing fibers; and a plurality of elastic fibers. The absorbent fibers comprise from about 20% to about 60% by weight of the fluid management layer. The reinforcing fibers have a dtex of 4 to 10 and the elastic fibers have a dtex of 3 to 12.)

1. A fluid management layer comprising an integrated carded nonwoven having a basis weight of about 115 grams per square meter (gsm) to about 250gsm, the fluid management layer comprising a plurality of absorbent fibers, a plurality of reinforcing fibers, and a plurality of elastic fibers, wherein the absorbent fibers comprise about 20% to about 60% by weight, as determined by the material composition analysis method; wherein the reinforcing fibers have a dtex of 4 to 10 and the elastic fibers have a dtex of 3 to 12, as determined by the fiber dtex method.

2. The fluid management layer of claim 1 wherein the absorbent fibers comprise a plurality of first fibers having a first decitex value and a plurality of second fibers having a second decitex value, wherein the first decitex value is less than the second decitex value.

3. The fluid management layer of claim 2 wherein the first divisor value is less than three and the second divisor value is greater than 3.

4. The fluid management layer of any of claims 2 to 3 wherein the first denominator value is 1.7 and the second denominator value is 3.3.

5. The fluid management layer of any of claims 2 to 4, wherein the ratio of the plurality of first fibers to the plurality of second fibers is from about 1.5:1 to about 1:1.5, more preferably from 1.3:1 to about 1:1.3, or most preferably from about 1.2:1 to about 1:1.2, as determined via the method of SEM method for determining the amount of cellulosic fibers.

6. The fluid management layer of any of claims 2 to 5 wherein the first plurality of fibers have a cross-sectional shape that is different from a cross-sectional shape of the second plurality of fibers.

7. The fluid management layer of any preceding claim comprising from about 21 wt% to about 50 wt%, or most preferably from about 22 wt% to about 45 wt% absorbent fibers.

8. The fluid management layer of any preceding claim comprising from about 25 to about 70 wt%, more preferably from about 30 to about 60 wt%, or most preferably from about 35 to about 50 wt% elastic fibers as determined by the material composition analysis method.

9. The fluid management layer of any of the preceding claims comprising from about 15 wt% to about 60 wt%, more preferably from about 20 wt% to about 50 wt%, or most preferably from about 25 wt% to about 40 wt% reinforcing fibers, as determined by the material composition analysis method.

10. The fluid management layer of any of the preceding claims wherein the fluid management layer comprises a spunlace nonwoven.

11. A disposable absorbent article comprising a topsheet, a backsheet, a storage layer disposed between the topsheet and the backsheet, and a fluid management layer according to any of the preceding claims.

12. The disposable absorbent article of claim 11, wherein the absorbent article exhibits a stain size of less than 5000mm ^2, more preferably less than 4500mm ^2, or most preferably less than 4200mm ^2, as determined by the stain size measurement method.

13. The disposable absorbent article of any of claims 11 to 12, wherein the absorbent article has an acquisition time of less than 10 seconds, more preferably less than 9 seconds, or most preferably less than 8.5 seconds for the first, second, and third gushes as determined by the repeated acquisition time and rewet method.

14. The disposable absorbent article of any of claims 11 to 13, wherein the absorbent article has an acquisition time of less than 4.5 seconds for the first gush as determined by the repeated acquisition time and rewet method.

15. The disposable absorbent article according to any one of claims 11 to 14, wherein the absorbent article has an acquisition time for the second gush of less than 8 seconds, more preferably less than 7 seconds, or most preferably less than 6 seconds, as determined by the repeat acquisition time and rewet method.

16. The disposable absorbent article according to any one of claims 11 to 15, wherein the storage layer comprises an Absorbent Gelling Material (AGM) disposed between two liquid permeable fibrous layers.

17. The disposable absorbent article of claim 16, wherein the AGM in the storage layer has a basis weight of between 30gsm and 50 gsm.

Technical Field

The present disclosure relates generally to an absorbent layer for a disposable absorbent article having a carded staple fiber nonwoven with improved performance characteristics.

Background

Disposable absorbent articles such as feminine hygiene articles, taped diapers, pant diapers, and incontinence articles are designed to absorb fluid from the body of the wearer. Users of such disposable absorbent articles have many concerns in selecting the products they desire. For example, leakage from products such as catamenial pads, diapers, sanitary napkins and incontinence pads is an important concern. In addition, the comfort of the product and the feel of the product as it fits the wearer's body are also an area of concern. To provide better comfort, current disposable absorbent articles are typically provided with a topsheet that is flexible, soft-feeling, and non-irritating to the wearer's skin. The topsheet itself does not contain the discharged fluid. Rather, the topsheet is fluid pervious permitting fluid to flow into the absorbent core.

In terms of comfort, some consumers may desire products that are thin enough and flexible enough not to impede their movement. However, other consumers may desire that the article have sufficient thickness and stiffness to provide the desired degree of protection. Unfortunately, these goals become more challenging when considering the dynamic nature of absorbent articles. For example, the weight, thickness, and flexibility of the absorbent article may all change as fluid enters the article. Thus, an article that can meet the consumer's requisite criteria prior to use may no longer be comfortable, flexible, or have a desired stiffness for the user after the absorbent article has absorbed a given amount of fluid.

Thus, there is a need to create an absorbent article that allows for possible trade-offs such that it is both comfortable and maintains performance. In particular, there is a need for absorbent articles that produce a balance of performance and comfort. Accordingly, there is a continuing interest in the development of new and improved absorbent articles and absorbent cores for absorbent articles.

Disclosure of Invention

Absorbent articles of the present disclosure include a topsheet, a backsheet, and an absorbent core disposed between the topsheet and the backsheet. The fluid management layer is disposed between the topsheet and the absorbent core. The fluid management layer includes an integrated carded staple fiber nonwoven material comprising a plurality of fibers.

In one particular example, the fluid management layer has: a basis weight of about 115 grams per square meter (gsm) to about 250 gsm; a plurality of absorbent fibers; a plurality of reinforcing fibers; and a plurality of elastic fibers. The absorbent fibers comprise from about 20% to about 60% by weight of the fluid management layer. The reinforcing fibers have a dtex of 4 to 10 and the elastic fibers have a dtex of 3 to 12.

Drawings

While the specification concludes with claims particularly pointing out and distinctly claiming the subject matter that is regarded as the present invention, it is believed that the invention will be more fully understood from the following description taken in conjunction with the accompanying drawings. Some of these figures may have been simplified by the omission of selected elements in order to more clearly show other elements. Such omissions of elements in certain figures do not necessarily indicate the presence or absence of particular elements in any of the exemplary embodiments, unless explicitly stated to the contrary in the corresponding written description. The figures are not drawn to scale.

FIG. 1A is a schematic view of a disposable absorbent article constructed according to the present disclosure;

FIG. 1B is a schematic view of an absorbent system of the disposable absorbent article shown in FIG. 1A;

FIG. 2 is a schematic view of a process that may be used to construct the fluid management layers of the present disclosure;

FIG. 3 is a schematic illustration of a front view of a fluid management layer constructed according to the present disclosure; and is

Fig. 4-6B are schematic diagrams illustrating an apparatus for performing the repeat acquisition time and rewet test method.

Detailed Description

As used herein, the following terms shall have the meanings specified below:

"absorbent article" refers to a wearable device that absorbs and contains liquid, and more specifically, refers to a device that is placed against or in proximity to the body of the wearer to absorb and contain the various exudates discharged from the body. Absorbent articles may include diapers, training pants, adult incontinence undergarments (e.g., liners, pads, and briefs), and/or feminine hygiene articles.

A "longitudinal" direction is a direction extending parallel to the maximum linear dimension (typically the longitudinal axis) of the article and includes directions within 45 ° of the longitudinal direction. As used herein, "length" of an article or component thereof generally refers to the size/distance of the largest linear dimension, or generally the size/distance of the longitudinal axis of the article or component thereof.

The "lateral" or "transverse" direction is orthogonal to the longitudinal direction, i.e. in the same major plane of the article and the longitudinal axis, and the transverse direction is parallel to the transverse axis. As used herein, the "width" of an article or a component thereof refers to the size/distance of the dimension orthogonal to the longitudinal direction of the article or a component thereof, i.e. orthogonal to the length of the article or a component thereof, and typically it refers to the distance/size of the dimension parallel to the transverse axis of the article or component.

The "Z-direction" is orthogonal to both the longitudinal and transverse directions.

As used herein, "machine direction" or "MD" refers to the direction parallel to the flow of carded staple fiber nonwoven through a nonwoven preparation machine and/or absorbent article product manufacturing equipment.

As used herein, "cross-machine direction" or "CD" refers to a direction parallel to the width of the carded staple fiber nonwoven preparation machine and/or absorbent article product manufacturing apparatus and perpendicular to the machine direction.

As used herein, the term "integrated" is used to describe fibers of a nonwoven material that have been interwoven, entangled, and/or pushed/pulled in the positive and/or negative Z-direction (the thickness direction of the nonwoven material). Some exemplary processes for integrating the fibers of a nonwoven web include hydroentangling and needling. Hydroentangling uses a plurality of high pressure water jets to entangle the fibers. Needling involves the use of needles to push and/or pull the fibers to entangle them with other fibers in the nonwoven. Also this type of integration does not require an adhesive or binder to hold the fibers of the fluid management layer together.

As used herein, the term "carded" is used to describe structural features of the fluid management layers described herein. Carded nonwovens utilize fibers that are cut to specific lengths, otherwise known as "short length fibers". The short length fibers may be of any suitable length. For example, short length fibers may have a length of up to 120mm or may have a length as short as 10 mm. However, if the particular set of fibers are short length fibers (e.g., viscose fibers), the length of each of the viscose fibers in the carded nonwoven is predominantly the same, i.e., short length. It is noted that where additional staple length fiber types are included, such as polypropylene fibers, the length of each of the polypropylene fibers in the carded nonwoven is also predominantly the same. However, the short length of the viscose fibres and the short length of the polypropylene fibres may be different.

In contrast, continuous filaments, such as by a spunbond process or a meltblown process, do not produce short length fibers. Rather, these filaments have indeterminate lengths and are not cut to specific lengths as described with respect to their staple length counterparts.

The carded integrated nonwoven as disclosed herein can be used in a variety of disposable absorbent articles, but is particularly useful in diapers, feminine hygiene articles, and incontinence articles such as sanitary napkins and incontinence pads. The integrated carded nonwovens of the present disclosure may be particularly useful as fluid management layers in the absorbent articles described above. Fig. 1A shows a schematic cross-section of an exemplary absorbent article.

As shown, an absorbent article 10 according to the present disclosure includes a topsheet 20, a backsheet 50, and an absorbent core 40 disposed between the topsheet 20 and the backsheet 50. The fluid management layer 30 is disposed between the topsheet 20 and the absorbent core 40. The absorbent article has a wearer-facing surface 60 and an opposite garment-facing surface 62. The wearer-facing surface 60 may comprise the topsheet 20 and the garment-facing surface 62 may comprise the backsheet 50. Additional components may be included in the wearer-facing surface 60 and/or the garment-facing surface 62. For example, if the absorbent article is an incontinence pad, a pair of barrier cuffs extending generally parallel to the longitudinal axis L of the absorbent article 10 may also form a portion of the wearer-facing surface 60. Similarly, a fastening adhesive may be present on the backsheet 50 and form a portion of the garment-facing surface 62 of the absorbent article.

Referring now to fig. 1A and 1B, the fluid management layer 30 includes opposing end edges 32A and 32B that may extend generally parallel to the transverse axis T. Moreover, the fluid management layer 30 includes side edges 31A and 32B that may extend substantially parallel to the longitudinal axis L. Similarly, the absorbent core 40 includes opposing end edges 42A and 42B that may extend generally parallel to the transverse axis T. Moreover, the absorbent core 40 may comprise side edges 41A and 41B extending substantially parallel to the longitudinal axis L.

As shown, each of the end edges 32A and 32B of the fluid management layer 30 may be disposed longitudinally outboard of the absorbent core 40. However, this is not necessarily required. For example, the end edges 32A and/or 32B may be coextensive with the absorbent core 40, or the end edges 32A and/or 32B may be disposed longitudinally inboard of the end edges 42A and/or 42B of the absorbent core 40.

Similarly, the side edges 31A and/or 31B may be disposed laterally outward of the side edges 41A and 41B of the absorbent core 40. Alternatively, the side edges 31A and/or 31B may be coextensive with the side edges 41A and/or 41B of the absorbent core 40.

As previously mentioned, the fluid management layer of the present disclosure is an integrated carded nonwoven. A schematic of a carding and integration process suitable for producing the fluid management layer 30 of the present disclosure is provided in fig. 2. As shown, a plurality of carders 210, 220, and 230 may each produce a carded nonwoven web that is transferred to a conveyor belt 240, such as 214, 224, and 234, respectively. Each of the carded nonwoven webs 214, 224, and 234 can be provided to a conveyor belt 240 via web chutes 212, 222, 232, respectively. It is also worth noting that after the carded nonwoven 214 is deposited on the conveyor belt 240, the carded nonwoven 224 is then deposited on the first carded nonwoven 214 on the conveyor belt 240. Similarly, a third carded nonwoven web 234 is deposited on the second carded nonwoven 224 and the first carded nonwoven 214 on the conveyor belt 240. Subsequently, each of the first, second, and third carded nonwoven webs 214, 224, 234 are then provided to an integration process 250 that utilizes needles and/or high pressure water streams to entangle the fibers of the first, second, and third carded nonwoven webs. Both carding and integration processes are well known in the art.

Additional carding machines may be utilized. Or alternatively, the first carded nonwoven web can be recyclated under a carding machine to create additional layering on the first carded nonwoven web. The same operation can be performed on the second carded nonwoven web. The resulting structure will be a nonwoven web having four strata.

It is noted that a variety of configurations for the fluid management layer may be achieved using the arrangement provided in the schematic diagram of fig. 2. However, it is important that the fluid management layers of the present disclosure have sufficient openness to allow rapid fluid collection, but also have the ability to lock in liquid intrusions to reduce the likelihood of rewet. Accordingly, the carded webs, i.e., 214, 224, and/or 234, can be different from one another. For example, one of the carded webs may comprise a different blend of fibers than the other carded webs. In particular, given that the first carded web will be closest to the wearer-facing surface in the absorbent article, the selection of fibers for the first carded web 214 may be such that there are more openings associated with that web. The second carded web 224 may take a similar configuration. In contrast, the third carded web 234 can be configured to reduce the likelihood of false positives of the visual system that treats the open areas as defects. The third carded web 234 can be configured to effectively distribute liquid insults to the underlying absorbent core in conjunction with or independent of reduction of false positives. In the case where at least two of the sub-layers have different fiber compositions, the nonwoven web is referred to as a heteroconfigurational configuration. Where all of the layers have the same fiber make-up, the nonwoven web is referred to as being of a homogeneous configuration.

Referring now to fig. 1A-3, the first carded nonwoven 214, the second carded nonwoven 224 (optionally, as previously described), and the third carded nonwoven 234 are integral. Once these carded nonwovens are integrated, they cannot be separated manually, at least without significant effort and time. Each carded nonwoven web forms a stratified layer throughout the fluid management layer 30. Each of the stratified layers, even when integrated into a larger fluid management layer 30, may retain the unique characteristics of at least a portion of the stratified layer in the z-direction. The fluid management layer 30 provides capillary suction to "pull" fluid through the topsheet 20, an operation that is opposed by trickle/low flow conditions. The fluid management layer 30 may also contain gushes of fluid by providing a distribution function to efficiently utilize the absorbent core 40 and provide intermediate storage until the absorbent core 40 can accept the fluid.

The fluid management layer 30 has a first surface 300A and an opposing second surface 300B. Between the first surface 300A and the second surface 300B, the fluid distribution layer 30 includes three or more stratified layers along the Z-direction. The fluid management layer 30 may have a basis weight of up to 250 grams per square meter (gsm); or a basis weight of at most 200 gsm; or a basis weight in the range of from greater than about 115gsm to about 250 gsm; or a basis weight in the range of from greater than about 120gsm to about 200 gsm; or a basis weight in the range of greater than about 125gsm to about 190gsm, including any value within these ranges and any range formed thereby. In one particular example, the fluid management layer 30 may have a basis weight of greater than about 115 gsm.

Still referring to fig. 1A-3, due to fiber integration, fluid management layer 30 does not require an adhesive or latex adhesive to achieve stability. In addition, the carded staple fiber nonwoven of the fluid management layer 30 can be made from a wide variety of suitable fiber types that yield the desired performance characteristics. For example, the fluid management layer 30 may include a combination of reinforcing fibers, absorbent fibers, and elastic fibers.

To enhance the stabilizing effect of the integration, crimped fibers may be utilized. As discussed in more detail below, the fluid management layers of the present disclosure may include absorbent fibers, reinforcing fibers, and elastic fibers. One or more of these fibers may be crimped prior to integration. For example, where synthetic fibers are utilized, the fibers may be mechanically crimped via intermeshing teeth. Also for absorbent fibers, these fibers may be mechanically crimped and/or may have chemically induced crimps due to the variable skin thickness formed during the production of the absorbent fiber.

As previously described, several samples were generated and evaluated based on a number of different criteria. The sample list is shown below. Notably, the basis weight in the "GSM" column is the target GSM. The measured gsm for each of the samples is provided in table 2.

TABLE 1

The fluid management layer of the present disclosure may comprise from about 20 wt% to about 60 wt%, more preferably from about 21 wt% to about 50 wt%, or most preferably from about 22 wt% to about 45 wt% of the absorbent fibers, specifically including any value within these ranges and any range formed thereby.

Additionally, it is noted that the numbering of the layers does not necessarily explain that the component layers form the wearer-facing surface of the fluid management layer and the garment-facing surface of the fluid management layer. For example, for samples 1-5, the resulting final web (fluid management layer web) comprised a layer 2 forming the wearer-facing surface of the web and a layer 3 forming the garment-facing surface of the web. Layer 1 is positioned between layer 2 and layer 4.

Similarly, the fluid management layer of the present disclosure may comprise from about 25% to about 70%, more preferably from about 30% to about 60%, or most preferably from about 35% to about 50%, by weight, of the elastic fibers, specifically including all values within these ranges and any ranges formed therefrom. In one particular example, the fluid management layer 30 may include about 35 wt% to about 43 wt% of the elastic fibers.

Moreover, the fluid management layers of the present disclosure may include from about 15 wt.% to about 60 wt.%, more preferably from about 20 wt.% to about 50 wt.%, or most preferably from about 25 wt.% to about 40 wt.% of the reinforcing fibers, specifically including all values within these ranges and any ranges formed therefrom. In one particular example, the fluid management layer 30 may include 25 wt% to about 35 wt% reinforcing fibers.

Whether the fluid management layer is used in an adult incontinence article or a catamenial article, it is crucial that the fluid management layer acquires the liquid insult from the topsheet and pulls the liquid away from the topsheet far enough so that the ability of the topsheet to be wet is not felt. To achieve this, the inventors have found that while absorbent fibers adjacent to the topsheet can help draw liquid from the topsheet, too much absorbent fibers can result in a moist feel to the topsheet. Therefore, the amount of absorbent fibers in the strata closest to the topsheet is critical. That is, the presence of too many absorbent fibers in the first carded nonwoven web 214 and/or the second carded nonwoven web 224 may result in the topsheet 20 having a feeling of wetness (assuming that the first carded nonwoven 214 and the second carded nonwoven 224 are closer to the topsheet 20 than the third carded nonwoven 234).

Additionally, while a higher weight percentage of absorbent fibers may be beneficial in treating more viscous fluid insults (e.g., menses), the incorporation of a higher weight percentage of absorbent fibers may also adversely affect the elasticity and stiffness of the fluid management layer. Also, too low a weight percentage of absorbent fibers may result in a more "wet feeling" topsheet, which may create an adverse impression of the product in the mind of the consumer.

In addition, the inventors have found that adjacent to the topsheet, the fluid management layer may comprise sufficient void volume to allow rapid fluid acquisition. Generally, for a given basis weight, a larger diameter fiber can provide a greater void volume between adjacent fibers than its smaller diameter counterpart. Therefore, it is also critical that the fiber size of the fibers in the layering be close to the topsheet. That is, if the diameter of the excess fibers in the first carded nonwoven 214 and/or the second carded nonwoven 224 is too small, this may adversely affect the void volume created for rapid fluid acquisition (assuming the first and second carded nonwovens 214, 224 are closer to the topsheet than the third carded nonwoven 234). This can also result in a moist feel to the topsheet.

In general, the fluid management layers of the present disclosure may have a ratio of absorbent fibers to elastic fibers of about 1:4 to about 3:1, more preferably about 1:3 to about 2:1, or most preferably about 1:2.5 to about 1.5:1, specifically including all values within these ranges and any ranges formed therefrom. Similarly, the ratio of absorbent fibers to reinforcing fibers may be in the range of about 1:3 to about 4:1, more preferably about 1:2 to about 2.5:1, or most preferably about 1:1.5 to about 1.2:1, specifically including all values within these ranges and any ranges formed therefrom.

Still referring to fig. 1A-3, according to which the inventors have carefully selected not only the type of fiber in each of the sublayers in the fluid management layer, but also the diameter (or linear density) of that fiber type. The type of fibers of each layer is discussed in more detail below. Notably, unless otherwise indicated, the following discussion regarding the types of fibers in the layers of the fluid management layers of the present disclosure assumes that the first carded nonwoven web 214 is closer to the topsheet than the third carded nonwoven web 234.

The first carded nonwoven 214 (or first laminate 214) may include absorbent fibers, reinforcing fibers, and elastic fibers. To obtain sufficient void volume and ensure that liquid insult is removed from the topsheet in a timely manner, the first stratified layer 214 may comprise from about 5% to about 35%, from about 6% to about 30%, or from about 10% to about 25% by weight of absorbent fibers, specifically including all values within these ranges and any ranges formed thereby. In one particular example, the first layer 214 may include about 10% to about 22% by weight absorbent fibers.

The first layer 214 may also include from about 20% to about 60%, from about 25% to about 50%, from about 30% to about 45%, by weight, of elastic fibers, specifically including all values within these ranges and any ranges formed therefrom. In one particular example, the first layer 214 may include about 35% to about 45% by weight of the elastic fibers.

First sub-layer 214 may also include from about 25 wt.% to about 60 wt.%, from about 30 wt.% to about 55 wt.%, and from about 35 wt.% to about 50 wt.% of reinforcing fibers, including specifically all values within these ranges and any ranges formed therefrom. In one particular example, the first layer 214 may include about 40 wt% to about 45 wt% reinforcing fibers.

The second carded nonwoven 224 (or second laminate 224) may be configured similar to the first laminate 214. This configuration of the second tier 224 facilitates manufacturing to some extent. It is also contemplated that second sublayer 224 is optional. However, when the second stratified layer 224 is disposed farther from the topsheet 20 than the first stratified layer 214, the void volume may be adjusted slightly downward. Accordingly, smaller diameter fibers may be utilized in the second tier 224 to help establish a capillary gradient that directs fluid away from the topsheet.

With respect to the third carded nonwoven 234 (or third layer 234), the configuration of the layer may vary. In order to properly deliver the desired acquisition and distribution attributes, absorbent fibers may be utilized. Thus, the third component 234 can comprise about 40 wt.% to about 100 wt.%, about 50 wt.% to about 75 wt.%, or about 55 wt.% to about 65 wt.% of the absorbent fibers, specifically including all values within these ranges and any ranges formed therefrom. In one particular example, the third sublayer 234 may include 65% absorbent fibers.

With respect to the reinforcing and elastic fibers in the third sub-layer 234, as noted, the third sub-layer should be provided with the ability to acquire and distribute fluid from the void volume of the first and second sub-layers 214, 224. Additionally, the third layer may include between 10 wt.% and about 45 wt.%, between about 15 wt.% and about 40 wt.%, or between about 20 wt.% and about 35 wt.% of the reinforcing and/or elastic fibers, specifically including all values within these ranges and any ranges formed thereby.

Where a fourth layer is included as previously described, suitable combinations of absorbent fibers, reinforcing fibers, and/or elastic fibers may be utilized. For example, the fourth layer may include between about 5 wt% to about 50 wt%, 7 wt% to about 40 wt%, or about 10 wt% to about 30 wt% absorbent fibers. In one particular example, the fourth layer includes between about 10% to about 30% by weight absorbent fibers.

The fourth layer may include between 15 wt.% to about 65 wt.%, about 20 wt.% to about 55 wt.%, or about 30 wt.% to about 50 wt.% of the elastic and/or reinforcing fibers. In one particular example, the fourth layer includes between about 30 wt% to about 45 wt% of the reinforcing fibers and/or elastic fibers.

Still referring to fig. 1A-3, where absorbent fibers are utilized, any suitable diameter of absorbent fibers may be utilized. A suitable diameter measure may be associated with the linear density. For first and/or second sublayers 214, 224, larger values of line density may be utilized because increased void volume may be desirable. For example, in the first and/or second strata 214, 224, the absorbent fibers can have a linear density in a range of from about 1 dtex to about 4 dtex, from about 2.0 dtex to about 3.7 dtex, or from about 2.5 dtex to about 3.5 dtex, specifically including all values within these ranges and any ranges formed therefrom. In one particular example, the absorbent fibers may include a linear density of about 1.7 dtex.

The linear density of the absorbent fibers in the third component 234 can range from about 1 dtex to about 3 dtex, from about 1.4 dtex to about 2.7 dtex, or from about 1.7 dtex to about 2.0 dtex, specifically including all values within these ranges and any ranges formed therefrom. In one particular example, the absorbent fibers in the third layer 234 may include a linear density of about 1.7 dtex. In another example, the third component 234 may include absorbent fibers having two different cross-sectional shapes (e.g., circular and trilobal) and/or having two different decitex values (e.g., 1.7 decitex and 3.3 decitex). The fourth layer may be configured as described above with respect to the first and second or third layers.

Where the fluid management layer of the present disclosure includes a plurality of linear densities of absorbent fibers, the ratio of the first linear density absorbent fibers to the second linear density absorbent fibers may be from about 1.5:1 to about 1:1.5, more preferably from 1.3:1 to about 1:1.3, or most preferably from about 1.2:1 to about 1:1.2, specifically including all values within these ranges and any ranges formed thereby. The ratio of the absorbent fibers can be determined by the method of SEM method used to determine the amount of cellulose fibers. Also, where multiple linear densities of absorbent fibers are utilized, the first plurality of fibers may have a dtex that is different from the dtex of the second plurality of fibers. For example, the first plurality of fibers may have a dtex less than 3, and the second plurality of fibers may have a dtex greater than 3.

The absorbent fibers of the fluid management layer 30 may have any suitable shape. Some examples include trilobal, "H" -shaped, "Y" -shaped, "X" -shaped, "T" -shaped, or circular. Further, the absorbent fibers may be solid, hollow, or multi-hollow. Other examples of suitable multilobal absorbent fibers for use in the carded staple fiber nonwovens detailed herein are disclosed in the following patents: U.S. patent 6,333,108 to Wilkes et al, U.S. patent 5,634,914 to Wilkes et al, and U.S. patent 5,458,835 to Wilkes et al. The trilobal shape improves wicking and improves masking. Suitable trilobal rayon fibers are available from Kelheim fibers and are sold under the trade name Galaxy. Although each layer may comprise different shapes of absorbent fibers (much like described above), not all carding equipment may be adapted to handle such variations between two/more layers. In one particular example, the fluid management layer comprises circular absorbent fibers.

Any suitable absorbent fiber may be utilized. Some conventional absorbent fibers include cotton, rayon, or regenerated cellulose, or combinations thereof. In one example, the fluid management layer 30 may include viscose cellulose fibers. The absorbent fibers may comprise short length fibers. The staple length of the absorbent fibers can range from about 20mm to about 100mm, or from about 30mm to about 50mm, or from about 35mm to about 45mm, specifically including all values within these ranges and any ranges formed therefrom.

As previously mentioned, the fluid management layer 30 may also include reinforcing fibers in addition to the absorbent fibers. Reinforcing fibers may be utilized to help provide structural integrity to the fluid management layer 30. The reinforcing fibers can help improve the structural integrity of the fluid management layer 30 in the machine direction and cross direction, which facilitates web handling during handling of the fluid management layer for incorporation into a disposable absorbent article. In view of this, the constituent materials of the reinforcing fibers, the weight percentage of the reinforcing fibers, and the heating process should be carefully selected. The thermal hardening process is discussed below.

Any suitable reinforcing fiber may be utilized. Some examples of suitable reinforcing fibers include bicomponent fibers comprising polyethylene and polyethylene terephthalate components or polyethylene terephthalate and co-polyethylene terephthalate components. The components of the bicomponent fiber can be arranged in a sheath-core configuration, a side-by-side configuration, an eccentric sheath-core configuration, a trilobal configuration, and the like. In one particular example, the reinforcing fibers may comprise bicomponent fibers arranged in a concentric core-sheath configuration having a polyethylene/polyethylene terephthalate component, wherein the polyethylene is the sheath. As another example, monocomponent fibers may be utilized, and the constituent materials of the monocomponent may include polypropylene or polylactic acid (PLA). It is noted that these components, such as polypropylene and polylactic acid, may also be used in bicomponent fibers.

The reinforcing fibers may be polyethylene terephthalate (PET) fibers or other suitable non-cellulosic fibers known in the art. The staple length of the reinforcing fibers may be in the range of about 28mm to about 100mm, or in the range of about 37mm to about 50 mm. Some carded staple fiber nonwovens include reinforcing fibers having staple lengths of about 38mm to 42 mm. The PET fibers may have any suitable structure or shape. For example, the PET fibers may be round or have other shapes, such as helical, notched elliptical, trilobal, notched ribbon, and the like. Furthermore, the PET fibers may be solid, hollow, or multi-hollow. In some embodiments of carded staple fiber nonwovens, the reinforcing fibers may be fibers made of hollow/spiral PET. Optionally, the reinforcing fibers may be spiral-pleated or flat-pleated. The reinforcing fibers may have a crimp value of between about 4 and about 12 crimps per inch (cpi), or between about 4 and about 8cpi, or between about 5 and about 7cpi, or between about 9 and about 10 cpi. Specific non-limiting examples of reinforcing fibers are available from Wellman, inc. Other examples of reinforcing fibers suitable for use in the carded staple fiber nonwovens detailed herein are disclosed in U.S. patent 7,767,598 to Schneider et al.

Other suitable examples of reinforcing fibers include polyester/co-extruded polyester fibers. The reinforcing fibers may be so-called bicomponent fibers, wherein the individual fibers are provided by different materials, typically a first polymer material and a second polymer material. The two materials may be chemically different (so the fibres are chemically dissimilar), or they may differ only in their physical properties but at the same time be chemically identical (so the fibres are chemically homogeneous). For example, the intrinsic viscosities of the two materials may not be the same, and they have been found to affect the crimp properties of the bicomponent fiber. Bicomponent fibers suitable for use as reinforcing fibers are side-by-side bicomponent fibers as disclosed, for example, in WO 99/00098. The reinforcing fibers may also be a blend of bicomponent fibers with polyester fibers.

With particular reference to bicomponent fibers composed of polypropylene/polyethylene fiber compositions, in a cross-sectional view of the fibers, the material having the higher softening temperature can provide the central portion (i.e., core) of the fiber. The core typically enables the bicomponent fiber to transmit forces and to have some rigidity or otherwise provide a structure with elasticity. The outer coating (i.e., sheath) on the core of the fibers may have a lower melting point and is used to facilitate thermal bonding of substrates comprising such fibers. In one embodiment, the polypropylene core is provided with a polyethylene coating on the outside, such that about 50% by weight of the fibrous material is polypropylene and 50% by weight of the fibrous material is polyethylene. Of course, other quantities may be selected. For example, the bicomponent fibers may have a composition of about 30% to about 70% by weight polyethylene, while the other fibers have about 35% to about 65% by weight polyethylene. In some embodiments, the bicomponent fibers may have a composition of from about 40% to about 60% or from about 45% to about 55% by weight of polyethylene.

Another suitable bicomponent reinforcing fiber is a fiber having a circular cross-section with a hollow space in the center with a helical pleat. 10% to 15% of the cross-sectional area may be hollow, or 20% to 30% of the cross-sectional area may be hollow. Without being bound by theory, it is believed that the helical pleating of the fibers is beneficial to their liquid acquisition and distribution properties. The helical pleat is assumed to increase void space in acquisition members formed from such fibers. Typically, absorbent articles are exposed to a certain pressure exerted by the wearer when worn, which pressure may reduce the void space in the acquisition member. Having good permeability and sufficient available void space is important for good liquid distribution and transport. It is also believed that the bicomponent helically pleated fibers described above are adapted to maintain sufficient void volume even when the acquisition member is exposed to pressure. In addition, it is also believed that the helically pleated fibers provide good permeability for a given fiber dtex value, with the hollow fiber cross-section allowing the fibers to have a larger outer diameter than a compact cross-section. The outer diameter of the fibers appears to determine the permeability properties of an acquisition member formed from such fibers.

Any suitable size of reinforcing fibers may be utilized in the layering of the fluid management layers. Suitable linear densities of the reinforcing fibers may be from about 1.7 dtex to about 12 dtex, from about 4 dtex to about 10 dtex, or from about 5 dtex to about 7 dtex, specifically including all values within these ranges and any ranges formed therefrom. In one particular example, the reinforcing fibers may include 7 dtex polyethylene terephthalate/co-polyethylene terephthalate fibers. Similar to the absorbent fibers, it is contemplated that the reinforcing fibers also include decitex that varies between and/or within the strata.

As previously described, the fluid management layer 30 may be heat treated (thermally hardened). This heat treatment may create joints between the reinforcing fibers of the fluid management layer 30. Thus, with a higher percentage of reinforcing fibers present, more connection points may be formed. Too many additional connection points may create a much stiffer fluid management layer, which may adversely affect comfort. Therefore, the weight percentage of the reinforcing fibers is crucial when designing the absorbent article.

With respect to the thermal hardening process, any suitable temperature may be utilized. Moreover, the appropriate temperature may be influenced in part by the constituent chemicals of the reinforcing fibers and by the treatment of the fluid management layer web. The fluid management layer web may be thermally cured at 132 degrees celsius. It should also be noted that in order to provide uniform stiffness properties throughout the fluid management layer, any heating operation should be arranged to provide uniform heating to the fluid management layer web. Even small temperature changes can greatly affect the tensile strength of the fluid management layer.

As previously mentioned, the fluid management layers of the present disclosure may additionally include elastic fibers. The elastic fibers may help the fluid management layer maintain its permeability. Any size suitable fiber may be utilized. For example, the elastic fibers can have a linear density of about 4 to about 12, about 6 to about 11, or about 8 to about 10 dtex, specifically including all values within these ranges and any ranges formed therefrom. In one particular example, the elastic fibers can comprise hollow spiral polyethylene terephthalate fibers having a linear density of about 6.7 dtex to about 10 dtex. In another specific example, the fluid management layer may include elastic fibers having variable cross-sections (e.g., circular and hollow helical) and/or may include elastic fibers having variable decitex.

Notably, if a smaller fiber size is utilized, it is expected that the elasticity of the fluid management layer will be reduced. Also, at the same weight percentage, a higher number of fibers per gram would equate to a lower permeability of the fluid management layer as the size decreases.

The elastic fibers may be any suitable thermoplastic fibers such as polypropylene (PP), polyethylene terephthalate, or other suitable thermoplastic fibers known in the art. Staple fiber lengths of the elastic fibers may range from about 20mm to about 100mm, or from about 30mm to about 50mm, or from about 35mm to about 45 mm. The thermoplastic fibers can have any suitable structure or shape. For example, the thermoplastic fibers may be round or have other shapes, such as a spiral, a notched oval, a trilobal, a notched ribbon, and the like. Further, the PP fibers may be solid, hollow, or multi-hollow. The elastic fibers may be solid and round in shape. Other suitable examples of elastic fibers include polyester/co-extruded polyester fibers. In addition, other suitable examples of elastic fibers include bicomponent fibers such as polyethylene/polypropylene, polyethylene/polyethylene terephthalate, polypropylene/polyethylene terephthalate. These bicomponent fibers can be configured as a sheath and a core. Bicomponent fibers can provide a cost effective way to increase the basis weight of the material while also optimizing the pore size distribution.

Notably, the reinforcing fibers and elastic fibers should be carefully selected. For example, while the constituent chemistries of the reinforcing fibers and elastic fibers may be similar, the elastic fibers should be selected such that the melting temperature of their constituent materials is higher than the melting temperature of the reinforcing fibers. Otherwise, during heat treatment, the elastic fibers will bond to the reinforcing fibers and vice versa, and an overly rigid structure may result. It is noted that where the reinforcing fibers comprise bicomponent fibers (i.e., a core/sheath configuration), the elastic fibers may comprise the chemical component of the core.

As previously described, various attributes were tested with respect to samples 1-5. Table 2 provides a list of the attributes tested.

TABLE 2

Table 3 is a table of data relating to simulated menses stain size on the samples described previously as well as some conventional samples. Each of the sample and the conventional sample were incorporated into an absorbent article that included a topsheet that was an apertured film. Conventional sample absorbent articles also include an airlaid core. Specifically, the conventional sample 1 absorbent article included an airlaid core having a basis weight of 170gsm, and the conventional sample 2 absorbent article included an airlaid core having a basis weight of 163 gsm. Conventional sample 1 and conventional sample 2 are three layered fluid management layers having a basis weight of 50gsm and an isotropic construction. Each of the tiers comprises: 40% by weight of 1.7 dtex viscose rayon; 20% by weight of 4.4 dtex polyethylene terephthalate; and 40 wt% 1.7 polypropylene/polyethylene bicomponent fiber. Each of samples 1-5 included a storage layer disposed opposite the topsheet. The storage layer is a laminate material comprising AGM sandwiched between two liquid permeable fibrous layers, e.g. tissue layers, and having an AGM basis weight of between 30gsm and 50 gsm. The storage layer is discussed in additional detail below.

Sample numbering	Stain size (mm ^2)
		Sample 1	3867
Sample 2	3530
		Sample 3	5387
Sample No. 4	6104
		Sample No. 5	5220
General sample 1	5593
		Conventional sample 2	5401

TABLE 3

As shown by the data in table 3, absorbent articles comprising the fluid management layer of sample 1 or sample 2 constructed according to the present disclosure exhibited significantly reduced staining compared to the other samples. Absorbent articles constructed according to the present disclosure exhibit stains of less than 5000mm 2, more preferably less than 4500mm 2, or most preferably less than 4200mm 2, specifically including all values within this range and any ranges formed therefrom.

Table 4 includes data on the acquisition rates for a plurality of inrush currents.

TABLE 4

As shown by the data in table 4, the acquisition time associated with the absorbent articles combining sample 1 and sample 2 was greatly reduced relative to the acquisition time of the remaining samples. Also in the case of rewet, samples 1 and 2 outperformed most of the other samples tested or at least functioned equally with sample 3. The absorbent article incorporating sample 2 exhibited the best rewet characteristics in all absorbent articles.

Absorbent articles constructed according to the present disclosure may exhibit acquisition times of less than 10 seconds, more preferably less than 9 seconds, or most preferably less than 8.5 seconds for each of the first, second, and third gushes, specifically including all values within these ranges and any ranges formed thereby. Absorbent articles constructed according to the present disclosure may exhibit an acquisition rate of less than 4.5 seconds for the first gush, specifically including all values within this range and any ranges formed therefrom. Absorbent articles constructed according to the present disclosure may exhibit an acquisition speed for the second gush of less than 8 seconds, more preferably less than 7 seconds, or most preferably less than 6 seconds, specifically including all values within these ranges and any ranges formed thereby.

Absorbent articles constructed according to the present disclosure can exhibit acquisition rates

Absorbent article

Referring back to fig. 1A and 1B, as previously described, the disposable absorbent articles of the present disclosure may include a topsheet 20 and a backsheet 50. The fluid management layer 30 and absorbent core 40 may be sandwiched between the topsheet and the backsheet. Additional layers may be positioned between the topsheet 20 and the backsheet 50.

The topsheet 20 may be joined to the backsheet 50 by attachment methods such as are known in the art (not shown). The topsheet 20 and the backsheet 50 may be joined directly to each other in the periphery of the article and may be joined together indirectly by joining them directly to the absorbent core 40, the fluid management layer 30 and/or additional layers disposed between the topsheet 20 and the backsheet 50. Such indirect or direct engagement may be accomplished by attachment methods well known in the art.

The topsheet 20 may be compliant, soft feeling, and non-irritating to the wearer's skin. Suitable topsheet materials include liquid pervious materials that are oriented toward and contact the body of the wearer, allowing bodily discharges to pass rapidly therethrough without allowing fluid to pass back through the topsheet to the skin of the wearer. While the topsheet allows for rapid transfer of fluid therethrough, the lotion composition can also be transferred or migrated to the outside or inside of the wearer's skin.

A suitable topsheet 20 may be manufactured from a wide variety of materials, such as woven and nonwoven materials; an apertured film material comprising an apertured formed thermoplastic film, an apertured plastic film and a filament wound apertured film; hydroforming a thermoplastic film; a porous foam; reticulated foam; a reticulated thermoplastic film; a thermoplastic scrim; or a combination thereof.

Apertured film materials suitable for use as topsheets include those apertured plastic films that do not absorb and transmit body exudates and that ensure that fluids transmitted through the topsheet flow back or not at all. Non-limiting examples of other suitable shaped films (including apertured and non-apertured shaped films) are described in more detail in the following patents: U.S. Pat. No. 3,929,135 to Thompson at 30/12/1975; U.S. Pat. No. 4,324,246 to Mullane et al, 4/13 in 1982; U.S. Pat. No. 4,342,314 to Radel et al, 8/3/1982; U.S. Pat. No. 4,463,045 to Ahr et al, 31/7/1984; U.S. Pat. No. 5,006,394 to Baird at 9.4.1991; U.S. Pat. No. 4,609,518 to Curro et al, 9/2/1986; and U.S. Pat. No. 4,629,643, issued to Curro et al, 12/16/1986.

Non-limiting examples of woven and nonwoven materials suitable for use as a topsheet include fibrous materials made from natural fibers (e.g., cotton, including 100% organic cotton), modified natural fibers, synthetic fibers, or combinations thereof. These fibrous materials may be hydrophilic or hydrophobic, but preferably the topsheet is hydrophobic or rendered hydrophobic. As an option, portions of the topsheet can be treated to be hydrophilic by using any known method for making topsheets comprising hydrophilic components. The nonwoven fibrous topsheet 20 can be produced by any known process for making nonwoven webs, non-limiting examples of such processes include spunbonding, carding, wet-laying, air-laying, meltblowing, needle-punching, mechanical winding, thermo-mechanical winding, and hydroentangling.

The topsheet 20 may be formed from a combination of apertured film and nonwoven. For example, the film web and nonwoven web may be combined as described in U.S. patent 9,700,463. Alternatively, the film may be extruded onto the nonwoven material, which is believed to provide enhanced contact between the film layer and the nonwoven material. Exemplary processes for such combination are described in U.S. patents 9,849,602 and 9,700,463.

The backsheet 50 may be positioned adjacent the garment-facing surface of the absorbent core 40 and may be joined thereto by attachment methods such as those well known in the art. For example, the backsheet 50 may be secured to the absorbent core 40 by a uniform continuous layer of adhesive, a patterned layer of adhesive, or a series of separate lines, spirals, or spots of adhesive. Alternatively, the attachment method may include the use of thermal bonding, pressure bonding, ultrasonic bonding, dynamic mechanical bonding, or any other suitable attachment method or combination of these attachment methods as known in the art.

The backsheet 50 may be impervious or substantially impervious to liquids (e.g., urine) and may be manufactured from a lightweight, thin plastic film, although other liquid impervious, flexible materials may also be used. As used herein, the term "flexible" refers to materials that are compliant and readily conform to the general shape and contours of the human body. The backsheet 207 may prevent or at least inhibit the exudates absorbed and contained by the absorbent core 205 from wetting a garment article, such as an undergarment, in contact with the incontinence pad 10. However, the backsheet 50 may allow vapors to escape from the absorbent core 40 (i.e., breathable), while in some cases the backsheet 50 may not allow vapors to escape (i.e., non-breathable). Accordingly, backsheet 50 may comprise a polymeric film, such as a thermoplastic polyethylene film or a polypropylene film. For example, a suitable material for the backsheet 50 is a thermoplastic film having a thickness of about 0.012mm (0.5 mil) to about 0.051mm (2.0 mils). Any suitable backsheet known in the art may be used in the present invention.

The backsheet 50 acts as a barrier to any absorbent bodily fluids that may pass through the absorbent core 40 to its garment surface, resulting in a reduced risk of soiling undergarments or other garments. Preferred materials are soft, smooth, pliable liquid and vapor permeable materials that provide comfortable softness and conformability, and that produce low noise so that no objectionable noise is caused while exercising.

Exemplary backsheets are described in U.S. patent 5,885,265(Osborn, III.) published on 23.3.1999; 6,462,251(Cimini) published at 10/8/2002; 6,623,464(Bewick-Sonntag) published on 23/9/2003 or U.S. Pat. No. 6,664,439(Arndt) published on 16/12/2003. Suitable bi-or multi-layer breathable backsheets for use herein include those exemplified in U.S. patent 3,881,489, U.S. patent 4,341,216, U.S. patent 4,713,068, U.S. patent 4,818,600, EP 203821, EP 710471, EP 710472, and EP 793952.

Suitable breathable backsheets for use herein include all breathable backsheets known in the art. There are two main types of breathable backsheets: a single layer breathable backsheet that is breathable and liquid impervious, and a backsheet having at least two layers that combine to provide breathability and liquid impermeability. Suitable single layer breathable backsheets for use herein include those described in, for example, GB a 2184389, GB a 2184390, GB a 2184391, U.S. patent No. 4,591,523, U.S. patent No. 3989867, U.S. patent No. 3,156,242 and WO 97/24097.

The backsheet is a nonwoven web having a basis weight between about 20gsm and about 50 gsm. In one embodiment, the backsheet is a 23gsm spunbond nonwoven web of relatively hydrophobic 4 denier polypropylene fibers available from Fiberweb Neuberger under the trade name F102301001. The backsheet may be coated with an insoluble liquid swellable material as described in U.S. patent 6,436,508 (ciammachella) published on 8/20 2002.

The backsheet has a garment-facing side and an opposite body-facing side. The garment facing side of the backsheet comprises a non-adhesive region and an adhesive region. The adhesive region may be provided by any conventional method. Pressure sensitive adhesives have generally been found to be very suitable for this purpose.

The absorbent core 40 of the present disclosure may comprise any suitable shape including, but not limited to, oval, circular, rectangular, asymmetric, and hourglass shapes. For example, in some forms of the invention, the absorbent core 205 may have a contoured shape, e.g., narrower in the middle region than in the end regions. As another example, the absorbent core may have a tapered shape with a wider portion at one end region of the pad and tapering to a narrower end region at the other end region of the pad. The absorbent core 40 may include varying stiffness in the MD and CD.

The configuration and construction of the absorbent core 40 may vary (e.g., the absorbent core 40 may have varying caliper zones, a hydrophilic gradient, a superabsorbent gradient, or lower average density and lower average basis weight acquisition zones). In addition, the size and absorbent capacity of the absorbent core 40 can also be varied to accommodate a wide variety of wearers. However, the total absorbent capacity of the absorbent core 40 should be compatible with the design loading and intended use of the disposable absorbent article or incontinence pad 10.

In some forms of the invention, the absorbent core 40 may include multiple functional layers in addition to the first laminate and the second laminate. For example, the absorbent core 40 may include a core wrap (not shown) that may be used to enclose the first and second laminates, as well as other optional layers. The core wrap may be formed from two nonwoven materials, substrates, laminates, films, or other materials. In one form, the core wrap may comprise only a single material, substrate, laminate, or other material that is wrapped at least partially around itself.

The absorbent core 40 of the present disclosure may include one or more adhesives, for example, to help secure the SAP or other absorbent material within the first laminate and the second laminate.

Absorbent cores containing relatively high levels of SAP with various core designs are disclosed in U.S. patent No. 5,599,335 to Goldman et al, EP 1,447,066 to Busam et al, WO 95/11652 to Tanzer et al, U.S. patent publication No. 2008/0312622a1 to huntorf et al, and WO2012/052172 to Van Malderen. These can be used to construct the superabsorbent layer.

The addition of the core of the present disclosure is contemplated. Specifically, potential additions to current multiple laminate Absorbent cores are described in U.S. Pat. No. 4,610,678 entitled "High-Density Absorbent Structures" issued to Weisman et al on 9/9 1986; U.S. Pat. No. 4,673,402 entitled "Absorbent articules With Dual-Layered Cores" to Weisman et al, 16.6.1987; U.S. Pat. No. 4,888,231 entitled "Absorbent Core Having A Dusting Layer" issued to Angstadt at 19.12.1989; and U.S. Pat. No. 4,834,735 entitled "High Density Absorbent Members Having Low Power Density and Low Basis Weight Acquisition Zones" issued on 30.5.1989. The Absorbent core may further comprise an additional layer which mimics a dual core system comprising an acquisition/distribution core of chemically stiffened fibers positioned over an Absorbent storage core, as described in U.S. Pat. No. 5,234,423 entitled "Absorbent Article With Elastic Waist Feature and Enhanced Absorbent Article" issued on 8/10 of 1993 to Alemany et al; and U.S. Pat. No. 5,147,345. These are useful as long as they do not counteract or conflict with the action of the below-described laminate of the absorbent core of the present invention.

Some examples of suitable absorbent cores 40 that may be used in the absorbent articles of the present disclosure are described in U.S. patent application publications 2018/0098893 and 2018/0098891.

As previously mentioned, absorbent articles comprising a fluid management layer of the present disclosure comprise a storage layer. Referring back to fig. 1A and 1B, the storage layer will generally be positioned where the absorbent core 40 is depicted. The storage layer may be constructed as described in relation to the absorbent core. The storage layer may comprise a conventional absorbent material. In addition to conventional absorbent materials such as creped cellulose wadding, fluff cellulose fibers, rayon fibers, wood pulp fibers, also known as airfelt, and textile fibers, the storage layer often comprises superabsorbent material which absorbs fluids and forms hydrogels. Such materials are also known as Absorbent Gelling Materials (AGM) and may be included in particulate form. AGMs are generally capable of absorbing large amounts of body fluids and retaining them under moderate pressure. Synthetic fibers may also be used for the second storage layer, including cellulose acetate, polyvinyl fluoride, polyvinylidene 1, 1-dichloride, acrylic resins (such as orlon), polyvinyl acetate, insoluble polyvinyl alcohol, polyethylene, polypropylene, polyamides (such as nylon), polyesters, bicomponent fibers, tricomponent fibers, mixtures thereof, and the like. The storage layer may also include filler materials such as perlite, diatomaceous earth, vermiculite, or other suitable materials that reduce rewet problems.

The storage layer may have a uniform distribution of Absorbent Gelling Material (AGM) or may have a non-uniform distribution of AGM. AGM may be in the form of grooves, pits, strips, criss-cross patterns, swirls, dots, or any other conceivable pattern (two-dimensional or three-dimensional). The AGM may be sandwiched between a pair of liquid permeable fibrous cover layers, such as tissue layers. Or the AGM may be at least partially encapsulated by a single fibrous cover layer. An exemplary storage layer comprising superabsorbent polymer (SAP) (e.g., AGM) particles may have a liquid permeable layer (such as, for example, 18 g/m) laminated to it²A conventional tissue layer of basis weight) or a hydrophilic nonwoven material (such as a topsheet conventionally used in absorbent articles). Such materials are commercially available, such as under the trade nameLaminates are commercially available from Gelok International, OH, US, or under the trade nameCommercially available from Domtar, SC, US. The storage layer may comprise a first cellulosic layer and a second cellulosic layer with superabsorbent material disposed therebetween. In this case the storage layer may be laminated with mechanical compression (instead of using an adhesive).

Portions of the storage layer may be formed solely of superabsorbent material, or may be formed of superabsorbent material dispersed in a suitable carrier, such as cellulosic fibers or reinforcing fibers in the form of fluff. One example of a non-limiting storage layer is a first layer formed only of superabsorbent material disposed on a second layer formed of superabsorbent material dispersed within cellulosic fibers.

Materials particularly suitable for the storage layer have been described in EP2872097 and may be sold under the trade name "eCore^TM"e.g. eCore^TM100. Or eCore^TM270. Or eCore^TM400 is commercially available from Glatfelter Falkhang, Germany. Such materials include an airlaid mixture of cellulose fibers and SAP particles, which is wrapped with a latex surface layer sprayed onto the cellulose, resulting in a highly absorbent but light, flexible and dust-free structure.

Detailed examples of absorbent cores formed from layers of superabsorbent material and/or layers of superabsorbent material dispersed within cellulosic fibers that can be used in absorbent articles (e.g., sanitary napkins, incontinence articles) detailed herein are disclosed in U.S. patent publication 2010/0228209a 1. Absorbent cores comprising relatively high levels of SAP with various core designs are disclosed in U.S. patent 5,599,335 to Goldman et al, EP 1,447,066 to Busam et al, WO 95/11652 to Tanzer et al, U.S. patent publication 2008/0312622a1 to huntorf et al, WO2012/052172 to Van Malderen, U.S. patent 8,466,336 to carrucci, and U.S. patent 9,693,910 to carrucci. These may be used to construct the second storage layer.

Notably, with the fluid management layers of the present disclosure in the mentioned basis weight ranges, the storage layer can reduce capacity to some extent. For example, for catamenial products, the storage layer may have a basis weight between 15gsm to about 130gsm, more preferably between about 15gsm to about 90gsm, or most preferably between about 15gsm to about 75gsm, specifically including all values within these ranges and any ranges formed therefrom. In the context of incontinence products, the storage layer may have a basis weight in the range of about 120gsm to about 500gsm, more preferably in the range of about 120gsm to about 400gsm, or most preferably in the range of about 120gsm to about 300gsm, specifically including all values within these ranges and any ranges formed thereby.

The absorbent article 10 may also include barrier cuffs. Some examples of other suitable barrier cuffs are described in the following patents: U.S. Pat. No. 4,695,278, U.S. Pat. No. 4,704,115, U.S. Pat. No. 4,795,454, U.S. Pat. No. 4,909,803, U.S. patent application publication No. 2009/0312730. Additional suitable barrier cuffs are described in U.S. patent application publications 2018/0098893 and 2018/0098891.

Additional embodiments：

Example A

A1. An absorbent article comprising a topsheet, a backsheet, a storage layer disposed between the topsheet and the backsheet, and a fluid management layer disposed between the storage layer and the topsheet, wherein the fluid management layer comprises an integrated carded nonwoven having a basis weight of 115 grams per square meter to about 250gsm, wherein the fluid management layer comprises a plurality of absorbent fibers, a plurality of reinforcing fibers, and a plurality of elastic fibers, wherein the ratio of absorbent fibers to elastic fibers is in the range of about 1:4 to about 3:1, and wherein the ratio of absorbent fibers to reinforcing fibers is in the range of about 1:3 to about 4: 1.

A2. The absorbent article of embodiment a1, wherein the ratio of absorbent fibers to elastic fibers is from about 1:3 to about 2:1, or most preferably from about 1:2.5 to about 1.5: 1.

A3. The absorbent article of any of embodiments a 1-a 2, wherein the ratio of absorbent fibers to reinforcing fibers is from about 1:2 to about 2.5:1, or most preferably from about 1:1.5 to about 1.2: 1.

A4. The absorbent article according to any of embodiments a1 to A3, wherein the absorbent article has an acquisition time of less than 10 seconds, more preferably less than 9 seconds, or most preferably less than 8.5 seconds for each of the first gush, the second gush, and the third gush, according to a repeated acquisition and rewet method.

A5. The absorbent article of any of embodiments a 1-a 4, wherein the absorbent article may exhibit an acquisition speed of less than 4.5 seconds for a first gush.

A6. The absorbent article according to any of embodiments a 1-a 5, wherein the absorbent article may exhibit an acquisition speed for the second gush of less than 8 seconds, more preferably less than 7 seconds, or most preferably less than 6 seconds.

A7. The absorbent article of any of embodiments a 1-a 6, wherein the absorbent fibers comprise a plurality of first fibers having a first dtex value and a plurality of second fibers having a second dtex value, wherein the first dtex value is less than the second dtex value.

A8. The absorbent article of embodiment a7, wherein the first dtex is less than three and the second dtex is greater than 3.

A9. The absorbent article of any one of embodiments a 7-A8, wherein the first dtex value is 1.7 and the second dtex value is 3.3.

A10. The absorbent article according to any one of embodiments a 7-a 9, wherein the ratio of the plurality of first fibers to the plurality of second fibers is from about 1.5:1 to about 1:1.5, more preferably 1.3:1 to about 1:1.3, or most preferably about 1.2:1 to about 1:1.2, as determined via the method of SEM method for determining the amount of cellulosic fibers.

A11. The absorbent article of any of embodiments a 7-a 10, wherein the plurality of first fibers have a cross-sectional shape that is different from a cross-sectional shape of the plurality of second fibers.

A12. The absorbent article according to any of embodiments a 1-a 11, wherein the fluid management layer further comprises about 21% to about 50% by weight, or most preferably about 22% to about 45% by weight absorbent fibers.

A13. The absorbent article according to any of embodiments a1 to a12, wherein the fluid management layer further comprises from about 25% to about 70%, more preferably from about 30% to about 60%, or most preferably from about 35% to about 50% by weight elastic fibers as determined by the material composition analysis method.

A14. The absorbent article according to any of embodiments a 1-a 13, wherein the fluid management layer further comprises from about 15% to about 60%, more preferably from about 20% to about 50%, or most preferably from about 25% to about 40% by weight reinforcing fibers, as determined by material composition analysis method.

A15. The disposable absorbent article according to any of embodiments A1-A14, wherein the absorbent article exhibits a stain size of less than 5000mm ^2, more preferably less than 4500mm ^2, or most preferably less than 4200mm ^2, as determined by the stain size measurement method.

A16. The fluid management layer according to any preceding claim wherein the fluid management layer comprises a spunlace nonwoven.

A17. The disposable absorbent article according to any of embodiments a 1-a 16, wherein the storage layer comprises an absorbent gelling material disposed between two liquid permeable fibrous layers.

A18. The disposable absorbent article according to embodiments a 1-a 17, wherein the basis weight of the AGM in the storage layer is between 30gsm and 50 gsm.

Test method

Fibre dtex (dtex)

Textile webs (e.g., woven, nonwoven, air-laid webs) are composed of individual material fibers. The fibers are measured in terms of linear mass density, which is reported in decitex. The decitex value is 10,000 meters of the mass of the fiber present in the fiber (in grams). The dtex values of the fibers within the web of material are often reported by the manufacturer as part of the specification. If the decitex of the fiber is unknown, it can be calculated by: the cross-sectional area of the fibers is measured via a suitable microscopy technique such as Scanning Electron Microscopy (SEM), the composition of the fibers is determined with a suitable technique such as FT-IR (fourier transform infrared) spectroscopy and/or DSC (dynamic scanning calorimetry), and then the mass of the fibers (in grams) present in 10,000 meters of fibers is calculated using literature values for the density of the composition. All tests were performed in a chamber maintained at a temperature of 23 ℃ ± 2.0 ℃ and a relative humidity of 50% ± 2%, and the samples were conditioned under the same environmental conditions for at least 2 hours prior to testing.

If desired, a representative sample of the web material of interest can be cut from the absorbent article. In this case, the web material is removed in order to not stretch, deform or contaminate the sample.

SEM images were obtained and analyzed as follows to determine the cross-sectional area of the fibers. To analyze the cross-section of a sample of the web material, test samples were prepared as follows. Samples of about 1.5cm (height) by 2.5cm (length) and no creases or wrinkles were cut from the web. The sample was immersed in liquid nitrogen and the edges were broken along the length of the sample with a razor blade (VWR single-edged industrial razor blade No. 9, surgical carbon steel). The samples were sputter coated with gold and then adhered to an SEM mount using double-sided conductive tape (Cu, 3M, available from electron microscopy sciences). The sample is oriented so that the cross-section is as perpendicular as possible to the detector to minimize any oblique distortion of the measured cross-section. SEM images were obtained at a resolution sufficient to clearly elucidate the cross-section of the fibers present in the sample. The fiber cross-section may vary in shape, and some fibers may be composed of multiple individual filaments. Regardless, the area of each of the fiber cross-sections is determined (e.g., using the diameter of a round fiber, the major and minor axes of an elliptical fiber, and for image analysis of more complex shapes). If the fiber cross-section indicates a non-uniform cross-sectional composition, the area of each identifiable component is recorded and the decitex contribution for each component is calculated and then summed. For example, if the fiber is bicomponent, the cross-sectional areas of the core and sheath are measured separately, and the dtex contributions from the core and sheath are calculated separately and summed. If the fibres are hollow, then transverseThe cross-sectional area does not include the inner portion of the fiber, which is composed of air, which does not contribute significantly to the fiber dtex. In summary, at least 100 such measurements of the cross-sectional area were made for each fiber type present in the sample, and in square micrometers (μm)²) The cross-sectional area a of each fiber was recorded as a unit_kTo an arithmetic mean of (to the nearest 0.1 μm)²)。

Fiber composition is determined using common characterization techniques such as FTIR spectroscopy. For more complex fiber compositions, such as polypropylene core/polyethylene sheath bicomponent fibers, a combination of general techniques (e.g., FTIR spectroscopy and DSC) may be required to fully characterize the fiber composition. This process is repeated for each fiber type present in the web material.

Dtex d of each fiber type in the web material_kThe values are calculated as follows:

d_k＝10 0OOm×a_k×ρ_k×10^-6

wherein d is_kIn grams (per calculated 10,000 meters length), a_kIn μm²Is a unit, and ρ_kIn grams per cubic centimeter (g/cm)³) Is a unit. The dtex (accurate to 0.1g (per calculated 10,000 meter length)) and fiber type (e.g., PP, PET, cellulose, PP/PET bicomponent) are reported.

Basis weight

The basis weight of the test sample is the mass (in grams) per unit area (in square meters) of the individual material layers and is measured according to the pharmacopoeia method WSP 130.1. The mass of the test sample was cut to a known area and the mass of the test sample was determined using an analytical balance accurate to 0.0001 grams. All measurements were performed in a laboratory maintained at 23 ℃ ± 2 ℃ and 50% ± 2% relative humidity, and the test samples were conditioned in this environment for at least 2 hours prior to testing.

Measurements were made on test samples taken from rolls or sheets of stock material or from material layers removed from absorbent articles. When cutting the material layer from the absorbent article, care is taken not to cause any contamination or deformation of the layer during the process. The layer cut off should be free of residual adhesive. To ensure that all of the adhesive is removed, the layer is soaked in a suitable solvent that will dissolve the adhesive without adversely affecting the material itself. One such solvent is THF (tetrahydrofuran, CAS 109-99-9, which is available for general use from any convenient source). After the solvent soak, the material layer is allowed to air dry thoroughly in a manner that prevents excessive stretching or other deformation of the material. After the material had dried, a test sample was obtained. The sample must be as large as possible to account for any inherent material variability.

The dimensions of the single layer specimens were measured using a calibrated steel metal ruler from NIST or equivalent. The area of the sample was calculated and recorded to the nearest 0.0001 square centimeter. An analytical balance was used to obtain the mass of the sample and recorded to the nearest 0.0001 gram. Basis weight was calculated by dividing the mass (in grams) by the area (in square meters) and reported to the nearest 0.01 grams per square meter (gsm). In a similar manner, a total of ten replicate test samples were repeated. The arithmetic mean of the basis weights was calculated and reported to the nearest 0.01 grams per square meter.

The air permeability measurements provided herein were obtained using the Worldwide Strategic Partiners (WSP) Test Method 70.1. For the samples tested later, a pressure drop of 125Pa and an orifice of 38.3 square centimeters were used.

Thickness of

The thickness or thickness of a material is measured as the distance between a reference platform on which the material is placed and a pressure foot that applies a specified amount of pressure to the material for a specified amount of time. All measurements were performed in a laboratory maintained at 23 ℃ ± 2 ℃ and 50% ± 2% relative humidity, and the test samples were conditioned in this environment for at least 2 hours prior to testing.

The thickness was measured with a manually operated micrometer equipped with a pressure foot capable of applying a steady pressure of 0.50kPa ± 0.01kPa to the test specimen. The manually operated micrometer is a dead weight type instrument, which reads to the nearest 0.001 mm. A suitable instrument is Mitutoyo series 543ID-C Digimatic, available from VWR International, or equivalent. The pressure foot is a flat circular movable face of smaller diameter than the test specimen and capable of applying the required pressure. A suitable pressure foot has a diameter of 56mm, but smaller or larger pressure feet may be used depending on the size of the sample being measured. The test specimen is supported by a horizontal flat reference platform that is larger than and parallel to the surface of the pressure foot. The system was calibrated and operated according to the manufacturer's instructions.

If necessary, the test sample is obtained by taking it out of the absorbent article. When the test sample is cut from the absorbent article, care is taken not to cause any contamination or deformation to the test sample layer during this process. The test samples were taken from areas without creases or wrinkles and had to be larger than the pressure foot.

To measure the thickness, the micrometer is first zeroed relative to a horizontal flat reference platform. The test specimen is placed on the platform with the test position centered under the pressure foot. The pressure foot was gently lowered at a rate of 3.0mm ± 1.0mm per second drop until the full pressure was applied to the test sample. Wait 5 seconds and then record the thickness of the test specimen to the nearest 0.01 mm. In a similar manner, a total of five replicate test samples were replicated. The arithmetic mean of all thickness measurements was calculated and reported as "thickness" to the nearest 0.01 mm.

Analysis of material composition

The quantitative chemical composition of test samples comprising a mixture of fiber types was determined using ISO 1833-1. All tests were carried out in a laboratory maintained at 23 ℃. + -. 2 ℃ and 50%. + -. 2% relative humidity.

The analysis is performed on test samples taken from rolls or sheets of stock material or from material layers removed from absorbent articles. When cutting the material layer from the absorbent article, care is taken not to cause any contamination or deformation of the layer during the process. The layer cut off should be free of residual adhesive. To ensure that all of the adhesive is removed, the layer is soaked in a suitable solvent that will dissolve the adhesive without adversely affecting the material itself. One such solvent is THF (tetrahydrofuran, CAS 109-99-9, which is available for general use from any convenient source). After the solvent soak, the material layer is allowed to air dry thoroughly in a manner that prevents excessive stretching or other deformation of the material. After the material has dried, a test sample is obtained and tested according to ISO 1833-1 to quantitatively determine its chemical composition.

Repeated collection time and rewet

Acquisition time of a dose administered to an absorbent article of Artificial Menses (AMF) as described herein was measured using a strike-through plate and an electronic circuit interval timer. The time required for the absorbent article to acquire a series of doses of AMF was recorded. After the collection test, a rewet test was performed. All tests were carried out in a laboratory maintained at 23 ℃. + -. 2 ℃ and 50%. + -. 2% relative humidity.

Referring to fig. 4-6B, a strike-through plate 9001 is constructed of plexiglas having overall dimensions of 10.2cm long by 10.2cm wide by 3.2cm high. The longitudinal slot 9007 extending the length of the plate is 13mm deep, 28mm wide at the top plane of the plate, and the side walls slope downwardly at 65 ° to a15 mm wide base. The central test fluid well 9009 is 26mm long, 24mm deep, 38mm wide at the top plane of the plate, and the side walls slope downward at 65 ° to a15 mm wide base. At the base of the test fluid well 9009, there is an "H" shaped test fluid reservoir 9003 which opens to the bottom of the plate to introduce fluid onto the test sample below. Test fluid reservoir 9003 has an overall length of 25mm, a width of 15mm and a depth of 8 mm. The longitudinal leg of the reservoir is 4mm wide and has a rounded end with a radius 9010 of 2 mm. The legs are 3.5mm apart. The center stay has a radius 9011 of 3mm and accommodates opposing electrodes spaced 6mm apart. The side walls of the reservoir curve outwardly at a radius 9012 of 14mm defined by an overall width 2013 of 15 mm. Two wells 9002(80.5mm long x 24.5mm wide x 25mm deep) located outside the lateral slots were filled with lead shot (or equivalent) to adjust the overall mass of the plate, providing 0.25psi (17.6 g/cm) for the test area²) The confining pressure of (1). The electrodes 9004 are embedded in the plate 9001, connecting an external banana jack 9006 to an internal wall 9005 of the fluid reservoir 9003. A circuit interval timer is inserted into the jack 9006, and the impedance between the two electrodes 9004 is monitored and measured from the introduction of the AMF into the reservoir 9003 up toThe time at which the AMF is exhausted from the reservoir. The timer has a resolution of 0.01 seconds.

For the rewet portion of the test, the pressure applied to the test sample was 1.0 psi. The rewet weight was constructed such that the dimensions of the bottom surface of the weight matched the dimensions of the moisture permeable plate, and the total mass required was calculated to provide a pressure of 1.0psi above the bottom surface of the weight. Thus, the bottom surface of the weight is 10.2cm long by 10.2cm wide and is constructed of a flat, smooth, rigid material (e.g., stainless steel) to provide a mass of 7.31 kg.

For each test sample, seven layers of filter paper cut to 150mm in diameter were used as the rewet substrate. Prior to testing, the filter paper was conditioned at 23 ℃. + -. 2 ℃ and 50%. + -. 2% relative humidity for at least 2 hours. Suitable filter papers have a basis weight of about 74gsm, a thickness of about 157 microns, and a medium porosity, and are available as grade 413 filter papers from VWR International.

The test samples were removed from all packages, taking care not to press or pull the product during handling. No attempt was made to smooth wrinkles. Prior to testing, the test samples were conditioned at 23 ℃. + -. 2 ℃ and 50%. + -. 2% relative humidity for at least 2 hours. Dosing positions were determined as follows. For a symmetrical sample (i.e., the front of the sample is the same shape and size as the back of the sample when divided laterally along the midpoint of the longitudinal axis of the sample), the dosing position is the intersection of the midpoint of the longitudinal axis and the midpoint of the lateral axis of the sample. For an asymmetric sample (i.e., the front of the sample, when divided laterally along the midpoint of the longitudinal axis of the sample, is different in shape and size than the back of the sample), the dosing position is the intersection of the midpoint of the longitudinal axis of the sample and the lateral axis located at the midpoint of the wings of the sample.

The required mass of the wet out plate must be calculated for the particular size of the test sample so that a confining pressure of 0.25psi is applied. The lateral width of the core at the dosing position was measured and recorded to the nearest 0.1 cm. The desired mass of the wet through sheet was calculated as the core width times the length of the wet through sheet (10.2cm) times 17.6g/cm²And the required mass was recorded to the nearest 0.1 g. Adding lead shot (or equivalent) to well of moisture permeable plate9002 to reach the calculated mass.

An electronic circuit interval timer is connected to the strikethrough plate 9001 and the timer is zeroed. The test specimen was placed on a flat horizontal surface with the body side facing up. The strike through plate 9001 is gently placed over the center of the test sample, ensuring that the "H" shaped reservoir 9003 is centered over the predetermined dosing position.

Using a mechanical pipette, 3.00mL ± 0.05mL of AMF was accurately pipetted into the test fluid reservoir 9003. Within 3 seconds or less, fluid is dispensed along the molded lip of the bottom of the reservoir 9003 without splashing. Immediately after the fluid has been collected, the collection time is recorded to the nearest 0.01 seconds and a5 minute timer is started. In a similar manner, a second and third dose of artificial menses liquid was applied to the test fluid reservoir, with each dose being administered with a5 minute wait time. The acquisition time was recorded to the nearest 0.001 seconds. Immediately after the third dose of artificial menstrual fluid has been collected, a5 minute timer is started and the filter paper of the rewet portion is ready for testing.

The mass of the 7-ply filter paper was obtained and recorded as dry mass_fpTo the nearest 0.001 g. At the 5 minute lapse after the third collection, the wet-out plate was gently removed from the test sample and set aside. A 7-ply pre-weighed filter paper was placed on the test sample, centering the stack of filter paper in the dosing position. The rewet weight is now placed centrally over the top layer of filter paper and a15 second timer is started. Once 15 seconds had elapsed, the rewet weight was gently removed and set aside. The mass of the 7-ply filter paper was obtained and recorded as the wet mass_fpTo the nearest 0.001 g. By wet mass_fpDry mass subtracted_fpAnd reported as the rewet value to the nearest 0.001 grams. Before testing the next sample, the electrodes 9004 were thoroughly cleaned and any residual test fluid was wiped from the bottom surface of the strike-through plate and rewet weight.

Immediately following the rewet portion of the test, the stain size method as described herein was continued using the dosed test samples.

In a similar manner, the entire process was repeated for ten replicate samples. The values reported are the arithmetic average of ten separately recorded acquisition time (first, second and third) measurements (accurate to 0.001 seconds) and rewet values (accurate to 0.001 grams).

Preparation of Artificial menses liquid (AMF)

Artificial Menstrual Fluid (AMF) consists of a mixture of defibrinated sheep blood, phosphate buffered saline solution and mucus components. AMF was prepared such that it had a viscosity between 7.15 and 8.65 centistokes at 23 ℃.

The viscosity of AMF was measured using a low viscosity rotational viscometer (a suitable Instrument is a Cannon LV-2020 rotational viscometer with UL adapter, Cannon Instrument co., State College, PA, or equivalent). A spindle of appropriate size within the viscosity range is selected and the instrument is operated and calibrated according to the manufacturer. The measurement was carried out at 23 ℃. + -. 1 ℃ and at 60 rpm. The results were recorded to the nearest 0.01 centistokes.

Reagents required for AMF production include: defibrinated sheep blood (collected under sterile conditions, available from Cleveland Scientific, inc., Bath, OH, or equivalent) having a packed cell volume of 38% or greater, gastric mucin (in crude form, available from Sterilized American Laboratories, inc., Omaha, NE, or equivalent) having a viscosity of 3 to 4 centistokes when prepared as a 2% aqueous solution, 10% v/v aqueous lactic acid, 10% w/v aqueous potassium hydroxide, anhydrous disodium hydrogen phosphate (reagent grade), sodium chloride (reagent grade), sodium dihydrogen phosphate monohydrate (reagent grade), and deionized water, each available from VWR International or equivalent sources.

The phosphate buffered saline solution consisted of two separately prepared solutions (solution a and solution B). To prepare 1L of solution A, 1.38. + -. 0.005g of sodium dihydrogen phosphate monohydrate and 8.50. + -. 0.005g of sodium chloride were added to a 1000mL volumetric flask and deionized water was added to volume. And mixing well. To prepare 1L of solution B, 1.42. + -. 0.005g of anhydrous disodium hydrogen phosphate and 8.50. + -. 0.005g of sodium chloride were added to a 1000mL volumetric flask and deionized water was added to volume. And mixing well. To prepare the phosphate buffered saline solution, 450 ± 10mL of solution B was added to a 1000mL beaker and stirred at low speed on a stir plate. A calibrated pH probe (accurate to 0.1) was inserted into the beaker of solution B and sufficient solution a was added while stirring to bring the pH to 7.2 ± 0.1.

The mucus component is a mixture of phosphate buffered saline solution, aqueous potassium hydroxide solution, gastric mucin, and aqueous lactic acid solution. The amount of gastric mucin added to the mucus component directly affects the final viscosity of the AMF produced. To determine the amount of gastric mucin required to achieve AMF within the target viscosity range (7.15-8.65 centistokes at 23 ℃), 3 batches of AMF were prepared with varying amounts of gastric mucin in the mucus component and then interpolated from the concentration versus viscosity curve using a three point least squares linear fit to obtain the exact amount required. The success range for gastric mucin is typically between 38 grams and 50 grams.

To prepare about 500mL of the mucus component, 460. + -.10 mL of the previously prepared phosphate buffered saline solution and 7.5. + -. 0.5mL of a 10% w/v aqueous potassium hydroxide solution were added to a 1000mL heavy glass beaker. The beaker was placed on a stirred hot plate and the temperature was raised to 45 ℃. + -. 5 ℃ while stirring. A predetermined amount of gastric mucin (± 0.50g) was weighed and slowly sprinkled into the previously prepared liquid that had reached 45 ℃ without coagulation. The beaker was covered and mixing continued. The temperature of the mixture is brought to above 50 ℃ but not more than 80 ℃ within 15 minutes. While maintaining this temperature range, heating was continued for 2.5 hours with gentle stirring. After 2.5 hours, the beaker was removed from the hot plate and cooled to below 40 ℃. Then 1.8. + -. 0.2mL of 10% v/v aqueous lactic acid was added and mixed well. The mucus component mixture was autoclaved at 121 ℃ for 15 minutes and cooled for 5 minutes. The mixture of mucus components was removed from the autoclave and stirred until the temperature reached 23 ℃ ± 1 ℃.

The temperature of the sheep blood and mucus components was allowed to reach 23 ℃. + -. 1 ℃. The volume of the entire batch of previously prepared mucus component was measured using a 500mL graduated cylinder and added to a 1200mL beaker. An equal amount of sheep blood was added to the beaker and mixed well. The viscosity method described previously was used to ensure that the viscosity of AMF was between 7.15 and 8.65 centistokes. If not, the batch is disposed of and another batch is made as needed for adjusting the mucus component.

Unless intended for immediate use, the qualified AMF should be refrigerated at 4 ℃. After preparation, AMF can be stored in an airtight container at 4 ℃ for up to 48 hours. Before testing, AMF must be brought to 23 ℃. + -. 1 ℃. After the test is complete, any unused portions are discarded.

Stain size measurement method

The method describes how to measure the size of fluid stains visible on an absorbent article. This process is performed on these test samples immediately after the test fluid has been dosed according to a separate method as described herein (e.g., a repeated collection and rewet method). The resulting test samples were photographed under controlled conditions. Each photographic image was then analyzed using image analysis software to obtain a measurement of the resulting visible stain size. All measurements were performed at constant temperature (23 ℃. + -. 2 ℃) and relative humidity (50%. + -. 2%).

The test specimen and a calibration ruler (traceable to NIST or equivalent standards) are placed horizontally on a matte black background within a light box that provides stable uniform illumination across the base of the light box. A suitable light box is Sanoto MK50 (Sanoto, guangdong, china) or equivalent, which provides 5500LUX of illumination at a color temperature of 5500K. A Digital Single Lens Reflex (DSLR) camera (e.g., Nikon D40X or equivalent available from Nikon inc. of tokyo, japan) with manual setting controls is mounted directly above the top opening of the light box so that the entire article and scale are visible within the field of view of the camera.

The white balance of the camera is set for the lighting conditions within the light box using a standard 18% Gray Card (e.g., Munsell 18% reflection (Gray) Neutral Patch/Kodak Gray Card R-27, available from X-Rite; Grand ratings, MI, or equivalent). The manual settings of the camera are set so that the image is correctly exposed so that there is no signal cut in any color channel. Suitable settings may be an f/11 aperture setting, an ISO setting of 400, and a shutter speed setting of 1/400 seconds. The camera was mounted approximately 14 inches above the article at a focal length of 35 mm. The image is correctly focused, photographed and saved as a JPEG file. The resulting image must contain the entire test sample and a distance scale with a minimum resolution of 15 pixels/mm.

The image was transferred to a computer running image analysis software (suitable software is MATLAB, available from The Mathworks, Inc, Natick, MA, or equivalent) to analyze The image. The image resolution is calibrated using a calibrated distance scale in the image to determine the number of pixels per millimeter. The images were analyzed by manually drawing the boundaries of the region of interest (ROI) around the visually discernable perimeter of the stain produced by the test liquid administered at the previous dose. The area of the ROI was calculated and reported as the total stain area to the nearest 0.01mm²Also noted are methods used (e.g., repeated collection and rewet) to generate the test sample to be analyzed.

This entire process was repeated for all replicate test samples generated by the dosing method. The reported values are the average of the measurements of the total stain area recorded separately, to the nearest 0.01mm²Also noted are methods used (e.g., repeated collection and rewet) to generate the test sample to be analyzed.

Density of

The density is calculated based on basis weight and thickness and is converted in appropriate units to obtain the density in g/cc.

SEM method for determining the amount of cellulose fibers

Scanning Electron Microscopy (SEM) was used to obtain images of both the first and second sides of the material test sample. From these images, the amount of cellulose filaments on each side of the test sample was determined using image analysis. All tests were performed in a chamber maintained at a temperature of 23 ℃ ± 2.0 ℃ and a relative humidity of 50% ± 2%, and the samples were conditioned under the same environmental conditions for at least 2 hours prior to testing.

If necessary, the test sample is obtained by taking it out of the absorbent article. When the sample is cut out of the absorbent article, care is taken not to cause any contamination or deformation to the sample layer during this process. The test samples were obtained from areas without creases or wrinkles. A total of 6 replicate test samples were obtained. The test areas on each test sample are marked in a manner that will allow the same area to be analyzed on each side. One suitable way of marking the facets of the detection zone is to use asymmetric notches.

Secondary Electron (SE) images were obtained using an SEM such as FEI Quanta450 (available from FEI corporation of hilsburer, oregon) or equivalent. The instrument was calibrated prior to use according to the manufacturer's instructions to ensure an accurate distance scale. The test area on the first side of the test sample was observed at low magnification (e.g., 200 x; horizontal field width about 1mm) so that a representative number of cellulose-based filaments were clearly seen for counting purposes, and an image was acquired. At the same test area, an image of the second side of the test sample is acquired using the same low magnification for the first side.

The low magnification Image of the first side of the test sample is turned on a computer running Image analysis software such as Image Pro Plus (available from Media Cybernetics, rockville, ma) or equivalent. All filaments within the image having a crenulated outer surface (e.g., viscose) and a first shape were counted manually and the number was recorded as a filament₁. Showing the crenulated surface and the different ends of the viscose. To prevent more than one counting of filaments, each counted filament is "marked" on the image. In a similar manner, the number of filaments having a crenulated surface and a second shape was counted on a low magnification image of the test sample at the same test area and recorded as a filament₂. By combining filaments₂Divided by filaments₁The filament ratio was calculated and recorded to the nearest 1 unit.

In a similar manner, all measurements were repeated for a total of 6 replicate test samples. The arithmetic mean of the filament ratios of all 6 replicates obtained was calculated and recorded to the nearest 1 unit.

The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Rather, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as "40 mm" is intended to mean "about 40 mm".

Each document cited herein, including any cross-referenced or related patent or application, is hereby incorporated by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with any disclosure of the invention or the claims herein or that it alone, or in combination with any one or more of the references, teaches, suggests or discloses any such invention. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.

While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.