阅读说明：本技术 一种固态硅胶皮革及其制备方法 (Solid silica gel leather and preparation method thereof ) 是由 巫青峰 李云 郝随众 苗辉 狄少锋 于 2021-08-18 设计创作，主要内容包括：本发明属于合成革领域,具体涉及一种固态硅胶皮革及其制备方法。该固态硅胶皮革的制备方法,包括以下步骤：(1)固态硅胶、色膏、铂金硫化剂混炼均匀,在纹路膜上压延,得到带有纹路膜的硅胶片；(2)带有纹路膜的硅胶片与基布压合,初步硫化,剥离纹路膜,得到带有纹路的硅胶皮革半成品；(3)在带有纹路的硅胶皮革半成品的纹路面上涂布手感油,终硫化。本发明的固态硅胶皮革的制备方法,使用固态硅胶为主体硅胶,利用混炼胶的初粘性粘合基布,不使用粘接剂；初步硫化后涂布手感油,手感油与硅胶共同终硫化。整个生产工艺设计合理,原料成本低,各层之间结合效果好,所得皮革制品性能良好。(The invention belongs to the field of synthetic leather, and particularly relates to solid silica gel leather and a preparation method thereof. The preparation method of the solid silica gel leather comprises the following steps: (1) mixing the solid silica gel, the color paste and the platinum vulcanizing agent uniformly, and rolling on the grain film to obtain a silica gel sheet with the grain film; (2) pressing the silica gel sheet with the grain film and the base cloth, preliminarily vulcanizing, and stripping the grain film to obtain a silica gel leather semi-finished product with grains; (3) coating hand feeling oil on the grain surface of the silica gel leather semi-finished product with the grains, and finally vulcanizing. The preparation method of the solid silica gel leather uses the solid silica gel as the main silica gel, utilizes the initial viscosity of the rubber compound to bond the base cloth, and does not use adhesive; after the preliminary vulcanization, hand feeling oil is coated, and the hand feeling oil and silica gel are finally vulcanized together. The whole production process has reasonable design, low raw material cost, good combination effect among layers and good performance of the obtained leather product.)

1. The preparation method of the solid silica gel leather is characterized by comprising the following steps:

(1) mixing the solid silica gel, the pigment and the platinum vulcanizing agent uniformly, and rolling on the grain film to obtain a silica gel sheet with the grain film;

(2) pressing the silica gel sheet with the grain film and the base cloth, preliminarily vulcanizing, and stripping the grain film to obtain a silica gel leather semi-finished product with grains;

(3) coating hand feeling oil on the grain surface of the silica gel leather semi-finished product with the grains, and finally vulcanizing.

2. The method for preparing solid silica gel leather as claimed in claim 1, wherein in the step (2), the grain film and the semi-finished silica gel leather are respectively rolled up when the grain film is peeled off; in the step (3), unreeling the semi-finished silica gel leather, coating hand feeling oil on line, forming solid silica gel leather after final vulcanization, and reeling.

3. The method for preparing solid silica gel leather as claimed in claim 2, wherein the primary vulcanization and the final vulcanization are both in-line vulcanization, and the leather material passes through the drying tunnel during the process of running and is correspondingly vulcanized after being taken out of the drying tunnel.

4. The method for preparing solid silica gel leather according to claim 1, wherein in the step (3), the coating thickness of the hand feeling oil is 0.05-0.2 mm.

5. The method for preparing solid silica gel leather according to claim 1, wherein in the step (1), the platinum vulcanizing agent consists of the agent A and the agent B, the mass of the agent A is 0.5-1.5% of the mass of the solid silica gel, and the mass of the agent B is 1-1.5% of the mass of the solid silica gel.

6. The method for preparing the solid silica gel leather as claimed in claim 5, wherein the temperature of the primary vulcanization is 115-150 ℃ and the time is 5-7 min; the final vulcanization temperature is 150-180 ℃, and the time is 3-5 min.

7. The method for preparing solid silica gel leather according to claim 1, wherein the grain film is one of grain paper, PP grain film, PET transfer printing grain film and HTR grain film.

8. The method for preparing the solid silica gel leather according to any one of claims 1 to 7, wherein the base fabric is one of a knitted fabric, a non-woven fabric and a microfiber base fabric which are subjected to corona treatment.

9. A solid silica gel leather, comprising:

the silica gel skin with the lines is formed by vulcanizing solid silica gel, and the surface of the silica gel skin is provided with the line road surface;

the hand feeling oil layer is attached to the grain pavement of the silica gel skin; the joint of the hand feeling oil layer and the silica gel skin is provided with a permeation transition layer formed by mutual permeation of the silica gel skin and the hand feeling oil;

the base cloth is attached to the surface of one side, away from the hand feeling oil layer, of the silica gel skin, and an entanglement transition layer formed by mutual entanglement of the silica gel skin and the base cloth is arranged at the attachment position of the base cloth and the silica gel skin.

10. The solid-state silica gel leather of claim 9, wherein the base fabric is one of a knitted polyester fabric, a non-woven fabric and a microfiber bass fabric.

Technical Field

The invention belongs to the field of synthetic leather, and particularly relates to solid silica gel leather and a preparation method thereof.

Background

Most of the leather for interior decoration of passenger cars and passenger cars is PVC leather and PU leather, the smell and the environmental protection are hard injuries which cannot be changed, along with the continuous upgrading of the consumption demand of client main bodies, and the future development trend of interior decoration of main passenger cars, business cars and the like in foreign countries, pollution-free, mildew-proof and healthy silica gel leather is inevitably required for the future development.

At present, liquid silica gel leather furniture is sold on the market, but the liquid silica gel leather raw material is basically imported, and the production cost is higher.

The application publication number is CN109680509A, and the application discloses a silica gel leather applied to vehicle interior or seat and a preparation method thereof, the silica gel leather is formed by bonding a surface layer, an intermediate base material layer, a bottom layer and a base fabric layer in sequence, wherein the base preparation raw materials of the surface layer, the intermediate base material layer and the bottom layer are organic silica gel, a hardening agent and vinyl silicone oil, in addition, the surface layer also comprises nano silica, and the bottom layer also comprises nano silica and a silane coupling agent.

The silica gel leather made of liquid silica gel needs complex organic silicon resin and organic matching of a surface layer, a middle layer and a bottom layer to generate a product which is comparable to the genuine leather, has complex production procedures and higher cost, and is not beneficial to popularization and use in China.

Disclosure of Invention

The invention aims to provide a preparation method of solid silica gel leather, which utilizes simpler production process and lower cost to produce leather products with good performance.

The second purpose of the invention is to provide the solid silica gel leather.

In order to achieve the purpose, the technical scheme of the preparation method of the solid silica gel leather is as follows:

a preparation method of solid silica gel leather comprises the following steps:

(1) mixing the solid silica gel, the pigment and the platinum vulcanizing agent uniformly, and rolling on the grain film to obtain a silica gel sheet with the grain film;

(2) pressing the silica gel sheet with the grain film and the base cloth, preliminarily vulcanizing, and stripping the grain film to obtain a silica gel leather semi-finished product with grains;

(3) coating hand feeling oil on the grain surface of the silica gel leather semi-finished product with the grains, and finally vulcanizing.

The preparation method of the solid silica gel leather uses the solid silica gel as the main silica gel, utilizes the initial viscosity of the rubber compound to bond the base cloth, and does not use adhesive; after the preliminary vulcanization, hand feeling oil is coated, and the hand feeling oil and silica gel are finally vulcanized together. The whole production process has reasonable design, low raw material cost, good combination effect among layers and good performance of the obtained leather product.

The leather prepared by the preparation method has good environmental protection performance, the smell reaches 2.5 grade, benzene, toluene and xylene are not detected, the TVOC content is low, and the leather has natural advantages compared with the existing PVC interior material.

In order to better realize industrial production, preferably, in the step (2), when the grain film is stripped, the grain film and the semi-finished silica gel leather are respectively rolled; and (3) unreeling the semi-finished silica gel leather, coating hand feeling oil on line, forming solid silica gel leather after final vulcanization, and reeling. More preferably, the primary vulcanization and the final vulcanization are both in-line vulcanization, and the leather material passes through a drying tunnel in the process of going on and is correspondingly vulcanized after being taken out of the drying tunnel.

Preferably, in the step (3), the coating thickness of the hand feeling oil is 0.05-0.2 mm.

Preferably, in the step (1), the platinum vulcanizing agent consists of an agent A and an agent B, wherein the mass of the agent A is 0.5-1.5% of that of the solid silica gel, and the mass of the agent B is 1-1.5% of that of the solid silica gel. The mass of the pigment is 1-3% of that of the solid silica gel. More preferably, the temperature of the primary vulcanization is 115-150 ℃, and the time is 5-7 min; the final vulcanization temperature is 150-180 ℃, and the time is 3-5 min.

Preferably, the grain film is one of grain paper, a PP grain film, a PET transfer printing grain film and an HTR grain film.

Preferably, the base fabric is one of a knitted fabric, a non-woven fabric and a microfiber bass which are subjected to corona treatment.

The technical scheme of the solid silica gel leather provided by the invention is as follows:

a solid silicone leather comprising:

the silica gel skin with the lines is formed by vulcanizing solid silica gel, and the surface of the silica gel skin is provided with the line road surface;

the hand feeling oil layer is attached to the grain pavement of the silica gel skin; the joint of the hand feeling oil layer and the silica gel skin is provided with a permeation transition layer formed by mutual permeation of the silica gel skin and the hand feeling oil;

the base cloth is attached to the surface of one side, away from the hand feeling oil layer, of the silica gel skin, and an entanglement transition layer formed by mutual entanglement of the silica gel skin and the base cloth is arranged at the attachment position of the base cloth and the silica gel skin.

According to the solid silica gel leather disclosed by the invention, the silica gel main body is formed by vulcanizing the solid silica gel, the handfeel oil layer, the base cloth and the silica gel leather are good in associativity, and the obtained solid silica gel leather is excellent in performance.

Preferably, the base cloth is one of polyester knitted cloth, non-woven cloth and microfiber bass.

Drawings

FIG. 1 is a process flow diagram of the method of preparing solid silica gel leather according to the present invention;

FIG. 2 is a schematic structural view of a solid silica gel leather of the present invention;

wherein, 1-silica gel skin with lines and 2-base cloth.

Detailed Description

The following further describes embodiments of the present invention with reference to the drawings.

In the following examples, commercially available silica gels are used, and preferably, the properties shown in Table 1 are satisfied, and in the examples, a 1160 type solid rubber compound is used as an example for description.

Table 1 specification of solid silica gel

Item	Unit of	Detection standard	Parameter range	Model 1160
					Density of	g/cm3	GB/T 533-2008	1.1-1.3	1.16
Hardness of	Shore A	GB/T 531.1-2008	40-65	57
					Tensile strength	≥Mpa	GB/T 528-1998	8.5-10	9.5
Elongation percentage	≥％	GB/T 528-1998	300-400	360
					Tear strength	≥KN/m	GB/T 529-2008	20-40	38
Shrinkage rate	％	GJB 5873-2006	3.0-4.0	3.3
					Rebound resilience	≥％	GB/T 1681-2009	40-55	52

The platinum vulcanizing agents are A-202 and B-213, and are purchased from silica gel Co., Ltd (available on the market). The A agent and the B agent in the platinum vulcanizing agent are matched with solid silica gel according to the recommended proportion for use. The color paste is a conventional commercial product.

The main component of the hand feeling oil is vinyl siloxane with the model of LA-P01-1, which is purchased from Wensheng rubber and plastic technology Limited company of Dongguan city (all available in the market as silica gel hand feeling oil).

First, a specific embodiment of the preparation method of the solid silica gel leather of the present invention

Example 1

The preparation method of the solid silica gel leather of the embodiment is shown in fig. 1, and comprises the following steps:

(1) mixing solid silica gel, color paste and platinum vulcanizing agent uniformly, wherein the ratio of the color paste to the solid silica gel is 2%, and in the platinum vulcanizing agent, the ratio of the agent A to the solid silica gel is 1% and the ratio of the agent B to the platinum vulcanizing agent is 1.2%;

(2) the uniformly mixed silica gel enters a calender to extrude silica gel sheets meeting the requirements of thickness and width, and meanwhile, grains on the surface of the leather are extruded through a grain film (made of a PP grain film) to generate a skin;

in other embodiments, the textured film may also be textured paper or a PET transfer textured film or HTR textured film.

(3) The skin with grains coming out of the calender enters a cloth sticking machine and is pressed with base cloth (polyester material) which is subjected to corona; in other embodiments, non-woven fabrics or microfiber bass fabrics may be used as the base fabric.

(4) After coming out of the cloth sticking machine, putting the cloth into an oven to be vulcanized for 5 minutes at the temperature of 130 ℃;

(5) after the silicon rubber leather and the grain film are taken out of the furnace channel, the silicon rubber leather and the grain film are respectively rolled by two rolling machines;

(6) transferring the coiled silica gel leather to an unreeling machine of a surface oil coating line, and coating hand feeling oil while unreeling, wherein the coating thickness of the hand feeling oil is 0.05-0.2 mm.

(7) After being coated with hand feeling oil, the mixture is put into a coating line red oven to be baked for 3 minutes at 165 ℃ for vulcanization and then is rolled.

Example 2

The preparation method of the solid silica gel leather of the embodiment is different from that of the embodiment 1 only in that:

in the step (1), the adding proportion of the color paste is 1%; the addition ratio of the agent A was 0.5%, and the addition ratio of the agent B was 1%.

In the step (4), the temperature of the primary vulcanization is 150 ℃ and the time is 6 min.

In the step (7), the temperature of final vulcanization is 180 ℃ and the time is 4 min.

Example 3

The preparation method of the solid silica gel leather of the embodiment is different from that of the embodiment 1 only in that:

in the step (1), the adding proportion of the color paste is 3 percent; the addition ratio of the agent A was 1.5%, and the addition ratio of the agent B was 1.5%.

In the step (4), the temperature of the primary vulcanization is 115 ℃ and the time is 7 min.

In the step (7), the final vulcanization temperature is 150 ℃ and the time is 5 min.

Second, the specific embodiment of the solid silica gel leather of the present invention

Example 4

The silica gel leather of this example, corresponding to the product obtained by the preparation method of example 1, has a structure diagram as shown in fig. 2, and includes a silica gel leather 1 with a texture, a base fabric 2 and a hand feeling oil layer.

The silica gel skin 1 with the lines is formed by vulcanizing solid silica gel, wherein one side surface of the silica gel skin is provided with the line road surface.

The hand feeling oil layer is attached to the grain pavement of the silica gel skin; because the hand feeling oil is coated on the textured pavement after the initial vulcanization, after the final vulcanization, the joint position of the hand feeling oil and the silica gel skin is provided with a permeation transition layer formed by the mutual permeation of the silica gel skin and the hand feeling oil; the presence of the penetrating transition layer may increase the abrasion resistance of the solid silicone leather.

The base cloth is polyester knitted fabric, and the laminating is kept away from on the oil layer's of feeling side surface at the silica gel skin, because the base cloth is in the same place with the pressfitting of silica gel piece (the precursor of silica gel skin) before preliminary vulcanization, through common preliminary vulcanization and final vulcanization process, mutual interlude, tangle can take place for the pressfitting face between them, forms the transition layer that entangles, and then reaches better, more unanimous combination effect.

The leather products obtained by the preparation methods of the examples 2 and 3 have basically the same structure as that of the example 4.

Third, Experimental example

The environmental protection characteristics and physical characteristics of the solid silica gel leather obtained by the preparation method of example 1 were measured, and the results are shown in tables 2 to 6 below. In table 2, each test item was performed according to the specification of the method for detecting volatile organic compounds in the non-metallic materials in VDA277 vehicle.

TABLE 2 TVOC and other test results of the solid silica gel leather obtained in example 1

(in the table, N.D. represents no detection; and P represents pass.)

Odor detection experiments were performed as follows:

a sample of 100 x 200mm is placed in a wide-mouth glass odor bottle (1000ml) closed tightly with a ground stopper, sealed with the stopper, and placed in a pre-heated incubator:

scheme 1: keeping the temperature at 23 ℃ for 24h +/-1 h, taking out the test container after the standing time is reached, and directly evaluating;

scheme 2: keeping the temperature at 40 ℃ for 24h +/-1 h, taking out the test container after the standing time is reached, and directly evaluating;

scheme 3: keeping at 80 + -2 deg.C for 2h + -10 min, taking out the odor bottle, naturally cooling to 60 + -5 deg.C, and immediately opening the bottle stopper for odor identification and grading. The odor ratings are specified in Table 3.

TABLE 3 odor Property rating Specification

The results of the evaluation of odor performance are shown in tables 4 and 5.

Table 4 evaluation of odor properties of solid silica gel leather obtained in example 1 by a person

Table 5 odor test results of the solid silica gel leather obtained in example 1

From the test results, the leather obtained in the examples has the smell reaching 2.5 grade, no benzene, toluene and xylene are detected, the TVOC content is low, and the leather has natural advantages compared with the existing PVC interior material.

The physical and mechanical properties of the solid silica gel leather obtained in example 1 were evaluated, and the results are shown in table 6.

Table 6 results of measuring physical and mechanical properties of solid silica gel leather obtained in example 1

As can be seen from the above table, the solid silica gel leather of the examples has excellent physical and mechanical properties and outstanding product performance. Meanwhile, the whole manufacturing process has no output of waste water, waste liquid and the like, and the silica gel waste can be repeatedly utilized, so that the method is very suitable for industrial production of silica gel.