阅读说明：本技术 油性化妆品 (Oily cosmetic ) 是由 宇田川史仁 于 2020-03-24 设计创作，主要内容包括：本发明是以提供不会损及使用性或完妆感、无二次附着效果优异、且色彩持久性良好的油性化妆品为课题。解决该课题的本发明的油性化妆品的特征在于,含有以下的成分(A)～(D)：成分(A)：在分子中具有2个以上羟基的油剂；成分(B)：碳数18以上的α-烯烃与乙烯基吡咯烷酮的共聚物；成分(C)：苯基改性有机硅；成分(D)：挥发性油剂。(The present invention provides an oil-based cosmetic composition which does not impair the use or finish, has no secondary adhesion, and has excellent color durability. The oil-based cosmetic composition of the present invention for solving the problem is characterized by containing the following components (a) to (D): component (A): an oil agent having 2 or more hydroxyl groups in the molecule; component (B): having 18 or more carbon atoms α Olefins with vinyl groupsCopolymers of pyrrolidones; component (C): phenyl modified silicone; component (D): a volatile oil agent.)

1. An oily cosmetic comprising the following components (A) to (D):

(A) an oil agent having 2 or more hydroxyl groups in the molecule;

(B) having 18 or more carbon atomsα-copolymers of olefins with vinylpyrrolidone;

(C) phenyl modified silicone;

(D) a volatile oil agent.

2. The oily cosmetic according to claim 1, wherein the content of the component (B) is 3 to 20% by mass based on the total amount of the cosmetic.

3. An oil-based cosmetic composition according to claim 1 or 2, wherein the content mass ratio of the component (A) to the component (B), (A)/(B), is 0.5 to 10.

4. The oil-based cosmetic according to any one of claims 1 to 3, further comprising:

component (E): carbon number 16 or lessαCopolymers of olefins with vinylpyrrolidone.

5. The oily cosmetic according to claim 4, wherein the component (E) is a (VP/hexadecene) copolymer.

6. The oil-based cosmetic according to any one of claims 1 to 5, wherein the component (A) is a polyglycerin fatty acid ester having a polymerization degree of 3 to 20.

7. The oily cosmetic according to any one of claims 1 to 6, wherein the component (B) is a (VP/eicosene) copolymer and/or TRICONTANYL PVP.

8. The oil-based cosmetic according to any one of claims 1 to 7, further comprising:

component (F): and (3) wax.

9. The oil-based cosmetic according to any one of claims 1 to 8, characterized in that the oil-based cosmetic is an oil-based solid.

10. An oily gel composition comprising:

component (A): an oil agent having 2 or more hydroxyl groups in the molecule; and

component (B): having 18 or more carbon atomsαCopolymers of olefins with vinylpyrrolidone.

11. An oil gelling agent for an oil agent having 2 or more hydroxyl groups in the molecule, which is an oil agent having 18 or more carbon atomsαCopolymers of olefins with vinylpyrrolidone as active ingredients.

Technical Field

The present invention relates to an oil-based cosmetic, and more particularly, to a cosmetic which is free from a burden feeling, is excellent in a secondary adhesion-free effect and color durability, has light, smooth and extensible properties without a sticky feeling, and has a good gloss feeling.

Background

Cosmetic products such as lipsticks, blushers, and eye shadows are articles that apply color tones to the applied parts such as lips, cheeks, and eyelids to make up a beautiful face. These are often provided as oil-based cosmetics in terms of color vividness and cosmetic durability. In addition to color development, gloss feeling, and feeling of use, recently, makeup durability function has become a very demanding function. In order to exert this function, combinations of various raw materials have been studied. Examples thereof include: a technique of exhibiting "transfer-free" characteristics by a mixture containing a volatile compound and a polymer of polyvinylpyrrolidone (see patent document 1); or by containing a silicone resin comprising phenyl groups in a certain ratio with (vinylpyrrolidone-αOlefin) copolymers to improve the durability of cosmetics (see patent document 2).

Documents of the prior art

Patent document

Patent document 1: japanese patent laid-open publication No. 10-67618;

patent document 2: japanese patent laid-open publication No. 2016-.

However, in the technique of using a combination of a volatile compound and a polyvinyl pyrrolidone polymer to exhibit "transfer-free" characteristics, satisfactory effects cannot be obtained, for example, a feeling of burden at the time of film formation is large, and a glossy feeling is not improved so much. In addition, the silicone resin containing phenyl and (vinylpyrrolidone-αOlefin) copolymers are not satisfactory because they tend to be heavy to use, feel a heavy burden, and have no secondary adhesion effect.

Disclosure of Invention

Problems to be solved by the invention

Therefore, the present invention has been made to solve the problem of developing an oil-based cosmetic composition which does not impair the usability or the finish appearance, has an excellent secondary adhesion-free effect, and has excellent color durability.

Means for solving the problems

In view of the above circumstances, the present inventors have made extensive studies to solve the above problems, and as a result, have found that: in the oil cosmetic, an oil agent containing 2 or more hydroxyl groups in the molecule and an oil cosmetic containing 18 or more carbon atoms are combinedα-copolymers of olefins with vinylpyrrolidone, gellable; further, compared with the case of using a conventional gelling agent, the feeling of burden when forming a coating film by gelling is reduced. Further, by using the above-mentioned components in combination with a phenyl-modified silicone and a volatile oil agent, an oil-based cosmetic can be obtained which is free from a burden feeling, is free from a secondary adhesion effect, is excellent in color durability, has smooth extensibility, and is also excellent in gloss, and the present invention has been completed.

That is, the present invention includes the following.

[1] An oily cosmetic comprising the following components (A) to (D):

component (A): an oil agent having 2 or more hydroxyl groups in the molecule;

component (B): having 18 or more carbon atomsα-copolymers of olefins with vinylpyrrolidone;

component (C): phenyl modified silicone;

component (D): a volatile oil agent.

[2] [1] the oily cosmetic composition according to the present invention, wherein the content of the component (B) is 3 to 20% by mass based on the total amount of the cosmetic composition.

[3] [1] the oil-based cosmetic according to [1] or [2], wherein the component (A) is contained in an amount of 0.5 to 10 by mass ((A)/(B)) relative to the component (B).

[4] The oil-based cosmetic according to any one of [1] to [3], further comprising:

component (E): carbon number 16 or lessαCopolymers of olefins with vinylpyrrolidone.

[5] [4] the oily cosmetic composition according to any one of the above aspects, wherein the component (E) is a copolymer of vinylpyrrolidone and hexadecene.

[6] The oil-based cosmetic according to any one of [1] to [5], wherein the component (A) is a polyglycerin fatty acid ester having a polymerization degree of 3 to 20.

[7] The oil-based cosmetic according to any one of [1] to [6], wherein the component (B) is a (VP/eicosene) copolymer and/or TRICONTANYL PVP (triacontyl PVP).

[8] The oil-based cosmetic according to any one of [1] to [7], further comprising:

component (F): and (3) wax.

[9] The oil-based cosmetic according to any one of [1] to [8], wherein the oil-based cosmetic is an oil-based solid.

[10] An oily gel composition comprising:

component (A): an oil agent having 2 or more hydroxyl groups in the molecule; and

component (B): having 18 or more carbon atomsαCopolymers of olefins with vinylpyrrolidone.

[11]An oil gelling agent for an oil agent having 2 or more hydroxyl groups in the molecule, which is an oil agent having 18 or more carbon atomsαCopolymers of olefins with vinylpyrrolidone as active ingredients.

Effects of the invention

The oil-based cosmetic composition of the present invention is free from a burden feeling, has an excellent secondary adhesion-free effect and color durability, has light, smooth and extensible properties without stickiness, and is excellent in a glossy feeling.

Detailed Description

The present invention will be described in detail below. In the present specification, "-" means a range including numerical values before and after the range, and "%" means "% by mass" unless otherwise specified.

The oil agent containing component (a) in the present invention, which contains 2 or more hydroxyl groups in the molecule, is not particularly limited as long as it is an oil agent generally used in cosmetics. Examples of such compounds include: esters of acids such as fatty acids and amino acids with glycerol or polymers thereof, pentaerythritol or polymers thereof, sucrose or polymers thereof, and the like, characterized in that 2 or more hydroxyl groups remain in the structure of the final product. The hydroxyl group of the component (a) in the present invention is not particularly limited in position or number as long as 2 or more hydroxyl groups are present in the molecule. For example, in the case of an ester, the alcohol may have 2 or more hydroxyl groups, or the fatty acid may have 2 or more hydroxyl groups, but the alcohol preferably has 2 or more hydroxyl groups. In the present invention, the number of hydroxyl groups in the molecule is not particularly limited as long as it is 2 or more, but is preferably 2 to 10, more preferably 2 to 7, and particularly preferably 2 to 3, from the viewpoint of affinity when combined with other components. Specifically, there may be mentioned: decaglyceryl decaisostearate (2 hydroxy groups), decaglyceryl nonaisostearate (3 hydroxy groups), decaglyceryl decaethylhexanoate (2 hydroxy groups), decaglyceryl pentaisostearate (7 hydroxy groups), diglyceryl isostearate (3 hydroxy groups), diglyceryl diisostearate (2 hydroxy groups), and the like, and 1 or 2 or more of these may be used. Among them, it is more preferable that the component (a) is a polyglycerin fatty acid ester having a polymerization degree of 3 to 20 because the color durability is more excellent. The fatty acid constituting the polyglycerin fatty acid ester is preferably a branched fatty acid, and is preferably a fatty acid having 8 to 18 carbon atoms, from the viewpoint of color durability and the like.

The content of the component (a) is not particularly limited, but is preferably 5 to 50%, more preferably 8 to 40%, and further preferably 8 to 30%. Within this range, the smoothness and ductility, no load feeling, and color durability are more preferable.

Component (B) in the present invention has 18 or more carbon atomsαThe copolymer of an olefin and vinylpyrrolidone is not particularly limited as long as it is a copolymer generally used in cosmetics, and is, for example, a copolymer having 18 or more carbon atomsαOlefins, which may be mentioned: 1-octadecene, 1-eicosene, 1-docosene, 1-tetracosene, 1-triacontene, etc., and copolymers obtained by copolymerization with vinylpyrrolidone may be used. Of component (B)αThe preferred olefin is C20-30, and 1-eicosene, 1-triacontene (VP/eicosene) copolymer, TRICONTANYL PVP are used, because they have no secondary adhesion effect or have excellent color durabilityThe (VP/eicosene) copolymer is particularly preferable because it is more excellent in terms of no load feeling and smooth ductility.

The content of the component (B) is not particularly limited, but is preferably 3 to 20%, more preferably 5 to 15%. Within this range, the smoothness and ductility, the absence of the secondary adhesion effect, and the color durability are more preferable.

In the oil-based cosmetic composition of the present invention, the content mass ratio ((a)/(B)) of the component (a) to the component (B) is not particularly limited, and (a)/(B) is preferably 0.5 to 10, more preferably 1 to 7.5. When the ratio of the component (a) to the component (B) is in this range, the feeling of no burden and the color durability are more excellent, and therefore, the ratio is more preferable.

The phenyl-modified silicone as the component (C) in the present invention is a silicone in which a part of the polysiloxane has phenyl groups. The component (C) in the present invention is not particularly limited, and any component that is generally used in cosmetics may be used. Examples thereof include: diphenylpolydimethylsiloxane, diphenylsiloxyphenyltrimethicones, trimethylsiloxyphenyldimethicones, trimethylpentaphenyltrisiloxanes, phenylpolytrimethicones, phenylmethylpolysiloxanes, and the like. Examples of commercially available products include: diphenyl polydimethylsiloxane; KF-54 (manufactured by shin-Etsu chemical industries Co., Ltd.), diphenylsiloxyphenyl trimethicone: KF-56 (manufactured by shin-Etsu chemical industries Co., Ltd.), trimethylsiloxyphenyl polydimethylsiloxane: BELSIL PDM 1000 (manufactured by Asahi Kasei Wacker Silicone Co., Ltd.), trimethylpentaphenyltrisiloxane: DOWSIL PH-1555 HRI Cosmetic Fluid (manufactured by Toray Dow Corning Corp.), and the like. These may be used in 1 kind or in combination of 2 or more kinds as required. Among these, diphenylpolydimethylsiloxane and trimethylpentaphenyltrisiloxane are more preferable because they are more excellent in gloss.

The content of the component (C) is not particularly limited, but is preferably 10 to 40%, more preferably 20 to 35%. When the amount is within this range, the gloss is excellent and the effect of no secondary adhesion is more excellent, which is more preferable.

The volatile oil of the component (D) in the present invention is an oil having a flash point of about 40 to 100 ℃. The component (D) in the present invention is not particularly limited, and any component that is generally used in cosmetics may be used. Examples thereof include: hydrocarbon oils such as isododecane and light liquid isoparaffin; silicone oils such as cyclotetradimethylsiloxane, cyclopentyldimethylsiloxane, trisiloxane, methylpolytrimethicone, and polydimethylsiloxane. These may be used in 1 kind or in combination of 2 or more kinds as required. Among these, volatile hydrocarbon oil is preferable because it is more excellent in the effect of no secondary adhesion, and isododecane is more preferable because it is more excellent in the effect of no secondary adhesion and also more excellent in the gloss, non-load bearing, smooth ductility and color durability.

The content of the component (D) is not particularly limited, but is preferably 1 to 30%, more preferably 5 to 20%. Within this range, the smoothness and ductility is excellent, the feeling of no load is not imparted, and the color durability is more excellent, which is more preferable.

In the present invention, the component (E) may contain a C16 or less carbon atomαCopolymers of olefins with vinylpyrrolidone. In the present invention, the component (E) is preferably contained in terms of gloss and color durability. Has 16 or less carbon atomsαOlefins, which may be mentioned: 1-hexadecene, 1-tetradecene, 1-dodecene, etc., and copolymers obtained by copolymerization with vinylpyrrolidone can be used. Of component (E)αThe (vinylpyrrolidone/hexadecene) copolymer in which the olefin is preferably a copolymer of 10 to 16, 1-hexadecene having a carbon number and vinylpyrrolidone is more preferable because it is more excellent in gloss and color durability.

The content of the component (E) is not particularly limited, but is preferably 3 to 20%, more preferably 5 to 15%. Within this range, the smoothness and ductility and the color durability are more excellent, and therefore, the range is more preferable.

The wax of the present invention may further contain a wax of component (F). In the present invention, the wax is a wax that holds an oil agent in the pores of a paper-house structure (card-house structure) formed as a plate-like crystal. In the present invention, the component (F) is preferably contained in order to have good smooth ductility and color durability. The component (F) in the present invention is not particularly limited as long as it is a component generally used in cosmetics, and may be any of synthetic hydrocarbons, natural and synthetic waxes. The melting point is not particularly limited, but a wax of 70 ℃ or higher is preferable, and 80 ℃ or higher is more preferable. In the present invention, the melting point (Tm) is defined as: the peak top of the peak observed on the highest temperature side of the melting endothermic curve obtained by holding the sample at-10 ℃ for 5 minutes in a nitrogen atmosphere using a Differential Scanning Calorimeter (DSC) and then raising the temperature at 10 ℃/minute. Specifically, there may be mentioned: paraffin wax, ceresin (セレシンワックス), ceresin, microcrystalline wax, fischer-tropsch wax, polyethylene wax, ethylene/propylene copolymer, candelilla wax, carnauba wax, beeswax, rice wax, wood wax, spermaceti wax, ozokerite (ジロウ), montan wax, stearyl-modified methylpolysiloxane, behenyl-modified methylpolysiloxane, or the like, and 1 or 2 or more of these can be used. Among them, 1 or 2 or more selected from the group consisting of fischer-tropsch wax, polyethylene wax and candelilla wax are more preferable because of their superior light, smooth and ductile properties without sticky feeling and shape stability.

The content of the component (F) is not particularly limited, but is preferably 5 to 25%, more preferably 7 to 15%. If the content is within this range, the color durability is more excellent, and therefore, the content is more preferable.

The oily cosmetic of the present invention may contain, in addition to the above components (a) to (F), components generally used in cosmetics, oily components other than the components (a) to (F), powders (powders), surfactants, fibers, aqueous components, ultraviolet absorbers, fading inhibitors, antioxidants, antifoaming agents, cosmetic components, preservatives, perfumes, and the like, within a range not to impair the effects of the present invention.

The oily cosmetic of the present invention can be obtained by a conventionally known method. An example of the manufacturing method is shown below, but the manufacturing method is not limited to this. For example, the components (a) to (F) can be obtained by heating to 110 ℃ to dissolve them, adding other components, filling the mixture in a container, and molding the mixture as needed.

The oily cosmetic of the present invention is not particularly limited, and examples thereof include: lipstick, lip gloss, base layer of lipstick, outer layer of lipstick, blush, eye shadow (eye color), etc., and lipstick is particularly preferable.

The oil-based cosmetic of the present invention is suitable for use in an oil-based oil composition containing an oil agent as a main component and a water-in-oil type oil composition containing an oil agent as an outer layer as a continuous phase, but preferably contains 1% or less of water as a continuous phase or contains substantially no water. The properties are not particularly limited, and examples thereof include: liquid, semisolid, solid, and the like, preferably solid, and most preferably rod-shaped.

The oily gel composition of the present invention comprises the above-mentioned component (A) (an oil agent having 2 or more hydroxyl groups in the molecule) and the above-mentioned component (B) (an oil agent having 18 or more carbon atoms)αCopolymers of olefins with vinylpyrrolidone). The components (a) and (B) are preferably the same as the above-mentioned oily cosmetic, or the content ratio by mass of the components (a) and (B) is preferably the same. The oil-based gel composition of the present invention forms a soft coating film having high followability and a less burden feeling when applied to the skin and gelled to form a coating film. Therefore, the oil-based cosmetic composition can be contained in various cosmetic compositions, and particularly preferably used in an oil-based cosmetic composition, and particularly when used in an oil-based cosmetic composition containing the components (C) and (D), has excellent non-secondary adhesion effect and color durability, and is also excellent in feeling of use and gloss. The content of the oily gel composition in the cosmetic is not particularly limited, and is, for example, preferably 1 to 80%, more preferably 5 to 60%. The gel strength of the oil-based gel composition of the present invention, which is obtained by preparing and measuring the oil-based gel according to the preparation method and the gel strength evaluation method described in examples, is preferably 1N or more, and more preferably 5N or more, from the viewpoint of color durability.

The oil gelling agent of the present invention is an oil gelling agent having (B) at least 18 carbon atomsαA copolymer of an olefin and vinylpyrrolidone as an active ingredient, which is added to (a) an oil agent having 2 or more hydroxyl groups in the molecule to form a gel. Preferred components of the components (A) and (B) or the content mass ratio of the components (A) and (B) are the same as those of the above-mentioned oil-based cosmetic. The formed oily gel is soft and has good followability and little burden on the skin. There are no particular limitations on the physical properties such as gel strength of the oily gelThe gel strength obtained by preparing and measuring the oil-based gel according to the preparation method and the gel strength evaluation method described in examples is preferably 5N or more, more preferably 8N or more, from the viewpoint of color durability and the like.

Examples

The present invention will be described in more detail below with reference to examples. It should be noted that they do not limit the invention in any way.

[ preparation of oily gel ]

Gel strength was measured for gels obtained by heating and melting compositions having the compositions shown in table 1 to 100 ℃ and pouring the melted compositions into a pot container by the following method. The results are also shown in table 1.

[ Table 1]

*1: ANTARON V-220 (manufactured by Ashland corporation);

*2: KEH-1010 (manufactured by Sakazaben pharmaceutical industries, Ltd.);

*3: S-Face IS-1005P (manufactured by Saka pharmaceutical industries, Ltd.);

*4: cosmol 43V (manufactured by Nisshin ovio Group corporation);

*5: liponate TDTM (manufactured by Vantage Speciality Chemical Co.);

*6: t.i.o (manufactured by Nisshin ovio Group).

(evaluation method)

Regarding the gel strength, the gel strength at the time of penetrating 2mm at 6cm/min was measured by using a 10mm plunger by a rheometer manufactured by FUDOH after each sample was allowed to stand at 25 ℃ for 1 hour. In the present invention, a combination of 5N or more is more preferable in terms of color durability.

Examples 1 to 15 and comparative examples 1 to 7: oily solid lipstick

The oily solid lipsticks obtained by producing the oily solid lipsticks having the compositions shown in tables 2 and 3 by the following production methods were evaluated for (a) a glossy feeling, (b) no load feeling, (c) smooth spreadability, (d) no secondary adhesion effect, and (e) cosmetic durability by the following methods. The results are also shown in tables 2 and 3.

[ Table 2]

[ Table 3]

*7: ANTARON WP-660 (manufactured by Ashland corporation);

*8: ANTARON V-216 (manufactured by Ashland corporation);

*9: unifilma HVY (manufactured by millettia millettii);

*10: KF-54 (manufactured by shin-Etsu chemical industries, Inc.);

*11: KF-96A-100cs (manufactured by shin-Etsu chemical industries, Inc.);

*12: KF-96A-1.5cs (manufactured by shin-Etsu chemical industries, Inc.).

(production method)

A: heating and dissolving the components (1) - (13) at 100-110 ℃;

b: adding the components (14) - (23) into the A, and uniformly mixing;

c: defoaming B, adding the components (24) - (26), and uniformly mixing;

d: heating the C to 90 ℃, directly pouring the C into a container, and cooling to obtain the oily solid lipstick.

(evaluation method)

For the following evaluation items (a) to (e), use tests were conducted on each sample with 20 professional functional inspectors (specialist panels). Each sample was applied to the lips of the mouth by each functional examiner, and the total score of all functional examiners was calculated by scoring according to the following absolute evaluation criteria, and the judgment was made according to the following rating criteria.

The evaluation items (a), (b), (c), and (d) were evaluated immediately after application, and the evaluation item (e) was evaluated by applying the sample to the lips and living for 8 hours.

< evaluation item >

(a) A glossy feel;

(b) no burden feeling;

(c) smooth ductility;

(d) no secondary adhesion;

(e) color persistence.

< Absolute evaluation criterion >

(score): (evaluation)

And 4, dividing: excellent;

and 3, dividing: good;

and 2, dividing: slightly worse;

1 minute: and (4) poor.

< decision reference >

(judgment): (general points)

Very good: more than 65 minutes;

o: 50 minutes or more and 64 minutes or less;

and (delta): 35 points or more and 49 points or less;

x: 34 minutes or less.

As is clear from tables 2 and 3, examples 1 to 15 of the present invention are excellent and good in all the evaluation items of smoothness, ductility, gloss, no load, no secondary adhesion, and color durability. On the other hand, in comparative examples 1,2 and 3 containing no component (a), no secondary adhesion effect or color persistence could be obtained, and the effect was insufficient. In comparative example 4 containing no component (B), no secondary adhesion effect or color persistence could be obtained, and the effect was insufficient. In comparative example 5 in which dextrin isostearate was contained as a coating forming agent instead of the component (B), the feeling of use was heavy and sticky, and the effect of no secondary adhesion was insufficient in addition to the feeling of burden. In addition, in comparative example 6 containing polydimethylsiloxane instead of component (C), the glossy feeling was poor, and satisfactory effects were not obtained in terms of no secondary adhesion or color durability. In comparative example 7 containing no component (D), lipstick became hard, smooth ductility could not be obtained, and no secondary adhesion effect could not be obtained.

Example 16: oily pouring eye shadow

(ingredient) (%)

1. (ethylene/propylene) copolymer 3

2. Microcrystalline wax 2

3. Rice wax 1.5

4. Decaglyceryl decaisostearate (2 hydroxy) 22

5. (VP/eicosene) copolymer 110

6. (hexadecene/VP) copolymer 85

7. Dipentaerythritol hexaisononanoate 8

8. (phytosterol/isostearyl alcohol/cetyl alcohol/stearyl alcohol/behenyl alcohol) dimerized linoleate 5

9. Diisostearyl malate balance

10. Methylphenylpolysiloxane 135

11. Trimethylsiloxyphenyl polydimethylsiloxane 1415

12.2, 6-di-tert-butyl-p-cresol 0.01

13. Dimethylsilylated silica 151

14.1, 3-butanediol 0.5

15. Red 202 number 0.2

16. Ultramarine 0.1

17. Titanium dioxide 1

18. Iron oxide black 0.01

19. Titanium oxide coated borosilicate (Ca/Al) 165

20. Silver/titanium oxide-coated borosilicate (Ca/Al) 173

21. Tocopheryl acetate 0.1

22. Hyaluronic acid 0.1

23. Collagen 0.1

24. Polydimethylsiloxane (2CS) 185

25. Fragrance 0.1

*13: KF-56 (manufactured by shin-Etsu chemical industries, Inc.);

*14: BELSIL PDM 1000 (manufactured by Wacker Silicone Co., Ltd.);

*15: AEROSIL R976S (manufactured by AEROSIL corporation, Japan);

*16: MICROGLAS METASHINE MT1080RB (manufactured by Nippon Sheet Glass Inc.);

*17: MICROGLAS METASHINE MC2080PS (manufactured by Nippon Sheet Glass Inc.);

*18: KF-96A-2cs (manufactured by shin-Etsu chemical industries, Inc.).

(production method)

A: heating and dissolving the components (1) - (9) at 100-110 ℃;

b: adding the components (10) - (23) into the A, and uniformly mixing;

c: defoaming B, adding the components (24) and (25), and uniformly mixing;

d: heating C to 110 ℃, directly pouring into a metal dish, standing and cooling to obtain the oily pouring eye shadow.

The eye shadow of example 16 was satisfactory in all of slipperiness extensibility, gloss feeling, no feeling of burden, no secondary adhesion, and color durability.

Example 17: oily stick-shaped blush

(ingredient) (%)

1. (ethylene/propylene) copolymer 2.5

2. Fischer-Tropsch wax 3.8

3. Candelilla wax esters 1

4. Carnauba wax 0.2

5. Polybutene 7.5

6. Decaglycerol decaethylhexanoate (2 hydroxyl groups) 8

7. Diglycerol isostearate (3 hydroxyl groups) 7

8. CONTANYL PVP *7 　 5

9. Triisostearic acid diglyceride 5

10. Trimethylpentyltrisiloxane 1920

11. 0.3 parts of phenoxyethanol

12.1, 2-pentanediol 0.2

13. Fumed silica 202

14. Zinc oxide 1

15. Nylon-12-215

16. Polymethyl methacrylate 2210

17. The rest of mica

18. Mica titanium treated with 3% perfluorooctyltriethoxysilane 5

19. Iron oxide coated mica titanium 2 treated with 3% perfluorooctyltriethoxysilane

20. Iron oxide Red 0.01 treated with 2% Triethoxyoctanoylsilane

21. Yellow iron oxide treated with 2% triethoxy octanoyl silane 0.1

22. Black iron oxide 0.001 treated with 2% triethoxycaprylylsilane

23. Titanium oxide treated with 2% Triethoxyoctanoylsilane 0.2

24. Rosemary extract 0.1

25. Hydrogenated polyisobutene 2310

*19: FZ-3156 (manufactured by Toray Dow Corning Co., Ltd.);

*20: AEROSIL 380S (manufactured by AEROSIL, Japan);

*21: orgasol 2002D (manufactured by ARKEMA corporation);

*22: ganz-paru GM-2800 (manufactured by Aica Kogyo Co.);

*23: IP Solvent 1620 MU (manufactured by Shizu Kogyo Co.).

(production method)

A: heating and dissolving the components (1) - (9) at 100-110 ℃;

b: adding the components (10) - (24) into the A, and uniformly mixing;

c: defoaming the B, adding the component (25), and uniformly mixing;

d: heating C to 110 deg.C, directly pouring into a container, and cooling to obtain oily stick blush.

The blush of example 17, which is satisfactory in all aspects of smooth extensibility, glossy feel, no feeling of burden, no secondary adhesion, color durability.

Example 18: oily liquid lipstick

(ingredient) (%)

1. (ethylene/propylene) copolymer 2.5

2. Polyethylene wax 5

3. Dextrin palmitate 241

4. Deca-2-ethylhexanoic acid deca glyceride 215

5. (VP/eicosene) copolymer 115

6. (phytosterol/octyldodecanol) lauroyl glutamate 255

7. Glycerol tris (ethylhexanoate) 5

8. Octyl dodecanol 3

9. The rest of triisostearic acid diglyceride

10. Lecithin 0.2

11. Diphenyl Dimethicone 15

12. Polydimethylsiloxane (100CS) 115

13. Talc 4

14. Red No. 226 0.5

15. Red 104 number 0.5

16. Red 218 number 0.03

17. Yellow No. 4 No. 1

18. Natural antibiotic E0.1

19. Arnica herb extract 0.1

20. Isododecane 15

*24: rheopearl KL2 (manufactured by millettia millettii Co.);

*25: ELDEW PS-203 (manufactured by Ajinomoto Co.).

(production method)

A: heating and dissolving the components (1) - (10) at 100-110 ℃;

b: adding the components (11) to (19) to the A, and uniformly mixing the mixture by using a roller mill;

c: defoaming the B, adding the component (20), and uniformly mixing;

d: and directly pouring the C into a container at room temperature to obtain the oily liquid lipstick.

The liquid lipstick of example 18 was satisfactory in all of smoothness, extensibility, gloss, no burden, no secondary adhesion, and color durability.

Example 19: oily solid eyebrow cosmetic

(ingredient) (%)

1. Deca-2-ethylhexanoic acid deca-glyceride 4

2. Dipentaerythritol tetra-2-ethylhexanoate 20

3. (VP/eicosene) copolymer 110

4. Diphenyl polydimethylsiloxane 8

5. Decamethylcyclopentasiloxane 35

6. (hexadecene/VP) copolymer 3

7. Polyethylene wax 4

8. Microcrystalline wax 1

9. The balance of glycerol tri-2-ethylhexanoate

10. Hollow silica 5

11. Iron oxide black 0.5

12. Iron oxide yellow 0.3

13. Iron oxide Red 0.2

14. Panthenol 0.001

15. Oriental cherry leaf extract 0.001

16. Green tea extract 0.001

17. Ascorbic acid glucoside 0.01

(production method)

A: heating and dissolving the components (1) - (4) and (6) - (9) at 100-110 ℃;

b: adding the components (10) to (13) to the A, and uniformly mixing the mixture by using a roller mill;

c: defoaming B, adding the components (5), (14) to (17), and uniformly mixing at 90 ℃;

d: pouring C into a disc-shaped container and cooling to room temperature to obtain oily solid eyebrow cosmetic.

The oily solid eyebrow cosmetic of example 19 is satisfactory in all of smoothness, spreadability, gloss, no burden, no secondary adhesion, and color durability.

Example 20: oily lip essence

1. Deca-2-ethylhexanoic acid deca-glyceride 50

2. (VP/eicosene) copolymer 20

3. Trimethylpentyltrisiloxane 10

4. Dimethylpolysiloxane (kinematic viscosity at 25 ℃ 2CS) 1

5. (ethylene/propylene) copolymer 4

6. Dextrin Isostearate 3

7. Squalane 0.1

8. Olive oil 0.01

9. Argania arguta oil 0.01

10. Camellia oil 0.001

11. Polyglyceryl diisostearate-2 balance

12. Fumed silica 200.5

13. Red No. 104 0.001

14. 0.1 part of aluminum powder

15. Radix Arnebiae extract 0.001

(production method)

A: heating and dissolving the components (1) - (3) and (5) - (11) at 100-110 ℃;

b: adding the components (12) to (15) to the component A, and uniformly mixing the components by using a roller mill;

c: defoaming the B, adding the component (4), and uniformly mixing at room temperature;

d: the oil lip essence was obtained by filling C in a tube container at room temperature.

The oily lip essence of example 20 was satisfactory in all of smoothness, extensibility, gloss, no burden, no secondary adhesion, and color durability.

Example 21: anti-wrinkle oil

1. Deca-2-ethylhexanoic acid deca-glyceride 20

(VP/eicosene) copolymer 25

3. Trimethylpentyltrisiloxane as the remainder

4. Decamethylcyclopentasiloxane 1

5. (vinylpyrrolidone/hexadecene) copolymer 20

6. Candelilla wax 3

7. Polysiloxane-152

8. Spherical silica (average particle diameter 7)μm) 1

9. Nicotinamide 1

10. Iron oxide yellow 0.3

11. Iron oxide Red 0.15

12. Iron oxide black 0.05

(production method)

A: heating and dissolving the components (1) - (3) and (5) - (7) at 90-100 ℃;

b: adding the components (8) to (10) to the A, and uniformly mixing the components by using a roller mill;

c: defoaming the B, adding the component (4), and uniformly mixing at room temperature;

d: the anti-wrinkling oil was obtained by filling C in a tank container at room temperature.

The wrinkle-preventing oil of example 21 was satisfactory in all of smoothness, extensibility, gloss, no feeling of burden, no secondary adhesion, and color durability.