阅读说明：本技术 一种uv格丽斯及其制备方法 (UV glaze and preparation method thereof ) 是由 周雪荣 李红燕 于 2021-10-14 设计创作，主要内容包括：本发明涉及格丽斯技术领域,尤其涉及一种UV格丽斯及其制备方法,按质量百分比计,其组分包括超支化含磷环氧丙烯酸树脂45～60%、无机纳米颗粒3～8%、第一光引发剂1～2%、第二光引发剂1.5～3%、活性稀释剂30～45%、流平剂0.8～1.6%。其制备方法包括如下步骤：将超支化含磷环氧丙烯酸树脂、活性稀释剂,在500-850W超声波中超声分散30～40分钟,加入无机纳米颗粒,在800-1000W超声波中超声分散15～20分钟,使无机纳米颗粒得到均匀分散,加入第一光引发剂、第二光引发剂和流平剂,在800-1000W超声波中超声分散10～15分钟,得到成品。本发明使用超支化含磷环氧丙烯酸树脂和无机纳米颗粒,明显提高阻燃性能。同时,增加了UV格丽斯的耐磨性、附着力。通过第一光引发剂与第二光引发剂的配伍作用,有效提高固化速度。(The invention relates to the technical field of glaze, in particular to UV glaze and a preparation method thereof, wherein the UV glaze comprises the following components, by mass, 45-60% of hyperbranched phosphorus-containing epoxy acrylic resin, 3-8% of inorganic nanoparticles, 1-2% of a first photoinitiator, 1.5-3% of a second photoinitiator, 30-45% of a reactive diluent and 0.8-1.6% of a leveling agent. The preparation method comprises the following steps: the preparation method comprises the steps of ultrasonically dispersing hyperbranched phosphorus-containing epoxy acrylic resin and a reactive diluent in 500-plus-850W ultrasonic wave for 30-40 minutes, adding inorganic nano particles, ultrasonically dispersing in 800-plus-1000W ultrasonic wave for 15-20 minutes to uniformly disperse the inorganic nano particles, adding a first photoinitiator, a second photoinitiator and a flatting agent, and ultrasonically dispersing in 800-plus-1000W ultrasonic wave for 10-15 minutes to obtain a finished product. The hyperbranched phosphorus-containing epoxy acrylic resin and the inorganic nano-particles are used, so that the flame retardant property is obviously improved. Meanwhile, the wear resistance and the adhesive force of UV glaze are increased. The curing speed is effectively improved through the compatibility of the first photoinitiator and the second photoinitiator.)

1. A UV glaze, characterized by: the composition comprises, by mass, 45-60% of hyperbranched phosphorus-containing epoxy acrylic resin, 3-8% of inorganic nanoparticles, 1-2% of a first photoinitiator, 1.5-3% of a second photoinitiator, 30-45% of an active diluent and 0.8-1.6% of a leveling agent.

2. A UV glaze according to claim 1 wherein: the UV glaze comprises, by mass, 51-58% of hyperbranched phosphorous epoxy acrylic resin, 4.2-6.5% of inorganic nanoparticles, 1-1.5% of a first photoinitiator, 2-3% of a second photoinitiator, 34-42% of a reactive diluent and 0.8-1.2% of a leveling agent.

3. A UV glaze according to claim 1 wherein: the inorganic nano-particles are at least one or a mixture of two of SiO2 nano-particles and ZnSnO4 nano-particles, and the average particle size of the inorganic nano-particles is 30-50 nm.

4. A UV glaze according to claim 1 wherein: the first photoinitiator is one or a mixture of two of 2, 2-dimethoxy-phenyl acetophenone and 1-hydroxycyclohexyl phenyl ketone, and the second photoinitiator is benzophenone.

5. A UV glaze according to claim 1 wherein: the active diluent is one or a mixture of more of tripropylene glycol diacrylate, trimethylolpropane triacrylate, hydroxyethyl acrylate, isobornyl acrylate and N-vinyl pyrrolidone.

6. A UV glaze according to claim 1 wherein: the leveling agent is polyether siloxane copolymer.

7. A preparation method of UV glaze is characterized in that: the preparation method specifically comprises the steps of adding the hyperbranched phosphorus-containing epoxy acrylic resin and the reactive diluent into a beaker, carrying out ultrasonic dispersion in an ultrasonic cleaning machine with the power of 500 plus 850W for 30-40 minutes, adding the inorganic nanoparticles, carrying out ultrasonic dispersion in an ultrasonic cleaning machine with the power of 800 plus 1000W for 15-20 minutes to uniformly disperse the inorganic nanoparticles, adding the first photoinitiator, the second photoinitiator and the leveling agent, and carrying out ultrasonic dispersion in an ultrasonic cleaning machine with the power of 800 plus 1000W for 10-15 minutes to prepare the UV glaze.

[ technical field ] A method for producing a semiconductor device

The invention relates to the technical field of glaze, in particular to UV glaze and a preparation method thereof.

[ background of the invention ]

Glaze is a translucent to transparent pigment colorant for woodware, and is formed by dissolving resin in an organic solvent, and the used organic solvent can volatilize into the air in the film forming process and cause harm to the environment and human health. The traditional glaze also has the problems of low drying speed, poor transparency and difficult coloring. The UV glaze mainly comprises oligomer, photoinitiator, reactive diluent and other auxiliary agents, and has the advantages of short curing time, low curing temperature and low volatile component. However, such products generally have the disadvantage of poor flame retardancy, are extremely flammable when exposed to fire, and are prone to property damage and personal safety hazards. Therefore, a UV glaze with good flame retardant property is needed to solve the defects of the existing products.

[ summary of the invention ]

The invention aims to provide UV glaze and a preparation method thereof, which are used for overcoming the defects in the prior art.

In order to achieve the purpose, the invention adopts the following technical scheme:

a UV glaze, characterized by: the composition comprises, by mass, 45-60% of hyperbranched phosphorus-containing epoxy acrylic resin, 3-8% of inorganic nanoparticles, 1-2% of a first photoinitiator, 1.5-3% of a second photoinitiator, 30-45% of an active diluent and 0.8-1.6% of a leveling agent.

As a further improvement of the invention, the UV glaze comprises, by mass, 51-58% of hyperbranched phosphorous epoxy acrylic resin, 4.2-6.5% of inorganic nanoparticles, 1-1.5% of a first photoinitiator, 2-3% of a second photoinitiator, 34-42% of a reactive diluent and 0.8-1.2% of a leveling agent.

As a further improvement of the invention, the inorganic nanoparticles are SiO₂Nanoparticles, ZnSnO₄At least one or a mixture of two of the nano-particles, wherein the average particle diameter of the inorganic nano-particles is 30-50 nm.

As a further improvement of the invention, the first photoinitiator is one or a mixture of two of 2, 2-dimethoxy-phenyl acetophenone and 1-hydroxycyclohexyl phenyl ketone, and the second photoinitiator is benzophenone.

As a further improvement of the invention, the reactive diluent is one or a mixture of more of tripropylene glycol diacrylate, trimethylolpropane triacrylate, hydroxyethyl acrylate, isobornyl acrylate and N-vinyl pyrrolidone.

As a further improvement of the invention, the levelling agent is a polyether siloxane copolymer.

A preparation method of UV glaze is characterized in that: the preparation method specifically comprises the steps of adding the hyperbranched phosphorus-containing epoxy acrylic resin and the reactive diluent into a beaker, carrying out ultrasonic dispersion in an ultrasonic cleaning machine with the power of 500 plus 850W for 30-40 minutes, adding the inorganic nanoparticles, carrying out ultrasonic dispersion in an ultrasonic cleaning machine with the power of 800 plus 1000W for 15-20 minutes to uniformly disperse the inorganic nanoparticles, adding the first photoinitiator, the second photoinitiator and the leveling agent, and carrying out ultrasonic dispersion in an ultrasonic cleaning machine with the power of 800 plus 1000W for 10-15 minutes to prepare the UV glaze.

Compared with the prior art, the invention has the beneficial effects that:

1. the hyperbranched phosphorus-containing epoxy acrylic resin is used as an oligomer, and the addition amount of the reactive diluent can be reduced by utilizing the advantages of low viscosity and high compatibility of the hyperbranched polymer. In addition, compared with epoxy acrylic resin, the phosphorus-containing epoxy acrylic resin is used, so that the flame retardant property is obviously improved. The hyperbranched phosphorus-containing epoxy acrylic resin can form an expanded carbon layer after being burnt during burning, so that the hyperbranched phosphorus-containing epoxy acrylic resin plays a role in blocking temperature and oxygen, and the flame retardant property is improved.

2. Inorganic nanoparticles also have a flame-retardant effect, ZnSnO₄Zn and Sn ions in the catalyst have the function of catalyzing polymer to form carbon in the polymer combustion process, and SiO₂The nano particles can form a barrier layer on the surface of the carbon layer during combustion, and the flame retardant property can be effectively improved under the combined action of the nano particles and the carbon layer. The addition of the inorganic nano-particles also increases the wear resistance and adhesive force of UV glaze.

3. The first photoinitiator and the second photoinitiator have different characteristic absorption wavelengths, and the curing speed is effectively improved through compatibility.

[ detailed description ] embodiments

The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments. It is to be understood that the described embodiments are merely exemplary of the invention, and not restrictive of the full scope of the invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

The reagents used in the following examples are, unless otherwise specified, commercially available in a conventional manner.

Example 1

Adding 550g of hyperbranched phosphorus-containing epoxy acrylic resin and 352g of trimethylolpropane triacrylate into a beaker, ultrasonically dispersing for 30-40 minutes in a 500-850W ultrasonic cleaning machine, and adding 24.5g of SiO with the average particle size of 30-50 nm₂Nanoparticles and 24.5g ZnSnO with the average particle size of 30-50 nm₄And ultrasonically dispersing the nano particles in an ultrasonic cleaning machine of 800-1000W for 15-20 minutes to uniformly disperse the inorganic nano particles, adding 10g of 1-hydroxycyclohexyl phenyl ketone, 30g of benzophenone and 9g of polyether siloxane copolymer, and ultrasonically dispersing in the ultrasonic cleaning machine of 800-1000W for 10-15 minutes to prepare the UV Grice.

Examples 2 to 8

The UV glaze of examples 2 to 8 was prepared in the same manner as in example 1, and the weight ratios of the components thereof are shown in Table 1.

TABLE 1 compositions of examples 2 to 8 and their mass ratios (g)

Remarking: in Table 1, the symbol "\" indicates none.

Example 9 Performance testing

Respectively carrying out performance test on the UV glaze prepared in the embodiments 1-8, wherein the test items comprise: hardness test, adhesion test, wear resistance test and flame retardant property test. The hardness test method is based on GB/T6739-2006 paint film hardness determination by color paint and varnish pencil method. The adhesive force test method is based on GB/T4893.4-2013 part 4 of furniture surface paint film physical and chemical property test, adhesive force cross cutting determination. The method for testing the wear resistance is based on GB/T4893.4-2013 part 8 of furniture surface paint film physical and chemical property test, namely a method for testing the wear resistance. The test method of the flame retardant property is based on GB/T8624 and 2012 'grading of the combustion performance of building materials and products'.

Table 2 results of flame retardancy test of examples 1 to 8

The hyperbranched phosphorus-containing epoxy acrylic resin is used as an oligomer, and SiO with the average particle size of 30-50 nm is added₂Nanoparticles and ZnSnO₄The nano particles improve the flame retardant property of UV glaze. SiO2₂Nanoparticles and ZnSnO₄The addition of the nano particles also enhances the adhesive force and the wear resistance of the UV glaze.