阅读说明：本技术 一种膨胀型抗蚀掺合料及其制备方法 (Expansive anti-corrosion admixture and preparation method thereof ) 是由 秦哲焕 纪宪坤 徐可 郭城瑶 方博 于 2021-10-20 设计创作，主要内容包括：本发明提供了一种膨胀型抗蚀掺合料及其制备方法,属于建筑材料技术领域。所述膨胀型抗蚀掺合料由以下质量百分比的原料制成：40～60％粉煤灰,20～40％矿渣粉,5～15％轻烧氧化镁,5～10％氧化钙类膨胀剂,1～2％石膏,0.015～0.03％六偏磷酸钠。本发明制备的膨胀型抗蚀掺合料通过各组分的相互配合,可以弥补单一组分单掺的缺点,综合提高混凝土的抗裂性能、力学性能和耐久性能。(The invention provides an intumescent anti-corrosion admixture and a preparation method thereof, belonging to the technical field of building materials. The intumescent anti-corrosion admixture is prepared from the following raw materials in percentage by mass: 40-60% of fly ash, 20-40% of slag powder, 5-15% of light-burned magnesium oxide, 5-10% of calcium oxide expanding agent, 1-2% of gypsum and 0.015-0.03% of sodium hexametaphosphate. The intumescent anti-corrosion admixture prepared by the invention can make up the defect of single component and single admixture through the mutual matching of the components, and comprehensively improves the crack resistance, the mechanical property and the durability of concrete.)

1. The intumescent anti-corrosion admixture is characterized by being prepared from the following raw materials in percentage by mass: 40-60% of fly ash, 20-40% of slag powder, 5-15% of light-burned magnesium oxide, 5-10% of calcium oxide expanding agent, 1-2% of gypsum and 0.015-0.03% of sodium hexametaphosphate; the mass ratio of the fly ash to the slag powder is (1:1) - (3: 1).

2. The admixture for intumescent anticorrosion as claimed in claim 1, wherein the mass ratio of said light-burned magnesia to said calcium oxide type expanding agent is (1:2) - (3: 1).

3. The intumescent anti-corrosion admixture according to claim 1, wherein said fly ash has a specific surface area of 600 to 800m²Per kg, the specific surface area of the slag powder is 600-800 m²/kg。

4. The intumescent anti-corrosion admixture according to claim 1, wherein said lightly calcined magnesia is an M-type magnesia expansive agent, the MgO content is not less than 80 wt%, the hydration activity value t is 100-200 s, the specific surface area is not less than 200M²Per kg, 1.18mm screen residue is less than or equal to 0.5 percent.

5. The intumescent anti-corrosion admixture of claim 4, wherein said lightly calcined magnesia has a hydration activity value t of from 120 to 150 seconds.

6. The intumescent anti-corrosion admixture according to claim 1, wherein said calcium oxide based intumescent agent has a specific surface area of 200m or more²Per kg, 1.18mm screen residue is less than or equal to 0.5 percent.

7. The intumescent anti-corrosion admixture according to claim 1 wherein said gypsum is one or more of desulfurized gypsum, dihydrate gypsum, hemihydrate gypsum, anhydrite.

8. The intumescent anti-corrosion admixture of claim 1, wherein said sodium hexametaphosphate is food grade sodium hexametaphosphate, the total phosphate content is not less than 68%, and the inactive phosphate content is not more than 7.5%.

9. The process for preparing an intumescent anti-corrosion admixture according to any of claims 1 to 8, comprising the steps of:

s1, weighing the light-burned magnesium oxide, the calcium oxide expanding agent, the gypsum and the sodium hexametaphosphate according to a set ratio, and premixing for 10-30 min to obtain a mixture A; weighing the fly ash and the slag powder according to a set ratio, and grinding until the specific surface area is 600-800 m²Homogenizing and standing for 1d to obtain a mixture B;

s2, fully and uniformly mixing the mixture A and the mixture B in the step S1 to obtain the intumescent anti-corrosion admixture.

Technical Field

The invention belongs to the technical field of building materials, and particularly relates to an intumescent anti-corrosion admixture and a preparation method thereof.

Background

In recent years, the building industry in China is rapidly developed, the performance requirement on a concrete structure is higher and higher, the performance of the concrete needs to consider the workability and the strength grade of the concrete, also the crack control of the concrete and the compactness of the structure, and the requirement on durability is met. The shrinkage of concrete is an important factor causing the cracking of concrete, and in order to reduce the cracking risk of the concrete and improve the durability of the concrete, technical personnel in the construction industry explore technical approaches for compensating the shrinkage of the concrete, reducing the early temperature rise of the concrete and improving the chloride ion permeability resistance of the concrete from different aspects of processes, materials and the like, such as measures of adding admixtures, adopting cooling water for stirring, reducing the temperature of raw materials, adding expanding agents and the like.

Patent application CN104386939A discloses a composite admixture, a compounding method and a construction method of coal mine inner wall concrete, and the main purpose is to reduce hydration heat released by the concrete in the curing process, thereby reducing cracks generated by the concrete. The composite admixture comprises: fly ash, mineral powder, an expanding agent and a reduction type water reducing agent. Wherein the fly ash accounts for the total mass of the composite admixture in percentage by mass: 15-30%; the percentage of the mineral powder in the total mass of the composite admixture is as follows: 20-50%; the expanding agent and the composite admixture account for the following percentage by mass: 30-60%; when the shrinkage-reducing water reducer is in a solid state, the mass of the shrinkage-reducing water reducer accounts for the total mass of the composite admixture in percentage by mass: 0.5-2%; when the shrinkage-reducing water reducer is in a liquid state, the percentage of the fracture-solid mass of the shrinkage-reducing water reducer in the total mass of the composite admixture is as follows: 0.5 to 2 percent. The use of the expanding agent can improve the anti-cracking effect of the concrete, but can reduce the mechanical property of the concrete within a certain range; and the calcium oxide expanding agent has high early hydration rate, so that most of expansion energy is consumed in the concrete plasticity stage, the compensation shrinkage capacity in an effective expansion window is insufficient, the compensation period is short, and the expected compensation shrinkage effect cannot be achieved.

At present, high-quality admixture is added to prepare high-durability concrete, so that several kinds of heat release of hydration heat are reduced, and the structural compactness of the concrete is improved, thereby improving the durability. But the high-quality admixture has limited resources, higher cost and larger production energy consumption. Therefore, it is necessary to develop a concrete admixture which can solve the cracking of concrete, has sufficient shrinkage compensation capability, and can improve the mechanical properties and durability of concrete.

Disclosure of Invention

In order to solve the defects in the prior art and achieve the purpose, the invention provides an intumescent anti-corrosion admixture which comprises the following raw materials in percentage by mass: 40-60% of fly ash, 20-40% of slag powder, 5-15% of light-burned magnesium oxide, 5-10% of calcium oxide expanding agent, 1-2% of gypsum and 0.015-0.03% of sodium hexametaphosphate; the mass ratio of the fly ash to the slag powder is (1:1) - (3: 1).

Preferably, the mass ratio of the lightly calcined magnesia to the calcium oxide-based expanding agent is (1:2) to (3: 1).

Preferably, the specific surface area of the fly ash is 600-800 m²Per kg, the specific surface area of the slag powder is 600-800 m²/kg。

Preferably, the light-burned magnesia is an M-type magnesia expanding agent, the MgO content is more than or equal to 80 wt%, the hydration activity value t is 100-200 s, and the specific surface area is more than or equal to 200M²Per kg, 1.18mm screen residue is less than or equal to 0.5 percent.

Further preferably, the hydration activity value t of the light calcined magnesia is 120-150 s.

Preferably, the specific surface area of the calcium oxide expanding agent is more than or equal to 200m²Per kg, 1.18mm screen residue is less than or equal to 0.5 percent.

Preferably, the gypsum is one or more of desulfurized gypsum, dihydrate gypsum, semi-hydrated gypsum and anhydrite.

Preferably, the sodium hexametaphosphate is food-grade sodium hexametaphosphate, the total amount of phosphate is more than or equal to 68 percent, and the inactive phosphate is less than or equal to 7.5 percent.

The invention also provides a preparation method of the intumescent anti-corrosion admixture, which comprises the following steps:

s1, weighing the light-burned magnesium oxide, the calcium oxide expanding agent, the gypsum and the sodium hexametaphosphate according to a set ratio, and premixing for 10-30 min to obtain a mixture A; weighing the fly ash and the slag powder according to a set ratio, and grinding until the specific surface area is 600-800 m²Homogenizing and standing for 1d to obtain a mixture B;

s2, fully and uniformly mixing the mixture A and the mixture B in the step S1 to obtain the intumescent anti-corrosion admixture.

The invention combines the early expansion effect of the calcareous expanding agent and the medium-long term expansion effect of the light burned magnesium oxide, and better compensates the contraction of the concrete in each period. The hydration reaction period of the magnesium oxide can reach more than 30 days or even years according to different activities, and the specific delayed expansion of the magnesium oxide can compensate the temperature reduction and shrinkage of mass concrete and make up the problem of insufficient compensation and shrinkage capacity of calcium oxide expansion agents; but the magnesium oxide has low activity at normal temperature, and the hydration reaction rate of the magnesium oxide in a concrete structure with the hydration temperature rise lower than 40 ℃ still cannot meet the shrinkage of concrete; and the use of an expanding agent reduces the mechanical properties of the concrete. In the invention, the admixture with lower performance is ground and optimized, wherein weaker Si-O bonds and Al-O bonds are broken and the structure is rearranged, so that the content of amorphous substances in the admixture is increased, and the activity of the admixture can be improved; the higher specific surface area enables the admixture and cement particles to form a better particle size distribution and a more compact and stacked state, and the refinement of the fly ash can also improve the volcanic ash effect of the fly ash; the densification of the structure reduces the way of corrosive ions or harmful substances to infiltrate into the interior of the concrete; therefore, the refined admixture can not only improve the mechanical property of concrete, but also improve part of durability indexes. When the sodium hexametaphosphate is applied to the reinforced concrete, a compact passive film can be generated on the surface of the steel bar, so that water and chloride ions in the concrete are isolated from contacting the steel bar, and the durability of the reinforced concrete is further improved; but the concrete has certain retardation and can reduce the early strength of the concrete, and the invention can make up the defect of single component and single mixing by the mutual matching of the components, thereby comprehensively improving the crack resistance, the mechanical property and the durability of the concrete.

Compared with the prior art, the invention has the beneficial effects that:

(1) the admixture provided by the invention can compensate the shrinkage of concrete in each period and can also compensate the negative influence of the expanding agent on the mechanical property of the concrete; on the other hand, the defect that the early strength of the concrete is reduced by the traditional rust inhibitor, so that the form removal time is prolonged can be overcome, and the durability of the concrete can be improved; the admixture can comprehensively improve the crack resistance, the mechanical property and the durability of concrete through the mutual synergistic effect among the components;

(2) the raw materials of the fly ash and the slag powder adopted by the invention have lower performance, the dependence on high-quality raw materials of high-durability concrete is reduced, and the utilization rate of inferior admixtures is improved; after the powder grinding, the activity of the admixture is improved, so that the performance of the admixture is better, and the mechanical property and partial durability of the concrete can be improved.

Detailed Description

The technical solution of the present invention is described in detail and fully with reference to the following examples, it is obvious that the described examples are only a part of the examples of the present invention, and not all of the examples. All other embodiments, which can be derived by a person skilled in the art from the embodiments of the present invention without any inventive step, are within the scope of the present invention. Any equivalent changes or substitutions by those skilled in the art according to the following embodiments are within the scope of the present invention.

In the following examples and comparative examples, the MgO content of the light-burned magnesium oxide is not less than 80%, the hydration activity value t is 100-200 s, and the specific surface area is not less than 200m²Per kg, 1.18mm screen residue is less than or equal to 0.5 percent; the specific surface area of the calcium oxide expanding agent is more than or equal to 200m²Per kg, the 1.18mm screen residue is less than or equal to 0.5 percent, and the content of free calcium oxide (f-CaO) in the calcium oxide expanding agent is 50-65 percent; the sodium hexametaphosphate is food-grade sodium hexametaphosphate, the total amount of phosphate is more than or equal to 68 percent, and the inactive phosphate is less than or equal to 7.5 percent. The fly ash is prepared by taking class F II fly ash purchased from Anbang mining industry Limited liability company of Jiayuguan city as a raw material and mechanically grinding the raw material into the fly ash with the specific surface area of 600-800 m²Per kg of fly ash; the slag powder is prepared by taking S75 grade slag powder purchased from Anbang mining industry Limited liability company of Jiayuguan city as a raw material and mechanically grinding the raw material into powder with the specific surface of 600-800 m²-kg of slag powder; the gypsum is desulfurized gypsum, dihydrate gypsum, semi-hydrated gypsum and anhydrite which are commonly available in the market, one or more of the desulfurized gypsum, the dihydrate gypsum, the semi-hydrated gypsum and the anhydrite can be selected and mixed according to any ratio, and the desulfurized gypsum, the dihydrate gypsum, the semi-hydrated gypsum and the anhydrite are not listed in the following examples.

Example 1

This example provides an intumescent anti-corrosive admixture comprising by massThe raw materials are as follows: 60% of fly ash, 20% of slag powder (namely the mass ratio of the fly ash to the slag powder is 3:1), 13.97% of light-burned magnesia, 5% of a calcium oxide expanding agent (namely the mass ratio of the light-burned magnesia to the calcium oxide expanding agent is 2.8:1), 1% of gypsum and 0.03% of sodium hexametaphosphate; the content of MgO in the light-burned magnesia is 90.5 percent, the hydration activity value t is 120s, and the specific surface area is 275m²Per kg, 1.18mm screen residue is 0.2%; the content of free calcium oxide (f-CaO) in the calcium oxide expanding agent is 55.2 percent, and the specific surface area is 256m²Per kg, 1.18mm screen residue is 0.4%; the gypsum is anhydrite;

the preparation method of the intumescent anticorrosion admixture comprises the following steps:

s1, weighing the light-burned magnesium oxide, the calcium oxide expanding agent, the gypsum and the sodium hexametaphosphate according to the mixture ratio, and premixing for 30min to obtain a mixture A; respectively weighing class F II fly ash and class S75 slag powder, respectively grinding for 50min until the specific surface area is 600-800 m²The mixture B is obtained by uniformly mixing the raw materials and the mixture for 1 d; the actual measurement of the specific surface area of pulverized fuel ash obtained after grinding is 723m²Kg, the actual measurement of the specific surface area of the ground slag powder is 644m²/kg；

S2, fully and uniformly mixing the mixture A and the mixture B in the step S1 to obtain the intumescent anti-corrosion admixture.

Example 2

The embodiment provides an intumescent anti-corrosion admixture which is prepared from the following raw materials in percentage by mass: 46 percent of fly ash, 40 percent of slag powder, 5.07 percent of light-burned magnesia, 7.9 percent of calcium oxide expanding agent, 1 percent of gypsum and 0.03 percent of sodium hexametaphosphate; the content of MgO in the light-burned magnesia is 89.3 percent, the hydration activity value t is 150s, and the specific surface area is 305m²Per kg, 1.18mm screen residue is 0.2%; the content of free calcium oxide (f-CaO) in the calcium oxide expanding agent is 58.5 percent, and the specific surface area is 287m²Per kg, 1.18mm screen residue is 0.4%; the gypsum is desulfurized gypsum;

the preparation method of the intumescent anti-corrosion admixture is basically the same as that of the embodiment 1, and in the step S1, the light-burned magnesia and calcia are adoptedPremixing the expanding agent, gypsum and sodium hexametaphosphate for 10min, and pulverizing to obtain fly ash with specific surface area of 751m²Kg, the actual measurement of the specific surface area of the ground slag powder is 678m²/kg。

Example 3

The embodiment provides an intumescent anti-corrosion admixture which is prepared from the following raw materials in percentage by mass: 50% of fly ash, 30% of slag powder, 7.985% of light-burned magnesium oxide, 10% of calcium oxide expanding agent, 2% of gypsum and 0.015% of sodium hexametaphosphate; the content of MgO in the light-burned magnesia is 89.3 percent, the hydration activity value t is 200s, and the specific surface area is 296m²Per kg, 1.18mm screen residue is 0.3%; the content of free calcium oxide (f-CaO) in the calcium oxide expanding agent is 57.4 percent, and the specific surface area is 291m²Per kg, 1.18mm screen residue is 0.3%; the gypsum is semi-hydrated gypsum;

the intumescent anti-corrosion admixture was prepared in the same manner as in example 1.

Example 4

The embodiment provides an intumescent anti-corrosion admixture which is prepared from the following raw materials in percentage by mass: 40% of fly ash, 32.985% of slag powder, 15% of light-burned magnesium oxide, 10% of calcium oxide expanding agent, 2% of gypsum and 0.015% of sodium hexametaphosphate; the content of MgO in the light-burned magnesia is 84.7 percent, the hydration activity value t is 100s, and the specific surface area is 288m²Per kg, 1.18mm screen residue is 0.3%; the content of free calcium oxide (f-CaO) in the calcium oxide expanding agent is 63.3 percent, and the specific surface area is 275m²Per kg, 1.18mm screen residue is 0.4%; the gypsum is dihydrate gypsum;

the intumescent anti-corrosion admixture was prepared in the same manner as in example 1.

Comparative example 1

The comparative example prepares a composite admixture according to the method of example 1, and is different from the method of example 1 in that the composite admixture is prepared from the following raw materials in percentage by mass: 60 percent of fly ash, 20.03 percent of slag powder, 13.97 percent of light-burned magnesia, 5 percent of calcium oxide expanding agent and 1 percent of gypsum. That is, the composite admixture prepared in this comparative example did not contain sodium hexametaphosphate as compared with example 1.

Comparative example 2

The comparative example prepares a composite admixture according to the method of example 1, and is different from the method of example 1 in that the composite admixture is prepared from the following raw materials in percentage by mass: 59.93 percent of fly ash, 20 percent of slag powder, 13.97 percent of light-burned magnesia, 5 percent of calcium oxide expanding agent, 1 percent of gypsum and 0.1 percent of sodium hexametaphosphate. That is, the amount of sodium hexametaphosphate in the composite admixture prepared in this comparative example was increased as compared with example 1.

Comparative example 3

The comparative example prepares a composite admixture according to the method of example 1, and is different from the method of example 1 in that the composite admixture is prepared from the following raw materials in percentage by mass: 65% of fly ash, 15% of slag powder (namely the mass ratio of the fly ash to the slag powder is 4.3:1), 13.97% of light-burned magnesia, 5% of calcium oxide expanding agent, 1% of gypsum and 0.03% of sodium hexametaphosphate.

Comparative example 4

The comparative example prepares a composite admixture according to the method of example 1, and is different from the method of example 1 in that the composite admixture is prepared from the following raw materials in percentage by mass: 30 percent of fly ash, 50 percent of slag powder (namely the mass ratio of the fly ash to the slag powder is 0.6:1), 13.97 percent of light-burned magnesia, 5 percent of calcium oxide expanding agent, 1 percent of gypsum and 0.03 percent of sodium hexametaphosphate.

Comparative example 5

The comparative example prepares a composite admixture according to the method of example 4, and is different from the method of example 4 in that the composite admixture is prepared from the following raw materials in percentage by mass: 40% of fly ash, 32.985% of slag powder, 20% of light-burned magnesia, 5% of a calcium oxide expanding agent (namely the mass ratio of the light-burned magnesia to the calcium oxide expanding agent is 4:1), 2% of gypsum and 0.015% of sodium hexametaphosphate.

Comparative example 6

The comparative example prepares a composite admixture according to the method of example 4, and is different from the method of example 4 in that the composite admixture is prepared from the following raw materials in percentage by mass: 40% of fly ash, 32.985% of slag powder, 6% of light-burned magnesia, 19% of a calcium oxide expanding agent (namely the mass ratio of the light-burned magnesia to the calcium oxide expanding agent is 0.3:1), 2% of gypsum and 0.015% of sodium hexametaphosphate.

Performance testing

Preparing the intumescent anti-corrosion admixture prepared in examples 1-4 and the composite admixture prepared in comparative examples 1-6 into concrete according to the mixing ratio of the concrete in the table 1, and preparing a reference concrete 1 and a reference concrete 2 according to the mixing ratio in the table 1 as a reference; the intumescent anti-corrosion admixtures prepared in the examples and the composite admixtures prepared in the comparative examples are collectively referred to as admixtures in Table 1. The performance of various concrete and standard concrete is tested according to the standard of the test method for the performance of common concrete mixtures (GB/T50080-2016), the standard of the test method for the physical and mechanical properties of concrete (GB/T50081-2019) and the standard of the test method for the long-term performance and the durability of common concrete (GB/T50082-2009), and the test results are shown in Table 2.

TABLE 1 concrete mix proportion (kg/m)³)

The cement in the table 1 is P.O 42.5 cement produced by Gansu wine Steel Honda building materials Limited liability company; the fine aggregate is sand in district II produced by Gansu Yinji Industrial and trade Co Ltd; the coarse aggregate is 5-25 mm continuous graded broken stone produced by Jinta county glittering and translucent building material Co., Ltd; the expanding agent is FQY high-performance expanding agent produced by Wuhan three-source special building materials Limited liability company; the water reducing agent is a polycarboxylic acid water reducing agent produced by Wuhan three-source special building material Limited liability company; the water is tap water.

TABLE 2 concrete Performance test results

TABLE 2 concrete Performance test results

From the data in table 2, it can be seen that, compared with the reference concrete 1 and 2, the concrete prepared by using the expansive anti-corrosion admixture prepared in the example has obviously improved compressive strength at 7d, 28d and 60d, obviously reduced dry shrinkage at 28d, obviously enhanced chloride ion penetration resistance and sulfate corrosion resistance, and obviously reduced carbonization degree. Compared with a system adopting a common admixture or adding an expanding agent into the common admixture, the expanding type anti-corrosion admixture prepared by the invention can improve the working performance of concrete, improve the mechanical property of the concrete in the middle and later periods, compensate the shrinkage of the concrete, reduce the possibility of shrinkage cracking of the concrete and play a positive role in improving the durability of the concrete.

The concrete prepared from the composite admixture without sodium hexametaphosphate in comparative example 1 had a weaker chloride ion penetration resistance than the concrete prepared from the intumescent anti-corrosive admixture of example 1; the early strength and the later strength of the concrete prepared by the composite admixture with higher sodium hexametaphosphate in the comparative example 2 are reduced, and especially the early strength is greatly reduced; after the concrete is prepared by the composite admixture with the mass ratio of the fly ash to the slag powder being more than 3:1 in the comparative example 3, the compressive strength is reduced, and the reduction amplitude of the early strength is higher than that of the later strength; compared with the concrete prepared by the composite admixture with the mass ratio of the fly ash to the slag powder being lower than 1:1 in the comparative example 4, the machine-out slump of the concrete is reduced, and the permeability of chlorine ion resistance is obviously reduced. Compared with the concrete prepared by using the expansive type anti-corrosion admixture in the example 4, after the composite admixture of which the mass ratio of the light-burned magnesia to the calcium oxide type expanding agent exceeds 3:1 in the comparative example 5 is prepared into the concrete, the out-machine slump of the concrete is reduced from 215mm to 180mm, the compressive strength and the anti-carbonization capability of the concrete are reduced, and the 60d dry shrinkage rate is slightly increased; in the comparative example 6, after the concrete is prepared by the composite admixture of the light-burned magnesia and the calcium oxide expanding agent with the mass ratio of less than 1:2, the compressive strength of the concrete is reduced.

The results of the examples 1 and 4 and the comparative examples 3 to 6 show that when the mass ratio of the fly ash to the slag powder is 1: 1-3: 1 and the mass ratio of the light-burned magnesia to the calcium oxide expanding agent is 1: 2-3: 1, the concrete prepared from the composite admixture has the optimal performance, and the concrete has the advantages of high strength, low shrinkage, and excellent chloride ion penetration resistance, sulfate corrosion resistance and carbonization resistance. When the mass ratio of the fly ash to the slag powder is high, the hydration of the fly ash occurs in the later stage, and the early strength of the concrete is reduced due to excessive fly ash; when the mass ratio of the fly ash to the slag powder is low, the compactness of the concrete is reduced, so that the chlorine ion penetration resistance and the carbonization resistance are reduced. When the mass ratio of the light-burned magnesia and the calcium oxide expanding agent is high, the light-burned magnesia has stronger adsorbability to water, and absorbs the water reducing agent to reduce the working state of concrete; when the mass ratio of the light-burned magnesia to the calcium oxide expanding agent is low, the later-stage compensation shrinkage capacity of the concrete is reduced, and the crack resistance of the concrete is reduced.

In summary, in the technical scheme of the invention, when the light-burned magnesium oxide or sodium hexametaphosphate is removed or the dosage of the light-burned magnesium oxide or the sodium hexametaphosphate is changed and is not in a limited range, the performance of the concrete can be obviously reduced, and the purposes of simultaneously improving the shrinkage compensation capacity and the mechanical property and the durability of the concrete cannot be achieved. According to the technical scheme, the components are mutually cooperated, and the purpose of improving the comprehensive performance of the concrete can be achieved only when the using amount is within a limited range.

The above description is only a preferred embodiment of the present invention, and is not intended to limit the scope of the present invention. The present invention may be subject to various modifications and changes by any person skilled in the art. Any simple equivalent changes and modifications made in accordance with the protection scope of the present application and the content of the specification are intended to be included within the protection scope of the present invention.