阅读说明：本技术 一种外墙面砖专用清洗剂及其制备方法 (Special cleaning agent for exterior wall tiles and preparation method thereof ) 是由 王金凤 谷满振 吴加柱 古家兴 何海 陆顺忠 于 2021-07-30 设计创作，主要内容包括：本申请涉及清洗剂技术领域,尤其涉及一种外墙面砖专用清洗剂,由如下重量百分比的组分组成：无机酸4-6wt%；有机酸4-8wt%；辛基酚聚氧乙烯醚10-20wt%；氟化铵1-2wt%；复合缓蚀剂0.05-0.15wt%；增效剂0.2-0.4 wt%；水余量；所述复合缓蚀剂由有机缓蚀剂、无机缓蚀剂和植物缓蚀剂组成；所述植物缓蚀剂由皂角提取物、甘草根提取物和刺梨叶提取物组成。本申请中制得的清洗剂,具有去污能力强,且对水泥胶凝体系和面砖釉面损伤较小的优点。(The application relates to the technical field of cleaning agents, in particular to a special cleaning agent for exterior wall tiles, which comprises the following components in percentage by weight: 4-6wt% of inorganic acid; 4-8wt% of organic acid; 10-20wt% of octyl phenol polyoxyethylene ether; 1-2wt% of ammonium fluoride; 0.05 to 0.15 weight percent of composite corrosion inhibitor; 0.2 to 0.4 weight percent of synergist; the balance of water; the composite corrosion inhibitor consists of an organic corrosion inhibitor, an inorganic corrosion inhibitor and a plant corrosion inhibitor; the plant corrosion inhibitor consists of a Chinese honeylocust fruit extract, a licorice root extract and a roxburgh rose leaf extract. The cleaning agent prepared in the application has the advantages of being strong in dirt-removing power and small in damage to a cement gelling system and a face brick glaze surface.)

1. The special cleaning agent for the exterior wall tile is characterized by comprising the following components in percentage by weight:

4-6wt% of inorganic acid;

4-8wt% of organic acid;

10-20wt% of octyl phenol polyoxyethylene ether;

1-2wt% of ammonium fluoride;

0.5-1.5 wt% of composite corrosion inhibitor;

0.2 to 0.4 weight percent of synergist;

the balance of water;

the composite corrosion inhibitor consists of an organic corrosion inhibitor, an inorganic corrosion inhibitor and a plant corrosion inhibitor;

the plant corrosion inhibitor consists of a Chinese honeylocust fruit extract, a licorice root extract and a roxburgh rose leaf extract;

the preparation steps of the plant corrosion inhibitor are as follows:

a. cleaning fructus Gleditsiae Abnormalis, Glycyrrhrizae radix and folium Rosae Normalis, sun drying, grinding respectively, soaking the ground product in 70-75% ethanol water solution, adjusting pH to 7-9 by adding sodium bicarbonate, and filtering to remove residue to obtain pre-extractive solution;

b. and (b) firstly, carrying out centrifugal separation on the pre-extraction solution prepared in the step a, carrying out reflux extraction on the upper layer solution, adding anhydrous sodium sulfate, drying and filtering to obtain plant extracts, and mixing the plant extracts of the three components according to the corresponding weight parts to obtain the plant corrosion inhibitor for later use.

2. The special cleaning agent for the exterior wall tile as claimed in claim 1, wherein the composite corrosion inhibitor comprises an inorganic corrosion inhibitor, an organic corrosion inhibitor and a plant corrosion inhibitor in a weight ratio of 1: (1.0-1.2): (2-3).

3. The special cleaning agent for the exterior wall tile as claimed in claim 2, wherein the plant corrosion inhibitor is prepared from Chinese honeylocust fruit extract, licorice root extract and rosa roxburghii tratt leaf extract according to a weight ratio of 1: (2-3): (0.5-0.8).

4. The special cleaning agent for the exterior wall tile as claimed in claim 1, wherein the inorganic corrosion inhibitor is prepared from sodium nitrite, zinc molybdate and sodium chromate in a weight ratio of 1: (2-3): (0.03-0.05).

5. The special cleaning agent for the exterior wall tile according to claim 1, wherein the organic corrosion inhibitor is prepared from ethanolamine, benzotriazole and alkylphenol polyoxyethylene ether according to a weight ratio of 1: (0.1-0.2): (0.03-0.05).

6. The special cleaning agent for the exterior wall tiles as claimed in claim 1, wherein the inorganic acid is prepared from phosphoric acid, hydrogen chloride and carbonic acid according to a weight ratio of 1: (2-3): (1.0-1.2).

7. The special cleaning agent for the exterior wall tiles as claimed in claim 1, wherein the organic acid is prepared from citric acid, tartaric acid and oxalic acid in a weight ratio of 1: (2-3): (5-8).

8. The special cleaning agent for the exterior wall tile as claimed in claim 1, wherein the synergist comprises one or more of polyoxyethylene lauryl ether, zinc sulfate and sodium alginate.

9. A preparation method of the special cleaning agent for the exterior wall tiles as claimed in any one of claims 1 to 8 is characterized by comprising the following preparation steps:

s1, mixing inorganic acid, organic acid, polyoxyethylene octylphenol ether, ammonium fluoride and water in corresponding parts by weight to prepare a mixed solution A;

and S2, adding the composite corrosion inhibitor and the synergist into the mixed solution A according to the corresponding parts by weight, and obtaining the special cleaning agent for the exterior wall tile.

Technical Field

The application relates to the technical field of cleaning agents, in particular to a special cleaning agent for exterior wall tiles and a preparation method thereof.

Background

The grade of the decorative material of the exterior wall of the modern city building is continuously improved, and the appearance of the building is newly marked from the original single cement to various exterior wall tiles, glass curtain walls and the like, so that strong visual impact is brought to people. However, in our daily life, as the face bricks are blown by wind and become dirty with the age, the face bricks can accumulate dirt, which not only affects the beauty but also pollutes the environment, therefore, the face bricks need to be cleaned regularly by using the cleaning agent for the face bricks to ensure the beauty.

The related technology discloses a cleaning agent for cleaning an outer wall tile, which comprises the following components in parts by weight: 8-15 parts by weight of hydrogen chloride; 3-8 parts by weight of oxalic acid; 50-90 parts by weight of water. The cleaning agent has low cost, can efficiently clean the external wall tiles, has strong dirt-removing capacity, easily causes damage to the glaze surface of the tiles, has large side effect, and can cause irreversible damage to the external wall tiles after long-term use.

Therefore, the cleaning agent special for the exterior wall tile and the preparation method thereof are provided for safely applying the cleaning agent to the exterior wall tile, ensuring the dirt-removing power and reducing the damage to the tile glaze.

Disclosure of Invention

In order to ensure the cleaning capability of the cleaning agent and reduce the side effect, the application provides the special cleaning agent for the outer wall face brick and the preparation method thereof.

The application provides a special cleaning agent for exterior wall tiles, and adopts the following technical scheme:

the special cleaning agent for the outer wall face brick comprises the following components in percentage by weight:

4-6wt% of inorganic acid;

4-8wt% of organic acid;

10-20wt% of octyl phenol polyoxyethylene ether;

1-2wt% of ammonium fluoride;

0.5-1.5 wt% of composite corrosion inhibitor;

0.2 to 0.4 weight percent of synergist;

the balance of water;

the composite corrosion inhibitor consists of an inorganic corrosion inhibitor, an organic corrosion inhibitor and a plant corrosion inhibitor;

the plant corrosion inhibitor consists of a Chinese honeylocust fruit extract, a licorice root extract and a roxburgh rose leaf extract;

the preparation steps of the plant corrosion inhibitor are as follows:

a. cleaning fructus Gleditsiae Abnormalis, Glycyrrhrizae radix and folium Rosae Normalis, sun drying, grinding respectively, soaking the ground product in 70-75% ethanol water solution, adjusting pH to 7-9 by adding sodium bicarbonate, and filtering to remove residue to obtain pre-extractive solution;

b. and (b) firstly, carrying out centrifugal separation on the pre-extraction solution prepared in the step a, carrying out reflux extraction on the upper layer solution, adding anhydrous sodium sulfate, drying and filtering to obtain plant extracts, and mixing the plant extracts of the three components according to the corresponding weight parts to obtain the plant corrosion inhibitor for later use.

By adopting the technical scheme, the corrosion inhibition effect of the cleaning solution is ensured by the compound use of the inorganic corrosion inhibitor, the organic corrosion inhibitor and the plant corrosion inhibitor, the damage of acidic components to the glazed tile in the cleaning process is further reduced, and the saponin extract, the licorice root extract and the roxburgh rose leaf extract in the plant corrosion inhibitor have the advantages of green and environment-friendly raw materials and components, and less pollution and toxic and side effects.

The saponin extract and the licorice extract have certain cleaning capacity and biological alkalinity, and can cooperate with each other under the blending action of the roxburgh rose leaf extract to form a protective film adhered to the surface of the glazed tile, so as to achieve the corrosion inhibition effect, and the saponin extract and trace calcium oxalate crystal fibers, ammonium glycyrrhetate and the like of the licorice extract residual in a cell matrix can form a small amount of composite fibers which can be fully dispersed and combined on the protective film, so as to improve the corrosion inhibition effect of the protective film.

Preferably, the composite corrosion inhibitor is prepared from an organic corrosion inhibitor, an inorganic corrosion inhibitor and a plant corrosion inhibitor according to a weight ratio of 1: (1.0-1.2): (2-3).

By adopting the technical scheme, the inorganic corrosion inhibitor, the organic corrosion inhibitor and the plant corrosion inhibitor which are proportioned have better compounding effect, can assist the plant corrosion inhibitor to quickly form a film, have high film forming stability, are not easy to damage, and can remarkably improve the corrosion inhibition effect of the plant corrosion inhibitor, thereby reducing the damage to the glazed tile.

Preferably, the plant corrosion inhibitor is prepared from saponin extract, licorice root extract and roxburgh rose leaf extract according to a weight ratio of 1: (2-3): (0.5-0.8).

By adopting the technical scheme, the plant corrosion inhibitor with the proportion has a good synergistic effect of the three, can be adhered to the surface of the glazed tile to form a stable protective film, and composite fibers combined on the protective film are dispersed and dense, so that the cleaning agent has an excellent corrosion inhibition effect, and the glazed tile wall is not easily damaged.

Preferably, the inorganic corrosion inhibitor is prepared from sodium nitrite, zinc molybdate and sodium chromate in a weight ratio of 1: (2-3): (0.03-0.05).

By adopting the technical scheme, the inorganic corrosion inhibitor prepared according to the proportion has good covering and film forming properties, can effectively assist in forming a film, reduces the damage of acidic liquid in the cleaning agent to the glazed tile, and further ensures the corrosion inhibition effect of the cleaning agent.

Preferably, the organic corrosion inhibitor is prepared from ethanolamine, benzotriazole and alkylphenol polyoxyethylene ether according to the weight ratio of 1: (0.1-0.2): (0.03-0.05).

By adopting the technical scheme, the organic corrosion inhibitor prepared according to the proportion has stronger surface activity, can effectively ensure the stability and the adhesion effect of a film structure, further reduces the damage of acid liquid in a cleaning agent to glazed tiles, and achieves excellent corrosion inhibition effect.

Preferably, the inorganic acid is prepared from phosphoric acid, hydrogen chloride and carbonic acid in a weight ratio of 1: (2-3): (1.0-1.2).

By adopting the technical scheme, the inorganic acid with the proportion can reduce the damage to the glazed tile while removing most impurities, and can be well matched with the composite corrosion inhibitor to ensure the corrosion inhibition effect of a film forming structure of the glazed tile.

Preferably, the organic acid is prepared from citric acid, tartaric acid and oxalic acid in a weight ratio of 1: (2-3): (5-8).

By adopting the technical scheme, the organic acid with the proportion has good matching effect with the composite corrosion inhibitor while the majority of impurities can be removed, the stability of a film forming structure can be effectively ensured, and then the damage of a pickling solution to the glazed tile is reduced.

Preferably, the synergist is composed of one or more of polyoxyethylene lauryl ether, zinc sulfate and sodium alginate.

By adopting the technical scheme, the synergist of the components can effectively enhance the cleaning effect of the cleaning solution, can play a corrosion inhibition effect to a certain extent, and endows the cleaning solution with relatively excellent performance.

In a second aspect, the application provides a preparation method of a special cleaning agent for exterior wall tiles, which adopts the following technical scheme:

a preparation method of a special cleaning agent for exterior wall tiles comprises the following steps:

s1, mixing inorganic acid, organic acid, polyoxyethylene octylphenol ether, ammonium fluoride and water in corresponding parts by weight to prepare a mixed solution A;

and S2, adding the composite corrosion inhibitor and the synergist into the mixed solution A according to the corresponding parts by weight, and obtaining the special cleaning agent for the exterior wall tile.

By adopting the technical scheme, the process is simple, various conditions are easy to control, and meanwhile, raw materials are easy to obtain, the environment-friendly cleaning agent is green and less in pollution, so that the low-corrosivity cleaning agent with stable performance can be obtained in large-scale industrial production.

In summary, the present application has the following beneficial effects:

1. according to the application, the corrosion inhibition effect of the cleaning solution is remarkably improved by the compound use of the inorganic corrosion inhibitor, the organic corrosion inhibitor and the plant corrosion inhibitor, and the plant corrosion inhibitor can be quickly and stably adhered to the surface of the glazed tile to form a film under the matched use of the inorganic corrosion inhibitor and the organic corrosion inhibitor, so that the protection and corrosion inhibition effects on the glazed tile are further realized;

2. according to the application, a stable film structure can be adhered to the surface of the glazed tile through the synergistic effect of the three components in the plant corrosion inhibitor, wherein the saponin extract and the trace calcium oxalate crystal fibers and ammonium glycyrrhizinate which are remained in a cell matrix of the liquorice extract can form a small amount of composite fibers, and the slow release effect of the plant corrosion inhibitor is further ensured through the combined dispersion of the composite fibers on the surface of the film;

3. the technology is simple, the raw materials are wide in source and easy to obtain, and various conditions are easy to control and achieve, so that the high-crack-resistance cleaning agent with stable performance can be produced in a large scale at low cost.

Detailed Description

The present application will be described in further detail with reference to examples.

The raw materials used in the examples of the present application are commercially available, except for the following specific descriptions:

polyoxyethylene octylphenol ether, CAS 2854-09-3;

ethanolamine, CAS 141-43-5;

alkylphenol ethoxylates, CAS 9002-93-1;

polyoxyethylene lauryl ether, CAS 9002-92-0.

Preparation example

Preparation example 1

A plant corrosion inhibitor is prepared by the following steps:

a. cleaning and drying gleditsia sinensis lam, licorice root and rosa roxburghii tratt leaf, respectively grinding, sieving with a 80-mesh sieve, mixing the ground product with 70% ethanol water solution in volume percentage concentration at a rotating speed of 200r/min for 30min, adjusting pH to 8 by adding sodium bicarbonate, and filtering to remove residues to obtain a pre-extraction solution;

b. firstly, carrying out centrifugal separation on the pre-extraction liquid prepared in the step a, namely centrifuging the pre-extraction liquid at the rotating speed of 3000r/min for 30min, then carrying out reflux extraction on the upper layer liquid, adding anhydrous sodium sulfate, drying and filtering to obtain a plant extract, and then mixing the saponin extract, the licorice root extract and the roxburgh rose leaf extract according to the weight ratio of 1: 1: 0.3, and preparing the plant corrosion inhibitor for later use.

Preparation example 2

A plant corrosion inhibitor is different from the preparation example 1 in that in the step a, the saponin extract, the licorice root extract and the roxburgh rose leaf extract are mixed according to the weight ratio of 1: 2: 0.5 mixing.

Preparation example 3

A plant corrosion inhibitor is different from the preparation example 1 in that in the step a, the saponin extract, the licorice root extract and the roxburgh rose leaf extract are mixed according to the weight ratio of 1: 2.5: 0.65 mixing.

Preparation example 4

A plant corrosion inhibitor is different from the preparation example 1 in that in the step a, the saponin extract, the licorice root extract and the roxburgh rose leaf extract are mixed according to the weight ratio of 1: 3: 0.8 mixing.

Preparation example 5

A plant corrosion inhibitor is different from the preparation example 1 in that in the step a, the saponin extract, the licorice root extract and the roxburgh rose leaf extract are mixed according to the weight ratio of 1: 4: 1.0 mixing.

Performance test

100ml of the cleaning agent prepared in each of examples and comparative examples was used as a test object, 150mm x 10mm glazed tiles were subjected to coating cleaning for 5min, after each cleaning, the cleaning solution was flushed with cold flowing water, and the presence or absence of corrosion was observed, and if two of the three glazed tiles were corroded, the maximum number of times of cleaning and the defect area a/%, at which corrosion occurred, were recorded, and if no corrosion occurred, the above operations were repeated until corrosion occurred, and the test results were counted in the following tables 2, 3, 5, 6, and 7.

Examples

Example 1

The special cleaning agent for the exterior wall tiles comprises the following components in parts by weight as shown in Table 1, and is prepared by the following steps: s1, mixing inorganic acid, organic acid, polyoxyethylene octylphenol ether, ammonium fluoride and water in corresponding parts by weight, namely mixing at 800r/min for 45min to prepare a mixed solution A;

the inorganic acid is hydrogen chloride;

the organic acid is oxalic acid;

s2, adding the composite corrosion inhibitor and the synergist into the mixed solution A according to the corresponding weight parts, and mixing for 30min at the speed of 300r/min to obtain the special cleaning agent for the exterior wall tile;

the composite corrosion inhibitor is prepared from an inorganic corrosion inhibitor, an organic corrosion inhibitor and a plant corrosion inhibitor in a weight ratio of 1: 0.5: 1, preparing a composition;

the inorganic corrosion inhibitor is prepared from sodium nitrite, zinc molybdate and sodium chromate in a weight ratio of 1: 1: 0.02 composition;

the organic corrosion inhibitor is prepared from ethanolamine, benzotriazole and alkylphenol polyoxyethylene ether according to the weight ratio of 1: 0.05: 0.02 composition;

the plant corrosion inhibitor is the plant corrosion inhibitor prepared in the preparation example 1;

the synergist is polyoxyethylene lauryl ether.

Examples 2 to 6

The special cleaning agent for the exterior wall tiles is different from the cleaning agent in example 1 in that the components and the corresponding weights thereof are shown in Table 1.

TABLE 1 Components and weights (kg) thereof in examples 1-6

TABLE 2 Performance test results

As can be seen by combining examples 1-6 and table 2, the cleaning solution prepared in examples 1-6 has small damage and side effect on the glazed tile, the maximum cleaning times are both more than 20, and the A/% of the defect area is both less than 0.5%;

the most effective cleaning frequency of example 3 is 22 times, and the defect area a/% is only 0.35%, it can be seen that the optimal amount of each component in example 3 is the amount of the above components, namely, the saponin extract, the licorice root extract and the rosa roxburghii leaf extract have the synergistic effect while the components are relatively green and have low pollution, and can be adhered to the surface of the glazed tile to form a protective film, and the saponin extract and the licorice root extract are left in trace calcium oxalate crystal fibers and ammonium glycyrrhizinate and the like in the cell matrix to form composite fibers, and the corrosion inhibition effect of the protective film is ensured by the dispersive combination of the composite fibers.

Example 7

The special cleaning agent for the outer wall facing brick is different from the cleaning agent in the embodiment 1 in that the composite corrosion inhibitor is prepared from an organic corrosion inhibitor, an inorganic corrosion inhibitor and a plant corrosion inhibitor in a weight ratio of 1: 1: 2.

Example 8

The special cleaning agent for the outer wall facing brick is different from the cleaning agent in the embodiment 1 in that the composite corrosion inhibitor is prepared from an organic corrosion inhibitor, an inorganic corrosion inhibitor and a plant corrosion inhibitor in a weight ratio of 1: 1.1: 2.5.

Example 9

The special cleaning agent for the outer wall facing brick is different from the cleaning agent in the embodiment 1 in that the composite corrosion inhibitor is prepared from an organic corrosion inhibitor, an inorganic corrosion inhibitor and a plant corrosion inhibitor in a weight ratio of 1: 1.2: 3, and (3).

Example 10

The special cleaning agent for the outer wall facing brick is different from the cleaning agent in the embodiment 1 in that the composite corrosion inhibitor is prepared from an organic corrosion inhibitor, an inorganic corrosion inhibitor and a plant corrosion inhibitor in a weight ratio of 1: 1.5: 4.

Comparative example 1

The special cleaning agent for the outer wall facing brick is different from the cleaning agent in the embodiment 1 in that the composite corrosion inhibitor does not contain a plant corrosion inhibitor.

TABLE 3 Performance test results

By combining the example 1, the examples 7 to 10 and the comparative example 1 and combining the table 3, the cleaning solution prepared in the examples 7 to 10 has small damage and side effect on the glazed tile, the maximum cleaning times are both more than 22, and the A/% of the defect area is both less than 0.4%;

in the comparative example 1, because no plant corrosion inhibitor is added, the composite corrosion inhibitor after the plant corrosion inhibitor is lacked is greatly reduced in corrosion inhibition performance, the damage and the side effect to the glazed tile are large, the maximum cleaning frequency is only 10 times, and the A/% of the defect area is as high as 1.25%;

the embodiment 8 is the best embodiment, the maximum cleaning times are 23 times, and the A/% of the defect area is only 0.35%, thus the composite corrosion inhibitor in the embodiment 8 is the best mixture ratio, namely the composite corrosion inhibitor is prepared from an organic corrosion inhibitor, an inorganic corrosion inhibitor and a plant corrosion inhibitor according to the weight ratio of 1: 1.1: 2.5, the complex formulation has the best effect, can form films on an anode and a cathode respectively, obviously improves the corrosion inhibition effect of the cleaning solution, and further reduces the damage to the glazed tile.

Examples 11 to 14

The special cleaning agent for the exterior wall tile is different from the cleaning agent in the embodiment 1 in that the using conditions of the used composite corrosion inhibitor are different, and the specific corresponding relation is shown in table 4.

TABLE 4 comparative table of use of plant corrosion inhibitors in examples 11-14

Group of	Plant corrosion inhibitor
		Example 11	Prepared from preparation example 2
Example 12	Prepared from preparation example 3
		Example 13	Prepared from preparation example 4
Example 14	Prepared from preparation example 5

Comparative example 2

The special cleaning agent for the exterior wall tile is different from the cleaning agent in the embodiment 1 in that the plant corrosion inhibitor does not contain saponin extracts.

Comparative example 3

The special cleaning agent for the exterior wall tile is different from the cleaning agent in the embodiment 1 in that the plant corrosion inhibitor does not contain licorice root extract.

Comparative example 4

The special cleaning agent for the exterior wall tile is different from the cleaning agent in the embodiment 1 in that the plant corrosion inhibitor does not contain a roxburgh rose leaf extract.

Comparative example 5

The special cleaning agent for the exterior wall tile is different from the cleaning agent in the embodiment 1 in that the plant corrosion inhibitor does not contain saponin extracts and licorice root extracts.

Comparative example 6

The special cleaning agent for the exterior wall tile is different from the cleaning agent in the embodiment 1 in that the plant corrosion inhibitor does not contain a saponin extract and a rosa roxburghii leaf extract.

Comparative example 7

The special cleaning agent for the exterior wall tile is different from the cleaning agent in the embodiment 1 in that the plant corrosion inhibitor does not contain licorice root extract and roxburgh rose leaf extract.

TABLE 5 Performance test results

As can be seen by combining examples 1, 11-14, and 2-7 and by combining Table 5, the cleaning solutions prepared in examples 11-14 have less damage and side effects on the glazed tile, the maximum cleaning times are all greater than 22, and the A/% defect area is less than 0.4%;

in comparative examples 2-7, the plant corrosion inhibitor lacks part of components, so that three components cannot play a synergistic effect, the corrosion inhibition performance is greatly reduced, the damage and the side effect to glazed tiles are large, the maximum cleaning times are all lower than 16 times, and the A/% of the defect area is higher than 0.20%;

example 12 is the best example, the maximum cleaning times are 24 times, and the A/% of the defect area is only 0.08%, thus the plant corrosion inhibitor in example 12 is the best mixture ratio, namely the plant corrosion inhibitor is prepared from saponin extract, licorice root extract and roxburgh rose leaf extract according to the weight ratio of 1: 0.25: 0.65, the synergistic effect is better, the saponin extract can be adhered to form a film with calcium oxalate cubic crystals, ammonium glycyrrhetate and the like in the licorice extract under the blending action of the rosa roxburghii tratt leaf extract, so that the cleaning agent is endowed with excellent corrosion inhibition effect, and the glazed tile wall is not easily damaged.

Example 15

The special cleaning agent for the exterior wall tile is different from the cleaning agent in the embodiment 1 in that an inorganic corrosion inhibitor is prepared from sodium nitrite, zinc molybdate and sodium chromate in a weight ratio of 1: 2: 0.03 composition.

Example 16

The special cleaning agent for the exterior wall tile is different from the cleaning agent in the embodiment 1 in that an inorganic corrosion inhibitor is prepared from sodium nitrite, zinc molybdate and sodium chromate in a weight ratio of 1: 2.5: 0.04.

Example 17

The special cleaning agent for the exterior wall tile is different from the cleaning agent in the embodiment 1 in that an inorganic corrosion inhibitor is prepared from sodium nitrite, zinc molybdate and sodium chromate in a weight ratio of 1: 3: 0.05 composition.

Example 18

The special cleaning agent for the exterior wall tile is different from the cleaning agent in the embodiment 1 in that an inorganic corrosion inhibitor is prepared from sodium nitrite, zinc molybdate and sodium chromate in a weight ratio of 1: 4: 0.06.

TABLE 6 results of Performance testing

By combining the example 1, the examples 15 to 18 and the table 6, it can be seen that the cleaning liquids prepared in the examples 15 to 18 have small damage and side effects on the glazed tile, the maximum cleaning times are both more than 21, and the A/% of the defect area is both less than 0.25%;

example 16 is the best example, the maximum cleaning times is 22, and the defect areas a/% are both only 0.20%, which shows that the inorganic corrosion inhibitor in example 16 is the best mixture ratio, i.e. the inorganic corrosion inhibitor is prepared from sodium nitrite, zinc molybdate and sodium chromate in a weight ratio of 1: 2.5: 0.04, the auxiliary film-forming property is better, so that the plant corrosion inhibitor can quickly form a film, the damage of acid liquid in the cleaning agent to the glazed tile is reduced, and the corrosion inhibition effect of the cleaning agent is ensured.

Example 19

The special cleaning agent for the exterior wall tile is different from the cleaning agent in the embodiment 1 in that the organic corrosion inhibitor is prepared from ethanolamine, benzotriazole and alkylphenol polyoxyethylene ether in a weight ratio of 1: 0.1: 0.03 composition.

Example 20

The special cleaning agent for the exterior wall tile is different from the cleaning agent in the embodiment 1 in that the organic corrosion inhibitor is prepared from ethanolamine, benzotriazole and alkylphenol polyoxyethylene ether in a weight ratio of 1: 0.15: 0.04.

Example 21

The special cleaning agent for the exterior wall tile is different from the cleaning agent in the embodiment 1 in that the organic corrosion inhibitor is prepared from ethanolamine, benzotriazole and alkylphenol polyoxyethylene ether in a weight ratio of 1: 0.2: 0.05 composition.

Example 22

The special cleaning agent for the exterior wall tile is different from the cleaning agent in the embodiment 1 in that the organic corrosion inhibitor is prepared from ethanolamine, benzotriazole and alkylphenol polyoxyethylene ether in a weight ratio of 1: 0.25: 0.06.

TABLE 7 results of Performance test

It can be seen by combining example 1, examples 19-22 and table 7 that the cleaning solutions prepared in examples 19-22 have less damage and side effects on glazed tiles, the maximum cleaning times are both greater than 20, and the defect area a/% is less than 0.25%;

the embodiment 20 is the best embodiment, the maximum cleaning times are 21 times, and the defect areas a/% are only 0.06%, which shows that the organic corrosion inhibitor in the embodiment 20 is the best mixture ratio, that is, the organic corrosion inhibitor is prepared from ethanolamine, benzotriazole and alkylphenol polyoxyethylene ether according to the weight ratio of 1: (0.1-0.2): (0.03-0.05), the stability of the film forming structure is stronger, the film structure is not easy to be damaged, the damage of acid liquid in the cleaning agent to the glazed tile is reduced, and the excellent corrosion inhibition effect is achieved.

Example 23

The special cleaning agent for the exterior wall tile is different from the cleaning agent in embodiment 1 in that inorganic acid is prepared from phosphoric acid, hydrogen chloride and ammonium fluoride according to a weight ratio of 1: 5: 1.

Example 24

The special cleaning agent for the exterior wall tile is different from the cleaning agent in embodiment 1 in that inorganic acid is prepared from phosphoric acid, hydrogen chloride and ammonium fluoride according to a weight ratio of 1: 6.5: 1.1.

Example 25

The special cleaning agent for the exterior wall tile is different from the cleaning agent in embodiment 1 in that inorganic acid is prepared from phosphoric acid, hydrogen chloride and ammonium fluoride according to a weight ratio of 1: 8: 1.2.

Example 26

The special cleaning agent for the exterior wall tile is different from the cleaning agent in the embodiment 1 in that the organic acid is prepared from citric acid, tartaric acid and oxalic acid in a weight ratio of 1: 2: 5.

Example 27

The special cleaning agent for the exterior wall tile is different from the cleaning agent in the embodiment 1 in that the organic acid is prepared from citric acid, tartaric acid and oxalic acid in a weight ratio of 1: 2.5: 6.5.

Example 28

The special cleaning agent for the exterior wall tile is different from the cleaning agent in the embodiment 1 in that the organic acid is prepared from citric acid, tartaric acid and oxalic acid in a weight ratio of 1: 3: 8.

Example 29

The special cleaning agent for the exterior wall tile is different from the cleaning agent in embodiment 1 in that zinc sulfate is used as a synergist.

Example 30

The special cleaning agent for the exterior wall tile is different from the cleaning agent in embodiment 1 in that a synergist is prepared from laurinol polyoxyethylene ether and zinc sulfate according to a weight ratio of 1: 1.

Example 31

The special cleaning agent for the exterior wall tile is different from the cleaning agent in embodiment 1 in that a synergist is prepared from laurinol polyoxyethylene ether, zinc sulfate and potassium chromate in a weight ratio of 1: 1: 1.

The present embodiment is only for explaining the present application, and it is not limited to the present application, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present application.